J. Gladysz

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Recoverable catalysts. Ultimate goals, criteria of evaluation, and the green chemistry interface

J. Gladysz, 2001 .

Photophysics of diplatinum polyynediyl oligomers: chain length dependence of the triplet state in sp carbon chains.

K. Schanze, J. Gladysz, Richard T. Farley, 2008, Inorganic chemistry.

Syntheses of Families of Enantiopure and Diastereopure Cobalt Catalysts Derived from Trications of the Formula [Co(NH2CHArCHArNH2)3]3.

Anilesh Kumar, J. Gladysz, Subrata K. Ghosh, 2017, Inorganic chemistry.

Phase Transfer Activation of Fluorous Analogs of Grubbs’ Second-Generation Catalyst: Ring-Opening Metathesis Polymerization

Hassan S. Bazzi, R. C. D. Costa, J. Gladysz, 2012 .

Fluorous membrane ion-selective electrodes for perfluorinated surfactants: trace-level detection and in situ monitoring of adsorption.

Andreas Stein, Philippe Bühlmann, A. Stein, 2013, Analytical chemistry.

Potentiometric sensors based on fluorous membranes doped with highly selective ionophores for carbonate.

P. Bühlmann, D. Mandal, J. Gladysz, 2011, Journal of the American Chemical Society.

Transition Metal Formyl Complexes

J. Gladysz, 1982 .

Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents

D. Mandal, J. Gladysz, 2010 .

Festschrift in Honor of István T. Horváth

J. Gladysz, 2018, ACS Sustainable Chemistry & Engineering.

Recycling and Delivery of Homogeneous Fluorous Rhodium Catalysts Using Poly(tetrafluoroethylene): “Catalyst-on-a-Tape”

J. Gladysz, Long V. Dinh, M. Jurisch, 2017 .

Chapter 3. Fluorous Solvents

I. Ryu, H. Matsubara, J. Gladysz, 2007 .

"Heavy fluorous" cyclopentadienes and cyclopentadienyl complexes with three to five ponytails: facile syntheses from polybromocyclopentadienyl complexes, phase properties, and electronic effects.

J. Gladysz, Long V. Dinh, 2005, Chemistry.

"Catalyst-on-a-tape"-Teflon: a new delivery and recovery method for homogeneous fluorous catalysts.

J. Gladysz, Long V. Dinh, 2005, Angewandte Chemie.

Convenient syntheses of "heavy fluorous" cyclopentadienes and cyclopentadienyl complexes with three to five ponytails.

J. Gladysz, Long V. Dinh, 2004, Chemical communications.

Thermomorphic fluorous imine and thioether palladacycles as precursors for highly active Heck and Suzuki catalysts; evidence for palladium nanoparticle pathways

J. Gladysz, C. Rocaboy, 2003 .

Synthesis and properties of fluorous arenes and triaryl phosphorus compounds with branched fluoroalkyl moieties (“split pony tails”)

J. Gladysz, Florian Seidel, M. Wende, 2003 .

Convenient syntheses of fluorous phenols of the formula HOC6H5−n((CH2)3(CF2)7CF3)n (n=1, 2) and the corresponding triarylphosphites

J. Gladysz, R. Meier, C. Rocaboy, 2003 .

Highly active thermomorphic fluorous palladacycle catalyst precursors for the Heck reaction; evidence for a palladium nanoparticle pathway.

J. Gladysz, C. Rocaboy, 2002, Organic letters.

Convenient Syntheses of a Family of Easily Recoverable Fluorous Primary, Secondary, and Tertiary Aliphatic Amines NH3−x[(CH2)m(CF2)7CF3]x(m = 3−5; x = 1−3) − Fine Tuning of Basicities and Fluorous Phase Affinities

J. Gladysz, W. Bauer, C. Rocaboy, 2000 .

Strategy and design in fluorous phase immobilization:a systematic study of the effect of ‘pony tails’ (CH2)3(CF2) n−1CF3 on the partition coefficients of benzenoid compounds

J. Gladysz, D. Rutherford, B. Bennett, 2000 .

Transition metal catalysis in fluorous media: extension of a new immobilization principle to biphasic and monophasic rhodium-catalyzed hydrosilylations of ketones and enones

J. Gladysz, Long V. Dinh, 1999 .

Chemistry in fluorous media: a user's guide to practical considerations in the application of fluorous catalysts and reagents

J. Gladysz, L. Barthel-Rosa, 1999 .

Synthesis, structure, and interconversion of chiral rhenium oxygen- and sulfur-bound sulfoxide complexes of formula [(η5-C5H5)Re(NO)(PPh3)(OS(Me)R)]+ X−; diastereoselective oxidations of coordinated methyl alkyl sulfides

J. Gladysz, A. Arif, M. Otto, 2001 .

A Step‐Growth Approach to Metal‐Capped One‐Dimensional Carbon Allotropes: Syntheses of C12, C16, and C20 μ‐Polyynediyl Complexes

J. Gladysz, R. Dembinski, T. Bartik, 1996 .

Role of chlorides in reactivation of contaminant nickel on fluid catalytic cracking (FCC) catalysts

Bilge Yilmaz, J. Gladysz, William J Maximuck, 2021 .

Syntheses of Enantiopure Bifunctional 2‑Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon−Carbon Bond Forming Reactions

J. Gladysz, N. Bhuvanesh, T. Mukherjee, 2014 .

Syntheses and structural analyses of chiral rhenium containing amines of the formula (η5-C5H5)Re(NO)(PPh3)((CH2)nNRR′) (n = 0, 1)

J. Gladysz, F. Hampel, Sabine N. Seidel, 2010 .

Synthesis, structure, and reactivity of palladacycles that contain a chiral rhenium fragment in the backbone: New cyclometalation and catalyst design strategies.

J. Gladysz, F. Hampel, Florian K. Friedlein, 2006, Chemistry.

Generation and reactions of ruthenium phosphido complexes [(eta5-C5H5)Ru(PR'3)2(PR2)]: remarkably high phosphorus basicities and applications as ligands for palladium-catalyzed Suzuki cross-coupling reactions.

J. Gladysz, F. Hampel, Jose Giner Giner Planas, 2005, Chemistry.

Synthesis and Reactivity of 1,2‐ and 1,3‐Diphosphanes that Contain Four Chiral Rhenium Fragments: Architecturally Novel Tetrametallo‐DMPE and ‐DMPP Species that are Unprivileged Ligands for Enantioselective Catalysis

J. Gladysz, F. Hampel, Markus Prommesberger, 2005 .

A new family of chelating diphosphines with a transition metal stereocenter in the backbone: novel applications of "chiral-at-rhenium" complexes in rhodium-catalyzed enantioselective alkene hydrogenations.

J. Gladysz, F. Hampel, B. D. Zwick, 2001, Chemistry.

Electronic Structure and Chain‐Length Effects in Diplatinum Polyynediyl Complexes trans,trans‐[(X)(R3P)2Pt(CC)nPt(PR3)2(X)]: A Computational Investigation

J. Gladysz, F. Zhuravlev, 2004 .

Synthesis, structure, and reactivity of transition metal/main group metal bridging carboxylate complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(CO2MLn) (M = Li, K, Ge, Sn, Pb)

J. Gladysz, R. Larsen, D. R. Senn, 1987 .

New hydrogen bonding motifs of phosphine oxides with a silanediol, a phenol, and chloroform

J. Gladysz, J. Blümel, N. Bhuvanesh, 2019, Inorganica Chimica Acta.

Synthesis, purification, and characterization of phosphine oxides and their hydrogen peroxide adducts.

J. Gladysz, J. Blümel, N. Bhuvanesh, 2012, Dalton transactions.

A Metal-Capped Conjugated Polyyne Threaded through a Phenanthroline-Based Macrocycle. Probing beyond the Mechanical Bond to Interactions in Interlocked Molecular Architectures

J. Gladysz, N. Bhuvanesh, J. Halet, 2013 .

Catalysis Involving Fluorous Phases: Fundamentals and Directions for Greener Methodologies

J. Gladysz, 2010 .

Monophosphine and diphosphine ligands for diplatinum polyynediyl complexes: Efficient syntheses of new functionality-containing systems and model compounds

J. Gladysz, F. Zhuravlev, J. Stahl, 2007 .

A direct route from white phosphorus and fluorous alkyl and aryl iodides to the corresponding trialkyl- and triarylphosphines

J. Gladysz, C. Cummins, Subrata K. Ghosh, 2018 .

Ionic transformations in extremely nonpolar fluorous media: phase transfer catalysis of halide substitution reactions.

J. Gladysz, Crestina S. Consorti, M. Jurisch, 2007, Organic letters.

Chiral Cobalt(III) Tris(1,2-diamine) Catalysts That Incorporate Nitrogenous Base Containing Anions for the Bifunctional Activation of Nucleophiles and Electrophiles in Enantioselective Addition Reactions

J. Gladysz, Connor Q Kabes, Reagan F. Lucas, 2021 .

Launching Werner Complexes into the Modern Era of Catalytic Enantioselective Organic Synthesis.

J. Gladysz, Connor Q Kabes, Aaron R Wegener, 2020, Accounts of chemical research.

An Air and Water Stable Hydrogen Bond Donor Catalyst for the Enantioselective Generation of Quarternary Carbon Stereocenters by Additions of Substituted Cyanoacetate Esters to Acetylenic Esters.

J. Gladysz, Quang H. Luu, 2020, Chemistry.

Rendering classical hydrophilic enantiopure Werner salts [M(en)3]n+nX- lipophilic (M/n = Cr/3, Co/3, Rh/3, Ir/3, Pt/4); new chiral hydrogen bond donor catalysts and enantioselectivities as a function of metal and charge.

J. Gladysz, William J Maximuck, Carola Ganzmann, 2020, Dalton transactions.

Lipophilic chiral cobalt (III) complexes of hexaamine ligands: Efficacies as enantioselective hydrogen bond donor catalysts

J. Gladysz, William J Maximuck, 2019, Molecular Catalysis.

New methodology for the introduction of sulfur into organic molecules

J. Gladysz, V. K. Wong, B. S. Jick, 1979 .

Λ-[Co((S,S)-dpen)3]3+ 2I-B(C6F5)4-: A Second Generation Air- and Water-Stable Chiral Solvating Agent for Chirality Sensing (dpen = NH2CHPhCHPhNH2).

J. Gladysz, A. Hasaninejad, Quang H. Luu, 2020, The Journal of organic chemistry.

Neutral metal formyl complexes: generation, reactivity, and models for Fischer-Tropsch catalyst intermediates

W. Wong, J. Gladysz, W. Tam, 1979 .

Synthesis of fluorous sulfur/carbon/sulfur pincer ligands and palladium complexes: New catalyst precursors for the Heck reaction

J. Gladysz, M. Jurisch, R. C. Costa, 2008 .

Transition metal catalysis in fluorous media: Application of a new immobilization principle to rhodium-catalyzed hydrogenation of alkenes

J. Gladysz, I. Horváth, D. Rutherford, 1998 .

Organometallic reactivity patterns in fluorocarbons and implications for catalysis: Synthesis, structure, solubility, and oxidative additions of a fluorous analogue of Vaska's complex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2) 5CF3)3]2

J. Gladysz, I. Horváth, A. Arif, 1998 .

Synthesis, Structure, and Oxidative Additions of a Fluorous Analogue of Vaska's Complex, trans‐[IrCl(CO){P[CH2CH2(CF2)5CF3]3}2]— Altered Reactivity in Fluorocarbons and Implications for Catalysis

J. Gladysz, A. Arif, Marie-Andrée Guillevic, 1997 .

Triisopropylsilyl (TIPS) Alkynes as Building Blocks for Syntheses of Platinum Triisopropylsilylpolyynyl and Diplatinum Polyynediyl Complexes

J. Gladysz, M. Hall, F. Hampel, 2019, Organometallics.

Introduction to frontiers in transition metal catalyzed reactions (and a brief adieu).

J. Gladysz, 2011, Chemical Reviews.

Mechanism of Coupling of Methylidene to Ethylene Ligands in Dimetallic Assemblies; Computational Investigation of a Model for a Key Step in Catalytic C1 Chemistry.

J. Gladysz, M. Hall, Taveechai Wititsuwannakul, 2022, Journal of the American Chemical Society.

Towards One-Dimensional Carbon Wires Connecting Single Metal Centers: A Cumulenic C5 Chain that Mediates Charge Transfer between Rhenium and Manganese Termini†

J. Gladysz, W. Weng, T. Bartik, 1994 .

A synthetic breakthrough into an unanticipated stability regime: a series of isolable complexes in which C6, C8, C10, C12, C16, C20, C24, and C28 polyynediyl chains span two platinum atoms.

T. Peters, J. Gladysz, F. Hampel, 2006, Chemistry.

Appreciably bent sp carbon chains: synthesis, structure, and protonation of organometallic 1,3,5-triynes and 1,3,5,7-tetraynes of the formula (η5-C5Me5)Re(NO)(PPh3)((CC)n-p-C6H4Me)

J. Gladysz, S. Szafert, T. Lis, 1999 .

A phase based approach to insulated molecular wires: Diplatinum octatetraynediyl complexes bearing fluorous trialkylphosphine ligands

J. Gladysz, N. Bhuvanesh, M. Clough, 2016 .

Wire-like PtC[triple bond]CC[triple bond]CC[triple bond]CC[triple bond]CPt moieties surrounded by double-helical "insulation": new motifs featuring P(CH2)20P and P(CH2)4O(CH2)2O(CH2)4P linkages.

J. Gladysz, F. Hampel, Laura de Quadras, 2006, Dalton transactions.

Cubic nonlinear optical properties of platinum-terminated polyynediyl chains.

Gulliver T. Dalton, H. Ågren, M. Samoć, 2008, Inorganic chemistry.

Transition metal catalysis in fluorous media: Practical application of a new immobilization principle to rhodium-catalyzed hydroboration

J. Gladysz, J. Juliette, I. T. Horvath, 1997 .

Are teflon "ponytails" the coming fashion for catalysts?

J. Gladysz, 1994, Science.

Organometallics Roundtable 2013–2014

Patrick L. Holland, C. E. Webster, Connie C. Lu, 2014 .

Syntheses and Carbonyliridium Complexes of Unsymmetrically Substituted Fluorous Trialkylphosphanes: Precision Tuning of Electronic Properties, Including Insulation of the Perfluoroalkyl Groups

T. Soós, J. Gladysz, R. Meier, 2000 .

Photophysics of platinum tetrayne oligomers: delocalization of triplet exciton.

K. Schanze, Yongjun Li, J. Gladysz, 2014, The journal of physical chemistry. A.

Ring opening metathesis polymerization of an η4-benzene complex: a direct synthesis of a polyacetylene with a regular pattern of π bound metal fragments.

J. Gladysz, T. Fiedler, P. D. Zeits, 2012, Chemical communications.

Convenient protocols for Mizoroki-Heck reactions of aromatic bromides and polybromides with fluorous alkenes of the formula H2C[double bond, length as m-dash]CH(CF2)n-1CF3 (n = 8, 10).

Hassan S. Bazzi, M. Al‐Hashimi, J. Gladysz, 2016, Organic & biomolecular chemistry.

Square-Planar and Octahedral Gyroscope-Like Metal Complexes Consisting of Dipolar Rotators Encased in Dibridgehead Di(triaryl)phosphine Stators: Syntheses, Structures, Dynamic Properties, and Reactivity.

Leyong Wang, J. Gladysz, F. Hampel, 2022, Inorganic chemistry.

Syntheses, Structures, Reactivities, and Dynamic Properties of Gyroscope-like Complexes Consisting of Rh(CO)(X) or Rh(CO)2(I) Rotators and Cage-like Trans Aliphatic Dibridgehead Diphosphine Stators

Leyong Wang, J. Gladysz, F. Hampel, 2022, Organometallics.

Structures and Dynamics of Secondary and Tertiary Alkylphosphine Oxides Adsorbed on Silica.

J. Gladysz, N. Bhuvanesh, Sugam Kharel, 2019, Chemistry, an Asian journal.

Nonenzymic nitrogen fixation by an iron-molybdenum model for nitrogenase.

J. Gladysz, J. Miller, E. E. Van Temelen, 1973, Journal of the American Chemical Society.

Temperature-Controlled Catalyst Recycling: New Protocols Based upon Temperature-Dependent Solubilities of Fluorous Compounds and Solid/Liquid Phase Separations

J. Gladysz, Verona Tesevic, V. Tesevic, 2006 .

Synthesis, properties, and reactions of enantiomerically pure, chiral fluorous phosphines of the formula (menthyl)P(CH2CH2(CF2)n−1CF3)2 (n=6, 8)

J. Gladysz, A. Klose, 1999 .

Syntheses and structures of complexes of .alpha.,.beta.-unsaturated carbonyl compounds and the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+: divergent kinetic and thermodynamic O:C/C:C and O:C/C.tplbond.C binding selectivities

Dennis M. Dalton, J. Gladysz, A. Arif, 1993 .

Phase and redox shifted four iron/four sulfur clusters: fluorous analogs of metalloenzyme cofactors.

Hassan S. Bazzi, J. Gladysz, B. Holliday, 2015, Dalton transactions.

Introduction of sulphur into organic molecules via lithium triethylborohydride reduction of S8

J. Gladysz, V. K. Wong, B. S. Jick, 1978 .

Organometallics Roundtable 2011

T. Marks, B. Rieger, I. Manners, 2012 .

Syntheses, Structures, Reactivities, and Basicities of Quinolinyl and Isoquinolinyl Complexes of an Electron Rich Chiral Rhenium Fragment and Their Electrophilic Addition Products.

J. Gladysz, M. Hall, F. Hampel, 2021, Chemistry.

Origin of Shielding and Deshielding Effects in NMR Spectra of Organic Conjugated Polyynes.

J. Gladysz, M. Hall, Andreas Ehnbom, 2019, Organic letters.

Gas and Liquid Phase Diffusivities of Isomeric Metal Complexes Derived from Multifold Ring-Closing Metatheses: Ion Mobility Mass Spectrometry Trumps DOSY NMR

J. Gladysz, D. Russell, Liuxi Chen, 2016 .

Bimetallic anionic formyl complexes: synthesis and properties

J. Gladysz, W. Tam, M. Marsi, 1983 .

Synthesis and electrophile-induced disproportionation of the neutral formyl triphenylphosphinenitrosyl-.eta.-cyclopentadienylrhenium formyl ((.eta.-C5H5)Re(NO)(PPh3)(CHO))

W. Kiel, W. Wong, J. Gladysz, 2002 .

Olefin metatheses in metal coordination spheres: versatile new strategies for the construction of novel monohapto or polyhapto cyclic, macrocyclic, polymacrocyclic, and bridging ligands.

J. Gladysz, S. Szafert, F. Hampel, 2001, Chemistry.

Octahedral Werner complexes with substituted ethylenediamine ligands: a stereochemical primer for a historic series of compounds now emerging as a modern family of catalysts.

J. Gladysz, Subrata K. Ghosh, Kyle G. Lewis, 2016, Chemical Society reviews.

Frontiers in Metal-Catalyzed Polymerization: Designer Metallocenes, Designs on New Monomers, Demystifying MAO, Metathesis Déshabillé.

J. Gladysz, 2000, Chemical reviews.

Synthesis and decarboxylation mechanism of the chiral rhenium formate (.eta.-C5H5)Re(NO)(PPh3)(OCHO)

J. Gladysz, J. Merrifield, 1983 .

Monophasic and biphasic hydrosilylations of enones and ketones using a fluorous rhodium catalyst that is easily recycled under fluorous-organic liquid-liquid biphasic conditions

J. Gladysz, Long V. Dinh, 2005 .

A New Reaction of Coordinated Sulfoxides: Facile and Highly Diastereoselective Deprotonation of a Chiral, Cationic Rhenium DMSO Complex to an Ylide and Subsequent [1,2] Migration of Rhenium from Sulfur to Carbon

J. Gladysz, A. Arif, O. Meyer, 1995 .

Theoretical study on the spin-state energy splittings and local spin in cationic [Re]-Cn-[Re] complexes.

M. Reiher, J. Gladysz, J. Neugebauer, 2005, Inorganic chemistry.

Bonding and electronic structure in consanguineous and conjugal iron and rhenium sp carbon chain complexes [MC4M'](n)+: computational analyses of the effect of the metal.

J. Gladysz, H. Jiao, L. Toupet, 2003, Journal of the American Chemical Society.

Consanguineous Families of Coordinated Carbon: A ReC4Re Assembly That Is Isolable in Three Oxidation States, Including Crystallographically Characterized ReC⋮CC⋮CRe and +ReCCCCRe+ Adducts and a Radical Cation in Which Charge Is Delocalized between Rhenium Termini

G. Frenking, J. Gladysz, A. Arif, 1997 .

Syntheses, structures, and stabilities of aliphatic and aromatic fluorous iodine(I) and iodine(III) compounds: the role of iodine Lewis basicity

Hassan S. Bazzi, S. Ghosh, J. Gladysz, 2017, Beilstein journal of organic chemistry.

An Analogue of Grubbs Third‐Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase‐Transfer Activation of Ring‐Closing Alkene Metathesis

Hassan S. Bazzi, J. Gladysz, Zhenxing Xi, 2016 .

New Chiral Cyclopentadienylrhenium Lewis Acids Featuring Fluorinated Triarylphosphanes and Enhanced Acceptor Abilities − An Unusual Carbon−Fluorine Bond Activation in a Metal Coordination Sphere

J. Gladysz, H. Jiao, W. Mohr, 2001 .

Gyroscope-Like Complexes Based on Dibridgehead Diphosphine Cages That Are Accessed by Three-Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)3, Fe(CO)2(NO)(+), and Fe(CO)3(H)(+) Rotators.

Leyong Wang, J. Gladysz, J. Blümel, 2016, Journal of the American Chemical Society.

Gyroscope like molecules consisting of trigonal or square planar osmium rotators within three-spoked dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties.

J. Gladysz, F. Hampel, N. Bhuvanesh, 2016, Dalton transactions.

Multifold Ring‐Closing Olefin Metatheses in Syntheses of Organometallic Molecules with Unusual Connectivities

J. Gladysz, T. Fiedler, 2014 .

Gyroscope-like molecules consisting of PdX₂/PtX₂ rotators within three-spoke dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties.

M. Barbasiewicz, J. Gladysz, S. Szafert, 2014, Chemistry.

Gyroscope-Like Platinum and Palladium Complexes with Trans-Spanning Bis(pyridine) Ligands

J. Gladysz, F. Hampel, J. Reibenspies, 2012 .

Direct conversion of aldehydes, esters, and 1,2-oxides to alkanes with carbon skeleton preservation

J. Gladysz, E. E. Tamelen, 1974 .

Synthesis, structure, and reactivity of fluorous phosphorus/carbon/phosphorus pincer ligands and metal complexes.

J. Gladysz, F. Hampel, Róbert Tuba, 2005, Dalton transactions.

Alkene metatheses in transition metal coordination spheres: dimacrocyclizations that join trans positions of square-planar platinum complexes to give topologically novel diphosphine ligands.

J. Gladysz, F. Hampel, T. Shima, 2004, Dalton transactions.

Syntheses, chemical properties, and x-ray crystal structures of rhenium formaldehyde and thioformaldehyde complexes

J. Gladysz, M. C. Etter, C. Strouse, 1983 .

An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthesis of 2‐Substituted Benzimidazoles

J. Gladysz, H. Safaei, S. Nouri, 2014 .

Syntheses, Structures, and Catalytic Reactions of Palladium Adducts of Chiral Diphosphines that Contain a Rhenium Stereocenter in the Backbone

J. Gladysz, F. Hampel, K. Kromm, 2002 .

Reactions of organorhenium complexes (η5-C5H5)Re(NO)(PPh3)(CH2R) with Ph3C+ PF6-; analysis of the energetics of α-hydride abstraction

S. Georgiou, J. Gladysz, 1986 .

Introduction: recoverable catalysts and reagents-perspective and prospective.

J. Gladysz, 2002, Chemical reviews.

Gyroscopes and the chemical literature: 1852–2002☆

John A. Gladysz, J. Gladysz, Katrin Skopek, 2007 .

Syntheses and Structures of Diplatinum Hexatriynediyl Complexes, in Which the sp Carbon Chains Are Shielded by sp3 Carbon Chains

Gareth R. Owen, J. Gladysz, F. Hampel, 2004 .

Syntheses, properties, and x-ray crystal structures of stable methylidene complexes of the formula [(.eta.-C5Me5)Re(NO)(L)(:CH2)]+ PF6-

C. Knobler, J. Gladysz, C. Strouse, 1983 .

Syntheses and structures of missing links among polybromocyclopentadienyl rhenium and manganese tricarbonyl complexes

J. Gladysz, F. Hampel, Long V. Dinh, 2005 .

Activation of Single-Component Nickel(II) Polyethylene Catalysts via Phase Transfer of Fluorous Phosphine Ligands.

Hassan S. Bazzi, J. Gladysz, Zhenxing Xi, 2015, Journal of the American Chemical Society.

Chiral-at-ansa-Bridged Group 4 Metallocene Complexes {(R1R2C)-(3,6-tBu2Flu)(3-R3-5-Me-C5H2)}MCl2: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselective Propylene Polymerization

J. Gladysz, T. Roisnel, F. Hampel, 2011 .

Over four hundred million characters served: 99 volumes, 2567 articles, 85623 pages, and more than 85 million words.

J. Michl, J. Gladysz, R. Kuchta, 2000, Chemical reviews.

Syntheses and structures of square planar diplatinum butadiynediyl complexes with two different monophosphine ligands on each terminus; probing the feasibility of a new type of inorganic atropisomerism ☆ ☆☆

J. Gladysz, N. Bhuvanesh, S. Dey, 2017 .

Coordination-driven self-assembly, structures, and dynamic properties of diplatinum hexatriynediyl and butadiynediyl complexes in which the sp carbon chains are shielded by sp3 carbon chains: towards endgroup-endgroup interactions.

Gareth R. Owen, J. Gladysz, F. Hampel, 2008, Chemistry.

sp Carbon chains surrounded by sp3 carbon double helices: wire-like Pt(CC)nPt moieties that are spanned by two α,ω-diphosphines that bear heteroatoms or alkyl substituents

J. Gladysz, F. Hampel, E. Bauer, 2007 .

New C1-Symmetric Ph2C-Bridged Multisubstituted ansa-Zirconocenes for Highly Isospecific Propylene Polymerization: Synthetic Approach via Activated Fulvenes†

J. Gladysz, T. Roisnel, F. Hampel, 2010 .

Handbook of fluorous chemistry

István T. Horváth, Dennis P. Curran, John A. Gladysz, 2004 .

New synthetic chemistry of transition metal trialkylsilane complexes

J. Gladysz, 1984 .

Mononuclear anionic formyl complexes; synthesis and properties

D. W. Parker, J. Gladysz, M. Marsi, 1981 .

Synthesis and structure of chiral rhenium allyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(CH2C(R') = CHR)

J. Gladysz, R. Larsen, K. Emerson, 1989 .

Convenient Modular Syntheses of Fluorous Secondary Phosphines and Selected Derivatives

J. Gladysz, Róbert Tuba, C. Emnet, 2005 .

A promising new catalyst family for enantioselective cycloadditions involving allenes and imines: chiral phosphines with transition metal–CH2–P: linkages

J. Gladysz, A. Scherer, 2006 .

Synthesis, photovoltaic performances and TD-DFT modeling of push-pull diacetylide platinum complexes in TiO2 based dye-sensitized solar cells.

E. Blart, F. Odobel, Y. Pellegrin, 2014, Dalton transactions.

Fluorous chemistry: From biphasic catalysis to a parallel chemical universe and beyond

J. Gladysz, D. Curran, 2002 .

Syntheses and Structures of Unsymmetrically 1,1- and 1,2-Disubstituted Alkene Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: Enantioface Binding Selectivities and Conformational Equilibria

J. Gladysz, Jiaqi Pu, T. Peng, 1994 .

Mechanism of equilibration of diastereomeric chiral rhenium alkene complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+BF4-. The metal traverses between alkene enantiofaces without dissociation!

J. Gladysz, T. Peng, 1992 .

Synthesis, structure, and reactivity of .eta.2-1,3-diene and enyne complexes of the chiral rhenium Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: ozonolysis within a metal coordination sphere

J. Gladysz, A. Arif, Yan Wang, 1993 .

Synthesis and reactivity of metallacyclic manganese .alpha.-(silyloxy)alkyl complexes [cyclic] (CO)4MnC(R)(OSi(CH3)3)P(C6H5)2. A new thermodynamic driving force for carbonyl insertion

J. Gladysz, G. D. Vaughn, K. A. Krein, 1986 .

Werner‐Komplexe mit ω‐Dimethylaminoalkyl‐substitutierten Ethylendiaminliganden: bifunktionale H‐Brückendonor‐Katalysatoren für hoch enantioselektive Michael‐Additionen

J. Gladysz, N. Bhuvanesh, Subrata K. Ghosh, 2016 .

Werner Complexes with ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands: Bifunctional Hydrogen-Bond-Donor Catalysts for Highly Enantioselective Michael Additions.

J. Gladysz, N. Bhuvanesh, Subrata K. Ghosh, 2016, Angewandte Chemie.

Tris(1,2-diphenylethylenediamine)cobalt(III) Complexes: Chiral Hydrogen Bond Donor Catalysts for Enantioselective α-Aminations of 1,3-Dicarbonyl Compounds.

Anilesh Kumar, J. Gladysz, Subrata K. Ghosh, 2016, Organic letters.

Metal-Templated Hydrogen Bond Donors as “Organocatalysts” for Carbon–Carbon Bond Forming Reactions: Syntheses, Structures, and Reactivities of 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes

J. Gladysz, F. Hampel, T. Mukherjee, 2014 .

Isomerization of diastereoisomeric alkene complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(H2CCHR)]+; the alkene enantioface bound to the metal can ‘flip’ without alkene dissociation

J. Gladysz, T. Peng, 1990 .

A new carbon-hydrogen bond activation reaction: stereospecific abstraction of vinylic protons from rhenium alkene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+ BF4- by the base tert-BuO-K+

J. Gladysz, T. Peng, 1990 .

Stereoselective addition of cyanide ion to chiral rhenium π-aldehyde complexes of the formulae [(η5-C5H5)Re(NO)(PPh3)(η2-OCHR)]+ BF4−

J. Gladysz, C. Garner, J. M. Fernández, 1989 .

Thione Complexes of Group Vib Pentacarbonyls

J. Gladysz, R. Avakian, 1975 .

Reactions of (CO)5MnSiMe3 and CO with aldehydes and cyclic ethers. Syntheses of functionalized pentacarbonylmanganese acyls and homologated organic compounds

J. Gladysz, K. Brinkman, 1984 .

Convenient one-flask synthesis of dialkyl selenides and diselenides via lithium triethylborohydride reduction of Sex

J. Gladysz, J. Hornby, James E. Garbe, 1978 .

Crystal structure of an unusual bis(fluorous phosphine) ruthenium(III) complex derived from a fluorous Grubbs’ catalyst

J. Gladysz, F. Hampel, R. C. Costa, 2007 .

Catalysis of Intramolecular Morita–Baylis–Hillman and Rauhut–Currier Reactions by Fluorous Phosphines; Facile Recovery by Liquid/Solid Organic/Fluorous Biphase Protocols Involving Precipitation, Teflon® Tape, and Gore‐Rastex® Fiber

J. Gladysz, Florian Seidel, 2008 .

A NEW FORM OF COORDINATED CARBON: AN UNSUPPORTED LINEAR C3 CHAIN SPANNING TWO DIFFERENT TRANSITION METALS

J. Gladysz, A. Arif, J. A. Ramsden, 1993 .

A VERSATILE NEW ROUTE TO CARBON COMPLEXES OF THE FORMULA LNMC.TPLBOND.CM'L'N': DEPROTONATION AND METALATION OF THE TERMINAL ACETYLIDE COMPLEX (.ETA.5-C5ME5)RE(NO)(PPH3)(C.TPLBOND.CH)

J. Gladysz, A. Arif, J. A. Ramsden, 1992 .

Additions of carbon nucleophiles to acyclic imine complexes of the chiral rhenium Lewis acid [(η5-C5H5)Re(NO)(PPh3]+: controlling factors in 1,3-asymmetric induction and syntheses of non-racemic organic amines

J. Gladysz, G. A. Stark, 1998 .

Phase-Transfer Activation of Transition Metal Catalysts.

Hassan S. Bazzi, J. Gladysz, John A Gladysz, 2015, Chemistry.

Diastereoselective 1,2 Additions of Nucleophiles to Quinoline Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+

J. Gladysz, A. Arif, G. A. Stark, 1994 .

Thermodynamic Enantioface‐Binding Selectivities of Monosubstituted Alkenes to a Highly Discriminating Chiral Transition ‐Metal Lewis Acid; equilibration of diastereoisomeric (cyclopentadienyl)(alkene)(nitrosyl)(triphenylphosphine)rhenium complexes ([Re(η5–C5H5)(CH2 = CHR)(NO) (PPh3)]+BF 4−)

J. Gladysz, A. Arif, T. Peng, 1992 .

Platinum complexes containing or derived from olefinic phosphines P(X)((CH2)6CH CH2)2 (X = OH, Ph, (CH2)6CH CH2); ring closing metatheses, structures, and trans/cis isomerizations

J. Gladysz, M. Hall, N. Bhuvanesh, 2019, Polyhedron.

Synthesis, structure, and reactivity of doubly trans-spanning bis(dialkyl selenide) complexes; a new route to diselenamacrocycles via alkene metathesis in metal coordination spheres

J. Gladysz, N. Bhuvanesh, Hemant Joshi, 2018, Journal of Organometallic Chemistry.

Non-metal-templated approaches to bis(borane) derivatives of macrocyclic dibridgehead diphosphines via alkene metathesis

M. Barbasiewicz, J. Gladysz, T. Fiedler, 2018, Beilstein journal of organic chemistry.

Syntheses, Structures, and Thermal Properties of Gyroscope-like Complexes Consisting of PtCl2 Rotators Encased in Macrocyclic Dibridgehead Diphosphines P((CH2)n)3P with Extended Methylene Chains (n = 20/22/30) and Isomers Thereof

J. Gladysz, N. Bhuvanesh, Hemant Joshi, 2018, Organometallics.

Partially Shielded Fe(CO)3 Rotors: Syntheses, Structures, and Dynamic Properties of Complexes with Doubly trans Spanning Diphosphines, trans-Fe(CO)3(PhP((CH2)n)2PPh)

J. Gladysz, F. Hampel, T. Shima, 2017 .

Syntheses, Reactivity, Structures, and Dynamic Properties of Gyroscope-like Iron Carbonyl Complexes Based on Dibridgehead Diarsine Cages

J. Gladysz, N. Bhuvanesh, J. Reibenspies, 2016 .

Syntheses of gyroscope-like molecules via three-fold ring closing metatheses of bis(phosphine) complexes trans-LyM(P((CH2)nCHCH2)3)2, and extensions to bis(phosphite) complexes trans-Fe(CO)3(P(O(CH2)nCHCH2)3)2

J. Gladysz, K. Skopek, 2008 .

Generation of trans-spanning diphosphine ligands via alkene metathesis: Synthesis, structure, and dynamic behavior of a missing link in a series of square-planar platinum complexes

J. Gladysz, J. Blümel, T. Oeser, 2006 .

Molecular gyroscopes: [Fe(CO)(3)] and [Fe(CO)(2)(NO)](+) rotators encased in three-spoke stators; facile assembly by alkene metatheses.

Takanori Shima, Frank Hampel, J. Gladysz, 2004, Angewandte Chemie.

Alkene Metatheses in Transition Metal Coordination Spheres: Effect of Ring Size and Substitution on the Efficiencies of Macrocyclizations That Join trans Positions of Square-Planar Platinum Complexes

J. Gladysz, F. Hampel, E. Bauer, 2003 .

Tungsten-Catalyzed Alkyne Metatheses in Transition-Metal Coordination Spheres: Versatile New Syntheses of Metallamacrocycles

J. Gladysz, S. Szafert, E. Bauer, 2003 .

Olefin metatheses in metal coordination spheres: A new approach to steric shielding in dirhenium sp carbon chain complexes of the formula (η5-C5Me5)-Re(NO)(PR3) (C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5)

J. Gladysz, J. Martín-Álvarez, C. Horn, 2002 .

Olefin Metatheses in Metal Coordination Spheres: A New Strategy for Cyclic and Macrocyclic Organometallic Compounds

J. Gladysz, F. Hampel, J. Martín-Álvarez, 1999 .

Dibridgehead diphosphines that turn themselves inside out.

Ryan M. Laddusaw, M. Barbasiewicz, J. Gladysz, 2011, Angewandte Chemie.

Synthetic approaches to the chiral, pyramidal, transition-metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+X-. Generation, characterization, and reactions of a dichloromethane adduct

J. Gladysz, J. M. Fernández, 1989 .

Synthesis, optical resolution, and absolute configuration of pseudotetrahedral organorhenium complexes (.eta.-C5H5)Re(NO)(PPh3)(X)

J. Gladysz, C. Strouse, J. Merrifield, 1982 .

A Novel Heterobimetallic Asymmetric Hydrogenation Catalyst Based Upon a Chiral Rhenium Template Containing Two Phosphido Substituents

J. Gladysz, A. Arif, B. D. Zwick, 1987 .

Binuclear and mixed metal formyl complexes: isolation, characterization, and chemistry

J. Gladysz, W. Tam, 1978 .

Update 1 of: Carbon in one dimension: structural analysis of the higher conjugated polyynes.

J. Gladysz, S. Szafert, and Slawomir Szafert, 2006, Chemical reviews.

New mechanistic probes of hydride abstraction from rhenium-alkyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(R) by Ph3C+ PF6-. Evidence for initial electron transfer

J. Gladysz, V. Parker, M. Nielsen, 1987 .

Syntheses of cyclic imine complexes of the chiral rhenium Lewis acid [(ν5-C5H5) Re(NO)(PPh3)]+ by hydride ion abstraction from amido complexes

J. Gladysz, G. B. Richter‐Addo, W. Cantrell, 1994 .

Selective binding and activation of one aldehyde enantioface by a chiral transition-metal Lewis acid: synthesis, structure, and reactivity of rhenium aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-O:CHR)]+X-

J. Gladysz, J. Kowalczyk, C. Garner, 1990 .

Chiral Recognition in π Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids; Development of a General Model for Enantioface Binding Selectivities

J. Gladysz, Brian J. Boone, 1997 .

Reactions of t-BuOK and Dibenzyl, Benzyl Allyl, and Allyl β-Keto Sulfide Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+: Highly Diastereoselective or Chemoselective [2,3]-Sigmatropic Rearrangements

J. Gladysz, D. Vichard, O. Meyer, 1996 .

Synthesis, structure, and dynamic behavior of rhenium sulfide and sulfoxide complexes of the formula [(.eta.5-C5H5)Re(NO)(L)(XRR')]+X'- (X = S, SO)

J. Gladysz, A. Arif, N. Mendez, 1991 .

Synthesis and properties of chiral rhenium ether complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(OR2)]+ X-

J. Gladysz, J. M. Fernández, S. Agbossou, 1990 .

Synthesis, structure, and reactivity of the thioformaldehyde complex [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-H2C:S)]+ PF6-

S. Georgiou, J. Gladysz, M. C. Etter, 1986 .

Convenient one-flask synthesis of dialkyl selenides and diselenides via lithium triethylborohydride reduction of Sex

J. Gladysz, J. Hornby, James E. Garbe, 1978 .

Fluorous phase-transfer activation of catalysts: application of a new rate-enhancement strategy to alkene metathesis.

J. Gladysz, Rosenildo Correa da Costa, 2006, Chemical communications.

Generation and reactions of chiral, pyramidal, transition-metal Lewis acids, .eta.5-cyclopentadienylnitrosyl(triphenylphosphine)rhenium(1+) complexes

J. Gladysz, J. M. Fernández, 1986 .

An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthesis of 2‐Substituted Benzimidazoles.

J. Gladysz, H. Safaei, S. Nouri, 2015 .

Structures of propionaldehyde, butyraldehyde, and pivalaldehyde complexes of the chiral rhenium fragment [(η5-C5H5)Re(NO)(PPh3)]+

J. Gladysz, A. Arif, D. P. Klein, 1993 .

HYDRIDE TRANSFER REACTIONS OF ANIONIC METAL FORMYL COMPLEXES: A MECHANISTIC TEST

J. Gladysz, J. Merrifield, J. H. Merrifield, 1978 .

Highly Active Families of Catalysts for the Ring-Opening Polymerization of Lactide: Metal Templated Organic Hydrogen Bond Donors Derived from 2-Guanidinobenzimidazole

J. Gladysz, C. Thomas, Coralie Thomas, 2014 .

Syntheses, structures, and reactions of cyrhetrenylphosphines; applications in palladium catalyzed Suzuki cross-coupling reactions

A. H. Klahn, J. Gladysz, N. Bhuvanesh, 2014 .

Transition-metal-containing chiral bidentate ligands for enantioselective catalysis: non-metallocene architectural units come of age.

J. Gladysz, O. Delacroix, 2003, Chemical communications.

Enantioselective Synthesis of Organosulfur Compounds via [2,3] Rearrangements of Ylides Derived from Di(allyl) and Di(propargyl) Sulfide Complexes. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary

J. Gladysz, A. Arif, O. Meyer, 1995 .

Enantioselective Syntheses of Organosulfur Compounds via [2,3] Sigmatropic Rearrangements of Ylides of Diallyl and Dipropargyl Sulfonium Salts. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition-Metal Auxiliary

J. Gladysz, A. Arif, P. C. Cagle, 1994 .

Synthesis and reactivity of metal .alpha.-hydroxyalkyl complexes; generation of (CO)5MCH(C6H5)OH (M = Mn, Re)

J. Gladysz, C. Strouse, J. C. Selover, 1986 .

.alpha.-Silyloxy and .alpha.-hydroxy manganese alkyls. Generation via a new five-membered metallocycle

J. Gladysz, C. Strouse, J. C. Selover, 1978 .

Steric control of the in/out sense of bridgehead substituents in macrobicyclic compounds: isolation of new "crossed chain" variants of in/out isomers.

J. Gladysz, D. Taher, N. Bhuvanesh, 2015, Chemical communications.

One-flask preparation of analytically pure dipotassium tetracarbonylferrate

J. Gladysz, W. Tam, 1978 .

Phase transfer of enantiopure Werner cations into organic solvents: an overlooked family of chiral hydrogen bond donors for enantioselective catalysis.

J. Gladysz, Carola Ganzmann, 2008, Chemistry.

Cleavage of the rhenium-methyl bond of (.eta.-C5H5)Re(NO)(PPh3)(CH3) by protic and halogen electrophiles: stereochemistry at rhenium

J. Gladysz, W. E. Buhro, J. Merrifield, 1984 .

The Solid State - Introduction

J. Michl, J. Gladysz, 1988 .

Structural, physical, and chemical properties of fluorous compounds.

J. Gladysz, M. Jurisch, 2012, Topics in current chemistry.

Syntheses and reactivity of analogues of grubbs' second generation metathesis catalyst with fluorous phosphines : A new phase-transfer strategy for catalyst activation

J. Gladysz, R. C. Costa, 2007 .

Chemical stability and application of a fluorophilic tetraalkylphosphonium salt in fluorous membrane anion-selective electrodes

P. Bühlmann, D. Mandal, J. Gladysz, 2010 .

Fluorophilic ionophores for potentiometric pH determinations with fluorous membranes of exceptional selectivity.

P. Bühlmann, J. Gladysz, J. Rábai, 2008, Analytical chemistry.

Hydrogen bonding motifs in structurally characterized salts of the tris(ethylenediamine) cobalt trication, [Co(en)3]3+; An interpretive review, including implications for catalysis

J. Gladysz, Subrata K. Ghosh, Kyle G. Lewis, 2017 .

Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions: A New Strategy for High-Activity Systems

J. Gladysz, F. Hampel, Sandra Eichenseher, 2005 .

Synthesis, structure, and reactivity of fluorous phosphorus/carbon/phosphorus pincer complexes derived from P(CH2)5P backbones

J. Gladysz, Crestina S. Consorti, F. Hampel, 2006 .

Highly stereoselective reduction of methyl ketone complexes of the chiral Lewis acid [(η5-C5H5)Re(NO)(PPh3)]+ by K(s-C4H9)3BH; synthesis of optically active secondary alcohols and derivatives

Dennis M. Dalton, J. Gladysz, 1989 .

Reactions of Diazo Compounds and Chiral Rhenium Alkylidene Complexes of the Formula [(η5‐C5H5)Re(NO)(PPh3)(CHR)]+ PF −6 A Versatile and Highly Stereoselective Route to Alkene Complexes

J. Gladysz, V. Wang, 1995 .

Synthesis and reactivity of bridging bis(alkyl) and bis(alkylidene) complexes derived from the chiral rhenium fragment [η5-C5H5)Re(NO)(PPh3)]+

J. Gladysz, C. Roger, T. Peng, 1992 .

Synthesis, Structure, and Reactivity of Chiral Rhenium Amido Complexes of the Formula (η5‐C5H5)Re(NO)(PPh3)(NRR')

J. Gladysz, A. Arif, D. Knight, 1992 .

Synthesis and Reactivity of Functionalized Dimethylsilyl Complexes of the Formula (η5‐C5H5)Re(NO)(PPh3)(SiMe2X); New Base‐Stabilized Silylene Complexes, Novel Lewis Acid Adducts, and Evidence for Base‐Free Silylene Complexes

J. Gladysz, A. Arif, K. E. Lee, 1991 .

Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula [(η5‐C5H5)Re(NO)(PPh3)(ROH)]⊕BF4⊖

Whitney W. Smith, J. Gladysz, S. Agbossou, 1990 .

Synthesis and reactivity of functionalized rhenium germyl complexes (η5-C5H5)Re(NO)(PPh3)(GePh2X); dynamic equilibria with germylene complex [(η5-C5H5)Re(NO)(PPh3)(GePh2)]+X−

J. Gladysz, K. E. Lee, 1988 .

Reactions of chiral (.alpha.-methoxyvinyl)rhenium complexes (.eta.5-C5H5)Re(NO)(PPh3)(C(OCH3)=CHR) with alkyl halides. Efficient 1,3-asymmetric induction

J. Gladysz, D. Smith, 1985 .

Electrochemical oxidation of rhenium alkyl complexes of the type [Re(.eta.-C5H5)(NO)(PPh3)R]: implications for the mechanism of hydride abstraction by Ph3C+PF6-

J. Gladysz, S. R. Cooper, M. Asaro, 1985 .

Synthesis, conformation, and reactivity of the rhenium phosphide complex (diphenylphosphido)(triphenylphosphine)nitrosyl(.eta.5-cyclopentadienyl)rhenium. The "Gauche effect" in transition metal chemistry

S. Georgiou, J. Gladysz, J. Hutchinson, 1985 .

Reactions of benzylrhenium complexes (.eta.5-C5H5)Re(NO)(L)(CH2Ar) with Ph3C+PF6. Analysis of the Re-C.alpha. rotamers involved in .alpha.-hydride abstraction

W. Kiel, J. Gladysz, W. E. Buhro, 1984 .

Mechanism of coupling of methylidene to ethylene at a homogeneous (triphenylphosphine)nitrosyl(.eta.-cyclopentadienyl)rhenium(+) [(.eta.-C5H5)Re(NO)(PPh3)]+ center. Remarkable enantiomer self-recognition

W. Kiel, J. Gladysz, G. Lin, 1983 .

Synthesis and properties of [(.eta.-C5H5)Re(NO)(PPh3)(:CHC6H5)]+PF6-: a benzylidene complex that is formed by a stereospecific .alpha.-hydride abstraction, exists as two geometric isomers, and undergoes stereospecific nucleophilic attack

W. Kiel, J. Gladysz, O. Eisenstein, 1982 .

Synthesis, crystal structure, and reactions of the 17-valence-electron rhenium methyl complex [(η5-C5Me5)Re(NO)(P(4-C6H4CH3)3)(CH3)]+ B(3,5-C6H3(CF3)2)4−: experimental and computational bonding comparisons with 18-electron methyl and methylidene complexes

J. Gladysz, H. Jiao, F. Hampel, 2000 .

A convenient preparation of metal carbonyl monoanions by trialkylborohydride cleavage of metal carbonyl dimers; observation and reactions of a bimetallic manganese-formyl intermediate

G. Williams, J. Gladysz, D. Johnson, 1977 .

Generation and reactivity of the chiral rhenium chlorobenzene complex [(η5-C5H5)Re(NO)(PPh3)(ClC6H5)]+BF−4: an improved functional equivalent of the chiral Lewis acid [(η5-C5H5)Re(NO)(PPh3)]+BF−4

J. Gladysz, J. Kowalczyk, S. Agbossou, 1990 .

Surface reactivity studies of bimetallic complexes, (η5-C5Me5)Re(NO)(PPh3)(CC)n(Ph3P)(ON)Re(η5-C5Me5) (n=2,4,6): candidates for molecular wires

D. Naugle, D. Cocke, J. Gladysz, 2000 .

Synthesis and structure of the rhenium phenylamido complex re(η5-C5H5)(NO)(PPh3)(NHPh); an unprecedented pyramidal amido ligand

J. Gladysz, A. Arif, M. Dewey, 1991 .

Reaction of the ylide complex [(η5-C5H5)Re(NO)(PPh3)(CH2P+Ar3)]PF6– with η-butyl-lithium–tetramethylenediamine; generation and stereospecific alkylation of a transition metal-substituted Wittig reagent

J. Gladysz, G. Crocco, 1986 .

Cyclometallapolysulfanes (and Selanes) of Bis(η5‐Cyclopentadienyl) Titanium(IV), Zirconium(IV), Molybdenum(IV), and Tungsten(IV)

A. Shaver, J. Gladysz, F. Bottomley, 2007 .

Reactions of ketals and acetals with (CO)5MnSi(CH3)3. A new vinyl ether synthesis

J. Gladysz, M. Marsi, 1982 .

Organic transformations via metal silane reagents: syntheses of vinyl ethers from dimethyl ketals and (CO)5MnSi(CH3)3

J. Gladysz, M. Marsi, 1982 .

Bis[1,3‐Bis(Trifluoromethyl)Benzene] Chromium‐(0), [1,3‐(Cf3)2C6h4]2Cr

K. Klabunde, J. Gladysz, H. F. Efner, 2007 .

Hydrogen bonding in organometallic ligands and possible implications for carbon monoxide/hydrogen molecule chemistry, First carbonylation of an isolable metal .alpha.-hydroxyalkyl complex

J. Gladysz, G. D. Vaughn, 1984 .

Alkylation and acylation of the iron carbonyl anion [(CO)4FeSi(CH3)3]-. Evidence for 1,3-silatropic shifts from iron to acyl oxygen

J. Gladysz, A. J. Blakeney, K. Brinkman, 1984 .

Regiospecific, diastereospecific and enantiospecific nucleophilic additions to chiral monosubstituted alkene complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(H2CCHR)]+ BF4−

J. Gladysz, T. Peng, 1990 .

New deoxygenative transformations; reactions of (CO)4Fe[Si(CH3)3]2 with acyclic ethers

J. Gladysz, A. J. Blakeney, 1981 .

Preparation and alkylation reactions of K+[(CO)4FeSi(CH3)3]−; Reductive elimination of tetramethylsilane from isolable (CO)4FeRSi(CH3)3 complexes

J. Gladysz, A. J. Blakeney, 1981 .

Preparation and properties of (η-C5H5)2ZrCl[Si(CH3)3] and (η-C5H5)2Zr[Si(CH3)3]2; trimethylsilyl group transfer from mercury to zirconium

J. Gladysz, A. J. Blakeney, 1980 .

29Si NMR spectra of metal carbonyl silanes by the selective population transfer method

J. Gladysz, D. Johnson, K. Servis, 1979 .

New approaches to high-activity transition-metal catalysts for carbon-carbon bond forming reactions. Rhenium-containing phosphorus donor ligands for palladium-catalyzed Suzuki cross-couplings.

J. Gladysz, Sandra Eichenseher, K. Kromm, 2002, Chemical communications.

Fluorous catalysis under homogeneous conditions without fluorous solvents: a "greener" catalyst recycling protocol based upon temperature-dependent solubilities and liquid/solid phase separation.

J. Gladysz, M. Wende, 2003, Journal of the American Chemical Society.

Fluorous catalysis without fluorous solvents: a friendlier catalyst recovery/recycling protocol based upon thermomorphic properties and liquid/solid phase separation.

J. Gladysz, R. Meier, M. Wende, 2001, Journal of the American Chemical Society.

Aldehyde and ketone ligands in organometallic complexes and catalysis

J. Gladysz, Y. Huang, 1988 .

REACTIONS OF (CO)5MNSI(CH3)3 WITH ORGANIC CARBONYL COMPOUNDS

J. Gladysz, D. Johnson, 1981 .

Synthesis and reactivity of chiral metal fluoride and water complexes derived from the rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+

A. Igau, J. Gladysz, C. Roger, 1992 .

Nucleophilic additions to the chiral rhenium alkene complexes [Re(η5-C5H5)(NO)(PPh3)(H2CCHR)]BF4(R = H, Me, CH2CH2Me, Ph or CH2Ph): regio-, diastereo- and enantio-selectivities

J. Gladysz, A. Arif, T. Peng, 1995 .

Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium-Catalyzed Hydroborations of Alkenes and Alkynes

J. Gladysz, I. Horváth, D. Rutherford, 1999 .

Synthesis and oxidation of chiral rhenium phosphine methyl complexes of the formula (η5-C5Me5)Re(NO)(PR3)(CH3): in search of radical cations with enhanced kinetic stabilities

W. Wong, J. Gladysz, J. Bras, 2000 .

Syntheses and structures of σ-pyridine, quinoline, and isoquinoline complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(NCxHy)]+ CF3SO3−

J. Gladysz, A. Arif, M. Dewey, 1990 .

Deoxygenation and desulfurization of organic compounds via transition metal atom cocondensation

B. Cho, J. Gladysz, M. Hasegawa, 1980 .

Facile separations of enantiomers of chiral organometallic compounds with a Bakerbond Chiralcel HPLC column

J. Gladysz, C. Garner, J. A. Ramsden, 1991 .

X-Ray crystal structure and chemical transformations of the neutral metal formyl [(η-C5H5)Re(PPh3)(NO)(CHO)]

W. Wong, J. Gladysz, W. Tam, 1979 .

Computational Investigation of Dichloromethane Ligand Substitution in the Enantiopure Cation [(η5-C5H5)Re(NO)(PPh3)(ClCH2Cl)]+, a Functional Equivalent of a Chiral Lewis Acid

J. Gladysz, M. Hall, Taveechai Wititsuwannakul, 2021 .

Transition Metal Formyl Complexes and Transition Metal Anions; Synthesis by Trialkylborohydride Attack on Metal Carbonyl Compounds

J. Gladysz, 1978 .

A versatile new synthesis of organic compounds with chiral methyl groups: stereochemistry of protolytic rhenium-carbon bond cleavage in chiral alkyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(R)

Motomasa Kobayashi, J. Gladysz, H. Floss, 1987 .

Syntheses and Structures of Digold Complexes of Macrobicyclic Dibridgehead Diphosphines That Can Turn Themselves Inside Out

J. Gladysz, N. Bhuvanesh, J. Reibenspies, 2011 .

An isolable organometallic cation radical in which a C4 chain conducts charge between two chiral and configurationally stable rhenium termini

J. Gladysz, Jeffery W. Seyler, Yuanlin Zhou, 1993 .

Synthesis of metal carbonyl monoanions by trialkylborohydride cleavage of metal carbonyl dimers: a convenient one-flask preparation of metal alkyls, metal acyls, and mixed-metal compounds

D. W. Parker, G. Williams, J. Gladysz, 1979 .

New families of coordinated carbon: oxidative coupling and cross-coupling of a transition metal butadiynyl complex to bimetallic M–CCCCCCCC–M and M–CCCCCC–M adducts

J. Gladysz, M. Brady, Weiqing Weng, 1994 .

Syntheses, Structures, and Spectroscopic Properties of 1,10-Phenanthroline Based Macrocycles threaded by PtC8Pt, PtC12Pt, and PtC16Pt Axles: Metal-capped Rotaxanes as Insulated Molecular Wires.

J. Gladysz, N. Bhuvanesh, J. Reibenspies, 2019, Chemistry.

Rotaxanes Derived from Dimetallic Polyynediyl Complexes: Extended Axles and Expanded Macrocycles

J. Gladysz, N. Bhuvanesh, H. Amini, 2014 .

A new type of insulated molecular wire: a rotaxane derived from a metal-capped conjugated tetrayne.

J. Gladysz, J. Reibenspies, S. Gauthier, 2012, Chemical communications.

Metal complexes of sulfur-containing ligands. Synthesis and properties of a series of rhenium-substituted sulfonium salts [(.eta.5-C5H5)Re(NO)(PPh3)(CH2)]nS+(CH3)3-n(n = 1-3)

J. Gladysz, W. B. Gleason, F. B. Mccormick, 1986 .

Cyclopentadienyl Rhenium Complexes

J. Gladysz, Kevin P. Gable, C. Garner, 2007 .

Metal Complexes of Sulfur-Containing Ligands. Synthesis and Properties of a Series of Rhenium-Substituted Sulfonium Salts ((η5-C5H5)Re(NO)(PPh3)(CH2-))nS+(CH3)3-n (n = 1-3).

J. Gladysz, W. B. Gleason, F. B. Mccormick, 1987 .

Structures and unexpected dynamic properties of phosphine oxides adsorbed on silica surfaces.

J. Gladysz, J. Blümel, N. Bhuvanesh, 2014, Chemistry.

Unprecedented regiospecificity and stereospecificity in reactions of Ph3C+PF6- with rhenium alkyls of the formula (.eta.-C5H5)Re(NO)(PPh3)(CH2R)

W. Kiel, J. Gladysz, G. Lin, 1980 .

Acetylpentacarbonylmanganese and Acetylpentacarbonylrhenium

J. Gladysz, C. Lukehart, B. Dombek, 2007 .

Synthesis, structure, dynamic behavior, and reactivity of rhenium phosphido complexes (.eta.5-C5H5)Re(NO)(PPh3)(PR2): the gauche effect in transition-metal chemistry

S. Georgiou, J. Gladysz, J. Hutchinson, 1988 .

Towards multistranded molecular wires: syntheses, structures, and reactivities of tetraplatinum bis(polyynediyl) complexes with [upper bond 1 start]Pt-C(x)-Pt-(P(CH2)3P)2-Pt-C(x)-Pt-(P(CH2)3P[upper bond 1 end])2 cores (x = 4, 6, 8).

Gareth R. Owen, J. Gladysz, F. Hampel, 2010, Dalton transactions.

Bent and stretched but not yet to the breaking point: C(8)-C(16) sp carbon chains that span two platinum atoms and the first structurally characterized 1,3,5,7,9,11,13,15-octayne.

J. Gladysz, F. Hampel, J. Stahl, 2001, Inorganic chemistry.

C8 and C12 sp Carbon Chains That Span Two Platinum Atoms: The First Structurally Characterized 1,3,5,7,9,11-Hexayne

T. Peters, J. Gladysz, J. Bohling, 1999 .

Syntheses, Structural Studies, and Copper Iodide Complexes of Macrocycles Derived from Williamson Ether Syntheses Involving 2,9-Bis(4-hydroxyphenyl)-1,10-phenanthroline, α,ω-Dibromides, and Resorcinol or 2,7-Dihydroxynaphthalene

J. Gladysz, N. Bhuvanesh, J. Reibenspies, 2017 .

Chiral Tricationic Tris(1,2-diphenylethylenediamine) Cobalt(III) Hydrogen Bond Donor Catalysts with Defined Carbon/Metal Configurations; Matched/Mismatched Effects upon Enantioselectivities with Enantiomeric Chiral Counter Anions

Anilesh Kumar, J. Gladysz, William J Maximuck, 2020 .

Configurational processes in coordinated ligands. Extremely facile phosphorus inversion in the pyramidal terminal phosphide complexes (.eta.5-C5H5)Re(NO)(PPh3)(PRR')

J. Gladysz, W. E. Buhro, 1985 .

"Giant" gyroscope-like molecules consisting of dipolar Cl-Rh-CO rotators encased in three-spoke stators that define 25-27-membered macrocycles.

Frank Hampel, Leyong Wang, J. Gladysz, 2006, Angewandte Chemie.

The robust, readily available cobalt(iii) trication [Co(NH2CHPhCHPhNH2)3]3+ is a progenitor of broadly applicable chirality and prochirality sensing agents

J. Gladysz, N. Bhuvanesh, Quang H. Luu, 2018, Chemical science.

A computational study of hydrogen bonding motifs in halide, tetrafluoroborate, hexafluorophosphate, and tetraarylborate salts of chiral cationic ruthenium and cobalt guanidinobenzimidazole hydrogen bond donor catalysts; acceptor properties of the “BArf” anion

J. Gladysz, M. Hall, Taveechai Wititsuwannakul, 2020 .

New Forms of Coordinated Carbon: Wirelike Cumulenic C3 and C5 sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer

J. Gladysz, S. Szafert, T. Bartik, 1998 .

Fluorous Solvents and Related Media

J. Gladysz, C. Emnet, 2005 .

Homeomorphic Isomerization as a Design Element in Container Molecules; Binding, Displacement, and Selective Transport of MCl2 Species (M = Pt, Pd, Ni).

J. Gladysz, D. Taher, N. Bhuvanesh, 2017, Journal of the American Chemical Society.

Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis

J. Gladysz, N. Bhuvanesh, Subrata K. Ghosh, 2015, ACS central science.

Facile and Selective Carbonylation of Methane in Superacids

J. Gladysz, I. Horváth, P. J. D. Rege, 2002 .

A synthetic breakthrough into an unanticipated stability regime: readily isolable complexes in which C16-C28 polyynediyl chains span two platinum atoms.

J. Gladysz, Qinglin Zheng, 2005, Journal of the American Chemical Society.

Synthesis, structure, and reactivity of sp carbon chains with bis(phosphine) pentafluorophenylplatinum endgroups: butadiynediyl (C4) through hexadecaoctaynediyl (C16) bridges, and beyond.

J. Gladysz, F. Hampel, J. Stahl, 2003, Chemistry.

Carbon in one dimension: structural analysis of the higher conjugated polyynes.

J. Gladysz, S. Szafert, and Slawomir Szafert, 2003, Chemical reviews.

A surprise landing on the terra incognita of macrocyclic dibridgehead diorganoarsines: syntheses, structures, and reactivities.

J. Gladysz, N. Bhuvanesh, Samuel R Zarcone, 2022, Chemical communications.

Three-Fold Intramolecular Ring Closing Alkene Metatheses of Square Planar Complexes with cis Phosphorus Donor Ligands P(X(CH2) mCH═CH2)3 (X = -, m = 5-10; X = O, m = 3-5): Syntheses, Structures, and Thermal Properties of Macrocyclic Dibridgehead Diphosphorus Complexes.

J. Gladysz, F. Hampel, N. Bhuvanesh, 2018, Journal of the American Chemical Society.

Octahedral Gyroscope-like Molecules Consisting of Rhenium Rotators within Cage-like Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties.

J. Gladysz, F. Hampel, T. Fiedler, 2017, Inorganic chemistry.

Synthesis, structure, and reactivity of stable alkyl and aryl iodide complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(IR)] +BF4 -

J. Gladysz, C. Winter, A. Arif, 1989 .

Mechanism of isomerization of rhenium alkylidene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(:CRCHR'R'')]+X- to alkene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(RHC:CR'R'')]+X-: an organometallic Wagner-Meerwein-type rearrangement

J. Gladysz, C. Roger, Gerardo S. Bodner, 1991 .

A new catalyst for the epimerization of secondary alcohols: carbon-hydrogen bond activation in the rhenium alkoxide complexes (.eta.5-C5R5)Re(NO)(PPh3)(OCHRR')

J. Gladysz, C. Garner, I. Saura-Llamas, 1991 .

Reactions of the neohexyl iodide complex [(.eta.5-C5H5)Re(NO)(PPh3)(ICH2CH2C(CH3)3)]+BF4- and nucleophiles: stereochemistry of carbon-iodine bond cleavage in highly accelerated SN2 reactions

A. Igau, J. Gladysz, 1991 .

Synthesis, structure, and reactivity of chiral rhenium alkyne complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(RC.tplbond.CR')]+BF4-

J. Gladysz, A. Arif, J. Kowalczyk, 1991 .

Synthesis, Structure, and Reactivity of Chiral Rhenium Cycloalkene Complexes of the Formula ; Facile Vinylic Deprotonation of a Coordinated Alkene

J. Gladysz, A. Arif, J. Kowalczyk, 1991 .

Synthesis, structure, and reactivity of functionalized germyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(GePh2X): equilibria involving the germylene complex [(.eta.5-C5H5)Re(NO)(PPh3)(:GePh2)]+ TfO-

J. Gladysz, A. Arif, K. E. Lee, 1991 .

Selective activation of one methyl ketone enantioface via .sigma.-binding to a chiral transition-metal template: synthesis, structure, and reactivity of rhenium ketone complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.1-O:C(CH3)R)]+X-

Dennis M. Dalton, J. Gladysz, A. Arif, 1990 .

Thermodynamic Aldehyde Enantioface Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomeric π‐Aldehyde Complexes [(η5‐C5H5)Re(NO)(PPh3)(η2‐OCHAr)]BF4

J. Gladysz, C. Mayne, N. Mendez, 1990 .

π/σ Equilibria in Metal Complexes of Organic Carbonyl Compounds; Synthesis and Structure of Chiral Rhenium Complexes [(η5‐C5H5)Re(NO)(PPh3)(O CHAr)]X

J. Gladysz, A. Arif, N. Mendez, 1990 .

Reactions of the rhenium cyanomethyl complex (.eta.5-C5H5)Re(NO)(PPh3)(CH2CN) and ylide complex [(.eta.5-C5H5)Re(NO)(PPh3)(CH2P(p-tol)3))]+PF6- with n-BuLi/TMEDA: generation, stereospecific alkylation, and basicity of transition-metal-substituted carbanions and ylides

J. Gladysz, G. Crocco, K. E. Lee, 1990 .

Synthesis, structure, and reactivity of chiral rhenium alkene complexes of the formula [(.eta.5-C5H5)Re(NO)PPh3)(H2C:CHR)]+ X-

J. Gladysz, A. Arif, Gerardo S. Bodner, 1990 .

Mechanism of equilibration of diastereomeric rhenium amide complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(NHCHRR'): rhenium versus carbon epimerization

J. Gladysz, M. Dewey, 1990 .

Synthesis, structure, and reactivity of the chiral rhenium phenyl complex (.eta.5-C5H5)Re(NO)(PPh3)(C6H5)

J. Gladysz, A. Patton, Gerardo S. Bodner, 1990 .

Synthesis and reactivity of chiral rhenium amine and amide complexes of the formulas [(.eta.5-C5H5)Re(NO)PPh3)(NHRR')]+TfO- and (.eta.5C5H5)Re(NO)(PPh3)NRR')

J. Gladysz, M. Dewey, J. Bakke, 1990 .

Optical resolution and absolute configuration of the chiral pentamethylcyclopentadienylrhenium carbonyl complex [(η5-C5Me5)Re(NO)(PPh3)(CO)]+ BF4−

J. Gladysz, A. Arif, F. Niedercorn, 1990 .

Synthesis, structure, and reactivity of bridging halide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)]2X+ BF4-. Preferential binding of one enantiomer of halide complexes (.eta.5-C5H5)Re(NO)(PPh3)(X) by the chiral Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+

J. Gladysz, C. Winter, A. Arif, 1989 .

Generation of the dichloromethane complex [(η5-C5Me5) Re (NO) (PPh3) (ClCH2Cl)]+ BF4−, and its conversion to the oxidative addition product [(η5-C5Me5) Re (NO) (PPh3) (Cl) (CH2Cl)]+ BF4-

J. Gladysz, C. Winter, 1988 .

Synthesis and reactivity of functionalized rhenium silyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(SiR2X). Anionic rearrangements leading to the disilametallacycle [cyclic] [.eta.5-C5H4Si(CH3)2]Re(NO)(PPh3)[Si(CH3)2]

C. S. Young, J. Gladysz, G. Crocco, 1988 .

Divergent kinetic and thermodynamic acidity in organotransition-metal hydride complexes: synthesis, structure, and reactivity of the rhenium anion of Li+ [(.eta.-C5H5)Re(NO)(PPh3)]-.

J. Gladysz, G. Crocco, 1988, Journal of the American Chemical Society.

Synthesis, structure, and reactions of chiral rhenium vinylidene and acetylide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(X)]n+. Vinylidene complexes that are formed by stereospecific C.beta. electrophilic attack, exist as two Re=C=C geometric isomers, and undergo stereospecific C.alpha. nu

J. Gladysz, C. Strouse, D. R. Senn, 1988, Journal of the American Chemical Society.

Synthesis, structure, and alkylation of chiral vinylrhenium complexes (.eta.5-C5H5)Re(NO)(PPh3)(CX:CHR) (X = H, OCH3). A mechanistic study of 1,3-asymmetric induction from rhenium to carbon

S. Georgiou, S. Geib, J. Gladysz, 1987 .

New method for the activation of metal-bound methyl groups. Oxidative disproportionation to coordinated ethylene and methane

J. Gladysz, M. Tilset, V. Parker, 1987 .

Deprotonation and anionic rearrangements of organometallic compounds. 5. Kinetic vs. thermodynamic deprotonation in reactions of cyclopentadienylrhenium acyl and alkyl complexes with strong bases

J. Gladysz, A. Patton, P. C. Heah, 1986 .

Synthesis and chemistry of chiral rhenium acyls (.eta.-C5H5)Re(NO)(PPh3)(COR)

J. Gladysz, A. Wong, W. E. Buhro, 1983 .

Regiospecific and stereospecific reactions of triphenylmethyl hexafluorophosphate with rhenium alkyls (.eta.-C5H5)Re(NO)(PPh3)(R). .alpha.- vs. .beta.-Hydride abstraction

W. Kiel, J. Gladysz, G. Lin, 1983 .

A general method for the selective binding and activation of one aldehyde enantioface. Synthesis and reactivity of rhenium aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-RCHO)]+ PF6-

J. Gladysz, K. Emerson, J. M. Fernández, 1986 .

Synthesis and reactivity of stable metallacyclic manganese and rhenium .alpha.-hydroxyalkyl complexes of the formula [cyclic] (CO)4MP(C6H5)2(o-C6H4CHOH)

J. Gladysz, C. Strouse, G. D. Vaughn, 1986 .

Synthesis and reactivity of metallacyclic manganese .alpha.-hydroxyalkyl complexes containing aliphatic bridges and phosphorus and nitrogen donor atoms; first carbonylation of an isolable .alpha.-hydroxyalkyl complex

J. Gladysz, G. D. Vaughn, 1986 .

Longitudinally Extended Molecular Wires Based upon PtC⋮CC⋮CC⋮CC⋮C Repeat Units: Iterative Syntheses of Functionalized Linear PtC8Pt, PtC8PtC8Pt, and PtC8PtC8PtC8Pt Assemblies

J. Gladysz, F. Hampel, Qinglin Zheng, 2004 .

The robust, readily available cobalt(iii) trication [Co(NH2CHPhCHPhNH2)3]3+ is a progenitor of broadly applicable chirality and prochirality sensing agents

J. Gladysz, N. Bhuvanesh, Quang H. Luu, 2018, Chemical science.

SYNTHESIS AND CRYSTAL STRUCTURE OF THE CONJUGATED TETRAYNE (ETA 5-C5ME5)RE(NO)(PPH3)(C=CC=CC=CC=CSIME3) : APPLICATION OF THE CADIOT-CHODKIEWICZ COUPLI NG REACTION TO THE CHAIN EXTENSION OF METAL-CAPPED SP-CARBON WIRES

J. Gladysz, A. Arif, R. Dembinski, 1997 .

A Nontemplated Route to Macrocyclic Dibridgehead Diphosphorus Compounds: Crystallographic Characterization of a "Crossed-Chain" Variant of in/out Stereoisomers.

J. Gladysz, J. Blümel, N. Bhuvanesh, 2018, Chemistry, an Asian journal.

Gyroscope-like molecules consisting of PdX2/PtX2 rotators encased in three-spoke stators: synthesis via alkene metathesis, and facile substitution and demetalation.

Takanori Shima, Frank Hampel, J. Gladysz, 2006, Journal of the American Chemical Society.

Generation and reactivity of substitution-labile dichloromethane and chlorobenzene adducts of the chiral Pentamethylcyclopentadienyl rhenium Lewis acid [(η5-C5Me5)Re(NO)(PPh3)]+

J. Gladysz, C. Winter, T. Peng, 1994 .

Deoxygenation of epoxides by metal atom co-condensation

J. Gladysz, S. Togashi, J. Fulcher, 1976 .

A new route to metal alkylidene complexes. Synthesis of ylide adducts (CO)4Fe-CH(R)P+Ar3 from aldehydes, triarylphosphines, and [cyclo] (CO)4FeSi(CH3)2CH2CH2Si(CH3)2

J. Gladysz, H. Nakazawa, D. Johnson, 1983 .

Reactions of the terminal rhenium acetylide complex Re(η5-C5H5)(NO)(PPh3)(CCH) and butyllithium; generation, alkylation and stannylation of lithiocarbide complexes of the formula Re(η5-C5H4)(NO)(PPh3)(CCLi)(X = H, Li)

J. Gladysz, J. A. Ramsden, Francine Agbossou, 1991 .

Electrophile-induced disproportionation of the neutral formyl (.eta.-C5H5)Re(PPh3)(NO)(CHO). Generation of cationic rhenium carbenes of the formula [(.eta.-C5H5)Re(PPh3)(NO)(CHX)]+ (X = hydrogen, methoxy, hydroxy)

W. Wong, J. Gladysz, W. Tam, 1979 .

Delocalized electronic interactions in chiral cyclopentadienylrhenium halide complexes. Valence photoelectron spectra of CpRe(NO)(L)X (Cp=η5-C5H5, η5-C5(CH3)5 ; L=CO, P(C6H5)3; X=Cl, Br, I)

D. Lichtenberger, A. Igau, J. Gladysz, 1991 .

Synthesis of iron carbonyl trimethylsilanes: preparations and interconversions of cis-(CO)4Fe[Si(CH3)3]2, M+[(CO)4FeSi(CH3)3]-, and trans- [Fe(CO)4Si(CH3)3]2

J. Gladysz, D. Johnson, A. J. Blakeney, 1981 .

Reactions of phosphorus electrophiles with [(.eta.5-C5Me5)Fe(CO)2]-; spectroscopic evidence for a phosphinidene complex

J. Gladysz, G. Bertrand, H. Nakazawa, 1984 .

Reactions of Diphenyl(trimethylsilyl)phosphane with Alkyl(pentacarbonyl)manganese; Synthesis of the Ylide Complexes and a New Driving Force for CO Insertion

J. Gladysz, G. D. Vaughn, K. A. Krein, 1984 .

Exploratory organometal-sulfur chemistry; syntheses and unusual properties of rhenium CH2SR, CHSRR′, and CHSR]+ complexes

J. Gladysz, F. B. Mccormick, 1981 .

Sp carbon chains surrounded by sp3 carbon double helices: a class of molecules that are accessible by self-assembly and models for "insulated" molecular-scale devices.

T. Peters, J. Gladysz, F. Hampel, 2002, Angewandte Chemie.

Reactions of benzaldehyde with trialkylsilyl metal carbonyl complexes

J. Gladysz, D. Johnson, 1979 .

Simplified in situ syntheses of anhydrous pentacarbonylhydromanganese

D. W. Parker, G. Williams, J. Gladysz, 1979 .

Enantioselective Additions of Stabilized Carbanions to Imines Generated from α-Amido Sulfones By Using Lipophilic Salts of Chiral Tris(1,2-diphenylethylenediamine) Cobalt(III) Trications as Hydrogen Bond Donor Catalysts

J. Gladysz, Subrata K. Ghosh, Hemant Joshi, 2017 .

Attaching Metal‐Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η5‐C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)y(X)z]m+, Including Carbon Geometries More Distorted than Planar Tetracoordinate

J. Gladysz, S. Szafert, A. Arif, 1998 .

Methods for attaching metal-capped sp carbon chains to metalclusters: synthesis, structure and reactivity of rhenium–triosmiumcarbon complexes[(η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)10H]

J. Gladysz, A. Arif, Stephen B. Falloon, 1997 .

Synthesis and reactivity of bimetallic bridging haloalkyl complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)X(CH2)xM(CO)5]+ BF4- (X = iodo, bromo, chloro; M = rhenium, manganese; x = 1, 4)

J. Gladysz, Yuanlin Zhou, 1993 .

Synthesis, structure, and reactivity of allene complexes of the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+

J. Gladysz, A. Arif, Jiaqi Pu, 1992 .

Syntheses and structures of monoplatinum model complexes for diplatinum polyynediyl adducts LnPt(CC)zPtLn

T. Peters, J. Gladysz, F. Hampel, 2002 .

Stereospecific and chemospecific interconversions of the rhenium alkylidene [(η-C5H5)Re(NO)(PPh3)(CHC6H5)]+PF6− and the alkylrhenium (η-C5H5)Re(NO)(PPh3)(CH(OCH3)C6H5)

J. Gladysz, A. Constable, 1980 .

UNPRECEDENTED REGIOSPECIFICITY AND STEREOSPECIFICITY IN REACTIONS OF PH3C+PF6- WITH RHENIUM ALKYLS OF THE FORMULA (η-C5H5)RE(NO)(PPH3)(CH2R)

W. Kiel, J. Gladysz, G. Lin, 1980 .

Neutral metal formyl complexes: generation, reactivity, and models for Fischer-Tropsch catalyst intermediates

W. Wong, J. Gladysz, W. Tam, 1979 .

A Quest for Atropisomerism in Cojoined Square‐Planar Metal Complexes: Synthesis and Structures of Sterically Congested Diplatinum Ethynediyl Adducts

J. Gladysz, N. Bhuvanesh, Tianyi Zhang, 2017 .

Syntheses and reactivities of disubstituted and trisubstituted fluorous pyridines with high fluorous phase affinities: solid state, liquid crystal, and ionic liquid-phase properties.

J. Gladysz, F. Hampel, C. Rocaboy, 2002, The Journal of organic chemistry.

Three rational syntheses of new stable metal .alpha.-hydroxyalkyl complexes

J. Gladysz, G. D. Vaughn, 1981 .

TRANSITION METAL FORMYL COMPLEXES. SYNTHESIS BY TRIALKYLBOROHYDRIDE ATTACK ON METAL CARBONYL ACYLS

J. Gladysz, J. C. Selover, 1978 .

Vibrational progressions in the valence ionizations of transition metal hydrides: evaluation of metal-hydride bonding and vibrations in (eta(5)-C(5)R(5))Re(NO)(CO)H [R = H, CH(3)].

D. Lichtenberger, A. Igau, J. Gladysz, 2002, Journal of the American Chemical Society.

Strained Organic Compounds: Introduction

Josef Michl, John A. Gladysz, J. Michl, 1989 .

Chemistry via metal atom cocondensation: isomerization and complexation reactions of organocyclopropanes and spirocycles

A. Bocarsly, J. Gladysz, A. Hanlan, 1980 .

Reactions of (cyclopentadienyl)rhenium halide complexes (η5-C5H5)Re(NO)(PPh3)(X) with n-BuLi/TMEDA; generation and methylation of lithio- and dilithiocyclopentadienyl ligands

J. Gladysz, 1988 .

Metal–metal interactions across bridging elemental carbon chains: a computational study of odd-carbon complexes

J. Gladysz, H. Jiao, 2001 .

Substitution mechanisms at metal carbonyl centers; conversion of Ph3P(CO)4ReBr to Ph3P(CO)4ReCH3 via an anionic acyl intermediate

D. W. Parker, J. Gladysz, M. Marsi, 1980 .

SYNTHESIS, STRUCTURE, AND REACTIVITY OF POLYMETALLIC C3OME COMPLEXES OF THE FORMULA (ETA 5-C5ME5)RE(NO)(PPH3)(C=CC(OME)=)MM(CO)N (M/M/N = RE/2/9, OS/3 /11) : A NEW FORM OF COORDINATED CARBON IN WHICH A C3 CHAIN LINKS TWO METAL S AND SPANS A THIRD

J. Gladysz, A. Arif, Weiqing Weng, 1997 .

A new form of coordinated carbon : a C3 chain that is anchored by a transition metal on each end and spanned by a third

J. Gladysz, A. Arif, Weiqing Weng, 1993 .

New families of coordinated carbon: oxidative coupling of an ethynyl complex to isolable and crystallographically characterized MC.tplbond.CC.tplbond.CM and +M:C:C:C:C:M+ assemblies

J. Gladysz, A. Arif, Jeffery W. Seyler, 1993 .

Synthesis, Structure, and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC2M', MC4M', and MC4M'C4M Linkages. Transmetalations of Lithiocarbon Complexes (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CLi) and (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CC.tplbond.CLi)

J. Gladysz, A. Arif, T. Bartik, 1995 .

Electrophile-Induced Cyclizations of Chiral Rhenium Ethynyl and C2Li Complexes of the Formula (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CX): Synthesis, Structure, and Reactivity of Unusual 1,3-Dimetalated Cyclic C4H3 and C4H4 Species

J. Gladysz, A. Arif, T. Bartik, 1995 .

Selective Binding of One Enantioface of Monosubstituted Alkenes to the Chiral Transition Metal Lewis Acid ((η5-C5H5)Re(NO)(PPh3))+.

J. Gladysz, A. Arif, Gerardo S. Bodner, 1988 .

Selective binding of one enantioface of monosubstituted alkenes to the chiral transition metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+

J. Gladysz, A. Arif, Gerardo S. Bodner, 1988 .

Synthesis, structure, dynamic behavior, and reactivity of chiral rhenium primary phosphine and phosphido complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(PRH2)]+X- and (.eta.5-C5H5)Re(NO)(PPh3) [P(:)RH]

J. Gladysz, A. Arif, D. Knight, 1992 .

Synthesis, structure, and reactivity of (pentamethylcyclopentadienyl)rhenium aldehyde complexes [(.eta.5-C5Me5)Re(NO)(PPh3)(.eta.2-O:CHR)]+ BF4-: highly diastereoselective deuteride additions

J. Gladysz, A. Arif, J. A. Ramsden, 1992 .

π/σ Equilibria in rhenium ketone complexes [(η5-C5H5)Re(NO)(PPh3)(OCRR′)]+X−; a marked electronic effect upon the binding mode

Dennis M. Dalton, J. Gladysz, A. Arif, 1991 .

The selective activation of one methyl ketone enantioface viaσ-binding to a chiral metal template: synthesis and reactivity of rhenium ketone complexes [(η5-C5H5)Re(NO)(PPh3)(η1-Me(R)CO)]+PF6–

J. Gladysz, R. Larsen, K. Emerson, 1988 .

A crystallographic map of chiral recognition in π complexes of aromatic aldehydes and a chiral transition metal Lewis acid: enantioface binding selectivities in solution correlate to distances between metal and carbon stereocentres in the solid state

J. Gladysz, A. Arif, D. P. Klein, 1995 .

Gyroscope-like molecules consisting of three-spoke stators that enclose "switchable" neutral dipolar rhodium rotators; reversible cycling between faster and slower rotating Rh(CO)I and Rh(CO)2I species.

Leyong Wang, J. Gladysz, F. Hampel, 2006, Chemical communications.

Syntheses of kinetically unstable neutral formyl complexes via Li(C2H5)3BH and "transformylation" reactions of metal carbonyl cations

J. Gladysz, W. Tam, G. Lin, 1982 .

Reactions of (CO)5MnSi(CH3)3 with .alpha.-bromo carbonyl and related organic compounds. Facile reductive silylation

J. Gladysz, M. Marsi, G. D. Vaughn, 1985 .

New methods for metal–carbon bond formation; reactions of (OC)5MnSiMe3 with cyclic ethers

J. Gladysz, K. Brinkman, 1980 .

Mono- and disubstitution reactions of gyroscope like complexes derived from Cl Pt Cl rotators within cage like dibridgehead diphosphine ligands

J. Gladysz, D. Taher, F. Hampel, 2016 .

Configurational Processes in Coordinated Ligands. Extremely Facile Phosphorus Inversion in the Pyramidal Terminal Phosphide Complexes (η5-C5H5)Re(NO)(PPh3)(PRR′).

J. Gladysz, W. E. Buhro, 2002 .

Synthesis and properties of chiral rhenium pentatetraenylidene complexes of the formula [(η5-C5Me5)Re(NO)(PPh3)(CCCCCAr2)]+BF4− (CAr2=9-fluorenylidene)

J. Gladysz, S. Szafert, Pierre Haquette, 2000 .

Synthesis, Structure, and Reactivity of Chiral Rhenium N‐Pyrrolyl Complexes Regiochemistry of Electrophilic Addition and Unprecedented Rearrangements to Carbon‐Ligated Species

J. Gladysz, T. J. Johnson, A. Arif, 1995 .

Synthesis and characterization of chiral rhenium σ-ketone complexes. Binding properties of symmetrical ketones and alkylcyclohexanones

Dennis M. Dalton, J. Gladysz, 1991 .

Synthesis, Structure, Dynamic Behavior, and Reactivity of Rhenium Phosphido Complexes (η5-C5H5)Re(NO)(PPh3)(PR2). The “Gauche Effect” in Transition-Metal Chemistry.

S. Georgiou, J. Gladysz, J. Hutchinson, 1988 .

Deprotonation of rhenium terminal acetylide complexes (.eta.5-C5R5)Re(NO)(PPh3)(C.tplbond.CH): generation and reactivity of rhenium/lithium C2 complexes

J. Gladysz, J. A. Ramsden, Weiqing Weng, 1992 .

Molecular wires in single-molecule junctions: charge transport and vibrational excitations.

H. B. Weber, W. Hieringer, A. Görling, 2010, Chemphyschem : a European journal of chemical physics and physical chemistry.

An unexpected insertion of acetone into the silicon-carbon terminus of an sp carbon chain: syntheses and structures of model monoplatinum hexatriynyl and octatetraynyl complexes

T. Peters, J. Gladysz, F. Hampel, 2002 .

Tracking Energy Transfer across a Platinum Center

J. Gladysz, A. Burin, I. Rubtsov, 2022, The journal of physical chemistry. A.

Trapping of Terminal Platinapolyynes by Copper(I) Catalyzed Click Cycloadditions; Probes of Labile Intermediates in Syntheses of Complexes with Extended sp Carbon Chains, and Crystallographic Studies.

J. Gladysz, F. Hampel, N. Bhuvanesh, 2021, Chemistry.

Wire like diplatinum, triplatinum, and tetraplatinum complexes featuring X[PtCCCCCCCC]mPtX segments; iterative syntheses and functionalization for measurements of single molecule properties

J. Gladysz, F. Hampel, Qinglin Zheng, 2019, Dalton Transactions.

C8 and C12 sp Carbon Chains that Span Two Platinum Atoms: The First Structurally Characterized 1,3,5,7,9,11‐Hexayne.

T. Peters, J. Gladysz, J. Bohling, 1999 .

A general class of stable alkyl halide complexes: Synthesis, structure, and reactivity of alkyl iodide complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(IR)] +BF4-

J. Gladysz, C. Winter, A. Arif, 1987 .

Deprotonation and anionic rearrangements of organometallic compounds. 1. Reactions of cyclopentadienylrhenium acyl and alkyl complexes with strong bases

J. Gladysz, P. C. Heah, 1984 .

Ionic transformations in extremely nonpolar fluorous media: easily recoverable phase-transfer catalysts for halide-substitution reactions.

D. Mandal, J. Gladysz, Crestina S. Consorti, 2008, Chemistry, an Asian journal.

Crystal structure and computational investigation of an analogue of Grubbs' second generation catalyst with a fluorous phosphine.

Hassan S. Bazzi, E. Brothers, J. Gladysz, 2012, Inorganic chemistry.

Potentiometric Selectivities of Ionophore-Doped Ion-Selective Membranes: Concurrent Presence of Primary Ion or Interfering Ion Complexes of Multiple Stoichiometries.

P. Bühlmann, J. Gladysz, Li D. Chen, 2019, Analytical chemistry.

Deprotonation and anionic rearrangements of organometallic compounds. 1. Reactions of cyclopentadienylrhenium acyl and alkyl complexes with strong bases

J. Gladysz, P. C. Heah, 1984 .

sp carbon chains surrounded by sp(3) carbon double helices: coordination-driven self-assembly of wirelike Pt(CC)(n)Pt moieties that are spanned by two P(CH(2))(m)P linkages.

Gareth R. Owen, T. Peters, J. Gladysz, 2007, Journal of the American Chemical Society.

Syntheses, Structures, and Electronic and Photophysical Properties of Unsymmetrically Substituted Butadiynediyl and Hexatriynediyl Complexes Derived from (C 6 F 5 )(R 3 P) 2 Pt, ( p -tol)(R 3 P) 2 Pt, and (Ph 3 P)Au End-Groups

K. Schanze, J. Gladysz, F. Hampel, 2008 .

Liquid/solid phase transfer activation of Grubbs-type alkene metathesis catalysts; application of silver salts of sulfonated polystyrene

Hassan S. Bazzi, J. Gladysz, Zhenxing Xi, 2014 .

Main-Group Chemistry: Introduction

J. Michl, J. Gladysz, 1990 .

Introduction: Enantioselective Catalysis

Carsten Bolm, John A. Gladysz, C. Bolm, 2003 .

Analogs of Grubbs' second generation catalyst with hydrophilic phosphine ligands: phase transfer activation of ring closing alkene metathesis.

Hassan S. Bazzi, J. Gladysz, Zhenxing Xi, 2011, Organic letters.

Azide- and Fluorine-Containing Polystyrenes as Potential ″Phosphine Sponges″ Based upon Staudinger Reactions: Application to the Phase Transfer Activation of Grubbs’ Catalyst

J. Gladysz, Katherine Wang, 2022, Macromolecules.

Substitution and Catalytic Chemistry of Gyroscope‐Like Complexes Derived from Cl–Rh–CO Rotators and Triply trans Spanning Di(trialkylphosphine) Ligands

J. Gladysz, J. Blümel, N. Bhuvanesh, 2015 .

ChemInform Abstract: Syntheses, Oxidations, and Palladium Complexes of Fluorous Dialkyl Sulfides: New Precursors to Highly Active Catalysts for the Suzuki Coupling.

J. Gladysz, C. Rocaboy, 2002 .

5,6-dehydro[3.3]Paracyclophane: Bridged benzobarrelene formation by intramolecular trapping of a novel aryne

J. Gladysz, D. T. Longone, 1976 .

A convenient synthesis of [3.3]paracyclophane

J. Gladysz, Seli̇m H. Küsefoǧlu, D. T. Longone, 1977 .

Synthesis and reactivity of chiral rhenium indenyl complexes of the formula [(.eta.5-C9H7)Re(NO)(PPh3)(X)]n+

J. Gladysz, M. Dewey, Yuanlin Zhou, 1993 .

Crystallographic and theoretical analyses of the structures of rhenium formyl and acyl complexes of the formula (.eta.5-C5H5)Re(NO)(PR3)(COR')

S. Georgiou, J. Gladysz, W. Tam, 1987 .

New media for classical coordination chemistry: phase transfer of Werner and related polycations into highly nonpolar fluorous solvents.

J. Gladysz, N. Bhuvanesh, Subrata K. Ghosh, 2013, Inorganic chemistry.

Convenient syntheses of fluorous aryl iodides and hypervalent iodine compounds: ArI(L)n reagents that are recoverable by simple liquid/liquid biphase workups, and applications in oxidations of hydroquinones.

J. Gladysz, C. Rocaboy, 2003, Chemistry.

Syntheses and Properties of Fluorous Quaternary Phosphonium Salts that Bear Four Ponytails; New Candidates for Phase Transfer Catalysts and Ionic Liquids

J. Gladysz, Crestina S. Consorti, A. Stuart, 2006 .

Additions of PH(3) to Monosubstituted Alkenes of the Formula H(2)C=CH(CH(2))(x)()(CF(2))(y)()CF(3): Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkylphosphines with Modulated Electronic Properties and Fluorous Phase Affinities.

J. Gladysz, D. Rutherford, J. Juliette, 1998, The Journal of organic chemistry.

The Experimental Assay of Catalyst Recovery: General Concepts

J. Gladysz, 2009 .

Synthesis and chemistry of chiral vinylrhenium complexes (.eta.-C5H5)Re(NO)(PPh3)(CH:CHR'). Stereoselective reactions with electrophiles and a spontaneous alkylidene to olefin rearrangement

J. Gladysz, W. Hatton, 1983 .

An easily accessed class of recyclable hypervalent iodide reagents for functional group oxidations: bis(trifluoroacetate) adducts of fluorous alkyl iodides, CF3(CF2)n−1I(OCOCF3)2

J. Gladysz, V. Tesevic, 2005 .

Cleaning of pH Selective Electrodes with Ionophore‐doped Fluorous Membranes in NaOH Solution at 90 °C

P. Bühlmann, J. Gladysz, J. Rábai, 2018 .

How to insulate a reactive site from a perfluoroalkyl group: photoelectron spectroscopy, calorimetric, and computational studies of long-range electronic effects in fluorous phosphines P((CH(2))(m)(CF(2))(7)CF(3))(3).

S. Nolan, T. Soós, J. Gladysz, 2002, Journal of the American Chemical Society.

Synthesis of a series of ω-dimethylaminoalkyl substituted ethylenediamine ligands for use in enantioselective catalysis

J. Gladysz, Subrata K. Ghosh, Carola Ganzmann, 2015 .

Highly selective detection of silver in the low ppt range with ion-selective electrodes based on ionophore-doped fluorous membranes.

A. Stein, P. Bühlmann, Melissa A. Fierke, 2010, Analytical chemistry.

Ene reactions of β-pinene at room temperature and 40 kbar pressure

J. Gladysz, Y. S. Yu, 1978 .

High-pressure cycloadditions of pyrones: synthesis of highly functionalized six-membered rings by inhibition of carbon dioxide loss

J. Gladysz, S. J. Lee, J. Tomasello, 1977 .

Structures and energies of 10-azatriquinacene and its hydrogenation products: a computational study.

J. Gladysz, J. Halet, H. Jiao, 2001, Journal of Organic Chemistry.

Synthesis, reactivity, structures, and dynamic properties of gyroscope like iron complexes with dibridgehead diphosphine cages: pre- vs. post-metathesis substitutions as routes to adducts with neutral dipolar Fe(CO)(NO)(X) rotors.

J. Gladysz, F. Hampel, Georgette M. Lang, 2016, Dalton transactions.

Synthesis and reactivity of fluorous and nonfluorous aryl and alkyl iodine(III) dichlorides: new chlorinating reagents that are easily recycled using biphasic protocols.

M. Zupan, S. Stavber, J. Gladysz, 2009, The Journal of organic chemistry.

Deoxygenation of nitro and nitroso arenes via chromium atom cocondensation

J. Gladysz, S. Togashi, J. Fulcher, 1977 .

Pyrrolyl-N and pyrrolyl-C complexes of the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+: synthesis, protonation, and rearrangement chemistry

J. Gladysz, T. J. Johnson, A. Arif, 1993 .

Chiral Recognition in π‐Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids. Development of a General Model for Enantioface Binding Selectivities

J. Gladysz, Brian J. Boone, 1997 .

A Versatile New Synthesis of Organic Compounds with Chiral Methyl Groups: Stereochemistry of Protolytic Rhenium-Carbon Bond Cleavage in Chiral Alkyl Complexes (η5-C5H5)Re(NO)(PPh3)(R).

Motomasa Kobayashi, J. Gladysz, H. Floss, 1987 .

Enantioselective Synthesis: Introduction

J. Michl, J. Gladysz, 1992 .

Synthesis, Reactivity, and Metal Complexes of Fluorous Triarylphosphines of the Formula P(p-C6H4(CH2)3(CF2)n-1CF3)3 (n = 6, 8, 10)

T. Soós, J. Gladysz, D. Rutherford, 2001 .

Syntheses of Iron(0) Complexes of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3

Leyong Wang, J. Gladysz, T. Shima, 2015 .

Toward Permetalated Alkyne/Azide 3 + 2 or “Click” Cycloadducts

J. Gladysz, N. Bhuvanesh, M. Clough, 2012 .

Introduction: Natural Product Synthesis

J. Gladysz, 2005 .

Oxidations of secondary alcohols to ketones using easily recyclable bis(trifluoroacetate) adducts of fluorous alkyl iodides, CF3(CF2)(n-1)I(OCOCF3)2.

J. Gladysz, V. Tesevic, 2006, The Journal of organic chemistry.

Gyroscope-like platinum(IV) complexes of the macrocyclic dibridgehead diphosphine P((CH2)14)3P

J. Gladysz, N. Bhuvanesh, Joseph H. Reibenspies, 2023, Journal of Organometallic Chemistry.

New strategies for enantioselective syntheses of 1-alkyl- and 1,4-dialkyl-1,2,3,4-tetrahydroisoquinolines: diastereoselective additions of nucleophiles and electrophiles to isoquinoline mediated by an easily resolved and recycled chiral transition metal auxiliary

J. Gladysz, G. B. Richter‐Addo, A. Arif, 1993 .

Building Blocks for Molecular Polygons Based on Platinum Vertices and Polyynediyl Edges

J. Gladysz, F. Hampel, N. Bhuvanesh, 2023, Organometallics.

A new supramolecular bonding motif involving NH bonds of ammonium salts and macrocycles derived from platinum corners and butadiynediyl linkers.

J. Gladysz, N. Bhuvanesh, Brenna K. Collins, 2022, Dalton transactions.

Shortwave infrared fluorofluorophores for multicolor in vivo imaging.

J. Gladysz, Shang Jia, Ellen M. Sletten, 2022, Angewandte Chemie.

Three-fold intramolecular ring-closing metatheses involving square-planar platinum complexes with cis-phosphorus donor ligands: syntheses, structures, and properties of parachute-like complexes.

M. Barbasiewicz, J. Gladysz, F. Hampel, 2008, Inorganic chemistry.

Octahedral Gyroscope-Like Molecules with M(CO)3(X) Rotators Encased in Three-Spoked Diphosphine Stators: Syntheses by Alkene Metathesis/Hydrogenation Sequences, Structures, Dynamic Properties, and Reactivities

J. Gladysz, and Frank Hampel, Gisela D Hess, 2007 .

Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes

T. Peters, J. Gladysz, S. Szafert, 2000 .

Configurational equilibria in amido and lithioamido complexes of formulas ({eta}{sup 5}-C{sub 5}H{sub 5})Re(NO)(PAr{sub 3})(NHCHRR`) and ({eta}{sup 5}-C{sub 5}H{sub 5})Re(NO)(PAr{sub 3})(NLiR``): Epimerization occurs at rhenium via phosphine dissociation

J. Gladysz, M. Dewey, G. A. Stark, 1996 .

Transition metal formyl complexes: Synthesis by trialkylborohydride attack on metal carbonyl acyls

J. Gladysz, J. C. Selover, 1978 .

Phase‐Transfer Activation of Transition Metal Catalysts

Hassan S. Bazzi, J. Gladysz, Zhenxing Xi, 2016 .

Thermomorphic Fluorous Palladacycles

J. Gladysz, 2008 .

Synthesis, structure, and spectroscopic properties of chiral rhenium aromatic aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(O:CHAr)]+X-: equilibria between .pi. and .sigma. aldehyde binding modes

J. Gladysz, A. Arif, Jeffery W. Seyler, 1993 .

A new asymmetric synthesis of cyanohydrins and oxygen-functionalized derivatives: stereoselective addition of cyanide to chiral rhenium aldehyde and ketone complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(O:CRR')]+BF4-

Dennis M. Dalton, J. Gladysz, C. Garner, 1991 .

A CRYSTALLOGRAPHIC MAP OF CHIRAL RECOGNITION IN PI COMPLEXES OF AROMATIC ALDEHYDES AND A CHIRAL TRANSITION METAL LEWIS ACID : ENANTIOFACE BINDING SEL ECTIVITIES IN SOLUTION CORRELATE TO DISTANCES BETWEEN METAL AND CARBON STER EOCENTERS IN THE SOLID STATE

J. Gladysz, A. Arif, D. P. Klein, 1996 .

Crystal structures of diastereomeric styrene complexes of the chiral rhenium fragment [(η5-C5H5)Re(NO)(PPh3)]+: effect of ligating enantioface upon bonding and conformation

J. Gladysz, A. Arif, M. Sanaú, 1995 .

Synthesis, structure, and dynamic behavior of symmetrical cis- and trans-alkene complexes of the chiral rhenium Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: binding selectivities and isomerization processes

J. Gladysz, A. Arif, C. Mayne, 1993 .

J. Gladysz, F. Hampel, N. Bhuvanesh, 2016, Dalton Transactions.

Square-Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH2)4CH═CH2 Substituents; Two- and Three-Fold Intramolecular Ring-Closing Metatheses

Leyong Wang, J. Gladysz, Jun Han, 2010 .

Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3

M. Barbasiewicz, J. Gladysz, T. Shima, 2010 .

Synthesis and Reactivity of Functionalized Dimethylgermyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(GeMe2X); Equilibria Involving the Dimethylgermylene Complex [(η5-C5H5)Re(NO)(PPh3)(=GeMe2)]• TfO−

J. Gladysz, K. Lee, 1994 .

Award Winning Green Organometallic Chemistry: The Presidential Green Chemistry Challenge

J. Gladysz, 2011 .

Award-Winning Organometallic Chemistry: The 2011 ACS Award in Organometallic Chemistry

J. Gladysz, 2011 .

Award-Winning Organometallic Chemistry: Le Grand Prix Achille Le Bel of the Societé Chimique de France (SCF)

J. Gladysz, 2011 .

Award-Winning Organometallic Chemistry: the Israeli Chemical Society (ICS) Outstanding Young Scientist Prize

J. Gladysz, 2011 .

Award-Winning Organometallic Chemistry: the Alfred-Stock-Gedächtnispreis of the GDCh

J. Gladysz, 2011 .

Award-Winning Organometallic Chemistry and the Adolf-von-Baeyer-Denkmünze of the GDCh

J. Gladysz, 2011 .

Inaugural Schlenk Lecture at the University of Tübingen

J. Gladysz, R. Anwander, 2012 .

Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 10: Catalysis

J. Gladysz, 2002 .

sp carbon chains surrounded by sp(3) carbon double helices: directed syntheses of wirelike Pt(CC)(n)Pt moieties that are spanned by two P(CH(2))(m)P linkages via alkene metathesis.

T. Peters, J. Gladysz, F. Hampel, 2007, Journal of the American Chemical Society.

Syntheses, homeomorphic and configurational isomerizations, and structures of macrocyclic aliphatic dibridgehead diphosphines; molecules that turn themselves inside out

J. Gladysz, N. Bhuvanesh, Hemant Joshi, 2022, Chemical science.

Synthesis, structure, and reactivity of fluorous phosphorus/carbon/phosphorus pincer ligands and metal complexes.

J. Gladysz, F. Hampel, Róbert Tuba, 2005, Dalton transactions.

Chelating diphosphines that contain a rhenium stereocenter in the backbone: Applications in rhodium-catalyzed enantioselective ketone hydrosilylations and alkene hydrogenations

J. Gladysz, K. Kromm, P. Osburn, 2002 .

Chiral-at-Metal Ruthenium Complexes with Guanidinobenzimidazole and Pentaphenylcyclopentadienyl Ligands: Synthesis, Resolution, and Preliminary Screening as Enantioselective Second Coordination Sphere Hydrogen Bond Donor Catalysts

J. Gladysz, N. Bhuvanesh, Subrata K. Ghosh, 2020 .

Computational Investigations of Enantioselection in Carbon–Carbon Bond Forming Reactions of Ruthenium Guanidinobenzimidazole Second Coordination Sphere Hydrogen Bond Donor Catalysts

J. Gladysz, M. Hall, T. Mukherjee, 2020 .

Optical rotation measurements of organometallic compounds: caveats and recommended procedures

J. Gladysz, M. Dewey, 1993 .

New author guidelines for 2014: A format for computational structural data that can be opened with freely available programs such as "mercury"1

D. Lichtenberger, J. Gladysz, 2014 .