A. J. Downs

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Methylzinc tetrahydroborate: investigation of the vapour phase by spectroscopic and quantum chemical techniques

S. Aldridge, A. J. Downs, M. Hofmann, 1998 .

The photochemical behaviour of matrix-isolated W(CO)6 in the presence of alkynes☆

A. J. Downs, T. Szymańska-Buzar, T. M. Greene, 1995 .

Matrix-isolation studies of intermediates in the photochemical reaction of W(CO)6 with CCl4

A. J. Downs, T. Szymańska-Buzar, T. M. Greene, 1991 .

Molecular structure of gaseous titanium tris(tetrahydroborate), Ti(BH4)3: experimental determination by electron diffraction and molecular orbital analysis of some Ti(BH4)3 derivatives

H. Robertson, David G. Evans, A. J. Downs, 1991 .

Coming to Grips with Reactive Intermediates

A. J. Downs, T. M. Greene, 1998 .

26 – CHLORINE, BROMINE, IODINE AND ASTATINE

A. J. Downs, C. Adams, 1973 .

Matrix Photochemistry of Gallium and Indium Atoms (M) in the Presence of Methane: Formation and Characterization of the Divalent Species CH3MH and Univalent Species CH3M

L. Andrews, A. J. Downs, T. M. Greene, 2000 .

Some chemical properties of monochlorogallane: decomposition to gallium(I) trichlorogallate(III), Ga(+)[GaCl3H](-), and other reactions.

A. J. Downs, C. Pulham, T. M. Greene, 2001, Inorganic chemistry.

Reactions of ground state and electronically excited atoms of main group elements: a matrix perspective.

A. J. Downs, T. M. Greene, Hans‐Jörg Himmel, 2002, Chemical reviews.

Characterization and photochemistry of the gallium and indium subhydrides Ga2H2 and In2H2.

L. Manceron, A. J. Downs, Hans‐Jörg Himmel, 2002, Angewandte Chemie.

Matrix reactivity of Al and Ga atoms (M) in the presence of silane: generation and characterization of the eta2-coordinated complex M.SiH4, the insertion product HMSiH3, and the MI species MSiH3 in a solid argon matrix.

A. J. Downs, T. M. Greene, Hans‐Jörg Himmel, 2004, Chemistry.

The molecular structure of tetramethyldiarsine, As2 (CH3)4, in the gas phase as determined by electron diffraction

H. Robertson, A. J. Downs, D. Rankin, 1991 .

Molecular structures of free quinuclidine and its adducts with metal trihydrides, MH3 (M=B, Al or Ga), studied by gas-phase electron diffraction, X-ray diffraction and quantum chemical calculations.

H. Robertson, A. J. Downs, D. Wann, 2007, Dalton transactions.

Removal of methylene blue from colored effluents by adsorption on montmorillonite clay.

C. A. D. Mello, N. A. Debacher, A. J. Downs, 2009, Journal of colloid and interface science.

Molecular structure of Hf(BH4)4 investigated by quantum mechanical calculations and gas-phase electron diffraction.

H. Robertson, A. J. Downs, D. Rankin, 2004, Dalton transactions.

Matrix photooxidation of the metal carbonyls (M(CO)6 (M=Cr, W) by the isoelectronic molecules carbon dioxide and nitrous oxide

R. Perutz, A. J. Downs, M. Almond, 1985 .

The length, strength and polarity of metal–carbon bonds: dialkylzinc compounds studied by density functional theory calculations, gas electron diffraction and photoelectron spectroscopy

A. Haaland, Jennifer C. Green, A. J. Downs, 2003 .

Photooxidation of matrix-isolated iron pentacarbonyl. 1. Peroxo- and oxoiron carbonyl reaction intermediates

A. J. Downs, T. M. Greene, M. Almond, 1992 .

PHOTOOXIDATION OF MATRIX-ISOLATED NICKEL TETRACARBONYL IN THE PRESENCE OF DIOXYGEN

A. J. Downs, T. M. Greene, C. Gordon, 1995 .

Molecular Orbital Analysis of the Intermediates and Products Generated by the Photooxidation of Iron Pentacarbonyl

P. Lyne, D. Mingos, A. J. Downs, 1993 .

Formation of trans-M(O)2(CO)4 (M=Mo and W): intermediates in the photooxidation of matrix-isolated (M(CO)6

M. Poliakoff, A. J. Downs, M. Almond, 1984 .

Peroxo and dioxo metal carbonyl intermediates in the photooxidation of matrix-isolated M(CO)6 (M = Cr, Mo, W) in the presence of dioxygen: a vibrational spectroscopic study using oxygen-18

M. Poliakoff, A. J. Downs, M. Almond, 1986 .

Photooxidation of matrix-isolated iron pentacarbonyl. II: Binary iron oxide reaction products and the overall reaction mechanism

A. J. Downs, T. M. Greene, M. Almond, 1992 .

Structural and vibrational properties of ClC(O)SY compounds with Y = Cl and CH3

A. J. Downs, R. M. Romano, C. Védova, 2003 .

mer-Triiodotripyridineindium(III).

A. J. Downs, T. M. Greene, A. Cowley, 2005, Acta crystallographica. Section C, Crystal structure communications.

Compounds featuring a bond between a Group 13 (M) and a Group 15 element (N or P) and with the formulae HmMNHn and HmMPHn: structural aspects and bonding

Jennifer C. Green, A. J. Downs, T. M. Greene, 2001 .

Electronic structure of the sulfur nitrides. Ab initio calculations and photoelectron spectra

R. Egdell, A. J. Downs, R. Findlay, 1980 .

Spectroscopy of Matrix Isolated Molecules. 1. Principles, Procedures and Pitfalls

A. J. Downs, 1996 .

Stereochemistry of fluorophosphoranes—II The vibrational spectra and molecular structures of dimethyltrifluorophosphorane (CH3)2PF3 and trimethyldifluorophosphorane, (CH3)3PF2

A. J. Downs, R. Schmutzler, 1967 .

Structural studies and matrix photochemistry of tetramethyloxorhenium(VI), (CH3)4ReO, and related compounds

S. Teat, Jennifer C. Green, A. J. Downs, 2002 .

Removal of astrazon blue dye from aqueous media by a low-cost adsorbent from coal mining

A. J. Downs, N. Naidek, M. F. Viante, 2016 .

A MATRIX-ISOLATION STUDY OF GASEOUS INTERMEDIATES IN THE DIRECT FORMATION OF POLY(SULPHUR NITRIDE) FROM TETRASULPHUR TETRANITRIDE USING A SILVER SELENIDE CATALYST: EVIDENCE FOR THE INVOLVEMENT OF HNSO

A. J. Downs, M. Almond, Trevor L. Jeffery, 1988 .

Valence shell charge concentrations at pentacoordinate d0 transition-metal centers: non-VSEPR structures of Me2NbCl3 and Me3NbCl2.

H. Verne, A. Haaland, A. J. Downs, 2005, Chemistry.

Infrared spectroscopic evidence for photochemical generation of the metallocenes [(η-C5H5)2M](M = Mo or W) in low-temperature matrices

Malcolm L. H. Green, R. Perutz, A. J. Downs, 1979 .

The hydrides of aluminium, gallium, indium, and thallium: a re-evaluation

A. J. Downs, C. Pulham, 1994 .

Aspects of transition metal pentacoordination: investigation of the structure and bonding of Me3NbCl2, Me3TaCl2 and Me2NbCl3 by photoelectron spectroscopy and density functional theory calculations

Jennifer C. Green, A. J. Downs, G. Mcgrady, 2000 .

An electron-diffraction study of gaseous tetrasulphur tetranitride, S4N4

A. J. Downs, M. Almond, D. A. Rice, 1989 .

Spectroscopy of Matrix Isolated Molecules. 2. Applications: Pointing the way to Synthesis and Mechanisms in Inorganic and Organometallic Chemistry

A. J. Downs, 1996 .

The molecular structure of chloromethylphosphine, CClH2PH2, as determined by gas-phase electron diffraction and ab initio computations

H. Robertson, A. J. Downs, M. Hofmann, 1995 .

Formal Oxidation State +3: Organometallic Chemistry

S. Aldridge, A. J. Downs, D. Kays, 2011 .

The dixenon(1+) cation: formation in the condensed phases and characterization by ESR, UV-visible, and Raman spectroscopy

J. Norris, A. J. Downs, L. Stein, 1992 .

Molecular structures of gaseous trifluoro(methyl)sulfurane, CH3SF3, and trifluoro(trifluoromethyl)sulfurane, CF3SF3: experimental determination by electron diffraction and ab initio calculations

H. Robertson, J. E. Boggs, A. J. Downs, 1989 .

Fluorination of dimethyl sulphide. Formation of the fluorodimethylsulphonium cation, [Me2SF]+, and dimethylsulphur difluoride, Me2SF2

A. J. Downs, A. M. Forster, 1984 .

Hydrides of the main-group metals: new variations on an old theme.

S. Aldridge, A. J. Downs, Simon Aldridge, 2001, Chemical reviews.

FLUORINATION OF DIMETHYL SULFIDE. FORMATION OF THE FLUORODIMETHYLSULFONIUM CATION, (ME2SF)+, AND DIMETHYLSULFUR DIFLUORIDE, ME2SF2

A. J. Downs, A. M. Forster, 1985 .

Reactions of xenon difluoride: Oxidative fluorination of methyl derivatives of the p-block elements

A. J. Downs, A. M. Forster, 1985 .

Formation of the dixenon cation, Xe2+, in fluoroantimonate(V) media by oxidation–reduction methods: spectroscopic properties of the ion

J. Norris, A. J. Downs, L. Stein, 1978 .

The dixenon(l+) cation: the resolution of some outstanding problems

A. J. Downs, L. Stein, A. Minihan, 1991 .

Synthesis, physical characterisation and chemical properties of methylsulphur trifluoride, CH3SF3

A. J. Downs, G. Mcgrady, A. M. Forster, 1991 .

THE MOLECULAR STRUCTURE OF TRITHIAZYL TRIFLUORIDE IN THE GAS PHASE AS DETERMINED BY ELECTRON DIFFRACTION

H. Robertson, A. J. Downs, D. Rankin, 1990 .

Molecular Structures of Gaseous Trifluoromethylsulfurane, CH3SF3, and Trifluoro(trifluoromethyl)sulfurane, CF3SF3: Experimental Determination by Electron Diffraction and ab initio Calculations.

H. Robertson, J. E. Boggs, A. J. Downs, 1989 .

846. Thiocarbonyl fluoride

A. J. Downs, 1962 .

705. Silyl trifluoromethyl sulphide

A. J. Downs, E. Ebsworth, 1960 .

New Light on the Chemistry of the Group 13 Metals

A. J. Downs, Hans‐Jörg Himmel, 2011 .

Recent advances in the chemistry of the Group 13 metals: hydride derivatives and compounds involving multiply bonded Group 13 metal atoms

A. J. Downs, 1999 .

Chemistry of Aluminium, Gallium, Indium and Thallium

A. J. Downs, Anthony J. Downs, 2012 .

Amidoalane, amidogallane and amidoindane, H2MNH2 (M = Al, Ga or In): a matrix study of three prototypal molecules with the potential for M–N multiple bonding

A. J. Downs, T. M. Greene, Hans‐Jörg Himmel, 2000 .

Chemistry of the Group 13 metals: some themes and variations

A. J. Downs, 1993 .

Synthesis and X-ray crystal structure of a unique puckered six-membered metallacycle in Mo6O6Cl6(µ3-O)2(µ2-EtO)6(µ2-Cl)2

A. J. Downs, C. Limberg, S. Parsons, 1994 .

Modeling the Formation of Molybdenum Oxides from Alkoxides: Crystal Structures of [Mo4O4Cl4(μ2-OEt)4(HOEt)2(μ3-O)2] and [PPN]+[Et3NH]+[Cl2(O)Mo(μ2-O)2Mo(O)Cl2]2-

A. Blake, A. J. Downs, C. Limberg, 1996 .

Isolation and crystal structure of a dimeric oxomolybdenum(V) complex containing two ethoxy bridges and one ethanol bridge

A. J. Downs, C. Limberg, D. Watkin, 1994 .

IR and Raman characterization of the zincocenes (eta(5)-C5Me5)2Zn2 and (eta(5)-C5Me5)(eta(1)-C5Me5)Zn.

A. J. Downs, E. Carmona, C. Tang, 2008, The journal of physical chemistry. A.

Matrix Photochemistry of Methyltrioxorhenium(VII), CH3ReO3: Formation of the Methylidene Tautomer H2CRe(O)2OH and Its Potential Relevance to Olefin Metathesis

A. J. Downs, T. M. Greene, O. Gropen, 2001 .

Crystal Structures of Tris(tert-butyl)boron, -aluminum, -gallium, and -indium: Nonplanarity of the AlC3 Skeleton and Evidence of Inter- and Intramolecular “Agostic” or Hyperconjugative Interactions

A. J. Downs, A. Cowley, S. Parsons, 2005 .

Equilibration of ortho- and para-hydrogen by homogeneous hydrogenation catalysts in solution; A test for the reversibility of hydrogen addition using Raman spectroscopy

A. J. Downs, John M. Brown, A. M. Forster, 1983 .

Helical, Polymeric Chains in Crystalline Gallaborane [GaBH6]n at 110 K

A. J. Downs, C. Pulham, S. Parsons, 1997 .

Development of the chemistry of indium in formal oxidation States lower than +3.

A. J. Downs, J. A. Pardoe, 2007, Chemical reviews.

Hexameric Aggregates in Crystalline (Pentamethylcyclopentadienyl)gallium(I) at 200 K

A. J. Downs, H. Schnöckel, E. Baum, 1997 .

Hexamere Aggregate in kristallinem (Pentamethylcyclopentadienyl)gallium(I) bei 200 K

A. J. Downs, H. Schnöckel, E. Baum, 1997 .

The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities

S. Aldridge, A. J. Downs, 2011 .

On the Nature and Incidence of β-Agostic Interactions in Ethyl Derivatives of Early Transition Metals: Ethyltitanium Trichloride and Related Compounds

K. Ruud, O. Swang, A. Haaland, 1998 .

Thermal and Photolytic Reactions of Gallium and Indium Atoms (M) and Their Dimers M2 with Carbon Monoxide in Low-Temperature Matrices: Formation of Terminal, Bridged, and Ionic Carbonyl Derivatives †

A. J. Downs, T. M. Greene, Hans‐Jörg Himmel, 2000 .

Matrix Infrared Spectroscopic and ab Initio Studies of ZnH2, CdH2, and Related Metal Hydride Species

Pekka Pyykkö, W. A. Brown, Wendy A. Brown, 1995 .

Monochlorogallane: synthesis, properties, and structure of the dimer H2Ga(µ-Cl)2GaH2 in the gas phase as determined by electron diffraction

H. Robertson, A. J. Downs, C. Pulham, 1988 .

Stereochemistry of fluorophosphoranes—I The vibrational spectrum and molecular structure of methyltetrafluorophosphorane, CH3PF4

A. J. Downs, R. Schmutzler, 1965 .

The Hunting of the Gallium Hydrides

A. J. Downs, C. Pulham, 1994 .

Molecular Structures of EtTiCl3 and EtTiCl3(dmpe) (dmpe = Me2PCH2CH2PMe2): New Insights into β-Agostic Bonding

A. Haaland, A. J. Downs, W. Scherer, 1998 .

The digallane molecule, Ga2H6: experimental update giving an improved structure and estimate of the enthalpy change for the reaction Ga2H6(g) --> 2GaH3(g).

H. Robertson, A. J. Downs, C. Pulham, 2010, Dalton transactions.

Gas electron diffraction study of the vapour over dimethylamine-gallane leading to an improved structure for dimeric dimethylamidogallane, [Me2NGaH2]2: a cautionary tale.

Lorna J. Kettle, H. Robertson, A. J. Downs, 2006, Dalton transactions.

1,1,3,3-Tetramethylguanidine-gallane, (Me2N)2CN(H).GaH3: an unusually strongly bound gallane adduct.

A. J. Downs, Hans‐Jörg Himmel, A. Cowley, 2005, Dalton transactions.

Low valent and would-be multiply bonded derivatives of the Group 13 metals Al, Ga and In revealed through matrix isolation

L. Manceron, A. J. Downs, Hans‐Jörg Himmel, 2002 .

Oligomeric structures of the crystalline dimethylamine adducts Me2(H)N·MH3 (M = Al or Ga) and the dimethylamido derivative [Me2NGaH2]3

A. J. Downs, T. M. Greene, S. Parsons, 2001 .

Methylgallium and methylindium: the first sighting of the simplest organic derivatives of Ga(I) and In(I)

L. Andrews, A. J. Downs, T. M. Greene, 1999 .

Molecular structure of trimethylamine–gallane, Me3N·GaH3: ab initio calculations, gas-phase electron diffraction and single-crystal X-ray diffraction studies†

A. J. Downs, T. M. Greene, D. Rankin, 1998 .

UV Photoelectron Spectra of the μ-Hydrido Bridge-Bonded Molecules B2H6, GaBH6, and Ga2H6

J. Dyke, L. Andrews, A. J. Downs, 1996 .

Dimethylindium octahydrotriborate, Me2InB3H3: synthesis, crystal structure and spectroscopic properties of a volatile indium hydride

S. Aldridge, A. J. Downs, S. Parsons, 1996 .

Hydridogallium Bis(tetrahydroborate) in the Gas Phase: Vibrational Properties and Structure Determined by Electron Diffraction and ab Initio and Density Functional Theory Computations

H. Robertson, P. Schleyer, A. J. Downs, 1995 .

OBSERVED AND CALCULATED RAMAN SPECTRA OF THE GA2H6 AND GA2D6 MOLECULES

H. Schaefer, B. Ma, L. Andrews, 1994 .

The spectroscopic properties and X-ray crystal structure of a discrete molecular alane, dimethylamidoalane, [Me2NAlH2]3

A. J. Downs, C. Pulham, Jonathan C. Machell, 1992 .

Gallane: synthesis, physical and chemical properties, and structure of the gaseous molecule Ga2H6 as determined by electron diffraction

H. Robertson, A. J. Downs, C. Pulham, 1991 .

The molecular structures of the gaseous dimeric molecules Me2Ga(µ-H)2GaMe2 and Me2Ga(µ-Cl)2GaMe2 as determined by electron diffraction

H. Robertson, A. J. Downs, D. Rankin, 1990 .

Gallaborane, H2Ga(µ-H)2BH2: synthesis, properties, and structure of the gaseous molecule as determined by electron diffraction

H. Robertson, A. J. Downs, C. Pulham, 1990 .

The molecular structure of gaseous dimethylamidogallane: characterization of the dimer [Me2NGaH2]2 by electron diffraction and vibrational spectroscopy

H. Robertson, A. J. Downs, D. Rankin, 1985 .

The vibrational and nuclear magnetic resonance spectra of the isocyanate dimer (CF3SNCO)2

A. J. Downs, A. Haas, 1967 .

Methylzinc tetrahydroborate: physical and chemical properties and crystal structure at low temperature

A. J. Blake, A. Blake, S. Aldridge, 1996 .

Vibrational properties of the disulfur dinitride molecule, S2N2: IR and Raman spectra of the matrix-isolated molecule.

A. J. Downs, R. Evans, R. Köppe, 2011, The journal of physical chemistry. A.

The molecular structure of tetraboron tetrachloride in the gas phase, determined by electron diffraction

H. Robertson, A. J. Downs, D. Rankin, 1989 .

Molecular structures of two metal tetrakis(tetrahydroborates), Zr(BH4)(4) and U(BH4)(4): equilibrium conformations and barriers to internal rotation of the triply bridging BH4 groups.

O. Swang, A. Haaland, A. J. Downs, 2002, Inorganic chemistry.

The infra-red spectra of thiocarbonyl fluoride and thiocarbonyl chloride

A. J. Downs, 1963 .

Crystal structure of trans-[W(CO)4(η2-C2H4)2] and IR and 1H NMR studies of the reactions of this and related ethene carbonyl complexes of tungsten(0), [W(CO)n(η2-C2H4)6-n] (n=3–5)

A. J. Downs, T. Szymańska-Buzar, T. M. Greene, 1999 .

Molecular recognition in the solid state: topology of experimental and theoretical charge densities for tetrasulfur tetranitride

B. Reinhard, M. Tafipolsky, W. Hieringer, 2000 .

Vibrational properties and matrix photochemistry of trimethyldioxorhenium(VII), (CH3)3ReO2

Jennifer C. Green, A. J. Downs, T. M. Greene, 2002 .

Photoelectron spectra of metal tetrahydroborates

R. Egdell, A. J. Downs, A. F. Orchard, 1979 .

Preparation and properties of gallaborane, GaBH6: structure of the gaseous molecule H2Ga(μ-H)2BH2 as determined by vibrational, electron diffraction, and ab initio studies, and structure of the crystalline solid at 110 K as determined by x-ray diffraction``

C. Morrison, A. J. Downs, C. Pulham, 2001 .

The methylzinc hydroborate derivative [(MeZn)2B3H7]2: synthesis, crystal structure and vibrational spectra of an unprecedented cluster compound

A. J. Blake, A. Blake, S. Aldridge, 1995 .

Hydridoaluminium bis(tetrahydroborate): A new synthesis and some physical and chemical properties

A. J. Downs, L. Jones, 1994 .

624. The Raman spectra of bis(trifluoromethylthio)mercury and derived compounds

A. J. Downs, H. Emeléus, E. Ebsworth, 1961 .

Molecular aluminium trihydride, AlH3: generation in a solid noble gas matrix and characterisation by its infrared spectrum and Ab initio calculations

A. J. Downs, C. Pulham, F. Kurth, 1993 .

Matrix-isolation studies of alkyne complexes in the photochemical reactions of Mo(CO)6 with alkynes

A. J. Downs, T. Szymańska-Buzar, T. M. Greene, 1995 .

The vibrational spectra and structures of selenium tetrafluoride and tellurium tetrafluoride: including a matrix-isolation study

A. J. Downs, C. J. Adams, 1972 .

Some tetrahydroborate derivatives of aluminium: crystal structures ofdimethylaluminium tetrahydroborate and the α and β phases ofaluminium tris(tetrahydroborate) at low temperature

A. J. Blake, A. Blake, S. Aldridge, 1997 .

Formation and Characterization of the Indium Hydride Molecules H2InCl and HInCl2: Matrix Isolation and Quantum Chemical Studies

A. J. Downs, T. M. Greene, Hans‐Jörg Himmel, 2000 .

The Reaction of Zinc, Cadmium, and Mercury Atoms with Methane: Infrared Spectra of the Matrix-Isolated Methylmetal Hydrides

Lester Andrews, L. Andrews, A. J. Downs, 1995 .

Essays in structural chemistry

A. J. Downs, L. Staveley, D. A. Long, 1971 .

The molecular structure of trimethylamine–gallane in the gas phase as determined by electron diffraction

A. J. Downs, D. Rankin, P. Baxter, 1984 .

Molecular structure of trimethylphosphine–gallane, Me3P·GaH3: gas-phase electron diffraction, single-crystal X-ray diffraction, and quantum chemical studies

Lorna J. Kettle, H. Robertson, A. J. Downs, 2003 .

2-Galla-arachno-tetraborane(10), H2GaB3H8: synthesis, properties and structure of the gaseous molecule as determined by electron diffraction

H. Robertson, A. J. Downs, C. Pulham, 1992 .

Structures and aggregation of the methylamine-borane molecules, Me(n)H(3-n)N.BH(3) (n = 1-3), studied by X-ray diffraction, gas-phase electron diffraction, and quantum chemical calculations.

H. Robertson, S. Aldridge, A. J. Downs, 2009, Journal of the American Chemical Society.

Features of the coordination chemistry of B-metals—II: Bromoantimonates(V)[1]

A. J. Downs, C. J. Adams, 1972 .

Enhanced removal of p-nitrophenol from aqueous media by montmorillonite clay modified with a cationic surfactant.

A. J. Downs, C. Almeida, M. F. Viante, 2018, Journal of hazardous materials.

Methanesulfenyl fluoride, CH3SF, a missing link in the family of sulfenyl halides: formation and characterization through the matrix photochemistry of methyl thiofluoroformate, FC(O)SCH3.

A. J. Downs, R. M. Romano, C. D. Della Védova, 2007, Chemistry.

Matrix Reactivity of Zn, Cd, or Hg Atoms (M) in the Presence of Silane: Photogeneration and Characterization of the Insertion Product HMSiH3 in a Solid Argon Matrix

A. J. Downs, T. M. Greene, Victoria A. Macrae, 2004 .

Some novel binuclear group 13 metal tin hydrides formed in Ar matrices following the codeposition of the metal vapor with SnH4.

A. J. Downs, Hans‐Jörg Himmel, B. Gaertner, 2004, Chemistry.

Matrix studies of the thermal and photolytic reactions of Zn, Cd and Hg (M) atoms with H2O: formation and characterisation of the adduct M⋯OH2 and photoproduct HMOH

A. J. Downs, T. M. Greene, Victoria A. Macrae, 2004 .

Characterization by infrared and Raman spectroscopy of matrix-isolated M(CO)5N2 (M = chromium, molybdenum, or tungsten) produced by photolysis of M(CO)6

R. F. Turner, J. Burdett, A. J. Downs, 1978 .

Matrix studies of the thermal and photolytic reactions of Ga vapour species with H2O: formation and characterisation of the adducts Ga·OH2 and Ga2·OH2 and the photoproducts HGaOH, GaOH and Ga(μ-H)(μ-OH)Ga

A. J. Downs, Victoria A. Macrae, 2004 .

Molecular Structures of Methyldifluoroarsine, CH(3)AsF(2), and Dimethylfluoroarsine, (CH(3))(2)AsF, in the Gas Phase As Determined by Electron Diffraction and ab InitioCalculations.

H. Robertson, I. Alberts, A. J. Downs, 1996, Inorganic chemistry.

Infrared spectra, structures, and force constants of the matrix-isolated thiazyl halides CISN and BrSN

A. J. Downs, S. Peake, 1974 .

Matrix isolation

A. J. Downs, 1976, Nature.

Decomposition of monochlorogallane, [H2GaCl]n, and adducts with amine and phosphine bases: formation of cationic gallane derivatives.

A. J. Downs, T. M. Greene, S. Parsons, 2005, Inorganic chemistry.

Photo-induced tautomerisation of methyltrioxorhenium(vii): the intermediate in olefin metathesis?

A. J. Downs, T. M. Greene, O. Gropen, 2000 .

Matrix photochemistry of ethyltrioxorhenium(VII), C2H5ReO3: Tautomerisation via β-hydrogen migration with the sequential formation of two different ethene derivatives

A. J. Downs, T. M. Greene, L. J. Morris, 2012 .

Dimethylalane, [Me2AlH]n, in the Vapor Phase and in Hydrocarbon Solution: Gas-Phase Electron Diffraction, Spectroscopic, Colligative, and ab Initio Studies

C. Morrison, A. Barron, A. J. Downs, 2000 .

Infrared spectra of MeTiCl3 species, methyl group geometry and a force field

J. M. Dickinson, D. C. Mckean, A. J. Downs, 1991 .

Selenium, Tellurium and Polonium

A. J. Downs, 1966, Nature.

Production of binary oxides by photolysis of M(CO)6 molecules (M = Cr, Mo, or W) isolated in O2-doped argon matrices

A. J. Downs, M. Almond, 1988 .

Infra-red and Raman spectra of dimeric gallium trihalides

N. N. Greenwood, A. J. Downs, A. Balls, 1966 .

Features of the co-ordination chemistry of B-metals. Part I. Antimony(III) fluoride complexes

A. J. Downs, C. J. Adams, 1971 .

The Molecular Structure of Gaseous Titanium Tris(tetrahydridoborate) as Determined by Electron Diffraction

A. J. Downs, D. Rankin, C. Dain, 1982 .

The synthesis and crystal structure of [K(18-crown-6)]+[NCS·SO2]–(18-crown-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane)

A. J. Downs, A. Edwards, S. Parsons, 1994 .

Photochemistry of argon matrices containing nitric oxide and carbonyl sulfide. 1. The photolysis of the nitric oxide dimer, cis-N/sub 2/O/sub 2/

A. J. Downs, M. Hawkins, 1984 .

The chemistry of chlorine, Bromine, iodine and astatine

A. J. Downs, C. Adams, 1975 .

Photochemistry of an ozone molecular complex with iodine monochloride in cryogenic matrixes. The infrared spectra of iodosyl chloride (OICl) and iodyl chloride (O2ICl)

L. Andrews, A. J. Downs, M. Hawkins, 1984 .

The molecular structures of gaseous tetrakis(dimethylamino)-diboron, B2(NMe2)4, and tetrakis(methoxy)diboron, B2(OMe)4, as determined by electron diffraction

H. Robertson, A. J. Downs, D. Rankin, 1991 .

The molecular structure of tetraborane(10) in the gas phase as determined by a joint analysis of electron-diffraction and microwave data

A. J. Downs, D. Rankin, C. Dain, 1981 .

The Molecular Structures of Gaseous Tetrakis(dimethylamino)diboron, B2( NMe2)4, and Tetrakis(methoxy)diboron, B2(OMe)4, as Determined by Electron Diffraction.

H. Robertson, A. J. Downs, D. Rankin, 1991 .

Molecular structure of 1-(dichloroboryl)pentaborane(9), in the gas phase as determined by electron diffraction and supported by theoretical calculations

H. Robertson, I. Alberts, P. Schleyer, 1995 .

Matrix Photochemistry of the Chlorocarbonyl Sulfenyl Compounds ClC(O)SY, with Y = Cl or CH3

A. J. Downs, R. M. Romano, C. Védova, 2004 .

Matrix photochemistry of syn-(chlorocarbonyl)sulfenyl bromide, syn-ClC(O)SBr: precursor to the novel species anti-ClC(O)SBr, syn-BrC(O)SCl, and BrSCl.

A. J. Downs, T. M. Greene, R. M. Romano, 2001, Journal of the American Chemical Society.

Monochlorogallane: physical properties and structure of the gaseous molecule H2Ga(mu-Cl)2GaH2 as determined by vibrational, electron diffraction, and ab initio studies.

A. J. Downs, C. Pulham, T. M. Greene, 2000, Inorganic chemistry.

Photo-reversible isomerisation of trans- to cis-[W(CO)4(η2-alkene)2] complexes in low-temperature matrices

A. J. Downs, T. Szymańska-Buzar, T. M. Greene, 1997 .

Matrix-Isolated van der Waals Complexes Formed between CO and Dihalogen Molecules, XY with X, Y ) Cl, Br, or I

A. J. Downs, R. M. Romano, R. Romano, 2003 .

Experimental and theoretical characterization of molecular complexes formed between OCS and XY molecules (X, Y = F, Cl and Br) and their role in photochemical matrix reactions.

A. J. Downs, R. M. Romano, H. Willner, 2010, Physical chemistry chemical physics : PCCP.

New members of an old family: isolation of IC(O)Cl and IC(O)Br and evidence for the formation of weakly bound Br*...CO.

A. J. Downs, R. M. Romano, H. Willner, 2005, Inorganic chemistry.

Photochemistry of low-temperature matrixes containing carbonyl sulfide: reactions of sulfur atoms with the phosphorus trihalides phosphorus trifluoride (PF3) and phosphorus trichloride (PCl3) and the hydrocarbons methane, ethene, and ethyne

A. J. Downs, M. Almond, M. Hawkins, 1985 .

Formation of new halogenothiocarbonylsulfenyl halides, XC(S)SY, through photochemical matrix reactions starting from CS2 and a dihalogen molecule XY (XY=Cl2, Br2, or BrCl).

A. J. Downs, R. M. Romano, C. Védova, 2007, Inorganic chemistry.

Matrix-isolated van der Waals complexes formed between CS2 and dihalogen molecules XY, Where XY = Cl2, Br2, BrCl, ICl, or IBr.

A. J. Downs, R. M. Romano, A. Picone, 2006, The journal of physical chemistry. A.

Photochemical reaction channels of OCS with Cl2, ICl, or IBr isolated together in an argon matrix: isolation of syn-iodocarbonylsulfenyl bromide.

A. J. Downs, R. M. Romano, Y. Tobón, 2006, The journal of physical chemistry. A.

Formation and characterization of the gallium and indium subhydride molecules Ga2H2 and In2H2: a matrix isolation study.

Hans-Jörg Himmel, Pluton Pullumbi, L. Manceron, 2002, Journal of the American Chemical Society.

Transition metal derivatives of SiO: interaction of molecular SiO with silver atoms in an argon matrix

T. Mehner, A. J. Downs, M. Almond, 1988 .

The vibrational spectra of a heterocyclic azoborane

A. J. Downs, J. H. Morpis, 1966 .

Synthesis and structural characterisation of primary amine adducts of gallane, RH2N.GaH3, and of their decomposition products, [RHNGaH2]n(R = Me, n= 3; R =tBu, n= 2).

A. J. Downs, T. M. Greene, Hans‐Jörg Himmel, 2005, Dalton transactions.

The Photochemistry of [CpMo(CO)3(η1‐C3H5)] in Frozen Gas Matrices at 10 K and the Behaviour of [CpMo(CO)2(η3‐C3H5)] Isomers in Different Media

A. J. Downs, T. M. Greene, C. Limberg, 2001 .

Characterisation of monomeric methylsodium and methylpotassium: infrared spectra of the matrix-isolated molecules

A. J. Downs, Klaus Burczyk, Anthony J. Downs, 1990 .

Symmetrical distortion of the methyl group of methyltrichlorotitanium: gas phase structure and H,H coupling constant

Malcolm L. H. Green, J. M. Dickinson, H. Robertson, 1986 .

Polymorphism in the Crystal Structures of the Group 13 Trimethyls

C. Morrison, A. J. Downs, T. M. Greene, 2003 .

(Bromocarbonyl)sulfenyl bromide, BrC(O)SBr: a novel carbonyl sulfenyl compound formed by the photochemical reaction between Br2 and OCS isolated together in an Ar matrix

A. J. Downs, R. M. Romano, C. Védova, 2001 .

Structure and vibrational properties of ethyltrioxorhenium(VII), C2H5ReO3, investigated by gas electron diffraction, single crystal X-ray diffraction, IR spectroscopy and quantum chemical calculations

A. Haaland, A. J. Downs, T. M. Greene, 2002 .

Synthesis and crystal structure of an encapsulated fragment of MoO2 in the unique Mo8 oxo-cluster compound [Mo8O8Cl6(µ3-O)4(OH)2(µ-OH)4(µ-OEt)4(HOEt)4] and its relevance to the sol–gel synthesis of molybdenum oxides

A. J. Blake, A. J. Downs, C. Limberg, 1995 .

FORMATION OF TRANS-M(O)2(CO)4 (M = MO AND W): INTERMEDIATES IN THE PHOTOOXIDATION OF MATRIX-ISOLATED M(CO)6

M. Poliakoff, A. J. Downs, M. Almond, 1985 .

Formation and Characterization of the Cationic Gallane Derivatives [(RH2N)2GaH2]Cl (R = Me or iPr) and [{(iPrH2N)GaH2NHiPr}2GaH2]Cl

A. J. Downs, A. Cowley, S. Parsons, 2008 .

Trichloromethyl chloroformate ("diphosgene"), ClCOOCCl3: structure and conformational properties in the gaseous and condensed phases.

A. J. Downs, S. Parsons, C. O. Della Védova, 2006, The Journal of organic chemistry.

STRUCTURE OF TETRAMETHYLTELLURIUM(IV) DETERMINED EXPERIMENTALLY IN THE SOLID AND GAS PHASES AND BY AB INITIO CALCULATIONS

Alexander J. Blake, Bruce A. Smart, A. Blake, 1994 .

The vibrational spectra of natural and perdeuterated monochlorogallane, H2Ga(μ-Cl)2GaH2, and an empirical harmonic potential function

A. J. Downs, C. Pulham, M. J. Goode, 1995 .

ChemInform Abstract: Hydrides of the Main-Group Metals: New Variations on an Old Theme

S. Aldridge, A. J. Downs, 2002 .

Vibrational properties of ethyltitanium trichloride and its 1,2-bis(dimethylphosphino)ethane adduct: characterisation of isolated ν(C–H) modes and implications for agostic bonding

D. C. Mckean, A. Haaland, A. J. Downs, 1997 .

Gallane at last! Synthesis and properties of binary gallium hydride

A. J. Downs, C. Pulham, M. J. Goode, 1989 .