Shenglai Yao

发表

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

M. Driess, Shenglai Yao, Y. Xiong, 2011 .

Dual Reactivity of a Stable Zwitterionic N-Heterocyclic Silylene and Its Carbene Complex Probed with Muonium

R. West, B. McCollum, J. Brodovitch, 2012 .

Chelate Silylene-Silyl Ligand Can Boost Rhodium-Catalyzed C-H Bond Functionalization Reactions.

M. Driess, Shenglai Yao, Z. Mo, 2018, Chemistry.

New Types of Ge2 and Ge4 Assemblies Stabilized by a Carbanionic Dicarborandiyl-Silylene Ligand.

M. Driess, A. Růžička, Shenglai Yao, 2021, Journal of the American Chemical Society.

A bis(silylene)-stabilized diphosphorus compound and its reactivity as a monophosphorus anion transfer reagent

M. Driess, Shenglai Yao, Yuwen Wang, 2020, Nature Chemistry.

Facile Rearrangement of a Bis(N-heterocyclic carbene)borate Chelate Ligand and Access to [:GeX]+Complexes (X = H, Cl): Rearrangement of a Bis(NHC)borate Chelate Ligand

M. Driess, Shenglai Yao, Y. Xiong, 2015 .

Isolable Dibenzo[a,e]disilapentalene with a Dichotomic Reactivity toward CO2.

M. Driess, Shenglai Yao, A. Kostenko, 2020, Journal of the American Chemical Society.

Silicon-Mediated Selective Homo- and Heterocoupling of Carbon Monoxide.

M. Driess, Shenglai Yao, Yuwen Wang, 2018, Journal of the American Chemical Society.

An S-Oxygenated [NiFe] Complex Modelling Sulfenate Intermediates of an O2 -Tolerant Hydrogenase.

M. Driess, I. Zebger, Shenglai Yao, 2017, Angewandte Chemie.

From Silylone to an Isolable Monomeric Silicon Disulfide Complex.

M. Driess, M. Kaupp, Shenglai Yao, 2015, Angewandte Chemie.

An Isolable Silicon Dicarbonate Complex from Carbon Dioxide Activation with a Silylone.

M. Driess, M. Kaupp, Shenglai Yao, 2017, Angewandte Chemie.

Synthesis of an Isolable Bis(silylene)-Stabilized Silylone and Its Reactivity Toward Small Gaseous Molecules.

M. Driess, Y. Apeloig, Shenglai Yao, 2019, Journal of the American Chemical Society.

Photoredox-mediated N-centered radical addition/semipinacol rearrangement for the convenient synthesis of β-amino (spiro)cyclic ketones

Shenglai Yao, W. Xiao, T. Ma, 2021 .

Hydride binding to the active site of [FeFe]-hydrogenase.

M. Driess, M. Haumann, Shenglai Yao, 2014, Inorganic chemistry.

Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins.

M. Driess, Shenglai Yao, Yuwen Wang, 2017, Journal of the American Chemical Society.

Lessons from isolable nickel(I) precursor complexes for small molecule activation.

M. Driess, Shenglai Yao, 2012, Accounts of chemical research.

A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(mu-OH)2NiL].

K. Wieghardt, M. Driess, Shenglai Yao, 2008, Angewandte Chemie.

O-O bond activation in heterobimetallic peroxides: synthesis of the peroxide [LNi(mu,eta2:eta2-O2)K] and its conversion into a bis(mu-hydroxo) nickel zinc complex.

M. Driess, Shenglai Yao, Y. Xiong, 2009, Angewandte Chemie.

Dioxygenase-like reactivity of an isolable superoxo-nickel(II) complex.

M. Driess, K. Ray, Shenglai Yao, 2010, Chemistry.

From a paramagnetic, mononuclear supersulfidonickel(II) complex to a diamagnetic dimer with a four-sulfur two-electron bond.

K. Wieghardt, M. Driess, Shenglai Yao, 2008, Journal of the American Chemical Society.

A high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups.

P. Hildebrandt, M. Driess, F. Pfaff, 2013, Angewandte Chemie.

From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature.

M. Driess, M. Kaupp, Shenglai Yao, 2010, Nature chemistry.

EPR spectroscopic characterization of persistent germyl-substituted Pb(III)- and Sn(III)-radicals.

D. Hinderberger, Shenglai Yao, D. Kurzbach, 2010, Dalton transactions.

From an Fe2P3 complex to FeP nanoparticles as efficient electrocatalysts for water-splitting

P. Menezes, M. Driess, M. Haumann, 2018, Chemical science.

Monooxygenase-like reactivity of an unprecedented heterobimetallic {FeO2Ni} moiety.

M. Driess, Shenglai Yao, Y. Xiong, 2010, Angewandte Chemie.

From a Molecular 2Fe-2Se Precursor to a Highly Efficient Iron Diselenide Electrocatalyst for Overall Water Splitting.

P. Menezes, M. Driess, Shenglai Yao, 2017, Angewandte Chemie.

Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks.

M. Driess, Shenglai Yao, Y. Xiong, 2013, Angewandte Chemie.

β-Diketiminato Nickel(I) Complexes with Very Weak Ligation Allowing for H2 and N2 Activation

M. Driess, Shenglai Yao, C. Limberg, 2009 .

A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)2 M'] Complexes in Oxidation Reactions.

P. Hildebrandt, M. Driess, K. Ray, 2017, Angewandte Chemie.

A heterofulvene-like germylene with a betain reactivity.

M. Brym, M. Driess, Shenglai Yao, 2006, Angewandte Chemie.

Reversible P(4) activation with nickel(I) and an eta(3)-coordinated tetraphosphorus ligand between two Ni(I) centers.

M. Driess, Shenglai Yao, Y. Xiong, 2010, Chemistry.

Facile dissociation of [(LNi(II))2E2] dichalcogenides: evidence for [LNi(II)E2] superselenides and supertellurides in solution.

M. Driess, H. Schwarz, Shenglai Yao, 2009, Angewandte Chemie.

An unsymmetric substituted digermylene with a Ge(I)-Ge(I) bond and synthesis of a germylene-stannylene with a Ge(I)-Sn(I) bond.

M. Driess, Shenglai Yao, S. Inoue, 2009, Chemical communications.

An Isolable 2,5‐Disila‐3,4‐Diphosphapyrrole and a Conjugated Si=P−Si=P−Si=N Chain Through Degradation of White Phosphorus with a N,N‐Bis(Silylenyl)Aniline

M. Driess, Shenglai Yao, Y. Xiong, 2022, Angewandte Chemie.

A bis(silylene)pyridine pincer ligand can stabilize mononuclear manganese(0) complexes: facile access to isolable analogues of the elusive d7-Mn(CO)5 radical

M. Driess, Shenglai Yao, K. Meyer, 2022, Chemical science.

Unexpected White Phosphorus (P4) Activation Modes with Silylene‐Substituted o‐Carboranes and Access to an Isolable 1,3‐Diphospha‐2,4‐disilabutadiene

M. Driess, Shenglai Yao, Y. Xiong, 2022, Angewandte Chemie.

A cyclic germadicarbene ("germylone") from germyliumylidene.

M. Driess, Shenglai Yao, Y. Xiong, 2013, Journal of the American Chemical Society.

N-heterocyclic carbene (NHC)-stabilized silanechalcogenones: NHC-->Si(R2)=E (E=O, S, Se, Te).

M. Driess, Shenglai Yao, Y. Xiong, 2010, Chemistry.

From NHC-->germylenes to stable NHC-->germanone complexes.

M. Driess, Shenglai Yao, Y. Xiong, 2009, Chemical communications.

An isolable NHC-supported silanone.

M. Driess, Shenglai Yao, Y. Xiong, 2009, Journal of the American Chemical Society.

Si=X multiple bonding with four-coordinate silicon? Insights into the nature of the Si=O and Si=S double bonds in stable silanoic esters and related thioesters: a combined NMR spectroscopic and computational study.

J. Epping, M. Driess, Y. Apeloig, 2010, Journal of the American Chemical Society.

A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom.

J. Epping, M. Driess, Shenglai Yao, 2013, Angewandte Chemie.

Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application.

M. Driess, Shenglai Yao, C. Limberg, 2017, Dalton transactions.

Striking reactivity of a stable, zwitterionic silylene towards substituted diazomethanes, azides, and isocyanides.

M. Driess, Shenglai Yao, Y. Xiong, 2009, Chemistry.

Dichotomic reactivity of a stable silylene toward terminal alkynes: facile C-H bond insertion versus autocatalytic formation of silacycloprop-3-ene.

M. Driess, Shenglai Yao, Christoph van Wüllen, 2008, Angewandte Chemie.

An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal-Free Dehydrogenation of Water.

M. Driess, Shenglai Yao, Z. Mo, 2017, Angewandte Chemie.

A zwitterionic silylene as reactive intermediate and its unusual dimerization to an N-heterobicyclic disilane.

M. Driess, Shenglai Yao, Y. Xiong, 2009, Chemistry, an Asian journal.

Striking reactivity of ylide-like germylene toward terminal alkynes: [4+2] cycloaddition versus C-H bond activation.

M. Driess, Shenglai Yao, Christoph van Wüllen, 2008, Chemical communications.

Facile metalation of silicon and germanium analogues of thiocarboxylic acids with a manganese(II) hydride precursor.

M. Driess, Shenglai Yao, Y. Xiong, 2012, Chemistry.

A new type of heteroleptic complex of divalent lead and synthesis of the P-plumbyleniophosphasilene, R2Si=P-Pb(L): (L = beta-diketiminate).

M. Brym, M. Driess, Shenglai Yao, 2007, Chemical communications.

Synthesis and tunable reactivity of N-heterocyclic germylene.

M. Driess, Shenglai Yao, Y. Xiong, 2012, Chemistry, an Asian journal.

Changing the chemical and physical properties of high valent heterobimetallic bis-(μ-oxido) Cu-Ni complexes by ligand effects.

M. Orio, P. Hildebrandt, M. Driess, 2016, Dalton transactions.

Consecutive insertion of a silylene into the P4 tetrahedron: facile access to strained SiP4 and Si2P4 cage compounds.

M. Brym, M. Driess, Shenglai Yao, 2007, Angewandte Chemie.

Silicon-Mediated Coupling of Carbon Monoxide, Ammonia and Primary Amines to Form Acetamides.

M. Driess, Shenglai Yao, Yuwen Wang, 2019, Angewandte Chemie.

Silicon‐Mediated Coupling of Carbon Monoxide, Ammonia, and Primary Amines to Form Acetamides

M. Driess, Shenglai Yao, Yuwen Wang, 2019, Angewandte Chemie.

Synthesis, structure, and reactivity of a pyridine-stabilized germanone.

M. Driess, Shenglai Yao, Y. Xiong, 2011, Chemistry.

Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2 Group and Related PR2 Derivatives

M. Brym, M. Driess, K. Merz, 2008 .

Synthesis and rearrangement of stable NHC-->silylene adducts and their unique reactivity towards cyclohexylisocyanide.

M. Driess, Shenglai Yao, Y. Xiong, 2010, Chemistry, an Asian journal.

Isomerization of an N-Heterocyclic Germylene to an Azagermabenzen-1-ylidene and Its Coupling to a Unique Bis(germylene)§

M. Driess, H. Schwarz, Shenglai Yao, 2010 .

An isolable bis-silylene oxide ("disilylenoxane") and its metal coordination.

M. Driess, Shenglai Yao, S. Inoue, 2010, Journal of the American Chemical Society.

Reactivity of N-Heterocyclic Germylene Toward Ammonia and Water

M. Driess, Shenglai Yao, S. Inoue, 2011 .

Facile Access to NaOC≡As and Its Use as an Arsenic Source To Form Germylidenylarsinidene Complexes.

M. Driess, Shenglai Yao, A. Kostenko, 2017, Angewandte Chemie.

Taming Silicon Congeners of CO and CO2 : Synthesis of Monomeric SiII and SiIV Chalcogenide Complexes.

M. Driess, M. Kaupp, Shenglai Yao, 2017, Angewandte Chemie.

The elusive silyliumylidene [ClSi:]+ and silathionium [ClSi=S]+ cations stabilized by bis(iminophosphorane) chelate ligand.

M. Driess, Shenglai Yao, Y. Xiong, 2012, Angewandte Chemie.

Versatile reactivity of a zwitterionic isolable silylene toward ketones: silicon-mediated, regio- and stereoselective C-H activation.

M. Driess, Shenglai Yao, Y. Xiong, 2009, Chemistry.

Homo‐ and Heteroleptic Hypersilylcuprates — Valuable Reagents for the Synthesis of Molecular Compounds with a Cu−Si Bond

J. Klett, Shenglai Yao, Y. Xiong, 2003 .

Versatile conversion of N-heterocyclic silylene to silyl metal compounds by insertion of divalent silicon into metal-carbon and metal-hydrogen bonds.

M. Driess, Shenglai Yao, Y. Xiong, 2012, Chemistry.

An Isolable Bis(Silanone–Borane) Adduct

M. Driess, Shenglai Yao, Marcel-Philip Luecke, 2020, Chemistry.

Biomimetic [2Fe-2S] clusters with extensively delocalized mixed-valence iron centers.

F. Meier, M. Driess, M. Haumann, 2015, Angewandte Chemie.

A heterobimetallic approach to stabilize the elusive disulfur radical trianion ("subsulfide") S2(·3-).

F. Meier, M. Driess, M. Kaupp, 2013, Chemistry.

From a Molecular Single‐Source Precursor to a Selective High‐Performance RhMnOx Catalyst for the Conversion of Syngas to Ethanol

R. Kraehnert, M. Driess, Shenglai Yao, 2019, ChemCatChem.

Bis(silylene)‐Stabilized Monovalent Nitrogen Complexes

M. Driess, A. Růžička, Shenglai Yao, 2020, Angewandte Chemie.

Synthesis and structure of the azidogermyliumylidene azide complex [L(N3)Ge:](+)N3- with covalently and ionically bonded azide ligands at germanium(II) [L = bis(N-heterocyclic carbene)].

M. Driess, Shenglai Yao, Y. Xiong, 2014, Chemical communications.

From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character.

M. Brym, M. Driess, Shenglai Yao, 2007, Angewandte Chemie.

Silicon analogues of carboxylic acids: synthesis of isolable silanoic acids by donor-acceptor stabilization.

M. Driess, Shenglai Yao, Y. Xiong, 2010, Angewandte Chemie.

An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity.

M. Driess, Y. Apeloig, Shenglai Yao, 2018, Journal of the American Chemical Society.

Reductive cleavage of P4 by iron(I) centres: synthesis and structural characterisation of Fe2(P2)2 complexes with two bridging P2(2-) ligands.

M. Driess, Shenglai Yao, Y. Xiong, 2015, Chemical communications.

Heavier congeners of CO and CO2 as ligands: from zero-valent germanium (‘germylone’) to isolable monomeric GeX and GeX2 complexes (X = S, Se, Te)

M. Driess, Y. Apeloig, Shenglai Yao, 2016, Chemical science.

Coordination of a SiO subunit to metals: complexes of donor-stabilized silanone featuring a terminal SiO→M coordination (M = Zn, Al)

M. Driess, Shenglai Yao, Y. Xiong, 2010 .

Activation of ammonia by a Si=O double bond and formation of a unique pair of sila-hemiaminal and silanoic amide tautomers.

M. Driess, M. Kaupp, Shenglai Yao, 2010, Journal of the American Chemical Society.

From a stable silanone complex to isolable, donor-supported silicoxonium halides [LSi(dmap)=O-SiMe3](+)X-.

M. Driess, Shenglai Yao, Y. Xiong, 2011, Chemistry.

Coordination of a Si[double bond, length as m-dash]O subunit to metals: complexes of donor-stabilized silanone featuring a terminal Si[double bond, length as m-dash]O→M coordination (M = Zn, Al).

M. Driess, Shenglai Yao, Y. Xiong, 2010, Dalton transactions.

An isolable silanoic ester by oxygenation of a stable silylene.

M. Brym, M. Driess, Shenglai Yao, 2007, Journal of the American Chemical Society.

A series of isolable silanoic thio-, seleno-, and telluroesters (LSi(=X)OR) with donor-supported Si=X double bonds (L = beta-diketiminate; X = S, Se, Te).

M. Brym, M. Driess, Shenglai Yao, 2008, Chemistry, an Asian journal.

Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand

M. Driess, A. Růžička, Shenglai Yao, 2021, Angewandte Chemie.

Redox Non-Innocent Monoatomic Silicon(0) Complex ('Silylone'): Its One-Electron-Reduction Induces an Intramolecular One-Electron-Oxidation of Silicon(0) to Silicon(I).

M. Driess, A. Růžička, Shenglai Yao, 2020, Journal of the American Chemical Society.

A New Area in Main-Group Chemistry: Zerovalent Monoatomic Silicon Compounds and Their Analogues.

M. Driess, Shenglai Yao, Y. Xiong, 2017, Accounts of chemical research.

A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity.

M. Driess, Y. Apeloig, Shenglai Yao, 2016, Angewandte Chemie.

From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene.

M. Driess, Shenglai Yao, Y. Xiong, 2016, Angewandte Chemie.

A new type of N-heterocyclic silylene with ambivalent reactivity.

M. Brym, M. Driess, Shenglai Yao, 2006, Journal of the American Chemical Society.

A neutral tetraphosphacyclobutadiene ligand in cobalt(I) complexes.

M. Driess, Shenglai Yao, Y. Xiong, 2015, Angewandte Chemie.

Distinctly different reactivity of bis(silylenyl)-versus phosphanyl-silylenyl-substituted o-dicarborane towards O2, N2O and CO2.

M. Driess, A. Růžička, Shenglai Yao, 2021, Chemical communications.

Chelating Bis-silylenes As Powerful Ligands To Enable Unusual Low-Valent Main-Group Element Functions.

M. Driess, Shenglai Yao, Y. Xiong, 2023, Accounts of chemical research.

Homocoupling of CO and isocyanide mediated by a C,C'-bis(silylenyl)-substituted ortho-carborane.

M. Driess, A. Růžička, Shenglai Yao, 2019, Chemical communications.

Side-on coordination of a P-P bond in heterobinuclear tetraphosphorus complexes with a [Si(mu,eta(2:2)-P(4))Ni] core and nickel(I) centers.

M. Driess, Shenglai Yao, Y. Xiong, 2009, Inorganic chemistry.

Low-valent silicon cations with two-coordinate silicon and aromatic character.

M. Brym, M. Driess, Shenglai Yao, 2006, Angewandte Chemie.

Facile Access to an Active γ‐NiOOH Electrocatalyst for Durable Water Oxidation Derived From an Intermetallic Nickel Germanide Precursor

P. Menezes, M. Driess, Shenglai Yao, 2020, Angewandte Chemie.

Where silylene-silicon centres matter in the activation of small molecules.

M. Driess, Shenglai Yao, Changkai Shan, 2020, Chemical Society reviews.

Boosting Electrocatalytic Hydrogen Evolution Activity with a NiPt3@NiS Hetero-Nanostructure Evolved from a Molecular Nickel-Platinum Precursor.

Johannes Schmidt, P. Menezes, M. Driess, 2019, Journal of the American Chemical Society.

Synthesis, Reactivity, and Electronic Structure of a Bioinspired Heterobimetallic [Ni(μ-S2)Fe] Complex with Disulfur Monoradical character

F. Meier, M. Driess, M. Kaupp, 2014 .

Unexpected Photodegradation of a Phosphaketenyl-Substituted Germyliumylidene Borate Complex.

M. Driess, Shenglai Yao, Y. Xiong, 2017, Angewandte Chemie.

From zinco(ii) arsaketenes to silylene-stabilised zinco arsinidene complexes.

M. Driess, Shenglai Yao, T. Szilvási, 2018, Chemical communications.

Synthesis and unexpected reactivity of germyliumylidene hydride [:GeH]+ stabilized by a bis(N-heterocyclic carbene)borate ligand.

M. Driess, Shenglai Yao, Y. Xiong, 2014, Journal of the American Chemical Society.

A class of non-aromatic 1,3-disilapyrroles acting as stable organosilicon-based triplet diradicals

M. Driess, Shenglai Yao, Y. Xiong, 2023, Nature Synthesis.

Taming the germyliumylidene [CIGe:]+ and germathionium [CIGe=S]+ ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene.

M. Driess, Shenglai Yao, Y. Xiong, 2012, Chemical communications.

Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst†

M. Driess, Shenglai Yao, M. Lücke, 2021, Chemical science.

Synthesis and Reactivity of an Anti-van't Hoff/Le Bel Compound with a Planar Tetracoordinate Silicon(II) Atom.

M. Driess, Shenglai Yao, Shicheng Dong, 2023, Journal of the American Chemical Society.

An isolable β-diketiminato chlorosilylene.

M. Driess, Shenglai Yao, Y. Xiong, 2018, Dalton Transactions.

From an N-Heterocyclic Silacyclopropene to Donor-Supported Silacyclopropenylium Cations

M. Driess, Shenglai Yao, Y. Xiong, 2009 .

Twice silicon-induced C-H activation and tautomerisation of a beta-diketiminato ligand and formation of new types of N-heterocyclic silanes.

M. Driess, Shenglai Yao, Y. Xiong, 2009, Dalton transactions.

A cyclopentadienide analogue containing divalent germanium and a heavy cyclobutadiene-like dianion with an unusual Ge4 core.

M. Driess, Shenglai Yao, Christoph van Wüllen, 2008, Journal of the American Chemical Society.