T. Fehlner

发表

Molecular QCA cells. 2. Characterization of an unsymmetrical dinuclear mixed-valence complex bound to a Au surface by an organic linker.

Z. Li, T. Fehlner, 2003, Inorganic chemistry.

Molecular quantum cellular automata cells. Electric field driven switching of a silicon surface bound array of vertically oriented two-dot molecular quantum cellular automata.

C. Lent, A. Orlov, G. Snider, 2003, Journal of the American Chemical Society.

Molecular QCA cells. 1. Structure and functionalization of an unsymmetrical dinuclear mixed-valence complex for surface binding.

Z. Li, T. Fehlner, A. Beatty, 2003, Inorganic chemistry.

The Dissociation of BH3CO into BH3 and CO1

T. Fehlner, W. S. Koski, 1965 .

On the energetics of the formation of EHM from MHM interactions on transition metal clusters

T. Fehlner, 1990 .

The interface of metal-metal multiple bond compounds and organometallic clusters: synthesis and structure of Mo2{.mu.-[(CO)9Co3(.mu.3-CCO2)]}4[(CO)9Co3(.mu.3-CCO2H)]2 and related compounds

P. Lindenfeld, T. Fehlner, W. Cen, 1992 .

Electronic quantum-dot cellular automata

C. Lent, G. Bernstein, A. Orlov, 2008, 2008 9th International Conference on Solid-State and Integrated-Circuit Technology.

The relevance of the Dewar model to neighboring p-block element analogs of metal hydrocarbon π-complexes

T. Fehlner, 2001 .

MOLECULAR ORBITAL ANALYSIS OF THE TREND IN 11B NMR CHEMICAL SHIFTS FOR (CP*M)2B5H9 (M = CR, MO, W; CP* = ETA 5-C5ME5)

T. Fehlner, A. Weller, 1999 .

On the fast addition reactions of BH3

T. Fehlner, 1975 .

Reactivity of Dimetallapentaboranes—nido-[CpM2B3H7]—with Alkynes: Insertion to Form a Ruthenacarborane (M=RuH) versus Catalytic Cyclotrimerization to Form Arenes (M=Rh)

T. Fehlner, A. Beatty, Hong Yan, 2001 .

Cluster Equilibria. Relevance to the Energetics and Reactivity of Surface Bound Fragments

T. Fehlner, 1995 .

Calculations on the orientation on the fragment in Co3(CO)9(μ3-CH): Implications for metal surfaces

R. L. Dekock, T. Fehlner, 1982 .

Some implications of transition metal cluster chemistry on hydrogen embrittlement and alloy behavior

T. Fehlner, N. F. Fiore, M. A. Cavanaugh, 1982 .

Metalloboranes: Their Relationships to Metal-Hydrocarbon Complexes and Clusters

T. Fehlner, C. Housecroft, 1982 .

SOME PHYSICAL AND CHEMICAL CONSEQUENCES OF THE IRON TRICARBONYL FRAGMENT IN BORANE CAGES

T. Fehlner, 1979 .

Apparent oxidative coupling of the ferraborane dianion [B2H4Fe2(CO)6][Li]2. Preparation and structural characterization of conjuncto-B4H8Fe4(CO)12

T. Fehlner, Xiangsheng Meng, K. Haller, 1991 .

Reactions of borane (BH3). V. Mass spectrometric observation of the products of addition to diborane(L) and pentaborane(9)

T. Fehlner, S. Fridmann, 1972 .

Direct observation of the addition products of the reaction of borane with diborane and of the reaction of borane with pentaborane(9)

T. Fehlner, S. Fridmann, 1971 .

Mass spectrometric investigation of the low-pressure pyrolysis of borane carbonyl. Bond dissociation energy of diborane

T. Fehlner, G. Mappes, 1969 .

Photoelectron spectrum of boron hydride sulfide

D. W. Turner, T. Fehlner, 1973 .

Reactions of borane (BH3). VI. Reactions with alcohols

T. Fehlner, 1973 .

Reactions of borane (BH3). IV. Absolute rate of reaction with acetone

T. Fehlner, 1972 .

Clusters as Substituents. Synthesis and Thermal Decomposition of Metal Carboranecarboxylates

T. Fehlner, A. Rheingold, M. Shang, 1994 .

Effect of Precursor Core Structure on the Hydrogenation of 1,3-Butadiene Catalyzed by Cluster-Derived Model Catalysts

E. Wolf, T. Fehlner, M. Bañares, 1995 .

Chemistry of a transition metal cluster substituted carboxylic acid: synthesis and structure of [CH3(OCH2CH2)4OCH3]

T. Fehlner, X. Lei, M. Shang, 1997 .

Ferraborane cluster chemistry: reactions of [(.mu.-H)Fe3(CO)9BH3]- with Lewis bases leading to substitution via hydrogen elimination or to cluster degradation

T. Fehlner, C. Housecroft, 1986 .

Synthesis of Novel Molybdaboranes from (η5-C5R5)MoCln Precursors (R = H, Me; n = 1, 2, 4)

T. Fehlner, S. Aldridge, M. Shang, 1998 .

Clusters as ligands. Stabilization of a cadmium-cobalt Cd3Co core in [.mu.3-Co(CO)3]Cd3{.mu.-[(CO)9Co3(.mu.3-CCO2)]}3(THF)3

T. Fehlner, K. Haller, W. Cen, 1992 .

Selective Hydrogenation of 2-Butenal Using Cluster of Clusters-Based Catalysts

E. Wolf, T. Fehlner, M. Bañares, 1996 .

Titanium-Cobalt Cluster of Cluster-Based Catalysts for the Selective Hydrogenation of α,β-Unsaturated Aldehydes☆

E. Wolf, T. Fehlner, X. Lei, 1998 .

Comparison of the geometric and molecular orbital structures of (Cp*Cr)2B4H8 and (Cp*Re)2B4H8, Cp*=η5-C5Me5. Structural consequences of delocalized electronic unsaturation in a metallaborane cluster

T. Fehlner, Sundargopal Ghosh, M. Shang, 2000 .

FACILE REDUCTION OF AN UNSATURATED CHROMABORANE

T. Fehlner, K. Kawamura, 1998 .

Cluster Expansion Reactions of Group 6 Metallaboranes. Syntheses, Crystal Structures, and Spectroscopic Characterizations of (Cp*Cr)2B5H9, (Cp*Cr)2B4H8Fe(CO)3, (Cp*Cr)2B4H7Co(CO)3, and (Cp*Mo)2B5H9Fe(CO)3

T. Fehlner, S. Aldridge, K. Kawamura, 1998 .

SYNTHESIS AND STRUCTURE OF ETA 5-C5H5CR2MU -ETA 6 :ETA 6-(MU -1,2-C3H6-1,2-C2B4H4). AN UNUSUAL 24-ELECTRON TRIPLE-DECKER SANDWICH COMPLEX CONTAINING A METAL-STABILIZED, PLANAR TETRABORABENZENE

O. Wiest, T. Fehlner, K. Kawamura, 1998 .

A molecular orbital analysis of four chromaboranes

T. Fehlner, 1998 .

Exploring the interactions of d-block elements with boron. A case for electronically unsaturated metallaborane clusters

T. Fehlner, 1998 .

Directed Synthesis of Chromium and Molybdenum Metallaborane Clusters. Preparation and Characterization of (Cp*Cr)2B5H9, (Cp*Mo)2B5H9, and (Cp*MoCl)2B4H10

T. Fehlner, S. Aldridge, M. Shang, 1997 .

REACTIONS OF AN ELECTRONICALLY UNSATURATED CHROMABORANE. COORDINATION OF CS2 TO (ETA 5-C5ME5)2CR2B4H8 AND ITS HYDROBORATION TO A METHANEDITHIOLATO LIG AND

T. Fehlner, H. Hashimoto, M. Shang, 1996 .

CLUSTERS AS LIGANDS. COORDINATION OF AN ELECTRONICALLY UNSATURATED CHROMABORANE TO AN IRON TRICARBONYL FRAGMENT

T. Fehlner, H. Hashimoto, M. Shang, 1996 .

HIGH YIELD SYNTHESIS AND CHARACTERIZATION OF CHROMOBARONES. COMPARISON OF THE GEOMETRIC, ELECTRONIC, AND CHEMICAL PROPERTIES OF AN ELECTRONICALLY UNSA TURATED (ETA 5-C5ME5)2CR2B4H8 CLUSTER WITH ITS SATURATED DERIVATIVE (ETA 5- C5ME5)2CR2(CO)2B4H6

T. Fehlner, Y. Nishihara, J. Ho, 1995 .

Preparation and Structure of (Cp*Cr)2B4H8. An Unsaturated Metallaborane Cluster with an Unexpected Structure

T. Fehlner, Y. Nishihara, M. Shang, 1994 .

Clusters as Ligands – Large Assemblies of Transition Metal Clusters

Thomas P. Fehlner, E. Wolf, T. Fehlner, 1998 .

Novel cluster-derived catalysts for the selective hydrogenation of crotonaldehyde

E. Wolf, T. Fehlner, M. Bañares, 1995 .

Clusters as Ligands, Part 3: Generation of Tricobalt Cluster Carboxylate-bridged Iron - Cobalt and Manganese - Cobalt Mixed-metal Alkoxide Cubes from Iron and Manganese Tricobalt Cluster Metal Carboxylates

T. Fehlner, W. Haase, G. Long, 1997 .

Formation of a high surface area, regular porous solid from the cluster of clusters, Zn4IIO[(CO)9Co3CCO2]6

T. Fehlner, W. Cen, B. Ladna, 1993 .

The syntheses and X-ray crystal structures of novel transition metal cluster arrays containing 2–5 coordinated [(CO)9Co3(μ3-CCOO)]− ligands in a variety of geometries

T. Fehlner, A. Rheingold, G. Yap, 1999 .

Preparation of a carbon-rich metallacarborane from a metallacycle

T. Fehlner, D. B. Palladino, 1983 .

Chapter 4 – Gas Phase Reactions of Borane

T. Fehlner, 1975 .

Main Group Fragments as Ligands to Transition Metals

T. Fehlner, 1992 .

Clusters as Ligands. 5. Tricobalt Cluster Alkoxycarboxylates of Titanium and Zirconium Exhibiting Novel Structures and Properties

T. Fehlner, X. Lei, M. Shang, 1997 .

Synthesis and Structure of an Extended Cluster Lead(II) Carboxylate, [Pb{(CO)(9)Co(3)(&mgr;(3)-CCO(2))}(2)](n)(). Role of Core Metals in Cluster-Derived Hydrogenation Catalysts.

E. Wolf, T. Fehlner, X. Lei, 1996, Inorganic chemistry.

Isoelectronic Organometallic Molecules

T. Fehlner, A. Aradi, 1990 .

Utilization of a Cobalt Carbonyl Cluster Carboxylic Acid in the Isolation of Novel Titanium(IV) Oxo Alkoxy Carboxylates

T. Fehlner, X. Lei, M. Shang, 1996 .

Clusters as ligands. Comparison of the reactivity of (CO)9Co3(.mu.3-CR) (R = COOH, p-C6H4(CH2)2COOH) leading to the formation of Zn[p-C6H4(CH2)2CO2]2 vs MII4O[(CO)9Co3CCO2]6 (M = Zn, Co)

T. Fehlner, K. Haller, W. Cen, 1993 .

Transition-metal clusters as substituents. Synthesis, structure, and thermal decomposition of Zn4O[(CO)9Co3(.mu.3-CCO2)]6. [Erratum to document cited in CA116(5):41702n]

T. Fehlner, K. Haller, W. Cen, 1992 .

Transition-metal clusters as substituents. Synthesis, structure, and thermal decomposition of Zn4O[(CO)9Co3(.mu.3-CCO2)]6

T. Fehlner, K. Haller, W. Cen, 1991 .

On the role of PES data in the identification of metal—metal charge transfer bands in clusters of clusters

T. Fehlner, W. Cen, V. Calvo-Pérez, 1993 .

Cluster Compounds: Inorganometallic Compounds Containing Transition Metal & Main Group Elements

T. Fehlner, 2006 .

Synthese von 2,3,4-Tris(η5-cyclopentadienyl)-1,5-diphenyl-1-phospha-2,3,4-tricobalta-closo-pentaboran(5). Übertragung einer Phenylgruppe von Phosphor auf Bor

T. Fehlner, A. Rheingold, Jiang Feilong, 1988 .

Preparation of 2,3,4-Tris(η5-cyclopentadienyl)-1,5-diphenyl-1-phospha-2,3,4- tricobaltapentaborane(5); Phenyl Group Migration from Phosphorus to Boron†

T. Fehlner, A. Rheingold, Jiang Feilong, 1988 .

Synthesis of (CH3)4C4B4H4. An example of photochemical addition of an alkyne to a borane via a ferraborane intermediate

T. Fehlner, 1977 .

Metallaborane Reaction Chemistry. nido-Dirhodapentaborane Isomer Structures and Stabilities and Utilization of Dirhodaboranes as Catalysts for Alkyne Cyclotrimerization

T. Fehlner, Hong Yan, A. A. Beatty, 2002 .

Reactions of borane. II. Absolute rate of the reaction of borane with ethylene in the gas phase

T. Fehlner, 1971 .

UV photoelectron spectra of group IV alkyl hydrides

T. Fehlner, K. Mochida, J. Kochi, 1980 .

Metal-Rich Ferra- and Cobaltaboranes. Mimics of Organometallic Clusters

T. Fehlner, 1989 .

Implications of the photoelectron spectrum of a methylene-bridged, dinuclear transition-metal complex

T. Fehlner, J. Vites, 1981 .

The unusual bonding capabilities of a tetrametal butterfly cluster fragment: electronic structures of HFe4(CO)12CH and HFe4(CO)13-

T. Fehlner, C. Housecroft, 1984 .

Effects of bridging hydrogens on metal-metal bonds. 1. Geometrical comparison of Fe3(.mu.-H)3(CO)9(.mu.3-CMe), Co3(CO)9(.mu.3-CMe), and model compounds

T. Fehlner, D. Chipman, K. Haller, 1982 .

Effects of bridging hydrogens on metal-metal bonds. 2. UV photoelectron and uv-visible spectra and quantum-chemical calculations for Fe/sub 3/(. mu. -H)/sub 3/(CO)/sub 9/(. mu. /sub 3/-CCH/sub 3/) and Co/sub 3/(CO)/sub 9/(. mu. /sub 3/-CCH/sub 3/)

R. L. Dekock, T. Fehlner, K. Wong, 1982 .

Quantum-chemical investigation of (2,2'-bpy)SnB4H4(CCH3)2 and (CO)3FeB4H4(CCH3)2. Origin of observed structural distortions from idealized closo geometries

T. Fehlner, N. Hosmane, R. Barreto, 1988 .

Characterization of ferraboranes by ultraviolet photoelectron spectroscopy

T. Fehlner, J. Ulman, E. Andersen, 1978 .

The ferraborane B5H9Fe(CO)3 and its conjugate base B5H8Fe(CO)3

T. Fehlner, S. Shore, M. Mangion, 1976 .

Clusters as Ligands. 4. Synthesis, Structure, and Characterization of the Tungsten(II)-Tungsten(III) Cluster Carboxylate {[Na][W(2){OOCCCo(3)(CO)(9)}(2)(OOCCF(3))(4)(THF)(2)]}(2).

T. Fehlner, A. Rheingold, V. Calvo-Pérez, 1996, Inorganic chemistry.

Skeletal rearrangement of boridohexadecacarbonyltetrairondirhodate(1-). An example of an associative cluster isomerization

T. Fehlner, R. Khattar, A. Bandyopadhyay, 1989 .

Molecular Clusters: A Bridge to Solid-State Chemistry

T. Fehlner, J. Saillard, J. Halet, 2007 .

The Metallic Face of Boron

T. Fehlner, 1990 .

Protonation of cluster molecules: Bridging hydrogen sites in tetrahedral, octahedral and capped square pyramidal clusters: Be4H8, Be4H8

T. Fehlner, K. Wade, R. Stramel, 1985 .

Molecular Clusters: Inter-conversion of clusters and solid-state materials

T. Fehlner, J. Saillard, J. Halet, 2007 .

Synthesis and structure of [(η5-C5Me5)WCl2(μ-H)]2. A dinuclear tungsten hydride with a double bond formed from the reaction of BH3THF with (η5-C5Me5)WCl4

T. Fehlner, M. Shang, Melanie A. Peldo, 2000 .

The making and breaking of carbon-hydrogen bonds on a metal cluster framework. Analysis of the tautomerization and deprotonation of Fe3(CO)9CH4 leading to the interconversion of FeHFe and CHFe interactions

T. Fehlner, T. Dutta, J. Vites, 1987 .

PROTONS ON A CLUSTER SURFACE. REVERSIBLE GENERATION OF AGOSTIC (CARBON-HYDROGEN-METAL) HYDROGENS FROM IRON HYDRIDES (IRON-HYDROGEN-IRON) ON A SATURATED TRIIRON CLUSTER

T. Fehlner, T. Dutta, J. Vites, 1985 .

Dependence of field switched ordered arrays of dinuclear mixed-valence complexes on the distance between the redox centers and the size of the counterions.

Anuradha Gupta, Thomas P Fehlner, C. Lent, 2005, Journal of the American Chemical Society.

Ultraviolet photoelectron spectroscopy of thiaboranes

T. Fehlner, R. Rudolph, M. Wu, 1980 .

Ultraviolet photoelectron spectroscopy of boranes and carboranes. Five-, six-, and seven-atom frameworks

T. Fehlner, J. Ulman, 1978 .

Substituent effects in cluster species. Photoelectron spectra of 1-, 2-, and .mu.-substituted pentaborane(9)

T. Fehlner, J. Ulman, 1976 .

Synthesis of BC4H5Fe(CO)3. An example of the conversion of an organometallic compound into a metallocarborane

T. Fehlner, 1978 .

Electronic structure and photoelectron spectra of S2Fe2(CO)6

D. Salahub, T. Fehlner, E. Andersen, 1980 .

The structure and properties of HFe3(CO)9BH3R and the conjugate bases [HFe3(CO)9BH2R]- (R = H and CH3). Inorganometallic analogs of hydrocarbyltriiron clusters

T. Fehlner, C. Eigenbrot, G. Long, 1986 .

Alloy Thin Films from Discrete Metallaborane Clusters

O. A. Pringle, F. P. Fehlner, T. Fehlner, 1988 .

Preparation of tris(.mu.2-hydro)-nonacarbonyl-.mu.3-ethylidyne-triiron from pentacarbonyliron

T. Fehlner, K. Wong, 1981 .

Condensed metallaborane clusters: synthesis and structure of Fe2(CO)6(eta5-C5Me5RuCO)(eta5-C5Me5Ru)B6H10.

T. Fehlner, B. Noll, Sundargopal Ghosh, 2005, Chemical communications.

Synthesis of metal-rich metallaborane clusters. Evidence for a mechanism involving fragment condensation

T. Fehlner, Xiangsheng Meng, Friedrich-Wilhelm Grevels, 1990 .

Synthesis, characterization, and ligand substitution of [HFe4(CO)12BH]−: an isoelectronic and isoprotonic inorganometallic analogue of HFe4(CO)12CH

T. Fehlner, G. Long, C. Housecroft, 1987 .

Substituent effects in clusters. UV-photoelectron spectroscopic and quantum-chemical analyses of triosmium carbonyl hydrides H3Os3(CO)9BCO, H2Os3(CO)9CCO, and related clusters

T. Fehlner, L. Hsu, D. Jan, 1986 .

Main group chemistry on a metal framework. Reactions of [(.mu.-H)Fe3(CO)9BH2R]- (R = H, CH3) with Lewis bases

T. Fehlner, C. Housecroft, 1986 .

Electronic charge control of stable sites and mobilities of hydrogen atoms on a main-Group transition metal cluster surface. A comparison of [HFe4(CO)12-n(PPhMe2)nBH]PPN (n = 0-2) and HFe4(CO)12CH

T. Fehlner, C. Housecroft, 1986 .

Synthesis of [(.mu.-H)Fe4(CO)12BH]- from [(.mu.-H)Fe3(CO)9BH3]- via cluster expansion involving hydrogen elimination

T. Fehlner, C. Housecroft, 1986 .

CLUSTER MIMETICS. THE PREPARATION AND CHARACTERIZATION OF (μ-H)FE3(CO)9(μ3-BH4)

T. Fehlner, C. Eigenbrot, J. Vites, 1984 .

Cluster mimetics. 2. The preparation and characterization of (.mu.-H)(.mu.-CO)Fe3(CO)9BH2, (.mu.-CO)Fe3(CO)9BH2-, and Fe3(CO)9BH4-

T. Fehlner, C. Housecroft, J. Vites, 1984 .

Crystal, geometrical and electronic structure of HFe4(CO)12BH2. A boron analog of a protonated carbido cluster

T. Fehlner, C. Housecroft, W. Scheidt, 1983 .

Preparation and characterization of HFe4(BH2)(CO)12. A hydrogenated iron boride cluster

T. Fehlner, W. Scheidt, K. Wong, 1982 .

Electronic structure of diiron ferraboranes

R. L. Dekock, T. Fehlner, E. Andersen, 1981 .

Crystal and molecular structure of (CO)6Fe2B3H7, a diiron analog of pentaborane(9)

T. Fehlner, K. Haller, E. Andersen, 1981 .

Ferraborane B3H7Fe2(CO)6, a diiron analog of pentaborane(9)

T. Fehlner, K. Haller, E. Andersen, 1979 .

A diborane(6) bridged diiron hexacarbonyl: preparation of B2H6Fe2(CO)6

T. Fehlner, E. Andersen, 1978 .

Electron counting in cluster species. The significance of the structure and isomerism of the iron-molybdenum-sulfur cluster compound (dicyclopentadienyldimolybdenum)diron octacarbonyl disulfide, (.eta.5-C5H5)2Mo2Fe2(CO)8S2, a hexanuclear species in which two Mo2FeS tetrahedra share a common molybden

T. Fehlner, C. Housecroft, K. Wade, 1983 .

Expansion of iridaborane clusters by addition of monoborane. Novel metallaboranes and mechanistic detail.

T. Fehlner, B. Noll, Sundargopal Ghosh, 2008, Dalton transactions.

Chemistry of Dimetallaboranes Derived from the Reaction of [Cp*MCl2]2 with Monoboranes (M = Ru, Rh; Cp* = η5-C5Me5)

T. Fehlner, X. Lei, M. Shang, 1999 .

Activity and characterization of self-supported model catalysts derived from cobalt-based clusters of clusters: Hydrogenation of 1,3-butadiene

E. Wolf, T. Fehlner, M. Bañares, 1995 .

Single-source precursors of structured catalysts for the hydrogenation of 1,3-butadiene

E. Wolf, T. Fehlner, Z. Kalenik, 1993 .

Substituent effects in cluster species. 4. Ultraviolet-photoelectron spectroscopic and molecular orbital studies of carbyne complexes of multinuclear cobalt carbonyls

R. L. Dekock, T. Fehlner, C. Housecroft, 1983 .

NATURE OF THE HIGHEST OCCUPIED MOLECULAR ORBITAL IN R2C2CO2(CO)6

R. L. Dekock, T. Fehlner, J. Hwang, 1981 .

Cluster mimetics. The preparation and characterization of (.mu.-H)Fe3(CO)9(.mu.3-BH4)

T. Fehlner, C. Eigenbrot, J. Vites, 1984 .

Novel Iridaboranes from the Reactions of Cp*2Ir2HxCl4-x, x = 0−2, with LiBH4. Existence of a Concurrent Reaction Channel in the Conversion of Metal Chlorides to Metal Hydrides

T. Fehlner, X. Lei, M. Shang, 1999 .

Synthesis of Mono- and Ditungstaboranes from Reaction of Cp*WCl4 and [Cp*WCl2]2 with BH3·thf or LiBH4 (Cp* = η5-C5Me5). Control of Reaction Pathway by Choice of Monoboron Reagent and Oxidation State of Metal Center

T. Fehlner, A. Weller, M. Shang, 1999 .

Synthesis and Structure of the Metallaborane Cp*3(μ-H)W3B8H8 from the Thermolysis of Cp*H3WB4H8 (Cp* = η5-C5Me5). A Close-Packed 11-Atom Boron-Rich Cluster

T. Fehlner, A. Weller, M. Shang, 1998 .

Origins of Unsaturation in Group 6 Metallaboranes. Synthesis, Crystal Structure, and Molecular Orbital Calculations for (Cp*MoCl)2B3H7 (Cp* = Pentamethylcyclopentadienyl)

T. Fehlner, S. Aldridge, M. Shang, 1997 .

Synthesis of Cobaltaborane Clusters from [Cp*CoCl]2 and Monoboranes. New Structures and Mechanistic Implications

T. Fehlner, A. Rheingold, Y. Nishihara, 1994 .

ON THE ELECTRONIC STRUCTURE OF TRANSITION METAL CLUSTERS CONTAINING INTERSTITIAL BORON ATOMS AN INTERPRETATION OF THE 11B NMR PARAMETERS

T. Fehlner, P. Czech, R. Khattar, 1991 .

Application of the Fenske-Hall molecular orbital method to the calculation of boron-11 NMR chemical shifts. Antipodal substituent effects in deltahedral clusters

T. Fehlner, P. Czech, R. F. Fenske, 1990 .

Interaction of iron with boron in metal-rich metallaboranes resulting in large deshielding and rapid relaxation processes of the boron-11 nucleus

T. Fehlner, N. Rath, 1988 .

Endo hydrogens on Main Group-transition metal clusters. Theoretical analysis of the interconversion of FeHFe and EHFe interactions and deprotonation of Fe3(CO)9EHx (E = B, x = 5; E = C, x = 4)

T. Fehlner, D. Chipman, Mary M. Lynam, 1987 .

Cluster isomerization. The case of M4B4metallaboranes

T. Fehlner, 1994 .

Synthesis of [(Cp*Re)2BnHn] n=8–10: Metal Boride Particles That Stretch the Cluster Structure Paradigms

T. Fehlner, Sundargopal Ghosh, M. Shang, 2001 .

Preparation and Structure of [AsPh4]2[HFe7(CO)20B]. Evidence for the Sequential Encapsulation of a Boron Atom into an Iron Cage by a Radical-Driven Cluster-Building Process

T. Fehlner, M. Shang, Chang-Soo Jun, 1994 .

Synthesis of [AsPh4][Fe3(CO)9(.mu.-CO)(.mu.3-HBCl)] by Oxidative Chloride Substitution of [Fe3(CO)9(.mu.3-HBCO)]2-

T. Fehlner, R. Ostrander, A. Rheingold, 1994 .

Kinetic control of the oxidative coupling of [B2H4Fe2(CO)6][Li]2. X-ray crystal structures and interconversion of B,Fe-conjuncto-{B2H4Fe2(CO)6}2 and B,B-conjuncto-{B2H4Fe2(CO)6}2

T. Fehlner, D. Powell, K. Haller, 1993 .

Another rule-breaker. Characterization of the unusual cobalt carbonyl borane Co5(CO)13(.mu.-CO)B2H

T. Fehlner, A. Rheingold, Chang-Soo Jun, 1993 .

Boron in new environments. Structure and reaction properties of discrete, mixed-metal, hexanuclear borides

T. Fehlner, A. Rheingold, R. Khattar, 1992 .

Preparation of a discrete, closed-transition-metal boride. Characterization and structure of trans-[Fe4Rh2(CO)16B]PPN

T. Fehlner, A. Rheingold, R. Khattar, 1989 .

Main-group chemistry in a metal framework: preparation and characterization of (diborane)hexacarbonyldiiron and its conjugate base [B2H5Fe2(CO)6]-

T. Fehlner, G. Long, C. Housecroft, 1987 .

Multiple deprotonation of a ferraborane. Evidence for the formation of a discrete transition metal boride

T. Fehlner, N. Rath, 1987 .

Designer clusters: synthesis and characterization of Cp*2Rh2Co3(CO)8B3HCl (Cp* =η5-C5Me5)

T. Fehlner, X. Lei, M. Shang, 1999 .

Heterobimetallic Metallaborane Chemistry: Synthesis and Characterization of a "Lightly Stabilized" Molybdairidahexaborane, [{Cp^*Ir}{(CO)~3(THF)Mo}-B~4H~8], and Its Direct Conversion to [{Cp^*Ir}{(CO)~3(L)Mo}B~4H~8] (L = CO, PPh~3, NCPh, CNBu, NH~3, PPh~3=CHC(O)-OMe)

T. Fehlner, B. Noll, R. Macías, 2004 .

Chemistry of [1-Cp*-arachno-1-IrB4H10] and [1-Cp*-arachno-1-IrB3H9]: Synthesis and Characterization of the New Substituted Iridaboranes [1-Cp*-arachno-1-IrB3H7-2-L], [1-Cp*-arachno-1-IrB2H6-2-L], and [1-Cp*-arachno-1-IrB4H8-2,5-(Br)2] (L = PMe3, PMe2Ph, PMePh2, py, NEt3)

T. Fehlner, A. Beatty, R. Macías, 2004 .

Synthesis and characterization of hypoelectronic rhenaboranes. Analysis of the geometric and electronic structures of species following neither borane nor metal cluster electron-counting paradigms.

T. Fehlner, A. Beatty, B. le Guennic, 2004, Journal of the American Chemical Society.

Transition-metal variation as a probe of the origins of hypoelectronic metallaboranes: eight- and ten-vertex open ruthenaboranes.

T. Fehlner, A. Beatty, Sundargopal Ghosh, 2003, Angewandte Chemie.

Reaction of the Transition Metal Hydrides [Cp*MH2]2 (Cp* = η5-C5Me5; M = Fe, Ru) with BH3·THF to Yield Metallaboranes. Improved Kinetic Control Leads to Novel Ferraboranes

T. Fehlner, A. A. Beatty, Melanie A. Peldo, 2003 .

An iridaborane reaction cycle driven by PMe3 and BH3.THF: synthesis and characterization of [Cp*IrB3H7(PMe3)] and [Cp*IrB2H6(PMe3)].

T. Fehlner, A. Beatty, R. Macías, 2002, Angewandte Chemie.

The Reaction of Cp*ReH6, Cp* = C5Me5, with Monoborane to Yield a Novel Rhenaborane. Synthesis and Characterization of arachno-Cp*ReH3B3H8

T. Fehlner, A. Beatty, Sundargopal Ghosh, 2002 .

Synthesis and characterization of bicapped hexagonal bipyramidal 2,3-Cl(2)-1,8-[Cp*Re](2)B(6)H(4)([Cp*Re](2)[mu-eta(6):eta(6)-1,2-B(6)H(4)Cl(2)], Cp* = eta(5)-C(5)Me(5)): the missing link connecting (p - 2) skeletal electron pair hypoelectronic rhenaboranes and 24-valence electron triple-decker comp

T. Fehlner, A. Beatty, S. Ghosh, 2001, Journal of the American Chemical Society.

Synthesis and Characterization of the Hypoelectronic Ruthenaborane {(η5-C5Me5)Ru}2{η6-C6H6)Ru}B7H7}

T. Fehlner, X. Lei, and Maoyo Shang, 2001 .

Metallaboranes of the earlier transition metals. An arachno nine-vertex, nine-skeletal electron pair rhenaborane of novel shape: importance of total vertex connectivities in such systems

T. Fehlner, A. Rheingold, Sundargopal Ghosh, 2001 .

Reaction of Phosphines and Pyridine with a Heterometal Metallaborane. Ligand Substitution on Boron vs Metal Sites, Borane Displacement, and Orthometalation of a Boron-Coordinated Pyridine

T. Fehlner, X. Lei, and Maoyu Shang, 2000 .

Role of the transition metal in metallaborane chemistry. Reactivity of (Cp*ReH2)2B4H4 with BH3.thf, CO, and Co2(CO)8.

T. Fehlner, S. Ghosh, X. Lei, 2000, Inorganic chemistry.

Systematic Metallaborane Chemistry

T. Fehlner, 2000 .

Utilization of Transition-Metal Properties To Control Polyborane Formation. Synthesis of the arachno-Diiridahexaborane(12) 2,5-{Cp*IrH}2B4H8 and Its Conversion to the nido-Diiridahexaborane(10) 1,2-{Cp*Ir}2(μ-H)B4H7 (Cp* = η5-C5Me5)

T. Fehlner, X. Lei, and Maoyu Shang, 2000 .

A Novel Coordinated Inorganic Benzene: Synthesis and Characterization of {η5-C5Me5Re}2{μ-η6:η6-B4H4Co2(CO)5}

T. Fehlner, Sundargopal Ghosh, M. Shang, 1999 .

2,2'-commo-Bis[2-ruthena-nido-1-(η5-pentamethylcyclopentadienyl)ruthenahexaborane(12)]: An Unusual Ruthenaborane Related to Ruthenocene and Exhibiting a Linear Triruthenium Fragment.

T. Fehlner, X. Lei, M. Shang, 1999, Angewandte Chemie.

Early versus late transition metals. Electronic structure of nido-2-CpMLnB4H8, CpMLn=CpTaCl2, CpWH3 and CpCo

T. Fehlner, S. Aldridge, A. Weller, 1999 .

New Structural Motifs in Metallaborane Chemistry. Synthesis, Characterization, and Solid-State Structures of (Cp*W)3(μ-H)B8H8, (Cp*W)2B7H9, and (Cp*Re)2B7H7(Cp* = η-C5Me5)

T. Fehlner, A. Weller, M. Shang, 1999 .

Synthesis and Characterization of Cp(3)Ru(3)B(3)H(8), Cp = eta(5)-C(5)Me(5), Exhibiting a Capped Nido Geometry. Cluster Geometry Driven by Hydrogen Bridging.

T. Fehlner, X. Lei, M. Shang, 1998, Inorganic chemistry.

Reactions of the Cobaltaborane 2,4-{(η5-C5Me5)Co}2B3H7 with Metal Fragments. Synthesis and Characterization of nido-1-{(η5-C5Me5)Co}-2-{(CO)3Fe}B3H7 and arachno-(η5-C5Me5)(CO)CoB3H7

T. Fehlner, X. Lei, M. Shang, 1998 .

Synthesis and characterization of the nine-atom, rhena- and tungsta-boranes (Cp*Re)2B7H7 and (Cp*W)2B7H9, Cp* = η5-C5Me5. Molecular mimics of hypoelectronic main-group clusters in Zintl phases

T. Fehlner, A. Weller, M. Shang, 1998 .

Cp*TaCl2B4H8: synthesis, crystal structure and spectroscopic characterization of an air-stable, electronically unsaturated, chiral tantalaborane

T. Fehlner, S. Aldridge, H. Hashimoto, 1998 .

SYNTHESIS OF B2H5FECO(CO)6, FE2CO(CO)9(MU -CO)BH2, FECO2(CO)9(MU -CO)BH, FECO2(CO)9(BH)2, AND HFE3CO(CO)12BH. CO(CO)3 FRAGMENT ADDITION AND FRAGMENT E XCHANGE IN FERRABORANE CLUSTERS

T. Fehlner, Chang-Soo Jun, A. Bandyopadhyay, 1996 .

PREPARATION AND CHARACTERIZATION OF COBALTABORANES CONTAINING COBALT CARBONYL FRAGMENTS

T. Fehlner, A. Rheingold, J. Halet, 1995 .

Which Metallaborane, B2H5FeCo(CO)6 or B2H6Fe2(CO)6, Has the Higher Broensted Acidity?

T. Fehlner, Chang-Soo Jun, 1994 .

Ferraborane Cluster Chemistry: Reactions of [(μ-H)Fe3(CO)9BH3]-with Lewis Bases Leading to Substitution via H2Elimination or to Cluster Degradation.

T. Fehlner, C. Housecroft, 1986 .

The relevance of boranes and metallaboranes to the structures of p-block element nanoparticles

T. Fehlner, 2009 .

Electronic and steric control of the formation of C-H-M from M-H-M interactions in carbon-atom-capped transition metal carbonyl clusters. Effect of the metal fragment

T. Fehlner, R. Barreto, J. Puga, 1990 .

Tautomerization involving M―H―M and C―H―M interactions in capped trimetal clusters. Promotion of the C―H―M interaction in a mixed-metal cluster

T. Fehlner, R. Barreto, 1988 .

Synthesis and characterization of [exo-BH2(Cp*M)2B9H14] (M = Ru, Re), and the conversion of the ruthenaborane into [(Cp*Ru)2B10H16] with an open cluster framework based on a capped truncated tetrahedron.

T. Fehlner, B. Noll, Sundargopal Ghosh, 2005, Angewandte Chemie.

Routes to Compounds Containing M−B Bonds. Reaction of [Cp*FeH2]2 with BH3·THF, Yielding the Hydrogen-Rich arachno-Ferrapentaborane 1-Cp*FeB4H11 (Cp* = η5-C5Me5)

T. Fehlner, A. A. Beatty, Melanie A. Peldo, 2002 .

SEARCH FOR A GENERAL ROUTE TO METALLABORANES VIA THE REACTION OF MONOCYCLOPENTADIENYL METAL CHLORIDES WITH MONOBORANE. SYNTHESIS AND REACTIVITY OF THE RHODABORANE NIDO-1-CL-2,3-(ETA 5-C5ME5)RH2B3H6

T. Fehlner, X. Lei, M. Shang, 1998 .

Borane mimics of classic organometallic compounds: [(Cp*Ru)B8H14(RuCp*)]0,+, isoelectronic analogues of dinuclear pentalene complexes.

T. Fehlner, B. Noll, Sundargopal Ghosh, 2005, Angewandte Chemie.

Symmetrical Scission of the Coordinated Tetraborane in [(Cp*ReH2)2B4H4] on CO Addition and Reassociation of the Coordinated Diboranes on H2 Loss

T. Fehlner, Sundargopal Ghosh, C. Cahill, 2000 .

Molecular Models of Solid State Metal Boride Structures

Thomas P. Fehlner, T. Fehlner, 2000 .

Triborane. A transition metal ligand or heterocluster fragment

T. Fehlner, C. Housecroft, 1982 .

Preparation of [B5H3(CO)2Fe(CO)3]. A ferraborane analogue of B6H62–

T. Fehlner, J. Ulman, 1976 .

Binary Thin Films from Molecular Precursors

T. Fehlner, G. Long, Chang-Soo Jun, 1992 .

Incorporation of a complexed hydridoaluminum (AlH) fragment into a metallacycle. Preparation and characterization of CpCoC4Ph4AlH.cntdot.NEt3

T. Fehlner, A. Aradi, F. Hong, 1991 .

COUPLING OF A ETA 5-BOROLE COMPLEX VIA A B-O-B LINK BY REACTION OF THE B-BR DERIVATIVE WITH KOH. X-RAY STRUCTURE OF 1-ETA 5-(2,3,4,5-PH4C4B)ETA 5-(C5 H5)CO2O

T. Fehlner, A. Rheingold, F. Hong, 1991 .

Conversion of an unsaturated metallacycle into a carbon-rich nido-metallacarborane. The BH fragment as a cluster functional group

T. Fehlner, C. Eigenbrot, F. Hong, 1989 .

Properties of a mixed-valence (Fe(II))2(Fe(III))2 square cell for utilization in the quantum cellular automata paradigm for molecular electronics.

Jieying Jiao, Gary J Long, Fernande Grandjean, 2005, Journal of the American Chemical Society.

Synthesis and Characterization of (Cp*Ru)3Co(CO)2(μ3-CO)B3H3 (Cp* = η5-C5Me5): A Metallaborane with Cubane Cluster Structure

T. Fehlner, X. Lei, and Maoyu Shang, 2000 .

Synthesis and reactivity of the metal-substituted borane (CO)4CoBH2.cntdot.THF. Preparation of the ambiphilic clusters (CO)9Co3C(CH2)nOH (n = 4,5)

T. Fehlner, A. Aradi, C. Eigenbrot, 1990 .

Preparation and mass spectrometry of triphosphine-5

T. Fehlner, 1968 .

Preparation of an iron-nitride film from a molecular tetrairon nitrido cluster

O. A. Pringle, F. P. Fehlner, T. Fehlner, 1990 .

Reaction of nido-1,2-(Cp∗RuH)2B3H7 with ethynylferrocene to yield new metallacarboranes

T. Fehlner, Hong Yan, B. Noll, 2006 .

Reactions of nido-1,2-(Cp*RuH)2B3H7 with RCCR′ (R, R′=H, Ph; Me, Me) to yield novel metallacarboranes

T. Fehlner, A. Beatty, Hong Yan, 2003 .

PROTONATION OF CLUSTER MOLECULES: BRIDGING HYDROGEN SITES IN TETRAHEDRAL, OCTAHEDRAL AND CAPPED SQUARE PYRAMIDAL CLUSTERS: BE4H8, B4H8, B6H7- AND B6H8 AS MAIN GROUP MODELS FOR TRANSITION METAL CLUSTER SYSTEMS

T. Fehlner, K. Wade, R. Stramel, 1985 .

Incorporation of unsaturated hydrocarbons into a borane cage. A model for the irreversible adsorption of alkynes

R. L. Dekock, T. Fehlner, C. Housecroft, 1982 .

Reaction of 2-butyne with nido-[1,2-(Cp*RuH)2B3H7]: improved kinetic control leads to metallacarboranes of novel composition and structure.

T. Fehlner, A. Beatty, Hong Yan, 2002, Angewandte Chemie.

Reactivity of Dimetallapentaboranes-nido-[Cp$\rm{^{{\ast}}_{2}}$M(2)B(3)H(7)]-with Alkynes: Insertion to Form a Ruthenacarborane (M=RuH) versus Catalytic Cyclotrimerization to Form Arenes (M=Rh) This work was supported by the National Science Foundation. Cp*=eta-C(5)Me(5).

T. Fehlner, A. Beatty, Hong Yan, 2001, Angewandte Chemie.

Reactions of (.mu.-H)3Fe3(CO)9(.mu.3-CCH3). Hydrogen displacement by CO and H2 elimination following deprotonation

T. Fehlner, Xiangsheng Meng, T. Dutta, 1987 .

The mechanism of the hydrogenation-dehydrogenation of a C2 fragment on a triiron cluster site

T. Fehlner, T. Dutta, J. Vites, 1986 .

Interaction of triruthenium dodecacarbonyl with silanols and silanolate groups. X-ray crystal structure analysis of (.mu.-H)Ru3(CO)10(.mu.-OSiEt3), a molecular analogue of a silica-supported metal cluster

D. Braga, F. Grepioni, T. Fehlner, 1990 .

The Identification of the P2H2 Molecule in the Pyrolysis of Diphosphine

T. Fehlner, 1966 .

Photoelectron spectroscopy (HeI) of the dithione, bisimine and monoimine of tetramethyl-1,3- cyclobutanedione

T. Fehlner, J. Behan, R. Johnstone, 1977 .

The Fragmentation of Some Boron Hydrides by Electron Impact

T. Fehlner, W. S. Koski, 1964 .

Relative abundances of doubly charged ions in the mass spectra of boron hydrides and some derivatives

T. Fehlner, L. Ardini, 1973 .

On the orbital interactions of three-membered rings with .pi. systems. Electronic structure of alkenylidenecyclopropanes

T. Fehlner, D. Pasto, M. Schwartz, 1976 .

Direct Detection of the Borane Molecule and the Boryl Radical by Mass Spectrometry

T. Fehlner, W. S. Koski, 1964 .

Analysis of the reactivity of alkenylidenecyclopropanes in cycloaddition reactions

T. Fehlner, J. Borchardt, D. Pasto, 1976 .

Photoelectron spectroscopy of unstable species. The PN molecule

T. Fehlner, M. Wu, 1975 .

Selective Hydrogenation of Crotonaldehyde Over Cobalt Based Self-Supported Catalysts

E. Wolf, T. Fehlner, M. Bañares, 1994 .

Photoelectron spectrum of silicon difluoride

D. W. Turner, T. Fehlner, 1974 .

Photoelectron spectroscopy of tin compounds

T. Fehlner, M. Zeller, P. A. Grutsch, 1973 .

Mass spectrometric investigation of the low-pressure pyrolysis of diborane

T. Fehlner, S. Fridmann, 1970 .

On the Mechanism for the Pyrolysis of Diborane

T. Fehlner, 1965 .

Proton Power: An Intuitive Approach to the Electronic Structures of Molecular Hydrides.

J. R. Bowser, T. Fehlner, 1988 .

Reactions of borane (BH3). III. Absolute rates of formation of the donor-acceptor adducts phosphorus trifluoride-borane (BH3PF3) and trimethylamine-borane (BH3N(CH3)3)

T. Fehlner, S. Fridmann, 1971 .

2,2′‐commo‐Bis[2‐ruthena‐nido‐1‐(η5‐pentamethylcyclopentadienyl)ruthenahexaboran(12)]: ein ungewöhnliches, Ruthenocen‐artiges Ruthenaboran mit linearem Trirutheniumfragment

T. Fehlner, X. Lei, M. Shang, 1999 .

Building blocks for the molecular expression of quantum cellular automata. Isolation and characterization of a covalently bonded square array of two ferrocenium and two ferrocene complexes.

Jieying Jiao, Gary J Long, Fernande Grandjean, 2003, Journal of the American Chemical Society.

UV PHOTOELECTRON SPECTRA AND ELECTRONIC STRUCTURE OF (η5-C5H5)(CO)2FEB2H5. COMPARISON OF THE IRON-BORON BONDING WITH THE IRON-CARBON BONDING I (CO)4FEC2H4

R. L. Dekock, T. Fehlner, C. Housecroft, 1983 .

Relative energies of metal-metal bonding and nonbonding molecular orbitals in bridged diiron complexes

T. Fehlner, E. Andersen, 1979 .

A facile equilibrium involving carbon monoxide and hydrogen molecule. The iron-hydrogen-iron bond energy in (.mu.2-H)3Fe3(CO)9(.mu.3-CCH3)

T. Fehlner, J. Vites, 1984 .

Preparation and characterization of (η5-C5H5Co)2-(μ-PPh2)B2H5: evidence for multicenter cluster bonding in σ-π vinyl transition metal complexes

T. Fehlner, A. Rheingold, Jiang Feilong, 1988 .

UV photoelectron spectra and electronic structure of (η5-C5H5)(CO)2FeB2H5. Comparison of the iron-boron bonding with the iron-carbon bonding in (CO)4FeC2H4

R. L. Dekock, T. Fehlner, C. Housecroft, 1983 .

Experimental and theoretical studies of photoelectron spectra of oxetane and some of its halogenated methyl derivatives

T. Fehlner, K. Balasubramanian, W. S. Koski, 1992 .

Experimental and Theoretical Studies of Photoelectron Spectra of Oxetane and Some of Its Halogenated Methyl Derivatives.

T. Fehlner, K. Balasubramanian, W. S. Koski, 1992 .

Synthesis and characterization of the chiral cluster Fe3(CO)9[.eta.3-B(H)C(H)C(Me)]. An unambiguous example of a transition metal-main group six atom cluster

T. Fehlner, A. Rheingold, Xiangsheng Meng, 1990 .

Preparation and NMR spectra of B5H9Fe(CO)3, an analog of hexaborane(10)

T. Fehlner, S. Shore, C. Cottrell, 1979 .

Cluster chemistry driven by ligand bulk. Significance of the synthesis of nido-1-(.eta.5-C5Me5)Co-2-(.eta.4-C5Me5H)CoB3H8 and its dehydrogenation to nido-2,4-{(.eta.5-C5Me5)Co}2B3H7

T. Fehlner, Y. Nishihara, M. Shang, 1993 .

Metallaborane reactivity. A stoichiometric mechanism for the insertion of two alkynes into an iridaborane framework via a disposable molybdenum chaperone.

T. Fehlner, B. Noll, J. Saillard, 2007, Journal of the American Chemical Society.

Synthesis of

Rui, T. Fehlner, Sundargopal Ghosh, 2001, Angewandte Chemie.

Valence level photoelectron spectra of some heavy group 4-6 diatomic molecules

T. Fehlner, M. Wu, 1976 .

Synthesis of

T. Fehlner, Sundargopal Ghosh, Yaping Li, 2001, Angewandte Chemie.