F. Thomas

发表

Nuclease and anti-proliferative activities of copper(II) complexes of N3O tripodal ligands involving a sterically hindered phenolate.

C. Philouze, N. Berthet, V. Martel-Frachet, 2013, Dalton transactions.

Toward a new generation of white phosphors for solid state lighting using glassy yttrium aluminoborates

F. Thomas, A. Hernandes, B. Viana, 2015 .

A Nanotube-Supported Dicopper Complex Enhances Pt-free Molecular H2/Air Fuel Cells

S. Cosnier, F. Thomas, A. le Goff, 2019, Joule.

Interaction of Metal Complexes with G‐Quadruplexes

T. Lavergne, F. Thomas, O. Jarjayes, 2020, Encyclopedia of Inorganic and Bioinorganic Chemistry.

Unprecedented redox-driven ligand ejection in nickel(II)-diiminosemiquinonate radical complexes.

C. Philouze, F. Thomas, N. Leconte, 2014, Chemical communications.

Geometric and Electronic Structures of Nickel(II) Complexes of Redox Noninnocent Tetradentate Phenylenediamine Ligands.

C. Philouze, F. Thomas, N. Leconte, 2016, Inorganic chemistry.

Exploiting exciton coupling of ligand radical intervalence charge transfer transitions to tune NIR absorption† †Electronic supplementary information (ESI) available: Full synthetic details, DPV data, supplementary EPR data, full UV-vis-NIR spectra for [2˙˙]2+, [4˙˙]2+, and [5˙˙]2+, 195 K UV-vis-NIR

F. Thomas, T. Storr, L. Kaake, 2017, Chemical science.

A versatile electronic hole in one-electron oxidized NiIIbis-salicylidene phenylenediamine complexes.

C. Philouze, F. Thomas, O. Jarjayes, 2007, Chemical communications.

A Diferric Peroxo Complex with an Unprecedented Spin Configuration: An S=2 System Arising from an S=5/2, 1/2 Pair

L. Que, M. Fontecave, F. Thomas, 2002 .

A singlet ground state for a cobalt(II)-anilinosalen radical complex.

C. Philouze, F. Thomas, N. Leconte, 2014, Chemical communications.

Ligand contributions to the electronic structures of the oxidized cobalt(II) salen complexes.

M. Orio, C. Philouze, H. Vezin, 2012, Inorganic chemistry.

Air-persistent monomeric (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes.

F. Thomas, G. Bertrand, A. Rheingold, 2015, Journal of the American Chemical Society.

Synthesis, Characterization, and Photocatalytic H2-Evolving Activity of a Family of [Co(N4Py)(X)](n+) Complexes in Aqueous Solution.

C. J. McAdam, M. Sliwa, G. Jameson, 2016, Inorganic chemistry.

Characterization of one-electron oxidized copper(II)-salophen-type complexes; effects of electronic and geometrical structures on reactivities.

T. Kohzuma, F. Thomas, F. Tani, 2014, Dalton transactions.

Coordination Chemistry of the Redox Non‐Innocent Ligand Bis(2‐amino‐3,5‐di‐tert‐butylphenyl)amine with Group 10 Metal Ions (Ni, Pd, Pt)

C. Philouze, F. Thomas, F. Molton, 2018 .

Oxovanadium-salen and -salan complexes as effective labels for electrochemical immunosensing: a case study for estradiol detection.

T. Noguer, F. Thomas, G. Istamboulié, 2014, Chemical communications.

Comparison between five acellular oxidative potential measurement assays performed with detailed chemistry on PM10 samples from the city of Chamonix (France)

F. Kelly, F. Thomas, F. Molton, 2017, Atmospheric Chemistry and Physics.

Copper(II) complexes of N3O tripodal ligands appended with pyrene and polyamine groups: Anti-proliferative and nuclease activities.

N. Berthet, V. Martel-Frachet, X. Ronot, 2018, Journal of inorganic biochemistry.

Ni(II) Complexes of the Redox-Active Bis(2-aminophenyl)dipyrrin: Structural, Spectroscopic, and Theoretical Characterization of Three Members of an Electron Transfer Series.

C. Philouze, F. Thomas, N. Leconte, 2017, Inorganic chemistry.

Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species.

M. Sliwa, F. Thomas, Jérôme Fortage, 2019, Inorganic chemistry.

Supramolecular control of monooxygenase reactivity in a copper(ii) cryptate.

F. Thomas, X. Ottenwaelder, L. Chaloner, 2016, Dalton transactions.

Structural and spectroscopic investigation of an anilinosalen cobalt complex with relevance to hydrogen production.

F. Neese, C. Philouze, F. Thomas, 2013, Inorganic chemistry.

Seven Reversible Redox Processes in a Self-Assembled Cobalt Pentanuclear Bis(triple-stranded helicate): Structural, Spectroscopic, and Magnetic Characterizations in the CoICoII4, CoII5, and CoII3CoIII2 Redox States.

F. Thomas, F. Molton, R. Clérac, 2020, Inorganic chemistry.

Copper Complexes of the Tetradentate N,N′ ‐Bis(2‐amino‐3,5‐di‐ tert ‐butylphenyl)‐2,2′‐diaminobiphenyl Ligand

C. Philouze, F. Thomas, N. Leconte, 2021 .

Coordination chemistry of a redox non-innocent NHC bis(phenolate) pincer ligand with nickel(II)

C. Philouze, F. Thomas, O. Jarjayes, 2018, Inorganica Chimica Acta.

Redox control of rotary motions in ferrocene-based elemental ball bearings.

F. Thomas, M. Oltean, B. Baptiste, 2012, Journal of the American Chemical Society.

Electrocatalytic O2 Reduction at a Bio-inspired Mononuclear Copper Phenolato Complex Immobilized on a Carbon Nanotube Electrode.

C. Philouze, F. Thomas, M. Holzinger, 2016, Angewandte Chemie.

Functionalizing Carbon Nanotubes with Bis(2,9-dialkyl-1,10-phenanthroline)copper(II) Complexes for the Oxygen Reduction Reaction.

C. Philouze, F. Thomas, M. Holzinger, 2022, Inorganic chemistry.

Calcein as a Fluorescent Probe for Ferric Iron

M. Fontecave, F. Thomas, G. Serratrice, 1999, The Journal of Biological Chemistry.

High‐Field EPR Study of Frozen Aqueous Solutions of Iron(III) Citrate Complexes

F. Thomas, C. Duboc, B. Barbara, 2005 .

Ten years of a biomimetic approach to the copper(II) radical site of Galactose oxidase

F. Thomas, 2007 .

Chromium Nitride Umpolung Tuned by the Locus of Oxidation.

F. Thomas, T. Storr, R. Clarke, 2022, Journal of the American Chemical Society.

Multireversible Redox Processes in a Self‐Assembled Nickel Pentanuclear Bis(Triple‐stranded Helicate): Structural and Spectroscopic Characterizations in the Ni II 5 and Ni I Ni II 4 Redox States

F. Thomas, Jérôme Fortage, J. Pécaut, 2021, ChemElectroChem.

Template-Mediated Stabilization of a DNA G-Quadruplex formed in the HIV-1 Promoter and Comparative Binding Studies.

T. Lavergne, F. Thomas, E. Defrancq, 2017, Chemistry.

Templated Formation of Discrete RNA and DNA:RNA Hybrid G-Quadruplexes and Their Interactions with Targeting Ligands.

T. Lavergne, F. Thomas, E. Defrancq, 2016, Chemistry.

One-electron oxidized nickel(II) complexes of bis and tetra(salicylidene) phenylenediamine Schiff bases: from monoradical to interacting Ni(III) ions.

C. Philouze, F. Thomas, O. Jarjayes, 2009, Dalton transactions.

Fine tuning of the oxidation locus, and electron transfer, in nickel complexes of pro-radical ligands.

C. Philouze, F. Thomas, E. saint-Aman, 2006, Chemistry.

Influence of Electron-Withdrawing Substituents on the Electronic Structure of Oxidized Ni and Cu Salen Complexes.

F. Thomas, T. Storr, Linus Chiang, 2015, Inorganic chemistry.

Valence tautomerism in octahedral and square-planar phenoxyl-nickel(II) complexes: are imino nitrogen atoms good friends?

C. Philouze, F. Thomas, E. saint-Aman, 2006, Chemistry.

Redox noninnocence of the bridge in copper(II) salophen and bis(oxamato) complexes.

M. Orio, C. Philouze, F. Thomas, 2015, Inorganic chemistry.

Reversible double oxidation and protonation of the non-innocent bridge in a nickel(II) salophen complex.

M. Orio, F. Thomas, A. Aukauloo, 2012, Inorganic chemistry.

Intramolecularly hydrogen-bonded versus copper(II) coordinated mono- and bis-phenoxyl radicals.

C. Philouze, F. Thomas, C. Duboc, 2004, Dalton transactions.

Dicopper(II) complexes of H-BPMP-type ligands: pH-induced changes of redox, spectroscopic ((19)F NMR studies of fluorinated complexes), structural properties, and catecholase activities.

C. Philouze, S. Hamman, F. Thomas, 2002, Inorganic chemistry.

The crystal structure of copper(II) complexes with N-substituted o -hydroxyacetophenone imines: R = methyl, n-octyl, benzyl, and 2-phenylethyl

F. Thomas, G. D. Andreetti, E. C. Lingafelter, 1973 .

Copper(II) complexes of N3O ligands as models for galactose oxidase: Effect of variation of steric bulk of coordinated phenoxyl moiety on the radical stability and spectroscopy

C. Philouze, F. Thomas, F. Molton, 2017, Inorganica Chimica Acta.

Copper(II) complex of a Schiff base of dehydroacetic acid: Characterization and aerobic oxidation of benzyl alcohol

C. Philouze, F. Thomas, M. Hammadi, 2016 .

An unprecedented bridging phenoxyl radical in dicopper(II) complexes: evidence for an s=3/2 spin state.

C. Philouze, F. Michel, S. Hamman, 2005, Angewandte Chemie.

Structural and spectroscopic investigations of nine-coordinate redox active lanthanide complexes with a pincer O,N,O ligand.

C. Philouze, F. Thomas, D. Luneau, 2020, Dalton transactions.

Structural snapshots of the rearrangement of the bis(di-tert-butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions.

C. Philouze, F. Thomas, N. Leconte, 2018, Dalton transactions.

Stable anilinyl radicals coordinated to nickel: X-ray crystal structure and characterization.

M. Orio, C. Philouze, F. Thomas, 2013, Chemistry.

CoIII and CuII complexes of reduced Schiff bases: Generation of phenoxyl radical species

C. Philouze, F. Thomas, O. Jarjayes, 2010 .

Mn(iv) and Mn(v)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand.

C. Philouze, F. Thomas, T. Storr, 2017, Chemical communications.

New insights into the electronic structure and reactivity of one-electron oxidized copper(II)-(disalicylidene)diamine complexes.

F. Thomas, F. Tani, T. Storr, 2012, Inorganic chemistry.

Radical localization in a series of symmetric Ni(II) complexes with oxidized salen ligands.

M. Orio, H. Vezin, F. Thomas, 2012, Chemistry.

One-electron oxidized copper(II) salophen complexes: phenoxyl versus diiminobenzene radical species.

M. Orio, C. Philouze, H. Vezin, 2012, Chemistry.

Metal Coordinated Phenoxyl Radicals

F. Thomas, 2010 .

X-ray structures of copper(II) and nickel(II) radical salen complexes: the preference of galactose oxidase for copper(II).

M. Orio, F. Neese, C. Philouze, 2010, Angewandte Chemie.

The structure of a one-electron oxidized Mn(iii)-bis(phenolate)dipyrrin radical complex and oxidation catalysis control via ligand-centered redox activity.

C. Philouze, F. Thomas, T. Storr, 2016, Dalton transactions.

Fe(III) bipyrrolidine phenoxide complexes and their oxidized analogues.

F. Thomas, T. Storr, D. Savard, 2014, Inorganic chemistry.

Effect of Distortions on the Geometric and Electronic Structures of One-Electron Oxidized Vanadium(IV), Copper(II), and Cobalt(II)/(III) Salen Complexes.

C. Philouze, F. Thomas, T. Storr, 2020, Inorganic chemistry.

Stable M(II)-Radicals and Nickel(III) Complexes of a Bis(phenol) N-Heterocyclic Carbene Chelated to Group 10 Metal Ions.

C. Philouze, F. Thomas, O. Jarjayes, 2019, Inorganic chemistry.

Ligand-centred oxidative chemistry in sterically hindered salen complexes: an interesting case with nickel.

F. Thomas, 2016, Dalton transactions.

Complexes of the Bis(di-tert -butyl-aniline)amine Pincer Ligand: The Case of Copper

C. Philouze, F. Thomas, A. le Goff, 2020 .

Co(II), Ni(II), Cu(II) and Zn(II) complexes of a bipyridine bis-phenol conjugate: generation and properties of coordinated radical species.

C. Philouze, F. Thomas, O. Jarjayes, 2010, Dalton transactions.

Nickel(ii) radical complexes of thiosemicarbazone ligands appended by salicylidene, aminophenol and aminothiophenol moieties.

C. Philouze, F. Thomas, G. Gellon, 2015, Dalton transactions.

A Structurally Characterized CuIII Complex Supported by a Bis(anilido) Ligand and Its Oxidative Catalytic Activity.

C. Philouze, F. Thomas, N. Leconte, 2017, Chemistry.

Detailed Geometric and Electronic Structures of a One-Electron-Oxidized Ni Salophen Complex and Its Amido Derivatives

C. Philouze, F. Thomas, T. Storr, 2014 .

A highly active diradical cobalt(iii) catalyst for the cycloisomerization of alkynoic acids.

C. Philouze, F. Thomas, N. Leconte, 2018, Chemical communications.

Peculiar properties of homoleptic Cu complexes with dipyrromethene derivatives.

W. Dehaen, F. Thomas, E. Cauët, 2013, Dalton transactions.

A structural and functional model of galactose oxidase: control of the one-electron oxidized active form through two differentiated phenolic arms in a tripodal ligand.

F. Thomas, I. Gautier-Luneau, G. Gellon, 2002, Angewandte Chemie.

Distorted copper(II) radicals with sterically hindered salens: electronic structure and aerobic oxidation of alcohols.

C. Philouze, F. Thomas, T. Storr, 2020, Dalton transactions.

Galactose oxidase models: tuning the properties of CuII-phenoxyl radicals.

C. Philouze, S. Hamman, F. Thomas, 2003, Chemistry.

Thermodynamic and kinetic studies of the sulfonated derivative of the iron chelator TRENCAM, an analog of enterobactin

F. Thomas, G. Serratrice, J. Pierre, 1999 .

Galactose oxidase models: insights from 19F NMR spectroscopy.

C. Philouze, F. Michel, S. Hamman, 2009, Dalton transactions.

Galactose Oxidase Models: Creation and Modification of Proton Transfer Coupled to Copper(II) Coordination Processes in Pro-Phenoxyl Ligands

C. Philouze, F. Michel, S. Hamman, 2006 .

Protonation of the oxygen axial ligand in galactose oxidase model compounds as seen with high resolution X-ray emission experiments and FEFF simulations.

B. Weckhuysen, S. Hamman, F. Thomas, 2011, Physical chemistry chemical physics : PCCP.

Ligand-centered redox activity in cobalt(II) and nickel(II) bis(phenolate)-dipyrrin complexes.

C. Philouze, F. Thomas, T. Storr, 2012, Chemistry.

Kinetics of Aqueous Acid Hydrolysis of Iron(III) 5-Substituted-8-Hydroxyquinoline Complexes: Mechanistic Implications

F. Thomas, H. Boukhalfa, G. Serratrice, 2002 .

Thermically and electrochemically induced isomerization of a (bis(ferrocene)-cyclam)copper(II) complex.

F. Thomas, C. Bucher, S. Torelli, 2003, Inorganic chemistry.

Ten years of a biomimetic approach to the copper(II) radical site of Galactose oxidase

F. Thomas, 2007 .

Up to four phenoxyl radicals coordinated to two metal ions in copper and zinc complexes?

C. Philouze, F. Thomas, E. saint-Aman, 2007, Dalton transactions.

Pseudo‐Octahedral Schiff Base Nickel(II) Complexes: Does Single Oxidation Always Lead to the Nickel(III) Valence Tautomer?

C. Philouze, F. Thomas, V. Labet, 2008 .

Sulfide oxidation by hydrogen peroxide catalyzed by iron complexes: two metal centers are better than one.

L. Que, M. Fontecave, F. Thomas, 2002, Chemistry.

Homolytic C–H bond cleavage (H-atom transfer): chemistry for a paramount biological process

F. Thomas, J. Pierre, 2005 .

Calix[4]phyrin based redox architectures: towards new molecular tools for electrochemical sensing.

F. Thomas, C. H. Devillers, C. Bucher, 2005, Dalton transactions.

Redox-responsive porphyrin-based molecular tweezers.

F. Thomas, M. Retegan, C. Bucher, 2012, Chemistry.

New 8-hydroxyquinoline and catecholate iron chelators: influence of their partition coefficient on their biological activity.

G. Lescoat, R. Crichton, F. Thomas, 2001, Biochemical pharmacology.

Synthesis and iron(III) complexing ability of CacCAM, a new analog of enterobactin possessing a free carboxylic anchor arm. Comparative studies with TRENCAM

F. Thomas, D. Imbert, G. Serratrice, 2000 .

Redox-triggered molecular movement in a multicomponent metal complex in solution and in the solid state.

F. Thomas, C. Bucher, J. Moutet, 2004, Inorganic chemistry.

A redox active switch for lanthanide luminescence in phenolate complexes.

C. Philouze, F. Thomas, L. Fédèle, 2017, Chemical communications.

Geometric and electronic structures of phenoxyl radicals hydrogen bonded to neutral and cationic partners.

M. Orio, C. Philouze, F. Thomas, 2012, Chemistry.

Partition coefficients (free ligands and their iron(III) complexes) and lipophilic behavior of new abiotic chelators. Correlation to biological activity.

F. Thomas, D. Imbert, G. Serratrice, 1999, Bioorganic & medicinal chemistry letters.

Mechanism of the Stepwise Dissociation of FeIII Complexes with Tripodal Ligands as Siderophore Models

F. Thomas, G. Serratrice, F. Biaso, 2004 .

Iron(III) chelation: Tuning of the pH dependence by mixed ligands

A. Albrecht-Gary, S. Blanc, F. Thomas, 2003 .

Efficient Inhibition of Telomerase by Nickel–Salophen Complexes

T. Lavergne, J. Mergny, F. Thomas, 2016, ChemMedChem.

Interaction of polycationic Ni(II)-salophen complexes with G-quadruplex DNA.

C. Philouze, J. Mergny, F. Thomas, 2014, Inorganic chemistry.

Seven-coordinate lanthanide complexes with a tripodal redox active ligand: structural, electrochemical and spectroscopic investigations.

C. Philouze, F. Thomas, L. Fédèle, 2018, Dalton transactions.

Copper(II)‐Coordinated α‐Azophenols: Effect of the Metal‐Ion Geometry on Phenoxyl/Phenolate Oxidation Potential and Reactivity

C. Philouze, F. Thomas, M. Gastel, 2014 .

Cobalt(III) tetraaza-macrocyclic complexes as efficient catalyst for photoinduced hydrogen production in water: Theoretical investigation of the electronic structure of the reduced species and mechanistic insight.

M. Sliwa, F. Thomas, Jérôme Fortage, 2015, Journal of photochemistry and photobiology. B, Biology.

Spin interaction in octahedral zinc complexes of mono- and diradical Schiff and mannich bases.

M. Orio, F. Neese, C. Philouze, 2010, Inorganic chemistry.

Galactose Oxidase models: 19F NMR as a powerful tool to study the solution chemistry of tripodal ligands in the presence of copper(II).

C. Philouze, F. Michel, S. Hamman, 2006, Chemical communications.

Galactose oxidase models: solution chemistry, and phenoxyl radical generation mediated by the copper status.

F. Michel, S. Hamman, F. Thomas, 2004, Chemistry.

Lanthanide complexes as redox and ROS/RNS probes: A new paradigm that makes use of redox-reactive and redox non-innocent ligands

F. Thomas, D. Leguerrier, J. K. Molloy, 2021 .

Structural and spectroscopic investigations of redox active seven coordinate luminescent lanthanide complexes

C. Philouze, F. Thomas, L. Fédèle, 2018, Inorganica Chimica Acta.

Cyclodecapeptides to mimic the radical site of tyrosyl‐containing proteins

S. Hamman, F. Thomas, D. Boturyn, 2006, Journal of peptide science : an official publication of the European Peptide Society.

Radicals of Free and Zinc(II)‐Coordinated α‐Azophenols

M. Orio, C. Philouze, F. Thomas, 2011 .

Unsymmetrical one-electron oxidized Ni(II)-bis(salicylidene) complexes: a protonation-induced shift of the oxidation site.

M. Orio, F. Neese, F. Thomas, 2010, Chemical communications.

Single-Oxidation of Ni(II) Complexes of Bidentate Fused N-Heterocyclic Carbene–Phenol Conjugates

C. Philouze, F. Thomas, T. Storr, 2023, Organometallics.

Synthesis and Characterization of Bis-1,2,3-Triazole Ligand and its Corresponding Copper Complex for the Development of Electrochemical Affinity Biosensors.

T. Noguer, C. Philouze, F. Thomas, 2021, Chemistry.

Substituent Effects in Carbon-Nanotube-Supported Copper Phenolato Complexes for Oxygen Reduction Reaction.

C. Philouze, F. Thomas, A. le Goff, 2021, Inorganic chemistry.

Luminescent pro-nitroxide lanthanide complexes for the detection of reactive oxygen species.

F. Thomas, L. Fédèle, J. K. Molloy, 2019, Chemical communications.

How single and bifurcated hydrogen bonds influence proton-migration rate constants, redox, and electronic properties of phenoxyl radicals.

S. Hamman, F. Thomas, C. Duboc, 2004, Angewandte Chemie.

Electronic Structure and Reactivity of One-Electron-Oxidized Copper(II) Bis(phenolate)-Dipyrrin Complexes.

C. Philouze, F. Thomas, T. Storr, 2018, Inorganic Chemistry.

Radical complexes of nickel(II)/copper(II) and redox non-innocent MB-DIPY ligands: unusual stability and strong near-infrared absorption at lmax ~1300 nm.

F. Thomas, V. Nemykin, David E. Herbert, 2022, Chemistry.

Seven-coordinate lanthanide complexes with a tripodal redox active ligand: structural, electrochemical and spectroscopic investigations.

C. Philouze, F. Thomas, L. Fédèle, 2018, Dalton transactions.

Lanthanide complexes of DOTA-nitroxide conjugates for redox imaging: spectroelectrochemistry, CEST, relaxivity, and cytotoxicity.

C. Philouze, V. Martel-Frachet, F. Thomas, 2021, Dalton transactions.