A. Igau

发表

Broad HOMO-LUMO gap tuning through the coordination of a single phosphine, aminophosphine or phosphite onto a Ru(tpy)(bpy)2+ core.

I. Dixon, Emilie Lebon, Gilles Loustau, 2008, Dalton transactions.

Early Transition Metal α‐Diazoalkane Complexes

J. Majoral, A. Igau, M. Zabłocka, 2000 .

Early Transition Metalα-Diazoalkane Complexes

J. Majoral, A. Igau, M. Zabłocka, 2000 .

Emerging Earth-abundant (Fe, Co, Ni, Cu) molecular complexes for solar fuel catalysis

P. Sutra, A. Igau, 2018 .

N-Phosphanylformamidines (phosfam) R2′N–C(H)=N–PR2: One-Pot Synthesis and Versatile Protonation Reaction

J. Sotiropoulos, L. Vendier, A. Igau, 2008 .

Photophysical and electrochemical properties of polypyridine imine ruthenium(II) complexes: a comparative experimental and theoretical study

Emilie Lebon, P. Sutra, A. Igau, 2012 .

Anionic phosph(in)ito (“phosphoryl”) ligands: Non-classical “actor” phosphane-type ligands in coordination chemistry

P. Sutra, A. Igau, 2016 .

Multi-site coordination N-phosphanylamidine ligands as stabilizers for the synthesis of ruthenium nanoparticles

K. Philippot, A. Igau, B. Chaudret, 2011 .

Phosphoryl group as a strong σ-donor anionic phosphine-type ligand: a combined experimental and theoretical study on long-lived room temperature luminescence of the [Ru(tpy)(bpy)(Ph2PO)]+ complex.

Emilie Lebon, P. Sutra, A. Igau, 2014, Inorganic chemistry.

Benzyne-Zirconocene Reagents as Tools in Phosphorus Chemistry

J. Majoral, A. Igau, M. Zabłocka, 2002 .

X-ray structure, redox and spectroscopic properties of ruthenium phosphine complexes [Ru(tpy)(bpy)(PPh3)]2+ and [Ru(tpy)(bpy)(PCy3)]2+

I. Dixon, Emilie Lebon, P. Sutra, 2007 .

Evidence of the unprecedented conversion of intermolecular proton to water bridging of two phosphoryl ruthenium complexes

P. Sutra, L. Vendier, A. Igau, 2013 .

Can a functionalized phosphine ligand promote room temperature luminescence of the [Ru(bpy)(tpy)]2+ core?

I. Dixon, Emilie Lebon, P. Sutra, 2012, Chemical communications.

Luminescent ruthenium-polypyridine complexes & phosphorus ligands: anything but a simple story.

I. Dixon, Emilie Lebon, P. Sutra, 2009, Chemical Society reviews.

Bis(2,2′-bipyridine)[1,9-bis(diphenylphosphanyl)-1,2,3,4,6,7,8,9-octahydropyrimido[1,2-a]pyrimidin-5-ium]ruthenium(II) hexafluoridophosphate dibromide dichloromethane disolvate monohydrate

P. Sutra, L. Vendier, A. Igau, 2013, Acta crystallographica. Section E, Structure reports online.

Intramolecular coupling of acetylenic groups of bis(alkynyl)phosphanes and silanes mediated by benzynezirconocene: a route to new mono- and tricyclic heterocycles

J. Majoral, A. Igau, P. Meunier, 2004 .

X-H (X = C, N, O, P, S) bond activations induced by beta-heterosubstituted zirconaindenes.

J. Majoral, A. Igau, M. Zabłocka, 2001, Chemistry.

2H‐1,2‐Azaphosphindoles – Synthesis and Characterization

J. Majoral, A. Igau, V. Cadierno, 2000 .

Zirconaindane phospholanes: key reagents for the synthesis of mono-or tri-cyclic phosphanes and related species

J. Majoral, A. Igau, M. Zabłocka, 1997 .

When organophosphorus ruthenium complexes covalently bind to ruthenium nanoparticles to form nanoscale hybrid materials.

K. Philippot, P. Sutra, A. Igau, 2020, Chemical communications.

N-phosphanylamidine ligands and their catalytic activity in the hydroformylation of 1-octene and styrene

L. Vendier, A. Igau, P. Kalck, 2011 .

[Bis(diisopropylamino)phosphino]trimethylsilylcarbene: A Stable Nucleophilic Carbene

G. Trinquier, A. Igau, G. Bertrand, 1989 .

Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene

A. Igau, G. Bertrand, A. Baceiredo, 1988 .

Reductive Elimination of α-Phosphinozirconocene Iminoacyl Complexes: First Evidence of Neutral η1-Imine Zirconocene. Synthesis of Bi- or Tricyclic β-Phosphino Imines

J. Majoral, A. Igau, M. Zabłocka, 1999 .

Synthesis and Reactivity of the First Stable λ5-Phosphaacetylene

A. Igau, G. Bertrand, H. Grützmacher, 1990 .

Analogous α,α′-Bis-Carbenoid Triply Bonded Species: Synthesis of a Stable λ3-Phosphinocarbene-λ5-Phosphaacetylene.

A. Igau, G. Bertrand, A. Baceiredo, 1989 .

Phosphinocarbene-phosphaalkene rearrangement and intramolecular Wittig-like reaction involving a phosphorus vinyl ylide.

A. Igau, G. Bertrand, A. Baceiredo, 1986, Journal of the American Chemical Society.

Zirconium Species as Tools in Phosphorus Chemistry, 1 [Cp2ZrHCI]n, a Versatile Reagent

J. Majoral, A. Igau, M. Zabłocka, 1996 .

Unprecedented rearrangement during the formation of P–P homoatomic N-phosphino formamidine complexes

J. Sotiropoulos, A. Igau, Y. Coppel, 2009 .

Investigation in the coupling of zirconocene complexes and trimethylsilyl(diphenylphosphino)acetylene. P–C bond cleavage chemistry from protonolysis reactions

J. Majoral, A. Igau, V. Cadierno, 2004 .

Malonodinitrile CH2(CN)2 as Synthon for the Preparation of Unprecedented N-Metalla- and N-Phosphino-β-diimine Ligands

J. Majoral, A. Igau, Alexandrine Maraval, 2001 .

N -phosphonio formamidine derivatives: Synthesis, characterization, X-ray crystal structures, and deprotonation reactions

L. Vendier, A. Igau, T. Huỳnh, 2010 .

Syntheses and crystallographic characterizations of trinuclear (µ3-O) zirconium complexes

J. Jaud, G. Erker, J. Majoral, 1995 .

[Cp2ZrHCl]n a useful reducing agent in phosphorus chemistry

J. Majoral, A. Igau, M. Zabłocka, 1997 .

Synthesis, reactivity, and crystal structure of the first methylenephosphonium ion: a severely twisted valence isoelectronic olefin

A. Igau, G. Bertrand, A. Baceiredo, 1989 .

Shvo-Type Metal–Ligand Cooperative Catalysts: Tethered η5-Oxocyclohexadienyl Ruthenium Complexes

J. Sotiropoulos, P. Sutra, L. Vendier, 2022, Organometallics.

Iminophosphine Palladium Complexes in Catalytic Stille Coupling Reactions: From Monomers to Dendrimers

Victorio Cadierno, Valérie Maraval, Anne-Marie Caminade, 2002 .

η5-Oxocyclohexadienyl ligands in transition metal chemistry: Neglected (Brønsted) base ligands in cooperative catalysis

A. Igau, 2017 .

Tethered η5-Oxocyclohexadienyl Piano-Stool Ruthenium(II) Complexes: A New Class of Catalysts?

J. Sotiropoulos, L. Vendier, A. Igau, 2014 .

Chlorido(η6-N 2-diphenylphosphanyl-N 1,N 1-diisopropyl-4-methoxybenzamidine-κP)(triphenylphosphane-κP)ruthenium(II) trifluoromethansulfonate acetone disolvate

L. Vendier, A. Igau, Manel Kéchaou-Perrot, 2013, Acta crystallographica. Section E, Structure reports online.

A Straightforward Synthesis of N‐Functionalized β‐Diimines

J. Majoral, A. Igau, Alexandrine Maraval, 2003 .

Stereoselective synthesis of 2-phosphino-1-zirconaindenes andrelated 2-phosphinophospholes and stiboles

J. Majoral, A. Igau, P. Meunier, 1997 .

A practical and efficient synthetic route to stable zirconocene-ate zwitterionic complexes

J. Majoral, A. Igau, M. Zabłocka, 1999 .

Synthesis and reactivity of chiral metal fluoride and water complexes derived from the rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+

A. Igau, J. Gladysz, C. Roger, 1992 .

Versatile behaviour of the phosphanyl salt (Pri2N)2 P+CF3SO3– towards zirconocene derivatives

J. Jaud, J. Majoral, A. Igau, 1993 .

Synthesis of mono- and di-cationic phosphorus–zirconium species

J. Jaud, J. Majoral, A. Igau, 1993 .

Reactions of the neohexyl iodide complex [(.eta.5-C5H5)Re(NO)(PPh3)(ICH2CH2C(CH3)3)]+BF4- and nucleophiles: stereochemistry of carbon-iodine bond cleavage in highly accelerated SN2 reactions

A. Igau, J. Gladysz, 1991 .

Hydride transfer reactions from [PPh4][HFe(CO)4]. III: Synthesis of a stable anionic phosphido complex [PPh4][((CO)4Fe)2PHNMe2]

A. Caminade, J. Majoral, A. Igau, 1987 .

Delocalized electronic interactions in chiral cyclopentadienylrhenium halide complexes. Valence photoelectron spectra of CpRe(NO)(L)X (Cp=η5-C5H5, η5-C5(CH3)5 ; L=CO, P(C6H5)3; X=Cl, Br, I)

D. Lichtenberger, A. Igau, J. Gladysz, 1991 .

ZIRCONOCENE PHOSPHINIDENE COMPLEX TRAPPING REACTIONS

J. Majoral, A. Igau, A. Mahieu, 1995 .

Vibrational progressions in the valence ionizations of transition metal hydrides: evaluation of metal-hydride bonding and vibrations in (eta(5)-C(5)R(5))Re(NO)(CO)H [R = H, CH(3)].

D. Lichtenberger, A. Igau, J. Gladysz, 2002, Journal of the American Chemical Society.

Theoretical investigation of phosphinidene oxide polypyridine ruthenium(II) complexes: toward the design of a new class of photochromic compounds.

P. Sutra, A. Igau, J. Heully, 2013, The journal of physical chemistry. A.

Synthesis and Reactivity of Me2P(ZrCp2Cl)NAr, the First Iminozirconiophosphorane, a Masked Iminophosphide†

J. Majoral, A. Igau, N. Dufour, 1993 .

Zirconium species as tools in phosphorus chemistry: II [Cp2ZrMe2], a useful reagent

J. Majoral, A. Igau, 1998 .

Zirconocene [Cp2Zr] synthon and benzynezirconocene complexes as tools in main group element chemistry

J. Majoral, A. Igau, M. Zabłocka, 1998 .

Base-Free Reversible Hydrogen Storage Using a Tethered π-Coordinated-Phenoxy Ruthenium-Dimer Precatalyst

P. Sutra, A. Igau, C. Fischmeister, 2023, ACS Catalysis.

Early Transition Metal alpha-Diazoalkane Complexes This work was supported by the CNRS, France and KBN (Poland, Grant No 3T09A03619). V.C. thanks the Spanish Ministerio de Educacion y Cultura for postdoctoral fellowship.

J. Majoral, A. Igau, M. Zabłocka, 2000, Angewandte Chemie.

Dendrimers Containing Zwitterionic [Phosphonium Anionic Zirconocene(IV)] Complexes

J. Majoral, A. Igau, V. Cadierno, 1999 .

Theoretical investigation on the photophysical properties of model ruthenium complexes with diazabutadiene ligands [Ru(bpy)(3-x)(dab)(x)](2+) (x = 1-3).

Emilie Lebon, P. Sutra, A. Igau, 2010, Inorganic chemistry.