M. Shibasaki

发表

Concise enantioselective synthesis of duloxetine via direct catalytic asymmetric aldol reaction of thioamide.

Yuta Suzuki, M. Iwata, R. Yazaki, 2012, The Journal of organic chemistry.

Catalytic asymmetric total synthesis of (+)-caprazol.

T. Masuda, M. Shibasaki, Takumi Watanabe, 2014, Organic letters.

Direct Catalytic Asymmetric Mannich-type Reaction of α,β-Unsaturated γ-Butyrolactam with Ketimines.

N. Kumagai, M. Shibasaki, Shaoquan Lin, 2016, Chemistry.

Direct Catalytic Asymmetric Vinylogous Michael Reaction of α,β-Unsaturated γ-Butyrolactam under Dinuclear Nickel Schiff Base Catalysis

S. Matsunaga, Yingjie Xu, M. Shibasaki, 2012 .

Direct catalytic asymmetric Mannich-type reactions of gamma-butenolides: effectiveness of Brønsted acid in chiral metal catalysis.

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2008, Organic letters.

Direct catalytic asymmetric vinylogous Mannich-type and Michael reactions of an alpha,beta-unsaturated gamma-butyrolactam under dinuclear nickel catalysis.

S. Matsunaga, Yingjie Xu, M. Shibasaki, 2010, Journal of the American Chemical Society.

Strategic Immobilization of Molecular Catalysts onto Carbon Nanotubes via Noncovalent Interaction for Catalytic Organic Transformations

N. Kumagai, M. Shibasaki, 2017 .

Catalytic asymmetric carbon-carbon bond-forming reaction utilizing rare earth metal complexes

M. Shibasaki, H. Sasai, 1996 .

An efficient method for the synthesis of versatile intermediates leading to 13-deoxy- and 9,13-dideoxyphorbols

N. Kumagai, M. Shibasaki, A. Sekine, 2000 .

TriQuinoline

N. Kumagai, M. Shibasaki, S. Adachi, 2019, Nature Communications.

Neighboring Protonation Unveils Lewis Acidity in the B3NO2 Heterocycle.

N. Kumagai, M. Shibasaki, H. Noda, 2019, Journal of the American Chemical Society.

Studies on catalytic enantioselective total synthesis of caprazamycin B: construction of the western zone.

M. Shibasaki, Takumi Watanabe, P. Gopinath, 2012, The Journal of organic chemistry.

Multimetallic Bifunctional Asymmetric Catalysis Based on Proximity Effect Control

S. Matsunaga, M. Shibasaki, 2008 .

Direct Catalytic Asymmetric Aldol Reactions of Aldehydes with Unmodified Ketones

Yoichi M. A. Yamada, M. Shibasaki, H. Sasai, 1997 .

Towards Perfect Asymmetric Catalysis: Additives and Cocatalysts.

H. Gröger, M. Shibasaki, E. Vogl, 1999, Angewandte Chemie.

Direct Catalytic Asymmetric Aldol Reaction

Yoichi M. A. Yamada, M. Shibasaki, H. Sasai, 1999 .

Photocatalytic α-Acylation of Ethers.

N. Kumagai, M. Shibasaki, Zhongdong Sun, 2017, Organic letters.

Introduction of a 7-aza-6-MeO-indoline auxiliary in Lewis-acid/photoredox cooperative catalysis: highly enantioselective aminomethylation of α,β-unsaturated amides†

N. Kumagai, M. Shibasaki, Santosh K Pagire, 2020, Chemical science.

A carbon nanotube confinement strategy to implement homogeneous asymmetric catalysis in the solid phase.

N. Kumagai, M. Shibasaki, Kazuki Hashimoto, 2015, Chemistry.

Efficient Synthesis of Chiral α‐ and β‐Hydroxy Amides: Application to the Synthesis of (R)‐Fluoxetine

T. Nemoto, M. Shibasaki, H. Kakei, 2004 .

( 2R , 3S )‐3,4,4,4‐Tetrafluorovaline: A Fluorinated Bioisostere of Isoleucine

N. Kumagai, M. Shibasaki, H. Noda, 2020 .

Chiral Bimetallic Lewis Acids

N. Kumagai, M. Shibasaki, 2015 .

Lewis Acid–Brønsted Base Catalysis

N. Kumagai, M. Shibasaki, 2015 .

Direct catalytic asymmetric addition of allyl cyanide to ketones via soft Lewis acid/hard Brønsted base/hard Lewis base catalysis.

R. Yazaki, N. Kumagai, M. Shibasaki, 2010, Journal of the American Chemical Society.

Non-C2-symmetric, chirally economical, and readily tunable linked-binols: design and application in a direct catalytic asymmetric mannich-type reaction.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2005, Angewandte Chemie.

Cu(I)-catalyzed direct enantioselective cross aldol-type reaction of acetonitrile.

M. Kanai, M. Shibasaki, Yutaka Suto, 2005, Organic letters.

Synthesis of intervenolin, an antitumor natural quinolone with unusual substituents.

A. Nomoto, M. Kawada, M. Shibasaki, 2013, Organic letters.

Silver salt effects on an asymmetric heck reaction. Catalytic asymmetric total synthesis of (+)-xestoquinone

M. Shibasaki, K. Uotsu, F. Miyazaki, 1998 .

Anti-influenza virus activity of a salcomine derivative mediated by inhibition of viral RNA synthesis

N. Takizawa, M. Shibasaki, Takumi Watanabe, 2018, Archives of Virology.

Inhibition of mitochondria ATP synthase suppresses prostate cancer growth through reduced insulin‐like growth factor‐1 secretion by prostate stromal cells

M. Kawada, M. Shibasaki, Takumi Watanabe, 2020, International journal of cancer.

AN IMPROVED ROUTE TO (+)-9(O)-METHANO-Δ6(9α)-PROSTAGLANDIN-I1 (ISOCARBACYCLIN)

S. Ikegami, M. Shibasaki, H. Okabe, 1984 .

Multimetallic Multifunctional Catalysts for Asymmetric Reactions

M. Kanai, S. Matsunaga, N. Kumagai, 2011 .

Catalytic asymmetric synthesis of R207910.

M. Kanai, M. Shibasaki, S. Makino, 2010, Journal of the American Chemical Society.

Limited Brain Distribution of [3R,4R,5S]-4-Acetamido-5-amino-3-(1-ethylpropoxy)-1-cyclohexene-1-carboxylate Phosphate (Ro 64-0802), a Pharmacologically Active Form of Oseltamivir, by Active Efflux across the Blood-Brain Barrier Mediated by Organic Anion Transporter 3 (Oat3/Slc22a8) and Multidrug Res

H. Kusuhara, Y. Sugiyama, M. Kanai, 2009, Drug Metabolism and Disposition.

P-glycoprotein Restricts the Penetration of Oseltamivir Across the Blood-Brain Barrier

H. Kusuhara, Y. Sugiyama, M. Kanai, 2008, Drug Metabolism and Disposition.

ACTIVE EFFLUX OF RO 64-0802, THE ACTIVE FORM OF OSELTAMIVIR, ACROSS THE BLOOD-BRAIN BARRIER

H. Kusuhara, Y. Sugiyama, M. Kanai, 2008 .

Corrigendum: Solvent‐Dependent Self‐Discrimination of Bis(2‐hydroxyphenyl)diamides

N. Kumagai, M. Shibasaki, Akinobu Matsuzawa, 2011 .

Stromal Cells Positively and Negatively Modulate the Growth of Cancer Cells: Stimulation via the PGE2-TNFα-IL-6 Pathway and Inhibition via Secreted GAPDH-E-Cadherin Interaction

A. Nomoto, H. Inoue, M. Kawada, 2015, PloS one.

The Different Faces of [Ru(bpy)3Cl2] and fac[Ir(ppy)3] Photocatalysts: Redox Potential Controlled Synthesis of Sulfonylated Fluorenes and Pyrroloindoles from Unactivated Olefins and Sulfonyl Chlorides.

N. Kumagai, M. Shibasaki, Santosh K Pagire, 2020, Organic letters.

A fluorogenic C4N4 probe for azide-based labelling.

N. Kumagai, M. Shibasaki, H. Noda, 2019, Organic & biomolecular chemistry.

Identification of self-growth-inhibiting compounds lauric acid and 7-(Z)-tetradecenoic acid from Helicobacter pylori.

A. Nomoto, M. Shibasaki, C. Hayashi, 2015, Microbiology.

Synthesis and assignment of the absolute configuration of indenotryptoline bisindole alkaloid BE-54017.

M. Shibasaki, M. Imoto, Takumi Watanabe, 2012, Organic letters.

Sequential Regulation of DOCK2 Dynamics by Two Phospholipids During Neutrophil Chemotaxis

M. Kanai, Takehiko Sasaki, M. Frohman, 2009, Science.

Oseltamivir enhances hippocampal network synchronization.

N. Matsuki, Y. Ikegaya, Takuya Sasaki, 2008, Journal of pharmacological sciences.

In situ manipulation of catalyst performance via the photocontrolled aggregation/dissociation state of the catalyst.

N. Kumagai, M. Shibasaki, Akihiro Nojiri, 2013, Chemical communications.

The first catalytic asymmetric total synthesis of ent-hyperforin

M. Kanai, M. Shibasaki, Shi‐Liang Shi, 2010 .

Catalytic asymmetric total synthesis of ent-hyperforin.

M. Kanai, M. Shibasaki, Shi‐Liang Shi, 2010, Angewandte Chemie.

A new approach for the construction of a highly congested bicyclic system in polycyclic polyprenylated acylphloroglucinols (PPAPs)

M. Kanai, M. Shibasaki, Yohei Shimizu, 2007 .

Cu/Pd Synergistic Dual Catalysis: Asymmetric α-Allylation of an α-CF3 Amide.

N. Kumagai, M. Shibasaki, A. Saito, 2017, Angewandte Chemie.

Enantioselective syntheses and biological studies of aeruginosin 298-A and its analogs: application of catalytic asymmetric phase-transfer reaction.

T. Kisugi, T. Nemoto, M. Shibasaki, 2004, Proceedings of the National Academy of Sciences of the United States of America.

Direct Catalytic Asymmetric Aldol Reaction of α-Alkoxyamides to α-Fluorinated Ketones.

N. Kumagai, M. Shibasaki, Roman Pluta, 2019, Angewandte Chemie.

Catalytic asymmetric conjugate addition of alpha-cyanoketones for the construction of a quaternary stereogenic center.

Yuji Kawato, N. Kumagai, M. Shibasaki, 2010, Organic letters.

Formal Total Synthesis of (−)-Dendrobine Using Zirconium Promoted Cyclization. Determination of the Absolute Configuration of the Intermediary Tricyclic Ketone

M. Shibasaki, M. Mori, F. Saitoh, 1993 .

Ring construction by zirconium-promoted reductive coupling of nitrites with alkenes

M. Shibasaki, M. Mori, N. Uesaka, 1990 .

Total synthesis of lactacystin and salinosporamide A.

M. Kanai, M. Shibasaki, N. Fukuda, 2007, Chemistry, an Asian journal.

Overexpression of glucose transporter modulates insulin biosynthesis in insulin producing cell line

T. Asano, Y. Oka, Y. Akanuma, 1990, FEBS letters.

Rediscovery of 4‐Trehalosamine as a Biologically Stable, Mass‐Producible, and Chemically Modifiable Trehalose Analog

M. Shibasaki, Takumi Watanabe, C. Hayashi, 2022, Advanced biology.

Embryo Spacing and Implantation Timing Are Differentially Regulated by LPA3-Mediated Lysophosphatidic Acid Signaling in Mice1

N. Matsuki, Hiroshi Suzuki, J. Chun, 2007, Biology of reproduction.

Generation and application of Cu-bound alkyl nitrenes for the catalyst-controlled synthesis of cyclic β-amino acids†

R. Tak, M. Shibasaki, H. Noda, 2021, Chemical science.

O-Benzoylhydroxylamines as Alkyl Nitrene Precursors: Synthesis of Saturated N-Heterocycles from Primary Amines.

M. Shibasaki, H. Noda, Yasuko Asada, 2020, Organic letters.

Heterobimetallic transition metal/rare earth metal bifunctional catalysis: a Cu/Sm/Schiff base complex for syn-selective catalytic asymmetric nitro-Mannich reaction.

S. Matsunaga, M. Shibasaki, Shinya Handa, 2010, Journal of the American Chemical Society.

Catalytic asymmetric epoxidation of alpha,beta-unsaturated phosphane oxides with a Y(O-iPr)3/biphenyldiol complex.

S. Matsunaga, So-Young Park, M. Shibasaki, 2008, Chemistry, an Asian journal.

Catalytic asymmetric synthesis of 2,2-disubstituted terminal epoxides via dimethyloxosulfonium methylide addition to ketones.

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2008, Journal of the American Chemical Society.

Reversible Stereoselective Folding/Unfolding Fueled by the Interplay of Photoisomerism and Hydrogen Bonding.

N. Kumagai, M. Shibasaki, Christopher R. Opie, 2017, Angewandte Chemie.

Direct aldol strategy in enantioselective total synthesis of thuggacin B.

N. Kumagai, M. Shibasaki, Akinobu Matsuzawa, 2014, Chemistry.

Catalytic Asymmetric Nitro-Mannich Reactions with a Yb/K Heterobimetallic Catalyst

N. Kumagai, M. Shibasaki, Tatsuya Nitabaru, 2010, Molecules.

Direct catalytic asymmetric aldol reactions promoted by novel heterobimetallic catalysts possessing strong Brønsted base: a new strategy for the development of Lewis acid–Brønsted base bifunctional catalysts

M. Shibasaki, N. Yoshikawa, 2001 .

Formal total synthesis of (+)-wortmannin using catalytic asymmetric intramolecular aldol condensation reaction

M. Shibasaki, T. Ohshima, Takashi Mizutani, 2005 .

The first chemical synthesis of wortmannin by starting from hydrocortisone

Seiji Sato, M. Shibasaki, M. Nakada, 1996 .

Managing the retro-pathway in direct catalytic asymmetric aldol reactions of thioamides† †Electronic supplementary information (ESI) available: Experimental procedures and characterization of new compounds. See DOI: 10.1039/c5sc02218e

N. Kumagai, M. Shibasaki, Youmei Bao, 2015, Chemical science.

Chiral poly-rare earth metal complexes in asymmetric catalysis

M. Shibasaki, 2006, Proceedings of the Japan Academy. Series B, Physical and biological sciences.

Catalytic Asymmetric Total Synthesis of Leucinostatin A

M. Shibasaki, Takumi Watanabe, Hikaru Abe, 2020, Chemical record.

Structure-activity relationship study of leucinostatin A, a modulator of tumor−stroma interaction

M. Kawada, M. Shibasaki, Takumi Watanabe, 2018, Tetrahedron.

Catalytic Asymmetric Total Synthesis and Stereochemical Revision of Leucinostatin A: A Modulator of Tumor-Stroma Interaction.

M. Kawada, M. Shibasaki, Takumi Watanabe, 2017, Chemistry.

Conquering amide planarity: Structural distortion and its hidden reactivity

N. Kumagai, M. Shibasaki, S. Adachi, 2018 .

Thieme Chemistry Journals Awardees – Where Are They Now? Bis(2-pyridyl)amides as Readily Cleavable Amides Under Catalytic, Neutral, and Room-Temperature Conditions

N. Kumagai, M. Shibasaki, S. Adachi, 2017 .

Pyramidalization/twisting of the amide functional group via remote steric congestion triggered by metal coordination

N. Kumagai, M. Shibasaki, S. Adachi, 2016, Chemical science.

Mixed La-Li heterobimetallic complexes for tertiary nitroaldol resolution

S. Matsunaga, M. Shibasaki, S. Harada, 2009 .

Self‐Assembly of Heterobimetallic Complexes and Reactive Nucleophiles: A General Strategy for the Activation of Asymmetric Reactions Promoted by Heterobimetallic Catalysts

Yoichi M. A. Yamada, M. Shibasaki, T. Arai, 1996 .

Catalytic enantioselective allylation of ketoimines.

M. Kanai, M. Shibasaki, Reiko Wada, 2006, Journal of the American Chemical Society.

Catalytic enantioselective allylboration of ketones.

M. Kanai, M. Shibasaki, Reiko Wada, 2004, Journal of the American Chemical Society.

Catalytic asymmetric 1,4-addition reactions using α, β-unsaturated N-acylpyrroles as highly reactive monodentate α, β-unsaturated ester surrogates

S. Matsunaga, M. Shibasaki, S. Harada, 2004 .

Sequential Wittig Olefination–Catalytic Asymmetric Epoxidation with Reuse of Waste Ph3P(O): Application of α,β‐Unsaturated N‐Acyl Pyrroles as Ester Surrogates

S. Matsunaga, M. Shibasaki, S. Okada, 2003 .

Catalytic asymmetric epoxidation of alpha,beta-unsaturated esters with chiral yttrium-biaryldiol complexes.

S. Matsunaga, M. Shibasaki, H. Kakei, 2007, Chemistry, an Asian journal.

syn-Selective catalytic asymmetric nitro-Mannich reactions using a heterobimetallic Cu-Sm-Schiff base complex.

S. Matsunaga, M. Shibasaki, Shinya Handa, 2007, Journal of the American Chemical Society.

Synthetic Strategies for Oseltamivir Phosphate

M. Kanai, M. Shibasaki, 2008 .

The First Enantioselective and Diastereoselective Catalytic Nitro-Mannich Reaction: A New Entry to Chiral Vicinal Diamines

M. Shibasaki, Ken‐ichi Yamada, G. Moll, 2001 .

Catalytic asymmetric nitroaldol reaction of α,α-difluoro aldehydes mediated by rare earth-lithium-BINOL complexes

M. Shibasaki, H. Sasai, K. Iseki, 1996 .

Efficient Diastereoselective and Enantioselective Nitroaldol Reactions from Prochiral Starting Materials: Utilization of La-Li-6,6'-Disubstituted BINOL Complexes as Asymmetric Catalysts

M. Shibasaki, T. Tokunaga, H. Sasai, 1995 .

Syntheses of (S)-(−)-pindolol and [3′-13C]-(R)-(−)-pindolol utilizing a lanthanum-lithium-(R)-BINOL ((R)-LLB) catalyzed nitroaldol reaction

Yoichi M. A. Yamada, M. Shibasaki, H. Sasai, 1994 .

Catalytic asymmetric nitroaldol reaction using optically active rare earth BINOL complexes : investigation of the catalyst structure

Koichi Tanaka, M. Shibasaki, H. Sasai, 1993 .

Total synthesis of (+/-)-wortmannin.

M. Shibasaki, Takashi Mizutani, S. Honzawa, 2002, Angewandte Chemie.

Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

S. Matsunaga, M. Shibasaki, T. Ohshima, 2000 .

A catalytic asymmetric synthesis of a versatile intermediate for phorbol derivatives

M. Shibasaki, Yun-sik Kim, Hideaki Sato, 1999 .

An enantioselective synthesis of the key intermediate for triazole antifungal agents; application to the catalytic asymmetric synthesis of efinaconazole (Jublia).

N. Kumagai, M. Shibasaki, K. Tamura, 2014, The Journal of organic chemistry.

The Catalytic Asymmetric Strecker Reaction

M. Kanai, M. Shibasaki, T. Mita, 2008 .

Nucleophilic activation of alkenyl and aryl boronates by a chiral Cu(I)F complex: catalytic enantioselective alkenylation and arylation of aldehydes.

M. Kanai, M. Shibasaki, D. Tomita, 2006, Chemistry, an Asian journal.

Leptolyngbyolides, Cytotoxic Macrolides from the Marine Cyanobacterium Leptolyngbya sp.: Isolation, Biological Activity, and Catalytic Asymmetric Total Synthesis.

M. Shibasaki, Takumi Watanabe, K. Suenaga, 2017, Chemistry.

Catalytic asymmetric anti-selective nitroaldol reaction en route to zanamivir.

N. Kumagai, M. Shibasaki, Tatsuya Nitabaru, 2012, Angewandte Chemie.

Catalytic enantioselective construction of tetrasubstituted carbons by self-assembled poly rare earth metal complexes.

M. Kanai, M. Shibasaki, 2007, Organic & biomolecular chemistry.

Catalytic asymmetric nitroaldol reactions. A new practical method for the preparation of the optically active lanthanum complex

M. Shibasaki, H. Sasai, Takeyuki Suzuki, 1993 .

Catalytic asymmetric synthesis of chiral tertiary organoboronic esters through conjugate boration of beta-substituted cyclic enones.

M. Kanai, M. Shibasaki, L. Yin, 2009, Journal of the American Chemical Society.

CATALYTIC ASYMMETRIC SYNTHESIS OF ARBUTAMINE

Yoichi M. A. Yamada, M. Shibasaki, H. Sasai, 1997 .

Dynamic structural change of the self-assembled lanthanum complex induced by lithium triflate for direct catalytic asymmetric aldol-Tishchenko reaction.

M. Shibasaki, H. Masu, K. Yamaguchi, 2005, Chemistry.

A heterobimetallic Ni/La-salan complex for catalytic asymmetric decarboxylative 1,4-addition of malonic acid half-thioester.

S. Matsunaga, M. Shibasaki, Shinsuke Mouri, 2010, Chemistry, an Asian journal.

Bifunctional Asymmetric Catalysis Based on Dinuclear Schiff Base Complexes

S. Matsunaga, M. Shibasaki, 2010 .

Multimetallic Bifunctional Asymmetric Catalysis Based on Proximity Effect Control

S. Matsunaga, M. Shibasaki, 2008 .

Pd-Catalyzed allylic alkylation of secondary nitroalkanes

M. Kanai, M. Shibasaki, K. Maki, 2007 .

Diastereoselective catalytic asymmetric nitroaldol reaction utilizing rare earth-Li-(R)-BINOL complex. A highly efficient synthesis of norstatine

M. Shibasaki, H. Sasai, J. Hasegawa, 1994 .

SYNTHETIC STUDIES ON (+)-WORTMANNIN. AN ASYMMETRIC CONSTRUCTION OF AN ALLYLIC QUATERNARY CARBON CENTER BY A HECK REACTION

M. Shibasaki, Takashi Mizutani, S. Honzawa, 1999 .

Exploiting β-Amino Acid Enolates in Direct Catalytic Diastereo- and Enantioselective C-C Bond-Forming Reactions.

M. Shibasaki, H. Noda, Jin-Sheng Yu, 2018, Chemistry.

The asymmetric synthesis of cyclopentane derivatives by palladium-catalyzed coupling of prochiral alkylboron compounds

M. Shibasaki, S. Cho, 1998 .

Development of Multifunctional Asymmetric Catalysts and Their Application to Practical Organic Synthesis

Yoichi M. A. Yamada, M. Shibasaki, Takehiko Iida, 1998 .

Heterobimetallic asymmetric catalysts. Developments and applications

M. Shibasaki, T. Arai, H. Sasai, 1998 .

A method for the synthesis of an oseltamivir PET tracer.

Yasuyoshi Watanabe, M. Kanai, S. Matsunaga, 2008, Bioorganic & medicinal chemistry letters.

Profesor Shun-ichi Yamada

S. Ikegami, M. Shibasaki, T. Shioiri, 1997 .

Synthetic entry into a new type of prostaglandin: 6(9α),6(11α)-dioxido-15S-hydroxyprost-13E-enoic acid methyl ester

S. Ikegami, M. Shibasaki, Jun-ichi Deda, 1978 .

Vasodilation produced by prostacyclin (PGI2) and 9(O)-thiaprostacyclin (PGI2-S) in the canine femoral circulation.

M. Shibasaki, T. Kanayama, D. Horii, 1978, European journal of pharmacology.

SYNTHESIS OF 9(O)‐THIAPROSTACYCLIN

M. Shibasaki, S. Ikegami, 1978 .

Intramolecular sulfenyl bromide addition promising a new synthetic route to 9(O)-thiaprostacyclin

S. Ikegami, M. Shibasaki, 1978 .

Total synthesis of (+)-tautomycin

M. Shibasaki, M. Nakada, S. Shimizu, 1996 .

Multimetallic Schiff Base Complexes as Cooperative Asymmetric Catalysts

S. Matsunaga, M. Shibasaki, 2013 .

Recent progress in asymmetric bifunctional catalysis using multimetallic systems.

M. Kanai, S. Matsunaga, N. Kumagai, 2009, Accounts of chemical research.

Asymmetric synthesis of tertiary alcohols and alpha-tertiary amines via Cu-catalyzed C-C bond formation to ketones and ketimines.

M. Kanai, M. Shibasaki, 2008, Chemical reviews.

Enantio- and diastereoselective catalytic Mannich-type reaction of a glycine schiff base using a chiral two-center phase-transfer catalyst.

M. Shibasaki, H. Masu, K. Yamaguchi, 2005, Angewandte Chemie.

Copper(II) Fluoride

M. Kanai, M. Shibasaki, A. Watson, 2021, Encyclopedia of Reagents for Organic Synthesis.

Structural and Computational Investigation of Intramolecular N−H Interactions in α- and β-Fluorinated 7-Azaindoline Amides

N. Kumagai, M. Shibasaki, H. Noda, 2018 .

An alternative synthesis of Tamiflu®: a synthetic challenge and the identification of a ruthenium-catalyzed dihydroxylation route

M. Kanai, K. Yamatsugu, M. Shibasaki, 2009 .

Chromatography-free synthesis of Corey's intermediate for Tamiflu

N. Kumagai, M. Shibasaki, Takumi Watanabe, 2014 .

Two approaches toward the formal total synthesis of oseltamivir phosphate (Tamiflu): catalytic enantioselective three-component reaction strategy and L-glutamic acid strategy.

K. Yamatsugu, N. Kumagai, M. Shibasaki, 2013, The Journal of organic chemistry.

Recent Development in Synthetic Strategies for Oseltamivir Phosphate

M. Kanai, K. Yamatsugu, M. Shibasaki, 2011 .

Design and Synthesis of Resin-Conjugated Tamiflu Analogs for Affinity Chromatography †

M. Kanai, T. Kuzuhara, Yasuaki Kimura, 2010 .

Design and synthesis of immobilized Tamiflu analog on resin for affinity chromatography

M. Kanai, T. Kuzuhara, Yasuaki Kimura, 2009 .

A synthesis of Tamiflu by using a barium-catalyzed asymmetric Diels-Alder-type reaction.

M. Kanai, Yasuaki Kimura, K. Yamatsugu, 2009, Angewandte Chemie.

A concise synthesis of Tamiflu: third generation route via the Diels–Alder reaction and the Curtius rearrangement

M. Kanai, K. Yamatsugu, M. Shibasaki, 2007 .

Second generation catalytic asymmetric synthesis of Tamiflu: allylic substitution route.

M. Kanai, M. Shibasaki, F. Roca, 2007, Organic letters.

De novo synthesis of Tamiflu via a catalytic asymmetric ring-opening of meso-aziridines with TMSN3.

M. Kanai, M. Shibasaki, T. Mita, 2006, Journal of the American Chemical Society.

Catalytic asymmetric synthesis of a functionalized indolizidine derivative. A useful intermediate suitable for the synthesis of various glycosidase inhibitors

M. Sodeoka, M. Shibasaki, S. Nukui, 1993 .

Asymmetric heck reaction-anion capture process. A catalytic asymmetric synthesis of the key intermediates for the Capnellenols

M. Shibasaki, T. Ohshima, K. Kagechika, 1993 .

A catalytic asymmetric synthesis of hydrindans

M. Shibasaki, Y. Sato, T. Honda, 1992 .

Further studies on a catalytic asymmetric synthesis of decalin derivatives

M. Shibasaki, Y. Sato, Shoko Watanabe, 1992 .

A catalytic asymmetric synthesis of α-methylene lactones by the palladium-catalysed carbonylation of prochiral alkenyl halides

M. Shibasaki, Y. Uozumi, Takeyuki Suzuki, 1991 .

Incorporation of molecular nitrogen into organic compounds: IV. Novel lactam synthesis by nitrogenation of enol lactones

M. Shibasaki, Y. Uozumi, M. Mori, 1990 .

Catalytic asymmetric carbon-carbon bond formation: asymmetric synthesis of cis-decalin derivatives by palladium-catalyzed cyclization of prochiral alkenyl iodides

M. Sodeoka, M. Shibasaki, Y. Sato, 1989 .

Ring Construction of Bicyclic-b-lactam by Use of Palladium Catalyzed Carbonylation

M. Shibasaki, M. Mori, K. Kagechika, 1989 .

Direct N-acylation of sulfoximines with carboxylic acids catalyzed by the B3NO2 heterocycle.

N. Kumagai, M. Shibasaki, H. Noda, 2017, Chemical Communications.

Utilization of Me3SiSnBu3 in organic synthesis: I. Generation of a stannyl anion from Me3SiSnBu3 and R4NX

M. Shibasaki, M. Mori, Naohiro Isono, 1993 .

Reaction of metal free Bu3Sn− generated from Bu3SnSiMe3-R4NX with an aryl or vinyl halide

M. Shibasaki, M. Mori, Naohiro Isono, 1991 .

Catalytic asymmetric conjugate addition of thiols to α,β-unsaturated thioamides: expeditious access to enantioenriched 1,5-benzothiazepines.

N. Kumagai, M. Shibasaki, T. Ogawa, 2012, Angewandte Chemie.

Direct catalytic enantio- and diastereoselective aldol reaction of thioamides.

M. Iwata, R. Yazaki, N. Kumagai, 2011, Journal of the American Chemical Society.

Direct catalytic asymmetric aldol reactions of thioamides: toward a stereocontrolled synthesis of 1,3-polyols.

Yuta Suzuki, M. Iwata, R. Yazaki, 2009, Journal of the American Chemical Society.

Catalytic Conjugate Additions of Alkynes

N. Kumagai, M. Shibasaki, 2014 .

Cooperative Asymmetric Catalysis Using Thioamides toward Truly Practical Organic Syntheses

N. Kumagai, M. Shibasaki, 2012 .

Cooperative activation of alkyne and thioamide functionalities; direct catalytic asymmetric conjugate addition of terminal alkynes to α,β-unsaturated thioamides.

R. Yazaki, N. Kumagai, M. Shibasaki, 2011, Chemistry, an Asian journal.

Direct catalytic asymmetric conjugate addition of terminal alkynes to alpha,beta-unsaturated thioamides.

R. Yazaki, N. Kumagai, M. Shibasaki, 2010, Journal of the American Chemical Society.

Novel Synthesis of Nitrogen Heterocycles Using Zirconium-Promoted Reductive Cyclization

M. Shibasaki, M. Mori, F. Saitoh, 1994 .

Catalytic asymmetric conjugate addition of thiols to α,β-unsaturated thioamides: expeditious access to enantioenriched 1,5-benzothiazepines.

N. Kumagai, M. Shibasaki, T. Ogawa, 2012, Angewandte Chemie.

New Asymmetric Reactions Using a Gallium Complex: A Highly Enantioselective Ring Opening of Epoxides with Thiols Catalyzed by a Gallium·Lithium·Bis(binaphthoxide) Complex

M. Shibasaki, H. Sasai, Takehiko Iida, 1997 .

Direct Catalytic Asymmetric Mannich-Type Reaction of α- and β-Fluorinated Amides.

N. Kumagai, M. Shibasaki, Fernando Arteaga Arteaga, 2015, Journal of the American Chemical Society.

Catalytic asymmetric synthesis of 3-aminooxindoles: enantiofacial selectivity switch in bimetallic vs monometallic Schiff base catalysis.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2010, Journal of the American Chemical Society.

Catalytic enantioselective alkenylation and phenylation of trifluoromethyl ketones

M. Kanai, M. Shibasaki, D. Tomita, 2006 .

Catalytic enantioselective intermolecular reductive aldol reaction to ketones

M. Kanai, M. Shibasaki, Dongbo Zhao, 2006 .

Catalytic enantioselective aldol reaction to ketones.

M. Kanai, M. Shibasaki, Dongbo Zhao, 2006, Journal of the American Chemical Society.

Enantioselective alkenylation and phenylation catalyzed by a chiral CuF complex.

M. Kanai, M. Shibasaki, D. Tomita, 2005, Journal of the American Chemical Society.

Direct catalytic aldol-type reactions using RCH2CN.

M. Kanai, S. Matsunaga, N. Kumagai, 2003, Organic letters.

A new method for the catalytic aldol reaction to ketones.

M. Kanai, M. Shibasaki, K. Oisaki, 2003, Journal of the American Chemical Society.

A general catalytic allylation using allyltrimethoxysilane.

M. Kanai, M. Shibasaki, Reiko Wada, 2002, Journal of the American Chemical Society.

Self-assembling neodymium/sodium heterobimetallic asymmetric catalyst confined in a carbon nanotube network.

N. Kumagai, M. Shibasaki, T. Ogawa, 2013, Angewandte Chemie.

Control of ring-junction stereochemistry via radical cyclization. A new construction of trans-hydrindans

M. Sodeoka, M. Shibasaki, H. Sasai, 1991 .

Enantioselective synthesis of α,α-disubstituted α-amino acids via direct catalytic asymmetric addition of acetonitrile to α-iminoesters.

N. Kumagai, M. Shibasaki, Shaoquan Lin, 2016, Organic & biomolecular chemistry.

Direct catalytic addition of alkylnitriles to aldehydes by transition-metal/NHC complexes.

N. Kumagai, M. Shibasaki, D. Sureshkumar, 2014, Chemistry.

Recent Advances in Catalytic Asymmetric C–C Bond-Forming Reactions to Ketimines Promoted by Metal-Based Catalysts

N. Kumagai, M. Shibasaki, 2015 .

New C-N-C bond formation reaction using nitrogenation-transmetallation process. Novel ring construction of indole and quinoline derivatives

M. Shibasaki, Y. Uozumi, M. Mori, 1992 .

Incorporation of molecular nitrogen into organic compounds. 2. Novel lactam synthesis by use of a combination system of carbonylation and nitrogenation

M. Shibasaki, Y. Uozumi, M. Mori, 1989 .

Ring Construction of Bicyclic g-Lactams by Use of Electrochemical Oxidation

M. Shibasaki, M. Mori, Yumiko Watanabe, 1989 .

Studies toward the total synthesis of garsubellin A: a concise synthesis of the 18-epi-tricyclic core.

M. Kanai, M. Shibasaki, H. Usuda, 2002, Organic letters.

A practical large-scale synthesis of enantiomerically pure 3-[bis(methoxycarbonyl)methyl]cyclohexanone via catalytic asymmetric Michael reaction

M. Shibasaki, T. Ohshima, Youjun Xu, 2002 .

Catalytic aldol reaction with Sm(HMDS)3 and its application for the introduction of a carbon-carbon triple bond at C-13 in prostaglandin synthesis

M. Shibasaki, H. Sasai, S. Arai, 1994 .

Practical Catalytic Asymmetric Synthesis of a Promising Drug Candidate

M. Shibasaki, 2012 .

Catalytic asymmetric hydroxylation of α-alkoxycarbonyl amides with a Pr(OiPr)3/amide-based ligand catalyst

N. Kumagai, M. Shibasaki, S. Takechi, 2011 .

Managing highly coordinative substrates in asymmetric catalysis: a catalytic asymmetric amination with a lanthanum-based ternary catalyst.

N. Kumagai, M. Shibasaki, Tomoyuki Mashiko, 2009, Journal of the American Chemical Society.

Novel synthesis of heterocycles using stannyl anion generated from Me3SiSnBu3 and F

M. Shibasaki, M. Mori, A. Hashimoto, 1993 .

Direct catalytic asymmetric Mannich-type reaction of α-sulfanyl lactones.

N. Kumagai, M. Shibasaki, S. Takechi, 2013, Organic letters.

Asymmetric Catalysis with bis(hydroxyphenyl)diamides/rare-earth metal complexes.

N. Kumagai, M. Shibasaki, 2013, Angewandte Chemie.

Linking structural dynamics and functional diversity in asymmetric catalysis.

N. Kumagai, M. Shibasaki, Akihiro Nojiri, 2009, Journal of the American Chemical Society.

Enantioselective syntheses of aeruginosin 298-A and its analogues using a catalytic asymmetric phase-transfer reaction and epoxidation.

T. Nemoto, M. Shibasaki, T. Ohshima, 2003, Journal of the American Chemical Society.

Direct Catalytic Asymmetric Mannich‐Type Reaction of Benzyl Isocyanide: Stereoselective Synthesis of 1,2‐Diarylethylenediamines

N. Kumagai, M. Shibasaki, K. Tamura, 2015 .

A heterobimetallic Ga/Yb-Schiff base complex for catalytic asymmetric alpha-addition of isocyanides to aldehydes.

S. Matsunaga, Yingjie Xu, M. Shibasaki, 2009, Journal of the American Chemical Society.

Stereochemical Studies. XXIII. Stereochemistry of the Thermal Isocyanide-Cyanide Rearrangement

N. Ohashi, M. Shibasaki, S. Terashima, 1973 .

The intramolecular thermal ene reaction route to (+)-9(O)-methano-Δ6(9α) -PGI1

Y. Ogawa, M. Shibasaki, 1984 .

A Catalytic Michael Addition of Thiols to α,β-Unsaturated Carbonyl Compounds: Asymmetric Michael Additions and Asymmetric Protonations

M. Shibasaki, T. Arai, H. Sasai, 1998 .

A Catalytic Asymmetric Strecker‐Type Reaction: Interesting Reactivity Difference between TMSCN and HCN

M. Kanai, Y. Hamashima, M. Shibasaki, 2000 .

anti-Selective direct catalytic asymmetric Mannich-type reaction of hydroxyketone providing beta-amino alcohols.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2003, Journal of the American Chemical Society.

A C4N4 Diaminopyrimidine Fluorophore.

N. Noda, N. Takizawa, N. Kumagai, 2019, Chemistry.

Asymmetric Catalysis with Heterobimetallic Compounds

M. Shibasaki, T. Arai, H. Sasai, 1997 .

Catalytic Asymmetric Synthesis of .alpha.-Amino Phosphonates Using Lanthanoid-Potassium-BINOL Complexes

M. Shibasaki, H. Sasai, S. Arai, 1995 .

Dramatic ligand effect in catalytic asymmetric reductive aldol reaction of allenic esters to ketones.

M. Kanai, M. Shibasaki, Dongbo Zhao, 2006, Journal of the American Chemical Society.

Simple, stereocontrolled synthesis of 1β-methylcarbapenem antibiotics from 3(R)-hydroxybutyric acid

M. Shibasaki, T. Iimori, 1986 .

New synthesis of 4-acetoxy-2-azetidinones by use of electrochemical oxidation

M. Shibasaki, M. Mori, K. Kagechika, 1988 .

Asymmetric synthesis of the carbapenem antibiotic (+)-PS-5

Y. Ishida, M. Shibasaki, G. Iwasaki, 1987 .

Regioselective transformation of internal alkynes to unsymmetrical ketones. Novel routes to key intermediates for the synthesis of carbapenem and carbacephem skeletons

S. Ikegami, M. Shibasaki, Atsushi Mishida, 1982 .

The First Heterobimetallic Multifunctional Asymmetric Catalyst

Y. Satow, K. Houk, M. Shibasaki, 1995 .

Asymmetric Heck Reaction−Carbanion Capture Process. Catalytic Asymmetric Total Synthesis of (−)-Δ9(12)-Capnellene

M. Shibasaki, T. Ohshima, K. Kagechika, 1996 .

Asymmetric Heck reaction: a catalytic asymmetric synthesis of the key intermediate for .DELTA.9(12)-capnellene-3.beta.,8.beta.,10.alpha.-triol and .DELTA.9(12)-capnellene-3.beta.,8.beta.,10.alpha.,14-tetrol

M. Shibasaki, K. Kagechika, 1991 .

Palladium-catalyzed asymmetric arylation of 4,7-dihydro-1,3-dioxepin. Catalytic asymmetric synthesis of γ-butyrolactone derivatives

M. Sodeoka, Y. Koga, M. Shibasaki, 1994 .

Asymmetric Heck Reaction: Catalytic Asymmetric Syntheses of Bicyclic Enones, Dienones and the Key Intermediate for Vernolepin

M. Sodeoka, M. Shibasaki, K. Kondo, 1993 .

Heterogeneous Heterobimetallic Catalysis Enabling Expeditious Access to CF3-Containing vic-Amino Alcohols.

N. Kumagai, M. Shibasaki, Tomoya Karasawa, 2018, Organic Letters.

Enantioselective Synthesis of 2,2-Disubstituted Terminal Epoxides via Catalytic Asymmetric Corey-Chaykovsky Epoxidation of Ketones

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2012, Molecules.

Asymmetric synthesis of isothiazoles through Cu catalysis: direct catalytic asymmetric conjugate addition of allyl cyanide to α,β-unsaturated thioamides.

R. Yazaki, N. Kumagai, M. Shibasaki, 2011, Angewandte Chemie.

Copper(I) alkoxide-catalyzed alkynylation of trifluoromethyl ketones.

M. Kanai, M. Shibasaki, R. Motoki, 2007, Organic letters.

Catalytic enantioselective synthesis of key intermediates for triazole antifungal agents.

Masato Suzuki, M. Kanai, M. Shibasaki, 2005, Organic letters.

Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex.

M. Shibasaki, Ryo Takita, T. Ohshima, 2005, Journal of the American Chemical Society.

Synthesis and evaluation of a new chiral ligand: 2-diphenylarsino-2′-diphenylphosphino-1,1′-binaphthyl (BINAPAs)

M. Shibasaki, S. Cho, 1998 .

Asymmetric Heck Reaction

M. Shibasaki, T. Ohshima, E. Vogl, 1997 .

Efficient Synthesis of C10 Chiron by Lewis Acid Catalyzed Rearrangement of (+)-.alpha.-3,4-Epoxycarane

M. Shibasaki, T. Arai, H. Sasai, 1995 .

Formal Total Synthesis of (-)-Dendrobine Using Zirconium-Promoted Reductive Cyclization

M. Shibasaki, M. Mori, F. Saitoh, 1994 .

Bismuth-catalyzed direct substitution of the hydroxy group in alcohols with sulfonamides, carbamates, and carboxamides.

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2007, Angewandte Chemie.

Direct catalytic asymmetric aldol-Tishchenko reaction.

Masakatsu Shibasaki, Yoshihiro Horiuchi, M. Shibasaki, 2004, Journal of the American Chemical Society.

Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes.

S. Matsunaga, M. Shibasaki, 2014, Chemical communications.

Metal/linked-BINOL complexes: Applications in direct catalytic asymmetric Mannich-type reactions

S. Matsunaga, M. Shibasaki, 2006 .

Direct catalytic asymmetric Mannich-type reactions of N-(2-hydroxyacetyl)pyrrole as an ester-equivalent donor.

S. Matsunaga, M. Shibasaki, S. Harada, 2005, Angewandte Chemie.

Ligand accelerated indium(III)-catalyzed asymmetric alkynylation of aldehydes with 2-methyl-3-butyn-2-ol as an ethyne equivalent donor.

S. Matsunaga, M. Shibasaki, Ryo Takita, 2007, Chemical communications.

Toward a Rational Design of the Assembly Structure of Polymetallic Asymmetric Catalysts: Design, Synthesis, and Evaluation of New Chiral Ligands for Catalytic Asymmetric Cyanation Reactions.

M. Kanai, M. Shibasaki, M. Shiro, 2007 .

Catalytic enantioselective Strecker reaction of ketoimines.

Masato Suzuki, M. Kanai, M. Shibasaki, 2003, Journal of the American Chemical Society.

Novel synthesis of nitrogen heterocycles using zirconium-promoted reductive coupling. Formal total synthesis of dendrobine

M. Shibasaki, M. Mori, N. Uesaka, 1992 .

Catalytic asymmetric addition of diphenylphosphine oxide to cyclic imines

M. Kanai, M. Shibasaki, S. Harwood, 1999 .

A New and Highly Efficient Asymmetric Route to Cyclic α-Amino Phosphonates: The First Catalytic Enantioselective Hydrophosphonylation of Cyclic Imines Catalyzed by Chiral Heterobimetallic Lanthanoid Complexes

H. Gröger, M. Shibasaki, H. Sasai, 1998 .

A facile pathway to enantiomerically enriched 3-hydroxy-2-oxindoles: asymmetric intramolecular arylation of α-keto amides catalyzed by a palladium-DifluorPhos complex.

M. Kanai, M. Shibasaki, L. Yin, 2011, Angewandte Chemie.

Catalytic asymmetric synthesis of β-hydroxy-α-amino acid esters by direct aldol reaction of glycinate Schiff bases

M. Shibasaki, N. Yoshikawa, 2002 .

Stereodivergent catalytic doubly diastereoselective nitroaldol reactions using heterobimetallic complexes.

S. Matsunaga, M. Shibasaki, Y. Kato, 2008, Organic letters.

A bench-stable homodinuclear Ni2-Schiff base complex for catalytic asymmetric synthesis of alpha-tetrasubstituted anti-alpha,beta-diamino acid surrogates.

Masakatsu Shibasaki, Shigeki Matsunaga, S. Matsunaga, 2008, Journal of the American Chemical Society.

Catalytic Asymmetric Syntheses of ICI-199441 and CP-99994 Using Nitro-Mannich Reaction

Masakatsu Shibasaki, M. Shibasaki, Ken‐ichi Yamada, 2002 .

Nucleophile generation via decarboxylation: asymmetric construction of contiguous trisubstituted and quaternary stereocenters through a Cu(I)-catalyzed decarboxylative Mannich-type reaction.

M. Kanai, M. Shibasaki, L. Yin, 2009, Journal of the American Chemical Society.

Direct catalytic asymmetric Michael reaction of hydroxyketones: asymmetric Zn catalysis with a Et2Zn/linked-BINOL complex.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2003, Journal of the American Chemical Society.

Direct Asymmetric α-Allylation of Ketones with Allylic Alcohols via Pd/Enamine Cooperative Function

N. Kumagai, M. Shibasaki, S. Yasuda, 2012 .

Catalytic Asymmetric 1,4-Additions of β-Keto Esters to Nitroalkenes Promoted by a Bifunctional Homobimetallic Co2-Schiff Base Complex

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2010, Molecules.

anti-Selective catalytic asymmetric nitroaldol reaction via a heterobimetallic heterogeneous catalyst.

N. Kumagai, M. Shibasaki, Makoto Kobayashi, 2009, Journal of the American Chemical Society.

A homodinuclear Mn(III)2-Schiff base complex for catalytic asymmetric 1,4-additions of oxindoles to nitroalkenes.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2009, Journal of the American Chemical Society.

A stable homodinuclear biscobalt(III)-Schiff base complex for catalytic asymmetric 1,4-addition reactions of beta-keto esters to alkynones.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2009, Angewandte Chemie.

Strategies for Constructing Diverse Chiral Environments in Multimetallic Bifunctional Asymmetric Catalysis

S. Matsunaga, N. Kumagai, M. Shibasaki, 2008 .

A heterobimetallic Pd/La/Schiff base complex for anti-selective catalytic asymmetric nitroaldol reactions and applications to short syntheses of beta-adrenoceptor agonists.

S. Matsunaga, M. Shibasaki, Shinya Handa, 2008, Angewandte Chemie.

Key role of the Lewis base position in asymmetric bifunctional catalysis: design and evaluation of a new ligand for chiral polymetallic catalysts.

M. Kanai, M. Shibasaki, M. Shiro, 2006, Journal of the American Chemical Society.

Assembly state of catalytic modules as chiral switches in asymmetric Strecker amino acid synthesis.

M. Kanai, M. Kawano, M. Shibasaki, 2006, Journal of the American Chemical Society.

Catalytic enantioselective desymmetrization of meso-N-acylaziridines with TMSCN.

M. Kanai, M. Shibasaki, Ikuo Fujimori, 2005, Journal of the American Chemical Society.

Heterobimetallic catalysis in asymmetric 1,4-addition of O-alkylhydroxylamine to enones.

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2003, Journal of the American Chemical Society.

Lanthanide complexes in multifunctional asymmetric catalysis.

Masakatsu Shibasaki, M. Shibasaki, Naoki Yoshikawa, 2002, Chemical reviews.

Novel heterobimetallic asymmetric catalysis directing toward enzymatic function

M. Shibasaki, T. Arai, H. Sasai, 2000 .

WATER VS. DESICCANT. IMPROVEMENT OF YB-BINOL COMPLEX CATALYZED ENANTIOSELECTIVE EPOXIDATION OF ENONES

M. Shibasaki, T. Arai, H. Sasai, 1998 .

REGIOSELECTIVE CATALYTIC ASYMMETRIC REACTION OF HORNER-WADSWORTH-EMMONS REAGENTS WITH ENONES : THE ODYSSEY OF CHIRAL ALUMINUM CATALYSTS

M. Shibasaki, T. Arai, H. Sasai, 1998 .

Asymmetric Syn-Selective Vinylogous Addition of Butenolides to Chromones via Al-Li-BINOL Catalysis.

M. Shibasaki, Takumi Watanabe, H. Noda, 2023, Journal of Organic Chemistry.

Publication List by Masakatsu Shibasaki

M. Shibasaki, 2017 .

Catalytic asymmetric synthesis of CPZEN-45

Toshifumi Takeuchi, M. Shibasaki, Takumi Watanabe, 2016 .

Direct catalytic asymmetric intramolecular conjugate addition of thioamide to α,β-unsaturated esters.

Yuta Suzuki, R. Yazaki, N. Kumagai, 2011, Chemistry.

Direct catalytic asymmetric aldol reaction of beta-keto esters with formaldehyde promoted by a dinuclear Ni2-Schiff base complex.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2009, Chemical Communications.

Chiral-catalyst-based convergent synthesis of HIV protease inhibitor GRL-06579A.

S. Matsunaga, M. Shibasaki, H. Mihara, 2008, Chemistry, an Asian journal.

syn-Selective Direct Catalytic Asymmetric Mannich-Type Reactions of Aromatic and Heteroaromatic Hydroxy Ketones Promoted by Y[N(SiMe3)2]3/Linked-BINOL Complexes

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2006 .

Direct catalytic asymmetric Mannich-type reactions of isomerizable aliphatic imines: chemoselective enolate formation from a hydroxyketone by a Zn-catalyst

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2006 .

Design and application of linked-BINOL chiral ligands in bifunctional asymmetric catalysis.

Masakatsu Shibasaki, Shigeki Matsunaga, S. Matsunaga, 2006, Chemical Society reviews.

syn-selective direct catalytic asymmetric Mannich-type reactions of hydroxyketones using Y{N(SiMe3)2}3/linked-BINOL complexes.

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2005, Organic letters.

Direct catalytic asymmetric aldol reaction of hydroxyketones: asymmetric Zn catalysis with a Et(2)Zn/linked-BINOL complex.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2003, Journal of the American Chemical Society.

Asymmetric synthesis of dihydropyranones from ynones by sequential copper(I)-catalyzed direct aldol and silver(I)-catalyzed oxy-Michael reactions.

M. Kanai, M. Shibasaki, Shi‐Liang Shi, 2012, Angewandte Chemie.

Zirconium alkoxides in catalysis.

M. Kanai, M. Shibasaki, S. Yamasaki, 2001, Chemistry.

Solvent-Dependent Enantiodivergence in anti-Selective Catalytic Asymmetric Nitroaldol Reactions.

N. Kumagai, M. Shibasaki, A. Saito, 2019, Organic letters.

anti-Selective Catalytic Asymmetric Nitroaldol Reaction of α-Keto Esters: Intriguing Solvent Effect, Flow Reaction, and Synthesis of Active Pharmaceutical Ingredients.

N. Kumagai, M. Shibasaki, R. Oriez, 2018, Journal of the American Chemical Society.

Preparation of Nd/Na heterogeneous catalyst from bench-stable and inexpensive Nd salt for an anti-selective catalytic asymmetric nitroaldol reaction

N. Kumagai, M. Shibasaki, A. Saito, 2016 .

Self-assembled asymmetric catalyst engaged in a continuous-flow platform: an anti-selective catalytic asymmetric nitroaldol reaction.

N. Kumagai, M. Shibasaki, Kazuki Hashimoto, 2014, Organic letters.

A modified preparation procedure for carbon nanotube-confined Nd/Na heterobimetallic catalyst for anti-selective catalytic asymmetric nitroaldol reactions.

N. Kumagai, M. Shibasaki, D. Sureshkumar, 2013, The Journal of organic chemistry.

Recent advances in direct catalytic asymmetric transformations under proton-transfer conditions.

N. Kumagai, M. Shibasaki, 2011, Angewandte Chemie.

A catalytic asymmetric anti-selective nitroaldol reaction with a neodymium–sodium heterobimetallic complex

N. Kumagai, M. Shibasaki, Tatsuya Nitabaru, 2008 .

Direct catalytic asymmetric Mannich-type reaction of hydroxyketone using a Et2Zn/linked-BINOL complex: synthesis of either anti- or syn-beta-amino alcohols.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2004, Journal of the American Chemical Society.

DIRECT ASYMMETRIC α-ALLYLATION OF KETONES WITH ALLYLIC ALCOHOLS VIA Pd/ENAMINE COOPERATIVE FUNCTION (Dedicated to Professor Dr. Ei-ichi Negishi on the occasion of his 77th birthday)

N. Kumagai, M. Shibasaki, S. Yasuda, 2012 .

La/Ag heterobimetallic cooperative catalysis: a catalytic asymmetric Conia-ene reaction.

N. Kumagai, M. Shibasaki, Akinobu Matsuzawa, 2011, Angewandte Chemie.

Asymmetric flow catalysis: Mix-and-go solid-phase Nd/Na catalyst for expeditious enantioselective access to a key intermediate of AZD7594

N. Kumagai, M. Shibasaki, Akihito Nonoyama, 2017 .

Recent Advances in Rare Earth Metal Asymmetric Catalysis Toward Practical Synthesis of Therapeutics

N. Kumagai, M. Shibasaki, 2017 .

A NEW GLYCOSYLATION PROCEDURE UTILIZING RARE EARTH SALTS AND GLYCOSYL FLUORIDES, WITH OR WITHOUT THE REQUIREMENT OF LEWIS ACIDS

M. Shibasaki, H. Sasai, Won-Sup Kim, 1995 .

The synthesis of a new palladacycle catalyst. Development of a high performance catalyst for Heck reactions

M. Shibasaki, K. Yamaguchi, F. Miyazaki, 1999 .

Catalytic enantioselective Strecker reaction of ketoimines.

Masato Suzuki, M. Kanai, M. Shibasaki, 2003, Journal of the American Chemical Society.

Enantioselective Strecker-type reaction promoted by polymer-supported bifunctional catalyst

M. Kanai, S. Matsunaga, M. Shibasaki, 2001 .

General and practical catalytic enantioselective Strecker reaction of ketoimines: significant improvement through catalyst tuning by protic additives

Masato Suzuki, M. Kanai, M. Shibasaki, 2004 .

Recent progress in asymmetric two-center catalysis.

M. Kanai, M. Shibasaki, K. Funabashi, 2002, Chemical communications.

A Catalytic Asymmetric Strecker-Type Reaction: Interesting Reactivity Difference Between Tms-CN and HCN.

M. Kanai, Y. Hamashima, M. Shibasaki, 2000 .

A New Bifunctional Asymmetric Catalysis: An Efficient Catalytic Asymmetric Cyanosilylation of Aldehydes

Y. Hamashima, M. Shibasaki, D. Sawada, 1999 .

Multifunctional asymmetric catalysis.

M. Kanai, M. Shibasaki, 2001, Chemical & pharmaceutical bulletin.

Enantioselective synthesis of α-hydroxy phosphonates using the LaLi3tris(binaphthoxide) catalyst (LLB), prepared by an improved method

M. Shibasaki, T. Arai, H. Sasai, 1997 .

Catalytic Asymmetric Synthesis of alpha-Hydroxy Phosphonates Using the Al-Li-BINOL Complex.

M. Shibasaki, T. Arai, H. Sasai, 1996, The Journal of organic chemistry.

Bismuth-catalyzed intermolecular hydroamination of 1,3-dienes with carbamates, sulfonamides, and carboxamides.

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2006, Journal of the American Chemical Society.

Direct catalytic asymmetric vinylogous Mannich-type reaction of γ-butenolides with ketimines.

N. Kumagai, M. Shibasaki, L. Yin, 2013, Angewandte Chemie.

Catalytic enantioselective Mannich-type reactions of ketoimines.

M. Kanai, M. Shibasaki, Yutaka Suto, 2007, Journal of the American Chemical Society.

Identification of modular chiral bisphosphines effective for Cu(i)-catalyzed asymmetric allylation and propargylation of ketones.

M. Kanai, M. Shibasaki, K. Oisaki, 2010, Journal of the American Chemical Society.

Catalytic asymmetric nitroaldol reaction: An efficient synthesis of (S) propranolol using the lanthanum binaphthol complex

M. Shibasaki, H. Sasai, Takeyuki Suzuki, 1993 .

Bismuth- and hafnium-catalyzed hydroamination of vinyl arenes with sulfonamides, carbamates, and carboxamides.

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2007, Chemistry, an Asian journal.

The Asymmetric Synthesis of Cyclopentane Derivatives by Palladium-Catalyzed Coupling of Prochiral Alkylboron Compounds.

M. Shibasaki, S. Cho, 1999 .

Direct Catalytic Asymmetric Aldol Reaction

Yoichi M. A. Yamada, M. Shibasaki, H. Sasai, 1999 .

Direct catalytic asymmetric aldol reactions promoted by a novel barium complex

Yoichi M. A. Yamada, M. Shibasaki, 1998 .

Catalytic Enantioselective Addition of Diethyl Phosphite to N -Thiophosphinoyl Ketimines: Preparation of (R )-Diethyl (1-Amino-1-phenylethyl)phosphonate

N. Kumagai, M. Shibasaki, Shaoquan Lin, 2018, Organic Syntheses.

Catalytic asymmetric hydrophosphonylation of ketimines.

N. Kumagai, M. Shibasaki, Youmei Bao, 2013, Journal of the American Chemical Society.

Catalytic asymmetric ring-opening of meso-aziridines with malonates under heterodinuclear rare earth metal Schiff base catalysis.

M. Kanai, S. Matsunaga, Yingjie Xu, 2011, Journal of the American Chemical Society.

Direct catalytic enantio- and diastereoselective aldol reaction using a Zn-Zn-linked-BINOL complex: a practical synthesis of syn-1,2-diols.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2001, Organic letters.

Asymmetric Catalysis with Chiral Lanthanoid Complexes

M. Shibasaki, H. Sasai, 2007 .

Catalytic Asymmetric Michael Reactions Promoted by a Lithium-Free Lanthanum-BINOL Complex

M. Shibasaki, T. Arai, H. Sasai, 1994 .

Effects of rare earth metals on the catalytic asymmetric nitroaldol reaction

M. Shibasaki, H. Sasai, S. Arai, 1993 .

An efficient synthesis of bicyclic amidines by intramolecular cyclization.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2004, Angewandte Chemie.

Catalytic asymmetric intramolecular cyclopropanation of enol silyl ether. Synthesis of the phorbol CD-ring skeleton

M. Sodeoka, Hiroshi Tomiyama, M. Shibasaki, 1996 .

Nucleophilic and Electrophilic Activation of Non-Heteroaromatic Amides in Atom-Economical Asymmetric Catalysis.

N. Kumagai, M. Shibasaki, 2016, Chemistry.

Electrophilic Activation of α,β-Unsaturated Amides: Catalytic Asymmetric Vinylogous Conjugate Addition of Unsaturated γ-Butyrolactones.

N. Kumagai, M. Shibasaki, Ming Zhang, 2016, Chemistry.

Direct Catalytic Asymmetric Conjugate Addition of Saturated and Unsaturated Thioamides.

N. Kumagai, M. Shibasaki, A. Saito, 2015, Organic letters.

Regiodivergent kinetic resolution of terminal and internal rac-aziridines with malonates under dinuclear Schiff base catalysis.

M. Kanai, K. Kaneko, S. Matsunaga, 2014, Journal of the American Chemical Society.

Catalytic asymmetric synthesis of 2,2-disubstituted oxetanes from ketones by using a one-pot sequential addition of sulfur ylide.

S. Matsunaga, M. Shibasaki, G. Lu, 2009, Angewandte Chemie.

Asymmetric heck reaction of alkenyl iodides in the presence of silver salts. Catalytic asymmetric synthesis of decalin and functionalized indolizidine derivatives

M. Sodeoka, M. Shibasaki, Y. Sato, 1994 .

Catalytic asymmetric total synthesis of (+)-lactacystin.

M. Kanai, M. Shibasaki, K. Sasaki, 2006, The Journal of organic chemistry.

Short synthesis of (+)-cylindricine C by using a catalytic asymmetric Michael reaction with a two-center organocatalyst.

S. Sakuraba, M. Shibasaki, T. Ohshima, 2006, Angewandte Chemie.

Catalytic asymmetric synthesis of spirooxindoles by a mannich-type reaction of isothiocyanato oxindoles.

M. Kanai, S. Matsunaga, M. Shibasaki, 2012, Angewandte Chemie.

Stereodivergent direct catalytic asymmetric Mannich-type reactions of α-isothiocyanato ester with ketimines.

S. Matsunaga, M. Shibasaki, G. Lu, 2011, Angewandte Chemie.

Construction of contiguous tetrasubstituted chiral carbon stereocenters via direct catalytic asymmetric aldol reaction of alpha-isothiocyanato esters with ketones.

S. Matsunaga, M. Shibasaki, G. Lu, 2009, Journal of the American Chemical Society.

Enantioselective synthesis of SM-130686 based on the development of asymmetric Cu(I)F catalysis to access 2-oxindoles containing a tetrasubstituted carbon.

M. Kanai, K. Yamatsugu, M. Shibasaki, 2009, Journal of the American Chemical Society.

A direct,stereocontrolled total synthesis of the 9,11-azo analogue of the prostaglandin endoperoxide, PGH2.

E. Corey, M. Shibasaki, K. Narasaka, 1976, Journal of the American Chemical Society.

Catalytic asymmetric epoxidation of α,β-unsaturated amides: Efficient synthesis of β-aryl α-hydroxy amides using a one-pot tandem catalytic asymmetric epoxidation - Pd-catalyzed epoxide opening process

T. Nemoto, M. Shibasaki, H. Kakei, 2002 .

Direct catalytic asymmetric vinylogous conjugate addition of unsaturated butyrolactones to α,β-unsaturated thioamides.

N. Kumagai, M. Shibasaki, Shaoquan Lin, 2014, Angewandte Chemie.

Synthesis of 2-O-(3-O-carbamoyl-α-d-mannopyranosyl)-l-gulopyranose: Sugar moiety of antitumor antibiotic bleomycin

Takeshi Yoshizawa, Masakatsu Shibasaki, M. Tomita, 1997 .

Stimulating Concepts in Chemistry

J. F. Stoddart, F. Vögtle, M. Shibasaki, 2000 .

Direct catalytic asymmetric alkynylation of ketoimines.

R. Yazaki, N. Kumagai, M. Shibasaki, 2013, Organic letters.

Use of copper(I) trifluoromethanesulfonate in .beta.-lactam synthesis

M. Shibasaki, N. Miyachi, F. Kanda, 1989 .

Catalytic enantioselective desymmetrization of meso-glutaric anhydrides using a stable Ni2-Schiff base catalyst.

M. Shibasaki, Takumi Watanabe, P. Gopinath, 2012, Organic letters.

Regio- and Stereoselective Functionalization of an Optically Active Tetrahydroindolizine Derivative. Catalytic Asymmetric Syntheses of Lentiginosine, 1,2-Diepilentiginosine, and Gephyrotoxin 209D

M. Sodeoka, M. Shibasaki, H. Sasai, 1995 .

An enantioselective formal synthesis of 4-demethoxydaunomycin using the catalytic asymmetric ring opening reaction of meso-epoxide with p-anisidine

M. Shibasaki, A. Sekine, T. Ohshima, 2002 .

A New Multifunctional Heterobimetallic Asymmetric Catalyst for Michael Additions and Tandem Michael–Aldol Reactions

M. Shibasaki, T. Arai, H. Sasai, 1996 .

Catalytic asymmetric phase-transfer Michael reaction and Mannich-type reaction of glycine Schiff bases with tartrate-derived diammonium salts.

M. Shibasaki, T. Ohshima, H. Mihara, 2007, Chemistry, an Asian journal.

Catalytic asymmetric phase-transfer reactions using tartrate-derived asymmetric two-center organocatalysts

M. Shibasaki, T. Ohshima, Y. Fukuta, 2004 .

syn-Selective catalytic asymmetric 1,4-addition of alpha-ketoanilides to nitroalkenes under dinuclear nickel catalysis.

S. Matsunaga, Yingjie Xu, M. Shibasaki, 2010, Organic letters.

Catalytic asymmetric Michael reactions of dibenzyl malonate to α,β-unsaturated N-acylpyrroles using a La(O-iPr)3/Ph-linked-BINOL complex

S. Matsunaga, So-Young Park, M. Shibasaki, 2007 .

Catalytic asymmetric amination of N-nonsubstituted α-alkoxycarbonyl amides: concise enantioselective synthesis of mycestericin F and G.

N. Kumagai, M. Shibasaki, F. Berhal, 2011, Chemistry.

Synthesis and antiviral activity of formycin derivatives with anti-influenza virus activity.

N. Takizawa, M. Shibasaki, M. Igarashi, 2022, Bioorganic & medicinal chemistry.

Use of Copper(I) Trifluoromethanesulfonate in β-Lactam Synthesis.

M. Shibasaki, N. Miyachi, F. Kanda, 1990 .

Catalytic nucleophilic activation of acetonitrile via a cooperative catalysis of cationic Ru complex, DBU, and NaPF6

S. Matsunaga, N. Kumagai, M. Shibasaki, 2007 .

A catalytic enantioselective conjugate addition of cyanide to enones.

M. Kanai, M. Shibasaki, Yuta Tanaka, 2008, Journal of the American Chemical Society.

Catalytic Enantioselective Conjugate Addition of Cyanide to α,β-Unsaturated N-Acylpyrroles

M. Kanai, M. Shibasaki, K. Sasaki, 2005 .

Asymmetric catalysis via dynamic substrate/ligand/rare earth metal conglomerate.

N. Kumagai, M. Shibasaki, Akihiro Nojiri, 2008, Journal of the American Chemical Society.

Lanthanide Lewis Acids Catalysis

M. Shibasaki, Ken‐ichi Yamada, N. Yoshikawa, 2008 .

Direct Catalytic Asymmetric Mannich-Type Reaction of Alkylamides.

N. Kumagai, M. Shibasaki, Bo Sun, 2009, Organic letters.

Intermediate as catalyst: catalytic asymmetric conjugate addition of nitroalkanes to α,β-unsaturated thioamides.

R. Yazaki, N. Kumagai, M. Shibasaki, 2012, Organic letters.

β-Selective glycosylation with α-mannosyl fluorides using tin(II) triflate and lanthanum perchlorate

M. Shibasaki, H. Sasai, Won-Sup Kim, 1996 .

RARE EARTH SALTS PROMOTED GLYCOSIDATION OF GLYCOSYL FLUORIDES

M. Shibasaki, H. Sasai, Won-Sup Kim, 1996 .

Rare earth perchlorate catalyzed glycosidation of glycosyl fluorides with trimethylsilyl ethers

M. Shibasaki, H. Sasai, Won-Sup Kim, 1995 .

Enantioselective Total Synthesis of (−)-Strychnine Using the Catalytic Asymmetric Michael Reaction and Tandem Cyclization

D. Zhong, M. Shibasaki, Ryo Takita, 2002 .

A novel antileukemic sesquiterpene lactone. Synthesis of racemic eriolanin

M. Shibasaki, Y. Ban, T. Wakamatsu, 1988 .

Selective removal of tetrahydropyranyl ethers in the presence of t-butyldimethylsilyl ethers

Y. Ogawa, M. Shibasaki, 1984 .

Power of cooperativity : Lewis acid-lewis base bifunctional asymmetric catalysis

M. Kanai, M. Shibasaki, Nobuki Kato, 2005 .

Catalytic asymmetric cyano-ethoxycarbonylation reaction of aldehydes using a YLi3 tris(binaphthoxide) (YLB) complex: mechanism and roles of achiral additives.

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2005, Journal of the American Chemical Society.

An asymmetric cyanation reaction and sequential asymmetric cyanation-nitroaldol reaction using a [YLi(3)[tris(binaphthoxide)]] single catalyst component: catalyst tuning with achiral additives.

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2002, Angewandte Chemie.

Catalytic generation of α-CF3 enolate: direct catalytic asymmetric Mannich-type reaction of α-CF3 amide.

N. Kumagai, M. Shibasaki, L. Yin, 2014, Journal of the American Chemical Society.

Trichloromethyl ketones as synthetically versatile donors: application in direct catalytic mannich-type reactions and the stereoselective synthesis of azetidines.

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2006, Angewandte Chemie.

Chiral gamma-amino amide synthesis by heterobimetallic lanthanum/lithium/Pybox-catalyzed direct asymmetric mannich-type reactions of alpha-keto anilides.

S. Matsunaga, M. Shibasaki, G. Lu, 2008, Angewandte Chemie.

α-Halo Amides as Competent Latent Enolates: Direct Catalytic Asymmetric Mannich-Type Reaction.

N. Kumagai, M. Shibasaki, Bo Sun, 2017, Journal of the American Chemical Society.

Direct anti-selective catalytic asymmetric Mannich-type reactions of alpha-ketoanilides for the synthesis of gamma-amino amides and azetidine-2-amides.

S. Matsunaga, Yingjie Xu, M. Shibasaki, 2009, Angewandte Chemie.

Direct catalytic asymmetric Mannich reaction of unmodified ketones: Cooperative catalysis of an AlLibis(binaphthoxide) complex and La(OTf)3·nH2O

M. Shibasaki, S. Yamasaki, Takehiko Iida, 1999 .

A new entry in catalytic alkynylation of aldehydes and ketones: dual activation of soft nucleophiles and hard electrophiles by an indium(III) catalyst.

M. Shibasaki, Ryo Takita, T. Ohshima, 2005, Organic letters.

Catalytic chemical transformations with conformationally dynamic catalytic systems

N. Kumagai, M. Shibasaki, 2013 .

A catalytic enantioselective reaction using a C2-symmetric disulfonamide as a chiral ligand: Simmons-Smith cyclopropanation of allylic alcohols by the Et2Zn-CH2I2-disulfonamide system

Hideyo Takahashi, M. Ohno, M. Shibasaki, 1992 .

Synthesis and crystal structure of a new c2-symmetric chiral bis-sulfoxide ligand and its palladium(ii) complex

M. Sodeoka, M. Shibasaki, K. Aoe, 1995 .

A catalytic asymmetric synthesis of cis-decalin derivatives via π-allylpalladium intermediates

M. Sodeoka, M. Shibasaki, Y. Nishikimi, 1992 .

Multicenter strategy for the development of catalytic enantioselective nucleophilic alkylation of ketones: Me2Zn addition to alpha-ketoesters.

M. Kanai, M. Shibasaki, K. Funabashi, 2003, Angewandte Chemie.

Catalytic asymmetric aldol reaction of ketones and aldehydes using chiral calcium alkoxides

Y. Matsuo, R. Noyori, M. Shibasaki, 2001 .

Catalytic asymmetric epoxidation of α,β-unsaturated carboxylic acid imidazolides and amides by lanthanide–BINOL complexes

T. Nemoto, M. Shibasaki, H. Kakei, 2003 .

The first tandem inter-intramolecular catalytic asymmetric nitroaldol reaction utilizing a LnLi3tris((R)-binaphthoxide) complex ((R)-LnLB) (Ln: Lanthanoid)

Yoichi M. A. Yamada, M. Shibasaki, H. Sasai, 1997 .

Catalytic enantioselective alkylative aldol reaction: efficient multicomponent assembly of dialkylzincs, allenic esters, and ketones toward highly functionalized delta-lactones with tetrasubstituted chiral centers.

M. Kanai, M. Shibasaki, Dongbo Zhao, 2007, Journal of the American Chemical Society.

Stable, Storable, and Reusable Asymmetric Catalyst: A Novel La-linked-BINOL Complex for the Catalytic Asymmetric Michael Reaction

S. Matsunaga, M. Shibasaki, A. Sekine, 2000 .

Enantioselective 1,4-addition of unmodified ketone catalyzed by a bimetallic Zn-Zn-linked-BINOL complex.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2001, Organic letters.

An enantioselective synthesis of voriconazole.

N. Kumagai, M. Shibasaki, K. Tamura, 2013, The Journal of organic chemistry.

Catalyst-controlled asymmetric synthesis of fostriecin and 8-epi-fostriecin.

M. Kanai, M. Shibasaki, S. Tamura, 2005, Journal of the American Chemical Society.

Catalytic asymmetric synthesis of (S)-oxybutynin and a versatile intermediate for antimuscarinic agents

Masato Suzuki, M. Kanai, M. Shibasaki, 2004 .

Efficient Two-Step Conversion of α,β-Unsaturated Aldehydes to Optically Active γ-Oxy-α,β-unsaturated Nitriles and Its Application to the Total Synthesis of (+)-Patulolide C

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2003 .

Formal catalytic asymmetric total synthesis of fostriecin.

Masakatsu Shibasaki, M. Kanai, M. Shibasaki, 2003, Organic letters.

A practical synthesis of (S)-oxybutynin

Masato Suzuki, M. Kanai, M. Shibasaki, 2002 .

Switching enantiofacial selectivities using one chiral source: catalytic enantioselective synthesis of the key intermediate for (20S)-camptothecin family by (S)-selective cyanosilylation of ketones.

M. Kanai, Y. Hamashima, M. Shibasaki, 2001, Journal of the American Chemical Society.

Catalytic enantioselective cyanosilylation of ketones: improvement of enantioselectivity and catalyst turn-over by ligand tuning

M. Kanai, Y. Hamashima, M. Shibasaki, 2001 .

Enantioselective Total Synthesis of Epothilones A and B Using Multifunctional Asymmetric Catalysis

M. Shibasaki, D. Sawada, and Motomu Kanai, 2000 .

Catalytic Enantioselective Cyanosilylation of Ketones

Y. Hamashima, M. Shibasaki, and Motomu Kanai, 2000 .

A New Bifunctional Asymmetric Catalysis: An Efficient Catalytic Asymmetric Cyanosilylation of Aldehydes.

M. Kanai, Y. Hamashima, M. Shibasaki, 1999 .

Catalytic asymmetric Michael reactions promoted by the La-Na-BINOL complex (LSB). Enantioface selection on Michael donors

M. Shibasaki, T. Arai, H. Sasai, 1996 .

Linked‐BINOL: An Approach towards Practical Asymmetric Multifunctional Catalysis

S. Matsunaga, M. Shibasaki, T. Ohshima, 2002 .

Highly enantioselective cyanosilylation of aldehydes catalyzed by a Lewis acid–Lewis base bifunctional catalyst

M. Kanai, Y. Hamashima, M. Shibasaki, 2001 .

Asymmetric Reissert-type Reaction Promoted by Bifunctional Catalyst

M. Shibasaki, M. Takamura, K. Funabashi, 2000 .

Direct Catalytic Asymmetric Aldol Reactions Promoted by Novel Heterobimetallic Catalysts Possessing Strong Broensted Base: A New Strategy for the Development of Lewis Acid—Broensted Base Bifunctional Catalysts.

M. Shibasaki, N. Yoshikawa, 2001 .

Design of a new bifunctional asymmetric catalyst from carbohydrates: application to catalytic asymmetric cyanosilylation of aldehydes and acetophenone

M. Kanai, Y. Hamashima, M. Shibasaki, 2000 .

Highly regioselective synthesis of cyclic enol silyl ethers using ring-closing metathesis

M. Shibasaki, T. Ohshima, A. Okada, 2001 .

Z-Enolate Geometry in the Thioamide Aldol Reaction Illuminated by the 7-Azaindoline Auxiliary.

N. Kumagai, M. Shibasaki, Roman Pluta, 2019, Organic letters.

Asymmetric Synthesis Using Thioamides

N. Kumagai, M. Shibasaki, 2019, Chemistry of Thioamides.

Direct enolization chemistry of 7-azaindoline amides: A case study of bis(tetrahydrophosphole)-type ligands

N. Kumagai, M. Shibasaki, Z. Li, 2018, Tetrahedron.

Direct Catalytic Asymmetric Aldol Reaction of α-Alkylamides.

Toshifumi Takeuchi, N. Kumagai, M. Shibasaki, 2017, Organic letters.

Anti-selective direct catalytic asymmetric aldol reaction of thiolactams.

Yuji Kawato, M. Iwata, N. Kumagai, 2012, Organic letters.

A simplified catalytic system for direct catalytic asymmetric aldol reaction of thioamides; application to an enantioselective synthesis of atorvastatin

Yuji Kawato, M. Iwata, R. Yazaki, 2011 .

Catalytic asymmetric synthesis of a versatile intermediate for diterpene syntheses. Regioselective olefin insertion in asymmetric Heck reactions

M. Sodeoka, M. Shibasaki, K. Kondo, 1995 .

Enantioselective construction of quaternary stereocenter through a Reissert-type reaction catalyzed by an electronically tuned bifunctional catalyst: efficient synthesis of various biologically significant compounds.

M. Kanai, M. Shibasaki, H. Ratni, 2001, Journal of the American Chemical Society.

Lanthanum aryloxide/pybox-catalyzed direct asymmetric Mannich-type reactions using a trichloromethyl ketone as a propionate equivalent donor.

S. Matsunaga, M. Shibasaki, G. Lu, 2007, Journal of the American Chemical Society.

Direct catalytic asymmetric alkynylation of ketoimines.

R. Yazaki, N. Kumagai, M. Shibasaki, 2013, Organic letters.

An improved lanthanum catalyst system for asymmetric amination: toward a practical asymmetric synthesis of AS-3201 (Ranirestat).

N. Kumagai, M. Shibasaki, Tomoyuki Mashiko, 2008, Organic letters.

En route to an efficient catalytic asymmetric synthesis of AS-3201.

Y. Fujiwara, N. Kumagai, M. Shibasaki, 2007, Journal of the American Chemical Society.

Catalytic Asymmetric Synthesis of α‐Amino Phosphonates Using Lanthanoid‐Potassium‐BINOL Complexes.

M. Shibasaki, H. Sasai, S. Arai, 1996 .

Catalytic Asymmetric Epoxidation of α,β-Unsaturated Ketones Promoted by Lanthanoid Complexes

Masakatsu Shibasaki, M. Shibasaki, Masahiro Bougauchi, 1997 .

Basic character of rare earth metal alkoxides. Utilization in catalytic C-C bond-forming reactions and catalytic asymmetric nitroaldol reactions

Masakatsu Shibasaki, M. Shibasaki, Takayoshi Arai, 1992 .

Catalytic asymmetric epoxidation of enones using La-BINOL-triphenylarsine oxide complex: structural determination of the asymmetric catalyst.

T. Nemoto, M. Shibasaki, K. Yamaguchi, 2001, Journal of the American Chemical Society.

Enantioselective total syntheses of novel PKC activator (+)-decursin and its derivatives using catalytic asymmetric epoxidation of an enone

T. Nemoto, M. Shibasaki, T. Ohshima, 2000 .

The First Catalytic Enantioselective Synthesis of cis-Epoxyketones from cis-Enones

M. Shibasaki, T. Arai, H. Sasai, 1998 .

Catalytic Asymmetric Aldol Reaction via Chiral Pd(II) Enolate in Wet DMF

M. Sodeoka, M. Shibasaki, K. Ohrai, 1995 .

Catalytic asymmetric Michael addition of nitromethane to enones controlled by (R)-LPB

M. Kanai, M. Shibasaki, T. Arai, 1998 .

A Catalytic Asymmetric Synthesis of Tubifolidine.

M. Shibasaki, T. Arai, H. Sasai, 1998, The Journal of organic chemistry.

Enantioselective Ring Opening of Epoxides with 4-Methoxyphenol Catalyzed by Gallium Heterobimetallic Complexes: An Efficient Method for the Synthesis of Optically Active 1,2-Diol Monoethers.

S. Matsunaga, M. Shibasaki, H. Woo, 1998, Angewandte Chemie.

A Catalytic Asymmetric Synthesis of 11-Deoxy-PGF1α Using ALB, a Heterobimetallic Multifunctional Asymmetric Complex

M. Shibasaki, T. Arai, H. Sasai, 1998 .

Direct catalytic asymmetric aldol reaction: synthesis of either syn- or anti-alpha,beta-dihydroxy ketones.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2001, Journal of the American Chemical Society.

Superoxide ion as a synthetically useful oxygen nucleophile

E. Corey, K. Nicolaou, M. Shibasaki, 1975 .

Challenge toward structural complexity using asymmetric catalysis: target-oriented development of catalytic enantioselective Diels-Alder reaction.

M. Kanai, M. Shibasaki, H. Usuda, 2004, Organic letters.

Lanthanum(III)–Lithium–BINOL Complex

M. Shibasaki, N. Yoshikawa, 2003 .

Chiral Heterobimetallic Lanthanoid Complexes: Highly Efficient Multifunctional Catalysts for the Asymmetric Formation of C-C, C-O, and C-P Bonds

H. Gröger, M. Shibasaki, 1999 .

First catalytic asymmetric hydrophosphonylation of cyclic imines: Highly efficient enantioselective approach to a 4-thiazolidinylphosphonate via chiral titanium and lanthanoid catalysts

H. Gröger, M. Shibasaki, H. Sasai, 1996 .

New Catalytic Concepts for the Asymmetric Aldol Reaction

Masakatsu Shibasaki, Harald Gröger, H. Gröger, 1998 .

Direct catalytic asymmetric addition of allyl cyanide to ketones.

R. Yazaki, N. Kumagai, M. Shibasaki, 2008, Journal of the American Chemical Society.

Catalytic enantioselective Strecker reaction of ketoimines using catalytic amount of TMSCN and stoichiometric amount of HCN

Masato Suzuki, M. Kanai, M. Shibasaki, 2004 .

Recent Advances in the Catalytic Asymmetric Synthesis of β 2 ‐ and β 2,2 ‐Amino Acids

M. Shibasaki, H. Noda, 2020 .

Two methods for catalytic generation of reactive enolates promoted by a chiral poly gd complex: application to catalytic enantioselective protonation reactions.

M. Kanai, Yasuaki Kimura, M. Shibasaki, 2009, Journal of the American Chemical Society.

Catalytic asymmetric aza-Morita-Baylis-Hillman reaction of methyl acrylate: role of a bifunctional La(O-iPr)3/linked-BINOL complex.

S. Matsunaga, Yingjie Xu, M. Shibasaki, 2010, Journal of the American Chemical Society.

Enantioselective synthesis of a GPR40 agonist AMG 837 via catalytic asymmetric conjugate addition of terminal alkyne to α,β-unsaturated thioamide.

R. Yazaki, N. Kumagai, M. Shibasaki, 2011, Organic letters.

Perkin communications. The binary reagent PhSeSePH–CuOTf: a useful phenylselenylating agent

H. Satoh, M. Shibasaki, N. Miyachi, 1991 .

Ligand-Enabled, Copper-Catalyzed Electrophilic Amination for the Asymmetric Synthesis of β-Amino Acids.

R. Tak, M. Shibasaki, H. Noda, 2021, Organic letters.

Direct catalytic asymmetric addition of allylic cyanides to aldehydes for expeditious access to enantioenriched unsaturated δ-valerolactones.

N. Kumagai, M. Shibasaki, S. Yasuda, 2013, Chemistry, an Asian journal.

Cu ‐Catalyzed Asymmetric Synthesis

N. Kumagai, M. Shibasaki, H. Noda, 2020 .

Concise enantioselective synthesis of δ,δ-disubstituted δ-valerolactones

N. Kumagai, M. Shibasaki, A. Saito, 2014 .

Cu(I)-catalyzed decarboxylative aldol-type and Mannich-type reactions for asymmetric construction of contiguous trisubstituted and quaternary stereocenters

M. Kanai, M. Shibasaki, L. Yin, 2012 .

Catalytic asymmetric synthesis of key intermediate for scytophycin C

M. Shibasaki, Takumi Watanabe, Jin Cui, 2016 .

Copper(I) Fluoride and Copper(II) Fluoride

M. Kanai, M. Shibasaki, 2007 .

New chiral bis(diphenylphospholane) ligands: design, synthesis, and application to catalytic enantioselective aldol reaction to ketones

M. Kanai, M. Shibasaki, Dongbo Zhao, 2005 .

Direct Catalytic Asymmetric Aldol Reaction of Thioamide with an α-Vinyl Appendage.

N. Kumagai, M. Shibasaki, Takumi Watanabe, 2018, Chemistry.

Cyanomethylation of β‐Alkoxyaldehydes: Toward a Short Synthesis of Atorvastatin

R. Tak, M. Shibasaki, H. Noda, 2019, Asian Journal of Organic Chemistry.

Streamlined catalytic asymmetric synthesis of atorvastatin.

Yuji Kawato, N. Kumagai, M. Shibasaki, 2013, Chemistry.

Enantioselective total synthesis of (−)-strychnine: development of a highly practical catalytic asymmetric carbon–carbon bond formation and domino cyclization

M. Shibasaki, Ryo Takita, T. Ohshima, 2004 .

Synthesis and evaluation of a new chiral arsine ligand; 2,2′-bis(diphenylarsino)-1,1′-binaphthyl (BINAs)

Christopher D. J. Boden, M. Shibasaki, A. Kojima, 1997 .

New functions of (arene)tricarbonylchromium(0) complexes as hydrogenation catalysts: stereospecific semihydrogenation of alkynes and highly chemoselective hydrogenation of .alpha.,.beta.-unsaturated carbonyl compounds

M. Sodeoka, M. Shibasaki, 1985 .

Additions and Corrections - New Functions of (Arene)tricarbonylchromium(O) Complexes as Hydrogenation Catalysts: Stereospecific Semihydrogenation of Alkynes and Highly Chemoselective Hydrogenation of a, β-Unsaturated Carbonyl Compounds.

M. Sodeoka, M. Shibasaki, 1985 .

A simple preparation of (+)-4-phenylthioazetidin-2-one and an asymmetric synthesis of (+)-thienamycin

S. Ikegami, A. Nishida, M. Shibasaki, 1983 .

New synthesis of 4-acetoxy-2-azetidinones by use of electrochemical oxidation

M. Shibasaki, M. Mori, K. Kagechika, 1991 .

Further studies on the stereochemistry of metal enolate-imine condensation reactions

M. Shibasaki, Genji Iwasakia, 1987 .

Stereocontrolled synthesis of (+)-thienamycin from 3(R)-hydroxybutyric acid

M. Shibasaki, T. Iimori, 1985 .

Recent progress in Lewis acid-Lewis base bifunctional asymmetric catalysis

M. Kanai, M. Shibasaki, Nobuki Kato, 2005 .

A novel synthesis of (-)-carpetimycin A

Y. Ishida, M. Shibasaki, N. Okabe, 1985 .

Arene Chromium Tricarbonyl Catalyzed Reactions in Organic Synthesis

M. Sodeoka, M. Shibasaki, 1994 .

Solvent-dependent self-discrimination of bis(2-hydroxyphenyl)diamides.

N. Kumagai, M. Shibasaki, Akinobu Matsuzawa, 2010, Chemistry.

Highly Enantio- and Diastereoselective Synthesis of 1,2,3-Trisubstituted Cyclopropanes from α,β-Unsaturated Amides and Stabilized Sulfur Ylides Catalyzed by a Chiral Copper(I) Complex

N. Kumagai, M. Shibasaki, Santosh K. Pagire, 2021, ACS Catalysis.

Lewis base assisted Brønsted base catalysis: bidentate phosphine oxides as activators and modulators of Brønsted basic lanthanum-aryloxides.

S. Matsunaga, M. Shibasaki, G. Lu, 2008, Angewandte Chemie.

Catalytic asymmetric epoxidation of α,β-unsaturated N-acylpyrroles as monodentate and activated ester equivalent acceptors

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2006 .

New entries in Lewis acid-Lewis base bifunctional asymmetric catalyst: catalytic enantioselective Reissert reaction of pyridine derivatives.

Masato Suzuki, M. Kanai, M. Shibasaki, 2004, Journal of the American Chemical Society.

Catalytic enantioselective Reissert-type reaction: development and application to the synthesis of a potent NMDA receptor antagonist (-)-L-689,560 using a solid-supported catalyst.

M. Kanai, M. Shibasaki, M. Takamura, 2001, Journal of the American Chemical Society.

On the stereochemical course of vinyloxyborane-imine condensation ―the stereoselective formation of threo β-amino acid derivatives―

Y. Ishida, M. Shibasaki, T. Iimori, 1986 .

α,β-Unsaturated Amides as Dipolarophiles: Catalytic Asymmetric exo-Selective 1,3-Dipolar Cycloaddition with Nitrones.

N. Kumagai, M. Shibasaki, Ming Zhang, 2017, Chemistry.

Application of the Lewis acid-Lewis base bifunctional asymmetric catalysts to pharmaceutical syntheses: stereoselective chiral building block syntheses of human immunodeficiency virus (HIV) protease inhibitor and beta3-adenergic receptor agonist.

M. Kanai, M. Shibasaki, Hiroyuki Nogami, 2003, Chemical & pharmaceutical bulletin.

Tandem Suzuki cross-coupling-Heck reactions

Christopher D. J. Boden, M. Shibasaki, A. Kojima, 1997 .

Novel cyclization by stannyl anion generated from (trimethylsilyl)tributylstannane (Me3SiSnBu3) and fluoride ion. Application to natural product synthesis

M. Shibasaki, M. Mori, Naohiro Isono, 1993 .

The palladium-catalysed arylation and vinylation of alkenes—enantioselective fashion☆

M. Shibasaki, E. Vogl, 1999 .

Asymmetric heck reaction. A catalytic asymmetric synthesis of the key intermediate for vernolepin

M. Sodeoka, M. Shibasaki, K. Kondo, 1993 .

New synthetic routes to 9(0)-methanoprostacyclin. A highly stable and biologically potent analog of prostacyclin

S. Ikegami, M. Shibasaki, J. Ueda, 1979 .

Catalytic asymmetric cyclopropanation of enones with dimethyloxosulfonium methylide promoted by a La-Li3-(biphenyldiolate)3 + NaI complex.

S. Matsunaga, M. Shibasaki, H. Kakei, 2007, Journal of the American Chemical Society.

Chapter 3 Recent Studies on the Synthesis of Strychnine

Masakatsu Shibasaki, M. Shibasaki, Takashi Ohshima, 2007 .

Catalytic enantioselective construction of beta-quaternary carbons via a conjugate addition of cyanide to beta,beta-disubstituted alpha,beta-unsaturated carbonyl compounds.

M. Kanai, M. Shibasaki, Yuta Tanaka, 2010, Journal of the American Chemical Society.

Direct catalytic asymmetric and anti-selective vinylogous addition of butenolides to chromones†

N. Kumagai, M. Shibasaki, Takumi Watanabe, 2020, Chemical science.

Enantio- and diastereoselective construction of vicinal quaternary and tertiary carbon centers by catalytic Michael reaction of α-substituted β-keto esters to cyclic enones

M. Shibasaki, T. Ohshima, K. Majima, 2005 .

Catalytic asymmetric synthesis of 19,20-dihydroakuammicine.

M. Shibasaki, T. Ohshima, S. Shimizu, 2000, Chirality.

Catalytic Asymmetric Synthesis of Natural Products with Heterocyclic Rings

M. Shibasaki, A. Kojima, S. Shimizu, 1998 .

UTILIZATION OF HETEROBIMETALLIC COMPLEXES AS LEWIS ACIDS

M. Shibasaki, T. Arai, H. Sasai, 1998 .

The First Heterobimetallic Multifunctional Asymmetric Catalyst.

Y. Satow, K. Houk, M. Shibasaki, 1995 .

A Thirst for Enantioselectivity in Catalytic Addition of Alkylnitriles

N. Kumagai, M. Shibasaki, 2019, Chemistry Letters.

Catalytic Asymmetric Epoxidation of α, β-Unsaturated Carbonyl Compounds

T. Nemoto, M. Shibasaki, T. Ohshima, 2002 .

Catalytic asymmetric total synthesis of chimonanthine, folicanthine, and calycanthine through double Michael reaction of bisoxindole.

M. Kanai, S. Matsunaga, M. Shibasaki, 2012, Angewandte Chemie.

α-BROMOALLYLSTANNANES AS SYNTHETIC TOOLS: PREPARATIONS AND REACTIVITIES

S. Ikegami, M. Shibasaki, Hideyuki Suzuki, 1983 .

A new alkyltin (IV)-mediated coupling reaction of aldehydes to olefins

S. Ikegami, M. Shibasaki, Y. Torisawa, 1981 .

Enantioselective total syntheses of (+)-decursin and related natural compounds using catalytic asymmetric epoxidation of an enone

T. Nemoto, M. Shibasaki, T. Ohshima, 2003 .

Asymmetric Heck Reaction‐Carbanion Capture Process. Catalytic Asymmetric Total Synthesis of (‐)‐δ9(12)‐Capnellene (XIII).

M. Sodeoka, M. Shibasaki, T. Ohshima, 2010 .

Asymmetric Heck reaction: A catalytic asymmetric synthesis of the key intermediate of (−)-oppositol and (−)-prepinnaterpene

M. Shibasaki, M. Mori, Y. Sato, 1995 .

Manganese(III)-based oxidative free-radical reaction of α-allyl-β-keto ester with molecular oxygen

M. Sodeoka, M. Shibasaki, T. Ohshima, 1993 .

New Catalytic Asymmetric Carbon-Carbon Bond-Forming Reactions by Palladium and by Lanthanum

M. Shibasaki, 1993 .

Asymmetric Heck Reaction: A Catalytic Asymmetric Synthesis of the Key Intermediate for δ9(12)‐Capnellene‐3β,8β,10α‐ triol and δ9(12)‐Capnellene‐3β,8β,10α,14‐tetrol.

M. Shibasaki, K. Kagechika, 1991 .

Catalytic Asymmetric Synthesis of Halenaquinone and Halenaquinol

M. Sodeoka, M. Shibasaki, A. Kojima, 1996 .

A direct catalytic asymmetric aldol reaction of α-sulfanyl lactones: efficient synthesis of SPT inhibitors.

N. Kumagai, M. Shibasaki, S. Yasuda, 2012, Angewandte Chemie.

Quaternary β2,2 -Amino Acids: Catalytic Asymmetric Synthesis and Incorporation into Peptides by Fmoc-Based Solid-Phase Peptide Synthesis.

M. Shibasaki, H. Noda, Jin-Sheng Yu, 2018, Angewandte Chemie.

Asymmetric synthesis of (2R)-2-hydroxy-2-(2(Z)-octenyl)-1-cyclopentanone

M. Sodeoka, M. Shibasaki, K. Yoshida, 1988 .

Catalytic asymmetric synthesis of benzylic quaternary carbon centers. An efficient synthesis of (-)-eptazocine

M. Sodeoka, M. Shibasaki, H. Sasai, 1993 .

Asymmetric Heck Reaction: Catalytic Asymmetric Syntheses of Bicyclic Enones, Dienones, and the Key Intermediate for Vernolepin

M. Sodeoka, M. Shibasaki, K. Kondo, 1994 .

Palladium-Catalyzed Asymmetric Arylation of 4,7-Dihydro-1,3-dioxepin. Catalytic Asymmetric Synthesis of γ-Butyrolactone Derivatives.

M. Sodeoka, Y. Koga, M. Shibasaki, 2010 .

Catalytic Asymmetric Synthesis of Polycylic Compounds by Asymmetric Heck Reaction.

M. Shibasaki, Y. Sato, K. Kagechika, 1992 .

Catalytic asymmetric synthesis of CF3-substituted tertiary propargylic alcohols via direct aldol reaction of α-N3 amide

N. Kumagai, M. Shibasaki, H. Noda, 2017, Chemical science.

Direct Catalytic Asymmetric Mannich-Type Reaction of α-N3 Amide.

N. Kumagai, M. Shibasaki, Zhongdong Sun, 2015, Chemistry.

A designed amide as an aldol donor in the direct catalytic asymmetric aldol reaction.

N. Kumagai, M. Shibasaki, K. Weidner, 2014, Angewandte Chemie.

Mixed La-Li heterobimetallic complexes for tertiary nitroaldol resolution.

S. Matsunaga, M. Shibasaki, S. Harada, 2006, Journal of the American Chemical Society.

Cu(I)-catalyzed asymmetric allylation of ketones and ketimines

M. Kanai, M. Shibasaki, Reiko Wada, 2008 .

Catalytic Asymmetric Synthesis of α‐Trifluoromethylated Carbinols: A Case Study of Tertiary Propargylic Alcohols

N. Kumagai, M. Shibasaki, H. Noda, 2018 .

Copper(I) alkoxide-catalyzed alkynylation of trifluoromethyl ketones.

M. Kanai, M. Shibasaki, R. Motoki, 2007, Organic letters.

Bifunctional Asymmetric Catalysis Based on Dinuclear Schiff Base Complexes

S. Matsunaga, M. Shibasaki, 2010 .

Catalytic Asymmetric Epoxidation of α,β-Unsaturated Phosphane Oxides with a Y(O-iPr)3/Biphenyldiol Complex.

S. Matsunaga, So-Young Park, M. Shibasaki, 2008 .

Catalytic Asymmetric Synthesis of 2,2-Disubstituted Terminal Epoxides via Dimethyloxosulfonium Methylide Addition to Ketones.

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2008 .

Lewis acid-Lewis acid heterobimetallic cooperative catalysis: mechanistic studies and application in enantioselective aza-Michael reaction.

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2005, Journal of the American Chemical Society.

Catalytic Asymmetric Cyano-Ethoxycarbonylation Reaction of Aldehydes Using a YLi3Tris(binaphthoxide) (YLB) Complex: Mechanism and Roles of Achiral Additives.

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2005 .

An Asymmetric Cyanation Reaction and Sequential Asymmetric Cyanation—Nitroaldol Reaction Using a [YLi3{tris(binaphthoxide)}] Single Catalyst Component: Catalyst Tuning with Achiral Additives.

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2003 .

Direct Catalytic Asymmetric Addition of Acetonitrile to Aldimines.

N. Kumagai, M. Shibasaki, A. Saito, 2019, Organic letters.

Direct catalytic asymmetric addition of acetonitrile to N-thiophosphinoylimines.

Yuji Kawato, N. Kumagai, M. Shibasaki, 2013, Chemical communications.

Asymmetric Synthesis of Isothiazoles Through Cu Catalysis: Direct Catalytic Asymmetric Conjugate Addition of Allyl Cyanide to α,β‐Unsaturated Thioamides.

R. Yazaki, N. Kumagai, M. Shibasaki, 2012 .

Catalytic enantioselective synthesis of (20s)-camptothecin intermediates using cyanosilylation of ketones promoted by D-glucose-derived lanthanide catalyst

M. Kanai, M. Shibasaki, D. Curran, 2003 .

Direct catalytic asymmetric aldol reaction of thioamides: a concise asymmetric synthesis of (R)-fluoxetine

M. Iwata, R. Yazaki, N. Kumagai, 2010 .

Design and synthesis of a bis(hydroxyphenyl)diamide bearing a pendant thiazolium unit; application to the catalytic asymmetric intramolecular Stetter reaction

N. Kumagai, M. Shibasaki, Youmei Bao, 2014 .

Preparation of a new asymmetric lanthanoid complex catalyst for the Mukaiyama aldol reaction

M. Shibasaki, H. Sasai, K. Uotsu, 1995 .

Stereoselective Total Synthesis of KAE609 via Direct Catalytic Asymmetric Alkynylation to Ketimine.

N. Kumagai, M. Shibasaki, Hisashi Takada, 2015, Organic letters.

Catalytic Enantioselective Addition of Terminal Alkynes to Aldehydes: Preparation of (S)‐(‐)‐1,3‐Diphenyl‐2‐Propyn‐1‐OL and (S)‐(‐)‐4‐Methyl‐1‐Phenyl‐2‐Pentyn‐1,4‐Diol

S. Matsunaga, M. Shibasaki, Ryo Takita, 2008 .

Interplay of Diamides and Rare Earth Metals: Specific Molecular Spaces and Catalytic Activity

N. Kumagai, M. Shibasaki, 2018 .

Novel multiaction of Zr catalyst: one-pot synthesis of beta-cyanohydrins from olefins.

M. Kanai, M. Shibasaki, S. Yamasaki, 2001, Journal of the American Chemical Society.

An efficient synthesis of isocarbacyclin starting from furfural

M. Sodeoka, M. Shibasaki, T. Mase, 1985 .

Synthesis of 9(0)-Methano-Δ6(9α)-PGI1: The highly potent carbon analog of prostacyclin

S. Ikegami, M. Shibasaki, Y. Torisawa, 1983 .

Regiocontrolled conversion of α,β-unsaturated ketones to olefins allylsilanes: synthesis of -9(0)-methano-Δ6(9α)-PGI1

S. Ikegami, M. Shibasaki, H. Fukasawa, 1983 .

Asymmetric Heck-Type Reaction Utilizing Hypervalent Alkenyliodonium Salt

M. Sodeoka, M. Shibasaki, Y. Kurihara, 1994 .

A total synthesis of d1-coriolin

S. Ikegami, M. Shibasaki, K. Iseki, 1980 .

Synthesis and Evaluation of a New Chiral Ligand: 2‐Diphenylarsino‐2′‐diphenylphosphino‐1,1′‐binaphthyl (BINAPAs).

M. Shibasaki, S. Cho, 1998 .

Catalytic Asymmetric Synthesis of Halenaquinone and Halenaquinol.

M. Sodeoka, M. Shibasaki, A. Kojima, 1996 .

Asymmetric Heck Reaction : Catalytic Asymmetric Syntheses of Bioactive Molecules

M. Sodeoka, M. Shibasaki, 1994 .

REGIOSELECTIVE OLEFIN INSERTION IN ASYMMETRIC HECK REACTION. CATALYTIC ASYMMETRIC SYNTHESIS OF A VERSATILE INTERMEDIATE FOR DITERPENE SYNTHESES

M. Sodeoka, M. Shibasaki, K. Kondo, 1995 .

Effects of Solvents and Additives in the Asymmetric Heck Reaction of Alkenyl Triflates: Catalytic Asymmetric Synthesis of Decalin Derivatives and Determination of the Absolute Stereochemistry of (+)-Vernolepin

M. Sodeoka, M. Shibasaki, K. Kondo, 1994 .

On the Role of Silver Salts in Asymmetric Heck-type Reaction. A Greatly Improved Catalytic Asymmetric Synthesis of cis-Decalin Derivatives

M. Sodeoka, M. Shibasaki, Y. Sato, 1990 .

The first total syntheses of .DELTA.9(12)-Capnellene-8.beta.,10.alpha.-diol and .DELTA.9(12)-capnellene-3.beta.,8.beta.,10.alpha.-triol

S. Ikegami, M. Shibasaki, T. Mase, 1986 .

Efficient Synthesis of C10 Chiron by Lewis Acid Catalyzed Rearrangement of (+)-α-3,4-Epoxycarane.

M. Shibasaki, T. Arai, H. Sasai, 1995 .

Studies toward the total synthesis of garsubellin A: synthesis of 8-deprenyl-garsubellin A

M. Kanai, M. Shibasaki, H. Usuda, 2002 .

Highly efficient synthesis of a carbacyclin analog. Stereospecific synthesis of aryl-substituted exocyclic olefins

M. Sodeoka, M. Shibasaki, S. Satoh, 1988 .

Stereospecific synthesis of exo-trisubstituted olefins. The highly efficient synthesis of carbacyclins

M. Sodeoka, Y. Ogawa, M. Shibasaki, 1984 .

Chapter 13 – Catalytic Asymmetric Total Synthesis of (−)-Strychnine and Fostriecin

M. Kanai, M. Shibasaki, T. Ohshima, 2004 .

Desymmetrizing Heck Reactions

M. Shibasaki, T. Ohshima, 2009 .

Formal Total Synthesis of (‐)‐Dendrobine Using Zirconium‐Promoted Reductive Cyclization.

M. Shibasaki, M. Mori, F. Saitoh, 1995 .

Bifunctional Molecular Catalysis

T. Ikariya, M. Shibasaki, 2011 .

Cationic bismuth-catalyzed hydroamination and direct substitution of the hydroxy group in alcohols with amides.

S. Matsunaga, M. Shibasaki, 2012, Topics in current chemistry.

Multimetallic Catalysts in Organic Synthesis: SHIBASAKI:MULTIMET.CATAL. O-BK

M. Shibasaki, Yoshinori Yamamoto, 2004 .

Unique reactivity of α,β‐unsaturated carboxylic acid imidazolides: Catalytic asymmetric synthesis of α,β‐epoxy esters and α,β‐epoxy carboxylic acid derivatives

T. Nemoto, M. Shibasaki, T. Ohshima, 2003 .

Highly enantioselective catalytic Michael reaction of α-substituted malonates using La-linked-BINOL complex in the presence of HFIP (1,1,1,3,3,3-hexafluoroisopropanol)

M. Shibasaki, Ryo Takita, T. Ohshima, 2002 .

Water vs. Desiccant. Improvement of Yb—BINOL Complex Catalyzed Enantioselective Epoxidation of Enones.

M. Shibasaki, T. Arai, H. Sasai, 1998 .

Linking BINOL: C2-symmetric ligands for investigations on asymmetric catalysis

M. Kanai, S. Matsunaga, M. Shibasaki, 1998 .

Regioselective Catalytic Asymmetric Reaction of Horner—Wadsworth—Emmons Reagents with Enones: The Odyssey of Chiral Aluminum Catalysts.

M. Shibasaki, T. Arai, H. Sasai, 1998 .

CATALYTIC ASYMMETRIC AMINATION OF OXINDOLES UNDER DINUCLEAR NICKEL SCHIFF BASE CATALYSIS (Dedicated to Dr. Albert Padwa on his 75th birthday)

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2012 .

A homodinuclear Mn(III)2-Schiff base complex for catalytic asymmetric 1,4-additions of oxindoles to nitroalkenes.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2009, Journal of the American Chemical Society.

Catalytic asymmetric Michael reaction of beta-keto esters: effects of the linker heteroatom in linked-BINOL.

M. Shibasaki, Ryo Takita, T. Ohshima, 2003, Journal of the American Chemical Society.

Catalytic Enantioselective Desymmetrization of meso‐N‐Acylaziridines with TMSCN.

M. Kanai, M. Shibasaki, Ikuo Fujimori, 2005 .

Catalytic Asymmetric Synthesis of 3‐Aminooxindoles: Enantiofacial Selectivity Switch in Bimetallic vs. Monometallic Schiff Base Catalysis.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2010 .

Direct Catalytic Asymmetric Aldol Reaction of β-Keto Esters with Formaldehyde Promoted by a Dinuclear Ni2-Schiff Base Complex.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2010 .

A Heterobimetallic Ga/Yb-Schiff Base Complex for Catalytic Asymmetric α-Addition of Isocyanides to Aldehydes.

S. Matsunaga, Yingjie Xu, M. Shibasaki, 2009 .

Catalytic Asymmetric Synthesis of Nitrogen-Containing gem-Bisphosphonates Using a Dinuclear Ni2—Schiff Base Complex.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2009 .

Direct anti-Selective Catalytic Asymmetric Mannich-Type Reactions of α-Ketoanilides for the Synthesis of γ-Amino Amides and Azetidine-2-amides.

S. Matsunaga, Yingjie Xu, M. Shibasaki, 2009 .

Catalytic Asymmetric Synthesisof Nitrogen-Containing gem-Bisphosphonates Usinga Dinuclear Ni2-Schiff Base Complex

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2009 .

Direct Catalytic Asymmetric Mannich-Type Reaction of β-Keto Phosphonate Using a Dinuclear Ni2—Schiff Base Complex.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2008 .

A Heterobimetallic Pd/La/Schiff Base Complex for anti-Selective Catalytic Asymmetric Nitroaldol Reactions and Applications to Short Syntheses of β-Adrenoceptor Agonists.

S. Matsunaga, M. Shibasaki, Shinya Handa, 2008 .

Direct catalytic asymmetric Mannich-type reaction of beta-keto phosphonate using a dinuclear Ni2-Schiff base complex.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2008, Organic letters.

A Bench‐Stable Homodinuclear Ni2—Schiff Base Complex for Catalytic Asymmetric Synthesis of α‐Tetrasubstituted anti‐α,β‐Diamino Acid Surrogates.

S. Matsunaga, M. Shibasaki, Zhihua Chen, 2008 .

Sc3+-catalyzed aldol-type additions of N-benzoylcyclopropanecarboxamides via iodide-mediated ring-opening: stereoselective synthesis of gamma-lactams.

S. Matsunaga, M. Shibasaki, H. Noda, 2008, Organic letters.

Catalytic Enantioselective meso-Epoxide Ring Opening Reaction with Phenolic Oxygen Nucleophile Promoted by Gallium Heterobimetallic Multifunctional Complexes

S. Matsunaga, M. Shibasaki, and Kentaro Yamaguchi, 2000 .

All Non-Carbon B3 NO2 Exotic Heterocycles: Synthesis, Dynamics, and Catalysis.

N. Kumagai, M. Shibasaki, H. Noda, 2019, Chemistry.

Unique physicochemical and catalytic properties dictated by the B3NO2 ring system.

N. Kumagai, M. Shibasaki, H. Noda, 2017, Nature chemistry.

Mechanistic studies of a reaction promoted by the [YLi3[tris(binaphthoxide)]] complex: are three 1,1'-bi-2-naphthol units in a rare-earth-alkali-metal heterobimetallic complex necessary?

S. Matsunaga, M. Shibasaki, Noriyuki Yamagiwa, 2004, Angewandte Chemie.

syn-selective direct catalytic asymmetric Mannich-type reactions of hydroxyketones using Y{N(SiMe3)2}3/linked-BINOL complexes.

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2005, Organic letters.

Catalytic Asymmetric Epoxidation of α,β-Unsaturated Esters Using an Yttrium-Biphenyldiol Complex

M. Shibasaki, H. Kakei, T. Ohshima, 2005 .

Stereocontrolled synthesis of exocyclic olefins using arene tricarbonyl chromium complex-catalyzed hydrogenation. I. Efficient synthesis of carbacyclin and its analogs.

M. Sodeoka, Y. Ogawa, M. Shibasaki, 1991, Chemical & pharmaceutical bulletin.

Synthetic studies on capnellol family : an improved synthesis of Δ9(12)-capnellene-3β,8β,10α-triol and the first total synthesis of Δ9(12)-capnellene-β,8β,10α,14-tetrol

M. Shibasaki, T. Mase, 1986 .

The total synthesis of dl-coriolin

S. Ikegami, M. Shibasaki, Katsuhiko Isekia, 1981 .

New method for the stereocontrolled synthesis of silyl dienol ethers using (naphthalene)chromium tricarbonyl catalyzed isomerization

M. Sodeoka, M. Shibasaki, H. Yamada, 1990 .

Palladium-Mediated Asymmetric Synthesis of Cis-3,6-Disubstituted Cyclohexenes. A Short Total Synthesis of Optically Active (+)-.gamma.-Lycorane

H. Satoh, M. Shibasaki, M. Mori, 1995 .

A New and Selective Metal-Catalyzed Baeyer-Villiger Oxidation Procedure

M. Shibasaki, H. Sasai, R. Göttlich, 1997 .

Simple, stereocontrolled synthesis of thromboxane B2 from D-glucose

E. Corey, M. Shibasaki, J. Knolle, 1977 .

Catalytic asymmetric synthesis of alpha-alkylidene-beta-hydroxy esters via dynamic kinetic asymmetric transformation involving Ba-catalyzed direct aldol reaction.

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2009, Journal of the American Chemical Society.

Direct Catalytic Asymmetric Aldol Reaction Using Chiral Metal Complexes

S. Matsunaga, N. Kumagai, M. Shibasaki, 2008 .

Stable Diaqua Palladium(II) Complexes of BINAP and Tol-BINAP as Highly Efficient Catalysts for Asymmetric Aldol Reactions

M. Sodeoka, M. Shibasaki, F. Miyazaki, 1997 .

Catalytic Kinetic Resolution Reaction of (±)-5-Methylbicyclo[3.3.0]oct-1-ene-3,6-dione.

M. Shibasaki, Takehiko Iida, Eita Emori, 1999, The Journal of organic chemistry.

Asymmetric synthesis using palladium catalysts

M. Sodeoka, M. Shibasaki, 1998 .

Direct Catalytic Asymmetric Aldol Addition of an α-CF3 Amide to Arylglyoxal Hydrates.

N. Kumagai, M. Shibasaki, H. Noda, 2017, The Journal of organic chemistry.

Synthesis of caprazamycin B

M. Shibasaki, Takumi Watanabe, P. Gopinath, 2015 .

Identification of potent, selective protein kinase C inhibitors based on a phorbol skeleton.

M. Kanai, K. Yamatsugu, M. Shibasaki, 2006, Chemistry, an Asian journal.

Dynamic ligand exchange of the lanthanide complex leading to structural and functional transformation: one-pot sequential catalytic asymmetric epoxidation-regioselective epoxide-opening process.

M. Shibasaki, T. Ohshima, R. Tsuji, 2005, Journal of the American Chemical Society.

Dramatic switching of protein kinase C agonist/antagonist activity by modifying the 12-ester side chain of phorbol esters.

M. Kanai, M. Shibasaki, Reiko Wada, 2002, Journal of the American Chemical Society.

Efficient Synthesis of Antihyperglycemic (S)-α-Aryloxy-β-phenylpropionic Acid Using a Bifunctional Asymmetric Catalyst

M. Kanai, M. Shibasaki, M. Takamura, 2002 .

Practical synthesis of chiral ligands for catalytic enantioselective cyanosilylation of ketones

M. Kanai, M. Shibasaki, S. Masumoto, 2002 .

Diastereo- and enantioselective direct catalytic aldol reaction of 2-hydroxyacetophenones with aldehydes promoted by a heteropolymetallic complex: catalytic asymmetric synthesis of anti-1,2-diols.

M. Shibasaki, N. Yoshikawa, Takeyuki Suzuki, 2002, The Journal of organic chemistry.

A catalytic asymmetric strecker-type reaction promoted by Lewis acid-Lewis base bifunctional catalyst.

M. Kanai, Y. Hamashima, M. Shibasaki, 2000, Chemical & pharmaceutical bulletin.

Synthetic studies towards phorbols : synthesis of B or C ring substituted phorbol skeletons in the naturally occurring form

M. Shibasaki, K. Sugita, H. Sasai, 1994 .

Catalytic Asymmetric C-C Bond-Forming Reaction Using Optically Active Rare Earth Complex

M. Shibasaki, H. Sasai, 1993 .

Synthetic studies towards phorbols: A stereocontrolled synthesis of the phorbol skeleton in the naturally occurring form

M. Shibasaki, H. Sasai, K. Shigeno, 1992 .

Synthesis of E-Vinylsilanes from Olefins with Vicinal Silyl and Stannyl Substituents

M. Shibasaki, M. Mori, N. Kaneta, 1991 .

A new method for the stereocontrolled synthesis of dienamine derivatives using (naphthalene)chromium tricarbonyl catalyzed isomerization

M. Sodeoka, M. Shibasaki, H. Yamada, 1991 .

Catalytic asymmetric synthesis of both syn- and anti-3,5-dihydroxy esters: application to 1,3-polyol/alpha-pyrone natural product synthesis.

T. Nemoto, M. Shibasaki, T. Ohshima, 2003, Organic letters.

Catalytic Asymmetric Synthesis of α,β-Epoxy Esters, Aldehydes, Amides, and γ,δ-Epoxy β-Keto Esters: Unique Reactivity of α,β-Unsaturated Carboxylic Acid Imidazolides

T. Nemoto, M. Shibasaki, A. Ohshima, 2001 .

Direct catalytic asymmetric Mannich-type reaction of unmodified ketones utilizing the cooperation of an AlLibis(binaphthoxide) complex and La(OTf)3·nH2O

M. Shibasaki, S. Yamasaki, Takehiko Iida, 1999 .

7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective C–C Bond-Forming Catalysis

N. Kumagai, M. Shibasaki, 2018, Synthesis.

Direct catalytic asymmetric Mannich-type reactions of N-(2-hydroxyacetyl)pyrrole as an ester-equivalent donor.

S. Matsunaga, M. Shibasaki, S. Harada, 2005, Angewandte Chemie.

Concise and Stereodivergent Approach to Chromanone Lactones through Copper-Catalyzed Asymmetric Vinylogous Addition of Siloxyfurans to 2-Ester-Substituted Chromones.

M. Shibasaki, Takumi Watanabe, H. Noda, 2022, Angewandte Chemie.

Direct catalytic aldol-type reactions using RCH2CN.

M. Kanai, S. Matsunaga, N. Kumagai, 2003, Organic letters.

Synthetic Strategies of Fostriecin

M. Kanai, M. Shibasaki, 2005 .

Recent Progress in Asymmetric Two‐Center Catalysis

M. Kanai, M. Shibasaki, K. Funabashi, 2003 .

Direct Catalytic Asymmetric Aldol Reaction of an α-Azido Amide.

N. Kumagai, M. Shibasaki, Zhongdong Sun, 2015, Angewandte Chemie.

An improved method for the introduction of carbon-carbon triple bond at C-13 in PG synthesis

M. Shibasaki, Hiroyasu Sato, A. Takahashi, 1992 .

Zirconium tetra-tert-butoxide, an efficient and convenient basic reagent in organic synthesis. Utilization in cross and intramolecular aldol reactions

M. Shibasaki, H. Sasai, Y. Kirio, 1990 .

New method for the introduction of a carbon-carbon triple bond at C-13 in prostaglandin synthesis. Stereocontrolled synthesis of ZK 96 480

M. Shibasaki, A. Takahashi, 1988 .

Ligand accelerated indium(III)-catalyzed asymmetric alkynylation of aldehydes with 2-methyl-3-butyn-2-ol as an ethyne equivalent donor.

S. Matsunaga, M. Shibasaki, Ryo Takita, 2007, Chemical communications.

Utilization of Bu3SnSiMe3 in organic synthesis: II. New cyclization by a stannyl anion generated from Bu3SnSiMe3 and R4NX

M. Shibasaki, M. Mori, N. Kaneta, 1994 .

Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2005, Chemical communications.

Cooperative catalysis of a cationic ruthenium complex, amine base, and na salt: catalytic activation of acetonitrile as a nucleophile.

S. Matsunaga, N. Kumagai, M. Shibasaki, 2004, Journal of the American Chemical Society.

Dichlorotin oxide-catalyzed new direct functionalization of olefins: synthesis of trans β-azidohydrins and 1,2-diols

M. Kanai, M. Shibasaki, Isao Sakurada, 2000 .

Syntheses and biological activities of chemically stable prostacyclin mimics with cis-bicyclo[4.3.0]nonene ring system: the novel homoisocarbacyclin analogues.

M. Shibasaki, T. Yamaguchi, K. Kogi, 1993, Bioorganic & medicinal chemistry.

SYNTHESIS OF (Z)-4,5,13,14-TETRADEHYDRO-9(O)-METHANO-Δ6(9α)-PGI1

M. Shibasaki, M. Shinoda, K. Iseki, 1986 .

PRACTICAL SYNTHESIS OF (+)-9(O)-METHANO-Δ6(9α)-PGI1. THE HIGHLY POTENT CARBON ANALOG OF PROSTACYCLIN

M. Sodeoka, M. Shibasaki, 1984 .

Catalytic asymmetric synthesis of propranolol and metoprolol using a La–Li–BINOL complex

M. Shibasaki, H. Sasai, Takeyuki Suzuki, 1995 .

Practical synthesis of chiral ligands for catalytic enantioselective cyanosilylation of ketones and ketoimines.

M. Kanai, M. Shibasaki, Nobuki Kato, 2004, The Journal of organic chemistry.

Efficient Synthesis of a Key Intermediate of Neurokinin Receptor Antagonists Using a Bifunctional Asymmetric Catalyst

M. Kanai, M. Shibasaki, T. Nishi, 2003 .

Studies toward practical synthesis of (20S)-camptothecin family through catalytic enantioselective cyanosilylation of ketones: improved catalyst efficiency by ligand-tuning

M. Kanai, M. Shibasaki, D. Curran, 2002 .

Anti- and Syn-Selective Cyanosilylation Reactions Promoted by a Sugar-Based Bifunctional Catalyst: Stereoselective Syntheses of Essential Building Blocks for HIV Protease Inhibitors and Bestatin

M. Kanai, H. Gröger, M. Shibasaki, 2001 .

Identifying specific conformations by using a carbohydrate scaffold: discovery of subtype-selective LPA-receptor agonists and an antagonist.

Masato Suzuki, M. Kanai, H. Arai, 2004, Angewandte Chemie.

A DyI3-catalyzed Mannich-type Reaction of 1-Methylcyclopropanecarboxylate-type Donors for the Stereoselective Synthesis of Pyrrolidines with Quaternary Stereocenters

S. Matsunaga, M. Shibasaki, H. Noda, 2008 .

Recent Advances in Cooperative Bimetallic Asymmetric Catalysis: Dinuclear Schiff Base Complexes

S. Matsunaga, M. Shibasaki, 2014 .

Carbon-Carbon Bond-Forming Reaction through a .eta.5-Pentadienylchromium Complex

M. Sodeoka, M. Shibasaki, Toshiyuki Shimizu, 1994 .

Stereospecific synthesis of exo-allylic alcohol. An efficient asymmetric synthesis of (R)-(-)-2-acetyl-5,8-dimethoxy-1,2,3,4-tetrahydro-2-naphthols

M. Sodeoka, M. Shibasaki, T. Iimori, 1985 .

A new method for the conversion of aldehydes (RCH2CHO)to acetylenes (RC&.tbnd;CH) via 1-alkenylstannanes. Application to the synthesis of 9(O)-thia-Δ6-PGI1

S. Ikegami, M. Shibasaki, Y. Torisawa, 1982 .

Synthetic studies on tautomycin. Stereoselective construction of the C1–C26 region

M. Shibasaki, S. Nakamura, 1994 .

Synthetic studies of azadirachtin. Synthesis of the cyclic acetal intermediate in the naturally occurring form

M. Sodeoka, M. Shibasaki, T. Iimori, 1989 .

A TOTAL SYNTHESIS OF (+)-HIRSUTIC ACID

S. Ikegami, M. Nishida, M. Shibasaki, 1990 .

Copper(I)-secondary diamine complex-catalyzed enantioselective conjugate boration of linear β,β-disubstituted enones.

M. Kanai, M. Shibasaki, I-Hon Chen, 2010, Organic letters.

A convenient synthesis of β-alkynylpropionic acids from β-propiolactones. Synthesis of 4,4,5,5-tetradehydro-9(O)-methano-Δ6(9α)-PGI1

M. Shibasaki, M. Shinoda, K. Iseki, 1986 .

Stereo- and regiocontrolled construction of 3-alkyl-cis-bicyclo[4.3.0]non-3-ene derivatives. An efficient synthesis of the potent homoisocarbacyclin analog

M. Shibasaki, A. Takahashi, 1987 .

On the novel reactivity of -butyldimethylsilyl ether in prostaglandin synthesis: application to total synthesis of 11--PGF2α

S. Ikegami, M. Shibasaki, Y. Torisawa, 1979 .

Novel Synthesis of Nitrogen Heterocycles Using Zirconium-Promoted Reductive Coupling. Formal Total Synthesis of Dendrobine.

M. Shibasaki, M. Mori, N. Uesaka, 1992 .

Recent Progress in Asymmetric Bifunctional Catalysis Using Multimetallic Systems

M. Kanai, S. Matsunaga, N. Kumagai, 2010 .

A New and Highly Efficient Asymmetric Route to Cyclic α‐Amino Phosphonates: The First Catalytic Enantioselective Hydrophosphonylation of Cyclic Imines Catalyzed by Chiral Heterobimetallic Lanthanoid Complexes.

M. Shibasaki, H. Sasai, K. Yamaguchi, 2010 .

Catalytic Asymmetric Addition of Diphenylphosphine Oxide to Cyclic Imines.

M. Kanai, M. Shibasaki, S. Harwood, 1999 .

Less Is More: N(BOH)2 Configuration Exhibits Higher Reactivity than the B3NO2 Heterocycle in Catalytic Dehydrative Amide Formation.

N. Kumagai, M. Shibasaki, H. Noda, 2023, Organic letters.

The efficient synthesis of chiral key intermediates for monobactam antibiotics

S. Ikegami, A. Nishida, M. Shibasaki, 1984 .

Iterative direct aldol strategy for polypropionates: enantioselective total synthesis of (-)-membrenone A and B.

N. Kumagai, M. Shibasaki, Shaoquan Lin, 2014, Organic letters.

Asymmetric Carbon–Carbon Bond‐Forming Reactions: Asymmetric Michael Reactions

M. Kanai, M. Shibasaki, 2005 .

Zirconium Alkoxides in Catalysis

M. Kanai, M. Shibasaki, S. Yamasaki, 2002 .

Direct Chlorohydrin and Acetoxy Alcohol Synthesis from Olefins Promoted by a Lewis Acid, Bis(trimethylsilyl) Peroxide and (CH3)3SiX

M. Shibasaki, R. Göttlich, Isao Sakurada, 2000 .

Catalytic asymmetric mannich-type reaction of N-alkylidene-α-aminoacetonitrile with ketimines.

Yuji Kawato, N. Kumagai, M. Shibasaki, 2015, Angewandte Chemie.

Catalytic Asymmetric Synthesis of β-Hydroxy-α-amino Acid Esters by Direct Aldol Reaction of Glycinate Schiff Bases.

M. Shibasaki, N. Yoshikawa, 2003 .

Cu(I)-catalyzed hetero-Diels-Alder reaction between Danishefsky-type siloxy dienes and ketones.

M. Kanai, M. Shibasaki, K. Oisaki, 2008, Organic letters.

The use of silyltriorganostannanes, R3SiSnR'3, in organic synthesis. A novel palladium-catalyzed tandem transmetalation-cyclization reaction

M. Shibasaki, M. Mori, N. Kaneta, 1991 .

Development of new asymmetric two-center catalysts in phase-transfer reactions

M. Shibasaki, A. Sekine, T. Ohshima, 2002 .

Restructuring of the bleomycin metal core. Novel oxygen-activating ligands with symmetrized structure

H. Satake, Y. Sugiura, M. Otsuka, 1993 .

Short synthesis of (+)-cylindricine C and formal total synthesis of (-)-lepadiformine

M. Shibasaki, T. Ohshima, H. Mihara, 2007 .

Development of New Asymmetric Two-Center Catalysts in Phase-Transfer Reactions.

M. Shibasaki, A. Sekine, T. Ohshima, 2003 .

Synthesis of Unprotected Spirocyclic β-Prolines and β-Homoprolines by Rh-Catalyzed C-H Insertion.

M. Shibasaki, H. Noda, Miguel Espinosa, 2019, Organic letters.

Catalytic asymmetric synthesis of 2,3,3,3-tetrafluoro-2-methyl-1-arylpropan-1-amines as useful building blocks for SAR-studies

N. Kumagai, M. Shibasaki, L. Brewitz, 2017 .

Dynamic ligand exchange of the lanthanide complex leading to structural and functional transformation: one-pot sequential catalytic asymmetric epoxidation-regioselective epoxide-opening process.

M. Shibasaki, T. Ohshima, R. Tsuji, 2005, Journal of the American Chemical Society.

Strategy for enantio- and diastereoselective syntheses of all possible stereoisomers of 1,3-polyol arrays based on a highly catalyst-controlled epoxidation of alpha,beta-unsaturated morpholinyl amides: application to natural product synthesis.

T. Nemoto, M. Shibasaki, T. Ohshima, 2004, Chemistry.

Reversible heterochiral aggregation/dissociation of bis(2-hydroxyphenyl)diamides driven by UV/Vis irradiation.

N. Kumagai, M. Shibasaki, Akihiro Nojiri, 2012, Angewandte Chemie.

Direct catalytic asymmetric Mannich-type reaction of thioamides.

Yuta Suzuki, R. Yazaki, N. Kumagai, 2009, Angewandte Chemie.

Simple, stereocontrolled total synthesis fof a biologically active analog of the prostaglandin endoperoxides (PGH2, PGG2)

E. Corey, K. Nicolaou, B. Samuelsson, 1976 .

Formal Total Synthesis of (+)-Wortmannin Using Catalytic Asymmetric Intramolecular Aldol Condensation Reaction.

M. Shibasaki, T. Ohshima, Takashi Mizutani, 2005 .

Stereocontrolled syntheses of phorbol analogs and evaluation of their binding affinity to PKC

M. Sodeoka, M. Shibasaki, K. Sugita, 1995 .

Stereochemical Studies. XXXIX. A Novel Method for the Preparation of Optically Active Aldehydes. Syntheses of Optically Active (R) (+)-α-Cyclocitral, (S) (+)-Dehydrovomifoliol, and (S) (+)-Abscisic Acid

M. Shibasaki, S. Terashima, S. Yamada, 1976 .

Stereochemical Studies. XXXV. A Biogenetic-type Asymmetric Cyclization. Syntheses of optically Active α-Cyclocitral and trans-α-Damascone

M. Shibasaki, S. Terashima, S. Yamada, 1975 .

Stereocontrolled Syntheses of Phorbol Analogues (I) and Evaluation of Their Binding Affinity to PKC.

M. Sodeoka, M. Shibasaki, K. Sugita, 1995 .

Synthetic approaches to phorbols via the intramolecular nitrile oxide cycloaddition : stereocontrol of the B-C ring junction

Tetsuo Yamaguchi, M. Shibasaki, H. Sasai, 1992 .

A direct total synthesis of thromboxane B2 (

E. Corey, M. Shibasaki, J. Knolle, 1977 .

ATP Depletion Assay Led to the Isolation of New 36-Membered Polyol Macrolides Deplelides A and B from Streptomyces sp. MM581-NF15.

Toshifumi Takeuchi, M. Kawada, M. Shibasaki, 2017, Organic letters.

Quinofuracins A-E, produced by the fungus Staphylotrichum boninense PF1444, show p53-dependent growth suppression.

A. Nomoto, M. Shibasaki, Takumi Watanabe, 2015, Journal of natural products.

Ba-Catalyzed Direct Mannich-Type Reactions of a β,γ-Unsaturated Ester Providing β-Methyl aza-Morita−Baylis−Hillman-Type Products

S. Matsunaga, M. Shibasaki, A. Yamaguchi, 2007 .

Synthesis of : Sugar moiety of antitumor antibiotic bleomycin

M. Tomita, M. Shibasaki, K. Takao, 1997 .

Discovery of 2-hydroxyarbekacin, a new aminoglycoside antibiotic with reduced nephrotoxicity

Yoshihiko Kobayashi, M. Shibasaki, Yoshiaki Takahashi, 2017, Journal of antibiotics (Tokyo. 1968).

The first total synthesis of the antitumor macrolide, rhizoxin

S. Iwasaki, M. Ohno, M. Shibasaki, 1993 .

Novel reactivities on tert-butyldimethylsilyl and tert-butyldiphenylsilyl ethers; Application to the synthesis of 11-epi-PGF2.ALPHA..

S. Ikegami, M. Shibasaki, Y. Torisawa, 1983 .

Simple stereospecific routes to 9-epi-prostaglandin F2α(PGF2β) and 11-epi-prostaglandin F2α

E. Corey, K. Nicolaou, M. Shibasaki, 1975 .

The First Total Synthesis of the Antitumor Macrolide, Rhizoxin (I).

S. Iwasaki, M. Ohno, M. Shibasaki, 1993 .

NOVEL REACTIVITIES ON TERT-BUTYLDIMETHYLSILYL AND TERT-BUTYLDIPHENYLSILYL ETHERS; APPLICATION TO THE SYNTHESIS OF 11-EPI-PGF2α

S. Ikegami, M. Shibasaki, Y. Torisawa, 1984 .

Total synthesis of punaglandin 4

M. Shibasaki, H. Sasai, 1987 .

Total synthesis of clavulones

Y. Ogawa, M. Shibasaki, 1985 .

Synthesis of dl-9(O)-methanoprostaglandin-I1.

M. Shibasaki, S. Ikegami, T. Okazaki, 1984, Chemical & pharmaceutical bulletin.

An Alternative Synthesis of Tamiflu®: A Synthetic Challenge and Identification of a Ruthenium‐Catalyzed Dihydroxylation Route.

M. Kanai, K. Yamatsugu, M. Shibasaki, 2009 .

Achiral Trisubstituted Thioureas as Secondary Ligands to CuI Catalysts: Direct Catalytic Asymmetric Addition of α-Fluoronitriles to Imines.

N. Kumagai, M. Shibasaki, L. Brewitz, 2019, Angewandte Chemie.

Achiral Trisubstituted Thioureas as Secondary Ligands to Cu I Catalysts: Direct Catalytic Asymmetric Addition of α‐Fluoronitriles to Imines

N. Kumagai, M. Shibasaki, L. Brewitz, 2018, Angewandte Chemie.

4-Propargyl-2-azetidinone as a Versatile Synthon for the Synthesis of β-Lactam Antibiotics : Hydrostannation and Its Reactivities

S. Ikegami, A. Nishida, M. Shibasaki, 1986 .

Pharmacologic action of oseltamivir on the nervous system.

Y. Ikegaya, M. Kanai, K. Sekimizu, 2008, Drug Discoveries & Therapeutics.

Targeting the ATG5-ATG16L1 Protein-Protein Interaction with a Hydrocarbon-Stapled Peptide Derived from ATG16L1 for Autophagy Inhibition.

Y. Fujioka, N. Noda, M. Shibasaki, 2022, Journal of the American Chemical Society.

Synthetic Strategies for Oseltamivir Phosphate (Eur. J. Org. Chem. 11/2008)

M. Kanai, M. Shibasaki, 2008 .

Synthesis of Androprostamine A and Resormycin.

M. Shibasaki, Takumi Watanabe, Hikaru Abe, 2016, Chemical & pharmaceutical bulletin.

Enantioselective Total Syntheses of (+)‐Decursin and Related Natural Compounds Using Catalytic Asymmetric Epoxidation of an Enone.

T. Nemoto, M. Shibasaki, T. Ohshima, 2003 .

Radiolabeling of catalytic subunits of pi 3-kinases with 17β-hydroxy-16α-(125I)iodowortmannin: Identification of the Gβγ-sensitive isoform as a complex composed of 45- and 100-kda subunits

T. Katada, I. Kukimoto, H. Kurosu, 1995 .

Further Studies on a Catalytic Asymmetric Synthesis of Decalin Derivatives.

M. Shibasaki, Y. Sato, Shoko Watanabe, 1992 .

Catalytic Asymmetric C-C Bond Formation: Asymmetric Synthesis of cis-Decalin Derivatives by Palladium-Catalyzed Cyclization of Prochiral Alkenyl Iodides.

M. Sodeoka, M. Shibasaki, Y. Sato, 1990 .

Catalytic Asymmetric Synthesis of a Functionalized Indolizidine Derivative. A Useful Intermediate Suitable for the Synthesis of Various Glycosidase Inhibitors.

M. Sodeoka, M. Shibasaki, S. Nukui, 1993 .

A Catalytic Asymmetric Synthesis of Hydrindans.

M. Shibasaki, Y. Sato, T. Honda, 1992 .

Asymmetric Heck Reaction‐Anion Capture Process. Catalytic Asymmetric Synthesis of the Key Intermediates for the Capnellenols.

M. Shibasaki, T. Ohshima, K. Kagechika, 1993 .

Incorporation of molecular nitrogen into organic compounds. III, reaction of titanium-nitrogen complexes with acid halides and acid anhydrides

M. Shibasaki, Y. Uozumi, M. Mori, 1990 .

Ring Construction of Bicyclic β-Lactam by Use of Palladium-Catalyzed Carbonylation.

M. Shibasaki, M. Mori, K. Kagechika, 1989 .

New anti-cancer chemicals Ertredin and its derivatives, regulate oxidative phosphorylation and glycolysis and suppress sphere formation in vitro and tumor growth in EGFRvIII-transformed cells

M. Shibuya, M. Kawada, Yoshihiko Kobayashi, 2016, BMC Cancer.

Asymmetric Heck Reactions

M. Shibasaki, F. Miyazaki, 2003 .

Utilization of Me3SiSnBu3 in Organic Synthesis. Part 1. Generation of a Stannyl Anion from Me3SiSnBu3 and R4NX.

M. Shibasaki, M. Mori, Naohiro Isono, 1993 .

Highly stereoselective synthesis of exocyclic tetrasubstituted enol ethers and olefins. A synthesis of nileprost

M. Sodeoka, M. Shibasaki, H. Sasai, 1989 .

Reaction of Metal Free Bu3Sn‐ Generated from Bu3SnSiMe3‐R4NX with an Aryl or Vinyl Halide.

M. Shibasaki, M. Mori, Naohiro Isono, 1992 .

Synthetic studies of viridiofungins, broad-spectrum antifungal agents and serine palmitoyl transferase inhibitors

N. Kumagai, M. Shibasaki, 2017, The Journal of Antibiotics.

Alkylated Levoglucosan in Organic Synthesis. : A Formal Total Synthesis of Elaiophylin

K. Arata, M. Shibasaki, Y. Ban, 1990 .

Catalysis and Multi-Component Reactions

O. V. Koryakova, M. Khorasani, D. Dorsch, 2011 .

Synthesis and Determination of Absolute Configuration of Lentztrehalose A.

M. Shibasaki, Takumi Watanabe, Ming Zhang, 2015, Chemical and pharmaceutical bulletin.

Developmental Changes in P-Glycoprotein Function in the Blood–Brain Barrier of Nonhuman Primates: PET Study with R-11C-Verapamil and 11C-Oseltamivir

C. Yokoyama, H. Onoe, Yasuyoshi Watanabe, 2011, The Journal of Nuclear Medicine.

Synthesis of 1-O-acylglycerol 2,3-cyclic phosphate : determination of the absolute structure of PHYLPA, a specific inhibitor of DNA polymerase α

M. Shibasaki, Susumu Kobayashi, K. Murakami‐Murofushi, 1993 .

Lysophosphatidylmethanol is a pan lysophosphatidic acid receptor agonist and is produced by autotaxin in blood.

N. Matsuki, R. Taguchi, M. Kanai, 2009, Journal of biochemistry.

Photoaffinity labeling of PKC isozymes by phorbol ester derivatives.

M. Sodeoka, M. Shibasaki, K. Uotsu, 1998, Bioorganic & medicinal chemistry.

New Asymmetric Reactions Using a Gallium Complex: A Highly Enantioselective Ring Opening of Epoxides with Thiols Catalyzed by a Gallium×Lithium×Bis(binaphthoxide) Complex.

M. Shibasaki, H. Sasai, Takehiko Iida, 1997 .

Direct Catalytic Asymmetric 1,6-Conjugate Addition of Amides to p-Quinone Methides.

N. Kumagai, M. Shibasaki, Bo Sun, 2018, Organic letters.

Direct Catalytic Asymmetric Aldol Reaction of α-Vinyl Acetamide.

Toshifumi Takeuchi, N. Kumagai, M. Shibasaki, 2018, The Journal of organic chemistry.

Direct Catalytic Asymmetric Mannich-Type Reaction en Route to α-Hydroxy-β-amino Acid Derivatives.

N. Kumagai, M. Shibasaki, Bo Sun, 2018, Organic letters.

Acremopeptin, a new peptaibol from Acremonium sp. PF1450

M. Kawada, M. Shibasaki, R. Sawa, 2017, The Journal of Antibiotics.

Protection of C. elegans from Anoxia by HYL-2 Ceramide Synthase

M. Kanai, S. Takasuga, Qinhong Cao, 2017 .

A general procedure for the catalytic hydrogenolysis of N-benzylamines under extremely mild conditions

M. Shibasaki, Y. Ban, K. Yoshida, 1988 .

A guanine derivative as a new MEK inhibitor produced by Streptomyces sp. MK63-43F2

M. Takekawa, M. Kawada, M. Shibasaki, 2017, The Journal of Antibiotics.

Structure–activity relationship study of intervenolin derivatives: synthesis, antitumor, and anti-Helicobacter pylori activities

A. Nomoto, M. Kawada, M. Shibasaki, 2013 .

A novel synthesis of prostaglandin D2

Y. Ogawa, M. Shibasaki, Makoto Nunomoto, 1986 .

Rare Variants of IFIH 1 , a Gene Implicated in Antiviral Responses , Protect Against Type 1 Diabetes

M. Kanai, Takehiko Sasaki, M. Frohman, 2009 .

Inhibition of MAO-A and stimulation of behavioural activities in mice by the inactive prodrug form of the anti-influenza agent oseltamivir

Y. Kirino, M. Kanai, M. Hiasa, 2013, British journal of pharmacology.

Catalytic Oligopeptide Synthesis.

N. Kumagai, M. Shibasaki, H. Noda, 2018, Organic Letters.

Catalytic asymmetric cyano-phosphorylation of aldehydes promoted by heterobimetallic YLi3tris(binaphthoxide) (YLB) complex

S. Matsunaga, M. Shibasaki, Y. Abiko, 2004 .

Coccoquinones A and B, new anthraquinone derivatives produced by Staphylotrichum coccosporum PF1460

A. Nomoto, M. Kawada, M. Shibasaki, 2015, The Journal of Antibiotics.

Catalytic Asymmetric 1,3-Dipolar Cycloaddition of α,β-Unsaturated Amide and Azomethine Imine.

N. Kumagai, M. Shibasaki, Z. Li, 2020, Chemical & pharmaceutical bulletin.

Traceless Electrophilic Amination for the Synthesis of Unprotected Cyclic β-Amino Acids.

M. Shibasaki, H. Noda, Miguel Espinosa, 2019, Journal of the American Chemical Society.

A biogenetic-type asymmetric cyclization syntheses of optically active α-cyclocitral and trans-α-damascone

M. Shibasaki, S. Terashima, S. Yamada, 1973 .

Determination of the C-7,9,12,13,17 and 18 stereochemistries of tautomycetin. Synthesis of the tautomycetin degradation product

M. Sodeoka, M. Shibasaki, Jiangkun Dai, 1996 .

Total synthesis of the carbon analog of Δ6-PGI1

S. Ikegami, M. Shibasaki, K. Iseki, 1980 .

An Efficient Synthesis of 7-endo-t-Butyldimethylsilyloxy-bicyclo[3.3.0]oct-8-en-2-one

S. Ikegami, M. Shibasaki, K. Iseki, 1980 .

1,2-CARBONYL TRANSPOSITION OF CIS-BICYCLO[3.3.O]OCTAN-2-ONE TO ITS 3-ONE SKELETON: APPLICATION TO SYNTHESES OF dl-HIRSUTIC ACID AND dl-9(0)-METHANOPROSTACYCLIN

S. Ikegami, M. Shibasaki, M. Yamazaki, 1981 .

1,2-CARBONYL TRANSPOSITION OF CIS-BICYCLO(3.3.0)OCTAN-2-ONE TO ITS 3-ONE SKELETON: APPLICATION TO SYNTHESES OF DL-HIRSUTIC ACID AND DL-9(0)-METHANOPROSTACYCLIN

S. Ikegami, M. Shibasaki, M. Yamazaki, 1982 .

Catalytic Asymmetric Epoxidation of a,-Unsaturated Esters with Chiral YttriumBiaryldiol Complexes

S. Matsunaga, M. Shibasaki, H. Kakei, 2007 .

Mizoroki-Heck Reaction

W. Itano, M. Shibasaki, T. Ohshima, 2011 .

Aprosamine Derivatives Active against Multidrug-Resistant Gram-Negative Bacteria.

M. Shibasaki, C. Hayashi, M. Igarashi, 2023, ACS infectious diseases.

Direct Catalytic Asymmetric Reactions of Thioamides: Toward a Stereocontrolled Synthesis of 1,3‐Polyols.

Yuta Suzuki, M. Iwata, R. Yazaki, 2010 .

Chembiomolecular Science

M. Iino, M. Shibasaki, H. Osada, 2013, Springer Japan.

Enantioselective Total Synthesis of Epothilone A Using Multifunctional Asymmetric Catalyses.

Shibasaki, M. Shibasaki, D. Sawada, 2000, Angewandte Chemie.

Monotherapy with a novel intervenolin derivative, AS‐1934, is an effective treatment for Helicobacter pylori infection

M. Kawada, M. Shibasaki, Takumi Watanabe, 2018, Helicobacter.

A C4N4 Diaminopyrimidine Fluorophore.

N. Noda, N. Takizawa, N. Kumagai, 2019, Chemistry.

Cooperative activation of alkyne and thioamide functionalities; direct catalytic asymmetric conjugate addition of terminal alkynes to α,β-unsaturated thioamides.

R. Yazaki, N. Kumagai, M. Shibasaki, 2011, Chemistry, an Asian journal.

Catalytic generation of α-CF3 enolate: direct catalytic asymmetric Mannich-type reaction of α-CF3 amide.

N. Kumagai, M. Shibasaki, L. Yin, 2014, Journal of the American Chemical Society.

syn-Selective catalytic asymmetric 1,4-addition of alpha-ketoanilides to nitroalkenes under dinuclear nickel catalysis.

S. Matsunaga, Yingjie Xu, M. Shibasaki, 2010, Organic letters.

Direct Catalytic Asymmetric Addition of α-Fluoronitriles to Aldehydes.

N. Kumagai, M. Shibasaki, Z. Li, 2020, Chemistry.

Direct catalytic asymmetric vinylogous Mannich-type reaction of γ-butenolides with ketimines.

N. Kumagai, M. Shibasaki, L. Yin, 2013, Angewandte Chemie.

Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes.

S. Matsunaga, M. Shibasaki, 2014, Chemical communications.

Synthesis of novobiocin derivatives and evaluation of their antigonococcal activity and pharmacokinetics.

M. Shibasaki, C. Hayashi, M. Igarashi, 2023, Bioorganic & medicinal chemistry.

Stereodivergent direct catalytic asymmetric Mannich-type reactions of α-isothiocyanato ester with ketimines.

S. Matsunaga, M. Shibasaki, G. Lu, 2011, Angewandte Chemie.

Stereoselective Total Synthesis of KAE609 via Direct Catalytic Asymmetric Alkynylation to Ketimine.

N. Kumagai, M. Shibasaki, Hisashi Takada, 2015, Organic letters.

Direct catalytic addition of alkylnitriles to aldehydes by transition-metal/NHC complexes.

N. Kumagai, M. Shibasaki, D. Sureshkumar, 2014, Chemistry.

On the mechanism of enzymatic inactivation of bleomycin. The β-aminoalaninamide moiety as an enzyme-dependent molecular switch

K. Maeda, Y. Sugiura, M. Otsuka, 1994 .

Self-assembling neodymium/sodium heterobimetallic asymmetric catalyst confined in a carbon nanotube network.

N. Kumagai, M. Shibasaki, T. Ogawa, 2013, Angewandte Chemie.

anti-Selective Catalytic Asymmetric Nitroaldol Reaction of α-Keto Esters: Intriguing Solvent Effect, Flow Reaction, and Synthesis of Active Pharmaceutical Ingredients.

N. Kumagai, M. Shibasaki, Tomoya Karasawa, 2018, Journal of the American Chemical Society.

anti-Selective catalytic asymmetric nitroaldol reaction via a heterobimetallic heterogeneous catalyst.

N. Kumagai, M. Shibasaki, Makoto Kobayashi, 2009, Journal of the American Chemical Society.

A heterobimetallic Pd/La/Schiff base complex for anti-selective catalytic asymmetric nitroaldol reactions and applications to short syntheses of beta-adrenoceptor agonists.

S. Matsunaga, M. Shibasaki, Shinya Handa, 2008, Angewandte Chemie.

Catalytic asymmetric synthesis of 2,2-disubstituted oxetanes from ketones by using a one-pot sequential addition of sulfur ylide.

S. Matsunaga, M. Shibasaki, G. Lu, 2009, Angewandte Chemie.

Catalytic enantioselective intermolecular reductive aldol reaction to ketones

M. Kanai, M. Shibasaki, Dongbo Zhao, 2006 .

Catalytic asymmetric epoxidation of alpha,beta-unsaturated phosphane oxides with a Y(O-iPr)3/biphenyldiol complex.

S. Matsunaga, So-Young Park, M. Shibasaki, 2008, Chemistry, an Asian journal.

Catalytic asymmetric cyclopropanation of enones with dimethyloxosulfonium methylide promoted by a La-Li3-(biphenyldiolate)3 + NaI complex.

S. Matsunaga, M. Shibasaki, H. Kakei, 2007, Journal of the American Chemical Society.

Direct catalytic asymmetric addition of allyl cyanide to ketones via soft Lewis acid/hard Brønsted base/hard Lewis base catalysis.

R. Yazaki, N. Kumagai, M. Shibasaki, 2010, Journal of the American Chemical Society.

Asymmetric reductive Mannich reaction to ketimines catalyzed by a Cu(I) complex.

M. Kanai, M. Shibasaki, K. Oisaki, 2008, Journal of the American Chemical Society.

A heterobimetallic Ni/La-salan complex for catalytic asymmetric decarboxylative 1,4-addition of malonic acid half-thioester.

S. Matsunaga, M. Shibasaki, Shinsuke Mouri, 2010, Chemistry - An Asian Journal.

Titelbild: Multicenter Strategy for the Development of Catalytic Enantioselective Nucleophilic Alkylation of Ketones: Me2Zn Addition to α‐Ketoesters (Angew. Chem. 44/2003)

M. Kanai, M. Shibasaki, K. Funabashi, 2003 .

Asymmetric Heck Reaction

M. Shibasaki, T. Ohshima, E. Vogl, 2004 .

Quaternary β2,2 -Amino Acids: Catalytic Asymmetric Synthesis and Incorporation into Peptides by Fmoc-Based Solid-Phase Peptide Synthesis.

M. Shibasaki, H. Noda, Jin-Sheng Yu, 2018, Angewandte Chemie.