A. C. Filippou

发表

Alkylierungsreaktionen eines anionischen ethylisocyanid-komplexes von W0; Synthese von alkyl-, η2-iminoacyl-, 1-azaallyl- und dialkylaminocarbin-komplexen des wolframs

A. C. Filippou, Walter Grünleitner, P. Kiprof, 1991 .

Half-sandwich rhenium(III) acyl complexes: synthesis, structure and conversion to rhenium(I) and rhenium(III) isonitrile complexes

A. C. Filippou, B. Lungwitz, Gabriele Kociok-Ko¨hn, 1996 .

Metal-silicon triple bonds: the molybdenum silylidyne complex [Cp(CO)2Mo[triple bond]Si-R].

G. Schnakenburg, A. C. Filippou, O. Chernov, 2010, Angewandte Chemie.

Observing the formation and the reactivity of an octahedral iron(V) nitrido complex in real time.

Ujjal Das, P. Vöhringer, A. C. Filippou, 2013, Angewandte Chemie.

Thermodynamic Properties of Binary Mixtures of Cyclohexanone with n-Alkanols (C1–C5) at 293.15 K

A. C. Filippou, N. Tsierkezos, Ioanna E. Molinou, 2005 .

Enantioselective Synthetic Methodology to Prepare trans -Fused Bicyclo[5.3.0]decane Systems: an Approach to the Synthesis of the Pseudoguaiane Carbon Framework

G. Kociok‐Köhn, A. C. Filippou, Á. Montaña, 2000 .

Insertion of GeCl2 into group VI transition metal-chlorine bonds: synthesis, spectroscopy and structure of molybdenum and tungsten trichlorogermyl complexes

G. Kociok‐Köhn, A. C. Filippou, Isolde Hinz, 1997 .

Reactivity of iridium(I) PNP amido complexes toward protonation and oxidation

A. C. Filippou, E. Herdtweck, S. Schneider, 2013 .

Metal-silicon triple bonds: nucleophilic addition and redox reactions of the silylidyne complex [Cp(CO)2 Mo≡Si-R].

G. Schnakenburg, A. C. Filippou, O. Chernov, 2011, Angewandte Chemie.

(NHC)Si═C═N-R: A Two-Coordinated Si0-Isocyanide Compound as Si(NHC) Transfer Reagent.

Ujjal Das, G. Schnakenburg, A. C. Filippou, 2021, Journal of the American Chemical Society.

Si=P double bonds: experimental and theoretical study of an NHC-stabilized phosphasilenylidene.

G. Schnakenburg, A. C. Filippou, Marius I Arz, 2015, Angewandte Chemie.

Carbyne-carbyne coupling at a single metal center. Synthesis structure of bis(diethylamino)acetylene complexes of molybdenum(II) and tungsten(II)

A. C. Filippou, Walter Grünleitner, P. Kiprof, 1992 .

Selective synthesis of four- and five-membered metallaheterocycles via CC bond-forming reactions of η2-iminoacyl and η3-1-azaallyl complexes of tungsten with alkyl isocyanides

A. C. Filippou, P. Kiprof, C. Völkl, 1991 .

One-Electron Oxidation of a Disilicon(0) Compound: An Experimental and Theoretical Study of [Si2](+) Trapped by N-Heterocyclic Carbenes.

G. Schnakenburg, A. C. Filippou, O. Schiemann, 2015, Chemistry.

Rhenium-germanium triple bonds: syntheses and reactions of the germylidyne complexes mer-[X2(PMe3)3Re≡Ge-R] (X=Cl, I, H; R=m-terphenyl).

Uttam Chakraborty, G. Schnakenburg, A. C. Filippou, 2013, Chemistry.

Metal Activation of a Germylenoid, a New Approach to Metal–Germanium Triple Bonds: Synthesis and Reactions of the Germylidyne Complexes [Cp(CO)2M≡Ge–C(SiMe3)3] (M = Mo, W)

G. Schnakenburg, A. C. Filippou, O. Chernov, 2012 .

Tungsten–Lead Triple Bonds: Syntheses, Structures, and Coordination Chemistry of the Plumbylidyne Complexes trans‐[X(PMe3)4WPb(2,6‐Trip2C6H3)]

A. Philippopoulos, G. Schnakenburg, A. C. Filippou, 2004 .

Triple Bonding to Tin: Synthesis and Characterization of the Square-Pyramidal Stannylyne Complex Cation [(dppe)2W⋮Sn−C6H3-2,6-Mes2]+ (dppe = Ph2PCH2CH2PPh2, Mes = C6H2-2,4,6-Me3)

G. Schnakenburg, A. C. Filippou, Andreas Philippopoulos, 2003 .

Triple Bonding to Tin: Synthesis and Characterization of the Stannylyne Complex trans‐[Cl(PMe3)4WSnC6H3‐2,6‐Mes2]

A. Philippopoulos, A. C. Filippou, P. Portius, 2003 .

Molybdenum and Tungsten Germylyne Complexes of the General Formula trans-[X(dppe)2M⋮Ge-(η1-Cp*)] (X = Cl, Br, I; dppe = Ph2PCH2CH2PPh2; Cp* = C5Me5): Syntheses, Molecular Structures, and Bonding Features of the Germylyne Ligand

A. Philippopoulos, A. C. Filippou, P. Portius, 2002 .

The Hexaazidogermanate(IV) Ion: Syntheses, Structures, and Reactions.

K. Wehrstedt, A. C. Filippou, P. Portius, 2000, Angewandte Chemie.

SiBr2(Idipp): a stable N-heterocyclic carbene adduct of dibromosilylene.

G. Schnakenburg, A. C. Filippou, O. Chernov, 2009, Angewandte Chemie.

Si=Si Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene.

Ujjal Das, G. Schnakenburg, A. C. Filippou, 2015, Angewandte Chemie.

Stable N-heterocyclic carbene adducts of arylchlorosilylenes and their germanium homologues.

G. Schnakenburg, A. C. Filippou, O. Chernov, 2010, Chemistry.

Activation of aryl germanium(II) chlorides by [Mo(PMe3)6] and [W(eta2-CH2PMe2)H(PMe3)4]: a new route to metal-germanium triple bonds.

A. Philippopoulos, G. Schnakenburg, A. C. Filippou, 2006, Angewandte Chemie.

Triple Bond to Lead: Synthesis and Characterization of the Plumbylidyne Complex trans‐[Br(PMe3)4MoPbC6H3‐2,6‐Trip2]

G. Schnakenburg, A. C. Filippou, H. Rohde, 2004 .

Triple bond to lead: synthesis and characterization of the plumbylidyne complex trans-[Br(PMe(3))(4)Mo[triple chemical bond]Pb--C(6)H(3)-2,6-Trip(2)].

G. Schnakenburg, A. C. Filippou, H. Rohde, 2004, Angewandte Chemie.

NHC‐stabilized Silicon(II) Halides: Reactivity Studies with Diazoalkanes and Azides

G. Schnakenburg, A. C. Filippou, Marius I Arz, 2016 .

The Si2H radical supported by two N-heterocyclic carbenes

G. Schnakenburg, A. C. Filippou, O. Schiemann, 2016, Chemical science.

Addition of Small Electrophiles to N-Heterocyclic-Carbene-Stabilized Disilicon(0): A Revisit of the Isolobal Concept in Low-Valent Silicon Chemistry.

G. Schnakenburg, A. C. Filippou, Marius I Arz, 2016, Journal of the American Chemical Society.

Silicon(i) chemistry: the NHC-stabilised silicon(i) halides Si2X2(Idipp)2 (X = Br, I) and the disilicon(i)-iodido cation [Si2(I)(Idipp)2]+

G. Schnakenburg, A. C. Filippou, Marius I Arz, 2015, Chemical science.

Chromium-silicon multiple bonds: the chemistry of terminal N-heterocyclic-carbene-stabilized halosilylidyne ligands.

G. Schnakenburg, A. C. Filippou, O. Chernov, 2011, Chemistry.

Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.

G. Schnakenburg, A. C. Filippou, Yury Lebedev, 2013, Angewandte Chemie.

Half-sandwich aminocarbyne complexes of chromium

A. C. Filippou, C. P. Mehnert, Klaus M. A. Wanninger, 1993 .

The chemistry of 1,3,5-triazacyclohexane complexes, 7 synthesis and structure determination of ethyl(-1,3,5-tribenzyl-(−1,3,5-triazacyclohexane)) zinc(II)-hexafluorophosphate

G. Kociok‐Köhn, A. C. Filippou, R. Köhn, 1998 .

CC-coupling reactions at low-valent molybdenum centers. Selective formation of η2-iminoacyl, η3-1-azaallyl and η2-1,4-diazabutadien-2-yl complexes of molybdenum from ethyl isocyanide complexes

A. C. Filippou, Walter Grünleitner, C. Völkl, 1991 .

Coordination Chemistry of [E(Idipp)]2+ Ligands (E = Ge, Sn): Metal Germylidyne [Cp*(CO)2W≡Ge(Idipp)]+ and Metallotetrylene [Cp*(CO)3W–E(Idipp)]+ Cations

Ujjal Das, G. Schnakenburg, A. C. Filippou, 2017 .

Synthesis and reactivity of molybdenocene isocyanide complexes; crystal structure of (η5-C5H5)2MoCNtBu

A. C. Filippou, P. Kiprof, M. J. Calhorda, 1992 .

Proton-induced coupling of a tertbutylisocyanide with a diethylaminocarbyne to yield an alkyne ligand at a single tungsten centre

A. C. Filippou, 1990 .

A pair of remarkably stable mononuclear chromium(III) and chromium(IV) hydrides.

G. Schnakenburg, A. C. Filippou, S. Schneider, 2003, Angewandte Chemie.

Unusually Stable Chromium(IV) Alkyls Bearing a Triamidoamine Ligand

A. C. Filippou, S. Schneider, 2003 .

Syntheses and Molecular Structures of Chromium(IV) Halides and Pseudohalides Bearing a Triamidoamine Ligand

A. C. Filippou, S. Schneider, B. Ziemer, 2002 .

Triamidoamine complexes of chromium(III) and chromium(IV).

A. C. Filippou, S. Schneider, 2001, Inorganic chemistry.

METAL-CENTERED COUPLING OF TWO CARBYNE LIGANDS TO FORM AN ALKYNE LIGAND

A. C. Filippou, Walter Grünleitner, P. Kiprof, 1991 .

A reaction pathway of [Fe(CO)(5)] with alkynes via ferrabicyclobutenones.

A. C. Filippou, Torsten Rosenauer, 2002, Angewandte Chemie.

[2+2+1] cycloadditions of bis(dialkylamino)acetylenes with SiI2(Idip): syntheses and reactivity studies of unprecedented 2,3,4,5-tetraamino-1 H-siloles.

Ujjal Das, G. Schnakenburg, A. C. Filippou, 2014, Chemistry.

[Na(THF)2Cr(N3N)]: The first trigonal monopyramidal chromium(II) complex.

G. Schnakenburg, A. C. Filippou, S. Schneider, 2003, Inorganic chemistry.

Silicon-oxygen double bonds: a stable silanone with a trigonal-planar coordinated silicon center.

G. Schnakenburg, A. C. Filippou, Yury Lebedev, 2014, Angewandte Chemie.

Germanium(II) azides: synthesis and crystal structure of Tp′GeN3 [Tp′ = hydrotris(3,5-dimethylpyrazol-1-yl)borato]

G. Kociok‐Köhn, A. C. Filippou, P. Portius, 1998 .

Dimetallagermanes of molybdenum and tungsten: synthesis, structure and reactions

G. Kociok‐Köhn, A. C. Filippou, Isolde Hinz, 1998 .

Insertion of GeCl2 into molybdenum-hydrogen bonds: A convenient route to dichlorogermyl complexes

G. Kociok‐Köhn, A. C. Filippou, Isolde Hinz, 1997 .

Metal-centred CC coupling of nitriles with 1-azaallyl ligands; synthesis and structure of β-diiminato complexes of tungsten

R. Rogers, A. C. Filippou, C. Völkl, 1993 .

TRICHLOROGERMYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN BEARING CYCLOPENTADIENYL LIGANDS : SYNTHESIS, STRUCTURE AND ISOMERIZATION STUDIES

G. Kociok‐Köhn, A. C. Filippou, M. Feist, 1998 .

Stereoselective insertion of GeCl2 into tungsten–chlorine bonds of aminomethylene and aminocarbyne complexes

G. Kociok‐Köhn, A. C. Filippou, P. Portius, 2001 .

Characterization and crystal structure of zinc azurin, a by-product of heterologous expression in Escherichia coli of Pseudomonas aeruginosa copper azurin.

R. Huber, H. Nar, M. Jaquinod, 1992, European journal of biochemistry.

Ge2 Trapped by Triple Bonds between Two Metal Centers: The Germylidyne Complexes trans,trans‐[Cl(depe)2MGeGeM(depe)2Cl] (M=Mo, W) and Bonding Analyses of the MGeGeM Chain

A. Philippopoulos, G. Schnakenburg, A. C. Filippou, 2005 .

Ge2 trapped by triple bonds between two metal centers: the germylidyne complexes trans,trans-[Cl(depe)2M[triple chemical bond]Ge--Ge[triple chemical bond]M(depe)2Cl] (M=Mo, W) and bonding analyses of the M[triple chemical bond]Ge--Ge[triple chemical bond]M chain.

A. Philippopoulos, G. Schnakenburg, A. C. Filippou, 2005, Angewandte Chemie.

Oxidation of germanium(II) azides with HN3: a convenient route to six-co-ordinate triazidogermanium(IV) compounds

G. Kociok‐Köhn, A. C. Filippou, P. Portius, 2000 .

Metal—carbon multiple bonds: Half-sandwich phenylcarbyne complexes of chromium—synthesis, structure, electrochemistry and reactions with PMe3

G. Kociok‐Köhn, A. C. Filippou, Isolde Hinz, 1997 .

Mononuclear bis-aminocarbyne complexes of tungsten with Tp' ligands; theory of metal-centred carbyne-carbyne coupling

A. C. Filippou, P. Kiprof, P. Hofmann, 1993 .

Insertion of Cp*GeCl into a Tungsten−Chlorine Bond and Crystal Structures of the Germylenes Cp*GeCl, [Cp*GeBr]2, and [Cp*Ge][BF4] (Cp* = Pentamethylcyclopentadienyl)

G. Kociok‐Köhn, A. C. Filippou, P. Portius, 1998 .

Homoleptic alkylisocyanide complexes of molybdenum(O) and tungsten(O), useful precursors for the synthesis of low-valent dialkylaminocarbyne complexes

A. C. Filippou, Walter Grünleitner, 1990 .

Thermodynamic investigation of N,N-dimethylformamide/toluene binary mixtures in the temperature range from 278.15 to 293.15 K

A. C. Filippou, N. Tsierkezos, 2006 .

INTRAMOLECULAR CARBYNE-ISOCYANIDE COUPLING TO AN ALKYNE LIGAND AT A D4 TUNGSTEN CENTER

G. Kociok‐Köhn, A. C. Filippou, B. Lungwitz, 1999 .

Metalcarbon multiple bonds: synthesis, structure, and electrochemistry of chromium aminocarbyne and phenylcarbyne complexes bearing phosphine or alkyl isonitrile ligands

G. Kociok‐Köhn, A. C. Filippou, Isolde Hinz, 1997 .

Metal-carbon multiple bonds: novel syntheses and reactions of aminocarbyne complexes of tungsten

A. C. Filippou, B. Lungwitz, 1995 .

Aminocarbyne Complexes of Chromium in a High Oxidation State—Synthesis, Structure, and Reactivity

A. C. Filippou, E. Herdtweck, B. Lungwitz, 1995 .

Übergangsmetall-Carbin-Komplexe, XC. Synthese neuer, siebenfach-koordinierter, kationischer Carbin-Komplexe des Wolframs in einer höheren Oxidationszahl / Transition Metal Carbyne Complexes, XC. Synthesis of New, Seven Coordinated, Cationic Tungsten Carbyne Complexes in a Higher Oxidation State

A. C. Filippou, E. Fischer, H. Guido, 1988 .

Tungsten-mediated activation of a Pb(II)-N bond: a new route to tungsten-lead triple bonds.

G. Schnakenburg, A. C. Filippou, N. Weidemann, 2008, Angewandte Chemie.

CARBENE COMPLEXES OF DIVALENT CHROMIUM

G. Kociok‐Köhn, A. C. Filippou, B. Lungwitz, 1996 .

Manganese-tin triple bonds: a new synthetic route to the manganese stannylidyne complex cation trans-[H(dmpe)2Mn≡Sn(C6H3-2,6-Mes2)]+ (dmpe = Me2PCH2CH2PMe2, Mes = 2,4,6-trimethylphenyl).

Uttam Chakraborty, G. Schnakenburg, A. C. Filippou, 2013, Journal of the American Chemical Society.

Carben- und Carbin-Komplexe des Technetiums und Rheniums - Synthese, Struktur und Reaktionen / Carbene and Carbyne Complexes of Technetium and Rhenium - Synthesis, Structure and Reactions

A. C. Filippou, W. Roth, Christos Apostolidis, 1995 .

Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [(κ3-tmps)(CO)2NbE–R] (E = Si, Ge, Sn; tmps = MeSi(CH2PMe2)3; R = aryl)

G. Schnakenburg, A. C. Filippou, David Hoffmann, 2017 .

Triazidogermyl complexes of tungsten: synthesis, crystal structure and hydrolysis to a metallocyclotrigermoxane

G. Kociok‐Köhn, A. C. Filippou, R. Steck, 1999 .

Aminomethylene complexes of molybdenum(IV) and tungsten(IV) bearing 1,2-dithiolato ligands

A. C. Filippou, P. Portius, C. Jankowski, 2001 .

Metal‐Centered Coupling Reactions of C1 Ligands Analogous to Carbon Monoxide

A. C. Filippou, 1999 .

CHROMIUM-CARBON MULTIPLE BONDS : AMINOCARBYNE COMPLEXES OF CHROMIUM BEARING ISOCYANIDE LIGANDS

A. C. Filippou, C. P. Mehnert, M. Kleine, 1995 .

Isocyanide derivatives of tungstenocene

A. C. Filippou, Ana M Martins, A. R. Dias, 1993 .

Alkyne Cleavage as a Novel Route to Low‐Valent Carbyne‐Metal Complexes

A. C. Filippou, Walter Grünleitner, P. Kiprof, 1990 .

Cyclopentadienyl substituted diethylaminocarbyne complexes of tungsten in a higher oxidation state

A. C. Filippou, 1989 .

Synthesis of [Et2NCW(CO)2(μ‐PPh2)2Mo(CO)4]⊖, the First Anionic Carbynemetal Complex; Addition of CO2 to the WC Bond

U. Thewalt, A. C. Filippou, H. Alt, 1985 .

Metal–Silicon Triple Bonds: Access to [Si(η5-C5Me5)]+ from SiX2(NHC) and its Conversion to the Silylidyne Complex [TpMe(CO)2MoSi(η3-C5Me5)] (TpMe = κ3-N,N′,N″-hydridotris(3,5-dimethyl-1-pyrazolyl)borate)

G. Schnakenburg, A. C. Filippou, Priyabrata Ghana, 2017 .

Electron-Rich Trichlorogermyl Complexes of Molybdenum and Tungsten Bearing a Cyclopentadienyl Ligand: Synthesis, Crystal Structures, and Cyclic Voltammetric Studies

G. Kociok‐Köhn, A. C. Filippou, C. Troll, 1999 .

The hexaazidosilicate(IV) ion: synthesis, properties, and molecular structure.

G. Schnakenburg, A. C. Filippou, P. Portius, 2002, Journal of the American Chemical Society.

Ultrafast primary processes of an iron-(III) azido complex in solution induced with 266 nm light.

F. Neese, D. Schwarzer, P. Vöhringer, 2012, Physical chemistry chemical physics : PCCP.

Neutral Lewis base adducts of silicon tetraazide.

K. Wehrstedt, G. Schnakenburg, A. C. Filippou, 2010, Angewandte Chemie.

Tris[2,2,6,6-tetramethyl-8-(trimethylsilyl)benzo[1,2-d;4,5-d′]bis(1,3-dithiol)-4-yl]methanol diethyl ether monosolvate

G. Schnakenburg, A. C. Filippou, O. Schiemann, 2018, Acta crystallographica. Section E, Crystallographic communications.

Metal-carbon multiple bonds: [2 + 2] cycloaddition of nitrilium salts across a metal-carbon triple bond; synthesis and structure of iminocarbene complexes of tungsten

A. C. Filippou, E. Herdtweck, B. Lungwitz, 1995 .

The Femtochemistry of a Ferracyclobutadiene.

J. Lindner, Ujjal Das, P. Vöhringer, 2017, Angewandte Chemie.

Planar Tetracoordinated Silicon (ptSi): Room-Temperature Stable Compounds Containing Anti-van't Hoff/Le Bel Silicon.

G. Schnakenburg, A. C. Filippou, Priyabrata Ghana, 2020, Journal of the American Chemical Society.

Open-shell complexes containing metal-germanium triple bonds.

G. Schnakenburg, A. C. Filippou, M. van Gastel, 2012, Angewandte Chemie.

Tebbe (Grubbs) reagent

A. C. Filippou, 2020 .

The Electronic Nature of Cationic Group 10 Ylidyne Complexes

A. C. Filippou, Leonard R. Maurer, J. Rump, 2023, Inorganics.

The photochemistry of [Fe(III)N3(cyclam-ac)]PF6 at 266 nm.

F. Neese, D. Schwarzer, P. Vöhringer, 2012, Chemistry.

acceptor ligands

A. C. Filippou, 2020, Catalysis from A to Z.

Linearly Two-Coordinated Silicon: Transition Metal Complexes with the Functional Groups M≡Si-M and M═Si═M.

Uttam Chakraborty, G. Schnakenburg, A. C. Filippou, 2018, Journal of the American Chemical Society.

Halide Substitution Reactions of the Germylidyne Complexes trans-[X(dppe)2W⋮Ge(η1-Cp*)] (X = Cl, I; dppe = Ph2PCH2CH2PPh2; Cp* = C5Me5)

A. Philippopoulos, G. Schnakenburg, A. C. Filippou, 2004 .

Ultrafast primary processes of an iron-(III) azido complex in solution induced with 266 nm light.

F. Neese, D. Schwarzer, P. Vöhringer, 2012, Physical chemistry chemical physics : PCCP.

Electron-Rich Tungsten Aminocarbyne Complexes with Cp* Ligands Synthesis and Protonation Reactions

A. C. Filippou, B. Lungwitz, 1993 .