David K. Smith

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High-tech applications of self-assembling supramolecular nanostructured gel-phase materials: from regenerative medicine to electronic devices.

David K Smith, Andrew R. Hirst, B. Escuder, 2008, Angewandte Chemie.

Polyglycerol-based amphiphilic dendrons as potential siRNA carriers for in vivo applications.

R. Einspanier, S. Sharbati, R. Haag, 2014, Journal of materials chemistry. B.

Shape-persistent and adaptive multivalency: rigid transgeden (TGD) and flexible PAMAM dendrimers for heparin binding.

Maurizio Fermeglia, Sabrina Pricl, Paola Posocco, 2014, Chemistry.

Hydrophobically modified dendrons: developing structure-activity relationships for DNA binding and gene transfection.

Maurizio Fermeglia, Sabrina Pricl, Paola Posocco, 2011, Molecular pharmaceutics.

Less is more – multiscale modelling of self-assembling multivalency and its impact on DNA binding and gene delivery

Sabrina Pricl, David K. Smith, Paola Posocco, 2010 .

Quantifying the effect of surface ligands on dendron-DNA interactions: insights into multivalency through a combined experimental and theoretical approach.

Sabrina Pricl, Giovanni M Pavan, Andrea Danani, 2010, Chemistry.

Synergistic effects on gene delivery--co-formulation of small disulfide-linked dendritic polycations with Lipofectamine 2000.

J. Hardy, David K. Smith, D. W. Pack, 2009, Organic & biomolecular chemistry.

Modeling the multivalent recognition between dendritic molecules and DNA: understanding how ligand "sacrifice" and screening can enhance binding.

Sabrina Pricl, Giovanni M Pavan, Andrea Danani, 2009, Journal of the American Chemical Society.

Synergistic effects in gene delivery-a structure-activity approach to the optimisation of hybrid dendritic-lipidic transfection agents.

Daniel W Pack, David K Smith, David K. Smith, 2008, Chemical communications.

Enantiomeric and Diastereomeric Self-Assembled Multivalent Nanostructures: Understanding the Effects of Chirality on Binding to Polyanionic Heparin and DNA.

E. Laurini, S. Pricl, David K. Smith, 2018, Angewandte Chemie.

Degradable self-assembling dendrons for gene delivery: experimental and theoretical insights into the barriers to cellular uptake.

R. Haag, S. Pricl, M. Calderón, 2011, Journal of the American Chemical Society.

Dendron-stabilised gold nanoparticles: generation dependence of core size and thermal stability

David K. Smith, C. Brennan, C. Love, 2004 .

Precisely defined protein-polymer conjugates: construction of synthetic DNA binding domains on proteins by using multivalent dendrons.

Olli Ikkala, David K. Smith, Mauri A. Kostiainen, 2007, ACS nano.

Multivalent dendrons for high-affinity adhesion of proteins to DNA.

O. Ikkala, G. Szilvay, M. Linder, 2006, Angewandte Chemie.

Ion exchange in alginate gels--dynamic behaviour revealed by electron paramagnetic resonance.

David K. Smith, V. Chechik, G. Ionita, 2015, Soft matter.

Multidomain hybrid hydrogels: spatially resolved photopatterned synthetic nanomaterials combining polymer and low-molecular-weight gelators.

David K. Smith, Babatunde O. Okesola, Daniel J. Cornwell, 2014, Angewandte Chemie.

Self-Assembling Fibrillar Networks—Supramolecular Gels

David K. Smith, David K. Smith, David K. Smith, 2012 .

Synthesis of gold nanoparticles within a supramolecular gel-phase network.

K. Wilson, David K. Smith, C. Brennan, 2005, Chemical communications.

Self‐Assembled Multivalency: Dynamic Ligand Arrays for High‐Affinity Binding

David K. Smith, Anna Barnard, 2012 .

Selective Extraction and In Situ Reduction of Precious Metal Salts from Model Waste To Generate Hybrid Gels with Embedded Electrocatalytic Nanoparticles.

David K. Smith, A. Parkin, Babatunde O. Okesola, 2016, Angewandte Chemie.

Photopatterned Multidomain Gels: Multi-Component Self-Assembled Hydrogels Based on Partially Self-Sorting 1,3:2,4-Dibenzylidene-D-sorbitol Derivatives.

David K. Smith, Oliver J. Daubney, Daniel J. Cornwell, 2015, Journal of the American Chemical Society.

Dendritic biomimicry: microenvironmental effects on tryptophan fluorescence†

David K. Smith, L. Müller, David K. Smith, 1999 .

Supramolecular gels: building bridges.

David K. Smith, David K. Smith, David K. Smith, 2010, Nature chemistry.

Dendrons with spermine surface groups as potential building blocks for nonviral vectors in gene therapy.

J. Hardy, David K. Smith, D. W. Pack, 2006, Bioconjugate chemistry.

Self‐Assembling Supramolecular Hybrid Hydrogel Beads

David K. Smith, Carmen C. Piras, P. Slavík, 2019, Angewandte Chemie.

Self‐Assembling Supramolecular Hybrid Hydrogel Beads

David K. Smith, Carmen C. Piras, P. Slavík, 2019, Angewandte Chemie.

Triggering a transient organo-gelation system in a chemically active solvent.

M. Pettersson, David K. Smith, Elina Kalenius, 2021, Chemical communications.

Self-organisation in the assembly of gels from mixtures of different dendritic peptide building blocks.

I. Hamley, Andrew R. Hirst, David K. Smith, 2007, Chemistry.

In situ aldehyde-modification of self-assembled acyl hydrazide hydrogels and dynamic component selection from complex aldehyde mixtures.

David K. Smith, S. Beckers, Sam Parkinson, 2019, Chemical communications.

Self-assembled gel tubes, filaments and 3D-printing with in situ metal nanoparticle formation and enhanced stem cell growth

P. Genever, David K. Smith, A. Kay, 2022, Chemical science.

Self-assembled low-molecular-weight gelator injectable microgel beads for delivery of bioactive agents†

P. Genever, David K. Smith, A. Kay, 2021, Chemical science.

Hybrid Self‐Assembled Gel Beads for Tuneable pH‐Controlled Rosuvastatin Delivery

David K. Smith, Carmen C. Piras, Anna K. Patterson, 2021, Chemistry.

Commercially Relevant Orthogonal Multi-Component Supramolecular Hydrogels for Programmed Cell Growth.

David K. Smith, M. D. de Jong, V. M. P. Vieira, 2018, Chemistry.

Shaping and Patterning Supramolecular Materials—Stem Cell-Compatible Dual-Network Hybrid Gels Loaded with Silver Nanoparticles

P. Genever, David K. Smith, Clare S. Mahon, 2022, ACS biomaterials science & engineering.

Multi-component hybrid hydrogels – understanding the extent of orthogonal assembly and its impact on controlled release† †Electronic supplementary information (ESI) available: Full experimental methods and further data from assays. See DOI: 10.1039/c7sc03301j Click here for additional data file.

David K. Smith, V. M. P. Vieira, Laura L. Hay, 2017, Chemical science.

Hybrid polymer and low molecular weight gels – dynamic two-component soft materials with both responsive and robust nanoscale networks

David K. Smith, Babatunde O. Okesola, Daniel J. Cornwell, 2013 .

NMR and ESR investigations of the interaction between a carboxylic acid and an amine at the focal point of L-lysine based dendritic branches.

David K. Smith, G. M. Dykes, A. Caragheorgheopol, 2004, Organic & biomolecular chemistry.

Controlled release of a dendritically encapsulated template molecule.

David K. Smith, G. M. Dykes, G. Seeley, 2002, Angewandte Chemie.

Branched ferrocene derivatives: using redox potential to probe the dendritic interior†

David K. Smith, David K. Smith, David K. Smith, 1999 .

Hierarchical assembly—dynamic gel–nanoparticle hybrid soft materials based on biologically derived building blocks

David K. Smith, I. Coates, David K. Smith, 2010 .

Dendron-protected Au nanoparticles--effect of dendritic structure on chemical stability.

David K. Smith, C. Brennan, C. Love, 2006, Journal of colloid and interface science.

Optically triggered release of DNA from multivalent dendrons by degrading and charge-switching multivalency.

O. Ikkala, David K. Smith, M. Kostiainen, 2007, Angewandte Chemie.

Dendritic hydrogen bonding receptors: enantiomerically pure dendroclefts for the selective recognition of monosaccharides

F. Diederich, David K. Smith, David K. Smith, 1998 .

Dendroclefts: Optically Active Dendritic Receptors for the Selective Recognition and Chiroptical Sensing of Monosaccharide Guests

F. Diederich, David K. Smith, A. Zingg, 1999 .

Heparin versus DNA: Chiral Preferences in Polyanion Binding to Self-Assembled Multivalent (SAMul) Nanostructures.

David K. Smith, Stephen M. Bromfield, David K. Smith, 2015, Journal of the American Chemical Society.

Comparing dendritic and self-assembly strategies to multivalency--RGD peptide-integrin interactions.

Daniel J. Welsh, David K. Smith, David K. Smith, 2011, Organic & biomolecular chemistry.

Molecular Gels – Nanostructured Soft Materials

David K. Smith, David K. Smith, 2008 .

Self-assembly of two-component gels: stoichiometric control and component selection.

I. Hamley, Andrew R. Hirst, B. Escuder, 2009, Chemistry.

Fluorescent 'two-faced' polymer wafers with embedded pyrene-functionalised gelator nanofibres.

David K. Smith, James Moffat, Jamie R Moffat, 2011, Chemical communications.

Nanostructured polymers with embedded self-assembled reactive gel networks.

David K. Smith, James Moffat, Andrew Burgess, 2008, Chemical communications.

Metastable two-component gel-exploring the gel-crystal interface.

David K. Smith, Jamie R Moffat, David K. Smith, 2008, Chemical communications.

Modular construction and hierarchical gelation of organooxotin nanoclusters derived from simple building blocks.

A. Kaeser, Andrew R. Hirst, David K. Smith, 2007, Chemical communications.

Lost in translation? Chirality effects in the self-assembly of nanostructured gel-phase materials.

David K. Smith, David K. Smith, David K. Smith, 2009, Chemical Society reviews.

Supramolecular dendritic solubilisation of a hydrophilic dye and tuning of its optical properties

David K. Smith, David K. Smith, 1999 .

Probing dendron structure and nanoscale self-assembly using computer-aided analysis of EPR spectra

David K. Smith, Anna Barnard, Simon P. Jones, 2012 .

Low-molecular-weight gelators: elucidating the principles of gelation based on gelator solubility and a cooperative self-assembly model.

I. Hamley, Andrew R. Hirst, B. Escuder, 2008, Journal of the American Chemical Society.

Anion binding at the core of branched ferrocene derivatives

David K. Smith, Diane L Stone, David K. Smith, 2003 .

Dendritic Hydrogen Bonding Receptors: Enantiomerically Pure Dendroclefts for the Selective Recognition of Monosaccharides.

F. Diederich, David K. Smith, 1999 .

Supramolecular Dendrimer Chemistry: Molecular Recognition within the Dendritic Environment

David K. Smith, F. Diederich, A. Zingg, 1999 .

Dendritic lanthanide complexes and the effect of Lewis-acid encapsulation

David K. Smith, G. M. Dykes, Diane L Stone, 2003 .

Dendritic receptors designed to bind polyanions in both organic and aqueous media.

J. Hardy, David K. Smith, C. Brennan, 2007, Organic & biomolecular chemistry.

Dendroclefts: Optically Active Dendritic Receptors for the Selective Recognition and Chiroptical Sensing of Monosaccharide Guests.

F. Diederich, David K. Smith, A. Zingg, 1999 .

Enantiomeric and Diastereomeric Self-Assembled Multivalent Nanostructures: Understanding the Effects of Chirality on Binding to Polyanionic Heparin and DNA.

E. Laurini, S. Pricl, David K. Smith, 2018, Angewandte Chemie.

Chiral recognition at self-assembled multivalent (SAMul) nanoscale interfaces - enantioselectivity in polyanion binding.

E. Laurini, S. Pricl, David K. Smith, 2016, Chemical communications.

Routes to fluoroaromatics

J. Clark, David K. Smith, 1985 .

Synthetically accessible, tunable, low-molecular-weight oligopeptide organogelators.

David K. Smith, C. Lagadec, David K. Smith, 2011, Chemical communications.

Self‐Assembled Supramolecular Hybrid Hydrogel Beads Loaded with Silver Nanoparticles for Antimicrobial Applications

David K. Smith, Clare S. Mahon, Carmen C. Piras, 2020, Chemistry.

Conductive Gels Based on Modified Agarose Embedded with Gold Nanoparticles and their Application as a Conducting Support for Shewanella Oneidensis MR‐1

David K. Smith, V. Chechik, A. Parkin, 2019, ChemElectroChem.

Syntheses of dendritic branches based on L-lysine: is the stereochemistry preserved throughout the synthesis?

David K. Smith, D. Goodall, M. Driffield, 2003, Organic & biomolecular chemistry.

Catalytic Gels for a Prebiotically Relevant Asymmetric Aldol Reaction in Water: From Organocatalyst Design to Hydrogel Discovery and Back Again

David K. Smith, P. Clarke, Anna K. Patterson, 2020, Journal of the American Chemical Society.

Double diffusion for the programmable spatiotemporal patterning of multi-domain supramolecular gels

David K. Smith, L. Schlichter, Carmen C. Piras, 2021, Chemical science.

Spatial and temporal diffusion-control of dynamic multi-domain self-assembled gels†

David K. Smith, L. Schlichter, Carmen C. Piras, 2021, Chemical science.

Photo-patterned multi-domain multi-component hybrid hydrogels.

David K. Smith, Daniel J. Cornwell, David K. Smith, 2020, Chemical communications.

Supramolecular Self-Assembly To Control Structural and Biological Properties of Multicomponent Hydrogels

A. Mata, D. Adams, David K. Smith, 2019, Chemistry of materials : a publication of the American Chemical Society.

Sequential Assembly of Mutually-Interactive Supramolecular Hydrogels and Fabrication of Multi-Domain Materials.

David K. Smith, Carmen C. Piras, David K. Smith, 2019, Chemistry.

Multi-component supramolecular gels for the controlled crystallization of drugs: synergistic and antagonistic effects

J. Buendía, L. Sánchez, David K. Smith, 2015 .

Speed versus stability – structure–activity effects on the assembly of two-component gels

David K. Smith, Stefan S Rohner, Jorge Ruíz-Olles, 2015 .

Enantioselective component selection in multicomponent supramolecular gels.

David K. Smith, W. Edwards, David K. Smith, 2014, Journal of the American Chemical Society.

Self-organisation effects in dynamic nanoscale gels self-assembled from simple mixtures of commercially available molecular-scale components

David K. Smith, W. Edwards, Michelle M. Smith, 2013 .

Self-sorting multi-gelator gels—mixing and ageing effects in thermally addressable supramolecular soft nanomaterials

David K. Smith, Michelle M. Smith, David K. Smith, 2011 .

Controlling the materials properties and nanostructure of a single-component dendritic gel by adding a second component.

J. Hardy, Andrew R. Hirst, David K. Smith, 2005, Chemical communications.

Two-component dendritic gel: effect of spacer chain length on the supramolecular chiral assembly.

M. C. Feiters, Andrew R. Hirst, David K. Smith, 2004, Langmuir : the ACS journal of surfaces and colloids.

Nanocomposite hydrogels—Controlled synthesis of chiral polyaniline nanofibers and their inclusion in agarose

A. Duhme-Klair, David K. Smith, P. Walton, 2009 .

Hybrid hydrogels loaded with palladium nanoparticles – Catalysts for environmentally-friendly Sonogashira and Heck cross-coupling reactions

David K. Smith, P. Slavík, David K. Smith, 2020 .

Prebiotic synthesis of 2-deoxy-d-ribose from interstellar building blocks promoted by amino esters or amino nitriles.

David K. Smith, P. Clarke, Nicolas Bia, 2017, Chemical communications.

Supramolecular materials.

J. Steed, D. Amabilino, David K. Smith, 2017, Chemical Society reviews.

Selective electrochemical recognition of bidentate anionic guests in competitive solvents using novel ferrocenyl thiourea and guanidinium receptors

P. Beer, M. Drew, David K. Smith, 1997 .

Quantitative and structural investigations of hydrogen bonding interactions in anion binding of mono- and 1,1′-bis-substituted aryl cobaltocenium receptors

P. Beer, M. Drew, David K. Smith, 1995 .

Dendrimers and hyperbranched polymers.

D. Yan, A. Caminade, David K. Smith, 2015, Chemical Society reviews.

Supramolecular Dendrimer Chemistry: A Journey Through the Branched Architecture

David K. Smith, François Diederich, F. Diederich, 2000 .

Transition metal cation and phosphate anion electrochemical recognition in water by new polyaza ferrocene macrocyclic ligands

P. Beer, M. Drew, David K. Smith, 1996 .

Anion Recognition by Redox-Responsive Ditopic Bis-Cobaltocenium Receptor Molecules Including a Novel Calix[4]arene Derivative That Binds a Dicarboxylate Dianion

P. Beer, M. Drew, David K. Smith, 1995 .

Tunable bis(ferrocenyl) receptors for the solution-phase electrochemical sensing of transition-metal cations

P. Beer, David K. Smith, David K. Smith, 1998 .

Robust gels created using a self-assembly and covalent capture strategy.

David K. Smith, C. Brennan, C. Love, 2005, Chemical communications.

Two-component dendritic gel: effect of stereochemistry on the supramolecular chiral assembly.

M. C. Feiters, Andrew R. Hirst, David K. Smith, 2004, Chemistry.

Self-assembled multivalent (SAMul) ligand systems with enhanced stability in the presence of human serum.

E. Laurini, D. Marson, S. Pricl, 2019, Biomaterials science.

Dendritic nanoparticles-the impact of ligand cross-linking on nanocore stability.

David K. Smith, C. Brennan, C. Love, 2007, Langmuir : the ACS journal of surfaces and colloids.

Pyrene-based heparin sensors in competitive aqueous media - the role of self-assembled multivalency (SAMul).

David K. Smith, C. W. Chan, C. Chan, 2016, Chemical communications.

Mallard blue: a high-affinity selective heparin sensor that operates in highly competitive media.

Maurizio Fermeglia, Sabrina Pricl, Paola Posocco, 2013, Journal of the American Chemical Society.

Enhanced Delivery of Neuroactive Drugs via Nasal Delivery with a Self‐Healing Supramolecular Gel

David K. Smith, Khuloud T Al Jamal, J. Wang, 2021, Advanced science.

Tuning gelled lyotropic liquid crystals (LLCs) - probing the influence of different low molecular weight gelators on the phase diagram of the system H2O/NaCl-Genapol LA070.

David K. Smith, J. V. van Esch, C. Stubenrauch, 2019, Soft matter.

Is variety the spice of life? Multiscale molecular simulations support experiments in nanocarrier/nucleic acid systems design

Maurizio Fermeglia, Sabrina Pricl, David K. Smith, 2010 .

Mallard Blue binding to heparin, its SDS micelle-driven de-complexation, and interaction with human serum albumin: A combined experimental/modeling investigation

Maurizio Fermeglia, Sabrina Pricl, David K. Smith, 2017, Fluid Phase Equilibria.

Supramolecular dendrimer chemistry: using dendritic crown ethers to reversibly generate functional assemblies

David K. Smith, David K. Smith, Graham M. Dykes, 2003 .

Exploring molecular recognition pathways in one- and two-component gels formed by dendritic lysine-based gelators

J. Hardy, Andrew R. Hirst, David K. Smith, 2012 .

Cation-responsive silver-selective organogel-exploiting silver-alkene interactions in the gel-phase.

David K. Smith, W. Edwards, David K. Smith, 2012, Chemical communications.

Supramolecular Dendrimer Chemistry: Using Dendritic Crown Ethers to Reversibly Generate Functional Assemblies.

David K. Smith, G. M. Dykes, 2003 .

Rapid screening of binding constants by calibrated competitive 1H NMR spectroscopy.

David K. Smith, G. M. Dykes, R. E. Heath, 2003, Chemistry.

Ferrocene encapsulated within symmetric dendrimers: a deeper understanding of dendritic effects on redox potential.

David K. Smith, P. Mcgrail, Diane L Stone, 2002, Journal of the American Chemical Society.

Supramolecular dendritic two-component gel

David K. Smith, G. M. Dykes, P. Mcgrail, 2001 .

Self-assembly using dendritic building blocks - towards controllable nanomaterials

David K. Smith, J. Hardy, Andrew R. Hirst, 2005 .

Solvent effects on supramolecular gel-phase materials: two-component dendritic gel.

Andrew R. Hirst, David K. Smith, David K. Smith, 2004, Langmuir : the ACS journal of surfaces and colloids.

One-component gels based on peptidic dendrimers: dendritic effects on materials properties.

Andrew R. Hirst, David K. Smith, C. Brennan, 2004, Langmuir : the ACS journal of surfaces and colloids.

Two-component dendritic gels: easily tunable materials.

M. C. Feiters, Andrew R. Hirst, David K. Smith, 2003, Journal of the American Chemical Society.

Dendrimers and the double helix--from DNA binding towards gene therapy.

David K. Smith, David K. Smith, 2008, Current topics in medicinal chemistry.