T. Cantat

发表

Complete Catalytic Deoxygenation of CO2 into Formamidine Derivatives

O. Jacquet, Christophe Das Neves Gomes, M. Ephritikhine, 2013 .

Evidence for the involvement of 5f orbitals in the bonding and reactivity of organometallic actinide compounds: thorium(IV) and uranium(IV) bis(hydrazonato) complexes.

B. Scott, C. Graves, T. Cantat, 2008, Journal of the American Chemical Society.

Recycling of carbon and silicon wastes: room temperature formylation of N-H bonds using carbon dioxide and polymethylhydrosiloxane.

O. Jacquet, M. Ephritikhine, T. Cantat, 2012, Journal of the American Chemical Society.

A copper(I)-catalyzed sulfonylative Hiyama cross-coupling.

T. Cantat, P. Thuéry, J. Berthet, 2021, Chemistry.

CO2 Conversion into Esters by Fluoride-Mediated Carboxylation of Organosilanes and Halide Derivatives.

G. Lefèvre, T. Cantat, P. Thuéry, 2016, Chemistry.

Efficient reductive depolymerization of hardwood and softwood lignins with Brookhart's iridium(III) catalyst and hydrosilanes

T. Cantat, J. Berthet, Louis Monsigny, 2018 .

Convergent reductive depolymerization of wood lignin to isolated phenol derivatives by metal-free catalytic hydrosilylation

T. Cantat, P. Thuéry, G. Carrot, 2015 .

Uranium(IV) Nucleophilic Carbene Complexes

M. Ephritikhine, T. Cantat, P. Thuéry, 2011 .

Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative.

T. Cantat, M. Geoffroy, P. le Floch, 2008, Chemical communications.

The Role of (tBuPOCOP)Ir(I) and iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes

T. Cantat, P. Thuéry, J. Berthet, 2021, Organometallics.

Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives

A. Tlili, T. Cantat, Xavier Frogneux, 2015 .

Reactivity and Structural Diversity in the Reaction of Guanidine 1,5,7-Triazabicyclo[4.4.0]dec-5-ene with CO2, CS2, and Other Heterocumulenes

G. Lefèvre, M. Ephritikhine, T. Cantat, 2017 .

Experimental and theoretical study of phosphinine sulfides

T. Cantat, Audrey Moores, P. Floch, 2007 .

Photocatalytic deoxygenation of N–O bonds with rhenium complexes: from the reduction of nitrous oxide to pyridine N-oxides

T. Cantat, P. Thuéry, Marianne Kjellberg, 2021, Chemical Science.

Additive-free selective methylation of secondary amines with formic acid over a Pd/In2O3 catalyst

T. Cantat, M. Pinault, Caroline Genre, 2022, Catalysis Science & Technology.

Transition‐Metal‐Free Carbon Isotope Exchange of Phenyl Acetic Acids

T. Cantat, L. Kingston, C. Elmore, 2020, Angewandte Chemie.

Arene-Bridged Dithorium Complexes: Inverse Sandwiches Supported by a δ Bonding Interaction.

Wenliang Huang, G. Lefèvre, T. Cantat, 2020, Journal of the American Chemical Society.

Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex

T. Cantat, P. Thuéry, E. Nicolas, 2020, Organometallics.

Synthesis, structure and electrochemical behavior of new RPONOP (R = tBu, iPr) pincer complexes of Fe2+, Co2+, Ni2+, and Zn2+ ions

G. Lefèvre, T. Cantat, P. Thuéry, 2016 .

Nitrite complexes of the rare earth elements.

T. Cantat, P. Thuéry, J. Berthet, 2014, Dalton transactions.

Uranium azide photolysis results in C-H bond activation and provides evidence for a terminal uranium nitride.

B. Scott, T. Cantat, E. Batista, 2010, Nature chemistry.

Coupling electrocatalytic CO2 reduction with thermocatalysis enables the formation of a lactone monomer.

M. Fontecave, T. Cantat, N. Tran, 2021, ChemSusChem.

Catalytic challenges and strategies for the carbonylation of σ-bonds

T. Cantat, E. Nicolas, Louise Ponsard, 2021, Green Chemistry.

Copper–Ligand Cooperativity in H2 Activation Enables the Synthesis of Copper Hydride Complexes

T. Cantat, P. Thuéry, J. Berthet, 2021, Organometallics.

Carbon dioxide reduction to methylamines under metal-free conditions.

T. Cantat, Enguerrand Blondiaux, Jacky Pouessel, 2014, Angewandte Chemie.

Metal-free reduction of CO2 with hydroboranes: two efficient pathways at play for the reduction of CO2 to methanol.

T. Cantat, P. Thuéry, Christophe Das Neves Gomes, 2014, Chemistry.

Pushing Back the Limits of Hydrosilylation: Unprecedented Catalytic Reduction of Organic Ureas to Formamidines

O. Jacquet, T. Cantat, Jacky Pouessel, 2013 .

CO2 as a C1-building block for the catalytic methylation of amines

O. Jacquet, T. Cantat, Xavier Frogneux, 2013 .

Dynamic Carbon Isotope Exchange of Pharmaceuticals with Labeled CO2.

Elodie Marcon, T. Cantat, O. Loreau, 2018, Journal of the American Chemical Society.

A N-aryloxy-β-diketiminate ligand in 4d, 4f and 5f-metals complexes.

M. Ephritikhine, T. Cantat, P. Thuéry, 2012, Dalton transactions.

Catalytic hydrosilylation of oxalic acid: chemoselective formation of functionalized C2-products

O. Jacquet, T. Cantat, P. Thuéry, 2014 .

Creating added value with a waste: methylation of amines with CO2 and H2.

A. Tlili, T. Cantat, Xavier Frogneux, 2014, Angewandte Chemie.

Catalytic Disproportionation of Formic Acid to Methanol by using Recyclable Silylformates

T. Cantat, P. Thuéry, C. Chauvier, 2020, Angewandte Chemie.

Catalytic Disproportionation of Formic Acid to Methanol using Recyclable Silylformates.

T. Cantat, P. Thuéry, C. Chauvier, 2020, Angewandte Chemie.

A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide

B. Scott, C. Graves, T. Cantat, 2008 .

Phosphorus-Stabilized Geminal Dianions

T. Cantat, L. Ricard, A. L. Floch, 2006 .

Bimetallic cleavage of aromatic C-H bonds by rare-earth-metal complexes.

Wenliang Huang, T. Cantat, Saeed I. Khan, 2014, Journal of the American Chemical Society.

Reduction of Secondary Amides to Imines Catalysed by Schwartz’s Reagent

T. Cantat, J. Berthet, Liam J Donnelly, 2022 .

Structural and kinetic effects of chloride ions in the palladium-catalyzed allylic substitutions

T. Cantat, A. Jutand, E. Génin, 2003 .

Activation of SO2 by N/Si+ and N/B Frustrated Lewis Pairs: Experimental and Theoretical Comparison with CO2 Activation.

G. Lefèvre, T. Cantat, P. Thuéry, 2019, Chemistry.

A bis(thiophosphinoyl)methanediide palladium complex: coordinated dianion or nucleophilic carbene complex?

T. Cantat, Y. Jean, P. le Floch, 2004, Angewandte Chemie.

Cover Picture: A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2 (Angew. Chem. Int. Ed. 1/2012)

Olivier Jacquet, Claude Villiers, Pierre Thuéry, 2012 .

Efficient metal-free hydrosilylation of tertiary, secondary and primary amides to amines.

T. Cantat, Enguerrand Blondiaux, 2014, Chemical communications.

Nitrite complexes of uranium and thorium.

M. Ephritikhine, T. Cantat, P. Thuéry, 2013, Chemical communications.

Redox control of a polymerization catalyst by changing the oxidation state of the metal center.

Tianpin Wu, Jeffrey T. Miller, T. Cantat, 2011, Chemical communications.

Synthesis of N-Aryloxy-β-diketiminate Ligands and Coordination to Zirconium, Ytterbium, Thorium, and Uranium

M. Ephritikhine, T. Cantat, P. Thuéry, 2013 .

The U=C double bond: synthesis and study of uranium nucleophilic carbene complexes.

M. Ephritikhine, T. Cantat, P. Thuéry, 2009, Journal of the American Chemical Society.

Coordination Behavior of the S–C–S Monoanion and O–C–O and S–C–S Dianions toward CoII

T. Cantat, Hadrien Heuclin, P. Floch, 2011 .

Synthesis, Reactivity, and DFT Studies of S−C−S Zirconium(IV) Complexes

T. Cantat, P. Floch, L. Ricard, 2006 .

Thulium Alkylidene Complexes: Synthesis, X-ray Structures, and Reactivity

T. Cantat, F. Jaroschik, P. Floch, 2006 .

A bis(thiophosphinoyl)methylene ruthenium carbene complex : Synthesis, X-ray crystal structure, and DFT calculations of its thermally promoted reverse α-hydride migration process

T. Cantat, Y. Jean, P. Floch, 2005 .

Convenient access to the anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2) and ThCl(4)(THF)(3.5) using commercially available and inexpensive starting materials.

B. Scott, T. Cantat, J. Kiplinger, 2010, Chemical communications.

Implications of CO2 Activation by Frustrated Lewis Pairs in the Catalytic Hydroboration of CO2: A View Using N/Si+ Frustrated Lewis Pairs

Jean-Claude Berthet, Pierre Thuéry, G. Lefèvre, 2016 .

Metal-free acceptorless decarbonylation of formic acid enabled by a liquid chemical looping strategy.

G. Lefèvre, T. Cantat, Arnaud Imberdis, 2019, Angewandte Chemie.

Carbonylation of C-N Bonds in Tertiary Amines Catalyzed by Low Valent Iron Catalysts.

T. Cantat, J. Berthet, E. Nicolas, 2019, Angewandte Chemie.

Carbonylation of C−N Bonds in Tertiary Amines Catalyzed by Low‐Valent Iron Catalysts

T. Cantat, J. Berthet, E. Nicolas, 2019, Angewandte Chemie.

Bridging Amines with CO2: Organocatalyzed Reduction of CO2 to Aminals

Pierre Thuéry, T. Cantat, P. Thuéry, 2015 .

Breaking C–O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes

T. Cantat, P. Thuéry, J. Berthet, 2019, ACS Catalysis.

Titelbild: A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2 (Angew. Chem. 1/2012)

O. Jacquet, M. Ephritikhine, T. Cantat, 2012 .

Bis-phosphorus stabilised carbene complexes.

T. Cantat, P. le Floch, N. Mézailles, 2008, Dalton transactions.

From a stable dianion to a stable carbenoid.

T. Cantat, X. L. Le Goff, P. le Floch, 2007, Angewandte Chemie.

UI4(1,4-dioxane)2, [UCl4(1,4-dioxane)]2, and UI3(1,4-dioxane)1.5: Stable and Versatile Starting Materials for Low- and High-Valent Uranium Chemistry

Marisa J. Monreal, B. Scott, T. Cantat, 2011 .

Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

T. Cantat, Nora Hellou, R. Romero, 2022, Chemical communications.

A Viewpoint on Chemical Reductions of Carbon–Oxygen Bonds in Renewable Feedstocks Including CO2 and Biomass

T. Cantat, Thibault Cantat, Clément Chauvier, 2017 .

Direct Carbon Isotope Exchange of Pharmaceuticals via Reversible Decyanation.

T. Cantat, P. Thuéry, C. Elmore, 2021, Journal of the American Chemical Society.

Metal-Free and Alkali-Metal-Catalyzed Synthesis of Isoureas from Alcohols and Carbodiimides.

G. Lefèvre, T. Cantat, P. Thuéry, 2018, Angewandte Chemie.

Complexes of the tripodal phosphine ligands PhSi(XPPh2)3 (X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2.

T. Cantat, P. Thuéry, J. Berthet, 2016, Dalton transactions.

SO2 conversion to sulfones: development and mechanistic insights of a sulfonylative Hiyama cross-coupling.

G. Lefèvre, T. Cantat, A. Adenot, 2019, Chemical communications.

Synthesis of Aromatic Sulfones from SO 2 and Organosilanes , Under Metal-free Conditions

T. Cantat, N. Wolff, Xavier Frogneux, 2019 .

Synthesis of Aromatic Sulfones from SO2 and Organosilanes Under Metal-free Conditions.

T. Cantat, Niklas von Wolff, Xavier Frogneux, 2017, Angewandte Chemie.

Actinide redox-active ligand complexes: reversible intramolecular electron-transfer in U(dpp-BIAN)2/U(dpp-BIAN)2(THF).

B. Scott, Ruilian Wu, T. Cantat, 2010, Inorganic chemistry.

A diagonal approach to chemical recycling of carbon dioxide: organocatalytic transformation for the reductive functionalization of CO2.

Olivier Jacquet, Claude Villiers, Pierre Thuéry, 2012, Angewandte Chemie.

Catalytic methylation of aromatic amines with formic acid as the unique carbon and hydrogen source.

G. Lefèvre, T. Cantat, J. Berthet, 2014, Chemical communications.

Uranyl(VI) Triflate as Catalyst for the Meerwein-Ponndorf-Verley Reaction.

T. Cantat, P. Thuéry, J. Berthet, 2021, Inorganic chemistry.

The Effect of Chloride Ions on the Mechanism of the Oxidative Addition of Cyclic Allylic Carbonates to Pd0 Complexes by Formation of Neutral[(η1‐allyl)PdClL2] Complexes

T. Cantat, R. Pleixats, A. Jutand, 2005 .

2,2'-Biphosphinines and 2,2'-bipyridines in homoleptic dianionic Group 4 complexes and neutral 2,2'-biphosphinine Group 6 d(6) metal complexes: octahedral versus trigonal-prismatic geometries.

I. Demachy, T. Cantat, Y. Jean, 2007, Chemistry.

A joint experimental and theoretical study of the palladium-catalyzed electrophilic allylation of aldehydes.

T. Cantat, P. Floch, N. Mézailles, 2007, The Journal of organic chemistry.

Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases

T. Cantat, J. Berthet, E. Nicolas, 2021, ACS Catalysis.

New mono- and bis-carbene samarium complexes: synthesis, X-ray crystal structures and reactivity.

T. Cantat, F. Jaroschik, P. le Floch, 2005, Chemical communications.

Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes.

T. Cantat, P. Thuéry, C. Chauvier, 2016, Angewandte Chemie.

A six-carbon 10π-electron aromatic system supported by group 3 metals

Wenliang Huang, Tianpin Wu, Jeffrey T. Miller, 2013, Nature Communications.

Structural Insights into the Nature of Fe0 and FeI Low-Valent Species Obtained upon the Reduction of Iron Salts by Aryl Grignard Reagents.

G. Lefèvre, T. Cantat, M. Clémancey, 2017, Inorganic chemistry.

Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates.

T. Cantat, Timothé Godou, C. Chauvier, 2017, Chemical communications.

Depolymerization of Waste Plastics to Monomers and Chemicals Using a Hydrosilylation Strategy Facilitated by Brookhart’s Iridium(III) Catalyst

T. Cantat, J. Berthet, Louis Monsigny, 2018, ACS Sustainable Chemistry & Engineering.

Room temperature organocatalyzed reductive depolymerization of waste polyethers, polyesters, and polycarbonates.

T. Cantat, Elias Feghali, 2015, ChemSusChem.

Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes.

T. Cantat, Elias Feghali, 2014, Chemical communications.

Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates

T. Cantat, P. Thuéry, Timothé Godou, 2017, Synlett.

EPR and DFT studies of the one-electron reduction product of phospholium cations.

T. Cantat, M. Geoffroy, P. le Floch, 2006, Physical chemistry chemical physics : PCCP.

Exploring the uranyl organometallic chemistry: from single to double uranium-carbon bonds.

M. Ephritikhine, T. Cantat, P. Thuéry, 2011, Journal of the American Chemical Society.

Challenging the metallocene dominance in actinide chemistry with a soft PNP pincer ligand: new uranium structures and reactivity patterns.

B. Scott, C. Graves, T. Cantat, 2009, Angewandte Chemie.

Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO2.

A. Tlili, T. Cantat, P. Thuéry, 2016, Chemical communications.

New anionic and dianionic polydentate systems featuring ancillary phosphinosulfides as ligands in coordination chemistry and catalysis

T. Cantat, M. Doux, P. Floch, 2007 .

Revisiting the chemistry of the actinocenes [(η8-C8H8)2An] (An = U, Th) with neutral Lewis bases. Access to the bent sandwich complexes [(η8-C8H8)2An(L)] with thorium (L = py, 4,4'-bipy, tBuNC, R4phen).

M. Ephritikhine, T. Cantat, J. Dognon, 2013, Journal of the American Chemical Society.

What a difference a 5f element makes: trivalent and tetravalent uranium halide complexes supported by one and two bis[2-(diisopropylphosphino)-4-methylphenyl]amido (PNP) ligands.

B. Scott, T. Cantat, J. Kiplinger, 2009, Inorganic chemistry.

Titanium(IV) Trifluoromethyl Complexes: New Perspectives on Bonding from Organometallic Fluorocarbon Chemistry

Felicia L. Taw, B. Scott, A. Clark, 2012 .

Formation and structure of a stable monoradical cation by reduction of a diphosphafulvenium salt.

T. Cantat, M. Geoffroy, P. le Floch, 2006, Angewandte Chemie.

Titanocene and zirconocene complexes of a phosphorus analog of an Arduengo's carbene: application in the synthesis of 1,3-diphosphafulvenes.

T. Cantat, P. le Floch, L. Ricard, 2004, Chemical communications.

Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines

Olivier Jacquet, O. Jacquet, T. Cantat, 2014 .

Structural Insights into the Nature of Fe 0 and Fe I Low-Valent Species Obtained upon the Reduction of Iron Salts by Aryl Grignard Reagents

G. Lefèvre, T. Cantat, M. Clémancey, 2019 .

Efficient disproportionation of formic acid to methanol using molecular ruthenium catalysts.

G. Lefèvre, T. Cantat, P. Thuéry, 2014, Angewandte Chemie.

Catalytic Metal-Free Deoxygenation of Nitrous Oxide with Disilanes

T. Cantat, E. Nicolas, Lucile Anthore-Dalion, 2019, ACS Catalysis.

Creating Added Value with a Waste: Methylation of Amines with CO2 and H2

A. Tlili, T. Cantat, Xavier Frogneux, 2014 .

Metal-free disproportionation of formic acid mediated by organoboranes

T. Cantat, P. Thuéry, C. Chauvier, 2016, Chemical science.

Metal-free dehydrogenation of formic acid to H2 and CO2 using boron-based catalysts

A. Tlili, T. Cantat, P. Thuéry, 2015, Chemical science.

Evaluation of acetophenone as a novel alcohol-cycloalkane bifunctional liquid organic hydrogen carrier (LOHC)

T. Cantat, V. Faucheux, G. Gebel, 2023, International Journal of Hydrogen Energy.

Novel carbon capture and utilisation technologies: Research and climate aspects

A. Azapagic, R. Schlögl, M. Mazzotti, 2018 .