S. Duckett

P. Rayner, G. Cheetham, S. Duckett, 2019, European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences.

Utilization of SABRE-derived hyperpolarization to detect low-concentration analytes via 1D and 2D NMR methods.

M. Bernstein, R. Lewis, S. Coombes, 2012, Journal of the American Chemical Society.

Photochemical reactions of (eta 5-cyclopentadienyl)bis(t-butylacrylate) rhodium with silanes: dynamics of isomer interconversion via Rh(eta 2-silane) species.

R. Perutz, S. Duckett, K. Ampt, 2004, Dalton transactions.

Addition of H2 to a cationic iridium(I) complex: a study using parahydrogen NMR

S. Duckett, L. Field, B. Messerle, 2000 .

Applications of the parahydrogen phenomenon: A chemical perspective

S. Duckett, C. Sleigh, 1999 .

NMR studies on ligand exchange at [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3] by para-hydrogen induced polarisation

S. Duckett, C. Sleigh, B. Messerle, 1996 .

Molecular MRI in the Earth's Magnetic Field Using Continuous Hyperpolarization of a Biomolecule in Water.

J. Hennig, D. Leibfritz, J. Korvink, 2016, The journal of physical chemistry. B.

Unlocking a Diazirine Long-Lived Nuclear Singlet State via Photochemistry: NMR Detection and Lifetime of an Unstabilized Diazo-Compound

S. Duckett, Soumya S. Roy, Barbara Procacci, 2018, Journal of the American Chemical Society.

Parahydrogen-based NMR methods as a mechanistic probe in inorganic chemistry

S. Duckett, Nicholas J. Wood, 2008 .

Ruthenium dihydride complexes: NMR studies of intramolecular isomerization and fluxionality including the detection of minor isomers by parahydrogen-induced polarization.

S. Duckett, C. Sleigh, J. Lowe, 2002, Inorganic chemistry.

The Study of Inorganic Systems by NMR Spectroscopy in Conjunction with Parahydrogen‐Induced Polarisation

D. Blazina, S. Duckett, 2003 .

The use of yttrium in medical imaging and therapy: historical background and future perspectives.

S. Duckett, G. Stasiuk, G. Angelovski, 2020, Chemical Society reviews.

Reversible Interactions with para-Hydrogen Enhance NMR Sensitivity by Polarization Transfer

K. D. Atkinson, J. Aguilar, S. Duckett, 2009, Science.

SABRE hyperpolarized anticancer agents for use in 1H MRI

A. Kennerley, P. Rayner, S. Duckett, 2022, Magnetic resonance in medicine.

Hyperpolarisation of weakly binding N-heterocycles using signal amplification by reversible exchange†

P. Rayner, S. Duckett, R. John, 2021, Chemical science.

Steric and electronic effects on the 1H hyperpolarisation of substituted pyridazines by signal amplification by reversible exchange

P. Rayner, S. Duckett, E. Fear, 2021, Magnetic resonance in chemistry : MRC.

Reversible Hyperpolarization of Ketoisocaproate Using Sulfoxide‐containing Polarization Transfer Catalysts

A. Whitwood, S. Duckett, Ben. J. Tickner, 2020, Chemphyschem : a European journal of chemical physics and physical chemistry.

Parahydrogen-induced Hyperpolarization of Gases.

S. Duckett, E. Chekmenev, I. Koptyug, 2020, Angewandte Chemie.

Using SABRE hyperpolarized 13C NMR to interrogate organic transformations of pyruvate.

P. Rayner, S. Duckett, Ben. J. Tickner, 2020, Analytical chemistry.

Remarkable Levels of 15N Polarization Delivered through SABRE into Unlabeled Pyridine, Pyrazine, or Metronidazole Enable Single Scan NMR Quantification at the mM Level

S. Duckett, F. Ahwal, M. Fekete, 2020, The journal of physical chemistry. B.

The Detection and Reactivity of Silanols and Silanes Using Hyperpolarized 29 Si Nuclear Magnetic Resonance

P. Rayner, S. Duckett, P. M. Richardson, 2020, Angewandte Chemie.

A role for low concentration reaction intermediates in the signal amplification by reversible exchange process revealed by theory and experiment.

S. Duckett, Soumya S. Roy, M. Fekete, 2020, Physical chemistry chemical physics : PCCP.

A simple and cost-efficient technique to generate hyperpolarized long-lived 15N-15N nuclear spin order in a diazine by signal amplification by reversible exchange

P. Rayner, S. Duckett, Soumya S. Roy, 2020, The Journal of chemical physics.

Optimisation of pyruvate hyperpolarisation using SABRE by tuning the active magnetisation transfer catalyst† †Electronic supplementary information (ESI) available. CCDC 1957542–1957543. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9cy02498k

P. Rayner, A. Whitwood, S. Duckett, 2020, Catalysis science & technology.

Enhancement of 1H NMR signals of 5-alkyl-6-phenylethynyl-2-pyrone using p-H2.

S. Duckett, I. Fairlamb, M. P. Kagoro, 2019 .

The Detection and Reactivity of Silanols and Silanes Using Hyperpolarized 29Si Nuclear Magnetic Resonance

P. Rayner, S. Duckett, P. M. Richardson, 2019, Angewandte Chemie.

Probing the Hydrogenation of Vinyl Sulfoxides Using para-Hydrogen

A. Whitwood, S. Duckett, Ben. J. Tickner, 2019, Organometallics.

Mechanistic insight into novel sulfoxide containing SABRE polarisation transfer catalysts.

A. Whitwood, S. Duckett, R. John, 2019, Dalton transactions.

Relayed hyperpolarization from para-hydrogen improves the NMR detectability of alcohols

P. Rayner, S. Duckett, Wissam Iali, 2019, Chemical science.

Iridium α-Carboxyimine Complexes Hyperpolarized with para-Hydrogen Exist in Nuclear Singlet States before Conversion into Iridium Carbonates.

A. Whitwood, S. Duckett, Wissam Iali, 2018, Chemphyschem : a European journal of chemical physics and physical chemistry.

In Situ SABRE Hyperpolarization with Earth’s Field NMR Detection

M. Halse, S. Duckett, P. M. Richardson, 2019, Molecules.

Using coligands to gain mechanistic insight into iridium complexes hyperpolarized with para-hydrogen† †Electronic supplementary information (ESI) available. CCDC 1893624. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc00444k; NMR can be located viahttps://do

A. Whitwood, S. Hart, S. Duckett, 2019, Chemical science.

Understanding substrate substituent effects to improve catalytic efficiency in the SABRE hyperpolarisation process

S. Duckett, P. M. Richardson, Emma V. Stanbury, 2019, Catalysis science & technology.

Signal Amplification by Reversible Exchange (SABRE): From Discovery to Diagnosis.

P. Rayner, S. Duckett, 2018, Angewandte Chemie.

Extending the Scope of 19F Hyperpolarization through Signal Amplification by Reversible Exchange in MRI and NMR Spectroscopy

S. Duckett, Wissam Iali, R. Mewis, 2017, ChemistryOpen.

SABRE-Relay: A Versatile Route to Hyperpolarization

S. Duckett, Kate M. Appleby, Soumya S. Roy, 2018, The journal of physical chemistry letters.

SABRE hyperpolarization enables high-sensitivity 1H and 13C benchtop NMR spectroscopy† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8an00596f

M. Halse, A. Nordon, S. Duckett, 2018, The Analyst.

Using 2H labelling to improve the NMR detectability of pyridine and its derivatives by SABRE

P. Rayner, S. Duckett, R. Mewis, 2018, Magnetic resonance in chemistry : MRC.

Fine-tuning the efficiency of para-hydrogen-induced hyperpolarization by rational N-heterocyclic carbene design

P. Rayner, A. Whitwood, S. Hart, 2018, Nature Communications.

Quantification of hyperpolarisation efficiency in SABRE and SABRE-Relay enhanced NMR spectroscopy† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8cp05473h

P. Rayner, M. Halse, A. Nordon, 2018, Physical chemistry chemical physics : PCCP.

Harnessing asymmetric N-heterocyclic carbene ligands to optimise SABRE hyperpolarisation† †Electronic supplementary information (ESI) available: NMR raw data can be found at https://doi.org/10.15124/42187464-6f06-4805-a487-9b469b7a15e4. CCDC 1848485. For ESI and crystallographic data in CIF or other

P. Rayner, A. Whitwood, S. Duckett, 2018, Catalysis science & technology.

Direct and indirect hyperpolarisation of amines using parahydrogen† †Electronic supplementary information (ESI) available: Full experimental procedures, characterisation data and example spectra. See DOI: 10.1039/c8sc00526e

P. Rayner, S. Duckett, Wissam Iali, 2018, Chemical science.

Using parahydrogen to hyperpolarize amines, amides, carboxylic acids, alcohols, phosphates, and carbonates

P. Rayner, S. Duckett, Wissam Iali, 2018, Science Advances.

Achieving High Levels of NMR‐Hyperpolarization in Aqueous Media With Minimal Catalyst Contamination Using SABRE

S. Duckett, Wissam Iali, G. Green, 2017, Chemistry.

Abstracts of the 25th International Isotope Society (UK group) Symposium: Synthesis & Applications of Labelled Compounds 2016.

P. Rayner, L. Carroll, E. Aboagye, 2017 .

A Simple Route to Strong Carbon‐13 NMR Signals Detectable for Several Minutes

P. Rayner, S. Duckett, Soumya S. Roy, 2017, Chemistry.

Achieving High 1 H Nuclear Hyperpolarization Levels with Long Lifetimes in a Range of Tuberculosis Drug Scaffolds.

P. Rayner, S. Duckett, G. Green, 2017, Chemistry.

Synthesis and hyperpolarisation of eNOS substrates for quantification of NO production by 1H NMR spectroscopy

D. Dawson, M. Zanda, S. Duckett, 2017, Bioorganic & medicinal chemistry.

Para-Hydrogen-Enhanced Magnetic Resonance

S. Duckett, 2017 .

Harnessing polarisation transfer to indazole and imidazole through signal amplification by reversible exchange to improve their NMR detectability

P. Rayner, S. Duckett, G. Green, 2017, Magnetic resonance in chemistry : MRC.

Following palladium catalyzed methoxycarbonylation by hyperpolarized NMR spectroscopy: a parahydrogen based investigation

S. Duckett, J. López‐Serrano, A. Holmes, 2017 .

Coherent evolution of parahydrogen induced polarisation using laser pump, NMR probe spectroscopy: Theoretical framework and experimental observation.

M. Halse, R. Perutz, S. Duckett, 2017, Journal of magnetic resonance.

Iridium Cyclooctene Complex That Forms a Hyperpolarization Transfer Catalyst before Converting to a Binuclear C–H Bond Activation Product Responsible for Hydrogen Isotope Exchange

A. Whitwood, S. Hart, S. Duckett, 2016, Inorganic chemistry.

Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para-hydrogen

S. Duckett, Kate M. Appleby, R. Mewis, 2015, Chemical science.

Catalytic Transfer of Magnetism using a Neutral Iridium Phenoxide Complex.

A. Whitwood, S. Duckett, R. Mewis, 2015, Organometallics.

Hyperpolarisation through reversible interactions with parahydrogen

R. Lewis, S. Coombes, S. Duckett, 2014 .

Toward Biocompatible Nuclear Hyperpolarization Using Signal Amplification by Reversible Exchange: Quantitative in Situ Spectroscopy and High-Field Imaging

J. Hennig, S. Duckett, D. von Elverfeldt, 2014, Analytical chemistry.

Optimization of SABRE for polarization of the tuberculosis drugs pyrazinamide and isoniazid

K. D. Atkinson, P. V. van Zijl, M. McMahon, 2013, Journal of magnetic resonance.

A continuous‐flow, high‐throughput, high‐pressure parahydrogen converter for hyperpolarization in a clinical setting

J. Hennig, D. Leibfritz, S. Duckett, 2013, NMR in biomedicine.

A hyperpolarized equilibrium for magnetic resonance

J. Hennig, D. Leibfritz, J. Korvink, 2013, Nature Communications.

Improving NMR and MRI sensitivity with parahydrogen.

S. Duckett, R. Mewis, 2013, Topics in current chemistry.

Iridium(III) Hydrido N-Heterocyclic Carbene–Phosphine Complexes as Catalysts in Magnetization Transfer Reactions

P. Rayner, A. Whitwood, S. Hart, 2013, Inorganic chemistry.

1 Continuous Proton Hyperpolaritzation via SABRE and Hollow Fiber Membranes

H. Spiess, S. Duckett, L. Schreiber, 2012 .

Selective detection of hyperpolarized NMR signals derived from para-hydrogen using the Only Para-hydrogen SpectroscopY (OPSY) approach.

J. Aguilar, S. Duckett, R. W. Adams, 2011, Journal of magnetic resonance.

Iridium N-Heterocyclic Carbene Complexes as Efficient Catalysts for Magnetization Transfer from para-Hydrogen

K. D. Atkinson, S. Duckett, R. Kerssebaum, 2011, Journal of the American Chemical Society.

Detection of picomole amounts of biological substrates by para-hydrogen-enhanced NMR methods in conjunction with a suitable receptor complex.

J. Brannigan, S. Duckett, S. Heath, 2007, Journal of the American Chemical Society.

Bridging the Gap from Mononuclear PdII Precatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd3(XPh3)4]2+ Clusters as Catalytic Species for Suzuki–Miyaura Couplings (X = P, As)

A. Whitwood, S. Hart, S. Duckett, 2021, Organometallics.

Para-hydrogen induced polarization without incorporation of para-hydrogen into the analyte.

K. D. Atkinson, A. Whitwood, S. Duckett, 2009, Inorganic Chemistry.

Coordination Chemistry and Diphenylacetylene Hydrogenation Catalysis of Planar Chiral Ferrocenylphosphane‐Thioether Ligands with Cyclooctadieneiridium(I)

S. Duckett, R. Poli, J. Dunne, 2006 .

Gd-functionalised Au nanoparticles as targeted contrast agents in MRI: relaxivity enhancement by polyelectrolyte coating.

S. Duckett, V. Chechik, R. W. Adams, 2010, Chemical communications.

Biocontrol of avocado dematophora root rot by antagonistic Pseudomonas fluorescens PCL1606 correlates with the production of 2-hexyl 5-propyl resorcinol.

J. Thomas-Oates, F. Cazorla, B. Lugtenberg, 2006, Molecular plant-microbe interactions : MPMI.

Toward Optimizing and Understanding Reversible Hyperpolarization of Lactate Esters Relayed from para-Hydrogen

S. Duckett, J. Vaara, Ben. J. Tickner, 2022, The journal of physical chemistry letters.

A simple and cost-efficient technique to generate hyperpolarized long-lived 15 N- 15 N nuclear spin order in a diazine by signal amplification by reversible exchange in laser-induced

P. Rayner, S. Duckett, Soumya S. Roy, 2020 .

Activation of a (cyclooctadiene) rhodium(I) complex supported by a chiral ferrocenyl phosphine thioether ligand for hydrogenation catalysis: a combined parahydrogen NMR and DFT study.

S. Duckett, R. Poli, E. Manoury, 2013, Dalton transactions.

Implementation of NMR quantum computation with parahydrogen-derived high-purity quantum states

J. A. Jones, M. S. Anwar, H. Carteret, 2004, quant-ph/0406044.

Preparing high purity initial states for nuclear magnetic resonance quantum computing.

Jonathan A. Jones, C. M. Kozak, J. A. Jones, 2003, Physical review letters.

Generation and interrogation of a pure nuclear spin state by parahydrogen‐enhanced NMR spectroscopy: a defined initial state for quantum computation

Jonathan A. Jones, C. M. Kozak, J. A. Jones, 2005, Magnetic resonance in chemistry : MRC.

Practical implementations of twirl operations

J. A. Jones, A. Short, L. Xiao, 2004, quant-ph/0409142.

Implementing Grover's Quantum Search on a Para-hydrogen based Pure State NMR Quantum Computer

J. A. Jones, M. S. Anwar, H. Carteret, 2004, quant-ph/0407091.

Bridging the Gap from Mononuclear PdII Precatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd3(XPh3)4]2+ Clusters as Catalytic Species for SuzukiMiyaura Couplings (X = P, As)

A. Whitwood, S. Hart, S. Duckett, 2021, Organometallics.

Towards measuring reactivity on micro-to-millisecond timescales with laser pump, NMR probe spectroscopy.

M. Halse, R. Perutz, S. Duckett, 2019, Faraday discussions.

Utilisation of water soluble iridium catalysts for signal amplification by reversible exchange.

S. Duckett, G. Dear, G. Green, 2015, Dalton transactions.

Palladium-catalyzed hydrogenation: detection of palladium hydrides. A joint study using para-hydrogen-enhanced NMR spectroscopy and density functional theory.

S. Duckett, A. Lledós, J. López‐Serrano, 2006, Journal of the American Chemical Society.

Photochemical-mediated solid-state [2+2]-cycloaddition reactions of an unsymmetrical dibenzylidene acetone (monothiophos-dba)

A. Whitwood, D. Allan, S. Duckett, 2012 .

Detection of unusual reaction intermediates during the conversion of W(N2)2(dppe)2 to W(H)4(dppe)2 and of H2O into H2.

Jason M. Lynam, S. Duckett, C. Sleigh, 2012, Journal of the American Chemical Society.

A model iridium hydroformylation system with the large bite angle ligand xantphos: reactivity with parahydrogen and implications for hydroformylation catalysis.

J. Schneider, S. Duckett, R. Eisenberg, 2006, Inorganic chemistry.

Photochemical isomerization of N-heterocyclic carbene ruthenium hydride complexes: in situ photolysis, parahydrogen, and computational studies.

R. Perutz, S. Duckett, K. Ampt, 2006, Journal of the American Chemical Society.

Contrasting photochemical and thermal reactivity of Ru(CO)2(PPh3)(dppe) towards hydrogen rationalised by parahydrogen NMR and DFT studies.

Jonathan A. Jones, M. S. Anwar, H. Carteret, 2006, Dalton transactions.

Real-Time High-Sensitivity Reaction Monitoring of Important Nitrogen-Cycle Synthons by 15N Hyperpolarized Nuclear Magnetic Resonance

A. Kennerley, P. Rayner, S. Duckett, 2022, Journal of the American Chemical Society.

Achieving Biocompatible SABRE: An in vitro Cytotoxicity Study

V. Perry, P. Rayner, A. Manoharan, 2018, ChemMedChem.

Only para-hydrogen spectroscopy (OPSY), a technique for the selective observation of para-hydrogen enhanced NMR signals.

J. Aguilar, S. Duckett, R. W. Adams, 2007, Chemical communications.

Observation of New Intermediates in Hydrogenation Catalyzed by Wilkinson's Catalyst, RhCl(PPh3)3, Using Parahydrogen-Induced Polarization

S. Duckett, R. Eisenberg, Connie L. Newell, 1994 .

More than INEPT: parahydrogen and INEPT + give unprecedented resonance enhancement to carbon-13 by direct proton polarization transfer

S. Duckett, R. Eisenberg, Connie L. Newell, 1993 .

Activation of H2 by chlorocarbonylbis(trimethylphosphine)rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe3)2(µ-H)(µ-Cl)RH(PMe3)(CO)

S. Duckett, R. Eisenberg, A. Goldman, 1993 .

A parahydrogen based NMR study of Pt catalysed alkyne hydrogenation.

S. Duckett, J. M. Hernández, J. Dunne, 2010, Dalton transactions.

Parahydrogen derived illumination of pyridine based coordination products obtained from reactions involving rhodium phosphine complexes.

J. Aguilar, S. Duckett, A. Charlton, 2005, Dalton transactions.

Palladium catalysed alkyne hydrogenation and oligomerisation: a parahydrogen based NMR investigation.

A. Whitwood, S. Duckett, J. Dunne, 2008, Dalton transactions.

Characterisation of tri-ruthenium dihydride complexes through the computation of NMR parameters.

S. Duckett, J. McGrady, M. Al-ibadi, 2012, Dalton transactions.

Delivering strong 1H nuclear hyperpolarization levels and long magnetic lifetimes through signal amplification by reversible exchange

P. Rayner, S. Duckett, R. Mewis, 2017, Proceedings of the National Academy of Sciences.

Catalyst-Substrate Effects on Biocompatible SABRE Hyperpolarization.

P. Rayner, A. Manoharan, S. Duckett, 2018, Chemphyschem : a European journal of chemical physics and physical chemistry.

Photochemical pump and NMR probe: chemically created NMR coherence on a microsecond time scale.

M. Halse, R. Perutz, D. Blazina, 2014, Journal of the American Chemical Society.

Computational Studies Explain the Importance of Two Different Substituents on the Chelating Bis(amido) Ligand for Transfer Hydrogenation by Bifunctional Cp*Rh(III) Catalysts

David J. Taylor, R. Perutz, S. Duckett, 2014 .

Parahydrogen studies of H2 addition to Ir(I) complexes containing chiral phosphine-thioether ligands: implications for catalysis.

A. Whitwood, S. Duckett, R. Poli, 2006, Dalton transactions.

Synthesis, structure and reactivity of N,O-metallacyclic (dicarbonyldiazene) platinum complexes

L. Cronin, R. Perutz, S. Duckett, 1998 .

A natural light induced regioselective 6pi-electrocyclisation-oxidative aromatisation reaction: experimental and theoretical insights.

S. Duckett, Zhenyang Lin, I. Fairlamb, 2008, Organic & biomolecular chemistry.

Manganese(I)‐Catalyzed C−H Activation: The Key Role of a 7‐Membered Manganacycle in H‐Transfer and Reductive Elimination

Jason M. Lynam, R. Perutz, A. Whitwood, 2016, Angewandte Chemie.

New insights into catalytic hydrogenation by phosphido-substituted triruthenium clusters: confirmation of intact cluster catalysis by parahydrogen NMR.

P. Dyson, D. Blazina, S. Duckett, 2004, Dalton transactions.

A model for homogeneous hydrodesulfurization. The importance of .eta.2-coordination and sulfur coordination in carbon-hydrogen and carbon-sulfur bond cleavage reactions of thiophene

S. Duckett, W. Jones, Lingzhen Dong, 1992 .

Photochemical studies of (η5-C5H5)Ru(PPh3)2Cl and (η5-C5H5)Ru(PPh3)2Me: formation of Si-H and C-H bond activation products.

S. Duckett, J. Clark, 2014, Dalton transactions.

Photochemical reactions of [CH2(eta5-C5H4)2][Rh(C2H4)2]2 with silanes: evidence for Si-C and C-H activation pathways.

S. Duckett, Jenny L. Cunningham, 2005, Dalton transactions.

Utilisation of an eta(3)-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (eta(5)-C(5)Me(5))Rh(CH(2)[double bond, length as m-dash]CHMe).

S. Duckett, A. Lledós, J. López‐Serrano, 2008, Chemical communications.

Mechanism of homogeneous hydrosilation of alkenes by (.eta.5-cyclopentadienyl)rhodium

R. Perutz, S. Duckett, 1992 .

Synthesis and structure of "16-electron" rhodium(III) catalysts fortransfer hydrogenation of a cyclic imine: mechanistic implications.

David J. Taylor, R. Perutz, A. Whitwood, 2009, Chemical communications.

Reactivity, Structures, and NMR Spectroscopy of Half-Sandwich Pentamethylcyclopentadienyl Rhodium Amido Complexes Relevant to Transfer Hydrogenation

R. Perutz, A. Whitwood, S. Duckett, 2009 .

A DFT Study on the Mechanism of Palladium-Catalyzed Alkyne Hydrogenation: Neutral versus Cationic Pathways

S. Duckett, A. Lledós, J. López‐Serrano, 2008 .

Chemical, Electrochemical, and Structural Aspects of the Ruthenium Complexes Ru(η-arene)Cl2(P) (Where Arene = Benzene, [2.2]Paracyclophane and P = Triphenylphosphine, rac-[2.2]Paracyclophanylphosphine)

J. Steed, P. Dyson, S. Duckett, 2002 .

η2-Alkene Complexes of [Rh(PONOP-iPr)(L)]+ Cations (L = COD, NBD, Ethene). Intramolecular Alkene-Assisted Hydrogenation and Dihydrogen Complex [Rh(PONOP-iPr)(η-H2)]+

S. Duckett, A. Weller, A. Martı́nez-Martı́nez, 2021, Inorganic chemistry.

On the products obtained from reaction of rac-diphenyl[2.2]para-cyclophanylphosphine with (cycloocta-1,5-diene)palladium(II)chloride

J. Steed, R. Scopelliti, P. Dyson, 2003 .

Hydrogenation studies involving halobis(phosphine)-rhodium(I) dimers: use of parahydrogen induced polarisation to detect species present at low concentration.

S. Duckett, R. Eisenberg, Simon A. Colebrooke, 2004, Chemistry.

Hydrogen activation by an aromatic triphosphabenzene.

C. A. Russell, S. Duckett, D. Stephan, 2014, Journal of the American Chemical Society.

A combined parahydrogen and theoretical study of H2 activation by 16-electron d8 ruthenium(0) complexes and their subsequent catalytic behaviour.

Jonathan A. Jones, A. Whitwood, H. Carteret, 2004, Dalton transactions.

Understanding the mechanism of cis–trans isomerism in photo-active palladium(II) complexes derived from the N,N-di-substituted benzoylthioureas

K. R. Koch, S. Duckett, B. Procacci, 2020 .

Reversible photo-isomerization of cis-[Pd(L-κS,O)2] (HL = N,N-diethyl-N'-1-naphthoylthiourea) to trans-[Pd(L-κS,O)2] and the unprecedented formation of trans-[Pd(L-κS,N)2] in solution.

K. R. Koch, S. Duckett, B. Procacci, 2019, Dalton transactions.

Dipyridylketone binding and subsequent C-C bond insertion reactions at cyclopentadienylrhodium.

R. Perutz, S. Duckett, C. Godard, 2003, Chemical communications.

Detection of platinum dihydride bisphosphine complexes and studies of their reactivity through para‐hydrogen‐enhanced NMR methods

A. Whitwood, S. Duckett, A. Lledós, 2008, Magnetic resonance in chemistry : MRC.

Direct Comparison of Hydrogenation Catalysis by Intact versus Fragmented Triruthenium Clusters.

P. Dyson, D. Blazina, S. Duckett, 2001, Angewandte Chemie.

A Parahydrogen Study of Catalytic Hydrogenation by Diphosphane- Substituted Triruthenium Clusters

P. Dyson, D. Blazina, S. Duckett, 2004 .

Strategies for the Hyperpolarization of Acetonitrile and Related Ligands by SABRE

P. Rayner, S. Duckett, R. Mewis, 2014, The journal of physical chemistry. B.

The theory and practice of hyperpolarization in magnetic resonance using parahydrogen.

S. Duckett, R. Mewis, R. W. Adams, 2012, Progress in nuclear magnetic resonance spectroscopy.

Catalytic hydrogenation by triruthenium clusters: a mechanistic study with parahydrogen-induced polarization.

P. Dyson, D. Blazina, S. Duckett, 2003, Chemistry.

NMR studies of Ru(3)(CO)(10)(PMe(2)Ph)(2) and Ru(3)(CO)(10)(PPh(3))(2) and their H(2) addition products: detection of new isomers with complex dynamic behavior.

P. Dyson, D. Blazina, S. Duckett, 2001, Journal of the American Chemical Society.

Characterisation and kinetic behaviour of H2Rh(PPh3)2(μ-Cl)2Rh(PPh3)(alkene) and related binuclear complexes detected during hydrogenation studies involving parahydrogen induced polarisation

S. Duckett, Simon A. Colebrooke, J. Lohman, 2000 .

NMR detection of thermal and photochemical dihydrogen addition products of mono- and tri-nuclear ruthenium complexes containing carbonyl and triphenylphosphine ligands through para-hydrogen induced polarisation

S. Duckett, C. Sleigh, J. Lowe, 1999 .

Structure and dynamics in metal phosphine complexes using advanced NMR studies with para-hydrogen induced polarisation

S. Duckett, C. Sleigh, M. Partridge, 1999 .

Observation of New Intermediates in Hydrogenation Catalyzed by Wilkinson's Catalyst, RhCl(PPh3)3, Using Parahydrogen-Induced Polarization J. Am. Chem. Soc. 1994, 116, 10548−10556

S. Duckett, R. Eisenberg, A. C. Newell, 1997 .

An NMR study of cobalt-catalyzed hydroformylation using para-hydrogen induced polarisation.

A. Whitwood, S. Duckett, R. Tooze, 2009, Dalton transactions.

Thermal and photochemical reactions of rhodium(trialkylsilyl)hydride complexes: NMR and bonding of poly(silyl)(hydride) complexes

R. Perutz, S. Duckett, 1991 .

Hyperpolarising Pyruvate through Signal Amplification by Reversible Exchange (SABRE)

A. Kennerley, S. Duckett, Wissam Iali, 2019, Angewandte Chemie.

A simple hand‐held magnet array for efficient and reproducible SABRE hyperpolarisation using manual sample shaking

M. Halse, A. Nordon, S. Duckett, 2018, Magnetic resonance in chemistry : MRC.

Application of parahydrogen induced polarization techniques in NMR spectroscopy and imaging.

S. Duckett, R. Mewis, SIMON B. DUCKETT, 2012, Accounts of chemical research.

A theoretical basis for spontaneous polarization transfer in non-hydrogenative parahydrogen-induced polarization.

S. Duckett, David C Williamson, Ralph W Adams, 2009, The Journal of chemical physics.

Spontaneous transfer of parahydrogen derived spin order to pyridine at low magnetic field.

K. D. Atkinson, A. Whitwood, S. Duckett, 2009, Journal of the American Chemical Society.

Nucleophilic attack on η3-allyl and η2-tetrahydroborate complexes of ruthenium(II)

S. Duckett, J. Lowe, R. Mawby, 2003 .

Low temperature in situ UV irradiation of [(eta 5-C5H5)Co(C2H4)2] in the NMR probe: formation of Co(III) silyl hydride complexes.

R. Perutz, S. Duckett, K. Ampt, 2007, Dalton transactions.

Multiple .eta.2-arene coordination. Structure and isomerism of naphthalene complexes of rhodium phosphine [(C5Me5)Rh(PMe3)]

S. Duckett, W. Jones, R. Chin, 1992 .

Exchange Processes in Complexes with Two Ruthenium (η2-Silane) Linkages: Role of the Secondary Interactions between Silicon and Hydrogen Atoms

R. Perutz, T. Braun, S. Duckett, 2002 .

Fine tuning of Si–H interligand hypervalent interactions (IHI) in half-sandwich silyl hydrido complexes of ruthenium

S. Duckett, G. Nikonov, L. G. Kuzmina, 2000 .

Use of the tetrahydroborate ligand as "gate-keeper" and protected hydride ligand: preparation and study of alkyl hydride and acyl hydride complexes of ruthenium(II).

S. Duckett, J. Lowe, R. Mawby, 2006, Dalton transactions.

Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(I).

R. Perutz, S. Duckett, D. Schott, 2004, Dalton transactions.

Photochemical substitution of ethene and hydrogen/deuterium exchange in (.eta.5-cyclopentadienyl)bis(ethene)rhodium

R. Perutz, D. Haddleton, S. Duckett, 1989 .

Facing and Overcoming Sensitivity Challenges in Biomolecular NMR Spectroscopy.

Harald Schwalbe, Lucio Frydman, Christian Griesinger, 2015, Angewandte Chemie.

Activation and η2-co-ordination of arenes: crystal and molecular structure of an (η2-hexafluorobenzene)rhodium complex

R. Perutz, S. Duckett, M. Helliwell, 1989 .

Rapid 13C NMR hyperpolarization delivered from para-hydrogen enables the low concentration detection and quantification of sugars† †Electronic supplementary information (ESI) available: NMR data used in this manuscript. See DOI: 10.1039/c9sc03450a

P. Rayner, M. Halse, S. Duckett, 2019, Chemical science.

Rapid13C NMR hyperpolarization delivered frompara-hydrogen enables the low concentration detection and quantification of sugars

P. Rayner, M. Halse, S. Duckett, 2019, Chemical Science.

Separation and characterisation of caprolactam-formaldehyde reaction products.

S. Duckett, D. Goodall, J. Nusselder, 2002, The Analyst.

Separation and characterisation of products of the reaction between propionamide and formaldehyde

S. Duckett, D. Goodall, F. Normand, 2002 .

SABRE hyperpolarization enables high-sensitivity 1H and 13C benchtop NMR spectroscopy

M. Halse, A. Nordon, S. Duckett, 2018, The Analyst.

Para-hydrogen induced polarisation effects in liquid phase hydrogenations catalysed by supported metal nanoparticles.

R. Luque, S. Duckett, A. M. Balu, 2009, Dalton transactions.

Mechanistic Insights into Molecular Crystalline Organometallic Heterogeneous Catalysis through Parahydrogen-Based Nuclear Magnetic Resonance Studies

S. Duckett, A. Weller, Cameron G Royle, 2023, Journal of the American Chemical Society.

Spectroscopic Properties of Inorganic and Organometallic Compounds: Techniques, Materials and Applications

S. Duckett, J. Yarwood, R. Douthwaite, 2010 .

A para-hydrogen investigation of palladium-catalyzed alkyne hydrogenation.

A. Whitwood, S. Duckett, J. Dunne, 2007, Journal of the American Chemical Society.

Observation of H2 oxidative addition to chlorocarbonylbis(triphenylphosphine)rhodium(I) using parahydrogen induced polarization

S. Duckett, E. Eisenberg, 1993 .

Definitive Evidence for a Pairwise Addition of Hydrogen to a Platinum Bis(phosphine) Complex Using Parahydrogen-Induced Polarization

S. Duckett, R. Eisenberg, M. Jang, 1996 .

Activation of H2 by halocarbonyl bis-phosphine and bis-arsine iridium(I) complexes. The use of parahydrogen induced polarisation to detect species present at low concentration and investigate their reactivity

Michael J. Taylor, S. Duckett, C. Sleigh, 2002 .

Reaction of iodocarbonylbis(trimethylphosphine)rhodium(I) with parahydrogen leads to the observation of five characterisable H2 addition products

S. Duckett, R. Eisenberg, Paul D. Morran, 1998 .

Mechanistic Aspects of Inorganic Chemistry Probed via the Parahydrogen Phenomenon

S. Duckett, 2001 .

Improving the Hyperpolarization of 31P Nuclei by Synthetic Design

P. Rayner, S. Duckett, R. Mewis, 2015, The journal of physical chemistry. B.

New perspectives in hydroformylation: a para-hydrogen study.

A. Whitwood, S. Duckett, C. Godard, 2004, Chemical communications.

Parahydrogen enhanced NMR studies on thermally and photochemically generated products from [IrH3(CO)(PPh3)2]

Michael J. Taylor, S. Duckett, S. Hasnip, 1998 .

LUMINESCENT IRIDIUM(I) DIETHYLDITHIOCARBAMATE COMPLEXES : SYNTHESIS, STRUCTURE, AND REACTIVITY INCLUDING STEREOSELECTIVE HYDROGEN OXIDATIVE ADDITION

S. Duckett, C. Sleigh, R. Eisenberg, 1997 .

Equilibria between isomers of ruthenium dihydride complexes: detection of minor isomers by parahydrogen induced polarisation

S. Duckett, M. Partridge, R. Mawby, 1996 .

Dalton communications. Rapid characterisation of rhodium dihydrides by nuclear magnetic resonance spectroscopy using indirect two-dimensional methods and para-hydrogen

S. Duckett, M. Partridge, B. Messerle, 1995 .

Using para hydrogen induced polarization to study steps in the hydroformylation reaction.

A. Whitwood, S. Duckett, R. Tooze, 2019, Dalton transactions.

Detection of intermediates in cobalt-catalyzed hydroformylation using para-hydrogen-induced polarization.

A. Whitwood, S. Duckett, R. Tooze, 2005, Journal of the American Chemical Society.

Parahydrogen‐Induced Polarization of Amino Acids

G. Buntkowsky, S. Duckett, I. Koptyug, 2021, Angewandte Chemie.

Probing signal amplification by reversible exchange using an NMR flow system

K. D. Atkinson, S. Duckett, R. Mewis, 2014, Magnetic resonance in chemistry : MRC.

Diastereoselective oxidative addition of dihydrogen to IrI(CO)((R)-BINAP) and [Ir(CO)2((R)-BINAP)][SbF6].

S. Duckett, R. Eisenberg, W. Brennessel, 2007, Inorganic Chemistry.

Control of .eta.2-coordination vs. carbon-hydrogen bond activation by rhodium: the role of aromatic resonance energies

R. Perutz, S. Duckett, W. Jones, 1993 .

Detection and reactivity of Pd((C8H14)PCH2 CH2 P(C8H14))(CHPhCH2Ph)(H) as determined by parahydrogen-enhanced NMR spectroscopy.

S. Duckett, J. Dunne, E. Drent, 2004, Journal of the American Chemical Society.

Control of η2-arene coordination and C–H bond activation by cyclopentadienyl complexes of rhodium

R. Perutz, S. Duckett, W. Jones, 1991 .

Quantification of hyperpolarisation eﬃciency in SABRE and SABRE-Relay enhanced NMR spectroscopy †

P. Rayner, M. Halse, A. Nordon, 2019 .

New products in an old reaction: isomeric products from H2 addition to Vaska’s complex and its analogues

Michael J. Taylor, S. Duckett, C. Sleigh, 1999 .

Detection of pyridine derivatives by SABRE hyperpolarization at zero field

S. Duckett, Oksana A. Bondar, S. Pustelny, 2023, Communications chemistry.

Sharing polarization within quantum subspaces

M. S. Anwar, S. Duckett, J. A. Jones, 2005, quant-ph/0509036.

Foundations of Spectroscopy

S. Duckett, B. C. Gilbert, 2000 .

detection of

S. Duckett, Soumya S. Roy, P. Norcott, 2019 .

Reversible Interactions with para-Hydrogen Enhance NMR Sensitivity by Polarization Transfer

K. D. Atkinson, J. Aguilar, S. Duckett, 2009, Science.

Exploring the hyperpolarisation of EGTA-based ligands using SABRE.

S. Duckett, G. Angelovski, Ben. J. Tickner, 2021, Dalton transactions.

A. Whitwood, S. Hart, S. Duckett, 2019, Chemical science.

P. Rayner, S. Duckett, Wissam Iali, 2018, Chemical science.

Direct enhancement of nitrogen-15 targets at high-field by fast ADAPT-SABRE

P. Rayner, S. Duckett, Soumya S. Roy, 2017, Journal of magnetic resonance.

Achieving High Levels of NMR‐Hyperpolarization in Aqueous Media With Minimal Catalyst Contamination Using SABRE

S. Duckett, Wissam Iali, G. Green, 2017, Chemistry.

Long-lived states to sustain SABRE hyperpolarised magnetisation† †Electronic supplementary information (ESI) available: Experimental details, sample specification, substrate characterisation, SABRE studies, pulse sequence details, simulations. See DOI: 10.1039/c6cp02844f Click here for additional da

P. Rayner, S. Duckett, Soumya S. Roy, 2016, Physical chemistry chemical physics : PCCP.

Deactivation of signal amplification by reversible exchange catalysis, progress towards in vivo application.

A. Whitwood, S. Duckett, R. Mewis, 2015, Chemical communications.

Utilisation of an eta(3)-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (eta(5)-C(5)Me(5))Rh(CH(2)[double bond, length as m-dash]CHMe).

S. Duckett, A. Lledós, J. López‐Serrano, 2008, Chemical communications.

A theoretical basis for spontaneous polarization transfer in non-hydrogenative parahydrogen-induced polarization.

S. Duckett, R. W. Adams, G. Green, 2009, The Journal of chemical physics.

Deactivation of signal amplification by reversible exchange catalysis, progress towards in vivo application.

A. Whitwood, S. Duckett, R. Mewis, 2015, Chemical Communications.

Iridium N-Heterocyclic Carbene Complexes as Efficient Catalysts for Magnetization Transfer from para-Hydrogen

K. D. Atkinson, S. Duckett, R. Kerssebaum, 2011, Journal of the American Chemical Society.

Gd-functionalised Au nanoparticles as targeted contrast agents in MRI: relaxivity enhancement by polyelectrolyte coating.

S. Duckett, V. Chechik, M. F. Warsi, 2010, Chemical communications.

Using coligands to gain mechanistic insight into iridium complexes hyperpolarized with para-hydrogen

A. Whitwood, S. Hart, S. Duckett, 2019, Chemical science.

Using hyperpolarised NMR and DFT to rationalise the unexpected hydrogenation of quinazoline to 3,4-dihydroquinazoline

A. Whitwood, S. Duckett, R. Mewis, 2018, Chemical communications.

Coherent evolution of parahydrogen induced polarisation using laser pump, NMR probe spectroscopy: Theoretical framework and experimental observation.

M. Halse, R. Perutz, S. Duckett, 2017, Journal of magnetic resonance.

Manganese alkane complexes: an IR and NMR spectroscopic investigation.

S. L. Matthews, Khuong Q. Vuong, R. Perutz, 2011, Journal of the American Chemical Society.

Modeling Ligand Exchange Kinetics in Iridium Complexes Catalyzing SABRE Nuclear Spin Hyperpolarization

S. Duckett, E. Chekmenev, J. Hövener, 2024, Analytical chemistry.

Solvent responsive catalyst improves NMR sensitivity via efficient magnetisation transfer

S. Duckett, Amy J. Ruddlesden, 2016, Chemical communications.

Improving NMR and MRI sensitivity with parahydrogen.

S. Duckett, R. Mewis, 2015, Topics in current chemistry.

Photochemical oxidative addition reactions of (.eta.5-cyclopentadienyl)bis(ethene)rhodium with dihydrogen and trialkylsilanes: formation and isolation of rhodium(III) and rhodium(V) hydrides

S. A. Jackson, M. Poliakoff, R. Perutz, 1988 .