Alexander J. M. Miller

发表

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

John E. Bercaw, Abraham Nudelman, Brian M. Stoltz, 2010 .

Catalytic disproportionation of formic acid to generate methanol.

J. Mayer, Alexander J. M. Miller, K. I. Goldberg, 2013, Angewandte Chemie.

Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO

Kyle A. Grice, C. Kubiak, J. Mayer, 2012, Proceedings of the National Academy of Sciences.

Deducing Reaction Mechanism: A Guide for Students, Researchers, and Instructors

Alexander J. M. Miller, S. Meek, Simon J. Meek, 2016 .

H2 Evolution at an Electrochemical “Underpotential” with an Iridium-Based Molecular Photoelectrocatalyst

Alexander J. M. Miller, B. Stratakes, 2020 .

Kinetics of the Trans Effect in Ruthenium Complexes Provide Insight into the Factors that Control Activity and Stability in CO2 Electroreduction.

Alexander J. M. Miller, C. Schauer, S. Gonell, 2020, Journal of the American Chemical Society.

Carbon Dioxide Electroreduction Catalyzed by Organometallic Complexes

Alexander J. M. Miller, S. Gonell, 2018 .

Efficient Photochemical Dihydrogen Generation Initiated by a Bimetallic Self-Quenching Mechanism.

Alexander J. M. Miller, M. K. Brennaman, Daniel A. Kurtz, 2016, Journal of the American Chemical Society.

Rapid water oxidation electrocatalysis by a ruthenium complex of the tripodal ligand tris(2-pyridyl)phosphine oxide

Alexander J. M. Miller, A. Walden, Andrew G. Walden, 2015, Chemical science.

Thermodynamic Hydricity of Transition Metal Hydrides.

A. Appel, Alexander J. M. Miller, R. Bullock, 2016, Chemical reviews.

Mechanism of Chemical and Electrochemical N2 Splitting by a Rhenium Pincer Complex

Alexander J. M. Miller, Christian Würtele, S. Schneider, 2018, Journal of the American Chemical Society.

Hydrogenation of carboxylic acids catalyzed by half-sandwich complexes of iridium and rhodium.

Alexander J. M. Miller, K. I. Goldberg, D. Heinekey, 2013, Journal of the American Chemical Society.

Stabilization of Ruthenium(II) Polypyridyl Chromophores on Mesoporous TiO2 Electrodes: Surface Reductive Electropolymerization and Silane Chemistry

Alexander J. M. Miller, M. K. Brennaman, T. Meyer, 2019, ACS central science.

Solvent-Dependent Thermochemistry of an Iridium/Ruthenium H2 Evolution Catalyst.

T. Cundari, Alexander J. M. Miller, C. Pitman, 2016, Inorganic chemistry.

Thermodynamic Hydricity across Solvents: Subtle Electronic Effects and Striking Ligation Effects in Iridium Hydrides

Alexander J. M. Miller, B. Stratakes, Caleb N. Jadrich, 2019, Organometallics.

Photochemical H2 Evolution from Bis(diphosphine)nickel Hydrides Enables Low-Overpotential Electrocatalysis.

F. Castellano, Alexander J. M. Miller, Daniel A. Kurtz, 2021, Journal of the American Chemical Society.

Photocatalytic Transfer Hydrogenation in Water: Insight into Mechanism and Catalyst Speciation

David M. Kaphan, K. Mulfort, Alexander J. M. Miller, 2021 .

Mechanistic basis for tuning iridium hydride photochemistry from H2 evolution to hydride transfer hydrodechlorination

Alexander J. M. Miller, Daniel A. Kurtz, J. Dempsey, 2020, Chemical science.

Photochemical Formic Acid Dehydrogenation by Iridium Complexes: Understanding Mechanism and Overcoming Deactivation

Alexander J. M. Miller, S. M. Barrett, S. Slattery, 2015 .

Molecular Photoelectrocatalysts for Visible Light-Driven Hydrogen Evolution from Neutral Water

Alexander J. M. Miller, C. Pitman, Catherine L Pitman, 2014 .

Simultaneous Electrosynthesis of Syngas and an Aldehyde from CO2 and an Alcohol by Molecular Electrocatalysis

Ying Wang, Alexander J. M. Miller, T. Meyer, 2018, ACS Applied Energy Materials.

The Trans Effect in Electrocatalytic CO2 Reduction: Mechanistic Studies of Asymmetric Ruthenium Pyridyl-Carbene Catalysts.

J. Muckerman, Alexander J. M. Miller, C. Schauer, 2019, Journal of the American Chemical Society.

Photoswitchable hydride transfer from iridium to 1-methylnicotinamide rationalized by thermochemical cycles.

Alexander J. M. Miller, C. Pitman, A. Walden, 2014, Journal of the American Chemical Society.

Potential Economic Feasibility of Direct Electrochemical Nitrogen Reduction as a Route to Ammonia

Patrick L. Holland, G. Hochman, J. Mayer, 2019, ACS Sustainable Chemistry & Engineering.

Reductive coupling of carbon monoxide in a rhenium carbonyl complex with pendant Lewis acids.

J. Bercaw, Alexander J. M. Miller, J. Labinger, 2008, Journal of the American Chemical Society.

Decarbonylative ether dissection by iridium pincer complexes†

Alexander J. M. Miller, C. Yoo, Henry M. Dodge, 2020, Chemical science.

Controlling ligand binding for tunable and switchable catalysis: cation-modulated hemilability in pincer-crown ether ligands.

Alexander J. M. Miller, 2017, Dalton transactions.

Cation-modulated reactivity of iridium hydride pincer-crown ether complexes.

Alexander J. M. Miller, Matthew R. Kita, 2014, Journal of the American Chemical Society.

Ammonia Synthesis from a Pincer Ruthenium Nitride via Metal-Ligand Cooperative Proton-Coupled Electron Transfer.

Quinton J. Bruch, Alexander J. M. Miller, F. Hasanayn, 2017, Journal of the American Chemical Society.

Dinitrogen Reduction to Ammonium at Rhenium Utilizing Light and Proton-Coupled Electron Transfer.

Quinton J. Bruch, P. Holland, Alexander J. M. Miller, 2019, Journal of the American Chemical Society.

Modulating the Elementary Steps of Methanol Carbonylation by Bridging the Primary and Secondary Coordination Spheres

Alexander J. M. Miller, P. White, Javier Grajeda, 2016 .

(Electro‐)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex

Alexander J. M. Miller, Christian Würtele, S. Schneider, 2020, European journal of inorganic chemistry.

Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel.

Alexander J. M. Miller, V. Iluc, G. Hillhouse, 2005, Chemical communications.

Arene Activation at Iridium Facilitates C–O Bond Cleavage of Aryl Ethers

W. Kaminsky, Alexander J. M. Miller, K. I. Goldberg, 2014 .

Correlating Thermodynamic and Kinetic Hydricities of Rhenium Hydrides.

N. E. Smith, Quinton J. Bruch, Alexander J. M. Miller, 2022, Journal of the American Chemical Society.

Oligomerization and polymerization of 5-ethylidene-2-norbornene by cationic palladium and nickel catalysts

Alexander J. M. Miller, M. Brookhart, Alexandra H. Farquhar, 2020 .

Mapping the Binding Modes of Hemilabile Pincer-Crown Ether Ligands in Solution Using Diamagnetic Anisotropic Effects on NMR Chemical Shift.

D. Dickie, Alexander J. M. Miller, P. White, 2017, Inorganic chemistry.

Molecular Photoelectrocatalysts for Light-Driven Hydrogen Production

Alexander J. M. Miller, Annabell G. Bonn, Kelsey R. Brereton, 2018 .

Accessing and Photo-Accelerating Low-Overpotential Pathways for CO2 Reduction: A Bis-Carbene Ruthenium Terpyridine Catalyst

Alexander J. M. Miller, Chun-Hsing Chen, S. Gonell, 2022, ACS Catalysis.

Homogeneous syngas conversion

J. Bercaw, Alexander J. M. Miller, J. Labinger, 2011 .

Temperature and Solvent Effects on H2 Splitting and Hydricity: Ramifications on CO2 Hydrogenation by a Rhenium Pincer Catalyst.

Quinton J. Bruch, Alexander J. M. Miller, Jenny Hu, 2020, Journal of the American Chemical Society.

A two-coordinate nickel imido complex that effects C−H amination.

T. Cundari, Alexander J. M. Miller, G. Hillhouse, 2011, Journal of the American Chemical Society.

Thermodynamic and kinetic hydricity of transition metal hydrides.

N. E. Smith, Alexander J. M. Miller, N. Hazari, 2020, Chemical Society reviews.

Aqueous Hydricity from Calculations of Reduction Potential and Acidity in Water.

T. Cundari, Alexander J. M. Miller, W. Jones, 2016, The journal of physical chemistry. B.

Organometallic Elaboration as a Strategy for Tuning the Supramolecular Characteristics of Aza-Crown Ethers

Alexander J. M. Miller, Chun-Hsing Chen, Alexandra H. Farquhar, 2019, Organometallics.

Trialkylborane-Assisted CO(2) Reduction by Late Transition Metal Hydrides.

J. Bercaw, Alexander J. M. Miller, J. Labinger, 2011, Organometallics.

Synthesis and C-C coupling reactivity of a dinuclear Ni(i)-Ni(i) complex supported by a terphenyl diphosphine.

T. Agapie, Alexander J. M. Miller, Sibo Lin, 2010, Journal of the American Chemical Society.

Thermodynamic Studies of Cation-Macrocycle Interactions in Nickel Pincer-Crown Ether Complexes Enable Switchable Ligation

Alexander J. M. Miller, P. White, Jacob B. Smith, 2017 .

Cation-controlled catalysis with crown ether-containing transition metal complexes.

Alexander J. M. Miller, C. Yoo, Henry M. Dodge, 2019, Chemical communications.

An Ion-Responsive Pincer-Crown Ether Catalyst System for Rapid and Switchable Olefin Isomerization.

Alexander J. M. Miller, Matthew R. Kita, 2017, Angewandte Chemie.

Long-lived and efficient emission from mononuclear amidophosphine complexes of copper.

Jillian L Dempsey, Alexander J. M. Miller, J. Dempsey, 2007, Inorganic chemistry.

Homogeneous CO hydrogenation: dihydrogen activation involves a frustrated Lewis pair instead of a platinum complex.

J. Bercaw, Alexander J. M. Miller, J. Labinger, 2010, Journal of the American Chemical Society.

Identifying and Evading Olefin Isomerization Catalyst Deactivation Pathways Resulting from Ion-Tunable Hemilability

Alexander J. M. Miller, Chun-Hsing Chen, Henry M. Dodge, 2020 .

Cation-Controlled Olefin Isomerization Catalysis with Palladium Pincer Complexes

Alexander J. M. Miller, Chun-Hsing Chen, Alexandra H. Farquhar, 2022, Organometallics.

A bis(arylphosphinito)amide pincer ligand that binds nickel forming six-membered metallacycles

Quinton J. Bruch, Alexander J. M. Miller, 2020 .

Connecting Neutral and Cationic Pathways in Nickel-Catalyzed Insertion of Benzaldehyde into a C-H Bond of Acetonitrile

Alexander J. M. Miller, Jacob B. Smith, 2015 .

Synthesis and characterization of three-coordinate Ni(III)-imide complexes.

Marisa J. Monreal, Alexander J. M. Miller, M. Monreal, 2011, Journal of the American Chemical Society.

Dehydrogenation of amine-boranes with a frustrated Lewis pair.

J. Bercaw, Alexander J. M. Miller, 2010, Chemical communications.

Selecting Double Bond Positions with a Single Cation-Responsive Iridium Olefin Isomerization Catalyst.

T. Blackburn, Alexander J. M. Miller, Chun-Hsing Chen, 2020, Journal of the American Chemical Society.

Diverse Cation-Promoted Reactivity of Iridium Carbonyl Pincer-Crown Ether Complexes

Alexander J. M. Miller, P. White, Javier Grajeda, 2016 .

Catalytic Dehydrogenation of Alkanes by PCP–Pincer Iridium Complexes Using Proton and Electron Acceptors

T. Emge, Alexander J. M. Miller, A. Goldman, 2021 .

Electrochemical C–H bond activation via cationic iridium hydride pincer complexes† †Electronic supplementary information (ESI) available. CCDC 1935784, 1935785 and 1935786. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc03076j

Alexander J. M. Miller, A. Goldman, Chun-Hsing Chen, 2019, Chemical science.

Thermodynamic studies of [H(2)Rh(diphosphine)(2)](+) and [HRh(diphosphine)(2)(CH(3)CN)](2+) complexes in acetonitrile.

Aaron D. Wilson, J. Bercaw, D. Dubois, 2010, Inorganic chemistry.

Excited-State Switching between Ligand-Centered and Charge Transfer Modulated by Metal-Carbon Bonds in Cyclopentadienyl Iridium Complexes.

F. Castellano, Alexander J. M. Miller, E. Jakubikova, 2018, Inorganic chemistry.

Aqueous Hydricity of Late Metal Catalysts as a Continuum Tuned by Ligands and the Medium

Alexander J. M. Miller, C. Pitman, Kelsey R. Brereton, 2016, Journal of the American Chemical Society.

Probing the electronic structures of [Cu2(mu-XR2)]n+ diamond cores as a function of the bridging X atom (X = N or P) and charge (n = 0, 1, 2).

Alexander J. M. Miller, N. Mankad, J. Peters, 2008, Journal of the American Chemical Society.

Considering Electrocatalytic Ammonia Synthesis via Bimetallic Dinitrogen Cleavage

Quinton J. Bruch, P. Holland, Alexander J. M. Miller, 2020 .

Stepwise Iodide-Free Methanol Carbonylation via Methyl Acetate Activation by Pincer Iridium Complexes.

Alexander J. M. Miller, C. Yoo, 2021, Journal of the American Chemical Society.

E-type delayed fluorescence of a phosphine-supported Cu2(mu-NAr2)2 diamond core: harvesting singlet and triplet excitons in OLEDs.

Alexander J. M. Miller, D. Giesen, S. Switalski, 2010, Journal of the American Chemical Society.

Synthesis and Characterization of Stable Gold(III) PNP Pincer Complexes

Quinton J. Bruch, D. Wragg, Alexander J. M. Miller, 2018 .

Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid-Assisted Reductive Coupling of Carbon Monoxide

J. Bercaw, Alexander J. M. Miller, J. Labinger, 2010 .

Determining the Overpotential of Electrochemical Fuel Synthesis Mediated by Molecular Catalysts: Recommended Practices, Standard Reduction Potentials, and Challenges

Alexander J. M. Miller, J. Dempsey, B. Stratakes, 2021, ChemElectroChem.

Using combinations of oxidants and bases as PCET reactants: thermochemical and practical considerations

J. Mayer, Alexander J. M. Miller, T. Tronic, 2012 .

α-l-Formamidinoglutaric acid as a formylating agent☆

Alexander J. M. Miller, H. Waelsch, 1955 .

Bathochromic Shifts in Rhenium Carbonyl Dyes Induced through Destabilization of Occupied Orbitals.

Jillian L Dempsey, Alexander J. M. Miller, Daniel A. Kurtz, 2018, Inorganic chemistry.

Spatiotemporal control for integrated catalysis

Dunwei Wang, Alexander J. M. Miller, Chong Liu, 2023, Nature Reviews Methods Primers.

Polyketones from Carbon Dioxide and Ethylene by Integrating Electrochemical and Organometallic Catalysis

Dunwei Wang, Alexander J. M. Miller, Benjamin S. Natinsky, 2023, ACS Catalysis.

Evaluating the Thermodynamics of Electrocatalytic N2 Reduction in Acetonitrile

J. Mayer, A. Appel, Alexander J. M. Miller, 2016 .

Let’s Talk About Safety: Open Communication for Safer Laboratories

Ian A. Tonks, Alexander J. M. Miller, 2018, Organometallics.

Understanding Terminal versus Bridging End-on N2 Coordination in Transition Metal Complexes.

P. Holland, Alexander J. M. Miller, F. Hasanayn, 2021, Journal of the American Chemical Society.

An Iron Pyridyl-Carbene Electrocatalyst for Low Overpotential CO2 Reduction to CO

Alexander J. M. Miller, J. Lloret‐Fillol, S. Gonell, 2020, ACS Catalysis.

Chemical Shifts of Trace Impurities : CommonLaboratory Solvents , Organics , and Gases in DeuteratedSolvents Relevant to the OrganometallicChemist

Gregory R. Fulmer, H. Gottlieb, I. Goldberg, 2010 .

Lewis Structures and the Bonding Classification of End-on Bridging Dinitrogen Transition Metal Complexes

Patrick L. Holland, P. Holland, Alexander J. M. Miller, 2023, Journal of the American Chemical Society.

Photochemical Production of Ethane from an Iridium Methyl Complex

Alexander J. M. Miller, C. Pitman, Catherine L Pitman, 2017 .

Stable Molecular Surface Modification of Nanostructured, Mesoporous Metal Oxide Photoanodes by Silane and Click Chemistry.

Alexander J. M. Miller, M. K. Brennaman, T. Meyer, 2019, ACS applied materials & interfaces.

Tunable and Switchable Catalysis Enabled by Cation-Controlled Gating with Crown Ether Ligands.

Alexander J. M. Miller, Sebastian Acosta-Calle, 2023, Accounts of chemical research.

An Iron Bis(carbene) Catalyst for Low Overpotential CO2 Electroreduction to CO: Mechanistic Insights from Kinetic Zone Diagrams, Spectroscopy, and Theory

Alexander J. M. Miller, J. Lloret‐Fillol, S. Gonell, 2021, ACS Catalysis.

Oxidative Addition of a Phosphinite P-O Bond at Nickel.

Quinton J. Bruch, Alexander J. M. Miller, Chun-Hsing Chen, 2023, Inorganic chemistry.

Salt-promoted catalytic methanol carbonylation using iridium pincer-crown ether complexes

Alexander J. M. Miller, P. White, Javier Grajeda, 2018 .

Cyclopentadiene-mediated hydride transfer from rhodium complexes.

Alexander J. M. Miller, C. Pitman, A. J. Miller, 2016, Chemical communications.