P. Gaspar

发表

Dewey Holten, D. Holten, P. Gaspar, 1987 .

J. Adloff, P. Gaspar, 1992 .

Dicyanogermylenes: a tale of isomers and interconversions.

H. Schaefer, P. Gaspar, Ashwini Bundhun, 2012, Inorganic chemistry.

Stannylenes: structures, electron affinities, ionization energies, and singlet-triplet gaps of SnX2/SnXY and XSnR/SnR2/RSnR′ species (X; Y = H, F, Cl, Br, I, and R; R' = CH3, SiH3, GeH3, SnH3).

H. Schaefer, P. Gaspar, Ashwini Bundhun, 2012, Inorganic chemistry.

The quest for triplet ground state silylenes

D. J. Berger, P. Gaspar, Manchao Xiao, 2002 .

From Silicon Halides

P. Gaspar, 2007 .

The methanium ion, CH5+. Evidence for the structure of a nonclassical ion from reaction studies by ion cyclotron resonance spectroscopy

P. Gaspar, M. Sefcík, J. M. Henis, 1974 .

Computational studies of the thermal fragmentation of P-arylphosphiranes: have arylphosphinidenes been generated by this method?

E. Davidson, P. Gaspar, D. Hrovat, 2005, Journal of the American Chemical Society.

Diadamantylsilylene and its stereochemistry of addition

P. Gaspar, M. Chiang, Manchao Xiao, 1991 .

Toward unsaturated stannylenes Y2ZSn: and related compounds with triplet electronic ground states

H. Schaefer, P. Gaspar, Ashwini Bundhun, 2016 .

Simplified method for the preparation of fluoroalkyl iodides

P. Gaspar, G. Hammond, D. H. Paskovich, 1967 .

GOLD ANALYSIS BY DIFFERENTIAL ABSORPTION OF γ‐RAYS

P. Gaspar, E. S. Macias, C. Radcliffe, 1980 .

Phenylium (C/sub 6/H/sub 5//sup +/) ion-molecule reactions studied by ion cyclotron resonance spectroscopy

P. Gaspar, M. Speranza, Sefcik, 1977 .

By Interaction with Unsaturated Organic Derivatives and Active Metals

P. Gaspar, 2007 .

2,2-Dimethoxyhexamethyltrisilane. A “One-pot” Silicon Atom Synthon

T. Barton, P. Gaspar, S. A. Burns, 1983 .

By Interaction with Organic Halides with Active Metals

P. Gaspar, 2007 .

Base-Catalyzed Deuterium Exchange in Cycloheptatriene. Evidence for the Cycloheptatrienide Anion

W. Doering, P. Gaspar, 1963 .

1-silacyclopent-3-en-1-ylidene, a cyclic silylene from the reactions of silicon atoms, and a silicon atom synthon

P. Gaspar, S. Konieczny, Yue-Shen Chen, 1981 .

REACTIONS OF RECOILING SILICON ATOMS WITH PHOSPHINE‐DIENE MIXTURES AND THE QUESTION OF SILYLENE INTERMEDIATES

P. Gaspar, R. Hwang, 1978 .

Silylene additions to cyclopentadiene and 1,3-cyclohexadiene. Evidence for the addition mechanism

P. Gaspar, R. Hwang, R. T. Conlin, 1975 .

Stereochemistry of a silylene addition reaction

P. Gaspar, R. Hwang, 1974 .

2,2-DIMETHOXYHEXAMETHYLTRISILANE. A ONE-POT SILICON ATOM SYNTHON

T. Barton, P. Gaspar, S. A. Burns, 1984 .

Addition of trimethylsilyl radical to ethylene. Flash photolysis-electron spin resonance kinetic study

K. Choo, P. Gaspar, 1974 .

Organosilicon iminamino radicals from the addition of silyl radicals to diphenyldiazomethane

Chi-Tang Ho, K. Choo, P. Gaspar, 1974 .

REARRANGEMENTS OF ALPHA-SILYLSILYLENES TO BETA-SILYLSILYLENES: A MECHANISTIC CONUNDRUM

M. A. North, P. Gaspar, Myong-Euy Lee, 1991 .

A New Stereoselective Synthesis of Phosphiranes.

P. Gaspar, Xinhua Li, K. Robinson, 1996, The Journal of organic chemistry.

2,6-DIMETHOXYPHENYLPHOSPHETANE SULFIDE SYNTHESIS, STRUCTURE AND EXPLORATORY PHOTOCHEMISTRY

P. Gaspar, H. Qian, N. Rath, 1999 .

Gas-phase synthesis, characterization, and reactivity studies of the prototype aromatic phosphirenylium ion

M. Gross, P. Gaspar, D. Giblin, 2005 .

An equilibrium between carbene and a metal-carbene complex. Homogeneous catalysis by mercury(II)

P. Mueller, P. Gaspar, J. B. Lambert, 1980 .

Disproportionation of trimethylsilyl radicals to a sila olefin in the liquid phase

K. Choo, P. Gaspar, B. J. Cornett, 1980 .

Photolysis of 1,3-dimesitylhexamethyltrisilane and 1,2-dimesityltetramethyldisilane

P. Gaspar, M. Chiang, J. Braddock-Wilking, 1993 .

The dimer of unsubstituted silole

B. Boo, P. Gaspar, Yue-Shen Chen, 1992 .

Octakis(trimethylsilyl)cyclotetrasilane. A stable cyclotetrasilane from a silylene precursor

P. Gaspar, Yue-Shen Chen, 1982 .

Disproportionation of trimethylsilyl radicals to a sila olefin in the liquid phase

K. Choo, P. Gaspar, B. J. Cornett, 1980 .

Evidence for the dimerization of dimethylsilylene to tetramethyldisilene

P. Gaspar, R. T. Conlin, 1976 .

An equilibrium between carbene and a metal-carbene complex. Homogeneous catalysis by mercury(II)

P. Mueller, P. Gaspar, J. B. Lambert, 1980 .

CHAPTER 13 – Silicon, Germanium, and Tin Structural Analogs of Carbenes1

P. Gaspar, 1971 .

Evidence from a hot atom experiment for the silylsilylene-to-disilene rearrangement: SiH/sub 3/SiH:. -->. SiH/sub 2/=SiH/sub 2/

B. Boo, P. Gaspar, D. Svoboda, 1987 .

Self-reaction of pentamethyldisilyl radicals: is dimethylsilylene a product?

J. Hawari, P. Gaspar, D. Griller, 1987 .

Formation of thermalized singlet silylene in the reactions of recoiling silicon atoms

P. Gaspar, S. Konieczny, S. H. Mo, 1984 .

SILYLENE REARRANGEMENTS IN THE REACTIONS OF RECOILING SILICON ATOMS WITH TRIMETHYLSILANE

P. Gaspar, S. Konieczny, S. H. Mo, 1982 .

From Silicon Alkoxides, Silicon Carboxylates or Siloxanes

P. Gaspar, 2007 .

1 : 2-adducts from silylenes and 1,3-butadiene

P. Gaspar, Kevin L. Bobbitt, 1995 .

Endothermic ion‐molecule reactions in silane

P. Gaspar, G. Stewart, J. M. Henis, 1973 .

Hydride Ion Transfer and Isotope Effects in CD4‐Silane Ion Molecule Reactions

P. Gaspar, G. Stewart, J. M. Henis, 1972 .

Ion-Molecule Reactions in Silane-Methane Mixtures

P. Gaspar, G. Stewart, J. M. Henis, 1972 .

Theoretical calculations on the tetramethyldisilene rearrangement: a new approach to an old mechanistic problem.

P. Gaspar, M. Nag, 2009, Chemistry.

A Retro-Diels Alder route to Tetramethyldisilene Me2Si=SiMe2 revisited: Flow Pyrolysis of 1,1,2,2-Tetramethyl-1,2-disilacyclohex-4-ene

M. Gross, H. Rohrs, P. Gaspar, 2007 .

Gas-Phase Chemistry of Methyl(trimethylsilyl)germylene

P. Gaspar, D. Lei, M. E. Lee, 1997 .

Rearrangement of bis(trimethylsilyl)silylene (Me3Si)2Si in the gas phase; new silylene-to-silylene interconversions

P. Gaspar, Yue-Shen Chen, B. H. Cohen, 1980 .

Reaction studies of hot silicon and germanium radicals. Progress report, September 1, 1975--August 30, 1976

P. Gaspar, 1976 .

Stereochemistry of dimetrylgermylene addition to E,E-and E,Z-2,4-hexadienes in the gas phase

P. Gaspar, Ken. Kobayashi, E. C. Ma, 1982 .

STEREOCHEMISTRY OF A SILYLEN ADDITION REACTION

P. Gaspar, R. Hwang, 1974 .

Carbon-hydrogen insertion in the copper-catalyzed decomposition of diazomethane in hexamethyldisilane. Silicon .alpha. effect

P. Gaspar, Maitland Jones, R. T. Conlin, 1972 .

By Interaction with Unsaturated Organic Compounds

P. Gaspar, 2007 .

By Reaction with Diazoalkanes

P. Gaspar, 2007 .

Sonochemical synthesis of 1,1-dimethyl-1-germacyclopent-3-enes and the extrusion of dimethylgermylene upon their pyrolysis

P. Gaspar, D. Lei, 1991 .

Laser photolysis of 2-phenylheptamethyltrisilane

C. Kirmaier, D. Holten, B. Boo, 1984 .

ADDITION OF TRIMETHYLSILYL RADICAL TO ETHYLENE, A FLASH PHOTOLYSIS-ELECTRON SPIN RESONANCE KINETIC STUDY

K. Choo, P. Gaspar, 1974 .

Frontiers of organosilicon chemistry

P. Gaspar, A. Bassindale, 1991 .

CHEMISTRY OF RECOILING SILICON ATOMS. V. PRODUCT-FORMING REACTIONS IN PHOSPHINE--SILANE MIXTURES.

P. Gaspar, P. Markusch, J. D. Holten, 1972 .

Preparation of trisilane by the Schlesinger method

P. Gaspar, G. Adair, C. A. Levy, 1970 .

Reactions of recoiling silicon atoms with phosphine, silane, and disilane

P. Gaspar, P. Markusch, 1970 .

Reactions of recoiling silicon atoms with phosphine, silane, and ethylene

W. Eckelman, P. Gaspar, S. Bock, 1968 .

Tris(triisopropylsilyl)silane and the Generation of Bis(triisopropylsilyl)silylene

T. Koetzle, A. Beatty, P. Gaspar, 1999 .

Rearrangements of a-Silylsilylenes to -Silylsilylenes: A Mechanistic Conundrum.

M. A. North, P. Gaspar, Michael G. Lee, 1991 .

Transposition ― a new rearrangement of α-silylsilylenes involving disilene intermediates

B. Boo, P. Gaspar, 1986 .

Extrusion of dimethylsilylene from 1,1-dimethyl-1-silacyclopent-3-enes

P. Gaspar, D. Lei, 1985 .

OBSERVATION OF A TRIPLET PHOSPHINIDENE BY ESR SPECTROSCOPY

A. Smirnov, P. Gaspar, Tien-Sung Lin, 1994 .

General approaches to phosphinidenes via retroadditions

P. Gaspar, M. Chiang, D. Lei, 1992 .

Dihydrobis(3,5-dimethylpyrazolyl)borate derivatives of ƒ elements

P. Gaspar, I. Santos, N. Marques, 1992 .

States of atomic carbon produced in decomposition of organic compounds in a microwave plasma

A. Wolf, P. Gaspar, Ernest Y. Y. Lam, 1971 .

2,6-Dimethoxyphenylphosphirane Oxide and Sulfide and their Thermolysis to Phosphinidene Chalcogenides—Kinetic and Mechanistic Studies

A. Beatty, D. D'avignon, P. Gaspar, 2000 .

Interconversion of o-, m- and p-Tolylcarbenes

P. Gaspar, W. J. Baron, Maitland Jones, 1970 .

Chemical Kinetics and Hot Atom Chemistry — Present Status and Future Perspectives

J. W. Root, P. Gaspar, 1981 .

Implications of ion‐molecule reactions observed in silane for recoil silicon atom studies

P. Gaspar, G. Stewart, J. M. Henis, 1973 .

Ion‐Molecule Reactions in Silane

P. Gaspar, G. Stewart, J. M. Henis, 1972 .

What accounts for the difference between singlet phenylphosphinidene and singlet phenylnitrene in reactivity toward ring expansion?

P. Gaspar, W. T. Borden, John Morrison Galbraith, 2002, Journal of the American Chemical Society.

REACTIONS OF RECOILING GERMANIUM ATOMS IN GERMANE, DIGERMANE AND GERMANE-SILANE MIXTURES

P. Gaspar, J. J. Frost, 1973 .

Silanium SiH5+. The protonation of silane and the chemistry of silanium ions studied by ion cyclotron resonance spectroscopy

P. Gaspar, M. Sefcík, J. M. Henis, 1974 .

Gas phase reactions of SiF2 with F2 and Cl2

A. Stanton, A. Freedman, P. Gaspar, 1985 .

Radical Cation/Radical Reactions: A Fourier Transform Ion Cyclotron Resonance Study of Allyl Radical Reacting with Aromatic Radical Cations.

M. Gross, H. Rohrs, P. Gaspar, 2009, International journal of mass spectrometry.

ADDITION OF DIPHENYLMETHYLENE TO 1,2-DICHLOROETHYLENES. NEW CHEMICAL EVIDENCE FOR A CARBENE SINGLET-TRIPLET EQUILIBRIUM

P. Gaspar, J. B. Lambert, Maitland Jones, 1980 .

Hydrogen elimination from carbon‐silicon ion molecule reaction intermediates

P. Gaspar, G. Stewart, J. M. Henis, 1974 .

Rates of reaction of hydrogen atoms with silane and germane

Alfred P. Wolf, A. Wolf, K. Choo, 1975 .

The phenylcarbene rearrangement revisited

P. Gaspar, Maitland Jones, S. Chari, 1985 .

Germanium atoms. Reactions with germane and silane [33]

P. Gaspar, C. A. Levy, J. J. Frost, 1969 .

Workshop on „the Applications of Quantum Mechanical Methods in Gas Phase Ion Chemistry“

D. J. Berger, K. Ruud, T. Helgaker, 1999 .

Germylene and Stannylene Anion-Radicals: Generation and Electronic Structure

P. Gaspar, O. M. Nefedov, T. Lin, 1995 .

Di(9-anthryl)carbene Revisited. Product Analysis and Spectroscopic Studies

P. Gaspar, Yasutake Takahashi, Katsuyuki Hirai, 2004 .

The disappearance of aryl carbenes in a reactive matrix

P. Gaspar, Cheng‐Tung Lin, 1981 .

Temperature dependence of gas phase reactions of SiF2 with F2 and Cl2

A. Freedman, P. Gaspar, J. Wormhoudt, 1987 .

Efficient Laboratory-Scale Germanium Direct Synthesis

P. Gaspar, Myong-Euy Lee, D. Lei, 1990 .

Efficient Laboratory-Scale Germanium Direct Synthesis.

P. Gaspar, Myong-Euy Lee, D. Lei, 1990 .

Molecular Orbital Theory for Organic Chemists

P. Gaspar, Peter P. Gaspar, 1966 .

Rate constants for the reactions of atomic chlorine with Group 4 and Group 5 hydrides

A. Wolf, D. Schlyer, P. Gaspar, 1978 .

Disappearance of silyl radicals in silane. Flash photolysis-electron spin resonance kinetic study

K. Choo, P. Gaspar, Allene D. Haizlip, 1972 .

Reaction of Recoiling Silicon Atoms with Phosphine and Silane

W. Eckelman, P. Gaspar, B. Pate, 1966 .

Addition of fluorenylidene to 1,2-dichloroethylenes. Effects of additives and the question of spin-state equilibrium

D. P. Mack, P. Gaspar, P. Balasubramanian, 1984 .

Tri-tert-butylsilylsilylenes with alkali metal substituents ((t)Bu3Si)SiM (M = Li, K): electronically and sterically accessible triplet ground states.

A. Sekiguchi, P. Gaspar, Takashi Tanaka, 2008, Journal of the American Chemical Society.

Tri-tert-butylsilyl(triisopropylsilyl)silylene (tBu)(3)Si-Si-Si(iPr)(3) and chemical evidence for its reactions from a triplet electronic state.

P. Gaspar, P. Jiang, 2001, Journal of the American Chemical Society.

In search of triplet silylenes

H. Schaefer, P. Gaspar, R. S. Grev, 1991 .

Time-resolved spectroscopic studies of the photochemistry of some diphenylgermylene (Ph2Ge:) precursors

P. Gaspar, W. Leigh, B. Chan, 2005 .

Kinetic Studies on the Thermal Decomposition of trans-2,3-Dimethyl-1-tri-tert-butylsilyl-1-triisopropylsilylsilirane and the Mechanism of Silylene Generation

P. Gaspar, P. Jiang, D. A. Trieber, 2003 .

REACTION STUDIES OF HOT SILICON AND GERMANIUM RADICALS. Progress Report, September 1, 1969--August 31, 1970.

P. Gaspar, 1974 .

R3Si+--Free at Last

P. Gaspar, 2002, Science.