Rajendra S. Ghadwal

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A dimer of silaisonitrile with two-coordinate silicon atoms.

G. Frenking, Rajendra S. Ghadwal, H. Roesky, 2011, Angewandte Chemie.

Mono- and di-cationic hydrido boron compounds.

G. Frenking, Rajendra S. Ghadwal, C. Schürmann, 2015, Dalton transactions.

A crystalline C5-protonated 1,3-imidazol-4-ylidene.

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2020, Chemical communications.

Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.

Rajendra S. Ghadwal, 2016, Dalton transactions.

Unprecedented Borylene Insertion into a C-N Bond: Unprecedented Borylene Insertion into a C-N Bond

Rajendra S. Ghadwal, C. Schürmann, F. Engelhardt, 2014 .

Double N-H bond activation of N,N'-bis-substituted hydrazines with stable N-heterocyclic silylene.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2012, Dalton transactions.

Reactions of Stable N-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2011 .

Isolation of Elusive Electrophilic Phosphinidene Complexes with π-Donor N-Heterocyclic Vinyl Substituents.

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2020, The Journal of organic chemistry.

Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.

D. Stalke, R. Herbst‐Irmer, R. Mata, 2013, Chemistry.

Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications.

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2020, Chemical communications.

Synthesis and Spectroscopic Characterization of Two Different Types of Heterobimetallic Glycolate Complexes of Niobium(V)

Anirudh Singh, Rajendra S. Ghadwal, R. C. Mehrotra, 2005 .

Nickel-catalysed direct C2-arylation of N-heterocyclic carbenes.

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2017, Dalton transactions.

Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3.

G. Frenking, Rajendra S. Ghadwal, D. Andrada, 2013, Chemical communications.

Synthesis and characterisation of heterobimetallic N-(hydroxyethyl)-salicylaldiminate–isopropoxide complexes of oxovanadium(V)

Anirudh Singh, Rajendra S. Ghadwal, R. C. Mehrotra, 2005 .

Tuning the Electronic Properties of Main-Group Species by N-Heterocyclic Vinyl (NHV) Scaffolds

Rajendra S. Ghadwal, 2022, Accounts of Chemical Research.

Quantifying the Electronic and Steric Properties of 1,3-Imidazole-Based Mesoionic Carbenes (iMICs)

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2020 .

Silylene-Functionalized N-Heterocyclic Carbene (Si-NHC).

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2018, Chemistry.

Normal-to-abnormal rearrangement of an N-heterocyclic carbene with a silylene transition metal complex.

G. Frenking, Rajendra S. Ghadwal, H. Stammler, 2017, Dalton transactions.

Synthesis and structural investigation of R2Si (R = Me, Ph) bridged di-N-heterocyclic carbenes.

R. Herbst‐Irmer, E. Carl, Rajendra S. Ghadwal, 2014, Dalton transactions.

Selective functionalization of a bis-silylene.

Rajendra S. Ghadwal, K. Pröpper, B. Dittrich, 2013, Chemical communications.

A facile route to functionalized N-heterocyclic carbenes (NHCs) with NHC base-stabilized dichlorosilylene.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2010, Journal of the American Chemical Society.

Facile routes to abnormal-NHC-cobalt(ii) complexes.

Rajendra S. Ghadwal, S. Demeshko, C. Schürmann, 2017, Dalton transactions.

Lewis base stabilized dichlorosilylene.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2009, Angewandte Chemie.

An Open‐Shell Singlet SnI Diradical and H2 Splitting

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2021, Angewandte Chemie.

Nickel‐Catalyzed Intramolecular 1,2‐Aryl Migration of Mesoionic Carbenes (iMICs)

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2020, Angewandte Chemie.

Saturated NHC Derived Dichalcogen Dications

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2020 .

Distannabarrelenes with Three Coordinated SnII Atoms

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2020, Chemistry.

Crystalline Divinyldiarsene Radical Cations and Dications

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2019, Angewandte Chemie.

Stable Carbon-Centered Radicals Based on N-Heterocyclic Carbenes

Rajendra S. Ghadwal, 2019, Synlett.

A Modular Access to Divinyldiphosphenes with a Strikingly Small HOMO-LUMO Energy Gap.

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2019, Chemistry.

A Phosphorus Analogue of p-Quinodimethane with a Planar P4 Ring: A Metal-Free Diphosphorus Source.

M. Nakano, R. Kishi, Rajendra S. Ghadwal, 2019, Chemistry.

The Viability of C5-Protonated- and C4,C5-Ditopic Carbanionic Abnormal NHCs: A New Dimension in NHC Chemistry.

Rajendra S. Ghadwal, A. Mix, B. Neumann, 2018, Chemistry.

N-Heterocyclic Vinylidene-Stabilized Phosphorus Biradicaloid.

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2017, Chemistry.

Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: an atom-economic route to mesoionic carbene ligands.

R. Herbst‐Irmer, Rajendra S. Ghadwal, S. Reichmann, 2015, Chemistry.

Dichlorosilylene: a high temperature transient species to an indispensable building block.

Rajendra S. Ghadwal, H. Roesky, R. Azhakar, 2013, Accounts of chemical research.

Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2019, Chemical science.

Abnormal-NHC Palladium(II) Complexes: Rational Synthesis, Structural Elucidation, and Catalytic Activity

Rajendra S. Ghadwal, B. Neumann, C. Schürmann, 2016 .

Crystalline Divinyldiarsenes and Cleavage of the As=As Bond.

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2019, Chemistry.

N-Heterocyclic Carbene Analogues of Thiele and Chichibabin Hydrocarbons.

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2018, Angewandte Chemie.

Expedient Access to Normal- and Abnormal- N-Heterocyclic Carbene (NHC) Magnesium Compounds from Imidazolium Salts

Rajendra S. Ghadwal, C. Schürmann, Dennis Rottschäfer, 2016 .

Mixed valence η6-arene cobalt(I) and cobalt(II) compound.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2013, Dalton transactions.

Facile access to transition-metal-carbonyl complexes with an amidinate-stabilized chlorosilylene ligand.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2012, Chemistry, an Asian journal.

Stabilization of low valent silicon fluorides in the coordination sphere of transition metals.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2012, Journal of the American Chemical Society.

N-heterocyclic carbene stabilized dichlorosilylene transition-metal complexes of V(I), Co(I), and Fe(0).

Rajendra S. Ghadwal, H. Roesky, K. Pröpper, 2011, Inorganic chemistry.

Lewis-base-stabilized dichlorosilylene: a two-electron sigma-donor ligand.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2010, Inorganic chemistry.

Diradical Character Enhancement by Spacing: N-Heterocyclic Carbene Analogues of Müller's Hydrocarbon.

M. Nakano, R. Kishi, Rajendra S. Ghadwal, 2018, Chemistry.

Crystalline Radicals Derived from Classical N-Heterocyclic Carbenes.

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2018, Angewandte Chemie.

Expanding the Scope of Cu(I) Catalyzed “Click Chemistry” with Abnormal NHCs: Three-Fold Click to Tris-Triazoles

R. Herbst‐Irmer, Rajendra S. Ghadwal, Dennis Rottschäfer, 2017 .

Donor-acceptor stabilized silaformyl chloride.

G. Frenking, Rajendra S. Ghadwal, H. Roesky, 2012, Chemical communications.

Lewis base mediated dismutation of trichlorosilane.

A. Singh, Rajendra S. Ghadwal, H. Roesky, 2012, Chemical communications.

Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2012 .

A début for base stabilized monoalkylsilylenes.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2012, Chemical communications.

Donor-acceptor-stabilized silicon analogue of an acid anhydride.

G. Frenking, Rajendra S. Ghadwal, H. Roesky, 2011, Journal of the American Chemical Society.

Neutral pentacoordinate silicon fluorides derived from amidinate, guanidinate, and triazapentadienate ligands and base-induced disproportionation of Si2Cl6 to stable silylenes.

Rajendra S. Ghadwal, H. Roesky, K. Pröpper, 2011, Inorganic chemistry.

N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR

Rajendra S. Ghadwal, H. Roesky, C. Schulzke, 2010 .

Convenient access to monosilicon epoxides with pentacoordinate silicon.

D. Stalke, D. Kratzert, Rajendra S. Ghadwal, 2010, Angewandte Chemie.

Ambiphilicity of dichlorosilylene in a single molecule.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2010, Chemistry.

Neutral Penta- and Hexacoordinate N-Heterocyclic Carbene Complexes Derived from SiX4 (X = F, Br)

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2009 .

N‐Heterocyclic Carbene Adducts of Aluminium Triiodide

R. Herbst‐Irmer, Rajendra S. Ghadwal, H. Roesky, 2009 .

Stable silaimines with three- and four-coordinate silicon atoms.

D. Stalke, R. Herbst‐Irmer, Rajendra S. Ghadwal, 2012, Inorganic chemistry.

Free radical reactivity of mono- and dichlorosilylene with muonium.

R. West, J. Brodovitch, P. W. Percival, 2011, Chemistry.

Isolation of a 16π‐Electrons 1,4‐Diphosphinine‐1,4‐diide with a Planar C4P2 Ring

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2020, Chemistry.

An access to base-stabilized three-membered silicon heterocycles.

Rajendra S. Ghadwal, H. Roesky, B. Dittrich, 2012, Dalton transactions.

Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: an atom-economic route to mesoionic carbene ligands.

R. Herbst‐Irmer, Rajendra S. Ghadwal, S. Reichmann, 2015, Chemistry.

Synthesis and Spectroscopic Properties of the First Series of Heteronuclear Derivatives Containing Organosilicon/Organotin (IV) and Oxovanadium (V) Moieties

Rajendra S. Ghadwal, R. C. Mehrotra, Anirudh P. Singh, 2006 .

Synthesis and Spectroscopic Characterisation of Six-Coordinate Complexes of Oxovanadium(V)

Rajendra S. Ghadwal, Malti Sharma, R. C. Mehrotra, 2004 .

Synthesis and spectroscopic properties of homo– and heterobimetallic complexes of oxovanadium (V)

Rajendra S. Ghadwal, Anirudh P. Singh, 2006 .

Homometallic glycolates containing hydroxyl functionality for anchoring another metal: synthesis and characterization of heterometallic alkoxide–glycolates of Ti and Zr incorporating Al and Nb

Rajendra S. Ghadwal, Shashank Mishra, E. Jeanneau, 2016 .

Synthesis and Spectroscopic Structural Elucidation of Some Novel Heterobimetallic Complexes of Monoorganotin (IV)

Rajendra S. Ghadwal, N. Sharma, Anirudh P. Singh, 2009 .

Kekulé diradicaloids derived from a classical N-heterocyclic carbene† †Electronic supplementary information (ESI) available. CCDC 1826567–1826570. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01209a

Rajendra S. Ghadwal, B. Neumann, H. Stammler, 2018, Chemical science.

Preparation and Characterisation of Heteronuclear Mixed Ligand Complexes of Aluminium Containing Organosilicon/Organotin Moieties

Rajendra S. Ghadwal, N. Sharma, Anirudh P. Singh, 2005 .

Preparation and Spectroscopic [IR, NMR (1H, 11B, 27Al, 51V)] Characterisation of New Types of Heteronuclear Derivatives of Aluminium and Boron Containing Bis (2,5- dimethyl-2,5-hexanediolato)oxovanadium(V) Group

Rajendra S. Ghadwal, R. C. Mehrotra, Anirudh P. Singh, 2004 .

Advances and recent trends in dipnictenes chemistry

Rajendra S. Ghadwal, Falk Ebeler, L. Weber, 2022, Coordination Chemistry Reviews.

Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom.

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2019, Chemical communications.

Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework.

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2019, Chemical communications.

Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2020, Chemical science.

Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting.

M. K. Sharma, Rajendra S. Ghadwal, B. Neumann, 2020, Journal of the American Chemical Society.

Reactivity Studies of a Stable N-Heterocyclic Silylene with Triphenylsilanol and Pentafluorophenol

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2012 .

Synthesis and Spectroscopic [IR,NMR(1H, 27Al and 51V)] Characterisation of Heterobimetallic Glycolate-and Diethanolaminate-Isopropoxide Complexes of Aluminium

Rajendra S. Ghadwal, R. C. Mehrotra, Anirudh P. Singh, 2006 .

Synthesis and Spectroscopic Characterisation of a New Class of Heterobimetallic Homoleptic Diethanolaminate Complexes of Niobium(V) and Tantalum(V) †

Rajendra S. Ghadwal, Anirudh P. Singh, 2006 .

Facile access to transition-metal-carbonyl complexes with an amidinate-stabilized chlorosilylene ligand.

D. Stalke, Rajendra S. Ghadwal, H. Roesky, 2012, Chemistry, an Asian journal.

Mono- and di-cationic hydrido boron compounds.

G. Frenking, Rajendra S. Ghadwal, C. Schürmann, 2015, Dalton transactions.

Synthesis and Characterisation of Some Novel Seven-membered Heterocyclic Antimony(III) Glycolate Complexes

Rajendra S. Ghadwal, Anirudh P. Singh, Nandu Β. Sharma †,, 2008 .