C. Hoff

发表

Reactions of the complexes M(Pr3)2(CO)3 (M = Cr, Mo, W; R =iPr, Cy) with thiols, hydrogen sulfide, disulfides, hydrogen iodide and iodine. The role of heteroatoms in determining the metal hydrogen bond strength at a sterically crowded metal center

G. Kubas, R. F. Lang, Telvin D. Ju, 1997 .

The thermodynamic driving force for CH activation at iridium

S. Nolan, C. Hoff, R. Bergman, 1988 .

Enthalpies of ligand substitution for [Mo(η5C5H5)(CO)2(NO)] – The role of π-bonding effects in metal–ligand bond strengths

S. Nolan, C. Hoff, Subhojit Majumdar, 2014 .

Organometallic Radicals: Thermodynamics, Kinetics, and Reaction Mechanisms

C. Hoff, T. Kégl, George C. Fortman, 2010 .

Heat of reaction of (norbornadiene)molybdenum tetracarbonyl with monodentate and bidentate ligands : solution thermochemical study of ligand substitution in the complexes cis-L2Mo(CO)4

S. Nolan, C. Hoff, Shakti L. Mukerjee, 1988 .

Steric and electronic properties of N-heterocyclic carbenes (NHC): a detailed study on their interaction with Ni(CO)4.

L. Cavallo, S. Nolan, E. Stevens, 2005, Journal of the American Chemical Society.

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System

L. Cavallo, S. Nolan, E. Stevens, 2008 .

Molecular Hydrogen Complexes of Mo and W

G. Kubas, C. Hoff, 2007 .

Dinuclear Gold(I) Complexes Bearing Alkyl-Bridged Bis(N-heterocyclic carbene) Ligands as Catalysts for Carboxylative Cyclization of Propargylamine: Synthesis, Structure, and Kinetic and Mechanistic Comparison to the Mononuclear Complex [Au(IPr)Cl]

S. Nolan, K. V. Hecke, C. Hoff, 2020 .

Coordination-mode control of bound nitrile radical complex reactivity: intercepting end-on nitrile-Mo(III) radicals at low temperature.

C. Hoff, C. Cummins, Rajeev Prabhakar, 2009, Journal of the American Chemical Society.

Role of axial base coordination in isonitrile binding and chalcogen atom transfer to vanadium(III) complexes.

C. Hoff, C. Cummins, Julia M. Stauber, 2014, Inorganic chemistry.

Thermodynamic and kinetic study of cleavage of the N-O bond of N-oxides by a vanadium(III) complex: enhanced oxygen atom transfer reaction rates for adducts of nitrous oxide and mesityl nitrile oxide.

A. Cozzolino, C. Hoff, C. Cummins, 2013, Journal of the American Chemical Society.

Why does D2 bind better than H2? A theoretical and experimental study of the equilibrium isotope effect on H2 binding in a M(η2-H2) complex. Normal coordinate analysis of W(CO)3(PCy3)2(η2-H2)

L. H. Jones, B. Swanson, J. Eckert, 1997 .

Heats of reaction of Cp*(PMe3)Ir(R)(H) (R = C6H5, C6H11, and H) with HCl, CCl4, CBr4, and CH3I : a solution thermochemical study of the C-H insertion reaction

S. Nolan, C. Hoff, J. M. Buchanan, 1987 .

The mechanism of carboxylative cyclization of propargylamine by N-heterocyclic carbene complexes of Au(I)

S. Nolan, C. Hoff, B. Captain, 2020 .

Synthesis, structure, and thermochemistry of adduct formation between N-heterocyclic carbenes and isocyanates or mesitylnitrile oxide

C. Hoff, Subhojit Majumdar, B. Captain, 2013, Structural Chemistry.

Rhodium alkoxide complexes : formation of an unusually strong intermolecular hydrogen bond in (PMe3)3Rh-Otol(HOtol)

S. Nolan, C. Hoff, R. Bergman, 1987 .

Structural and solution calorimetric studies of sulfur binding to nucleophilic carbenes.

S. Nolan, E. Stevens, C. Hoff, 2000, Inorganic chemistry.

Synthesis of [Pt(SnBu(t)3)(IBu(t))(μ-H)]2, a Coordinatively Unsaturated Dinuclear Compound which Fragments upon Addition of Small Molecules to Form Mononuclear Pt-Sn Complexes.

Lei Zhu, C. Hoff, Anjaneyulu Koppaka, 2016, Inorganic chemistry.

2-Pyridinethiol/2-pyridinethione tautomeric equilibrium. A comparative experimental and computational study.

Henry F Schaefer, H. Schaefer, P. Schleyer, 2002, The Journal of organic chemistry.

Thermodynamics of Ligand Binding and Exchange in Organometallic Reactions

C. Hoff, 2007 .

Functionalization reactions characteristic of a robust bicyclic diphosphane framework.

C. Hoff, C. Cummins, Daniel Tofan, 2013, Inorganic chemistry.

Stable, three-coordinate Ni(CO)(2)(NHC) (NHC = N-heterocyclic carbene) complexes enabling the determination of Ni-NHC bond energies.

S. Nolan, E. Stevens, C. Hoff, 2003, Journal of the American Chemical Society.

Dinuclear Organometallic Cluster Complexes

G. Kiss, C. Hoff, J. Mcdonough, 2006 .

N-heterocyclic carbene complexes of palladium in oxygen atom transfer reactions involving the making and breaking of N-O bonds

S. Nolan, C. Hoff, Subhojit Majumdar, 2017 .

Thermodynamic, kinetic, and mechanistic study of oxygen atom transfer from mesityl nitrile oxide to phosphines and to a terminal metal phosphido complex.

C. Hoff, C. Cummins, Subhojit Majumdar, 2011, Inorganic chemistry.

1,2-BIS(DIPHENYLPHOSPHINO)-1-PHENYLETHANE: A CHIRAL DITERTIARY PHOSPHINE DERIVED FROM MANDELIC ACID USED AS A LIGAND IN ASYMMETRIC HOMOGENEOUS HYDROGENATION CATALYSTS

J. Bakos, R. King, C. Hoff, 1979 .

Poly(tertiary phosphines and arsines). 17. Poly(tertiary phosphines) containing terminal neomenthyl groups as ligands in asymmetric homogeneous hydrogenation catalysts

J. Bakos, R. King, C. Hoff, 1979 .

1, 2-Bis(diphenylphosphino)-1-phenylethane: A Chiral Ditertiary Phosphine Derived from Mandelic Acid Used as a Ligand in Asymmetric Homogeneous Hydrogenation Catalysts

J. Bakos, R. King, C. Hoff, 1979 .

Heats of reaction of HMo(CO)3(C5R5) (R = H, CH3) with diphenyldisulfide and of formation of the clusters [PhSMo(CO)x(C5H5)]2, x = 1,2. Thermodynamic study of molybdenum-sulfur bond strengths

S. Nolan, R. F. Lang, Telvin D. Ju, 1995 .

Spectroscopic detection and theoretical confirmation of the role of Cr2(CO)5(C5R5)2 and .Cr(CO)2(ketene)(C5R5) as intermediates in carbonylation of N=N=CHSiMe3 to O=C=CHSiMe3 by .Cr(CO)3(C5R5) (R = H, CH3).

H. Schaefer, R. King, Qian-Shu Li, 2007, Journal of the American Chemical Society.

An investigation of the homolytic dissociation of [.eta.5-C5Me5Cr(CO)3]2 and related complexes. The role of ligand substitution on the solution thermochemistry of metal-metal bond cleavage

S. Fortier, G. Kiss, C. Hoff, 1992 .

Solution calorimetric and stopped-flow kinetic study of ligand substitution for the complexes M(CO)3(PCy3)2(L) (M = Cr, Mo, W). Comparison of first-, second-, and third-row transition-metal-ligand bonds at a sterically crowded metal center

G. Kubas, C. Hoff, Shakti L. Mukerjee, 1991 .

Solution calorimetric, equilibrium, and synthetic studies of oxidative addition/reductive elimination of C5R5H (R = H, Me, indenyl) to/from the complexes M(CO)3(RCN)3/(η5-C5R5)M(CO)3H (M = Cr, Mo, W)

G. Kubas, G. Kiss, C. Hoff, 1991 .

Thermodynamic and Kinetic Studies of Binding Nitrogen and Hydrogen to Complexes of Chromium, Molybdenum, and Tungsten

G. K. Khalsa, G. Kubas, C. Hoff, 1990 .

Entropy of binding molecular hydrogen and nitrogen in the complexes (P(C6H11)3)2M(CO)3 (M=Cr, Mo, W)

C. Hoff, Alberto A. Gonzalez, 1989 .

Rate of reaction of (P(C6H11)3)2W(CO)3 with py, P(OMe)3, PPh2Me, and 2,6-Me2py. Stopped-flow kinetic study of concerted reactions at a sterically crowded metal center

C. Hoff, Kai Zhang, Alberto A. Gonzalez, 1989 .

Stopped-flow kinetic study of the reaction of (P(C6H11)3)2W(CO)3(L) (L = H2, D2, and N2) with pyridine. Kinetic resolution of reaction of dihydride versus molecular hydrogen complexes

C. Hoff, Kai Zhang, Alberto A. Gonzalez, 1989 .

Thermodynamic and kinetic studies of the complexes W(CO)3(PCy3)2(L) (L=H2, N2, NCCH3, pyridine, P(OMe)3, CO)

S. Nolan, G. Kubas, C. Hoff, 1988 .

Synthesis of (PCy3)2Cr(CO)3 and its reactions with hydrogen, nitrogen, and other ligands

C. Hoff, Shakti L. Mukerjee, Zhang. Kai, 1988 .

The heat of reaction of EtMo(CO)3C5H5 and HMo(CO)3C5H5 and related reactions. Thermochemical study of reductive elimination in alkyl molybdenum complexes

S. Nolan, C. Hoff, Shakti L. Mukerjee, 1988 .

Heats of reaction of (toluene)Mo(CO)3 with substituted arenes, sodium cyclopentadiene, nitriles, isocyanides, and other ligands : solution thermodynamic study of ligand exchange in the complexes fac-L3Mo(CO)3

S. Nolan, C. Hoff, R. L. D. L. Vega, 1986 .

Thermochemical study of the Lewis acid promoted carbonyl insertion reaction.

S. Nolan, C. Hoff, R. López de la Vega, 1986, Journal of the American Chemical Society.

Heats of reaction of RMo(CO)3C5H5 (R = H, Me, Et) with phosphines and phosphites : thermodynamic study of the carbonyl-insertion reaction

S. Nolan, C. Hoff, Shakti L. Mukerjee, 1986 .

The heats of reaction of phosphines and phosphites with toluene-molybdenum tricarbonyl. Importance of both steric and electronic factors in determining the MoPR3 bond strength

S. Nolan, C. Hoff, 1985 .

Synthesis and thermochemistry of HMo(CO)3C5Me5; Comparison of cyclopentadienyl and pentamethylcyclopentadienyl ligands

J. Landrum, S. Nolan, C. Hoff, 1985 .

Thermochemistry of molybdenum tricarbonyl complexes of arenes and cyclic polyolefins

C. Hoff, 1985 .

The heats of iodination of chromium tricarbonyl complexes of arenes and cycloheptatriene

C. Hoff, 1983 .

Infrared spectra of isotopically substituted XCo(CO)4 (X=H, EtC(O), EtOC(O) and EtOC(O)CH2) molecules

R. Tannenbaum, C. Hoff, G. Pályi, 2003 .

Heats of Reaction of (Mo(CO)2Cp*)2 (Cp*: C5H5, C5(CH3)5, C9H7) with CO, HCCH, and C6H5CCH. Thermochemical Investigation of the Molybdenum-Molybdenum Triple Bond.

S. Nolan, C. Hoff, R. L. D. L. Vega, 1987 .

Photochemical reaction between cyclohexyl isocyanide and π-cyclopentadienyldicarbonyltrimethylsilyliron(II)

J. Connolly, C. Hoff, T. Chan, 1978 .

Thermodynamic, Kinetic, Structural, and Computational Studies of the Ph3Sn-H, Ph3Sn-SnPh3, and Ph3Sn-Cr(CO)3C5Me5 Bond Dissociation Enthalpies.

C. Hoff, Anjaneyulu Koppaka, Subhojit Majumdar, 2016, Inorganic chemistry.

Organic Compounds of Divalent Tin and Lead

J. Connolly, C. Hoff, 1981 .

On the origin of selective nitrous oxide N-N bond cleavage by three-coordinate molybdenum(III) complexes.

S. Nolan, C. Hoff, C. Cummins, 2001, Journal of the American Chemical Society.

Experimental and computational studies of binding of dinitrogen, nitriles, azides, diazoalkanes, pyridine, and pyrazines to M(PR(3))(2)(CO)(3) (M = Mo, W; R = Me, (i)Pr).

E. Fujita, J. Muckerman, C. Hoff, 2009, Inorganic chemistry.

Thermodynamic and kinetic studies of H atom transfer from HMo(CO)3(eta(5)-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: direct insertion of benzonitrile into the Mo-H bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C=N)Mo(N[t-Bu]Ar)3.

C. Hoff, C. Cummins, George C. Fortman, 2008, Inorganic chemistry.

Molybdenum chalcogenobenzimidato complexes: radical synthesis and nitrile extrusion via beta-EPh (E = S, Se, and Te) elimination.

C. Hoff, C. Cummins, E. Rybak-Akimova, 2003, Inorganic chemistry.

Direct solution calorimetric measurements of enthalpies of proton and electron transfer reactions for transition metal complexes : thermochemical study of metal-hydride and metal-metal bond energies

S. Nolan, G. Kiss, C. Hoff, 1994 .

Synthesis and Structure of W(CO)(phen)(SPh)2(.eta.2-SO2): A Tungsten(II) Sulfur Dioxide Complex That Spontaneously Extrudes Sulfur To Form the Tungsten(VI) Dioxo Complex W(phen)(SPh)2(O)2

G. Kubas, R. F. Lang, Telvin D. Ju, 1994 .

Synthesis and structure of W(eta(2)-mp)(2)(CO)(3) (mp = monoanion of 2-mercaptopyridine) and its reactions with 2,2'-pyridine disulfide and/or NO to yield W(eta(2)-mp)(4), W(eta(2)-mp)(2)(NO)(2), and W(eta(2)-mp)(3)(NO).

K. Abboud, C. Hoff, K. B. Capps, 2001, Inorganic Chemistry.

Crystallographic and spectroscopic assessment of chelate-stabilized aryl halide complexes at a seven-coordinate d4 molybdenum centre

R. F. Lang, Telvin D. Ju, G. Kiss, 1992 .

Heats of the reactions of tricarbonyl(naphthalene)chromium, tricarbonyl(cycloheptatriene)chromium, tricarbonyl(cycloheptatriene)tungsten, and tricarbonyltris(ethylcyanide)tungsten with pyridine, phosphines, phosphites, and other ligands : comparative thermochemical study of L3M(CO)3 complexes (M = C

S. Nolan, R. F. Lang, Telvin D. Ju, 1992 .

High quantum yield molecular bromine photoelimination from mononuclear platinum(IV) complexes.

A. R. Karikachery, C. Hoff, P. Sharp, 2013, Inorganic chemistry.

The rate and mechanism of oxidative addition of H2 to the Cr(CO)3C5Me5 radical—generation of a model for reaction of H2 with the Co(CO)4 radical

G. Kiss, C. Hoff, K. B. Capps, 1999 .

The heats of hydrogenation of the metal—metal bonded complexes [M(CO)3C5H5]2 (M = Cr, Mo, W)

J. Landrum, C. Hoff, 1985 .

Ground-State versus transition-state effects in arene displacement reactions of the complexes (η6-arene)Cr(CO)3 : linear dependence of transition-state energies and resonance energies of the arene ligands

R. F. Lang, Telvin D. Ju, G. Kiss, 1994 .

Two-step binding of O2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex.

A. Cozzolino, C. Hoff, C. Cummins, 2012, Journal of the American Chemical Society.

Thermodynamic and kinetic studies of stable low valent transition metal radical complexes

C. Hoff, 2000 .

Oxidative Addition of Disulfides to the Complex W(CO)3(phen)(EtCN). Synthesis, Structure, and Reactivity of W(CO)2(phen)(SR)2 (R = Ph, Me, CH2Ph, tBu; phen = 1,10-Phenanthroline) Coordinatively Unsaturated Complexes of Tungsten(II) that Reversibly Bind CO and Other Ligands

G. Kubas, R. F. Lang, Telvin D. Ju, 1994 .

Reactions of •Sn(Si(tBu)2Me)3 with HM(CO)3C5R5 (M = Cr or Mo, R = H or CH3) and Hg. Ionic, Covalent, and μ-CO Bonding Patterns between Transition Metals and Tin.

C. Hoff, Anjaneyulu Koppaka, Subhojit Majumdar, 2018 .

Pentamethylcyclopentadienylmolybdenumtricarbonyl hydride, pentamethylcyclopentadienylmolybdenumtricarbonyl dimer, cycloheptatriene molybdenumtricarbonyl, tris(pyridine)-molybdenumtricarbonyl and related L3Mo(CO)3 complexes

S. Nolan, C. Hoff, 1988 .

Heats of reaction of HMo(CO)3C5H5 with CCl4 and CBr4 and of NaMo(CO)3C5H5 with I2 and CH3. Solution thermochemical study of the MoX bond for X = H, Cl, Br, I and CH3

S. Nolan, C. Hoff, R. L. D. L. Vega, 1986 .

The Enthalpy of Insertion of Sulfur into the Metal-Hydrogen Bond. Synthetic, Structural, and Calorimetric Study of the Complexes HS-M(CO)(3)C(5)R(5) [M = Cr, Mo, W; R = H, Me].

K. Abboud, C. Hoff, K. B. Capps, 1999, Inorganic chemistry.

KINETICS OF THE REACTIONS OF (ETHOXYCARBONYL)METHYLCOBALT TETRACARBONYL WITH **1**3CO, Ph//3P, HCo(CO)//4, AND H//2. A COMPARISON OF THE REACTIVITIES OF RCo(CO)//4 (R equals CH//2COOEt, COOEt, AND H) COMPLEXES.

R. King, C. Hoff, L. Markó, 1985 .

Thermodynamic and Kinetic Study of Oxidative Addition/Reductive Elimination of H2 and D2 to FulvaleneCr2(CO)6: Evidence for Relatively Strong Metal−Metal Bonds in Fulvalenedimetals

A. Matzger, K. Vollhardt, C. Hoff, 1999 .

Thermochemistry of Sulfur Atom Transfer. Enthalpies of Reaction of Phosphines with Sulfur, Selenium, and Tellurium, and of Desulfurization of Triphenylarsenic Sulfide, Triphenylantimony Sulfide, and Benzyl Trisulfide

C. Hoff, K. B. Capps, A. Bauer, 1998 .

Dihydrogen : a better ligand than water ? IR and X-ray evidence for aquo coordination in W(CO)3(PR3)2(H2O), thermodynamics of H2O versus η2-H2 binding, and H2O/D2 isotopic exchange. Implications on the biological activation of hydrogen

G. K. Khalsa, Gabor Kiss, G. Kiss, 1992 .

Thermodynamic, kinetic, and computational study of heavier chalcogen (S, Se, and Te) terminal multiple bonds to molybdenum, carbon, and phosphorus.

S. Nolan, C. Hoff, C. Cummins, 2008, Inorganic chemistry.

Oxidative Addition of Thiols, Disulfides, Iodine, and Hydrogen Iodide to W(CO)3(PiPr3)2. Preparation of Stable 17-Electron Tungsten Thiolate Radicals from Complexes with Weak W-H Bonds

G. Kubas, R. F. Lang, Telvin D. Ju, 1994 .

Reductive functionalization of a rhodium(III)-methyl bond by electronic modification of the supporting ligand.

J. Groves, T. Cundari, C. Hoff, 2014, Dalton transactions.

Stoichiometric and Catalytic Conversion of 1-Adamantyl Azide to 1-Adamantyl Isocyanate by [Cr(CO)3Cp]2 and Reaction with Mo(CO)3(PiPr3)2 To Form Mo(κ2-iPr3P═NN═NAd)(CO)3(PiPr3)

C. Hoff, B. Captain, George C. Fortman, 2009 .

Synthesis and reactions of the transition metal substituted tin hydride HSn[Mo(CO)3C5H5]3

J. Connolly, C. Hoff, 1978 .

Thermal intersystem crossing in solids. Cophen2(NCBR3)2, R = H and phenyl

K. Purcell, T. Vrtiska, C. Hoff, 1983 .

Production of cis-Na2N2O2 and NaNO3 by Ball Milling Na2O and N2O in Alkali Metal Halide Salts

C. Hoff, B. Captain, Jack V. Davis, 2021, ACS omega.

First- and second-order mechanisms for oxidative addition for bound methyl disulfide in the complex W(CO)3(phen)(MeSSMe)

R. F. Lang, Telvin D. Ju, C. Hoff, 1998 .

Oxidative addition of thiols, and thiol/thiolate exchange reactions of low valent molybdenum and tungsten complexes. Synthetic, structural and calorimetric study of trigonal prismatic W(CO)2(1,10-phenanthroline)(3,4-toluenedithiolate)

G. Kubas, R. F. Lang, Telvin D. Ju, 2003 .

Reaction of Phenyl and Methyl Disulfide with ·Cr(CO)3C5Me5 and HCr(CO)3C5Me5. Metal Radical and Metal Hydride Reactivity at the Sulfur−Sulfur Bond. Different Mechanisms for Oxidative Addition of Alkyl and Aryl Disulfides

R. F. Lang, Telvin D. Ju, C. Hoff, 1997 .

Oxidative Addition of Butanethiol and Thiophenol to the •Cr(CO)3C5Me5 Radical. Kinetic and Thermodynamic Study of a Third-Order Reaction and Its Catalysis

R. F. Lang, Telvin D. Ju, C. Hoff, 1996 .

Benzonitrile extrusion from molybdenum(IV) ketimide complexes obtained via radical C-E (E = O, S, Se) bond formation: toward a new nitrogen atom transfer reaction.

C. Hoff, C. Cummins, E. Rybak-Akimova, 2006, Journal of the American Chemical Society.

Kinetics by high-pressure nuclear magnetic resonance: Reversible hydrogen binding in (η2-H2)Cr(CO)3[P(C6H 11)3]2

I. Horváth, R. Crabtree, C. Hoff, 1990 .

Organometallic chemistry of the transition metals: XXXIII. Some new reactions of cyclopentadienyltetracarbonylniobium

R. King, C. Hoff, 1982 .

Heats of Reaction of Cp*(PMe3)Ir(R)(H) (R: C6H5, C6H11, and H) with HCl, CCl4, CBr4, and CH3I. A Solution Thermochemical Study of the C-H Insertion Reaction.

S. Nolan, C. Hoff, J. M. Buchanan, 1987 .

Small-Molecule Activation by Molybdaziridine Hydride Complexes: Mechanistic Sequence of the Small-Molecule Binding and Molybdaziridine Ring-Opening Steps

Joshua S. Figueroa, C. Hoff, C. Cummins, 2004 .

Solution calorimetric and stopped-flow kinetic studies of the reaction of *Cr(CO)3C5Me5 with PhSe-SePh and PhTe-TePh. Experimental and theoretical estimates of the Se-Se, Te-Te, H-Se, and H-Te bond strengths.

C. Hoff, C. Cummins, E. Rybak-Akimova, 2005, Inorganic chemistry.

Mechanistic Pathways for N2O Elimination from trans-R3Sn-O-N═N-O-SnR3 and for Reversible Binding of CO2 to R3Sn-O-SnR3 (R = Ph, Cy).

C. Hoff, B. Captain, M. Temprado, 2021, Inorganic chemistry.

Oxygen binding to [Pd(L)(L')] (L= NHC, L' = NHC or PR3, NHC = N-heterocyclic carbene). synthesis and structure of a paramagnetic trans-[Pd(NHC)2(η(1)-O2)2] complex.

A. Slawin, S. Nolan, C. Hoff, 2011, Journal of the American Chemical Society.

Kinetic, thermodynamic, and mechanistic aspects of oxidative addition reactions of RE-ER (E = S, Se, Te) and transition metal complexes

C. Hoff, T. Kégl, George C. Fortman, 2008 .