S. Buchwald

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Synthesis of 4,5-dianilinophthalimide and related analogues for potential treatment of Alzheimer's disease via palladium-catalyzed amination.

E. Hennessy, S. Buchwald, 2005, The Journal of organic chemistry.

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

Stephen L. Buchwald, S. Buchwald, Paula Ruiz-Castillo, 2016, Chemical reviews.

Palladium-Mediated Arylation of Lysine in Unprotected Peptides.

S. Buchwald, B. Pentelute, Hong Geun Lee, 2017, Angewandte Chemie.

An integrated microreactor system for self-optimization of a Heck reaction: from micro- to mesoscale flow systems.

Klavs F Jensen, Matthew T. Stone, S. Buchwald, 2010, Angewandte Chemie.

Overcoming the Challenges of Solid Bridging and Constriction during Pd-Catalyzed C−N Bond Formation in Microreactors

Klavs F. Jensen, Nikolay Zaborenko, Ryan L. Hartman, 2010 .

Use of a "Catalytic" Cosolvent, N,N-Dimethyl Octanamide, Allows the Flow Synthesis of Imatinib with no Solvent Switch.

S. Buchwald, D. Niu, Jeffrey C Yang, 2016, Angewandte Chemie.

Suzuki-Miyaura cross-coupling reactions in flow: multistep synthesis enabled by a microfluidic extraction.

Timothy Noël, Klavs F Jensen, Simon Kuhn, 2011, Angewandte Chemie.

Accelerating reactions with microreactors at elevated temperatures and pressures: profiling aminocarbonylation reactions.

Klavs F Jensen, Nikolay Zaborenko, S. Buchwald, 2007, Angewandte Chemie.

The development of efficient protocols for the palladium-catalyzed cyclization reactions of secondary amides and carbamates.

S. Buchwald, B. Yang, 1999, Organic letters.

4,7-Dimethoxy-1,10-phenanthroline: an excellent ligand for the Cu-catalyzed N-arylation of imidazoles.

S. Buchwald, Ryan A. Altman, 2006, Organic letters.

A general and efficient copper catalyst for the amidation of aryl halides.

S. Buchwald, A. Klapars, Xiaohua Huang, 2002, Journal of the American Chemical Society.

Scope of the Intramolecular Titanocene-Catalyzed Pauson−Khand Type Reaction1

S. Buchwald, Natasha M. Kablaoui, Frederick A. Hicks, 1999 .

Development of an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates.

Nathaniel H. Park, S. Buchwald, Georgiy Teverovskiy, 2013, Organic letters.

An Efficient System For the Pd-Catalyzed Cross-Coupling of Amides and Aryl Chlorides.

S. Buchwald, B. Fors, Qingle Zeng, 2009, Tetrahedron.

Pd-catalyzed N-arylation of secondary acyclic amides: catalyst development, scope, and computational study.

S. Buchwald, J. Hicks, Alan M. Hyde, 2009, Journal of the American Chemical Society.

Mechanistic studies on the copper-catalyzed N-arylation of amides.

S. Buchwald, E. Strieter, Brijesh Bhayana, 2008, Journal of the American Chemical Society.

Orthogonal Cu- and Pd-based catalyst systems for the O- and N-arylation of aminophenols.

S. Buchwald, D. Maiti, S. Buchwald, 2009, Journal of the American Chemical Society.

Cu-catalyzed Goldberg and Ullmann reactions of aryl halides using chelating N- and O-based ligands

S. Buchwald, Ryan A. Altman, S. Buchwald, 2007, Nature Protocols.

Cu-catalyzed N- and O-arylation of 2-, 3-, and 4-hydroxypyridines and hydroxyquinolines.

S. Buchwald, Ryan A. Altman, 2007, Organic letters.

Pd-catalyzed amination reactions of aryl halides using bulky biarylmonophosphine ligands

S. Buchwald, B. Fors, Ryan A. Altman, 2007, Nature Protocols.

A general and efficient method for the copper-catalyzed cross-coupling of amides and thiophenols with 6-halogenoimidazo[1,2-a]pyridines

S. Buchwald, A. Gueiffier, C. Enguehard-Gueiffier, 2006 .

Domino cu-catalyzed C--N coupling/hydroamidation: a highly efficient synthesis of nitrogen heterocycles.

S. Buchwald, Ruben Martin, M. Rodríguez Rivero, 2006, Angewandte Chemie.

Mild and efficient copper-catalyzed amination of aryl bromides with primary alkylamines.

S. Buchwald, F. Kwong, S. Buchwald, 2003, Organic letters.

A general and efficient copper catalyst for the amidation of aryl halides.

S. Buchwald, A. Klapars, Xiaohua Huang, 2002, Journal of the American Chemical Society.

C-H functionalization/C-N bond formation: copper-catalyzed synthesis of benzimidazoles from amidines.

S. Buchwald, Gordon Brasche, S. Buchwald, 2008, Angewandte Chemie.

Pd-catalyzed intermolecular amidation of aryl halides: the discovery that xantphos can be trans-chelating in a palladium complex.

S. Buchwald, Jingjun Yin, 2002, Journal of the American Chemical Society.

Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins.

S. Buchwald, D. Lambrecht, Peng Liu, 2017, Journal of the American Chemical Society.

Palladium-catalyzed amination of aryl halides and sulfonates

S. Buchwald, Bryant H. Yang, S. Buchwald, 1999 .

Simple, efficient catalyst system for the palladium-catalyzed amination of aryl chlorides, bromides, and triflates.

S. Buchwald, J. Wolfe, H. Tomori, 2000, The Journal of organic chemistry.

Expanding Pd-catalyzed C-N bond-forming processes: the first amidation of aryl sulfonates, aqueous amination, and complementarity with Cu-catalyzed reactions.

S. Buchwald, A. Klapars, Xiaohua Huang, 2003 .

Mechanistically Guided Design of Ligands That Significantly Improve the Efficiency of CuH-Catalyzed Hydroamination Reactions.

S. Buchwald, Peng Liu, Andy A Thomas, 2018, Journal of the American Chemical Society.

Confronting the Challenging Asymmetric Addition of Vinyl Arene Pronucleophiles into Ketones: Ligand-Controlled Regiodivergent Processes Through a Dearomatized Allyl-Cu Species

Binh Khanh Mai, S. Buchwald, Peng Liu, 2021 .

Structural Insights into Active Catalyst Structures and Oxidative Addition to (Biaryl)phosphine−Palladium Complexes via Density Functional Theory and Experimental Studies

S. Buchwald, Timothy E. Barder, and Mark R. Biscoe, 2007 .

Insights into amine binding to biaryl phosphine palladium oxidative addition complexes and reductive elimination from biaryl phosphine arylpalladium amido complexes via density functional theory.

S. Buchwald, Timothy E. Barder, S. Buchwald, 2007, Journal of the American Chemical Society.

Copper-catalyzed coupling of alkylamines and aryl iodides: an efficient system even in an air atmosphere.

S. Buchwald, A. Klapars, F. Kwong, 2002, Organic letters.

Practical Palladium Catalysts for C-N and C-O Bond Formation

S. Buchwald, Alexander R. Muci, S. Buchwald, 2002 .

Continuous-Flow Preparation and Use of β-Chloro Enals Using the Vilsmeier Reagent

S. Buchwald, Laurent Pellegatti, 2012 .

A Phosphane‐Free Catalyst System for the Heck Arylation of Disubstituted Alkenes: Application to the Synthesis of Trisubstituted Olefins

S. Buchwald, C. Gürtler, 1999 .

The synthesis, reactions and molecular structure of zirconocene-alkyne complexes

S. Buchwald, J. Huffman, Brett T. Watson, 1987 .

Synthesis, structure, and reactions of (1-ethoxyethyl)zirconocene chloride, a stable acyclic secondary zirconocene alkyl

S. Buchwald, J. Dewan, R. Nielsen, 1988 .

Highly Active Palladium Catalysts for Suzuki Coupling Reactions

S. Buchwald, J. Wolfe, Bryant H. Yang, 1999 .

Industrial-Scale Palladium-Catalyzed Coupling of Aryl Halides and Amines –A Personal Account

S. Buchwald, G. Mignani, C. Mauger, 2006 .

A highly active catalyst for Pd-catalyzed amination reactions: cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl chlorides.

S. Buchwald, B. Fors, D. Watson, 2008, Journal of the American Chemical Society.

A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides.

S. Buchwald, B. Fors, M. R. Biscoe, 2008, Journal of the American Chemical Society.

A multiligand based Pd catalyst for C-N cross-coupling reactions.

S. Buchwald, B. Fors, S. Buchwald, 2010, Journal of the American Chemical Society.

Palladium-Catalyzed Coupling of Functionalized Primary and Secondary Amines with Aryl and Heteroaryl Halides: Two Ligands Suffice in Most Cases.

S. Buchwald, D. Maiti, Jaclyn L Henderson, 2010, Chemical science.

Efficient pd-catalyzed amination of heteroaryl halides.

S. Buchwald, M. D. Charles, P. Schultz, 2005, Organic letters.

Palladium-Catalyzed Negishi Coupling of α-CF3 Oxiranyl Zincate: Access to Chiral CF3-Substituted Benzylic Tertiary Alcohols.

S. Buchwald, Hu Zhang, S. Buchwald, 2017, Journal of the American Chemical Society.

CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence.

S. Buchwald, M. Baik, Jinhoo Jeong, 2018, Journal of the American Chemical Society.

A GENERAL COPPER-CATALYZED SYNTHESIS OF DIARYL ETHERS

S. Buchwald, J. Marcoux, A. S. Doye, 1997 .

In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides

S. Buchwald, Phillip J. Milner, Yang Yang, 2015, Organometallics.

Copper-catalyzed domino halide exchange-cyanation of aryl bromides.

S. Buchwald, J. Zanon, A. Klapars, 2003, Journal of the American Chemical Society.

A general, practical palladium-catalyzed cyanation of (hetero)aryl chlorides and bromides.

S. Buchwald, W. Shu, T. Senecal, 2013, Angewandte Chemie.

Regioselective Olefin Hydroformylation as a Route to Indolizidine and Pyrrolizidine Alkaloids

S. Buchwald, G. Cuny, 1995 .

Use of a Droplet Platform To Optimize Pd-Catalyzed C–N Coupling Reactions Promoted by Organic Bases

S. Buchwald, K. Jensen, J. Dennis, 2019, Organic Process Research & Development.

Synthesis of substituted pyrroles via zirconocene complexes of imines

S. Buchwald, Brett T. Watson, M. W. Wannamaker, 1989 .

Palladium-catalyzed synthesis of N-aryl carbamates.

Nathaniel H. Park, S. Buchwald, B. Fors, 2013, Organic letters.

Synthesis of optically pure 2-trifluoromethyl lactic acid by asymmetric hydroformylation.

S. Buchwald, Xiao Wang, S. Buchwald, 2013, The Journal of organic chemistry.

Synthesis, structure, and reactions of a zirconocene-benzdiyne complex

S. Buchwald, J. Dewan, E. Lucas, 1987 .

A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles.

S. Buchwald, H. Nguyen, Xiaohua Huang, 2007, Angewandte Chemie.

Pd-catalyzed Suzuki–Miyaura reactions of aryl halides using bulky biarylmonophosphine ligands

S. Buchwald, Ryan A. Altman, S. Buchwald, 2007, Nature Protocols.

Selective palladium-catalyzed arylation of ammonia: synthesis of anilines as well as symmetrical and unsymmetrical di- and triarylamines.

S. Buchwald, D. Surry, S. Buchwald, 2007, Journal of the American Chemical Society.

An Improved System for the Aqueous Lipshutz-Negishi Cross-Coupling of Alkyl Halides with Aryl Electrophiles.

S. Buchwald, B. O’Neill, Vasudev R. Bhonde, 2016, Angewandte Chemie.

ASYMMETRIC HYDROGENATION OF ENAMINES WITH A CHIRAL TITANOCENE CATALYST

S. Buchwald, N. Lee, 1994 .

Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols

S. Buchwald, Shi‐Liang Shi, Zackary L. Wong, 2016 .

Copper-catalyzed enantioselective stereodivergent synthesis of amino alcohols

S. Buchwald, Shi‐Liang Shi, Zackary L. Wong, 2016, Nature.

Palladium-catalyzed borylation of aryl chlorides: scope, applications, and computational studies.

S. Buchwald, Timothy E. Barder, K. Billingsley, 2007, Angewandte Chemie.

PALLADIUM-CATALYZED AMINATION OF ARYL IODIDES

S. Buchwald, J. Wolfe, S. Buchwald, 1996 .

A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines

S. Buchwald, R. Rennels, A. Guram, 1995 .

Development of a Method for the N-Arylation of Amino Acid Esters with Aryl Triflates

S. Buchwald, S. M. King, 2016, Organic letters.

Palladium-Protein Oxidative Addition Complexes by Amine-Selective Acylation.

Ivan V. Buslov, S. Buchwald, R. Raines, 2020, Journal of the American Chemical Society.

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

S. Buchwald, Yong Zhang, E. Cho, 2010, Science.

An efficient intermolecular palladium-catalyzed synthesis of aryl ethers.

S. Buchwald, Xiaohua Huang, C. Parrish, 2001, Journal of the American Chemical Society.

The palladium-catalyzed trifluoromethylation of vinyl sulfonates.

S. Buchwald, E. Cho, S. Buchwald, 2011, Organic letters.

Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides.

S. Buchwald, Chong Han, 2009, Journal of the American Chemical Society.

Enantio- and regioselective CuH-catalyzed hydroamination of alkenes.

S. Buchwald, Shaolin Zhu, N. Niljianskul, 2013, Journal of the American Chemical Society.

Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates.

S. Buchwald, A. T. Parsons, T. Senecal, 2012, Angewandte Chemie.

Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers

S. Buchwald, J. Wolfe, A. Aranyos, 1999 .

An improved Cu-based catalyst system for the reactions of alcohols with aryl halides.

Phillip A Lichtor, S. Buchwald, Ryan A. Altman, 2008, The Journal of organic chemistry.

Copper-catalyzed coupling of aryl iodides with aliphatic alcohols.

S. Buchwald, M. Wolter, G. Nordmann, 2002, Organic letters.

A general and efficient method for the palladium-catalyzed cross-coupling of thiols and secondary phosphines

S. Buchwald, Miki Murata, 2004 .

Highly selective room-temperature copper-catalyzed C-N coupling reactions.

S. Buchwald, A. Shafir, S. Buchwald, 2006, Journal of the American Chemical Society.

Amphiphilic Biaryl Monophosphine Ligands by Regioselective Sulfonation.

S. Buchwald, Jacob Rodriguez, Heemal H. Dhanjee, 2020, Organic letters.

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

S. Buchwald, Rúben Martín, R. Martín, 2008, Accounts of chemical research.

An improved synthesis of functionalized biphenyl-based phosphine ligands.

S. Buchwald, J. Fox, H. Tomori, 2000, The Journal of organic chemistry.

Copper-catalyzed C-P bond construction via direct coupling of secondary phosphines and phosphites with aryl and vinyl halides.

S. Buchwald, D. Gelman, Lei Jiang, 2003, Organic letters.

Pd(PhCN)(2)Cl(2)/P(t-Bu)(3): a versatile catalyst for Sonogashira reactions of aryl bromides at room temperature.

S. Buchwald, G. C. Fu, A. Littke, 2000, Organic letters.

Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents

S. Buchwald, Ye Zhu, 2014, Journal of the American Chemical Society.

Highly N2-selective palladium-catalyzed arylation of 1,2,3-triazoles.

S. Buchwald, S. Ueda, Mingjuan Su, 2011, Angewandte Chemie.

A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions.

S. Buchwald, N. Davis, Luca Salvi, 2011, Organic letters.

Significantly improved method for the pd-catalyzed coupling of phenols with aryl halides: understanding ligand effects.

S. Buchwald, Xiaohua Huang, Timothy E. Barder, 2006, Angewandte Chemie.

A general and mild copper-catalyzed arylation of diethyl malonate.

E. Hennessy, S. Buchwald, S. Buchwald, 2002, Organic letters.

A General Copper‐Catalyzed Synthesis of Diaryl Ethers.

S. Buchwald, S. Doye, J. Marcoux, 1998 .

Cascade palladium catalysis: a predictable and selectable regiocontrolled synthesis of N-arylbenzimidazoles.

S. Buchwald, N. Jui, S. Buchwald, 2013, Angewandte Chemie.

Palladium-catalyzed N-monoarylation of amidines and a one-pot synthesis of quinazoline derivatives.

S. Buchwald, Meredeth A. McGowan, Camille Z. McAvoy, 2012, Organic letters.

Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.

S. Buchwald, Jun Pan, Mingjuan Su, 2011, Angewandte Chemie.

C—H Functionalization/C—N Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines.

S. Buchwald, Gordon Brasche, 2008 .

Combined C-H functionalization/C-N bond formation route to carbazoles.

S. Buchwald, N. Zheng, W. Tsang, 2005, Journal of the American Chemical Society.

Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond Formation

John P. Wolfe, Stephen L. Buchwald, S. Buchwald, 1998 .

Biaryl Phosphine Based Pd(II) Amido Complexes: The Effect of Ligand Structure on Reductive Elimination

S. Buchwald, P. L. Arrechea, 2016, Journal of the American Chemical Society.

Design of New Ligands for the Palladium-Catalyzed Arylation of α-Branched Secondary Amines.

Nathaniel H. Park, S. Buchwald, E. Vinogradova, 2015, Angewandte Chemie.

Use of precatalysts greatly facilitate palladium-catalyzed alkynylations in batch and continuous-flow conditions

S. Buchwald, W. Shu, S. Buchwald, 2011 .

Palladium-Catalyzed Amination of Aryl Halides and Aryl Triflates: N-Hexyl-2-Methyl-4-Methoxyaniline and N-Methyl-N-(4-Chlorophenyl)Aniline

S. Buchwald, J. Wolfe, 2003 .

An air and thermally stable one- component catalyst for the amination of aryl chlorides.

S. Buchwald, D. Zim, 2003, Organic letters.

Copper-Catalyzed Arylation of β-Amino Alcohols

S. Buchwald, Gabriel E. Job, 2002 .

Palladium-catalyzed amination of aryl halides and aryl triflates: N-hexyl-2-methyl-4-methoxyaniline and N-methyl-N-(4-chlorophenyl) aniline: [ Benzenamine, 4-chloro-N-methyl-N-phenyl- ]

S. Buchwald, J. Wolfe, L. Hegedus, 2002 .

The use of palladium chloride as a precatalyst for the amination of aryl bromides

S. Buchwald, Xiao-xiang Zhang, J. Sadighi, 2001 .

Palladium-catalyzed intermolecular coupling of aryl halides and amides.

S. Buchwald, Jingjun Yin, J. Yin, 2000, Organic letters.

Rational Development of Practical Catalysts for Aromatic Carbon—Nitrogen Bond Formation

S. Buchwald, J. Wolfe, S. Wagaw, 1999 .

A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl-Aryl Cross-Coupling of Aryl Halides and Olefins.

S. Buchwald, Michael T Pirnot, Stig D. Friis, 2017, Angewandte Chemie.

Copper-Catalyzed Oxytrifluoromethylation of Unactivated Alkenes

S. Buchwald, R. Zhu, S. Buchwald, 2012 .

In Praise of Basic Research as a Vehicle to Practical Applications: Palladium-Catalyzed Coupling to Form Carbon-Nitrogen Bonds.

S. Buchwald, J. Hartwig, 2020, Israel journal of chemistry.

Development of an Aryl Amination Catalyst with Broad Scope Guided by Consideration of Catalyst Stability.

S. Buchwald, P. L. Arrechea, S. D. McCann, 2020, Journal of the American Chemical Society.

Pharmaceutical diversification via palladium oxidative addition complexes

S. Buchwald, T. Cernak, S. Krska, 2019, Science.

Biaryl Monophosphine Ligands in Palladium-Catalyzed C-N Coupling: An Updated User's Guide.

S. Buchwald, Corin C. Wagen, Bryan T. Ingoglia, 2019, Tetrahedron.

Regioselective Synthesis of Benzimidazolones via Cascade C–N Coupling of Monosubstituted Ureas

S. Buchwald, N. Jui, Nicholas E. S. Tay, 2014, Organic letters.

Mild and rapid Pd-catalyzed cross-coupling with hydrazine in continuous flow: application to the synthesis of functionalized heterocycles.

S. Buchwald, Dong-Hui Wang, A. Deangelis, 2013, Angewandte Chemie.

Concise palladium-catalyzed synthesis of dibenzodiazepines and structural analogues.

S. Buchwald, D. Tsvelikhovsky, S. Buchwald, 2011, Journal of the American Chemical Society.

Simple, efficient catalyst system for the palladium-catalyzed amination of aryl chlorides, bromides, and triflates.

S. Buchwald, J. Wolfe, Jingjun Yin, 2000, The Journal of organic chemistry.

Scope and limitations of the Pd/BINAP-catalyzed amination of aryl bromides.

S. Buchwald, J. Wolfe, John P. Wolfe† and, 2000, The Journal of organic chemistry.

Expanding Pd-catalyzed C-N bond-forming processes: the first amidation of aryl sulfonates, aqueous amination, and complementarity with Cu-catalyzed reactions.

S. Buchwald, A. Klapars, Xiaohua Huang, 2003, Journal of the American Chemical Society.

Palladium-Catalyzed α-Arylation of Ketones

S. Buchwald, M. Palucki, S. Buchwald, 1997 .

ELECTRONIC DEPENDENCE OF C-O REDUCTIVE ELIMINATION FROM PALLADIUM (ARYL)NEOPENTOXIDE COMPLEXES

S. Buchwald, R. Widenhoefer, S. Buchwald, 1998 .

Monodentate phosphines provide highly active catalysts for Pd-catalyzed C-N bond-forming reactions of heteroaromatic halides/amines and (H)N-heterocycles.

S. Buchwald, Ryan A. Altman, Takashi Ikawa, 2006, Angewandte Chemie.

Selective Palladium‐Catalyzed Arylation of Ammonia: Synthesis of Anilines as well as Symmetrical and Unsymmetrical Di‐ and Triarylamines.

S. Buchwald, D. Surry, 2008 .

Palladium‐Catalyzed Aromatic Aminations with in situ Generated Aminostannanes.

S. Buchwald, A. Guram, 1995 .

The Synthesis of Aminopyridines: A Method Employing Palladium- Catalyzed Carbon-Nitrogen Bond Formation.

S. Buchwald, S. Wagaw, 1997 .

Mechanistic Insight Leads to a Ligand Which Facilitates the Palladium-Catalyzed Formation of 2-(Hetero)Arylaminooxazoles and 4-(Hetero)Arylaminothiazoles.

S. Buchwald, P. L. Arrechea, Esben P K Olsen, 2017, Angewandte Chemie.

An Improved Synthesis of BrettPhos and RockPhos-Type Biarylphosphine Ligands.

S. Buchwald, Naoyuki Hoshiya, N. Hoshiya, 2012, Advanced synthesis & catalysis.

Completely N1-selective palladium-catalyzed arylation of unsymmetric imidazoles: application to the synthesis of nilotinib.

S. Buchwald, S. Ueda, Mingjuan Su, 2012, Journal of the American Chemical Society.

A single phosphine ligand allows palladium-catalyzed intermolecular C-O bond formation with secondary and primary alcohols.

S. Buchwald, B. Fors, Xiaoxing Wu, 2011, Angewandte Chemie.

Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides.

S. Buchwald, Phillip J. Milner, Yong Zhang, 2011, Journal of the American Chemical Society.

Synthesis of heterocycles via Pd-ligand controlled cyclization of 2-chloro-N-(2-vinyl)aniline: preparation of carbazoles, indoles, dibenzazepines, and acridines.

S. Buchwald, D. Tsvelikhovsky, 2010, Journal of the American Chemical Society.

Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.

S. Buchwald, Xiaoqiang Shen, Alan M. Hyde, 2010, Journal of the American Chemical Society.

Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides

S. Buchwald, Yong Zhang, D. Watson, 2009, Science.

A Highly Active Catalyst for Pd‐Catalyzed Amination Reactions: Cross‐Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines Using Aryl Chlorides.

S. Buchwald, B. Fors, D. Watson, 2009 .

Simple, Efficient Protocols for the Pd-Catalyzed Cross-Coupling Reaction of Aryl Chlorides and Dimethylamine.

S. Buchwald, M. R. Biscoe, Brian K Lee, 2009, Tetrahedron letters.

Palladium-catalyzed enantioselective alpha-arylation and alpha-vinylation of oxindoles facilitated by an axially chiral P-stereogenic ligand.

S. Buchwald, Alexander M. Taylor, Ryan A. Altman, 2009, Journal of the American Chemical Society.

An efficient process for pd-catalyzed C-N cross-coupling reactions of aryl iodides: insight into controlling factors.

S. Buchwald, B. Fors, N. Davis, 2009, Journal of the American Chemical Society.

Pd-catalyzed conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics.

S. Buchwald, B. Fors, S. Buchwald, 2009, Journal of the American Chemical Society.

An Umpolung Approach for the Chemoselective Arylation of Selenocysteine in Unprotected Peptides

S. Buchwald, B. Pentelute, Chi Zhang, 2015, Journal of the American Chemical Society.

Monophosphine Ligands Promote Pd-Catalyzed C-S Cross-Coupling Reactions at Room Temperature with Soluble Bases.

S. Buchwald, C. Yeung, Richard Y. Liu, 2019, ACS catalysis.

Palladium-Catalyzed Fluorination of Cyclic Vinyl Triflates: Effect of TESCF3 as an Additive.

S. Buchwald, Yuxuan Ye, T. Takada, 2016, Angewandte Chemie.

Dosage Delivery of Sensitive Reagents Enables Glove Box-Free Synthesis

S. Buchwald, Hong Geun Lee, Aaron C. Sather, 2015, Nature.

Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides

S. Buchwald, Phillip J. Milner, Hong Geun Lee, 2014, Journal of the American Chemical Society.

Studying Regioisomer Formation in the Pd-Catalyzed Fluorination of Aryl Triflates by Deuterium Labeling

S. Buchwald, Phillip J. Milner, Yong Zhang, 2014, Journal of the American Chemical Society.

An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates.

S. Buchwald, Phillip J. Milner, Hong Geun Lee, 2013, Organic letters.

Room temperature copper(II)-catalyzed oxidative cyclization of enamides to 2,5-disubstituted oxazoles via vinylic C-H functionalization.

S. Buchwald, C. Cheung, S. Buchwald, 2012, The Journal of organic chemistry.

Organic chemistry: A radical approach to diversity

S. Buchwald, A. T. Parsons, S. Buchwald, 2011, Nature.

Copper-catalyzed trifluoromethylation of unactivated olefins.

S. Buchwald, A. T. Parsons, S. Buchwald, 2011, Angewandte Chemie.

On the role of metal contaminants in catalyses with FeCl3.

S. Buchwald, C. Bolm, S. Buchwald, 2009, Angewandte Chemie.

Copper-diamine-catalyzed N-arylation of pyrroles, pyrazoles, indazoles, imidazoles, and triazoles.

S. Buchwald, Jeremy M. Baskin, J. Antilla, 2004, The Journal of organic chemistry.

Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides

S. Buchwald, Yang Yang, Chong Han, 2014, Organic letters.

Mild and general conditions for negishi cross-coupling enabled by the use of palladacycle precatalysts.

S. Buchwald, Yang Yang, Nathan J. Oldenhuis, 2012, Angewandte Chemie.

Accelerating palladium-catalyzed C-F bond formation: use of a microflow packed-bed reactor.

Timothy Noël, S. Buchwald, T. Noël, 2011, Angewandte Chemie.

The Evolution of Pd0/PdII-Catalyzed Aromatic Fluorination

S. Buchwald, Aaron C. Sather, 2016, Accounts of chemical research.

Accelerating Palladium-Catalyzed C—F Bond Formation: Use of a Microflow Packed-Bed Reactor.

S. Buchwald, T. Noël, T. Maimone, 2012 .

Zirconocene(iso-butyl) chloride: In situ generation of a zirconocene(methyl) chloride equivalent for use in organic synthesis

S. Buchwald, Brett T. Watson, K. Barr, 1991 .

Synthesis of Substituted Pyrroles via Zirconocene Complexes of Imines.

S. Buchwald, Brett T. Watson, M. W. Wannamaker, 1989 .

Palladium‐Catalyzed Aromatic Carbon‐Nitrogen Bond Formation

S. Buchwald, Lei Jiang, S. Buchwald, 2008 .

Nickel-Catalyzed Amination of Aryl Chlorides

S. Buchwald, John P. Wolfe† and, 1997 .

Evidence for the formation and structure of palladacycles during Pd-catalyzed C-N bond formation with catalysts derived from bulky monophosphinobiaryl ligands.

S. Buchwald, E. Strieter, S. Buchwald, 2006, Angewandte Chemie.

New ammonia equivalents for the Pd-catalyzed amination of aryl halides.

S. Buchwald, X. Huang, S. Buchwald, 2001, Organic letters.

Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes.

Alexander M. Spokoyny, S. Buchwald, Georgiy Teverovskiy, 2012, Organometallics.

A general and efficient copper catalyst for the amidation of aryl halides and the N-arylation of nitrogen heterocycles.

S. Buchwald, J. Antilla, A. Klapars, 2001, Journal of the American Chemical Society.

Diastereo- and Enantioselective CuH-Catalyzed Hydroamination of Strained Trisubstituted Alkenes.

S. Buchwald, P. Liu, Peng Liu, 2019, ACS catalysis.

Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones

S. Buchwald, Peng Liu, Yang Yang, 2016, Science.

Protein-Protein Cross-Coupling via Palladium-Protein Oxidative Addition Complexes from Cysteine Residues.

Ivan V. Buslov, S. Buchwald, B. Pentelute, 2020, Journal of the American Chemical Society.

Enantioselective synthesis of axially chiral biaryls by the Pd-catalyzed Suzuki-Miyaura reaction: substrate scope and quantum mechanical investigations.

S. Buchwald, Brijesh Bhayana, Xiaoqiang Shen, 2010, Journal of the American Chemical Society.

CuH-Catalyzed Olefin Functionalization: From Hydroamination to Carbonyl Addition.

S. Buchwald, Richard Y. Liu, S. Buchwald, 2020, Accounts of chemical research.

Copper‐Catalyzed, Enantioselective Hydrofunctionalization of Alkenes

S. Buchwald, Haoxuan Wang, 2019, Organic Reactions.

Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes

S. Buchwald, R. Zhu, 2015, Journal of the American Chemical Society.

Catalysts for Suzuki-Miyaura coupling processes: scope and studies of the effect of ligand structure.

S. Buchwald, J. R. Martinelli, Timothy E. Barder, 2005, Journal of the American Chemical Society.

Palladium Mediated Synthesis of Protein-Polyarene Conjugates.

S. Buchwald, B. Pentelute, Heemal H. Dhanjee, 2022, Journal of the American Chemical Society.

Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct.

S. Buchwald, Yang Yang, Yujing Zhou, 2019, Journal of the American Chemical Society.

Enantioselective Allylation from Allene, a Petroleum Cracking Byproduct

S. Buchwald, Yang Yang, Yujing Zhou, 2018 .

Synthesis of unsymmetrical diarylureas via Pd-catalyzed C-N cross-coupling reactions.

S. Buchwald, B. Fors, S. Breitler, 2011, Organic letters.

Palladium-Mediated Incorporation of Carboranes into Small Molecules, Peptides, and Proteins.

S. Buchwald, A. Loas, B. Pentelute, 2022, Journal of the American Chemical Society.

Confronting the Challenging Asymmetric Carbonyl 1,2-Addition Using Vinyl Heteroarene Pronucleophiles: Ligand-Controlled Regiodivergent Processes through a Dearomatized Allyl-Cu Species.

Binh Khanh Mai, S. Buchwald, P. Liu, 2022, Journal of the American Chemical Society.

Evidence for Simultaneous Dearomatization of Two Aromatic Rings Under Mild Conditions in Cu(I)-Catalyzed Direct Asymmetric Dearomatization of Pyridine.

S. Buchwald, Richard Y. Liu, Michael W. Gribble, 2020, Journal of the American Chemical Society.

Visible Light-Mediated (Hetero)aryl Amination Using Ni(II) Salts and Photoredox Catalysis in Flow: A Synthesis of Tetracaine.

S. Buchwald, Michael T Pirnot, Boyoung Y. Park, 2020, The Journal of organic chemistry.

Highly Enantioselective Synthesis of Indazoles with a C3-Quaternary Chiral Center Using CuH Catalysis.

S. Buchwald, Peng Liu, Peng Liu, 2019, Journal of the American Chemical Society.

The Evolution of Pd Citation

S. Buchwald, Stephen L. Buchwald, 2016 .

Room temperature aryl trifluoromethylation via copper-mediated oxidative cross-coupling.

S. Buchwald, A. T. Parsons, T. Senecal, 2011, The Journal of organic chemistry.

An Ammonia Equivalent for the Palladium-Catalyzed Amination of Aryl Halides and Triflates

S. Buchwald, J. Wolfe, J. Ahman, 1997 .

The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C-N Cross-Coupling.

S. Buchwald, J. Dennis, Richard Y. Liu, 2020, Journal of the American Chemical Society.

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands.

S. Buchwald, Bryan T. Ingoglia, S. Buchwald, 2017, Organic letters.

Expedited palladium-catalyzed amination of aryl nonaflates through the use of microwave-irradiation and soluble organic amine bases.

S. Buchwald, K. Anderson, Rachel E. Tundel, 2006, The Journal of organic chemistry.

Twofold C-H functionalization: palladium-catalyzed ortho arylation of anilides.

S. Buchwald, Gordon Brasche, J. García-Fortanet, 2008, Organic letters.

Arylierungschemie für die Biokonjugation

Alexander M. Spokoyny, E. V. Vinogradova, S. Buchwald, 2019, Angewandte Chemie.

A Dual Pd- and CuH-Catalyzed Approach for Alkyl-Aryl Cross-Coupling of Aryl Halides and Olefins

S. Buchwald, Michael T Pirnot, Laurence Dupuis, 2017 .

Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines

S. Buchwald, P. Liu, D. Niu, 2015, Science.

Ligand-controlled palladium-catalyzed regiodivergent Suzuki-Miyaura cross-coupling of allylboronates and aryl halides.

S. Buchwald, Yang Yang, S. Buchwald, 2013, Journal of the American Chemical Society.

Pd‐Catalyzed Synthesis of Ar—SCF3 Compounds under Mild Conditions.

S. Buchwald, Georgiy Teverovskiy, D. Surry, 2011 .

A Multi-Ligand Based Pd Catalyst for C–N Cross-Coupling Reactions

S. Buchwald, B. Fors, 2010 .

A highly active catalyst for Suzuki-Miyaura cross-coupling reactions of heteroaryl compounds.

S. Buchwald, K. Anderson, K. Billingsley, 2006, Angewandte Chemie.

Selective monoarylation of acetate esters and aryl methyl ketones using aryl chlorides.

S. Buchwald, M. R. Biscoe, 2009, Organic letters.

A General Method for the Direct α‐Arylation of Aldehydes with Aryl Bromides and Chlorides

S. Buchwald, Rúben Martín, R. Martín, 2007 .

An annulative approach to highly substituted indoles: unusual effect of phenolic additives on the success of the arylation of ketone enolates.

S. Buchwald, Matthew P. Rainka, J. L. Rutherford, 2002, Journal of the American Chemical Society.

Highly Active and Selective Catalysts for the Formation of α-Aryl Ketones

S. Buchwald, A. Chieffi, J. Fox, 2000 .

Efficient palladium-catalyzed coupling of aryl chlorides and tosylates with terminal alkynes: use of a copper cocatalyst inhibits the reaction.

S. Buchwald, D. Gelman, 2003, Angewandte Chemie.

Palladium-catalyzed carbonylation reactions of aryl bromides at atmospheric pressure: a general system based on Xantphos.

S. Buchwald, J. R. Martinelli, D. Watson, 2008, The Journal of organic chemistry.

A general and efficient method for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles.

S. Buchwald, K. Billingsley, S. Buchwald, 2008, Angewandte Chemie.

CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications.

S. Buchwald, Peng Liu, Yang Yang, 2018, Journal of the American Chemical Society.

Mechanistic Insight Facilitates Discovery of a Mild and Efficient Copper-Catalyzed Dehydration of Primary Amides to Nitriles Using Hydrosilanes.

S. Buchwald, Richard Y. Liu, Minwoo Bae, 2018, Journal of the American Chemical Society.

CuH-Catalyzed Asymmetric Hydroamidation of Vinylarenes.

S. Buchwald, J. Bandar, Yujing Zhou, 2018, Angewandte Chemie.

Highly Diastereo- and Enantioselective CuH-Catalyzed Synthesis of 2,3-Disubstituted Indolines

S. Buchwald, E. Ascic, 2015, Journal of the American Chemical Society.

Synthesis of indolines via a domino Cu-catalyzed amidation/cyclization reaction.

S. Buchwald, A. Minatti, S. Buchwald, 2008, Organic letters.

Copper-catalyzed halogen exchange in aryl halides: an aromatic Finkelstein reaction.

S. Buchwald, A. Klapars, Artis Klapars, 2002, Journal of the American Chemical Society.

Controlled Acceleration and Inhibition of Bergman Cyclization by Metal Chlorides

S. Buchwald, R. Broene, B. Warner, 1995, Science.

A Catalytic Method for the Conversion of Silanes to Stannanes

S. Buchwald, B. Warner, 1994 .

Cp2TiCH2 complexes in synthetic applications

S. Buchwald, R. Grubbs, L. Clawson, 1983 .

Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds Catalyzed by a Copper Carbene Complex

S. Buchwald, J. Sadighi, Valdas Jurkauskas, 2003 .

Copper Hydride Catalyzed Enantioselective Synthesis of Axially Chiral 1,3-Disubstituted Allenes

S. Buchwald, Liela Bayeh-Romero, S. Buchwald, 2019, Journal of the American Chemical Society.

A rationally designed universal catalyst for Suzuki-Miyaura coupling processes.

S. Buchwald, J. R. Martinelli, Timothy E. Barder, 2004, Angewandte Chemie.

Water-mediated catalyst preactivation: an efficient protocol for C-N cross-coupling reactions.

S. Buchwald, E. Strieter, B. Fors, 2008, Organic letters.

Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes

S. Buchwald, Shaolin Zhu, S. Buchwald, 2014, Journal of the American Chemical Society.

Copper-catalyzed N-arylation of imidazoles and benzimidazoles.

S. Buchwald, E. Koval, Ryan A. Altman, 2007, The Journal of organic chemistry.

Copper—Diamine‐Catalyzed N‐Arylation of Pyrroles, Pyrazoles, Indazoles, Imidazoles, and Triazoles.

S. Buchwald, Jeremy M. Baskin, J. Antilla, 2004 .

Palladium‐Catalyzed Stille Cross‐Coupling Reaction of Aryl Chlorides using a Pre‐Milled Palladium Acetate and XPhos Catalyst System

S. Buchwald, J. R. Naber, S. Buchwald, 2008 .

A domino copper-catalyzed C-O coupling-Claisen rearrangement process.

S. Buchwald, G. Nordmann, S. Buchwald, 2003, Journal of the American Chemical Society.

Palladium-Catalyzed Synthesis of Monodisperse, Controlled-Length, and Functionalized Oligoanilines

S. Buchwald, J. Sadighi, A. Singer, 1998 .

Synthesis of Heteroaryl Sulfonamides from Organozinc Reagents and 2,4,6-Trichlorophenyl Chlorosulfate

S. Buchwald, J. R. Debergh, James R. Colombe, 2015, Organic letters.

Synthesis of aryl sulfonamides via palladium-catalyzed chlorosulfonylation of arylboronic acids.

S. Buchwald, J. R. Debergh, N. Niljianskul, 2013, Journal of the American Chemical Society.

Enantioselective Hydroalkenylation of Olefins with Enol Sulfonates Enabled by Dual Copper Hydride and Palladium Catalysis.

S. Buchwald, James Levi Knippel, Gustavo M. Borrajo-Calleja, 2021, Journal of the American Chemical Society.

The Enantioselective Preparation of Arenes with β-Stereogenic Centers: Confronting the 1,1-Disubstituted Olefin Problem Using CuH/Pd Cooperative Catalysis.

S. Buchwald, Zhaohong Lu, 2020, Angewandte Chemie.

Use of tunable ligands allows for intermolecular Pd-catalyzed C--O bond formation.

S. Buchwald, Xiaohua Huang, A. Vorogushin, 2005, Journal of the American Chemical Society.

A new palladium precatalyst allows for the fast Suzuki-Miyaura coupling reactions of unstable polyfluorophenyl and 2-heteroaryl boronic acids.

S. Buchwald, Yong Zhang, T. Kinzel, 2010, Journal of the American Chemical Society.

Stereochemistry of nucleophilic displacement on two phosphoric monoesters and a phosphoguanidine: the role of metaphosphate

S. Buchwald, J. Knowles, J. Friedman, 1984 .

Stereochemistry of phospho transfer catalyzed by bovine liver acid phosphatase.

S. Buchwald, J. Knowles, R. V. Van Etten, 1981, The Journal of biological chemistry.

Synthesis and application of palladium precatalysts that accommodate extremely bulky di-tert-butylphosphino biaryl ligands.

S. Buchwald, Nicholas C. Bruno, S. Buchwald, 2013, Organic letters.

CuH-Catalyzed Regio- and Enantioselective Hydrocarboxylation of Allenes: Toward Carboxylic Acids with Acyclic Quaternary Centers.

S. Buchwald, Shengyu Feng, S. Buchwald, 2021, Journal of the American Chemical Society.

Carbonylation of aryl chlorides with oxygen nucleophiles at atmospheric pressure. Preparation of phenyl esters as acyl transfer agents and the direct preparation of alkyl esters and carboxylic acids.

S. Buchwald, D. Watson, D. A. Watson, 2008, The Journal of organic chemistry.

Palladium-catalyzed amination of aryl nonaflates.

S. Buchwald, K. Anderson, M. Méndez-Pérez, 2003, The Journal of organic chemistry.

The methylenation of enolizable ketones and esters using organotitanium chemistry

S. Buchwald, R. Grubbs, L. Clawson, 1985 .

Insights into the origin of high activity and stability of catalysts derived from bulky, electron-rich monophosphinobiaryl ligands in the Pd-catalyzed C-N bond formation.

S. Buchwald, E. Strieter, D. Blackmond, 2003, Journal of the American Chemical Society.

Use of polymer-supported dialkylphosphinobiphenyl ligands for palladium-catalyzed amination and Suzuki reactions.

S. Buchwald, C. Parrish, 2001, Journal of Organic Chemistry.

Efficient palladium-catalyzed N-arylation of indoles.

S. Buchwald, David W. Old, D. Old, 2000, Organic letters.

Intramolecular palladium-catalyzed aryl amination and aryl amidation

S. Buchwald, J. Wolfe, R. Rennels, 1996 .

Rhodium‐Catalyzed Hydroformylation of Internal Alkynes to α,β‐Unsaturated Aldehydes

S. Buchwald, G. Cuny, John R. Johnson, 1995 .

Practical, high-yield, regioselective, rhodium-catalyzed hydroformylation of functionalized .alpha.-olefins

S. Buchwald, G. Cuny, 1993 .

The selective reaction of aryl halides with KOH: synthesis of phenols, aromatic ethers, and benzofurans.

S. Buchwald, Takashi Ikawa, K. Anderson, 2006, Journal of the American Chemical Society.

Palladium-Catalyzed α-Arylation of Esters

S. Buchwald, W. Moradi, S. Buchwald, 2001 .

Asymmetric Arylation of Ketone Enolates

S. Buchwald, J. Wolfe, M. Palucki, 1998 .

A Catalytic Asymmetric Suzuki Coupling for the Synthesis of Axially Chiral Biaryl Compounds

S. Buchwald, Jingjun Yin and, 2000 .

Catalytic Arylhydroxylation of Dehydroalanine in Continuous Flow for Simple Access to Unnatural Amino Acids.

S. Buchwald, Yang Zhao, R. Khan, 2018, Chemistry.

Highly efficient monophosphine-based catalyst for the palladium-catalyzed suzuki-miyaura reaction of heteroaryl halides and heteroaryl boronic acids and esters.

S. Buchwald, K. Billingsley, S. Buchwald, 2007, Journal of the American Chemical Society.

Pd-Catalyzed C-N Coupling Reactions Facilitated by Organic Bases: Mechanistic Investigation Leads to Enhanced Reactivity in the Arylation of Weakly Binding Amines.

S. Buchwald, J. Dennis, Richard Y. Liu, 2019, ACS catalysis.

Synthesis of (MeCN)2Pd(CF3)OTs, a General Precursor to Palladium(II) Trifluoromethyl Complexes LPd(CF3)X

S. Buchwald, Ryan P. King, 2019, Organometallics.

Efficient Synthesis of Well-Defined, High Molecular Weight, and Processible Polyanilines under Mild Conditions via Palladium-Catalyzed Amination

S. Buchwald, Xiao-xiang Zhang, J. Sadighi, 2000 .

Palladium-Catalyzed Amination of Aryl Bromides: Use of Phosphinoether Ligands for the Efficient Coupling of Acyclic Secondary Amines

S. Buchwald, S. Wagaw, J. Marcoux, 1997 .

Synthesis of solid 2-pyridylzinc reagents and their application in Negishi reactions.

S. Buchwald, P. Knochel, Sebastian Bernhardt, 2013, Organic letters.

4,7-Dimethoxy-1,10-phenanthroline: an excellent ligand for the Cu-catalyzed N-arylation of imidazoles.

S. Buchwald, Ryan A. Altman, S. Buchwald, 2006, Organic letters.

Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes.

S. Buchwald, E. Strieter, S. Shekhar, 2006, Journal of the American Chemical Society.

Cu-catalyzed arylation of phenols: synthesis of sterically hindered and heteroaryl diaryl ethers.

S. Buchwald, D. Maiti, S. Buchwald, 2010, The Journal of organic chemistry.

Orthogonal Pd- and Cu-based catalyst systems for C- and N-arylation of oxindoles.

S. Buchwald, Ryan A. Altman, Xiaohua Huang, 2008, Journal of the American Chemical Society.

Pyrrole-2-carboxylic acid as a ligand for the Cu-catalyzed reactions of primary anilines with aryl halides.

S. Buchwald, Ryan A. Altman, K. Anderson, 2008, The Journal of organic chemistry.

Copper-catalyzed N-arylation of imidazoles and benzimidazoles.

S. Buchwald, E. Koval, Ryan A. Altman, 2007, The Journal of organic chemistry.

N- versus O-arylation of aminoalcohols: orthogonal selectivity in copper-based catalysts.

Phillip A Lichtor, S. Buchwald, A. Shafir, 2007, Journal of the American Chemical Society.

The role of chelating diamine ligands in the goldberg reaction: a kinetic study on the copper-catalyzed amidation of aryl iodides.

S. Buchwald, E. Strieter, D. Blackmond, 2005, Journal of the American Chemical Society.

Copper-catalyzed coupling of amides and carbamates with vinyl halides.

S. Buchwald, A. Klapars, Lei Jiang, 2003, Organic letters.

The copper-catalyzed N-arylation of indoles.

S. Buchwald, J. Antilla, A. Klapars, 2002, Journal of the American Chemical Society.

Structural reevaluation of the electrophilic hypervalent iodine reagent for trifluoromethylthiolation supported by the crystalline sponge method for X-ray analysis.

S. Buchwald, P. Müller, E. Vinogradova, 2014, Angewandte Chemie.

Rapid and efficient trifluoromethylation of aromatic and heteroaromatic compounds using potassium trifluoroacetate enabled by a flow system.

S. Buchwald, Mao Chen, S. Buchwald, 2013, Angewandte Chemie.

A highly active Suzuki catalyst for the synthesis of sterically hindered biaryls: novel ligand coordination.

S. Buchwald, Xiao-xiang Zhang, Matthew P. Rainka, 2002, Journal of the American Chemical Society.

Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis

S. Buchwald, Michael T Pirnot, Stig D. Friis, 2016, Journal of the American Chemical Society.

An improved palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.

S. Buchwald, Yong Zhang, Jun Pan, 2011, Organic letters.

General catalysts for the Suzuki-Miyaura and Sonogashira coupling reactions of aryl chlorides and for the coupling of challenging substrate combinations in water.

S. Buchwald, K. Anderson, S. Buchwald, 2005, Angewandte Chemie.

A Mild General Procedure for the One‐Pot Conversion of Amides to Aldehydes

S. Buchwald, S. Bower, K. A. Kreutzer, 1996 .

A general, efficient, and inexpensive catalyst system for the coupling of aryl iodides and thiols.

S. Buchwald, F. Kwong, S. Buchwald, 2002, Organic letters.

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

S. Buchwald, Stephen L Buchwald, David S Surry, 2010, Chemical science.

The Synthesis of Aminopyridines: A Method Employing Palladium-Catalyzed Carbon-Nitrogen Bond Formation.

S. Buchwald, S. Wagaw, S. Buchwald, 1996, The Journal of organic chemistry.

Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles: substrate scope and mechanistic investigation.

S. Buchwald, M. A. Düfert, K. Billingsley, 2013, Journal of the American Chemical Society.

Synthesis, structure, and reactivity of a zirconocene complex of cyclobutene

S. Buchwald, R. Fisher, 1990 .

A regiospecific method for the hydrocyanation of olefins

S. Buchwald, S. Lamaire, 1987 .

Copper-catalyzed vinylation of hydrazides. A regioselective entry to highly substituted pyrroles.

S. Buchwald, M. Rivero, S. Buchwald, 2007, Organic letters.

Synthesis of Substituted Oxindoles from α-Chloroacetanilides via Palladium-Catalyzed C−H Functionalization

E. Hennessy, S. Buchwald, S. Buchwald, 2003 .

An efficient copper-catalyzed coupling of aryl halides with imidazoles

S. Buchwald, J. Marcoux, Ayumu Kiyomori, 1999 .

Palladium-catalyzed intramolecular C-H difluoroalkylation: synthesis of substituted 3,3-difluoro-2-oxindoles.

S. Buchwald, Shi‐Liang Shi, S. Buchwald, 2014, Angewandte Chemie.

Mild and general palladium-catalyzed synthesis of methyl aryl ethers enabled by the use of a palladacycle precatalyst.

S. Buchwald, C. Cheung, 2013, Organic letters.

Diamine Ligands in Copper-Catalyzed Reactions.

S. Buchwald, D. Surry, 2010, Chemical science.

Mild Palladium-Catalyzed Cyanation of (Hetero)aryl Halides and Triflates in Aqueous Media

S. Buchwald, Daniel T. Cohen, S. Buchwald, 2015, Organic letters.

A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides

S. Buchwald, P. Müller, Yang Yang, 2015, Journal of the American Chemical Society.

Rapid Synthesis of Aryl Fluorides in Continuous Flow through the Balz-Schiemann Reaction.

Nathaniel H. Park, S. Buchwald, Timothy J Senter, 2016, Angewandte Chemie.

Novel Syntheses of Tetrahydropyrroloquinolines: Applications to Alkaloid Synthesis

S. Buchwald, Andrew J. Peat and, 1996 .

Palladium-catalyzed amination of unprotected halo-7-azaindoles.

S. Buchwald, Jaclyn L Henderson, Sarah M. McDermott, 2010, Organic letters.

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions†

S. Buchwald, Georgiy Teverovskiy, D. Surry, 2011 .

Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes.

S. Buchwald, Yang Yang, 2014, Angewandte Chemie.

Computational explorations of mechanisms and ligand-directed selectivities of copper-catalyzed Ullmann-type reactions.

S. Buchwald, Peng Liu, K. Houk, 2010, Journal of the American Chemical Society.

Synthesis of N-aryl hydrazides by copper-catalyzed coupling of hydrazides with aryl iodides.

S. Buchwald, M. Wolter, A. Klapars, 2001, Organic letters.

Palladium-catalyzed amination of aryl nonaflates.

S. Buchwald, K. Anderson, M. Méndez-Pérez, 2003, The Journal of organic chemistry.

Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst

S. Buchwald, T. Skrydstrup, Stig D. Friis, 2014, Organic letters.

Biaryl phosphane ligands in palladium-catalyzed amination.

S. Buchwald, D. Surry, 2008, Angewandte Chemie.

A Highly Active Catalyst for Palladium-Catalyzed Cross-Coupling Reactions: Room-Temperature Suzuki Couplings and Amination of Unactivated Aryl Chlorides

John P. Wolfe, Stephen L. Buchwald, S. Buchwald, 1998 .

Ipso- or cine-substitutions of 6-haloimidazo[1,2-a]pyridine derivatives with different azoles depending on the reaction conditions.

S. Buchwald, A. Gueiffier, H. Allouchi, 2003, The Journal of organic chemistry.

Continuous-Flow Synthesis of Biaryls by Negishi Cross-Coupling of Fluoro- and Trifluoromethyl-Substituted (Hetero)arenes.

S. Buchwald, Stefan Roesner, S. Buchwald, 2016, Angewandte Chemie.

Design and Preparation of New Palladium Precatalysts for C-C and C-N Cross-Coupling Reactions.

S. Buchwald, Stephen L Buchwald, M. Tudge, 2012, Chemical science.

An Improved Catalyst System for Aromatic Carbon−Nitrogen Bond Formation: The Possible Involvement of Bis(Phosphine) Palladium Complexes as Key Intermediates

John P. Wolfe, Stephen L. Buchwald, S. Buchwald, 1996 .

Asymmetric palladium-catalyzed intramolecular alpha-arylation of aldehydes.

S. Buchwald, J. García-Fortanet, 2008, Angewandte Chemie.

Copper-Catalyzed RegioselectiveorthoCH Cyanation of Vinylarenes

S. Buchwald, Yang Yang, 2014 .

Pd-catalyzed synthesis of Ar-SCF3 compounds under mild conditions.

S. Buchwald, Georgiy Teverovskiy, D. Surry, 2011, Angewandte Chemie.

P-chirogenic binaphthyl-substituted monophosphines: synthesis and use in enolate vinylation/arylation reactions.

S. Buchwald, Takayuki Hamada, 2002, Organic letters.

Catalytic asymmetric vinylation of ketone enolates.

S. Buchwald, A. Chieffi, J. Ahman, 2001, Organic letters.

Combined oxypalladation/C-H functionalization: palladium(II)-catalyzed intramolecular oxidative oxyarylation of hydroxyalkenes.

S. Buchwald, R. Zhu, S. Buchwald, 2012, Angewandte Chemie.

Enantioselective Synthesis of Carbo- and Heterocycles through a CuH-Catalyzed Hydroalkylation Approach

S. Buchwald, Yi‐Ming Wang, Nicholas C. Bruno, 2015, Journal of the American Chemical Society.

N-Substituted 2-Aminobiphenylpalladium Methanesulfonate Precatalysts and Their Use in C–C and C–N Cross-Couplings

S. Buchwald, Nicholas C. Bruno, N. Niljianskul, 2014, The Journal of organic chemistry.

The first general palladium catalyst for the Suzuki-Miyaura and carbonyl enolate coupling of aryl arenesulfonates.

S. Buchwald, H. Nguyen, Xiaohua Huang, 2003, Journal of the American Chemical Society.

Palladium-catalyzed method for the synthesis of carbazoles via tandem C-H functionalization and C-N bond formation.

S. Buchwald, Rachel Munday, Gordon Brasche, 2008, The Journal of organic chemistry.

A new approach to the synthesis of the CC-1065/duocarmycin pharmacophore

S. Buchwald, J. Tidwell, 1992 .

An extremely active catalyst for the Negishi cross-coupling reaction.

S. Buchwald, Jacqueline E. Milne, 2004, Journal of the American Chemical Society.

A High-Yield, General Method for the Catalytic Formation of Oxygen Heterocycles

S. Buchwald, K. E. Torraca, and Shin-Itsu Kuwabe, 2000 .

Carbon−Hydrogen Bond Activation of Aromatic Imines by (Cp*2SmH)2

S. Buchwald, B. Scott, C. Burns, 1996 .

Synthesis and Structure of a C2-Symmetric, Doubly Bridged ansa-Titanocene Complex

W. M. Davis, S. Buchwald, R. B. Grossman, 1994 .

Olefin insertion in a metal alkyl in a Ziegler polymerization system

S. Buchwald, M. Steigerwald, R. Grubbs, 1985 .

Palladium-catalyzed intramolecular C-O bond formation.

S. Buchwald, K. E. Torraca, S. Kuwabe, 2001, Journal of the American Chemical Society.

Synthesis of Oxygen Heterocycles via a Palladium-Catalyzed C−O Bond-Forming Reaction

S. Buchwald, J. Wolfe, M. Palucki, 1996 .

Synthesis of Polysubstituted Indoles and Indolines by Means of Zirconocene-Stabilized Benzyne Complexes

S. Buchwald, J. Tidwell, 1994 .

CONVENIENT TWO-STEP CONVERSION OF LACTONES INTO CYCLIC ETHERS

S. Buchwald, X. Verdaguer, M. Hansen, 1998 .

CATALYTIC ASYMMETRIC HYDROGENATION OF IMINES WITH A CHIRAL TITANOCENE CATALYST : SCOPE AND LIMITATIONS

S. Buchwald, C. A. Willoughby, 1994 .

Cobalt-phosphite-catalyzed asymmetric Pauson-Khand reaction.

S. Buchwald, S. Sturla, 2002, The Journal of organic chemistry.

Highly Enantioselective Catalytic Pauson−Khand Type Formation of Bicyclic Cyclopentenones

S. Buchwald, Frederick A. Hicks, 1996 .

Palladium-Catalyzed C-O Cross-Coupling of Primary Alcohols.

S. Buchwald, Paula Ruiz-Castillo, Hong Zhang, 2018, Organic letters.

Pd-catalyzed intermolecular amidation of aryl halides: the discovery that xantphos can be trans-chelating in a palladium complex.

S. Buchwald, Jingjun Yin, S. Buchwald, 2002, Journal of the American Chemical Society.

Regioselective 2-Amination of Polychloropyrimidines.

S. Buchwald, Sean M. Smith, 2016, Organic letters.

Titanocene-Based Method for Indole Synthesis

S. Buchwald, K. Aoki, A. Peat, 1998 .

Synthesis of 5,5-disubstituted butenolides based on a Pd-catalyzed gamma-arylation strategy.

S. Buchwald, Alan M. Hyde, 2009, Organic Letters.

Rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated alkenes.

S. Buchwald, Xiaoqiang Shen, S. Buchwald, 2009, Angewandte Chemie.

Synthesis and Solution Structure of Palladium Tris(o-tolyl)phosphine Mono(amine) Complexes

S. Buchwald, R. Widenhoefer, A. Zhong, 1996 .

Improved functional group compatibility in the palladium-catalyzed synthesis of aryl amines.

S. Buchwald, Xiaohua Huang, M. C. Harris, 2002, Organic letters.

Mild and highly selective palladium-catalyzed monoarylation of ammonia enabled by the use of bulky biarylphosphine ligands and palladacycle precatalysts.

S. Buchwald, D. Surry, C. Cheung, 2013, Organic letters.

Zirconocene complexes of imines. General synthesis, structure, reactivity, and in situ generation to prepare geometrically pure allylic amines

S. Buchwald, J. Dewan, Brett T. Watson, 1989 .

A method for the asymmetric hydrosilylation of N-aryl imines.

S. Buchwald, M. C. Hansen, S. Buchwald, 2000, Organic letters.

Synthesis of NPS R-568 utilizing titanium-catalyzed asymmetric hydrosilylation

S. Buchwald, M. Hansen, Marcus C. Hansen, 1999 .

Preparation and X-ray structure of a novel chiral methylene bridged titanocene complex

W. M. Davis, S. Buchwald, C. A. Willoughby, 1995 .

Catalytic Asymmetric Hydrogenation of Imines with a Chiral Titanocene Catalyst: Scope and Limitations.

S. Buchwald, C. A. Willoughby, 1995 .

Synthesis and reactions of a zirconocene-benzdiyne equivalent

S. Buchwald, E. Lucas, D. P. Hsu, 1990 .

Palladium-Catalyzed Coupling of Optically Active Amines with Aryl Bromides

S. Buchwald, S. Wagaw, R. Rennels, 1997 .

Preparation of Novel Titanium Complexes Bearing o-Phosphinophenol Ligands

W. M. Davis, S. Buchwald, C. A. Willoughby, 1996 .

Preparation, crystal structure analysis, and catalytic application of [(S)-BINAP]Ni(COD) and [(S)-BINAP]NiBr2

W. M. Davis, S. Buchwald, Dirk Spielvogel, 2002 .

Nickel-BINAP Catalyzed Enantioselective a-Arylation of a-Substituted ?-Butyrolactones

S. Buchwald, Dirk Spielvogel, 2002 .

Synthesis and x-ray crystal structure of a zirconocene complex of a cyclopentyne and its use to prepare bicyclic cyclopentenones

W. M. Davis, S. Buchwald, R. Lum, 1989 .

Group 4 Metal Complexes of Benzynes, Cycloalkynes, Acyclic Alkynes, and Alkenes

S. Buchwald, R. Nielsen, S. Buchwald, 1988 .

Synthesis, structure, and reactions of a zirconocene-cyclohexyne complex

S. Buchwald, J. Dewan, R. Lum, 1986 .

Olefin insertion in a metal alkyl in a Ziegler polymerization system

S. Buchwald, M. Steigerwald, R. Grubbs, 1985 .

Syntheses of [ethylene-1,2-bis(.eta.5-4,5,6,7-tetrahydro-1-indenyl)]zirconium and -hafnium hydride complexes. Improved syntheses of the corresponding dichlorides

S. Buchwald, R. B. Grossman, R. Doyle, 1991 .

Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV)

S. Buchwald, J. Storhoff, J. Jefferis, 2007 .

Kinetics and substituent effects in the formation of zirconocene thioaldehyde complexes: .beta.-hydride elimination versus cyclometalation

S. Buchwald, R. Nielsen, 1988 .

The synthesis, structure and reactivity of trimethylphosphine-zirconocene thioaldehyde complexes

S. Buchwald, J. Dewan, R. Nielsen, 1987 .

Trimethylphosphine adduct of the zirconocene-benzyne complex: synthesis, reactions, and x-ray crystal structure

S. Buchwald, J. Huffman, Brett T. Watson, 1986 .

Asymmetric titanocene-catalyzed hydrogenation of imines

S. Buchwald, C. A. Willoughby, 1992 .

Palladium-Catalyzed Aromatic Aminations with in situ Generated Aminostannanes

S. Buchwald, A. Guram, S. Buchwald, 1994 .

Rapid and efficient copper-catalyzed Finkelstein reaction of (hetero)aromatics under continuous-flow conditions.

S. Buchwald, Mao Chen, Stephen L Buchwald, 2015, Angewandte Chemie.

A Nickel(0)-Catalyzed Process for the Transformation of Enynes to Bicyclic Cyclopentenones.

S. Buchwald, Minghui Zhang, Ming-hui Zhang, 1996, The Journal of organic chemistry.

Development of a Titanocene-Catalyzed Enyne Cyclization/Isocyanide Insertion Reaction

S. Buchwald, R. B. Grossman, S. Berk, 1994 .

Reductive cyclization of ester-containing enynes with a practical titanocene reagent. Synthesis of bicyclic cyclopentenones and iminocyclopentenes

S. Buchwald, R. B. Grossman, 1992 .

One-pot synthesis of unsymmetrical triarylamines from aniline precursors.

S. Buchwald, M. C. Harris, 2000, The Journal of organic chemistry.

Palladium-catalyzed aminocarbonylation of aryl chlorides at atmospheric pressure: the dual role of sodium phenoxide.

S. Buchwald, Rachel Munday, J. R. Martinelli, 2007, Angewandte Chemie.

Enantioselective C2-Allylation of Benzimidazoles Using 1,3-Diene Pronucleophiles.

S. Buchwald, Yuxuan Ye, James Levi Knippel, 2021, Organic letters.

Palladium(0)-catalyzed arylative dearomatization of phenols.

Sophie A. L. Rousseaux, S. Buchwald, J. García-Fortanet, 2011, Journal of the American Chemical Society.

Palladium-Catalyzed Method for the Synthesis of Carbazoles via Tandem C—H Functionalization and C—N Bond Formation.

S. Buchwald, Rachel Munday, Gordon Brasche, 2009 .

Palladium-catalyzed asymmetric dearomatization of naphthalene derivatives.

S. Buchwald, F. Kessler, J. García-Fortanet, 2009, Journal of the American Chemical Society.

A Palladium-Catalyzed Method for the Preparation of Indoles via the Fischer Indole Synthesis

Stephen L. Buchwald, S. Buchwald, S. Wagaw, 1999 .

A Palladium-Catalyzed Strategy for the Preparation of Indoles: A Novel Entry into the Fischer Indole Synthesis

S. Buchwald, S. Wagaw, Bryant H. Yang, 1998 .

Microfluidic electrochemistry for single-electron transfer redox-neutral reactions

S. Buchwald, K. Jensen, N. Gershenfeld, 2020, Science.

Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes.

S. Buchwald, Stephen L Buchwald, Yi-Ming Wang, 2015, Angewandte Chemie.

Easy access to novel substituted 6-aminoimidazo[1,2-a]pyridines using palladium- and copper-catalyzed aminations.

S. Buchwald, A. Gueiffier, H. Allouchi, 2003, The Journal of organic chemistry.

Palladium-catalyzed carbonylation of aryl tosylates and mesylates.

S. Buchwald, Rachel Munday, J. R. Martinelli, 2008, Journal of the American Chemical Society.

Sequential Cu-catalyzed amidation-base-mediated camps cyclization: a two-step synthesis of 2-Aryl-4-quinolones from o-halophenones.

S. Buchwald, K. Anderson, Carrie P. Jones, 2007, The Journal of organic chemistry.

Convenient method for the preparation of Weinreb amides via Pd-catalyzed aminocarbonylation of aryl bromides at atmospheric pressure.

S. Buchwald, J. R. Martinelli, Stephen L Buchwald, 2006, Organic letters.

A GENERAL SYNTHESIS OF END-FUNCTIONALIZED OLIGOANILINES VIA PALLADIUM-CATALYZED AMINATION

S. Buchwald, J. Sadighi, R. Singer, 1998 .

Sequential copper-catalyzed vinylation/cyclization: an efficient synthesis of functionalized oxazoles.

S. Buchwald, A. Cuenca, Rúben Martín, 2007, Organic letters.

Copper-catalyzed regiospecific synthesis of N-alkylbenzimidazoles.

S. Buchwald, N. Zheng, S. Buchwald, 2007, Organic letters.

Synthesis and Reactions of 3-(Bromomethyl)-1-carbethoxy-4-iodoindole: The Preparation of 3,4-Differentially Substituted Indoles

S. Buchwald, J. Tidwell, A. Peat, 1994 .

An Intramolecular Titanium-Catalyzed Asymmetric Pauson−Khand Type Reaction1

S. Buchwald, Frederick A. Hicks, 1999 .

Catalytic Asymmetric Cyclocarbonylation of Nitrogen-Containing Enynes.

S. Buchwald, S. Sturla, 1999, The Journal of organic chemistry.

Titanocene-Catalyzed Cyclocarbonylation of Enynes to Cyclopentenones

S. Buchwald, Natasha M. Kablaoui, Frederick A. Hicks, 1996 .

Copper-catalyzed asymmetric conjugate reduction as a route to novel beta-azaheterocyclic acid derivatives.

S. Buchwald, Y. Aye, Matthew P. Rainka, 2004, Proceedings of the National Academy of Sciences of the United States of America.

Catalytic enantioselective conjugate reduction of lactones and lactams.

S. Buchwald, G. Hughes, M. Kimura, 2003, Journal of the American Chemical Society.

Asymmetric Conjugate Reduction of α,β-Unsaturated Esters Using a Chiral Phosphine−Copper Catalyst

S. Buchwald, Y. Moritani, R. Shintani, 1999 .

Cobalt—Phosphite-Catalyzed Asymmetric Pauson—Khand Reaction.

S. Buchwald, S. Sturla, 2002 .

Highly Enantioselective Catalytic Pauson‐Khand Type Formation of Bicyclic Cyclopentenones.

S. Buchwald, Frederick A. Hicks, 1997 .

Palladium‐Catalyzed γ‐Arylation of β,γ‐Unsaturated Ketones: Application to a One‐Pot Synthesis of Tricyclic Indolines

S. Buchwald, Alan M. Hyde, 2008 .

An improved catalyst for the asymmetric arylation of ketone enolates.

S. Buchwald, A. Chieffi, J. Ahman, 2002, Journal of the American Chemical Society.

Titanocene-Catalyzed Cyclocarbonylation of o-Allyl Aryl Ketones to γ-Butyrolactones

S. Buchwald, Natasha M. Kablaoui, Frederick A. Hicks, 1997 .

Halide and Amine Influence in the Equilibrium Formation of Palladium Tris(o-tolyl)phosphine Mono(amine) Complexes from Palladium Aryl Halide Dimers

S. Buchwald, R. Widenhoefer, 1996 .

Domino Cu-Catalyzed C—N Coupling/Hydroamidation: A Highly Efficient Synthesis of Nitrogen Heterocycles.

S. Buchwald, M. Rivero, Rúben Martín, 2007 .

IMPROVED FUNCTIONAL GROUP COMPATIBILITY IN THE PALLADIUM-CATALYZED AMINATION OF ARYL BROMIDES

S. Buchwald, J. Wolfe, 1997 .

Improved Process for the Palladium-Catalyzed C-O Cross-Coupling of Secondary Alcohols.

S. Buchwald, Paula Ruiz-Castillo, Hong Zhang, 2020, Organic letters.

Rational Ligand Design for the Arylation of Hindered Primary Amines Guided by Reaction Progress Kinetic Analysis

S. Buchwald, D. Blackmond, Paula Ruiz-Castillo, 2015, Journal of the American Chemical Society.

A bulky biaryl phosphine ligand allows for palladium-catalyzed amidation of five-membered heterocycles as electrophiles.

S. Buchwald, Mingjuan Su, S. Buchwald, 2012, Angewandte Chemie.

Me3(OMe)tBuXPhos: a surrogate ligand for Me4tBuXPhos in palladium-catalyzed C-N and C-O bond-forming reactions.

S. Buchwald, B. Fors, S. Ueda, 2012, The Journal of organic chemistry.

Pd-catalyzed O-arylation of ethyl acetohydroximate: synthesis of O-arylhydroxylamines and substituted benzofurans.

S. Buchwald, T. Maimone, S. Buchwald, 2010, Journal of the American Chemical Society.

Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane.

S. Buchwald, Timothy E. Barder, Eric McNeill, 2007, Organic letters.

Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Olefins with a Cationic Zirconocene Catalyst

S. Buchwald, D. Appella, Malisa V. Troutman, 1999 .

CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines.

S. Buchwald, Jeffrey C Yang, Haoxuan Wang, 2017, Journal of the American Chemical Society.

Palladium-(0)-Catalyzed Arylative Dearomatization of Phenols.

Sophie A. L. Rousseaux, S. Buchwald, J. García-Fortanet, 2011 .

Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes

S. Buchwald, Yi‐Ming Wang, 2016, Journal of the American Chemical Society.

Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective Hydrocupration

S. Buchwald, Yang Yang, Ian B. Perry, 2016, Journal of the American Chemical Society.

Catalyst-controlled chemoselective arylation of 2-aminobenzimidazoles.

S. Buchwald, S. Ueda, S. Buchwald, 2012, Angewandte Chemie.

Synthesis of chiral 3-substituted indanones via an enantioselective reductive-Heck reaction.

S. Buchwald, Xiaolai Zheng, A. Minatti, 2007, The Journal of organic chemistry.

Investigating the dearomative rearrangement of biaryl phosphine-ligated Pd(II) complexes.

S. Buchwald, Jiahao Chen, Phillip J. Milner, 2012, Journal of the American Chemical Society.

Unexpected Formation of Hexasubstituted Arenes through a Twofold Palladium-Mediated Ligand Arylation.

S. Buchwald, Corin C. Wagen, Bryan T. Ingoglia, 2019, The Journal of organic chemistry.

Efficient kinetic resolution in the asymmetric hydrosilylation of imines of 3-substituted indanones and 4-substituted tetralones.

S. Buchwald, J. Yun, S. Buchwald, 2000, The Journal of organic chemistry.

Cu-catalyzed tandem C-N bond formation for the synthesis of pyrroles and heteroarylpyrroles.

S. Buchwald, A. Cuenca, Rúben Martín, 2007, Organic letters.

Synthesis of medium ring nitrogen heterocycles via a tandem copper-catalyzed C-N bond formation-ring-expansion process.

Artis Klapars, S. Buchwald, Stephen L Buchwald, 2004, Journal of the American Chemical Society.

Pd-catalyzed amidation of aryl chlorides using monodentate biaryl phosphine ligands: a kinetic, computational, and synthetic investigation.

S. Buchwald, M. R. Biscoe, Takashi Ikawa, 2007, Journal of the American Chemical Society.

Enantioselective Synthesis of β-Amino Acid Derivatives Enabled by Ligand-Controlled Reversal of Hydrocupration Regiochemistry.

S. Buchwald, Sheng-Mei Guo, Jiaqi Zhu, 2020, Angewandte Chemie.

Asymmetric Synthesis of γ-Amino Alcohols by Copper-Catalyzed Hydroamination.

S. Buchwald, Saki Ichikawa, 2019, Organic letters.

Amine Additives Greatly Expand the Scope of Asymmetric Hydrosilylation of Imines.

S. Buchwald, X. Verdaguer, Udo E W Lange, 1998, Angewandte Chemie.

Highly Enantioselective Imine Hydrosilylation Using (S,S)-Ethylenebis(η5-tetrahydroindenyl)titanium Difluoride

S. Buchwald, X. Verdaguer, Udo E W Lange, 1996 .

Copper-catalyzed coupling of arylboronic acids and amines.

S. Buchwald, J. Antilla, S. Buchwald, 2001, Organic letters.

Use of polymer-supported dialkylphosphinobiphenyl ligands for palladium-catalyzed amination and Suzuki reactions.

S. Buchwald, C. Parrish, S. Buchwald, 2001, The Journal of organic chemistry.

Palladium-Catalyzed Hydroxylation of Aryl and Heteroaryl Halides Enabled by the Use of a Palladacycle Precatalyst

S. Buchwald, C. Cheung, S. Buchwald, 2014, The Journal of organic chemistry.

Synthesis of Pyrroles Through the CuH-Catalyzed Coupling of Enynes and Nitriles.

S. Buchwald, P. Liu, Peng Liu, 2020, Journal of the American Chemical Society.

Coupling of Secondary Alkylzinc Halides with Aryl Bromidesand Chlorides

S. Buchwald, C. Han, 2009 .

The Use of Catalytic Amounts of CuCl and Other Improvements in the Benzyne Route to Biphenyl‐Based Phosphine Ligands

S. Buchwald, S. Kaye, J. Fox, 2001 .

An extremely active catalyst for the Negishi cross-coupling reaction.

S. Buchwald, Jacqueline E. Milne, S. Buchwald, 2004, Journal of the American Chemical Society.

Short Enantioselective Total Syntheses of the Piperidine Alkaloids (S)-Coniine and (2R,6R)-trans-Solenopsin A via Catalytic Asymmetric Imine Hydrosilylation.

S. Buchwald, Matthew T. Reding, 1998, The Journal of organic chemistry.

Kinetic resolution and isomerization of 2,5-disubstituted pyrrolines.

S. Buchwald, J. Yun, 2000, Chirality.

Kinetic resolution of racemic disubstituted 1-pyrrolines via asymmetric reduction with a chiral titanocene catalyst

S. Buchwald, A. Viso, N. Lee, 1994 .

Short Enantioselective Total Syntheses of the Piperidine Alkaloids (S)-Coniine and (2R,6R)-trans-Solenopsin A via Catalytic Asymmetric Imine Hydrosilylation.

S. Buchwald, Matthew T. Reding, S. Buchwald, 1998, The Journal of organic chemistry.

A General and Efficient Method for the Palladium‐Catalyzed Cross‐Coupling of Thiols and Secondary Phosphines.

S. Buchwald, Miki Murata, 2004 .

Copper-catalyzed selective hydroamination reactions of alkynes

S. Buchwald, Shi‐Liang Shi, S. Buchwald, 2014, Nature Chemistry.

An improved catalyst for the asymmetric arylation of ketone enolates.

S. Buchwald, A. Chieffi, J. Ahman, 2002, Journal of the American Chemical Society.

Titanocene-Catalyzed Asymmetric Ketone Hydrosilylation: The Effect of Catalyst Activation Protocol and Additives on the Reaction Rate and Enantioselectivity

S. Buchwald, J. Yun, S. Buchwald, 1999 .

A New Palladium Precatalyst for the Suzuki Coupling of UnstableBoronic Acids

S. Buchwald, T. Kinzel, Y. Zhang, 2011 .

Palladium-catalyzed cross-coupling of aryl chlorides and triflates with sodium cyanate: a practical synthesis of unsymmetrical ureas.

S. Buchwald, B. Fors, E. Vinogradova, 2012, Journal of the American Chemical Society.

Palladium-catalyzed N-arylation of 2-aminothiazoles.

S. Buchwald, Jaclyn L Henderson, Meredeth A. McGowan, 2012, Organic letters.

An Inexpensive Air-Stable Titanium-Based System for the Conversion of Esters to Primary Alcohols

S. Buchwald, Matthew T. Reding, S. Buchwald, 1995 .

Dynamic Kinetic Resolution of α,β‐Unsaturated Lactones through Asymmetric Copper‐Catalyzed Conjugate Reduction: Application to the Total Synthesis of Eupomatilone‐3

S. Buchwald, Matthew P. Rainka, Jacqueline E. Milne, 2005 .

Oxygen-atom transfer from nitrous oxide. Synthesis and structure of a zirconocene oxametallacyclobutene complex

S. Buchwald, R. Lum, A. Rheingold, 1988 .

Synthesis and structure of a seven-membered cyclic cumulene

W. M. Davis, S. Buchwald, D. P. Hsu, 1993 .

An efficient one-pot method for the preparation of polysubstituted benzothiophenes

S. Buchwald, Qun Fang, S. Buchwald, 1989 .

Selective, zirconium-mediated cross-coupling of alkynes: the synthesis of isomerically pure 1,3-dienes and 1,4-diiodo-1,3-dienes

S. Buchwald, R. Nielsen, S. Buchwald, 1989 .

Cross-coupling in flow.

Timothy Noël, Stephen L. Buchwald, S. Buchwald, 2011, Chemical Society reviews.

Continuous-flow synthesis of 3,3-disubstituted oxindoles by a palladium-catalyzed α-arylation/alkylation sequence.

S. Buchwald, Pengfei Li, S. Buchwald, 2011, Angewandte Chemie.

An improved protocol for the Pd-catalyzed alpha-arylation of aldehydes with aryl halides.

S. Buchwald, Rúben Martín, R. Martín, 2008, Organic letters.

One-pot sequential Cu-catalyzed reduction and Pd-catalyzed arylation of silyl enol ethers.

S. Buchwald, Junghyun Chae, J. Yun, 2004, Organic letters.

Palladium-Catalyzed Intramolecular a-Arylation of a-Amino Acid Esters

S. Buchwald, Oliver Gaertzen, 2002 .

Enantioselective β-arylation of ketones enabled by lithiation/borylation/1,4-addition sequence under flow conditions.

S. Buchwald, W. Shu, S. Buchwald, 2012, Angewandte Chemie.

Enantioselective synthesis of α-aminosilanes by copper-catalyzed hydroamination of vinylsilanes.

S. Buchwald, Shaolin Zhu, N. Niljianskul, 2014, Angewandte Chemie.

Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination

S. Buchwald, D. Niu, S. Buchwald, 2015, Journal of the American Chemical Society.

Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins

S. Buchwald, J. Bandar, Michael T Pirnot, 2015, Journal of the American Chemical Society.

Organometallic Palladium Reagents for Cysteine Bioconjugation

Alexander M. Spokoyny, Bradley L. Pentelute, Stephen L. Buchwald, 2015, Nature.

Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles.

S. Buchwald, Richard Y. Liu, Chengxi Li, 2019, Angewandte Chemie.

Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids

S. Buchwald, J. Bandar, E. Ascic, 2016, Journal of the American Chemical Society.

Reductive Cyclization of Enones by a Titanium Catalyst

S. Buchwald, Natasha M. Kablaoui, 1995 .

Preparation of 2-amino-2′-hydroxy-1,1′-binaphthyl and N-arylated 2-amino-1,1′-binaphthyl derivatives via palladium-catalyzed amination

S. Buchwald, R. Singer, 1999 .

An air-stable catalyst system for the conversion of esters to alcohols. [Erratum to document cited in CA117(3):25599z]

S. Buchwald, S. Berk, 1993 .

Rh-catalyzed asymmetric hydroformylation of functionalized 1,1-disubstituted olefins.

S. Buchwald, Xiao Wang, S. Buchwald, 2011, Journal of the American Chemical Society.

Synthesis and structure of novel antimony thiametallacycles

W. M. Davis, S. Buchwald, R. Fisher, 1989 .

Dialkylbiaryl Phosphines in Pd‐Catalyzed Amination: A User′s Guide

S. Buchwald, D. Surry, 2011 .

Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes.

S. Buchwald, Yang Yang, Richard Y. Liu, 2016, Angewandte Chemie.

Titanocene-Based Method for Indole Synthesis.

S. Buchwald, K. Aoki, A. Peat, 1998 .

Titanocene-Catalyzed Reduction of Esters Using Polymethylhydrosiloxane as the Stoichiometric Reductant

S. Buchwald, Scott C. Berk, K. Barr, 1994 .

A Titanocene-Catalyzed Intramolecular Ene Reaction: Cycloisomerization of Enynes and Dienynes

S. Buchwald, S. Sturla, Natasha M. Kablaoui, 1999 .

CATALYTIC ASYMMETRIC HYDROGENATION OF IMINES WITH A CHIRAL TITANOCENE CATALYST : KINETIC AND MECHANISTIC INVESTIGATIONS

S. Buchwald, C. A. Willoughby, 1994 .

An air-stable catalyst system for the conversion of esters to alcohols

S. Buchwald, S. Berk, 1992 .

Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles

S. Buchwald, J. Bandar, Michael T Pirnot, 2017, Journal of the American Chemical Society.

One-pot sequential Cu-catalyzed reduction and Pd-catalyzed arylation of silyl enol ethers.

S. Buchwald, Junghyun Chae, J. Yun, 2004, Organic letters.

Synthesis and reactivity of a titanocene-benzyne complex

S. Buchwald, J. Cámpora, 1993 .

A Combined Zirconocene Benzyne−Palladium Cross-Coupling Route to Substituted Biphenyls and Terphenyls

S. Buchwald, A. Peat, D. Pérez, 1999 .

Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates.

S. Buchwald, J. Bandar, Yujing Zhou, 2017, Journal of the American Chemical Society.

Efficient catalyst for the Suzuki-Miyaura coupling of potassium aryl trifluoroborates with aryl chlorides.

S. Buchwald, Timothy E. Barder, 2004, Organic letters.

A general method for the preparation of zirconocene complexes of substituted benzynes: in situ generation, coupling reactions, and use in the synthesis of polyfunctionalized aromatic compounds

W. A. Nugent, S. Buchwald, R. Lum, 1987 .

Monocyclopentadienyltitanium aryloxide complexes: Preparation, characterization, and application in cyclization reactions

S. Buchwald, S. Sturla, 2002 .

Catalytic Asymmetric Synthesis of α-Arylpyrrolidines and Benzo-fused Nitrogen Heterocycles.

S. Buchwald, Xi-Jie Dai, Thierry León, 2019, Angewandte Chemie.

Catalytic Asymmetric Synthesis of α-Arylpyrrolidines and Benzo-fused Nitrogen Heterocycles.

S. Buchwald, Xi-Jie Dai, Thierry León, 2019, Angewandte Chemie.

A Dual CuH- and Pd-Catalyzed Stereoselective Synthesis of Highly Substituted 1,3-Dienes.

S. Buchwald, Anton Z Ni, James Levi Knippel, 2021, Organic letters.

Enantioselective functionalization of radical intermediates in redox catalysis: copper-catalyzed asymmetric oxytrifluoromethylation of alkenes.

S. Buchwald, R. Zhu, S. Buchwald, 2013, Angewandte Chemie.

A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes.

E. Y. Tsai, S. Buchwald, Yang Yang, 2018, Journal of the American Chemical Society.

Copper Hydride-Catalyzed Enantioselective Olefin Hydromethylation.

Binh Khanh Mai, S. Buchwald, P. Liu, 2022, Journal of the American Chemical Society.

Enantioselective hydrosilylation of ketones with a chiral titanocene catalyst

S. Buchwald, B. Schiøtt, A. Gutiérrez, 1994 .

Asymmetric hydrogenation of unfunctionalized trisubstituted olefins with a chiral titanocene catalyst

S. Buchwald, R. Broene, 1993 .

Synthesis of highly enantiomerically enriched cyclic amines by the catalytic asymmetric hydrogenation of cyclic imines

S. Buchwald, C. A. Willoughby, 1993 .

Enantioselective, zirconium-mediated synthesis of allylic amines

W. M. Davis, S. Buchwald, R. B. Grossman, 1991 .

An Improved Method for the Palladium-Catalyzed Amination of Aryl Triflates

S. Buchwald, J. Ahman, 1997 .

Continuous-flow synthesis of biaryls enabled by multistep solid-handling in a lithiation/borylation/Suzuki-Miyaura cross-coupling sequence.

S. Buchwald, M. Oberli, Stephen L Buchwald, 2011, Angewandte Chemie.

A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination.

S. Buchwald, Shaolin Zhu, Saki Ichikawa, 2018, Angewandte Chemie.

A titanium vinylidene route to substituted allenes

S. Buchwald, R. Grubbs, 1983 .

Rhodium‐katalysierte Hydroformylierung innerer Alkine zu α,β‐ungesättigten Aldehyden

S. Buchwald, G. Cuny, John R. Johnson, 1995 .

Multistep microchemical synthesis enabled by microfluidic distillation.

Ryan L Hartman, Klavs F Jensen, Ryan L. Hartman, 2010, Angewandte Chemie.

Synthesis of 5,5-disubstituted butenolides based on a Pd-catalyzed gamma-arylation strategy.

S. Buchwald, Alan M. Hyde, S. Buchwald, 2009, Organic letters.

Palladium-catalyzed completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophiles.

S. Buchwald, Yang Yang, P. Cheong, 2013, Angewandte Chemie.

Kinetics and Mechanism of the Reductive Elimination of Cyclic Titanocene Iminoacyls

S. Buchwald, E. Gutiérrez‐Puebla, J. Cámpora, 1995 .

Rhodium‐Catalyzed Asymmetric Intramolecular Hydroamination of Unactivated Alkenes.

S. Buchwald, Xiaoqiang Shen, 2010 .

Formation of Palladium Bis(amine) Complexes from Reaction of Amine with Palladium Tris(o-tolyl)phosphine Mono(amine) Complexes

S. Buchwald, R. Widenhoefer, 1996 .

Continuous-flow synthesis of monoarylated acetaldehydes using aryldiazonium salts.

S. Buchwald, N. Chernyak, 2012, Journal of the American Chemical Society.

Breaking the Base Barrier: An Electron-Deficient Palladium Catalyst Enables the Use of a Common Soluble Base in C-N Coupling.

S. Buchwald, J. Dennis, Richard Y. Liu, 2018, Journal of the American Chemical Society.

Dynamic kinetic resolution via asymmetric conjugate reduction: enantio- and diastereoselective synthesis of 2,4-dialkyl cyclopentanones.

S. Buchwald, Valdas Jurkauskas, 2002, Journal of the American Chemical Society.

One-pot synthesis of enantiomerically enriched 2,3-disubstituted cyclopentanones via copper-catalyzed 1,4-reduction and alkylation.

S. Buchwald, J. Yun, 2001, Organic letters.

Pd-catalyzed cross-coupling reactions of amides and aryl mesylates.

S. Buchwald, B. Fors, K. Dooleweerdt, 2010, Organic letters.

A direct approach to amines with remote stereocenters by enantioselective CuH-catalysed reductive relay hydroamination

S. Buchwald, Shaolin Zhu, N. Niljianskul, 2015, Nature chemistry.

Enantioselective Olefin Hydrocyanation Without Cyanide.

S. Buchwald, Gustavo M. Borrajo-Calleja, Alexander W. Schuppe, 2019, Journal of the American Chemical Society.

Copper-Catalyzed Enantioselective Hydroamination of Alkenes.

S. Buchwald, Richard Y. Liu, 2019, Organic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals.

Diastereoselective Synthesis of γ-Butyrolactones from Enones Mediated or Catalyzed by a Titanocene Complex

S. Buchwald, Natasha M. Kablaoui, Frederick A. Hicks, 1996 .

Regioselective, Directed Meta Acylation of Aromatic Compounds

S. Buchwald, S. Akai, A. Peat, 1998 .

Sequential N-Arylation of Primary Amines as a Route To Alkyldiarylamines

S. Buchwald, M. C. Harris, Oliver Geis, 1999 .

Reactions of propargyl alcohols with amide acetals

S. Buchwald, J. Petraitis, K. A. Parker, 1982 .

A bimetallic zirconium complex containing an in-plane bridging aromatic ring

W. M. Davis, S. Buchwald, E. Lucas, 1989 .

The Synthesis and Structure of Stibaindoles

S. Buchwald, B. Foxman, R. Fisher, 1990 .

Palladium-catalyzed formation of aryl tert-butyl ethers from unactivated aryl halides.

S. Buchwald, C. Parrish, S. Buchwald, 2001, The Journal of organic chemistry.

Palladium-Catalyzed Intermolecular Carbon−Oxygen Bond Formation: A New Synthesis of Aryl Ethers

John P. Wolfe, Stephen L. Buchwald, S. Buchwald, 1997 .

Palladium-catalyzed regioselective hydrodebromination of dibromoindoles: application to the enantioselective synthesis of indolodioxane U86192A.

S. Buchwald, Junghyun Chae, 2004, The Journal of organic chemistry.

New Ammonia Equivalents for the Pd‐Catalyzed Amination of Aryl Halides.

S. Buchwald, Xiaohua Huang, 2002 .

Synthesis of 3,4-disubstituted indoles via a sequential olefin-insertion/ene route

S. Buchwald, J. Tidwell, D. R. Senn, 1991 .

7.4 – Transition Metal Alkyne Complexes: Zirconium–Benzyne Complexes

S. Buchwald, 1995 .

Asymmetric Hydrogenation of Enamines with a Chiral Titanocene Catalyst.

S. Buchwald, N. Lee, 1994 .

A Neophyl Palladacycle as an Air- and Thermally Stable Precursor to Oxidative Addition Complexes.

S. Buchwald, S. Krska, Ryan P. King, 2021, Organic letters.

Aryl amination using ligand-free Ni(II) salts and photoredox catalysis

Ian W. Davies, Spencer D. Dreher, Stephen L. Buchwald, 2016, Science.

Synthesis of β-Alkyl Cyclopentanones in High Enantiomeric Excess via Copper-Catalyzed Asymmetric Conjugate Reduction

S. Buchwald, Y. Moritani, D. Appella, 2000 .

The reaction of tertiary ethynyl alcohols with formamide acetals: formation of dienamines and enamine orthoformates

S. Buchwald, J. Petraitis, K. A. Parker, 1976 .

Synthesis and Structure of a Novel Bis-Stibole

W. M. Davis, S. Buchwald, B. Warner, 1994 .

Development of a Method for the Reductive Cyclization of Enones by a Titanium Catalyst

S. Buchwald, Natasha M. Kablaoui, 1996 .

Stereochemical evidence for pseudorotation in the reaction of a phosphoric monoester

S. Buchwald, J. Knowles, D. Pliura, 1984 .

New insights into Xantphos/Pd-Catalyzed C-N bond forming reactions : A structural and kinetic study

Stephen L. Buchwald, S. Buchwald, E. Strieter, 2006 .

Cis difunctionalization of cyclic olefins with use of organozirconium intermediates

S. Buchwald, G. Cuny, A. Gutiérrez, 1991 .

Stibathiolanes: synthesis, solid-state structure, and solution behavior

W. M. Davis, S. Buchwald, R. Nielsen, 1991 .

The zirconocene induced coupling of benzyne with nitriles: Synthesis, structure and reactions of novel azametallacyclopentenes

S. Buchwald, J. Dewan, J. C. Dewan, 1987 .

The Regioselective Synthesis of Halophenols.

S. Buchwald, F. D. Rege, S. Buchwald, 1995 .

Schwartz's Reagent

Susan M. King, S. Buchwald, Brett T. Watson, 2003 .

Palladium-catalyzed amination reactions in flow: overcoming the challenges of clogging via acoustic irradiation

Jonathan P. McMullen, Klavs F. Jensen, Timothy Noël, 2011 .

Reaction of dicyclopentadienylmethylenetitanium with organic halides: Evidence for a radical mechanism

S. Buchwald, R. Grubbs, E. Anslyn, 2002 .

Packed-bed reactors for continuous-flow C-N cross-coupling.

S. Buchwald, J. R. Naber, John R Naber, 2010, Angewandte Chemie.

Addendum: Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols

S. Buchwald, Shi‐Liang Shi, Zackary L. Wong, 2018, Nature.

Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles.

S. Buchwald, Richard Y. Liu, Chengxi Li, 2019, Angewandte Chemie.

Diastereoselective Synthesis of γ‐Butyrolactones from Enones Mediated or Catalyzed by a Titanocene Complex.

S. Buchwald, Natasha M. Kablaoui, Frederick A. Hicks, 1996 .

Asymmetric Cu-Catalyzed 1,4-Dearomatization of Pyridines and Pyridazines without Preactivation of the Heterocycle or Nucleophile.

S. Buchwald, Sheng-Mei Guo, Michael W. Gribble, 2018, Journal of the American Chemical Society.

A catalytic method for the reduction of esters to alcohols

S. Buchwald, Scott C. Berk, S. Berk, 1991 .

Zirconocene Complexes of Imines: General Synthesis, Structure, Reactivity, and in situ Generation to Prepare Geometrically Pure Allylic Amines.

S. Buchwald, J. Dewan, Brett T. Watson, 1989 .

Palladium-catalyzed monoarylation of nitroalkanes.

S. Buchwald, E. Vogl, 2002, The Journal of organic chemistry.

Synthesis and X-ray Structure of a Zirconocene Complex of Two Alkynes

W. M. Davis, S. Buchwald, B. Warner, 1994 .

CuH-Catalyzed Asymmetric Reduction of α,β-Unsaturated Carboxylic Acids to β-Chiral Aldehydes.

S. Buchwald, J. Bandar, Yujing Zhou, 2018, Journal of the American Chemical Society.

A highly active palladium catalyst system for the arylation of anilines

S. Buchwald, J. Sadighi, M. C. Harris, 1998 .

An improved system for the palladium-catalyzed borylation of aryl halides with pinacol borane.

S. Buchwald, K. Billingsley, S. Buchwald, 2008, The Journal of organic chemistry.

An Improved Procedure for the Resolution of (rac)-Ethylenebis(tetrahydroindenyl)Titanium Derivatives

S. Buchwald, Bain Chin, 1996 .

A Method for the Asymmetric Hydrosilylation of N‐Aryl Imines.

S. Buchwald, M. Hansen, 2000 .

Improved Procedure for the Preparation of Enantiomerically Pure Ethylenebis(tetrahydroindenyl)zirconium Derivatives.

S. Buchwald, Bain Chin, 1997, The Journal of organic chemistry.

Copper-catalysed Selective Hydroamination Reactions of Alkynes Accessed Terms of Use Detailed Terms Copper-catalyzed Selective Hydroamination Reactions of Alkynes Nih Public Access Author Manuscript Results and Discussion Supplementary Material Refer to Web Version on Pubmed Central for Supplementar

S. Buchwald, Shi‐Liang Shi, 2022 .

Synthesis of NPS R-568 Utilizing Titanium-Catalyzed Asymmetric Hydrosilylation.

S. Buchwald, M. Hansen, 1999 .

Practical Palladium Catalysts for CN and CO Bond Formation

S. Buchwald, Alexander R. Muci, 2003 .

Palladium-Catalyzed Amination of Aryl Triflates

S. Buchwald, J. Wolfe, 1997 .

Synthesis and Reactions of a Zirconocene‐Benzdiyne Equivalent.

S. Buchwald, E. Lucas, D. P. Hsu, 1991 .

Regio- and Enantioselective Synthesis of 1,2-Diamine Derivatives by Copper-Catalyzed Hydroamination.

S. Buchwald, Xi-Jie Dai, Saki Ichikawa, 2019, Organic letters.

The development of efficient protocols for the palladium-catalyzed cyclization reactions of secondary amides and carbamates.

S. Buchwald, B. Yang, 1999, Organic letters.

Scope and limitations of the Pd/BINAP-catalyzed amination of aryl bromides.

S. Buchwald, J. Wolfe, 2000, The Journal of organic chemistry.

Palladium‐Catalyzed Coupling of Optically Active Amines with Aryl Bromides.

S. Buchwald, S. Wagaw, R. Rennels, 1997 .

Electronic effects on the selectivity of pd-catalyzed C-N bond-forming reactions using biarylphosphine ligands: the competitive roles of amine binding and acidity.

S. Buchwald, M. R. Biscoe, Timothy E. Barder, 2007, Angewandte Chemie.

Titanocene-Catalyzed Reduction of Lactones to Lactols.

S. Buchwald, X. Verdaguer, S. Berk, 1997, The Journal of organic chemistry.

An improved method for the palladium-catalyzed amination of aryl iodides.

S. Buchwald, Mayssam H. Ali, M. H. Ali, 2001, The Journal of organic chemistry.

A Modified Procedure for the Preparation of Cp2Zr(H)Cl (Schwartz's Reagent)

Susan M. King, S. Buchwald, Brett T. Watson, 1987 .

Synthesis of (alkoxymethyl)zirconocene chlorides: stereochemistry of carbon-carbon bond formation in a zirconocene-Wittig rearrangement

S. Buchwald, J. Dewan, R. Nielsen, 1989 .

Synthesis of thermochromic dibismuthines with nonthermochromic distibine analogs

S. Buchwald, R. Spence, D. P. Hsu, 1992 .

PREPARATION AND X-RAY STRUCTURE OF CP2TI(PH2SIH2)(PME3)

W. M. Davis, S. Buchwald, C. A. Willoughby, 1994 .

Synthesis, characterization, and reactivity of zirconocene and hafnocene silyl hydride complexes

W. M. Davis, S. Buchwald, Esther. Spaltenstein, 1991 .

Suzuki–Miyaura cross-coupling optimization enabled by automated feedback

Klavs F. Jensen, Yi-Ming Wang, Brandon J. Reizman, 2016 .

The regiospecific synthesis of polysubstituted naphthalenes and iodo(acyl)naphthoquinones via zirconocene complexes of naphthalynes

Susan M. King, S. Buchwald, 1991 .

Synthesis, reactions, and x-ray crystal structure determination of hafnocene complex Cp2Hf(isobutylene).cntdot.PMe3

S. Buchwald, R. Fisher, K. A. Kreutzer, 1990 .

A Practical Titanium-Catalyzed Synthesis of Bicyclic Cyclopentenones and Allylic Amines.

S. Buchwald, Frederick A. Hicks, S. Berk, 1996, The Journal of organic chemistry.

Room Temperature Catalytic Amination of Aryl Iodides

S. Buchwald, J. Wolfe, S. Buchwald, 1997 .

Palladium-Catalyzed Amination of Unprotected Five-Membered Heterocyclic Bromides

S. Buchwald, Naoyuki Hoshiya, Mingjuan Su, 2014, Organic letters.

Palladium Oxidative Addition Complexes for Peptide and Protein Cross-linking.

Peng Dai, S. Buchwald, P. Dai, 2018, Journal of the American Chemical Society.

Oligonucleotide Bioconjugation with Bifunctional Palladium Reagents

S. Buchwald, A. Loas, B. Pentelute, 2021, Angewandte Chemie.

Oligonucleotide Bioconjugation with Bifunctional Palladium Reagents.

S. Buchwald, A. Loas, B. Pentelute, 2021, Angewandte Chemie.

A Practical Electrophilic Nitrogen Source for the Synthesis of Chiral Primary Amines by Copper-Catalyzed Hydroamination.

S. Buchwald, Sheng-Mei Guo, Jeffrey C Yang, 2018, Journal of the American Chemical Society.

Palladium-catalyzed regioselective hydrodebromination of dibromoindoles: application to the enantioselective synthesis of indolodioxane U86192A.

S. Buchwald, Junghyun Chae, S. Buchwald, 2004, The Journal of organic chemistry.

A chemoselective strategy for late-stage functionalization of complex small molecules with polypeptides and proteins

Zachary Shriver, Kenneth D. Johnson, Scott J. Miller, 2018, Synthesis.

A versatile catalyst system for Suzuki-Miyaura cross-coupling reactions of C(sp(2))-tosylates and mesylates.

S. Buchwald, Brijesh Bhayana, B. Fors, 2009, Organic letters.

STILLE CROSS-COUPLING REACTIONS OF ARYL MESYLATES AND TOSYLATES USING A BIARYLPHOSPHINE BASED CATALYST SYSTEM.

S. Buchwald, J. R. Naber, B. Fors, 2009, Heterocycles.

A new method for the preparation of 3,5-disubstituted butenolides

Susan M. King, S. Buchwald, Qun Fang, 1988 .

Yeast Reveal a “Druggable” Rsp5/Nedd4 Network that Ameliorates α-Synuclein Toxicity in Neurons

Daniel F Tardiff, S. Buchwald, S. Lindquist, 2013, Science.

Identification and Rescue of α-Synuclein Toxicity in Parkinson Patient–Derived Neurons

Michael D. Pluth, Daniel F Tardiff, S. Buchwald, 2013, Science.

Pd-catalyzed Kumada-Corriu cross-coupling reactions at low temperatures allow the use of Knochel-type Grignard reagents.

S. Buchwald, R. Martín, 2007, Journal of the American Chemical Society.

Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis.

S. Buchwald, Michael T Pirnot, Stig D. Friis, 2016 .

Suzuki–Miyaura cross-coupling optimization enabled by automated feedback

Klavs F. Jensen, Brandon J. Reizman, Stephen L. Buchwald, 2016, Reaction chemistry & engineering.

A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines.

Stephen L. Buchwald, S. Buchwald, Anil S. Guram, 1995 .

Rationale behind the resistance of dialkylbiaryl phosphines toward oxidation by molecular oxygen.

S. Buchwald, Timothy E. Barder, 2007, Journal of the American Chemical Society.

Room Temperature Catalytic Amination of Aryl Iodides.

S. Buchwald, J. Wolfe, 1998 .

Chiral [16O, 17O, 18O]phosphoric monoesters as stereochemical probes of phosphotransferases.

S. Buchwald, J. Knowles, A. Hassett, 1982, Methods in enzymology.

A Fungal-Selective Cytochrome bc1 Inhibitor Impairs Virulence and Prevents the Evolution of Drug Resistance.

Raja R Srinivas, S. Buchwald, B. Tidor, 2016, Cell chemical biology.

Room-Temperature Cu-Catalyzed Amination of Aryl Bromides Enabled by DFT-Guided Ligand Design.

S. Buchwald, Albert Cabré, M. Strauss, 2023, Journal of the American Chemical Society.

An Improved Synthesis of Functionalized Biphenyl‐Based Phosphine Ligands.

S. Buchwald, J. Fox, H. Tomori, 2000 .

Reactions of propargyl alcohols with amide acetals

S. Buchwald, J. Petraitis, K. A. Parker, 1982 .

Divergent unprotected peptide macrocyclisation by palladium-mediated cysteine arylation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc05454d Click here for additional data file.

S. Buchwald, B. Pentelute, Chi Zhang, 2016, Chemical science.

Water-Soluble Palladium Reagents for Cysteine S-Arylation under Ambient Aqueous Conditions.

Bradley L. Pentelute, Stephen L. Buchwald, S. Buchwald, 2017, Organic letters.

Molecular Design of Deep Blue Thermally Activated Delayed Fluorescence Materials Employing a Homoconjugative Triptycene Scaffold and Dihedral Angle Tuning

S. Buchwald, T. Voorhis, H. Chae, 2018 .

Palladium‐Catalyzed Synthesis of Monodisperse, Controlled‐Length, and Functionalized Oligoanilines.

S. Buchwald, J. Sadighi, R. Singer, 1998 .

Highly Active Palladium Catalysts for Suzuki Coupling Reactions.

S. Buchwald, J. Wolfe, Bryant H. Yang, 2000 .

Direct 11CN-Labeling of Unprotected Peptides via Palladium-Mediated Sequential Cross-Coupling Reactions.

S. Buchwald, J. Hooker, Hong Geun Lee, 2017, Journal of the American Chemical Society.

Palladium‐Catalyzed Intermolecular Coupling of Aryl Halides and Amides.

S. Buchwald, Jingjun Yin, 2000 .

Palladium-Catalyzed N-Arylation of Iminodibenzyls and Iminostilbenes with Aryl- and Heteroaryl Halides.

S. Buchwald, Wenliang Huang, S. Buchwald, 2016, Chemistry.

Palladium‐Catalyzed Coupling of Functionalized Primary and Secondary Amines with Aryl and Heteroaryl Halides: Two Ligands Suffice in Most Cases.

S. Buchwald, D. Maiti, Jaclyn L Henderson, 2011 .

Pd-Catalyzed Amination of Base-Sensitive Five-Membered Heteroaryl Halides with Aliphatic Amines.

S. Buchwald, Kaibo Feng, Aaron C. Sather, 2023, Journal of the American Chemical Society.

Applications of Palladium-Catalyzed C-N Cross-Coupling Reactions

S. Buchwald, Paula Ruiz-Castillo, 2016 .

Highlights from the Flow Chemistry Literature 2013 (Part 1)

S. Buchwald, Mao Chen, T. Glasnov, 2013, Journal of Flow Chemistry.

Palladium-Catalyzed N-Arylation of 2-Aminothiazoles

S. Buchwald, Jaclyn L Henderson, Meredeth A. McGowan, 2012 .

Efficient Pd-catalyzed amination reactions for heterocycle functionalization.

S. Buchwald, Jaclyn L Henderson, 2010, Organic letters.

Cross-Coupling in Flow

Timothy Noël, Stephen L. Buchwald, S. Buchwald, 2012 .

Conjugate Reduction of α,β‐Unsaturated Carbonyl Compounds Catalyzed by a Copper Carbene Complex.

S. Buchwald, J. Sadighi, Valdas Jurkauskas, 2003 .

Structure and Reactivity of [(L•Pd)n•(1,5-cyclooctadiene)] (n=1-2) Complexes Bearing Biaryl Phosphine Ligands.

Michael T. Colvin, S. Buchwald, L. Andreas, 2014, Inorganica chimica acta.

Efficient Palladium‐Catalyzed Coupling of Aryl Chlorides and Tosylates with Terminal Alkynes: Use of a Copper Cocatalyst Inhibits the Reaction.

Stephen L. Buchwald, S. Buchwald, D. Gelman, 2004 .

Direct and selective elimination of specific prions and amyloids by 4,5-dianilinophthalimide and analogs

Andrew D. Steele, Martin L. Duennwald, J. King, 2008, Proceedings of the National Academy of Sciences.

CuH-Catalyzed Asymmetric Reductive Amidation of α,β-Unsaturated Carboxylic Acids.

S. Buchwald, Yujing Zhou, A. Link, 2020, Organic Letters.

Stereochemical course of phospho group transfer by human prostatic acid phosphatase.

S. Buchwald, J. Knowles, R. V. Van Etten, 1984, The Journal of biological chemistry.

A general method for Suzuki-Miyaura coupling reactions using lithium triisopropyl borates.

S. Buchwald, M. Oberli, S. Buchwald, 2012, Organic letters.

A New Palladium Precatalyst Allows for the Fast Suzuki—Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2‐Heteroaryl Boronic Acids.

S. Buchwald, Yong Zhang, T. Kinzel, 2011 .

Virtually instantaneous, room-temperature [(11)C]-cyanation using biaryl phosphine Pd(0) complexes.

S. Buchwald, J. Hooker, Michael S Placzek, 2015, Journal of the American Chemical Society.

Selective N-Arylation of p-Aminophenylalanine in Unprotected Peptides with Organometallic Palladium Reagents.

S. Buchwald, B. Pentelute, Aaron J. Mallek, 2021, Angewandte Chemie.

Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines

S. Buchwald, D. Niu, Yang Yang, 2015, Science.

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides.

S. Buchwald, Yong Zhang, E. Cho, 2010 .

Cross coupling.

S. Buchwald, 2008, Accounts of chemical research.

DIRECT OBSERVATION OF C-O REDUCTIVE ELIMINATION FROM PALLADIUM ARYL ALKOXIDE COMPLEXES TO FORM ARYL ETHERS

S. Buchwald, R. Widenhoefer, A. Zhong, 1997 .

Mechanistic insights into the Pd(BINAP)-catalyzed amination of aryl bromides: kinetic studies under synthetically relevant conditions.

S. Buchwald, E. Strieter, D. Blackmond, 2002, Journal of the American Chemical Society.

Titanocene-catalyzed conversion of enynes to bicyclic cyclopentenones

S. Buchwald, R. B. Grossman, S. Berk, 1993 .

Titanocene-Catalyzed Conversion of Enynes to Bicyclic Cyclopentenones.

S. Buchwald, R. B. Grossman, S. Berk, 1993 .

Engineering Bioactive Dimeric Transcription Factor Analogs via Palladium Rebound Reagents.

Carly K. Schissel, S. Buchwald, Isaac A. Klein, 2021, Journal of the American Chemical Society.

Palladium-Catalyzed Heck Alkynylation of Benzyl Chlorides

S. Buchwald, K. Anderson, Catharine H. Larsen, 2006 .

Abiotic peptides as carriers of information for the encoding of small-molecule library synthesis

S. Buchwald, B. Pentelute, N. Grob, 2023, Science.

Catalysts for Suzuki—Miyaura Coupling Processes: Scope and Studies of the Effect of Ligand Structure.

S. Buchwald, J. R. Martinelli, Timothy E. Barder, 2005 .

Copper-catalyzed enantioselective stereodivergent synthesis of amino alcohols

S. Buchwald, Shi‐Liang Shi, Zackary L. Wong, 2016, Nature.

Commentary on “A New, Efficient and Recyclable Lanthanum(III) Oxide-Catalyzed CN Cross-Coupling” by S. Narayana Murthy, B. Madhav, V. Prakash Reddy, and Y. V. D. Nageswar, Adv. Synth. Catal. 2010, 352, 3241–3245

S. Buchwald, B. Fors, 2010 .

NUCLEOPHILIC DISPLACEMENTS ON PHOSPHORIC MONOESTERS: STEREOCHEMICAL EVIDENCE

S. Buchwald, J. Knowles, 1982 .

Stereochemistry and mechanism of an acid-catalyzed 1,2-phospho group migration: evidence for pseudorotation in the reaction of a phosphoric monoester

S. Buchwald, J. Knowles, D. Pliura, 1982 .

Determination of the absolute configuration of [16O,17O,18O]phosphate monoesters by using phosphorus-31 NMR

S. Buchwald, J. Knowles, 1980 .

Stereoselective Synthesis of Trisubstituted Alkenes via Copper Hydride-Catalyzed Alkyne Hydroalkylation.

Binh Khanh Mai, S. Buchwald, P. Liu, 2023, Journal of the American Chemical Society.