J. Schomaker

发表

Tunable catalyst-controlled syntheses of β- and γ-amino alcohols enabled by silver-catalysed nitrene transfer

Minsoo Ju, Minxue Huang, Logan E. Vine, 2019, Nature Catalysis.

Origins of Catalyst-Controlled Selectivity in Ag-Catalyzed Regiodivergent C-H Amination.

J. Schomaker, Yue Fu, Emily E. Zerull, 2022, Journal of the American Chemical Society.

Nitrene transfer catalysts for enantioselective C–N bond formation

Minsoo Ju, J. Schomaker, 2021, Nature Reviews Chemistry.

Silver-catalyzed enantioselective functionalizations of alkenes and alkynes: A short review

Mahzad Dehghany, J. Schomaker, 2021 .

Silver-Catalyzed Enantioselective Propargylic C-H Bond Amination Through Rational Ligand Design.

Minsoo Ju, Minxue Huang, Jessica M. Roberts, 2020, Journal of the American Chemical Society.

Taming Nitrene Reactivity with Silver Catalysts

Logan E. Vine, J. Schomaker, Emily E. Zerull, 2020, Synlett.

Chemoselective allene aziridination via Ag(I) catalysis.

J. Schomaker, Jared W. Rigoli, C. D. Weatherly, 2013, Organic letters.

Tunable, chemoselective amination via silver catalysis.

J. Schomaker, Jared W. Rigoli, C. D. Weatherly, 2013, Journal of the American Chemical Society.

Ligand-Controlled, Tunable Silver-Catalyzed C–H Amination

J. Schomaker, Juliet M. Alderson, Alicia M. Phelps, 2014, Journal of the American Chemical Society.

A General Catalyst for Site‐Selective C(sp3)—H Bond Amination of Activated Secondary over Tertiary Alkyl C(sp3)—H Bonds.

J. Schomaker, I. Guzei, Ryan J. Scamp, 2016 .

Catalyst-Controlled and Tunable, Chemoselective Silver-Catalyzed Intermolecular Nitrene Transfer: Experimental and Computational Studies.

J. Schomaker, Ryan J. Scamp, Nicholas S. Dolan, 2016, Journal of the American Chemical Society.

A General Catalyst for Site-Selective C(sp(3))-H Bond Amination of Activated Secondary over Tertiary Alkyl C(sp(3))-H Bonds.

J. Schomaker, I. Guzei, Ryan J. Scamp, 2016, Organic letters.

Synthesis, Characterization, and Variable-Temperature NMR Studies of Silver(I) Complexes for Selective Nitrene Transfer.

Minxue Huang, J. Schomaker, Minxue Huang, 2017, Inorganic chemistry.

Tunable, Chemo- and Site-Selective Nitrene Transfer Reactions through the Rational Design of Silver(I) Catalysts.

J. Schomaker, Juliet M. Alderson, Joshua R. Corbin, 2017, Accounts of chemical research.

Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations.

Minsoo Ju, J. Schomaker, I. Guzei, 2017, Angewandte Chemie.

Site-Selective, Catalyst-Controlled Alkene Aziridination

J. Schomaker, Amirah Mat Lani, 2018, Synthesis.

Fine-Tuning Strain and Electronic Activation of Strain-Promoted 1,3-Dipolar Cycloadditions with Endocyclic Sulfamates in SNO-OCTs.

R. Raines, J. Schomaker, B. Gold, 2017, Journal of the American Chemical Society.

Mechanistic Aspects and Synthetic Applications of Radical Additions to Allenes.

J. Schomaker, Lu Liu, R. M. Ward, 2019, Chemical reviews.

Regioselective differentiation of vicinal methylene C-H bonds enabled by silver-catalysed nitrene transfer.

J. Schomaker, Ryan J. Scamp, B. Scheffer, 2019, Chemical communications.

Synthetic Applications of Flexible SNO-OCT Strained Alkynes and Their Use in Postpolymerization Modifications.

J. Schomaker, E. Burke, Eileen G. Burke, 2017, The Journal of organic chemistry.

Development of N-Heterocyclic Carbene–Copper Complexes for 1,3-Halogen Migration

J. Schomaker, Jared W. Rigoli, S. C. Schmid, 2015 .

Additions of N, O, and S heteroatoms to metal-supported carbenes: Mechanism and synthetic applications in modern organic chemistry

J. Schomaker, Hillary J Dequina, Kate A. Nicastri, 2021 .

Regioselective intramolecular allene amidation enabled by an EDA complex.

J. Schomaker, Lu Liu, R. M. Ward, 2020, Chemistry.

Triple, Mutually Orthogonal Bioorthogonal Pairs through the Design of Electronically Activated Sulfamate-Containing Cycloalkynes.

Ronald T. Raines, R. Raines, Jessica M. Roberts, 2020, Journal of the American Chemical Society.

Fluorinated Amine Stereotriads via Allene Amination.

J. Schomaker, I. Guzei, Lucas J. Oxtoby, 2017, Organic letters.

Triple, Mutually Orthogonal Cycloadditions Through the Design of Electronically Activated SNO-OCTs

Ronald T. Raines, R. Raines, Jessica M. Roberts, 2020 .

The synthesis of substituted phenylpyrimidines via suzuki coupling reactions

J. Schomaker, T. J. Delia, Alvin S. Kalinda, 2006 .

Back to basics

Logan E. Vine, J. Schomaker, 2022, Nature Chemistry.

Intermolecular 3+3 Ring Expansion of Aziridines to Dehydropiperidines through the Intermediacy of Aziridinium Ylides

J. Schomaker, I. Guzei, Israel Fernández, 2019 .

Copper-catalyzed recycling of halogen activating groups via 1,3-halogen migration.

J. Schomaker, R. Van Hoveln, R. D. Grigg, 2012, Journal of the American Chemical Society.

Heteroleptic Nickel Complexes for the Markovnikov-Selective Hydroboration of Styrenes

J. Schomaker, I. Guzei, R. V. Hoveln, 2016 .

Beyond benzyl grignards: facile generation of benzyl carbanions from styrenes.

J. Schomaker, Jared W. Rigoli, Samuel E. Neale, 2012, Chemistry.

1,3-Halogen migration as an entry to aryl coppers from an unintuitive starting material.

J. Schomaker, S. C. Schmid, R. Van Hoveln, 2014, Organic & biomolecular chemistry.

Re-evaluation of the mechanism of cytotoxicity of dialkylated lariat ether compounds

Mahzad Dehghany, J. Schomaker, B. Chanda, 2020, RSC advances.

Ring Expansion of Bicyclic Methyleneaziridines via Concerted, Near-Barrierless [2,3]-Stevens Rearrangements of Aziridinium Ylides.

J. Schomaker, I. Guzei, Israel Fernández, 2018, ACS catalysis.

Aminosugar motifs via an allene aziridination strategy

J. Schomaker, R. D. Grigg, C. S. Adams, 2014 .

Arylation of halogenated pyrimidines via a Suzuki coupling reaction.

J. Schomaker, T. J. Delia, 2001, The Journal of organic chemistry.

Organometallics Roundtable 2011

T. Marks, B. Rieger, I. Manners, 2012 .

Silver-Catalyzed Enantioselective Propargylic C-H Bond Amination Through Rational Ligand Design.

Minsoo Ju, Minxue Huang, Jessica M. Roberts, 2020, Journal of the American Chemical Society.

1,4-Diazaspiro[2.2]pentanes as a flexible platform for the synthesis of diamine-bearing stereotriads.

J. Schomaker, I. Guzei, Jared W. Rigoli, 2012, The Journal of organic chemistry.

Tandem Oxidative Derivatization of Nitrene Insertion Products for the Highly Diastereoselective Synthesis of 1,3-aminoalcohols.

J. Schomaker, Juliet M. Alderson, 2017, Chemistry.

Selectivity in the addition reactions of organometallic reagents to aziridine-2-carboxaldehydes: the effects of protecting groups and substitution patterns.

J. E. Jackson, B. Borhan, J. Schomaker, 2011, Chemistry.

Tetrasubstituted pyrrolidines via a tandem aza-Payne/hydroamination reaction.

B. Borhan, J. Schomaker, Rui Huang, 2007, Journal of the American Chemical Society.

A Stereoselective [3+1] Ring Expansion for the Synthesis of Highly Substituted Methylene Azetidines.

J. Schomaker, I. Guzei, S. C. Schmid, 2017, Angewandte Chemie.

Ligand-Controlled Synthesis of Azoles via Ir-Catalyzed Reactions of Sulfoxonium Ylides with 2-Amino Heterocycles.

S. Shekhar, J. Schomaker, Alicia M. Phelps, 2016, The Journal of organic chemistry.

Synthesis of propargylic and allenic carbamates via the C-H amination of alkynes.

J. Schomaker, Jared W. Rigoli, R. D. Grigg, 2012, Organic letters.

Modular functionalization of allenes to aminated stereotriads.

J. Schomaker, I. Guzei, C. S. Adams, 2012, Journal of the American Chemical Society.

α,β-Unsaturated imines via Ru-catalyzed coupling of allylic alcohols and amines.

J. Schomaker, Jared W. Rigoli, Sara A. Moyer, 2012, Organic & biomolecular chemistry.

The conversion of allenes to strained three-membered heterocycles.

J. Schomaker, C. D. Weatherly, E. Burke, 2014, Chemical Society reviews.

Re-Evaluation of Product Outcomes in the Rh-Catalyzed Ring Expansion of Aziridines with N-Sulfonyl-1,2,3-Triazoles.

J. Schomaker, Israel Fernández, S. C. Schmid, 2022, The Journal of organic chemistry.

Aziridinium Ylides: Underutilized Intermediates for Complex Amine Synthesis.

J. Schomaker, Hillary J Dequina, Hillary J. Dequina, 2020, Trends in chemistry.

Rh-Catalyzed Aziridine Ring Expansions to Dehydropiperazines.

J. Schomaker, Israel Fernández, Hillary J Dequina, 2020, Organic letters.

Synthesis of diastereomerically and enantiomerically pure 2,3-disubstituted tetrahydrofurans using a sulfoxonium ylide.

B. Borhan, J. Schomaker, V. R. Pulgam, 2004, Journal of the American Chemical Society.

Complete stereodivergence in the synthesis of 2-amino-1,3-diols from allenes

J. Schomaker, R. D. Grigg, C. S. Adams, 2014 .

Diastereoselective Synthesis of the Aminocyclitol Core of Jogyamycin via an Allene Aziridination Strategy.

J. Schomaker, Jared W. Rigoli, Nels C Gerstner, 2016, Organic letters.

Allene functionalization via bicyclic methylene aziridines.

J. Schomaker, J. Hershberger, R. D. Grigg, 2011, Organic letters.

Synthesis of 1,3-diaminated stereotriads via rearrangement of 1,4-diazaspiro[2.2]pentanes.

J. Schomaker, Jared W. Rigoli, C. D. Weatherly, 2012, Organic letters.

Diastereomerically and enantiomerically pure 2,3-disubstituted pyrrolidines from 2,3-aziridin-1-ols using a sulfoxonium ylide: a one-carbon homologative relay ring expansion.

B. Borhan, J. Schomaker, S. Bhattacharjee, 2007, Journal of the American Chemical Society.

Divergent reactivity of allene-containing α-diazoesters using Cu and Rh catalysis

J. Schomaker, Alicia M. Phelps, Nicholas S. Dolan, 2013 .

2,4,6‐trichloropyrimidine. Reaction with anilines

J. Schomaker, T. J. Delia, 2000 .

Biomimetic 2-Imino-Nazarov Cyclizations via Eneallene Aziridination.

J. Schomaker, Joshua R. Corbin, Israel Fernández, 2020, Journal of the American Chemical Society.

Scope and mechanistic investigations of Pd-catalyzed coupling/cyclizations and cycloisomerizations of allenyl malonates.

Logan E. Vine, J. Schomaker, Israel Fernández, 2021, ACS catalysis.

Polymorphism of 5-(pyridin-2-ylmethylene)-3-phenyl-2-methylthio-3,5-dihydro-4H-imidazole-4-one

Lara C. Spencer, J. Schomaker, I. Guzei, 2011 .

Stereocontrolled Syntheses of Seven-Membered Carbocycles by Tandem Allene Aziridination/[4+3] Reaction.

J. Schomaker, Nels C Gerstner, C. S. Adams, 2016, Angewandte Chemie.

Chiral amine synthesis refashioned

J. Schomaker, Emily E. Zerull, 2022, Nature Synthesis.

Stereocontrolled Synthesis of the Aminocyclopentitol Core of Jogyamycin via an Ichikawa Rearrangement Reaction.

J. Schomaker, Nels C Gerstner, 2019, The Journal of organic chemistry.

Oxidative allene amination for the synthesis of azetidin-3-ones.

J. Schomaker, E. Burke, 2015, Angewandte Chemie.

Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines

J. Schomaker, I. Guzei, Jared W. Rigoli, 2014, Organic letters.

Stereocontrolled Synthesis of 1,3‐Diamino‐2‐ols by Aminohydroxylation of Bicyclic Methylene‐Aziridines

J. Schomaker, I. Guzei, C. D. Weatherly, 2013 .

C–H amination/cyclocarbonylation of allene carbamates: a versatile platform for the synthesis of α,β-unsaturated γ-lactams

J. Schomaker, V. Timokhin, R. D. Grigg, 2011 .

Silver‐Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions

Mahzad Dehghany, Jessica M. Roberts, J. Schomaker, 2019, Silver Catalysis in Organic Synthesis.

Formal Asymmetric Hydrobromination of Styrenes via Copper-Catalyzed 1,3-Halogen Migration.

J. Schomaker, S. C. Schmid, R. Van Hoveln, 2014, Chemical science.

Total synthesis of (+)-tanikolide via oxidative lactonization.

B. Borhan, J. Schomaker, 2004, Organic & biomolecular chemistry.

Stereodivergent Metal-Catalyzed Allene Cycloisomerizations.

Logan E. Vine, J. Schomaker, Eleanor M. Landwehr, 2020, Synlett : accounts and rapid communications in synthetic organic chemistry.

Mechanistic studies of copper(I)-catalyzed 1,3-halogen migration.

Henry B. Wedler, J. Schomaker, D. Tantillo, 2015, Journal of the American Chemical Society.

Chemoselective silver-catalyzed nitrene insertion reactions

J. Schomaker, Jared W. Rigoli, Ryan J. Scamp, 2014 .

Formal Dyotropic Rearrangements in Organometallic Transformations

J. Schomaker, Michael F. Croisant, R. V. Hoveln, 2015 .

Investigation of transition metal-catalyzed nitrene transfer reactions in water.

J. Schomaker, Juliet M. Alderson, Joshua R. Corbin, 2018, Bioorganic & medicinal chemistry.

Cobalt-mediated [3 + 2]-annulation reaction of alkenes with alpha,beta-unsaturated ketones and imines.

J. Schomaker, R. Bergman, F. Toste, 2009, Organic letters.

Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins.

Ian C. Stewart, J. Schomaker, R. Bergman, 2008, Journal of the American Chemical Society.

Sequential Reduction of Nitroalkanes Mediated by CS2 and Amidine/Guanidine Bases: A Controllable Nef Reaction.

Minsoo Ju, J. Schomaker, Kaid C. Harper, 2019, Organic letters.

Inverting Steric Effects: Using "Attractive" Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer.

Minxue Huang, J. Schomaker, Tzuhsiung Yang, 2017, Journal of the American Chemical Society.

Catalyst-Controlled Nitrene Transfer by Tuning Metal:Ligand Ratios: Insight into the Mechanisms of Chemoselectivity

J. Schomaker, C. D. Weatherly, Juliet M. Alderson, 2017 .

An Enantiotropic Disorder–Partial Order Solid-State Transformation in a Molecular Solid Involving a Phase with Z′ = 12

A. Yakovenko, J. Schomaker, I. Guzei, 2017 .

One-pot regio- and stereoselective cyclization of 1,2,n-triols.

B. Borhan, J. Schomaker, R. Narayan, 2005, Journal of the American Chemical Society.

One‐Pot Regio‐ and Stereoselective Cyclization of 1,2,n‐Triols.

B. Borhan, J. Schomaker, R. Narayan, 2005 .

Cobalt-mediated, enantioselective synthesis of C(2) and C(1) dienes.

J. Schomaker, R. Bergman, Mark R. Crimmin, 2010, Journal of the American Chemical Society.

α-Tetrasubstituted Aldehydes through Electronic and Strain-Controlled Branch-Selective Stereoselective Hydroformylation.

J. Schomaker, C. Landis, Josephine Eshon, 2018, The Journal of organic chemistry.

2,4,6-Trifluoropyrimidine. Reactions with nitrogen nucleophiles

J. Schomaker, T. J. Delia, Dennis P. Anderson, 2004 .

Tunable differentiation of tertiary C-H bonds in intramolecular transition metal-catalyzed nitrene transfer reactions.

J. Schomaker, Joshua R. Corbin, 2017, Chemical communications.

Diastereoselective Au-Catalyzed Allene Cycloisomerizations to Highly Substituted Cyclopentenes.

J. Schomaker, Alicia M. Phelps, Ryan D. Reeves, 2017, Organic letters.

Allene Aziridination as a Tool for the Synthesis of Complex Amines

J. Schomaker, Lu Liu, 2018 .

The Conversion of Allenes to Strained Three-Membered Heterocycles

J. Schomaker, C. D. Weatherly, E. Burke, 2014 .

Tunable Aziridinium Ylide Reactivity: Non-covalent Interactions Enable Divergent Product Outcomes.

J. Schomaker, Israel Fernández, J. Pratt, 2021, ACS Catalysis.

2,4,6‐Trichloropyrimidine. Reaction with sodium amide

J. Schomaker, T. J. Delia, B. R. Meltsner, 1999 .

Direct lactonization of alkenols via osmium tetroxide-mediated oxidative cleavage.

B. Borhan, J. Schomaker, B. Travis, 2003, Organic letters.

Direct Lactonization of Alkenols via Osmium Tetroxide Mediated Oxidative Cleavage.

B. Borhan, J. Schomaker, B. Travis, 2003 .

Recent updates and future perspectives in aziridine synthesis and reactivity.

J. Schomaker, Corey L Jones, Hillary J. Dequina, 2023, Chem.

Acylated and alkylated benzo(crown-ethers) form ion-dependent ion channels in biological membranes

Mahzad Dehghany, J. Schomaker, B. Chanda, 2022, Biophysical journal.

Rigidifying Ag(I) Complexes for Selective Nitrene Transfer

Minxue Huang, J. Schomaker, J. Paretsky, 2020 .

Regioselective Rh-Catalyzed Hydroformylation of 1,1,3-Trisubstituted Allenes Using BisDiazaPhos Ligand.

J. Schomaker, C. Landis, Josephine Eshon, 2017, The Journal of organic chemistry.

Unnatural α-amino acid synthesis

J. Schomaker, Tuan A Trinh, 2023, Nature Synthesis.

Intermolecular [3+3] ring expansion of aziridines to dehydropiperi-dines through the intermediacy of aziridinium ylides

J. Schomaker, I. Guzei, Israel Fernández, 2020, Nature Communications.

Recent Developments and Strategies for Mutually Orthogonal Bioorthogonal Reactions

J. Schomaker, Yun Hu, 2021, Chembiochem : a European journal of chemical biology.

Pd-catalyzed Heck-type Reactions of Allenes for Stereoselective Syntheses of Substituted 1,3-Dienes.

Logan E. Vine, J. Schomaker, 2021, Chemistry.

α,β-Unsaturated imines via Ru-catalyzed coupling of allylic alcohols and amines.

J. Schomaker, Jared W. Rigoli, Sara A. Moyer, 2012, Organic & biomolecular chemistry.

Tunable, Chemo- and Site-Selective Nitrene Transfer Reactions through the Rational Design of Silver(I) Catalysts.

J. Schomaker, Juliet M. Alderson, Joshua R. Corbin, 2017, Accounts of chemical research.

Synthesis of propargylic and allenic carbamates via the C-H amination of alkynes.

J. Schomaker, Jared W. Rigoli, S. D. Pearce, 2012, Organic letters.

Progress toward the Total Synthesis of Nogalamycin Using a Benzyne Cycloaddition Strategy.

Logan E. Vine, J. Schomaker, William T. Raskopf, 2024, The Journal of organic chemistry.

A Synthetic Strategy toward S-, N-, and O-Heterocyclooctynes Facilitates Bioconjugation Using Multifunctional Handles.

J. Schomaker, Kyana M. Sanders, Yun Hu, 2024, The Journal of organic chemistry.

Iron-Catalyzed Site- and Regioselective 1,2-Azidoamidations of 1,3-Dienes.

J. Schomaker, Ilia A. Guzei, Zhen Dai, 2023, Organic letters.

Total synthesis of haterumalides NA and NC via a chromium-mediated macrocyclization.

B. Borhan, J. Schomaker, 2008, Journal of the American Chemical Society.