I. Sims

发表

Femtosecond real-time probing of reactions. VIII. The bimolecular reaction Br+I2

A. Zewail, M. Gruebele, I. Sims, 1992 .

Ultra‐low temperature kinetics of neutral–neutral reactions: The reaction CN+O2 down to 26 K

I. Smith, B. Rowe, I. Sims, 1992 .

A KINETIC DATABASE FOR ASTROCHEMISTRY (KIDA)

J. Troe, E. Herbst, A. Dalgarno, 2012, 1201.5887.

Benzonitrile as a Proxy for Benzene in the Cold ISM: Low-temperature Rate Coefficients for CN + C6H6

I. Sims, Ilsa R. Cooke, D. Gupta, 2020, The Astrophysical Journal.

A novel Ka-band chirped-pulse spectrometer used in the determination of pressure broadening coefficients of astrochemical molecules.

I. Sims, Brian M Hays, T. Hearne, 2020, The Journal of chemical physics.

Design and performance of an E-band chirped pulse spectrometer for kinetics applications: OCS – He pressure broadening

I. Sims, Brian M Hays, S. Picard, 2020, Journal of Quantitative Spectroscopy and Radiative Transfer.

A chirped-pulse Fourier-transform microwave/pulsed uniform flow spectrometer. I. The low-temperature flow system.

Kirill Prozument, G. B. Park, R. Field, 2014, The Journal of chemical physics.

Kinetics over a wide range of temperature (13–744 K): Rate constants for the reactions of CH(ν=0) with H2 and D2 and for the removal of CH(ν=1) by H2 and D2

Ian W. M. Smith, B. Rowe, A. Symonds, 1997 .

Pressure and temperature dependence of the rate constants for the association reaction of OH radicals with NO between 301 and 23 K

Ian W. M. Smith, B. Rowe, I. Sims, 1994 .

Supporting Online Material Material and Methods Supplemental Figures S1 – S9 Movies S1 – S7 Supplemental References

Ian W. M. Smith, A. Canosa, I. Sims, 2022 .

Rate coefficients for the reaction and relaxation of H2O in specific vibrational states with H atoms and H2O

Ian W. M. Smith, I. Sims, P. Barnes, 1999 .

An experimental study of the intersystem crossing and reactions of C2(X1Sigmag+) and C2(a3Pi(u)) with O2 and NO at very low temperature (24-300 K).

A. Canosa, I. Sims, S. L. Le Picard, 2006, The journal of physical chemistry. A.

Low temperature (39–298 K) kinetics study of the reactions of the C4H radical with various hydrocarbons observed in Titan's atmosphere

A. Canosa, I. Sims, Y. Bénilan, 2008 .

Low temperature rate coefficients for reactions of the butadiynyl radical, C4H, with various hydrocarbons. Part II: reactions with alkenes (ethylene, propene, 1-butene), dienes (allene, 1,3-butadiene) and alkynes (acetylene, propyne and 1-butyne).

N. Balucani, A. Canosa, I. Sims, 2010, Physical chemistry chemical physics : PCCP.

Effects of short‐term oxygen depletion on fish

J. Seager, I. Sims, I. Milne, 2000 .

Rate constants for the reactions CN(ν=0), CN(ν=1)+H2, D2→HCN, DCN+H, D between 295 and 768 K, and comparisons with transition state theory calculations

I. Smith, I. Sims, 1988 .

Experimental Studies of Gas-Phase Reactivity in Relation to Complex Organic Molecules in Star-Forming Regions

I. Sims, Ilsa R. Cooke, I. Cooke, 2019, ACS Earth and Space Chemistry.

Seeds Of Life In Space (SOLIS): The Organic Composition Diversity at 300–1000 au Scale in Solar-type Star-forming Regions

J. Pineda, R. Neri, L. Testi, 2017, 1710.10437.

Insights into the Role of Polycyclic Aromatic Hydrocarbon Condensation in Haze Formation in Jupiter's Atmosphere

S. Klippenstein, H. Sabbah, B. Rowe, 2011 .

Pressure and temperature dependence of the rate of reaction between CN radicals and NO over the range 99 ⩽T/K ⩽ 450

Ian W. M. Smith, I. Sims, 1993 .

Rate coefficients for the reactions of C2(a(3)Pi(u)) and C2(X(1)Sigma(g)(+)) with various hydrocarbons (CH4, C2H2, C2H4, C2H6, and C3H8): a gas-phase experimental study over the temperature range 24-300 K.

A. Canosa, I. Sims, S. L. Le Picard, 2008, The journal of physical chemistry. A.

Rate coefficients for the reactions of C($\mathsf{^3}$P$\mathsf{{\it _J}}$) atoms with C2H2, C2H4, CH3C$ \mathsf{\equiv} $CH and H2C$ \mathsf{=} $C$ \mathsf{=} $CH2 at temperatures down to 15 K

Ian W. M. Smith, I. Sims, S. Picard, 2001 .

Reactions of the methylidine radical with CH4, C2H2, C2H4, C2H6, and but-1-ene studied between 23 and 295 K with a CRESU apparatus

Ian W. M. Smith, B. Rowe, A. Canosa, 1997 .

Pulsed laser photolysis–laser-induced fluorescence measurements on the kinetics of CN(v= 0) and CN(v= 1) with O2, NH3 and NO between 294 and 761 K

Ian W. M. Smith, I. Sims, 1988 .

Insights into the Condensation of PAHs in the Envelope of IRC +10216

S. Klippenstein, H. Sabbah, B. Rowe, 2020, PAHs and the Universe.

The branching ratio between reaction and relaxation in the removal of H2O from its |04〉− vibrational state in collisions with H atoms

Ian W. M. Smith, G. Lendvay, G. Schatz, 2001 .

Seeds of Life in Space (SOLIS). III. Zooming Into the Methanol Peak of the Prestellar Core L1544

J. Pineda, R. Neri, L. Testi, 2018, 1802.00859.

Low-temperature reactions: Tunnelling in space.

I. Sims, 2013, Nature chemistry.

Seeds of Life in Space (SOLIS).VII. Discovery of a cold dense methanol blob toward the L1521F VeLLO system.

J. Pineda, R. Neri, L. Testi, 2020, 2002.07004.

The Thermodynamics of the Elusive HO3 Radical

Ian W. M. Smith, A. Canosa, I. Sims, 2010, Science.

Collisional excitation of HNC by He found to be stronger than for structural isomer HCN in experiments at the low temperatures of interstellar space

F. Thibault, I. Sims, Brian M Hays, 2022, Nature Chemistry.

Absolute measurements of state-to-state rotational energy transfer between CO and H2 at interstellar temperatures

P. Jankowski, K. Szalewicz, I. Sims, 2022, Physical Review A.

Gas-phase reactions and energy transfer at very low temperatures.

I. Smith, I. Sims, 1995, Annual review of physical chemistry.

Rotational energy transfer in collisions between CO and Ar at temperatures from 293 to 30 K

I. Sims, T. Stoecklin, S. Picard, 2017 .

Rotational energy transfer in collisions between CO(X 1Sigma+, v= 2 , J = 0, 1, 4, and 6) and He at temperatures from 294 to 15 K.

I. Smith, I. Sims, A. Goddard, 2004, The Journal of chemical physics.

A combined experimental and theoretical study of rotational energy transfer in collisions between NO(X 2Π1/2, v=3,J) and He, Ar and N2 at temperatures down to 7 K

Ian W. M. Smith, I. Sims, M. Alexander, 1998 .

Ultra-low temperature kinetics of neutral–neutral reactions: rate constants for the reactions of OH radicals with butenes between 295 and 23 K

Ian W. M. Smith, B. Rowe, I. Sims, 1994 .

Formation of fulvene in the reaction of C2H with 1,3-butadiene

S. Leone, I. Sims, D. Osborn, 2015 .

Formation of Fulvene in the Reaction of C 2 H with 1 , 3-Butadiene 1

S. Leone, I. Sims, D. Osborn, 2014 .

C+C2H2: A Key Reaction in Interstellar Chemistry

Ian W. M. Smith, D. Clary, I. Sims, 2002 .

Rate coefficients and cross-sections for the reactions of C(3PJ) atoms with methylacetylene and allene

Ian W. M. Smith, I. Sims, W. Geppert, 2000 .

Low temperature kinetics: the association of OH radicals with O2.

Ian W. M. Smith, I. Smith, A. Canosa, 2010, Physical chemistry chemical physics : PCCP.

Comparison of the cross-sections and thermal rate constants for the reactions of C(3PJ) atoms with O2 and NO

Ian W. M. Smith, I. Sims, W. Geppert, 2000 .

Understanding Reactivity at Very Low Temperatures: The Reactions of Oxygen Atoms with Alkenes

Ian W. M. Smith, S. Klippenstein, H. Sabbah, 2007, Science.

Femtosecond probing of bimolecular reactions : the collision complex

A. Zewail, M. Gruebele, I. Sims, 1991 .

Gas Phase Reactive Collisions at very Low Temperature: Recent Experimental Advances and Perspectives

B. Rowe, A. Canosa, I. Sims, 2008 .

Exploring the role of PAHs in the formation of soot : pyrene dimerization.

S. Klippenstein, H. Sabbah, B. Rowe, 2010 .

Rate coefficients for the vibrational self-relaxation of NO(X2Π, ν = 3) at temperatures down to 7 K

Ian W. M. Smith, I. Sims, P. L. James, 1997 .

SOLIS IV. Hydrocarbons in the OMC-2 FIR4 Region, a Probe of Energetic Particle Irradiation of the Region

J. Pineda, R. Neri, P. Caselli, 2018, The Astrophysical Journal.

SOLIS II. Carbon-chain growth in the Solar-type protocluster OMC2-FIR4

J. Pineda, R. Neri, L. Testi, 2017, 1707.01384.

Reaction rate and isomer-specific product branching ratios of C2H + C4H8: 1-butene, cis-2-butene, trans-2-butene, and isobutene at 79 K.

S. Leone, J. Bouwman, I. Sims, 2013, The journal of physical chemistry. A.

Rate Constants of the CN + Toluene Reaction from 15 - 294 K and Interstellar Implications.

M. Okumura, I. Sims, Ilsa R. Cooke, 2020, The journal of physical chemistry. A.

Ultralow-Temperature Kinetics of CH(X2Π) Reactions: Rate Coefficients for Reactions with O2 and NO (T = 13−708 K), and with NH3 (T = 23−295 K)

B. Rowe, I. Sims, D. Travers, 1996 .

Rate Constants for the Relaxation of CH(X 2 Π,ν=1) by CO and N 2 at Temperatures from 23 to 584 K

Ian W. M. Smith, B. Rowe, A. Symonds, 1996 .

Rate coefficients for interstellar gas-phase chemistry

B. Rowe, A. Canosa, I. Sims, 1993 .

Vibrational relaxation of highly excited NCNO in collisions with He, Ar and N2

Ian W. M. Smith, I. Sims, S. M. Wright, 2001 .

Neutral–neutral reactions at the temperatures of interstellar clouds Rate coefficients for reactions of C2H radicals with O2, C2H2, C2H4 and C3H6 down to 15 K

Ian W. M. Smith, I. Sims, D. Chastaing, 1998 .

Low temperature kinetics, crossed beam dynamics and theoretical studies of the reaction S((1)D) + CH4 and low temperature kinetics of S((1)D) + C2H2.

Marzio Rosi, Nadia Balucani, Piergiorgio Casavecchia, 2011, Physical chemistry chemical physics : PCCP.

THE 2014 KIDA NETWORK FOR INTERSTELLAR CHEMISTRY

G. Nyman, J. Tennyson, S. Schlemmer, 2015, 1503.01594.

Ultralow temperature kinetics of neutral–neutral reactions. The technique and results for the reactions CN+O2 down to 13 K and CN+NH3 down to 25 K

Ian W. M. Smith, B. Rowe, I. Sims, 1994 .

Neutral–neutral reactions at the temperatures of interstellar clouds: Rate coefficients for reactions of atomic carbon, C(3P), with O2, C2H2, C2H4 and C3H6 down to 15 K

Ian W. M. Smith, I. Sims, D. Chastaing, 1999 .

Total and state-to-state rate coefficients for rotational energy transfer in collisions between NO(X2Π) and He at temperatures down to 15 K

Ian W. M. Smith, I. Sims, P. L. James, 1997 .

Rate constants for the radical-radical reaction between CN and O2 at temperatures down to 99 K

Ian W. M. Smith, I. Sims, 1988 .

Kinetics at Ultra-low Temperatures: Non-Arrhenius Behaviour and Applications to the Chemistry of Interstellar Clouds

Ian W. M. Smith, B. Rowe, I. Sims, 1996 .

Rate constants for the reactions of CN with hydrocarbons at low and ultra-low temperatures

Ian W. M. Smith, B. Rowe, I. Sims, 1993 .

Low Temperature Kinetics of the Reaction Between Methanol and the CN Radical.

I. Sims, Brian M Hays, Ilsa R. Cooke, 2019, The journal of physical chemistry. A.

Ultra‐low temperature kinetics of neutral–neutral reactions: New experimental and theoretical results for OH+HBr between 295 and 23 K

David C. Clary, Ian W. M. Smith, D. Clary, 1994 .

Low temperature rate coefficients for the reaction CN + HC3N.

S. Klippenstein, I. Sims, J. Guillemin, 2013, The journal of physical chemistry. A.

The Radiative Association of CH with H2: A Mechanism for Formation of CH3 in Interstellar Clouds

Ian W. M. Smith, B. Rowe, A. Canosa, 1997 .

Observation of organosulfur products (thiovinoxy, thioketene and thioformyl) in crossed-beam experiments and low temperature rate coefficients for the reaction S(1D) + C2H4.

Marzio Rosi, Nadia Balucani, Piergiorgio Casavecchia, 2009, Physical chemistry chemical physics : PCCP.

Gas‐Phase Reactions at Low Temperatures: Towards Absolute Zero

Ian W. M. Smith, B. Rowe, I. Sims, 1997 .

Low temperature rate coefficients for reactions of the butadiynyl radical, C4H, with various hydrocarbons. Part I: reactions with alkanes (CH4, C2H6, C3H8, C4H10).

Nadia Balucani, N. Balucani, A. Canosa, 2010, Physical chemistry chemical physics : PCCP.

Kinetics of the Radical−Radical Reaction, O(3PJ) + OH(X2ΠΩ) → O2 + H, at Temperatures down to 39 K†

Ian W. M. Smith, I. Sims, A. Goddard, 2006 .

Direct kinetic measurements on reactions of atomic carbon, C(3P), with O2 and NO at temperatures down to 15 K

I. Sims, S. Picard, D. Chastaing, 2000 .

Crossed-beam dynamics, low-temperature kinetics, and theoretical studies of the reaction S(1D) + C2H4.

Marzio Rosi, Nadia Balucani, Dimitris Skouteris, 2009, The journal of physical chemistry. A.

Product Branching in the Low Temperature Reaction of CN with Propyne by Chirped-Pulse Microwave Spectroscopy in a Uniform Supersonic Flow.

R. Field, A. Suits, I. Sims, 2015, The journal of physical chemistry letters.

A chirped-pulse Fourier-transform microwave/pulsed uniform flow spectrometer. II. Performance and applications for reaction dynamics.

Kirill Prozument, G. B. Park, R. Field, 2014, The Journal of chemical physics.

Effects of short‐term pulsed ammonia exposure on fish

J. Seager, I. Sims, I. Milne, 2000 .

Supporting Online Material

Ian W. M. Smith, A. Canosa, I. Sims, 2004 .

The rate of the F + H2 reaction at very low temperatures.

A. Canosa, I. Sims, F. Lique, 2014, Nature chemistry.

A CROSSED MOLECULAR BEAM, LOW-TEMPERATURE KINETICS, AND THEORETICAL INVESTIGATION OF THE REACTION OF THE CYANO RADICAL (CN) WITH 1,3-BUTADIENE (C4H6). A ROUTE TO COMPLEX NITROGEN-BEARING MOLECULES IN LOW-TEMPERATURE EXTRATERRESTRIAL ENVIRONMENTS

R. Kaiser, A. Mebel, A. Canosa, 2011 .

A new instrument for kinetics and branching ratio studies of gas phase collisional processes at very low temperatures.

M. Okumura, A. Canosa, I. Sims, 2019, The Review of scientific instruments.

Arranging Reactive Meetings of Cold Radicals

I. Sims, 2011, Science.

A chemical dynamics, kinetics, and theoretical study on the reaction of the cyano radical (CN; X(2)Sigma+) with phenylacetylene (C6H5CCH; X(1)A1).

R. Kaiser, A. Canosa, I. Sims, 2010, Physical chemistry chemical physics : PCCP.

Relaxation of H2O from its /04>- vibrational state in collisions with H2O, Ar, H2, N2, and O2.

I. Smith, I. Sims, P. Barnes, 2004, The Journal of chemical physics.

Seeds of Life in Space (SOLIS) II. Formamide in protostellar shocks: Evidence for gas-phase formation

L. Bizzocchi, L. Testi, C. Favre, 2017, 1708.04663.

A chemical dynamics , kinetics , and theoretical study on the reaction of the cyano radical ( CN ; X 2 R + ) with phenylacetylene ( C 6 H 5 CCH ; X 1 A 1 ) w

R. Kaiser, A. Canosa, I. Sims, 2010 .

How measurements of rate coefficients at low temperature increase the predictivity of photochemical models of Titan's atmosphere.

P. Pernot, M. Dobrijevic, A. Canosa, 2009, The journal of physical chemistry. A.

Seeds of Life in Space (SOLIS) I. Carbon-chain growth in the Solar-type protocluster OMC2-FIR4

R. Neri, L. Testi, L. Bizzocchi, 2017 .

Experimental measurements of low temperature rate coefficients for neutral-neutral reactions of interest for atmospheric chemistry of Titan, Pluto and Triton: reactions of the CN radical.

A. Canosa, I. Sims, Sébastien D Le Picard, 2010, Faraday discussions.

Seeds of Life in Space (SOLIS)

Vastel, J. Pineda, R. Neri, 2020, Astronomy & Astrophysics.

Experimental and theoretical study of intramultiplet transitions in collisions of C(3P) and Si(3P) with He

B. Bussery-Honvault, B. Rowe, A. Canosa, 2002 .

Low temperature rate coefficients for the reactions of CN and C2H radicals with allene (CH2CCH2) and methyl acetylene (CH3CCH)

Ian W. M. Smith, I. Sims, V. L. Page, 2001 .

Experimental Investigation of Neutral-Neutral Reactions and Energy Transfer at Low Temperatures

I. Sims, 2005, Proceedings of the International Astronomical Union.

Experimental studies of gas‐phase reactions at extremely low temperatures

Ian W. M. Smith, B. Rowe, I. Sims, 2008 .

An experimental study of the reaction kinetics of C2(X1Σg+) with hydrocarbons (CH4, C2H2, C2H4, C2H6 and C3H8) over the temperature range 24–300 K: Implications for the atmospheres of Titan and the Giant Planets

A. Canosa, I. Sims, S. Picard, 2007 .