K. Karlin

发表

The extended environment of mononuclear metal centers in protein structures.

S. Karlin, Z. Y. Zhu, K. Karlin, 1997, Proceedings of the National Academy of Sciences of the United States of America.

Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions.

K. Karlin, E. Solomon, D. A. Quist, 2019, Journal of the American Chemical Society.

Selective DNA strand scission with binuclear copper complexes: implications for an active Cu2-O2 species.

K. Karlin, S. Rokita, S. Thyagarajan, 2006, Journal of the American Chemical Society.

One-Step Selective Hydroxylation of Benzene to Phenol with Hydrogen Peroxide Catalysed by Copper Complexes Incorporated into Mesoporous Silica-Alumina.

K. Karlin, S. Fukuzumi, Mihoko Yamada, 2015, Chemical science.

One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina

K. Karlin, S. Fukuzumi, Mihoko Yamada, 2016, Chemical Science.

CO and O2 binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism.

K. Karlin, G. Meyer, Heather R. Lucas, 2010, Journal of the American Chemical Society.

Bioinorganic Chemistry of Copper

K. Karlin, Z. Tyeklár, 1993, Springer Netherlands.

Kinetics and thermodynamics of formation of copper-dioxygen adducts: oxygenation of mononuclear copper(I) complexes containing tripodal tetradentate ligands

K. Karlin, A. D. Zuberbuehler, S. Kaderli, 1993 .

Modeling of End-On (&mgr;-Peroxo)dicopper(II) Complexes.

K. Karlin, P. Comba, P. Hilfenhaus, 1997, Inorganic chemistry.

Formation of a long-lived electron-transfer state in mesoporous silica-alumina composites enhances photocatalytic oxygenation reactivity

K. Karlin, K. Ohkubo, S. Fukuzumi, 2012, Proceedings of the National Academy of Sciences.

Celebrating Ed Solomon

K. Karlin, Larry Que, 2016, JBIC Journal of Biological Inorganic Chemistry.

Structure and reactions of an eight-coordinate Mn(II) complex: [Mn(TMPA)2](ClO4)2 (TMPA=tris[(2-pyridyl)methyl]amine)

K. Karlin, A. Farooq, Shun-Shun Liu, 1993 .

A new trinuclear copper complex and its reactions with plasmid DNA

K. Karlin, N. N. Murthy, S. Frey, 1996 .

A dinuclear zinc hydroxide complex which traps atmospheric carbon dioxide: formation of a tri-zinc complex with a triply bridging carbonate group

K. Karlin, N. N. Murthy, 1993 .

Copper(I)/Dioxygen Reactivity of Mononuclear Complexes with Pyridyl and Quinolyl Tripodal Tetradentate Ligands: Reversible Formation of Cu:O2 = 1:1 and 2:1 Adducts

K. Karlin, J. Zubieta, Qin Chen, 1994 .

Copper(I) complexes, copper(I)/O(2) reactivity, and copper(II) complex adducts, with a series of tetradentate tripyridylalkylamine tripodal ligands.

K. Karlin, J. Zubieta, F. Thaler, 2001, Inorganic chemistry.

One is lonely and three is a crowd: two coppers are for methane oxidation.

K. Karlin, Richard A. Himes, Kevin Barnese, 2010, Angewandte Chemie.

Nitric Oxide in Biological Denitrification: Fe/Cu Metalloenzyme and Metal Complex NOx Redox Chemistry

K. Karlin, S. Vries, P. Moënne‐Loccoz, 2002 .

Nitric oxide in biological denitrification: Fe/Cu metalloenzyme and metal complex NO(x) redox chemistry.

K. Karlin, S. de Vries, I. Schröder, 2002, Chemical reviews.

Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry.

K. Karlin, Amy A Sarjeant, E. Solomon, 2015, Journal of the American Chemical Society.

Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligand.

K. Karlin, M. Kubo, Kyung‐Bin Cho, 2011, Dalton transactions.

Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity.

K. Hodgson, K. Karlin, Amy A Sarjeant, 2010, Inorganic chemistry.

Heme-copper/dioxygen adduct formation, properties, and reactivity.

K. Karlin, E. Chufán, S. Puiu, 2007, Accounts of chemical research.

Kinetics and Thermodynamics of Copper(I)/Dioxygen Interaction

K. Karlin, A. Zuberbühler, S. Kaderli, 1997 .

A Peroxynitrite Dicopper Complex: Formation via Cu-NO and Cu-O2 Intermediates and Reactivity via O-O Cleavage Chemistry.

Ryan L. Lehane, K. Karlin, Eunsuk Kim, 2016, Journal of the American Chemical Society.

A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex-The Product of the Reaction of Nitrogen Monoxide (·NO(g)) with a Ferric-Superoxide Species.

K. Hodgson, K. Karlin, B. Hedman, 2017, Journal of the American Chemical Society.

Copper(I)/NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO(g) Disproportionation.

K. Karlin, M. Siegler, G. Wijeratne, 2017, Journal of the American Chemical Society.

Reactions of a heme-superoxo complex toward a cuprous chelate and •NO(g): CcO and NOD chemistry.

K. Karlin, Savita K. Sharma, Patrick J. Rogler, 2015, Journal of porphyrins and phthalocyanines.

Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction.

K. Karlin, Sunghee Kim, M. Siegler, 2014, Chemical communications.

Heme/O2/*NO nitric oxide dioxygenase (NOD) reactivity: phenolic nitration via a putative heme-peroxynitrite intermediate.

K. Karlin, Amy A Sarjeant, Dong-Heon Lee, 2009, Journal of the American Chemical Society.

L-edge X-ray absorption spectroscopy and DFT calculations on Cu2O2 species: direct electrophilic aromatic attack by side-on peroxo bridged dicopper(II) complexes.

K. Hodgson, K. Karlin, T. D. Stack, 2013, Journal of the American Chemical Society.

Improvement of durability of an organic photocatalyst in p-xylene oxygenation by addition of a Cu(II) complex.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2012, Physical Chemistry, Chemical Physics - PCCP.

A selective stepwise heme oxygenase model system: an iron(IV)-oxo porphyrin π-cation radical leads to a verdoheme-type compound via an isoporphyrin intermediate.

K. Karlin, I. Garcia-Bosch, Savita K. Sharma, 2013, Journal of the American Chemical Society.

Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes.

K. Karlin, S. Fukuzumi, 2013, Coordination chemistry reviews.

Concluding remarks: discussion on natural and artificial enzymes including synthetic models.

K. Karlin, Bohee Kim, P. K. Hota, 2022, Faraday discussions.

Tuning the Geometric and Electronic Structure of Synthetic High-Valent Heme Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial Ligands.

K. Hodgson, K. Karlin, B. Hedman, 2019, Journal of the American Chemical Society.

Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site.

K. Karlin, Heather R. Lucas, H. Lucas, 2009, Metal ions in life sciences.

Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2O2 Core with Unexpected Structure and Reactivity.

K. Karlin, E. Solomon, W. Nam, 2016, Chemistry.

An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion.

K. Karlin, W. Nam, Atsutoshi Yokoyama, 2014, Chemical communications.

Bioinorganic chemistry: Redox control of oxoiron(IV).

K. Karlin, 2010, Nature chemistry.

Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity.

K. Karlin, E. Solomon, Yuqi Li, 2011, Inorganic chemistry.

Dimethylanilinic N-Oxides and Their Oxygen Surrogacy Role in the Formation of a Putative High-Valent Copper-Oxygen Species.

K. Karlin, Daniel E. Diaz, Mayukh Bhadra, 2019, Inorganic chemistry.

Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases.

K. Karlin, D. Maiti, Amy A. Narducci Sarjeant, 2008, Inorganic chemistry.

Changing selectivity of DNA oxidation from deoxyribose to Guanine by ligand design and a new binuclear copper complex.

K. Karlin, S. Rokita, Lei Li, 2005, Journal of the American Chemical Society.

Targeted strand scission of DNA substrates by a tricopper(II) coordination complex.

K. Karlin, S. Rokita, K. Humphreys, 2002, Journal of the American Chemical Society.

Efficient and specific strand scission of DNA by a dinuclear copper complex: comparative reactivity of complexes with linked tris(2-pyridylmethyl)amine moieties.

K. Karlin, S. Rokita, K. Humphreys, 2002, Journal of the American Chemical Society.

Recognition and strand scission at junctions between single- and double-stranded DNA by a trinuclear copper complex.

K. Karlin, S. Rokita, K. Humphreys, 2001, Journal of the American Chemical Society.

Mechanistic Insights into the Oxidation of Substituted Phenols via Hydrogen Atom Abstraction by a Cupric–Superoxo Complex

K. Karlin, K. Ohkubo, S. Fukuzumi, 2014, Journal of the American Chemical Society.

Generation and characterization of [(P)M-(X)-Co(TMPA)]n+ assemblies; P = Porphyrinate, M = FeIII and CoIII, X = O2-, OH-, O2(2-), and TMPA = tris(2-pyridylmethyl)amine.

K. Karlin, C. Incarvito, A. Rheingold, 2007, Inorganic chemistry.

Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation.

K. Hodgson, K. Karlin, B. Hedman, 2006, Inorganic chemistry.

Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects.

K. Karlin, E. Solomon, Amy A. Narducci Sarjeant, 2006, Inorganic chemistry.

Synthetic models for heme-copper oxidases.

K. Karlin, Eunsuk Kim, E. Chufán, 2004, Chemical reviews.

Kinetic, thermodynamic, and spectral characterization of the primary copper-oxygen (Cu-O2) adduct in a reversibly formed and structurally characterized peroxo-dicopper(II) complex

K. Karlin, A. D. Zuberbuehler, S. Kaderli, 1991 .

Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry.

K. Karlin, E. Solomon, Andrew W. Schaefer, 2017, Journal of the American Chemical Society.

Oxidant types in copper–dioxygen chemistry: the ligand coordination defines the Cun-O2 structure and subsequent reactivity

K. Karlin, Lanying Q. Hatcher, 2004, JBIC Journal of Biological Inorganic Chemistry.

Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates.

K. Karlin, E. Solomon, D. A. Quist, 2019, Angewandte Chemie.

Recognition of guanines at a double helix-coil junction in DNA by a trinuclear copper complex.

K. Karlin, S. Rokita, S. Thyagarajan, 2005, Chemical communications.

Oxidative strand scission of nucleic acids by a multinuclear copper(II) complex

K. Karlin, S. Rokita, K. Humphreys, 2002, JBIC Journal of Biological Inorganic Chemistry.

A mononuclear nonheme {FeNO}6 complex: synthesis and structural and spectroscopic characterization

K. Hodgson, K. Karlin, B. Hedman, 2018, Chemical science.

Dioxygen reactivity of new bispidine-copper complexes.

K. Karlin, P. Comba, S. Pandian, 2012, Inorganic chemistry.

Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) Release.

K. Karlin, M. Siegler, G. Wijeratne, 2019, Journal of the American Chemical Society.

Synthesis and Characterization of New Trinuclear Copper Complexes.

K. Karlin, A. Rheingold, R. Ghiladi, 2012, Inorganica chimica acta.

Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes.

K. Karlin, Jun Wang, Amy A Sarjeant, 2010, Inorganic chemistry.

Heme-copper assembly mediated reductive coupling of nitrogen monoxide (*NO).

K. Karlin, Jun Wang, Amy A Sarjeant, 2009, Journal of the American Chemical Society.

Reactivity studies on Fe(III)-(O2(2-))-Cu(II) compounds: influence of the ligand architecture and copper ligand denticity.

K. Karlin, Biplab Mondal, Eunsuk Kim, 2007, Inorganic chemistry.

Nitric Oxide Reductase from Paracoccus denitrificans Contains an Oxo-Bridged Heme/Non-Heme Diiron Center

K. Karlin, S. Vries, R. Ghiladi, 2000 .

Formation and Characterization of a High-Spin Heme-Copper Dioxygen (Peroxo) Complex

Dong Heon Lee, K. Karlin, R. Cotter, 1999 .

Functional modeling of copper nitrite reductases: reactions of NO2- or nitric oxide with copper(I) complexes

K. Karlin, P. Paul, 1991 .

Isolation and x-ray structure of a dinuclear copper-nitrosyl complex

K. Karlin, J. Zubieta, A. Farooq, 1990 .

Crystal structure and electron spin echo envelope modulation study of [Cu(II)(TEPA)(NO2)]PF6 (TEPA = tris[2-(2-pyridyl)ethyl]amine): a model for the purported structure of the nitrite derivative of hemocyanin

K. Karlin, L. Bubacco, J. Peisach, 1993 .

Chemistry and structural studies on the dioxygen-binding copper-1,2-dimethylimidazole system

K. Karlin, R. Strange, I. Sanyal, 1993 .

Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O2 and NO and Mechanistic Insights into Metal Mediated Peroxynitrite Decomposition.

K. Karlin, Jeffrey J. Liu, M. Siegler, 2019, Angewandte Chemie.

Elaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generation.

K. Karlin, Jung Yoon Lee, J. Y. Lee, 2015, Current opinion in chemical biology.

Tetragonal vs. trigonal coordination in copper(II) complexes with tripod ligands: structures and properties of [Cu(C21H24N4)Cl]PF6 and [Cu(C18H18N4)Cl]PF6

K. Karlin, J. Zubieta, J. Hutchinson, 1982 .

Heme/non-heme diiron(II) complexes and O2, CO, and NO adducts as reduced and substrate-bound models for the active site of bacterial nitric oxide reductase.

K. Karlin, P. Moënne‐Loccoz, I. Wasser, 2005, Journal of the American Chemical Society.

Ligand Identity-Induced Generation of Enhanced Oxidative Hydrogen Atom Transfer Reactivity for a Cu II2 (O 2•− ) Complex Driven by Formation of a Cu II2 ( − OOH) Compound with a Strong O–H Bond

K. Karlin, D. A. Quist, Andrew W. Schaefer, 2019 .

Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes.

K. Karlin, Pankaj Kumar, Yong‐Min Lee, 2016, Angewandte Chemie.

Factors That Control the Reactivity of Cobalt(III)-Nitrosyl Complexes in Nitric Oxide Transfer and Dioxygenation Reactions: A Combined Experimental and Theoretical Investigation.

K. Karlin, Pankaj Kumar, J. Yao, 2016, Journal of the American Chemical Society.

Reactions of Co(III)-nitrosyl complexes with superoxide and their mechanistic insights.

K. Karlin, Pankaj Kumar, Yong‐Min Lee, 2015, Journal of the American Chemical Society.

Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes.

K. Karlin, Kyung‐Bin Cho, W. Nam, 2013, Journal of the American Chemical Society.

Bioinspired heme, heme/nonheme diiron, heme/copper, and inorganic NOx chemistry: *NO((g)) oxidation, peroxynitrite-metal chemistry, and *NO((g)) reductive coupling.

K. Karlin, Jun Wang, Mark P. Schopfer, 2010, Inorganic chemistry.

Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a "Bridging Peroxo" Intermediate Involved in Facile 4e(-)/4H(+) O2-Reduction.

K. Karlin, A. Dey, S. Chatterjee, 2015, Journal of the American Chemical Society.

Copper-oxygen chemistry

K. Karlin, 伊東忍, 2011 .

Influence of intramolecular secondary sphere hydrogen-bonding interactions on cytochrome c oxidase inspired low-spin heme–peroxo–copper complexes

K. Karlin, E. Solomon, D. A. Quist, 2019, Chemical science.

Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex.

K. Karlin, Amy A Sarjeant, E. Solomon, 2009, Journal of the American Chemical Society.

Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO).

K. Karlin, Richard A. Himes, 2009, Current opinion in chemical biology.

A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity.

K. Hodgson, K. Karlin, B. Hedman, 2021, Journal of the American Chemical Society.

Phosphate ester coordination to dicopper(II) compounds; X-ray structure of a bis(4-nitrophenyl)phosphato bridged dicopper(II) complex

K. Karlin, J. Zubieta, M. Mahroof-Tahir, 1993 .

Vibrational, electronic, and resonance Raman spectral studies of [Cu2(YXL-O-)O2]+, a copper(II) peroxide model complex of oxyhemocyanin

K. Karlin, E. Solomon, R. Cruse, 1987 .

Binding and Activation of Molecular Oxygen by Copper Complexes

K. Karlin, Y. Gultneh, 1988 .

Laser-Induced Dynamics of Peroxodicopper(II) Complexes Vary with the Ligand Architecture. One-Photon Two-Electron O2 Ejection and Formation of Mixed-Valent Cu(I)Cu(II)-Superoxide Intermediates.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2015, Journal of the American Chemical Society.

Copper-mediated hydroxylation of an arene: kinetics and mechanism of the reaction of a dicopper(II) m-xylyl-containing complex with H2O2 to yield a phenoxodicopper(II) complex

K. Karlin, C. Meyer, A. D. Zuberbuehler, 1988 .

Heme/copper assembly mediated nitrite and nitric oxide interconversion.

K. Karlin, M. Siegler, S. Hematian, 2012, Journal of the American Chemical Society.

Novel molecular receptors capable of formingCu2–O2 complexes. Effect of preorganization onO2 binding

M. C. Feiters, K. Karlin, R. Nolte, 1997 .

Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent.

K. Karlin, Sunghee Kim, N. Drichko, 2012, Inorganic chemistry.

Aryl hydroxylation from a mononuclear copper-hydroperoxo species.

K. Karlin, Amy A Sarjeant, D. Maiti, 2007, Journal of the American Chemical Society.

A μ‐η2:η2‐Disulfide Dicopper(II) Complex from Reaction of S8 with a Copper(I) Precursor: Reactivity of the Bound Disulfur Moiety

K. Karlin, L. Zakharov, J. Porco, 2006 .

Dicopper peroxo complexes: low temperature stopped-flow reaction kinetics of [(BQPA)CuI]+ and [(Me2-TMPA)CuI]+.

K. Karlin, M. Suzuki, A. Zuberbühler, 2004, Micron.

An iron-peroxo porphyrin complex: new synthesis and reactivity toward a Cu(II) complex giving a heme-peroxo-copper adduct.

K. Karlin, E. Chufán, 2003, Journal of the American Chemical Society.

Formation, characterization, and reactivity of bis(mu-oxo)dinickel(III) complexes supported by a series of bis[2-(2-pyridyl)ethyl]amine ligands.

K. Karlin, S. Fukuzumi, S. Itoh, 2001, Journal of the American Chemical Society.

Dioxygen reactivity of mononuclear heme and copper components yielding a high-spin heme-peroxo-cu complex.

K. Karlin, C. Krebs, R. Cotter, 2001, Journal of the American Chemical Society.

Spectroscopic and theoretical studies of an end-on peroxide-bridged coupled binuclear copper(II) model complex of relevance to the active sites in hemocyanin and tyrosinase

K. Karlin, E. Solomon, Z. Tyeklár, 1991 .

Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity.

K. Karlin, M. Kubo, W. Nam, 2012, Journal of the American Chemical Society.

Kinetic and thermodynamic parameters of copper-dioxygen interaction with different oxygen binding modes

K. Karlin, W. Tolman, A. Zuberbühler, 1997 .

Copper dioxygen complexes stable at ambient temperature:optimization of ligand design and solvent

K. Karlin, A. Zuberbühler, Dong-Heon Lee, 1997 .

Reversible O2 Binding to a Dinuclear Copper(I) Complex with Linked Tris(2-pyridylmethyl)amine Units: Kinetic-Thermodynamic Comparisons with Mononuclear Analogs

K. Karlin, A. D. Zuberbuehler, Dong-Heon Lee, 1995 .

Isocyanides as Ligand-Directed Indicators of Cu(I) Coordination in Copper Proteins. Probing the Inequivalence of the Cu(I) Centers in Reduced Dopamine-.beta.-monooxygenase

K. Karlin, B. Reedy, N. N. Murthy, 1995 .

Copper(I) Complexes with Pyridyl- and Imidazoyl-Containing Tripodal Tetradentate Ligands and Their Reactions with Dioxygen

K. Karlin, N. N. Murthy, Z. Tyeklár, 1994 .

Reversible reaction of O2 (and CO) with a copper(I) complex. X-ray structures of relevant mononuclear Cu(I) precursor adducts and the trans-(μ-1,2-peroxo)dicopper(II) product

K. Karlin, J. Zubieta, Z. Tyeklár, 1993 .

Dioxygen-copper reactivity. Reversible binding of O2 and CO to a phenoxo-bridged dicopper(I) complex

K. Karlin, J. Zubieta, A. Farooq, 1987 .

Tuning copper-dioxygen reactivity and exogenous substrate oxidations via alterations in ligand electronics.

K. Karlin, Hong Liang, J. Shearer, 2003, Journal of the American Chemical Society.

Reversible carbon monoxide photodissociation from Cu(I) coordination compounds.

K. Karlin, D. W. Thompson, D. V. Scaltrito, 2001, Inorganic chemistry.

Observation of a Cu(II)(2) (μ-1,2-peroxo)/Cu(III)(2) (μ-oxo)(2) equilibrium and its implications for copper-dioxygen reactivity.

K. Karlin, E. Solomon, A. Zuberbühler, 2014, Angewandte Chemie.

A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity.

K. Karlin, E. Solomon, Sunghee Kim, 2015, Journal of the American Chemical Society.

Tuning of the Copper–Thioether Bond in Tetradentate N3S(thioether) Ligands; O–O Bond Reductive Cleavage via a [CuII2(μ-1,2-peroxo)]2+/[CuIII2(μ-oxo)2]2+ Equilibrium

K. Karlin, E. Solomon, Sunghee Kim, 2014, Journal of the American Chemical Society.

Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex.

K. Karlin, E. Solomon, Yunho Lee, 2010, Chemical communications.

Cupric superoxo-mediated intermolecular C-H activation chemistry.

K. Karlin, S. Fukuzumi, E. Solomon, 2011, Journal of the American Chemical Society.

A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols.

K. Karlin, E. Solomon, D. Maiti, 2007, Journal of the American Chemical Society.

Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent variations.

K. Karlin, M. Costas, C. X. Zhang, 2003, Inorganic chemistry.

XAS Structural Comparisons of Reversibly Interconvertible Oxo- and Hydroxo-Bridged Heme-Copper Oxidase Model Compounds

K. Karlin, M. Wikström, N. Blackburn, 1996 .

Synthesis and X-ray absorption spectroscopy structural studies of Cu(I) complexes of histidylhistidine peptides: the predominance of linear 2-coordinate geometry.

K. Karlin, Richard A. Himes, N. Blackburn, 2007, Journal of the American Chemical Society.

Formation of a Copper-Dioxygen Complex (cu2-o2) Using Simple Imidazole Ligands

K. Karlin, R. Strange, I. Sanyal, 1991 .

Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity

K. Karlin, M. Siegler, S. Hematian, 2014, JBIC Journal of Biological Inorganic Chemistry.

A new copper-oxo player in methane oxidation

K. Karlin, Richard A. Himes, 2009, Proceedings of the National Academy of Sciences.

A cytochrome c oxidase reactivity model: generation of a peroxo-bridged iron/copper dinuclear complex

K. Karlin, M. S. Nasir, N. Ravi, 1992 .

Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex.

K. Karlin, L. Zakharov, E. Solomon, 2005, Journal of the American Chemical Society.

Photoinduced carbon monoxide migration in a synthetic heme-copper complex.

Andrew D. Cohen, K. Karlin, G. Meyer, 2005, Journal of the American Chemical Society.

Efficient photodissociation of O2 from synthetic heme and heme/M (M = Fe, Cu) complexes.

K. Karlin, G. Meyer, P. Hoertz, 2004, Journal of the American Chemical Society.

Copper-dioxygen complexes and their roles in biomimetic oxidation reactions

K. Karlin, Hong Liang, C. X. Zhang, 2003 .

3.07 – Copper Enzymes

K. Karlin, Sunghee Kim, R. L. Peterson, 2013 .

Copper Enzymes/Models

K. Karlin, Dong-Heon Lee, Ga Young Park, 2010 .

Peroxo-, Oxo-, and Hydroxo-Bridged Dicopper Complexes: Observation of Exogenous Hydrocarbon Substrate Oxidation

E. Pidcock, K. Karlin, E. Solomon, 1998 .

Catecholate coordination to copper: structural characterization of a tetrachloro-o-catecholate-bridged dicopper(II) complex as a model for intermediates in copper-catalyzed oxidation of catechols

K. Karlin, J. Zubieta, Y. Gultneh, 1985 .

Bioinorganic chemical modeling of dioxygen-activating copper proteins

K. Karlin, Y. Gultneh, 1985 .

Substrate oxidation by copper-dioxygen adducts: mechanistic considerations.

K. Karlin, L. Zakharov, J. Shearer, 2005, Journal of the American Chemical Society.

New thermally stable hydroperoxo- and peroxo-copper complexes

K. Karlin, J. Zubieta, M. Mahroof-Tahir, 1992 .

Unsymmetrical dicopper complexes. Direct observation of reversible O2 binding in a copper monooxygenase model system

K. Karlin, J. Zubieta, M. S. Nasir, 1991 .

Synthesis and structure of a CO-containing phenoxo-bridged dicopper(I) complex

K. Karlin, J. Zubieta, A. Farooq, 1988 .

NMR and Electronic Relaxation in Paramagnetic Dicopper(II) Compounds

K. Karlin, I. Bertini, C. Luchinat, 1997 .

A dinuclear mixed-valence Cu(I)/Cu(II) complex and its reversible reactions with dioxygen: generation of a superoxodicopper(II) species

K. Karlin, M. Mahroof-Tahir, 1992 .

Models for methemocyanin derivatives: Structural and spectroscopic comparisons of related azido-coordinated (N3 -) mono- and dinuclear copper(II) complexes

K. Karlin, J. Zubieta, A. Farooq, 1987 .

Binuclear Copper Complexes Based on the 6,6'-Bis[[bis(2-pyridylmethyl)amino]methyl]-2,2'-bipyridine Ligand.

K. Karlin, Dong-Heon Lee, N. N. Murthy, 1997, Inorganic chemistry.

Targeted guanine oxidation by a dinuclear copper(II) complex at single stranded/double stranded DNA junctions.

K. Karlin, S. Rokita, L. Zakharov, 2006, Inorganic chemistry.

Hydrolysis of Unactivated Esters and Acetonitrile Hydration by a Hydroxo-Dicopper(II) Complex.

K. Karlin, S. Weintraub, L. Thompson, 1997, Inorganic chemistry.

Dioxygen-copper reactivity. Comparisons of the reactions of electrophiles and other reagents with three classes of peroxo-dicopper(II), {Cu2-O2}n+, species

K. Karlin, J. Zubieta, A. Farooq, 1989 .

Peroxide coordination to a dicopper(II) center. Dioxygen binding to a structurally characterized phenoxide-bridged binuclear copper(I) complex

K. Karlin, J. Zubieta, J. C. Hayes, 1984 .

Studies on a model copper mono-oxygenase system: peroxo–CuII binuclear intermediates in the hydroxylation of an aromatic ring

K. Karlin, J. Zubieta, J. C. Hayes, 1984 .

Copper-mediated hydroxylation of an arene ― model system for the action of copper monooxygenases: structures of a binuclear Cu(I) complex and its oxygenated product

K. Karlin, J. Zubieta, J. Hutchinson, 1984 .

Activation of O2 by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; X-ray crystal structure of [Cu2{OC6H3[CH2N(CH2CH2py)2]2-2,6}(OMe)](py = 2-pyridyl)

K. Karlin, J. Zubieta, P. L. Dahlstrom, 1981 .

Redox behavior of blue copper model complexes. Redox potentials and electron-transfer kinetics of some copper(II)-copper(I) complexes with nitrogen and thioether donors

K. Karlin, J. K. Yandell, 1984 .

REDOX COMPARISONS OF PSEUDOTETRAHEDRAL COPPER(I) COMPLEXES CONTAINING TRIPOD LIGANDS

K. Karlin, S. Sherman, 1982 .

Rates of electron transfer and redox potentials of some copper(II) thioether complexes

K. Karlin, M. Augustin, J. K. Yandell, 1981 .

Models for met-hemocyanin derivatives: structural and spectroscopic comparisons of analogous phenolate and X (X = OH-, OMe-, N3-, Cl-, OAc-, OBz-) doubly bridged dinuclear copper(II) complexes

K. Karlin, J. Zubieta, A. Farooq, 1987 .

Biological & inorganic copper chemistry : proceedings of the Second Conference on Copper Coordination Chemistry held at the State University of New York at Albany, July 23-27, 1984

K. Karlin, J. Zubieta, 1986 .

Synthesis and characterization of a novel dicopper(I) complex of a thiaether containing meta-xylyl binucleating ligand

K. Karlin, J. Zubieta, J. Hutchinson, 1983 .

Structural comparison of CuI and CuII complexes displaying analogous N2S2 co-ordination; X-ray analysis of tetraco-ordinate [Cu(pma)]BPh4 and pentaco-ordinate [Cu(pma)SO4][pma2-pyridylmethylbis-(2-ethylthioethyl)amine]

K. Karlin, J. Zubieta, J. Hyde, 1980 .

The structure of the copper(II) analogue of a pseudotetrahedral copper(I) thioether complex

K. Karlin, J. Zubieta, P. L. Dahlstrom, 1981 .

Distorted tetrahedral complexes of copper(I) and copper(II) displaying N2S2 co-ordination. X-Ray crystal structure of [2-(2-pyridyl)ethyl]bis[2-(ethylthio)ethyl]aminecopper(I) tetraphenylborate

K. Karlin, J. Zubieta, P. L. Dahlstrom, 1979 .

Copper coordination chemistry : biochemical & inorganic perspectives

K. Karlin, J. Zubieta, 1983 .

Model for the possible 'endogenous' bridge in oxy-hemocyanin: a di-μ-(OR)2-bridged dicopper(II) complex (R = H, alkyl) with low-energy charge-transfer absorption

K. Karlin, J. Zubieta, A. Farooq, 1990 .

Ligand Identity Induced Generation of Enhanced Oxidative HAT Reactivity for a CuII2(O2•¬-) Complex Driven by Formation of a CuII2(-OOH) Compound with a Strong O-H Bond.

K. Karlin, E. Solomon, D. A. Quist, 2019, Journal of the American Chemical Society.

Biomimetic Binding and Activation of Dioxygen with Copper Complexes

K. Karlin, Z. Tyeklár, 1991 .

Dioxygen-copper reactivity: intermediacy of a peroxo-dicopper(II) (dioxygen-copper) complex in the hydroxylation reaction of a model mono-oxygenase system

K. Karlin, M. Haka, Y. Gultneh, 1986 .

Formation, Structure, and Reactivity of Copper Dioxygen Complexes

K. Karlin, A. Zuberbühler, 1999 .

Dioxygen Reactivity in Copper Proteins and Complexes

K. Karlin, S. Fox, 1995 .

Catecholate Coordination to Copper: Structural Characterization of a Tetrachloro- o-catecholate-Bridged Dicopper(II) Complex as a Model for Intermediates in Copper-Catalyzed Oxidation of Catechols.

K. Karlin, J. Zubieta, Y. Gultneh, 1986 .

Synthesis and x-ray structural characterization of Cu(I) and Cu(II) derivatives of a new symmetric tripodal ligand N(CH2CH2-py)3, (py = 2-pyridyl)

K. Karlin, J. Zubieta, J. Hutchinson, 1982 .

SYNTHESIS AND STRUCTURE OF A NOVEL DICOPPER(I) COMPLEX OF A NEW BINUCLEATING LIGAND

K. Karlin, J. Zubieta, J. Hyde, 1982 .

X-ray Structure Analysis of a Dicopper Complex of a New Binucleating Ligand Containing a para-Xylyl Connecting Group; Large Cu…Cu Separation in [(CuCl2C18H20N3)2]·2H2O

R. A. Simon, K. Karlin, J. Zubieta, 1981 .

Dioxygen—Copper Reactivity: Hydroxylation-induced Methyl Migration in a Copper Monooxygenase Model System

K. Karlin, J. Zubieta, R. R. Jacobson, 1987 .

Metalloenzymes, structural motifs, and inorganic models.

K. Karlin, 1993, Science.

Spectroscopic studies of the charge transfer and vibrational features of binuclear copper(II) azide complexes: comparison to the coupled binuclear copper active site in met azide hemocyanin and tyrosinase

K. Karlin, E. Solomon, C. Reed, 1989 .

Copper-dioxygen chemistry: a bioinorganic challenge

K. Karlin, Z. Tyeklár, 1989 .

Reactions of dioxygen (O2) with mononuclear copper(I) complexes: temperature-dependent formation of peroxo- or oxo- (and dihydroxo-) bridged dicopper(II) complexes

K. Karlin, J. Zubieta, A. Farooq, 1992 .

Vibrational spectroscopic studies of a hydroxo-bridged dinuclear copper complex, a potential model for multicopper proteins

K. Karlin, A. Farooq, J. Sanders-Loehr, 1992 .

Models for Methemocyanin Derivatives: Structural and Spectroscopic Comparisons of Related Azido‐Coordinated (N‐ 3) Mono‐ and Dinuclear Copper(II) Complexes.

K. Karlin, J. Zubieta, A. Farooq, 1987 .

Oxygen binding and activation by the complexes of PY2- and TPA-appended diphenylglycoluril receptors with copper and other metals.

M. C. Feiters, K. Karlin, B. Feringa, 2005, Dalton transactions.

Formation and Interconversion of End-on and Side-on μ-Peroxo−Dicopper(II) Complexes

K. Karlin, A. Zuberbühler, B. Jung, 1996 .

A Cu2-O2 Complex. Crystal Structure and Characterization of a Reversible Dioxygen Binding System

Jon Zubieta, Kenneth D. Karlin, Amjad Farooq, 1988 .

Synthesis and characterization of copper(II) complexes of a tetradentate N3O ligand: Mononuclear analogs for phenolate-bridged dinuclear complexes

K. Karlin, B. I. Cohen, 1985 .

Fluoride as a terminal and bridging ligand for copper: isolation and x-ray crystallographic characterization of copper monomeric and dimeric complexes [CuII(TMPA)F]nn+ (n = 1 or 2; TMPA = tris[(2-pyridyl)methyl]amine)

K. Karlin, J. Zubieta, Z. Tyeklár, 1991 .

Dioxygen–copper reactivity: a hydroperoxo–dicopper(II) complex

K. Karlin, Y. Gultneh, R. Cruse, 1987 .

Reversible Dioxygen Binding and Aromatic Hydroxylation in O2-Reactions with Substituted Xylyl Dinuclear Copper(I) Complexes: Syntheses and Low-Temperature Kinetic/Thermodynamic and Spectroscopic Investigations of a Copper Monooxygenase Model System

K. Karlin, A. D. Zuberbuehler, S. Kaderli, 1994 .

A dicopper(I) complex and its oxygenation chemistry using a dinucleating ligand with a pendant alkene group

K. Karlin, I. Sanyal, N. N. Murthy, 1993 .

Mechanism of aromatic hydroxylation in a copper monooxygenase model system. 1,2-methyl migrations and the NIH shift in copper chemistry

K. Karlin, M. S. Nasir, B. I. Cohen, 1992 .

Dioxygen-copper reactivity and functional modeling of hemocyanins. Reversible binding of O2 and CO to dicopper(I) complexes [CuI2(L)]2+ (L = dinucleating ligand) and the structure of a bis(carbonyl) adduct, [CuI2(L)(CO)2]2+

K. Karlin, J. Zubieta, A. Farooq, 1992 .

Reactivity patterns and comparisons in three classes of synthetic copper-dioxygen {Cu2-O2} complexes: implication for structure and biological relevance

K. Karlin, Z. Tyeklár, P. Paul, 1991 .

Dioxygen−copper reactivity: generation, characterization, and reactivity of a hydroperoxo−dicopper(II) complex

K. Karlin, J. Zubieta, R. Strange, 1988 .

Kinetic and thermodynamic studies on the reaction of oxygen with two dinuclear copper(I) complexes

K. Karlin, A. D. Zuberbuehler, S. Kaderli, 1988 .

Dioxygen-copper reactivity ― models for hemocyanin: reversible O2 and CO binding to structurally characterized dicopper(I) complexes containing hydrocarbon-linked bis[2-(2-pyridyl)ethyl]amine units

K. Karlin, J. Zubieta, A. Farooq, 1988 .

Functional Models for Hemocyanin and Copper Monooxygenases

K. Karlin, Z. Tyeklár, 1993 .

Mononuclear Copper(II)-Acylperoxo Complexes

K. Karlin, P. Ghosh, I. Sanyal, 1995 .

Chemistry of Pentacoordinate [LCuII-Cl]+ Complexes with Quinolyl Containing Tripodal Tetradentate Ligands L

K. Karlin, N. N. Murthy, Ning Wei, 1994 .

Kinetic Preference without Thermodynamic Stabilization in the Intra- vs Intermolecular Formation of Copper-Dioxygen Complexes

K. Karlin, A. D. Zuberbuehler, Dong-Heon Lee, 1994 .

X-ray Structure and Physical Properties of the Oxo-Bridged Complex [(F8-TPP)Fe-O-Cu(TMPA)]+, F8-TPP = Tetrakis(2,6-difluorophenyl)porphyrinate(2-), TMPA = Tris(2-pyridylmethyl)amine: Modeling the Cytochrome c Oxidase Fe-Cu Heterodinuclear Active Site

K. Karlin, B. Huynh, N. N. Murthy, 1994 .

Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes.

K. Karlin, Hong Liang, E. Solomon, 2002, Journal of the American Chemical Society.

Synthesis, structure, and characterization of a phenolate-bridged dimanganese(II) complex of a dinucleating phenol ligand

K. Karlin, J. Zubieta, A. Farooq, 1992 .

Model complexes for ligand probes of met-hemocyanin and met-tyrosinase derivatives. Structure of a novel 1,1-azido bridged binuclear copper(II) complex

K. Karlin, J. Zubieta, J. Hutchinson, 1983 .

Unprecedented direct cupric-superoxo conversion to a bis-μ-oxo dicopper(III) complex and resulting oxidative activity.

K. Karlin, D. A. Quist, Melanie A. Ehudin, 2019, Inorganica chimica acta.

Reversible dioxygen binding and arene hydroxylation reactions: Kinetic and thermodynamic studies involving ligand electronic and structural variations.

K. Karlin, C. X. Zhang, A. Rheingold, 2012, Inorganica chimica acta.

Geometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage.

K. Hodgson, K. Karlin, B. Hedman, 2012, Journal of the American Chemical Society.

Ligand Influences in Copper-Dioxygen Complex-Formation and Substrate Oxidations

K. Karlin, Lanying Q. Hatcher, 2006 .

Activation of dioxygen by copper metalloproteins and insights from model complexes

K. Karlin, D. A. Quist, Jeffrey J. Liu, 2016, JBIC Journal of Biological Inorganic Chemistry.

A molecular pinwheel multicopper(I) cluster, [(LS-)6CuI13(S2-)2]3+ with μ4-sulfido, μ3-thiolato and nitrogen ligands

K. Karlin, Amy A Sarjeant, Yunho Lee, 2006 .

Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2015, Journal of the American Chemical Society.

Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2013, Journal of the American Chemical Society.

Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complex.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2013, Journal of the American Chemical Society.

Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell.

K. Karlin, S. Fukuzumi, Yusuke Yamada, 2012, Electrochimica acta.

Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2013, Journal of the American Chemical Society.

Intermolecular versus intramolecular electron-/atom- (Cl) transfer in heme-iron and copper pyridylalkylamine complexes

K. Karlin, L. Zakharov, G. Meyer, 2008 .

Oxo-bridged haem/non-haem iron complexes

K. Karlin, N. N. Murthy, C. F. Martens, 1996 .

Dioxygen and nitric oxide reactivity of a reduced heme/non-heme diiron(II) complex [(5L)FeII⋯FeIICl]+. Using a tethered tetraarylporphyrin for the development of an active site reactivity model for bacterial nitric oxide reductase

K. Karlin, R. Cotter, Telvin D. Ju, 2000 .

Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function.

K. Karlin, D. A. Quist, Jeffrey J. Liu, 2018, Chemical reviews.

Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases.

K. Karlin, E. Solomon, Andrew W. Schaefer, 2017, Journal of the American Chemical Society.

Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive L2CuII2(O22-) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity.

K. Karlin, E. Solomon, Ryan E Cowley, 2017, Journal of the American Chemical Society.

Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo Heme-Fe(III)-O-Cu(II)(L) Constructs.

K. Karlin, I. Ivanović‐Burmazović, Maximilian Dürr, 2015, Journal of the American Chemical Society.

Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water.

K. Karlin, S. Fukuzumi, Yong‐Min Lee, 2012, Chemistry.

A peroxynitrite complex of copper: formation from a copper–nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration

K. Karlin, E. Solomon, Dong-Heon Lee, 2009, JBIC Journal of Biological Inorganic Chemistry.

Superoxo, μ-peroxo, and μ-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: Copper ligand influences in cytochrome c oxidase models

K. Karlin, C. Incarvito, A. Rheingold, 2003, Proceedings of the National Academy of Sciences of the United States of America.

Copper-Dioxygen Reactivity Using Dinucleating Ligands with Activated Methylene or Ketone Function

K. Karlin, Dong-Heon Lee, N. N. Murthy, 2007 .

X-ray absorption studies of three-coordinate dicopper(I) complexes and their dioxygen adducts

K. Karlin, R. Strange, A. Farooq, 1988 .

Cytochrome c Oxidase and Models

K. Karlin, Zakaria Halime, 2011 .

Copper-Oxygen Chemistry: Karlin/Copper-Oxygen Chemistry

K. Karlin, S. Itoh, 2011 .

Copper mediated hydroxylation of a modified monooxygenase model system

K. Karlin, J. Zubieta, A. Farooq, 1988 .

Facile amide hydrolysis effected by dinuclear copper complexes

Kenneth D. Karlin, Narasimha N. Murthy, K. Karlin, 1993 .

Dicopper(I) complexes of unsymmetrical binucleating ligands and their dioxygen reactivities.

K. Karlin, M. Mahroof-Tahir, N. N. Murthy, 2001, Inorganic chemistry.

Thiol-copper(I) and disulfide-dicopper(I) complex O2-reactivity leading to sulfonate-copper(II) complex or the formation of a cross-linked thioether-phenol product with phenol addition.

K. Karlin, Amy A Sarjeant, Yunho Lee, 2007, Journal of inorganic biochemistry.

Copper(I) and copper(II) complexes possessing cross-linked imidazole-phenol ligands: structures and dioxygen reactivity.

K. Karlin, L. Zakharov, A. Rheingold, 2003, Journal of the American Chemical Society.

Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach.

K. Karlin, D. A. Quist, Rui Cao, 2017, Chemistry.

Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy.

K. Karlin, S. Fukuzumi, E. Solomon, 2016, Journal of the American Chemical Society.

Copper Peroxide Bioinorganic Chemistry: From Metalloenzymes to Bioinspired Synthetic Systems

K. Karlin, I. Garcia-Bosch, 2014 .

Synthesis and Structure of a CO-Containing Phenoxo-bridged Dicopper(I) Complex.

K. Karlin, J. Zubieta, A. Farooq, 1988 .

EPR of trigonal bipyramidal copper(II) complexes with tripod ligands

K. Karlin, G. Kokoszka, J. Orsini, 1983 .

ESR spectra of new dicopper(II) complexes of novel binucleating ligands

K. Karlin, J. Orsini, R. Cruse, 1982 .

Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms.

K. Karlin, D. A. Quist, Jeffrey J. Liu, 2016, Israel journal of chemistry.

Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2012, Journal of the American Chemical Society.

Resonance raman studies of phenolate-bridged binuclear copper complexes. relevance to hemocyanin and tyrosinase

K. Karlin, L. Que, Glenn C. Vogel, 1984 .

Three-coordinate binuclear copper(I) complex: model compound for the copper sites in deoxyhemocyanin and deoxytyrosinase

K. Karlin, J. Zubieta, J. Hutchinson, 1982 .

Dioxygen-binding kinetics and thermodynamics of a series of dicopper(I) complexes with bis[2-(2-pyridyl)ethyl]amine tridendate chelators forming side-on peroxo-bridged dicopper(II) adducts.

K. Karlin, A. Zuberbühler, R. Dyson, 2000, Inorganic chemistry.

A Study of Solid [{Cu(MePY2)}2O2]2+ Using Resonance Raman and X-ray Absorption Spectroscopies: An Intermediate Cu2O2 Core Structure or a Solid Solution?

K. Hodgson, E. Pidcock, K. Karlin, 1999 .

Reactivity study of a hydroperoxodicopper(II) complex: hydroxylation, dehydrogenation, and ligand cross-link reactions.

K. Karlin, Amy A Sarjeant, Lei Li, 2006, Inorganic chemistry.

Heme-copper/dioxygen adduct formation relevant to cytochrome c oxidase: spectroscopic characterization of [(6L)FeIII-(O22−)-CuII]+

K. Karlin, C. Incarvito, R. Cotter, 2004, JBIC Journal of Biological Inorganic Chemistry.

Reductive Coupling of Nitric Oxide by Cu(I): Stepwise Formation of Mono- and Dinitrosyl Species En Route to a Cupric Hyponitrite Intermediate.

K. Karlin, Trokourey Albert, I. Ivanović‐Burmazović, 2023, Journal of the American Chemical Society.

Dioxygen-Copper Reactivity. Comparisons of the Reactions of Electrophiles and Other Reagents with Three Classes of Peroxo-Dicopper(II), (Cu2-O2)n+, Species.

K. Karlin, J. Zubieta, A. Farooq, 1989 .

Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues.

K. Hodgson, K. Karlin, Amy A Sarjeant, 2007, Inorganic chemistry.

Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu(2)((UN-O-)(OOH)](2+).

D. Root, K. Karlin, E. Solomon, 1998, Inorganic chemistry.

Copper(I)/Dioxygen Reactivity with Dinuclear Compounds: Catalytic Oxygenation and Oxo-Transfer to a Ketone.

K. Karlin, Dong-Heon Lee, N. N. Murthy, 1996, Inorganic chemistry.

Pyridine ligand donor substituent effects upon structure, redox properties and O2 reactivity of xylyl dinuclear copper(I) complexes

K. Karlin, J. Zubieta, M. S. Nasir, 1993 .

Copper: Hemocyanin/Tyrosinase Models

K. Karlin, J. Shearer, 2014 .

Dioxygen-activating bio-inorganic model complexes.

K. Karlin, H. Liang, M. Dahan, 1999, Current opinion in chemical biology.

Oxidative dehalogenation during a copper complex mediated hydroxylation reaction

K. Karlin, M. S. Nasir, B. I. Cohen, 1990 .

Synthesis and structure of a mono-chloro bridged copper(II) dimer containing a linear CuII-Cl-CuII bridge

K. Karlin, J. Zubieta, J. Hutchinson, 1984 .

Structure and properties of a monomeric copper(II) complex with a N3 tridentate unit containing 2-thio-1-methylimidazole

K. Karlin, J. Zubieta, J. C. Hayes, 1984 .

End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy.

K. Karlin, B. Hoffman, R. Davydov, 2022, Journal of the American Chemical Society.

Oxidation of (hydroxyethyl)ferrocene by [2-pyridylmethylbis(2-ethylthioethyl)/amine]copper(II)

K. Karlin, R. Holwerda, Maria C. Garcia, 1987 .

Models for Met-Hemocyanin Derivatives: Structural and Spectroscopic Comparisons of Analogous Phenolate and X (X: OH-, OMe-, N- 3, Cl-, OAc-, OBz-) Doubly Bridged Dinuclear Copper(II) Complexes.

K. Karlin, J. Zubieta, A. Farooq, 1987 .

Model complexes for the active sites of reduced and oxidized sites of hemocyanin and tyrosinase. Structures of binuclear Cu(I) and Cu(II) complexes and characterization of a model copper monooxygenase reaction

K. Karlin, J. Zubieta, J. Hutchinson, 1983 .

Copper(II)-hydroperoxo complex induced oxidative N-dealkylation chemistry.

K. Karlin, Amy A Sarjeant, D. Maiti, 2007, Journal of the American Chemical Society.

Solvent Effects on the Conversion of Dicopper(II) μ-η2:η2-Peroxo to Bis-μ-oxo Dicopper(III) Complexes: Direct Probing of the Solvent Interaction

K. Karlin, Hong Liang, E. Solomon, 2004 .

Copper(I) and copper(II) complexes of new chelating pterins

K. Karlin, J. Zubieta, Qin Chen, 1992 .

Computational study of the activated OH state in the catalytic mechanism of cytochrome c oxidase

Vivek Sharma, K. Karlin, M. Wikström, 2013, Proceedings of the National Academy of Sciences.

Hydrogen peroxide and dioxygen activation by dinuclear copper complexes in aqueous solution: hydroxyl radical production initiated by internal electron transfer.

K. Karlin, S. Rokita, N. Blough, 2008, Journal of the American Chemical Society.

Dioxygen-copper reactivity: EXAFS studies of a peroxo-dicopper(II) complex

K. Karlin, R. Strange, N. Blackburn, 1987 .

Models for Copper Proteins: Reversible Binding and Activation of Dioxygen and the Reactivity of Peroxo and Hydroperoxo Dicopper(II) Complexes

K. Karlin, J. Zubieta, A. Farooq, 1988 .

Dioxygen-copper reactivity: x-ray structure and characterization of an (acylperoxo)dicopper complex

K. Karlin, J. Zubieta, P. Ghosh, 1987 .

Dioxygen-Copper Reactivity: Intermediacy of a Peroxo-Dicopper(II) (Dioxygen-Copper) Complex in the Hydroxylation Reaction of a Model Mono-Oxygenase System.

K. Karlin, M. Haka, Y. Gultneh, 1987 .

Dioxygen-copper reactivity. Reversible oxygen and carbon monoxide binding by a new series of binuclear copper(I) complexes

K. Karlin, M. Haka, Y. Gultneh, 1985 .

Copper Ion Complexes with Derivatized Chelating Pterin Ligands

K. Karlin, Dong-Heon Lee, N. N. Murthy, 1997 .

Cu(I)-dioxygen reactivity: structural characterization of a bridged-binuclear Cu(II) complex formed by oxidation of a new binuclear Cu(I) compound

K. Karlin, J. Zubieta, J. Hutchinson, 1984 .

ORBITALLY DEPENDENT EXCHANGE IN TWO SULFUR‐BRIDGED BINUCLEAR IRON(II) COMPLEXES. MAGNETIC EXCHANGE IN TRANSITION METAL COMPLEXES. 11

A. P. Ginsberg, K. Karlin, S. Lippard, 1977 .

Orbitally dependent exchange in two sulfur-bridged binuclear iron(II) complexes. Magnetic exchange in transition metal complexes. 11

A. P. Ginsberg, K. Karlin, S. Lippard, 1976 .

Dioxygen Reactivity Models for Cytochrome C Oxidase: Synthesis and Characterization of Oxo and Hydroxo-Bridged Porphyrin-Iron/Copper Dinuclear Complexes

K. Karlin, B. Huynh, K. Hagen, 1993 .

Dioxygen-Copper Reactivity: Hydroxylation-Induced Methyl Migration in a Copper Monooxygenase Model System.

K. Karlin, J. Zubieta, R. R. Jacobson, 1988 .

Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds.

K. Karlin, Amy A Sarjeant, G. Meyer, 2008, Inorganic chemistry.

Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct.

K. Hodgson, K. Karlin, S. Fukuzumi, 2013, Journal of the American Chemical Society.

Dioxygen–copper reactivity at trinuclear centers: formation of hexanuclear and mixed-valent adducts

K. Karlin, Z. Tyeklár, Qin-fen Gan, 1999 .

Peroxide (O22−) as a bridging ligand for copper(II): strong exchange coupling in complexes derived from copper(I) and dioxygen

K. Karlin, A. Farooq, L. Wilson, 1991 .

Addition of nitrosonium ion to mercaptide-bridged binuclear iron(II) and cobalt(II) complexes

D. L. Lewis, K. Karlin, S. Lippard, 1974 .

Design and synthesis of model systems for oxygen binding and activation in dinuclear copper proteins.

M. C. Feiters, K. Karlin, R. Nolte, 1992 .

Reaction of organic halides with [CuI(TMPA)CH3CN]PF6

K. Karlin, Z. Tyeklár, R. R. Jacobson, 1991 .

Copper(I)-dioxygen reactivity. 2. Reaction of a three-coordinate copper(I) complex with dioxygen, with evidence for a binuclear oxo-copper(II) species: structural characterization of a parallel-planar dihydroxo-bridged dimer

K. Karlin, J. Zubieta, J. C. Hayes, 1984 .

Intramolecular Ligand Hydroxylation: Mechanistic High-Pressure Studies on the Reaction of a Dinuclear Copper(I) Complex with Dioxygen.

K. Karlin, T. Kaden, A. Zuberbühler, 1999, Inorganic chemistry.

Spectroscopic and Theoretical Studies of Oxygenated Dicopper(I) Complexes Containing Hydrocarbon-Linked Bis[2-(2-pyridyl)ethyl]amine Units: Investigation of a Butterfly [Cu2(μ-η2:η2)(O2)]2+ Core

E. Pidcock, K. Karlin, Hong Liang, 1999 .

Copper-dioxygen complexes: Functional models for proteins

K. Karlin, 1997 .

Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation.

Christian Würtele, Jörg Sundermeyer, K. Karlin, 2008, Angewandte Chemie.

Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes.

K. Karlin, Hong Liang, E. Solomon, 2003, Journal of the American Chemical Society.

A bis-acetonitrile two-coordinate copper(I) complex: synthesis and characterization of highly soluble B(C(6)F(5))(4)(-) salts of [Cu(MeCN)(2)](+) and [Cu(MeCN)(4)](+).

K. Karlin, Hong Liang, C. Incarvito, 2002, Inorganic chemistry.

Synthesis and characterization of PY2- and TPA-appended diphenylglycoluril receptors and their bis-CuI complexes

M. C. Feiters, K. Karlin, R. Nolte, 2006 .

Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform.

K. Karlin, C. Incarvito, A. Rheingold, 2004, Inorganic chemistry.

Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent.

K. Karlin, E. Solomon, D. Maiti, 2008, Inorganic chemistry.

Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species.

K. Karlin, E. Solomon, Yunho Lee, 2010, Inorganic chemistry.

Oxo- and hydroxo-bridged (porphyrin)iron(III)-copper(II) species as cytochrome c oxidase models: acid-base interconversions and x-ray structure of the Fe(III)-(O2-)-Cu(II) complex

K. Karlin, B. Huynh, K. Hagen, 1993 .

Kinetic Stability of the Cysteine Adduct with [Tris(2-(2-pyridyl)ethyl)amine]copper(II).

K. Karlin, H. K. Baek, R. Holwerda, 1986 .

EPR OF COPPER(II) COMPLEXES WITH TRIPODAL LIGANDS: DYNAMICAL PROPERTIES

K. Karlin, G. Kokoszka, F. Padula, 1984 .

Inferences from the 1H-NMR Spectroscopic Study of an Antiferromagnetically Coupled Heterobinuclear Fe(III)−(X)−Cu(II) S = 2 Spin System (X = O2-, OH-)

K. Karlin, S. Fox, A. Nanthakumar, 1997 .

A trinuclear copper(I) complex: Reaction with dioxygen and the formation of a hexanuclear copper(II) cluster

K. Karlin, J. Zubieta, A. Farooq, 1990 .

X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding.

K. Hodgson, K. Karlin, W. Tolman, 2008, Journal of the American Chemical Society.

Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry.

K. Karlin, Amy A Sarjeant, E. Solomon, 2007, Journal of the American Chemical Society.

Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues.

K. Karlin, E. Solomon, K. Fujisawa, 2003, Journal of the American Chemical Society.

Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry.

K. Karlin, L. Zakharov, E. Solomon, 2003, Journal of the American Chemical Society.

Celebrating Ed Solomon

K. Karlin, Larry Que, 2016, JBIC Journal of Biological Inorganic Chemistry.

Excitation wavelength dependent O2 release from copper(II)-superoxide compounds: laser flash-photolysis experiments and theoretical studies.

Frank Neese, F. Neese, K. Karlin, 2014, Journal of the American Chemical Society.

Thioether sulfur oxygenation from O2 or H2O2 reactivity of copper complexes with tridentate N2Sthioether ligands.

K. Karlin, L. Zakharov, Amy A Sarjeant, 2006, Inorganic chemistry.

The rate of O2 and CO binding to a copper complex, determined by a "flash-and-trap" technique, exceeds that for hemes.

K. Karlin, G. Meyer, D. V. Scaltrito, 2003, Journal of the American Chemical Society.

Distinguishing rate-limiting electron versus H-atom transfers in Cu2O2-mediated oxidative N-dealkylations: application of inter- versus intramolecular kinetic isotope effects.

K. Karlin, J. Shearer, C. X. Zhang, 2003, Journal of the American Chemical Society.

Structural studies of copper(I) complexes of amyloid-beta peptide fragments: formation of two-coordinate bis(histidine) complexes.

K. Karlin, Richard A. Himes, N. Blackburn, 2008, Angewandte Chemie.

Synthesis and characterization of the pentacoordinate mononitrosyliron complexes Fe(NO)[SCH2CH2N(CH3)(CH2)nN(CH3)CH2CH2S], n = 2,3

D. L. Lewis, K. Karlin, S. Lippard, 1977 .

Oxidative addition of nitrosonium ion to sulfur-bridged binuclear iron(II) and cobalt(II) complexes

K. Karlin, S. Lippard, H. Rabinowitz, 1977 .

Investigations of dioxygen reactivity with synthetic models of the metalloproteins hemocyanin and cytochrome c oxidase

K. Karlin, N. N. Murthy, Ning Wei, 1993 .

Binding and Activation of Molecular Oxygen by Copper Complexes

K. Karlin, Y. Gultneh, 2007 .

Aluminum halide promoted carbonylation reactions: facile synthesis of bicyclo[3.2.1]oct-2-ene-4,8-dione from cyclohexadiene (tricarbonyl)iron

K. Karlin, Jack Lewis, B. Johnson, 1978 .

Tricarbonyl[8-acetyl 2-4:6-7-η-bicyclo[3.2.1]octadienylium]iron, a novel rearrangement in the acylation of η-C8H8Fe(CO)3

G. Sheldrick, K. Karlin, P. Diversi, 1977 .

Probing metal-mediated O2 activation in chemical and biological systems

K. Karlin, Michael P. Lanci, J. Roth, 2006 .

Synthesis and spectroscopy of micro-oxo (O(2)(-))-bridged heme/non-heme diiron complexes: models for the active site of nitric oxide reductase.

K. Karlin, L. Zakharov, A. Rheingold, 2004, Inorganic chemistry.

Sulfur-bridged binuclear iron(II) complexes. Effect of ligand constraints on their physical properties; reactions with carbon monoxide and alkyl isocyanides

K. Karlin, S. Lippard, 1976 .

Formation and Reactivity of New Isoporphyrins: Implications for Understanding the Tyr-His Cross-Link Cofactor Biogenesis in Cytochrome c Oxidase.

K. Karlin, I. Ivanović‐Burmazović, Melanie A. Ehudin, 2019, Journal of the American Chemical Society.

Ligand Influences in Heme–Copper O2-Chemistry as Synthetic Models for Cytochrome c Oxidase

K. Karlin, Eunsuk Kim, 2004 .

Dioxygen-Copper Reactivity: Generation, Characterization, and Reactivity of a Hydroperoxo-Dicopper(II) Complex.

K. Karlin, J. Zubieta, R. Strange, 1989 .

Dioxygen-Copper Reactivity. Models for Hemocyanin: Reversible O2 and CO Binding to Structurally Characterized Dicopper(I) Complexes Containing Hydrocarbon-Linked Bis(2-(2-pyridyl)ethyl)amine Units.

K. Karlin, J. Zubieta, A. Farooq, 1988 .

Dioxygen mediated oxo-transfer to an amine and oxidative N-dealkylation chemistry with a dinuclear copper complex

K. Karlin, Hong Liang, C. X. Zhang, 2001 .

Spectroscopic and computational studies of an end-on bound superoxo-Cu(II) complex: geometric and electronic factors that determine the ground state.

Frank Neese, Li Tian, Eckhard Bill, 2010, Inorganic chemistry.

A Cu2-O2 Complex. Crystal Structure and Characterization of a Reversible Dioxygen Binding System.

K. Karlin, J. Zubieta, A. Farooq, 1988 .

Dioxygen Reactivity of Fully Reduced [LFeII···CuI]+ Complexes Utilizing Tethered Tetraarylporphyrinates: Active Site Models for Heme-Copper Oxidases

Dong Heon Lee, K. Karlin, R. Cotter, 1999 .

Copper–Peptide Complex Structure and Reactivity When Found in Conserved His-Xaa-His Sequences

K. Karlin, Richard A. Himes, N. Blackburn, 2014, Journal of the American Chemical Society.

Reaction of a copper-dioxygen complex with nitrogen monoxide (*NO) leads to a copper(II)-peroxynitrite species.

Jörg Sundermeyer, K. Karlin, J. Sundermeyer, 2008, Journal of the American Chemical Society.

Spectroscopic elucidation of a new heme/copper dioxygen structure type: implications for O···O bond rupture in cytochrome c oxidase.

K. Hodgson, K. Karlin, B. Hedman, 2012, Angewandte Chemie.

Tridentate copper ligand influences on heme-peroxo-copper formation and properties: reduced, superoxo, and mu-peroxo iron/copper complexes.

K. Karlin, C. Incarvito, A. Rheingold, 2005, Inorganic chemistry.

Dioxygen reactivity of copper and heme-copper complexes possessing an imidazole-phenol cross-link.

K. Karlin, A. Zuberbühler, S. Kaderli, 2005, Inorganic chemistry.

Heme/Cu/O2 reactivity: change in FeIII-(O2 2-)-CuII unit peroxo binding geometry effected by tridentate copper chelation.

K. Karlin, J. Shearer, A. Zuberbühler, 2004, Journal of the American Chemical Society.

(F(8)TPP)Fe(II)/O(2) reactivity studies [F(8)TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-)]: spectroscopic (UV-Visible and NMR) and kinetic study of solvent-dependent (Fe/O(2) = 1:1 or 2:1) reversible O(2)-reduction and ferryl formation.

K. Karlin, I. Guzei, A. Rheingold, 2001, Inorganic chemistry.

Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights

K. Karlin, S. Fukuzumi, Hiroaki Kotani, 2011, Proceedings of the National Academy of Sciences.

Electrocatalytic four-electron reductions of O2 to H2O with cytochrome c oxidase model compounds

K. Karlin, Hyosul Shin, C. Kang, 2003 .

X-RAY ABSORPTION-EDGE SPECTROSCOPY OF COPPER(I) COMPLEXES - COORDINATION GEOMETRY OF COPPER(I) IN THE REDUCED FORMS OF COPPER PROTEINS AND THEIR DERIVATIVES WITH CARBON-MONOXIDE

K. Karlin, J. Zubieta, R. Strange, 1989 .

Reaction of halides with tricarbonylcyclohexadienyliron cation: Preparation of tricarbonyl(5exo-Fluorocyclohexa-1,3-diene)iron

K. Karlin, Jack Lewis, D. Parker, 1978 .

Synthetic heme/copper assemblies: toward an understanding of cytochrome c oxidase interactions with dioxygen and nitrogen oxides.

K. Karlin, I. Garcia-Bosch, S. Hematian, 2015, Accounts of chemical research.

Enhanced Rates of C-H Bond Cleavage by a Hydrogen Bonded Synthetic Heme High-Valent Iron(IV) Oxo Complex.

K. Karlin, D. A. Quist, Melanie A. Ehudin, 2019, Journal of the American Chemical Society.

Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization

K. Karlin, M. Siegler, Hyun Kim, 2016, JBIC Journal of Biological Inorganic Chemistry.

A “Naked” FeIII-(O22–)-CuII Species Allows for Structural and Spectroscopic Tuning of Low-Spin Heme-Peroxo-Cu Complexes

K. Karlin, E. Solomon, Andrew W. Schaefer, 2015, Journal of the American Chemical Society.

An electron spin echo envelope modulation (ESEEM) study of electron-nuclear hyperfine and nuclear quadrupole interactions of dz2 ground state copper(II) complexes with substituted imidazoles

K. Karlin, J. Peisach, F. Jiang, 1993 .

Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase.

K. Hodgson, D. Sokaras, K. Karlin, 2020, Inorganic chemistry.

Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction.

K. Karlin, A. Dey, Sarmistha Bhunia, 2021, Inorganic chemistry.

Heme-FeIII Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: FeIII-O2•- Complex H-Atom Abstraction Reactivity.

K. Karlin, E. Solomon, Andrew W. Schaefer, 2020, Journal of the American Chemical Society.

Carbon monoxide and nitrogen monoxide ligand dynamics in synthetic heme and heme-copper complex systems.

K. Karlin, G. Meyer, H. Lucas, 2009, Journal of the American Chemical Society.

Fenton-like Chemistry by a Copper(I) Complex and H2O2 Relevant to Enzyme Peroxygenase C-H Hydroxylation.

K. Karlin, E. Solomon, Wesley J. Transue, 2023, Journal of the American Chemical Society.

Synthesis and structure of Fe(L'H)(NO)2, a tetracoordinate complex having a twelve-membered chelate ring, and its conversion to pentacoordinate FeL'(NO) through formal loss of "HNO" (L' = SCH2CH2NMeCH2CH2CH2NMeCH2CH2S-)

K. Karlin, S. Lippard, J. Dewan, 1980 .

A mononuclear nonheme {FeNO}6 complex: synthesis and structural and spectroscopic characterization

K. Hodgson, K. Karlin, B. Hedman, 2018, Chemical science.

Mononuclear copper complex-catalyzed four-electron reduction of oxygen.

K. Karlin, S. Fukuzumi, T. Suenobu, 2010, Journal of the American Chemical Society.

Isocyanide binding to the copper(I) centers of the catalytic core of peptidylglycine monooxygenase (PHMcc)

K. Karlin, N. N. Murthy, N. Blackburn, 2001, JBIC Journal of Biological Inorganic Chemistry.

Heme-Cu Binucleating Ligand Supports Heme/O2 and FeII-CuI/O2 Reactivity Providing High- and Low-Spin FeIII-Peroxo-CuII Complexes.

K. Karlin, E. Solomon, Andrew W. Schaefer, 2019, Inorganic chemistry.

Low-temperature UV-visible and NMR spectroscopic investigations of O(2) binding to ((6)L)Fe(II), a ferrous heme bearing covalently tethered axial pyridine ligands.

K. Karlin, R. Ghiladi, 2002, Inorganic chemistry.

Dioxygen Reactivity of Reduced Heme and Heme-Copper Complexes Utilizing Tetraarylporphyrinates Tethered with Both a Pyridyl Axial Ligand and N,N-Bis[2-(2-pyridyl)ethyl]amine Chelate.

K. Karlin, M. Kopf, 1999, Inorganic chemistry.

OXO- AND HYDROXO-BRIDGED HEME-COPPER ASSEMBLIES FORMED FROM ACID-BASE OR METAL-DIOXYGEN CHEMISTRY

K. Karlin, A. Zuberbühler, Y. Neuhold, 1999 .

Heterobinucleating Ligand-Induced Structural and Chemical Variations in [(L)FeIII−O−CuII]+ μ-Oxo Complexes

Dong Heon Lee, K. Karlin, G. V. Strijdonck, 1998 .

Synthesis, Structure, and Reactivity of Copper Dioxygen Complexes Derived from Molecular Receptor Ligands

V. A. Solé, M. C. Feiters, K. Karlin, 1999 .

Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes.

K. Karlin, E. Solomon, Sunghee Kim, 2018, Journal of the American Chemical Society.

Heme—Copper/Dioxygen Adduct Formation, Properties, and Reactivity

K. Karlin, E. Chufán, S. Puiu, 2007 .

Geometric and electronic structure of the heme-peroxo-copper complex [(F8TPP)FeIII-(O22-)-CuII(TMPA)](ClO4).

K. Hodgson, K. Karlin, B. Hedman, 2005, Journal of the American Chemical Society.

SULFUR‐BRIDGED BINUCLEAR IRON(II) COMPLEXES. EFFECT OF LIGAND CONSTRAINTS ON THEIR PHYSICAL PROPERTIES, REACTIONS WITH CARBON MONOXIDE AND ALKYL ISOCYANIDES

K. Karlin, S. Lippard, 1977 .

The environment of multinuclear copper metal linkages in protein structures

S. Karlin, K. Karlin, Zhan-yang Zhu, 1998, JBIC Journal of Biological Inorganic Chemistry.

Vibrational, Electronic, and Resonance Raman Spectral Studies of (Cu2(XYL‐O‐)O2)+ (I), a Copper(II) Peroxide Model Complex of Oxyhemocyanin.

K. Karlin, E. Solomon, R. Cruse, 1987 .

New heme-dioxygen and carbon monoxide adducts using pyridyl or imidazolyl tailed porphyrins.

K. Karlin, Yuqi Li, Savita K. Sharma, 2013, Polyhedron.

Molecular oxygen and sulfur reactivity of a cyclotriveratrylene derived trinuclear copper(I) complex.

K. Karlin, E. Solomon, D. Maiti, 2009, Inorganic chemistry.

Synthesis and X-ray crystal structure of a trinuclear copper(I) cluster

K. Karlin, J. Zubieta, A. Farooq, 1989 .

Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes.

K. Karlin, E. Solomon, Ryan E Cowley, 2013, Inorganic chemistry.

Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization

K. Karlin, M. Siegler, Hyun Kim, 2016, JBIC Journal of Biological Inorganic Chemistry.

Synthesis, characterization, and laser flash photolysis reactivity of a carbonmonoxy heme complex.

K. Karlin, G. Meyer, A. Rheingold, 2003, Inorganic Chemistry.

Synthesis and characterization of reduced heme and heme/copper carbonmonoxy species.

K. Karlin, R. Ghiladi, R. Kretzer, 2003, Inorganic Chemistry.

Ligand-Copper(I) Primary O2-Adducts: Design, Characterization, and Biological Significance of Cupric-Superoxides.

K. Karlin, Bohee Kim, 2023, Accounts of chemical research.

Aluminum trihalide interactions with polyolefin tricarbonyliron compounds

Joy H. Lewis, K. Karlin, B. Johnson, 1978 .

Extended metal environments of cytochrome c oxidase structures.

S. Karlin, Z. Y. Zhu, K. Karlin, 1998, Biochemistry.

L-edge X-ray absorption spectroscopy and DFT calculations on Cu2O2 species: direct electrophilic aromatic attack by side-on peroxo bridged dicopper(II) complexes.

K. Hodgson, K. Karlin, B. Hedman, 2013, Journal of the American Chemical Society.

Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases.

K. Karlin, E. Solomon, Andrew W. Schaefer, 2017, Journal of the American Chemical Society.

Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2015, Journal of the American Chemical Society.

Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2013, Journal of the American Chemical Society.

Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes.

K. Karlin, K. Ohkubo, S. Fukuzumi, 2012, Journal of the American Chemical Society.

Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water.

K. Karlin, S. Fukuzumi, Yong‐Min Lee, 2012, Chemistry.

Suggestion of an organometallic intermediate in an intramolecular dechlorination reaction involving copper(I) and a ArCH2Cl moiety.

K. Karlin, D. Maiti, S. Itoh, 2008, Journal of the American Chemical Society.

One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina

K. Karlin, S. Fukuzumi, Mihoko Yamada, 2016, Chemical science.

Reactions of Co(III)-nitrosyl complexes with superoxide and their mechanistic insights.

K. Karlin, Pankaj Kumar, Yong‐Min Lee, 2015, Journal of the American Chemical Society.

Progress in Inorganic Chemistry: Karlin/Inorganic Chemistry 54

K. Karlin, 2005 .

Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a "Bridging Peroxo" Intermediate Involved in Facile 4e(-)/4H(+) O2-Reduction.

K. Karlin, A. Dey, S. Chatterjee, 2015, Journal of the American Chemical Society.

Heme/O2/*NO nitric oxide dioxygenase (NOD) reactivity: phenolic nitration via a putative heme-peroxynitrite intermediate.

K. Karlin, Dong-Heon Lee, Biplab Mondal, 2009, Journal of the American Chemical Society.

Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity

K. Karlin, M. Siegler, S. Hematian, 2014, JBIC Journal of Biological Inorganic Chemistry.