R. S. Brown

发表

Structure of yeast phenylalanine tRNA at 3 Å resolution

B. Clark, A. Klug, J. Finch, 1974, Nature.

Mass resolution improvement by incorporation of pulsed ion extraction in a matrix-assisted laser desorption/ionization linear time-of-flight mass spectrometer.

R. S. Brown, J. J. Lennon, Robert S. Brown, 1995, Analytical chemistry.

Crystallographic and biochemical investigation of the lead(II)-catalyzed hydrolysis of yeast phenylalanine tRNA.

Aaron Klug, R. S. Brown, J. C. Dewan, 1985 .

Photoelectron-determined core binding energies and predicted gas-phase basicities for the 2-hydroxypyridine .dblarw. 2-pyridone system

J. Vederas, R. S. Brown, A. Tse, 1980 .

An AM1 calculational study of the protonation and reactions of 3,4-dihydro-2-oxo-1,4-ethanoquinoline, 3,4-dihydro-2-oxo-1,4-propanoquinoline, 3,3,4,5-tetrahydro-2-oxo-1,5-ethanobenzazepine, 3,3,4,5-tetrahydro-2-oxo-1,5-propanobenzazepine, and N-methyl-4-bromo-2-methylacetanilide

N. H. Werstiuk, R. S. Brown, Q. Wang, 1996 .

The crystal structure of EcoRV endonuclease and of its complexes with cognate and non‐cognate DNA fragments.

K S Wilson, D W Banner, D Tsernoglou, 1993, The EMBO journal.

Experimental Investigation of the Primary and Secondary Deuterium Kinetic Isotope Effects for Epoxidation of Alkenes and Ethylene with m-Chloroperoxybenzoic Acid.

R. S. Brown, Terry Koerner, H. Slebocka-Tilk, 1999, The Journal of organic chemistry.

Structure of nucleosome core particles of chromatin

L. C. Lutter, M. Levitt, A. Klug, 1977, Nature.

Negative chemical ionization and accurate mass measurement applications for a linked gas chromatography/Fourier transform infrared spectrometer/Fourier transform mass spectrometer

C. Wilkins, R. S. Brown, C. L. Johlman, 1986 .

Fourier transform infrared evidence for proline structural changes during the bacteriorhodopsin photocycle.

S. Pelletier, P. Roepe, J. Herzfeld, 1989, Proceedings of the National Academy of Sciences of the United States of America.

Cu(II)-Mediated decomposition of phosphorothionate P=S pesticides. Billion-fold acceleration of the methanolysis of fenitrothion promoted by a simple Cu(II)-ligand system.

R. S. Brown, A. A. Neverov, 2004, Organic & biomolecular chemistry.

DFT computational study of the methanolytic cleavage of DNA and RNA phosphodiester models promoted by the dinuclear Zn(II) complex of 1,3-bis(1,5,9-triazacyclododec-1-yl)propane.

N. Mosey, R. S. Brown, Christopher I. Maxwell, 2013, Journal of the American Chemical Society.

2004 Bader Award LectureMetal-ion-catalyzed acyl and phosphoryl transfer reactions to alcohols: La3+-promoted alcoholysis of activated amides, carboxylate esters, and neutral organophosphorus esters

G. Gibson, R. S. Brown, A. A. Neverov, 2004 .

Aspects of the hydrolysis of formamide: revisitation of the water reaction and determination of the solvent deuterium kinetic isotope effect in base

R. S. Brown, F. Sauriol, M. Monette, 2002 .

Ion detection limitations to mass resolution in matrix-assisted laser desorption time-of-flight mass spectrometry.

R. S. Brown, N. L. Gilfrich, 1992, Rapid communications in mass spectrometry : RCM.

Maximum-Likelihood Restoration Data Processing Techniques Applied to Matrix-Assisted Laser Desorption Mass Spectra

R. S. Brown, N. L. Gilfrich, 1993 .

N-[(R)-1-Phenylethyl]thiobenzamide

H. Fun, R. S. Brown, S. Chantrapromma, 2006 .

Matrix Isolation/Fourier Transform Infrared Spectrometry of Laser-Desorbed Species

R. S. Brown, B. Carr, B. L. Carr, 1995 .

Proton inventory study of the base-catalyzed hydrolysis of formamide. Consideration of the nucleophilic and general base mechanisms.

R. S. Brown, H. Ślebocka-tilk, A. A. Neverov, 2003, Journal of the American Chemical Society.

Opimizing signal and mass resolution for matrix‐assisted laser desorption utilizing a linear time‐of‐flight mass spectrometer

R. S. Brown, N. L. Glfrich, 1992 .

Design and performance of a matrix-assisted laser desorption time-of-flight mass spectrometer utilizing a pulsed nitrogen laser

R. S. Brown, N. L. Gilfrich, 1991 .

Fourier Transform Infrared Spectrometry Coupled with Cryogenic Trapping for the Study of Laser-Desorbed Species

R. S. Brown, N. L. Gilfrich, 1990 .

Density functional theory study of methoxide promoted and Zn(II)‐complexed methoxide promoted cleavages of aryl‐ and alkyl acetates in methanol. Transition from concerted to stepwise processes as a function of leaving group ability

N. Mosey, R. S. Brown, Christopher I. Maxwell, 2014 .

A mechanistic study of the [La2(OCH3)2]4+- and [(1,5,9-triazacyclodo-decane):Zn:(OCH3)]+-catalyzed methanolysis of carbonates: possible application for the recycling of bisphenol A polycarbonates

R. S. Brown, Christopher I. Maxwell, Le Chen, 2013 .

Trifunctional metal ion-catalyzed solvolysis: Cu(II)-promoted methanolysis of N,N-bis(2-picolyl) benzamides involves unusual Lewis acid activation of substrate, delivery of coordinated nucleophile, powerful assistance of the leaving group departure.

R. S. Brown, Christopher I. Maxwell, Mark A. R. Raycroft, 2012, Inorganic chemistry.

Cu(II)-promoted methanolysis of N,N-dipicolylacetamide. multistep activation by decoupling of > ̈̈N-C═O resonance via Cu(II)-N binding, delivery of the Cu(II):((-)OCH3) nucleophile, and metal ion assistance of the departure of the leaving group.

R. S. Brown, Christopher I. Maxwell, A. A. Neverov, 2012, The Journal of organic chemistry.

Methanolysis of thioamide promoted by a simple palladacycle is accelerated by 10(8) over the methoxide-catalyzed reaction.

N. Mosey, R. S. Brown, Christopher I. Maxwell, 2011, Journal of the American Chemical Society.

Linked gas chromatography/Fourier transform infrared/Fourier transform mass spectrometry with integrated electron impact and chemical ionization.

C. Wilkins, R. S. Brown, D. Laude, 1984, Analytical chemistry.

Quantification of 2,3,7,8-TCDD by GCMS

P. W. Jones, R. S. Brown, K. Pettit, 1990 .

La(3+)-Catalyzed methanolysis of hydroxypropyl-p-nitrophenyl phosphate as a model for the RNA transesterification reaction.

R. S. Brown, A. A. Neverov, J. S. Tsang, 2003, Journal of the American Chemical Society.

Direct O-acylation of small molecules containing CO2----HN .rarw. HO units by a distorted amide: enhancement of amine basicity by a pendant carboxylate in a serine protease mimic

K. Skorey, R. S. Brown, V. Somayaji, 1989 .

Addition of Bromine to Ketenes and Bisketenes: Electrophilic Attack at Carbonyl Carbon and Neighboring Group Participation.

A. Lough, K. Peters, R. S. Brown, 1998, The Journal of organic chemistry.

Basonuclin is associated with the ribosomal RNA genes on human keratinocyte mitotic chromosomes.

J. Biegel, R. S. Brown, H. Tseng, 1999, Journal of cell science.

The influence of altered amidic resonance on the infrared and carbon-13 and nitrogen-15 NMR spectroscopic characteristics and barriers to rotation about the N-C(O) bond in some anilides and toluamides

B. Santarsiero, A. J. Bennet, R. S. Brown, 1991 .

Influence of remote substituents on ionization potential. Part II. Enamines

R. S. Brown, 1976 .

The crystal structure of EcoRV endonuclease and of its complexes with cognate and non-cognate DNA fragments.

R. Bryan, F. Winkler, D. Banner, 1993 .

Laser-desorption Fourier transform mass spectrometry of synthetic porphyrins.

C. Wilkins, R. S. Brown, 1986, Analytical chemistry.

Primary structure and genetic organization of phage T4 DNA ligase.

A. Tsugita, J. Armstrong, R. S. Brown, 1983, Nucleic acids research.

Evolution of Models for the Structural, Spectroscopic, and Catalytic Properties of Carbonic Anhydrase

R. S. Brown, 1987 .

Observation of an unusually large inverse secondary deuterium kinetic isotope effect for the reaction of a sterically congested olefin with bromine

R. W. Nagorski, R. S. Brown, H. Ślebocka-tilk, 1994 .

Catalytic decomposition of simulants for chemical warfare V agents: highly efficient catalysis of the methanolysis of phosphonothioate esters.

R. S. Brown, A. A. Neverov, Stephanie A Melnychuk, 2006, Angewandte Chemie.

Dissection of Nucleophilic and General Base Roles for the Reaction of Phosphate with p-Nitrophenyl Thiolacetate, p-Nitrophenyl Thiolformate, and Phenyl Thiolacetate.

R. S. Brown, M. Gill, A. A. Neverov, 1997, The Journal of organic chemistry.

The Influence of Altered Amidic Resonance on the IR and 13C and 15N NMR Spectroscopic Characteristics and Barriers to Rotation About the N- C(O) Bond in Some Anilides and Toluamides

B. Santarsiero, A. J. Bennet, R. S. Brown, 1992 .

Carbonic anhydrase models. 5. Tris(4,5-di-n-propyl-2-imidazolyl)phosphine-zinc(2+) and bis(4,5-di-isopropyl-2-imidazolyl)-2-imidazolylphosphine-zinc(2+). Catalysts facilitating hydrogen carbonate .dblarw. carbon dioxide (HCO3- .dblarw. CO2) interconversion

R. S. Brown, H. Ślebocka-tilk, J. Cocho, 1984 .

Distorted amides as models for activated peptide N-C:O units produced during enzyme-catalyzed acyl transfer reactions. 1. The mechanism of hydrolysis of 3,4-dihydro-2-oxo-1,4-ethanoquinoline and 2,3,4,5-tetrahydro-2-oxo-1,5-ethanobenzazepine

R. S. Brown, V. Somayaji, 1986 .

Efficient Methanolytic Cleavage of Phosphate, Phosphonate, and Phosphonothioate Esters Promoted by Solid Supported Lanthanide Ions

R. S. Brown, A. A. Neverov, Tamer Andrea, 2010 .

Conservation of the molecular structure of yeast phenylalanine transfer RNA in two crystal forms.

A. Klug, J. Finch, J. Robertus, 1974, Proceedings of the National Academy of Sciences of the United States of America.

Development of metal ion promoted alcoholysis as a rapid methodology for the destruction of organophosphorus CW agents, their simulants and pesticides

R. S. Brown, A. A. Neverov, 2010 .

Biomimetic cleavage of RNA models promoted by a dinuclear Zn(II) complex in ethanol. Greater than 30 kcal/mol stabilization of the transition state for cleavage of a phosphate diester.

R. S. Brown, C. Liu, A. A. Neverov, 2008, Journal of the American Chemical Society.

Metal-catalyzed alcoholysis reactions of carboxylate and organophosphorus esters

R. S. Brown, A. A. Neverov, 2007 .

Reductive amination of aldehydes with sodium borohydride and lithium aluminum hydride in the presence of lithium perchlorate

R. S. Brown, M. R. Saidi, A. Ziyaei-Halimjani, 2007 .

Zinc(2+)-catalyzed decomposition of a tris(imidazol-2-yl)phosphine. Crystal and molecular structure of [bis(4,5-diisopropylimidazol-2-yl)phosphinic acid]dichlorozinc hydrate

R. S. Brown, R. Ball, J. Cocho, 1984 .

Solvent induced cooperativity of Zn(II) complexes cleaving a phosphate diester RNA analog in methanol.

R. S. Brown, Mark F. Mohamed, A. A. Neverov, 2012, Organic & biomolecular chemistry.

Cu(II)-ion-catalyzed solvolysis of N,N-bis(2-picolyl)ureas in alcohol solvents: evidence for cleavage involving nucleophilic addition and strong assistance of bis(2-picolyl)amine leaving group departure.

R. S. Brown, A. A. Neverov, Mei-Ni Belzile, 2014, Inorganic chemistry.

Rapid three-step cleavage of RNA and DNA model systems promoted by a dinuclear Cu(II) complex in methanol. energetic origins of the catalytic efficacy.

R. S. Brown, C. Liu, Zhong-lin Lu, 2007, Journal of the American Chemical Society.

Investigation of the effect of oxy bridging groups in dinuclear Zn(II) complexes that catalyze the cleavage of a simple phosphate diester RNA analogue.

R. S. Brown, Mark F. Mohamed, A. A. Neverov, 2009, Inorganic chemistry.

Mono and dinuclear M2+ chelates as catalysts for the hydrolysis of organophosphate triesters

R. S. Brown, H. Ślebocka-tilk, R. Clewley, 1989 .

Biomimetic and Nonbiological Dinuclear Mx+ Complex‐Catalyzed Alcoholysis Reactions of Phosphoryl Transfer Reactions

R. S. Brown, 2011 .

Solvent deuterium kinetic isotope effects for the methanolyses of neutral C=O, P=O and P=S esters catalyzed by a triazacyclododecane : Zn(2+)-methoxide complex.

R. S. Brown, Christopher I. Maxwell, A. A. Neverov, 2005, Organic & biomolecular chemistry.

Intramolecular Catalysis of Thiol Ester Hydrolysis by a Tertiary Amine and a Carboxylate

R. S. Brown, A. Aman, 1997 .

Enantioselective conjugate addition to α,β-unsaturated esters and amides mediated by lithium perchlorate

R. S. Brown, F. Rajabi, M. R. Saidi, 2005 .

On the question of stepwise vs. concerted cleavage of RNA models promoted by a synthetic dinuclear Zn(II) complex in methanol: implementation of a noncleavable phosphonate probe.

D. Edwards, R. S. Brown, W. Tsang, 2010, Organic & biomolecular chemistry.

Dinuclear Zn(II) catalysts as biomimics of RNA and DNA phosphoryl transfer enzymes: changing the medium from water to alcohol provides enzyme‐like rate enhancements

D. Edwards, R. S. Brown, W. Tsang, 2010 .

Dinuclear Zn(II) complex promotes cleavage and isomerization of 2-hydroxypropyl alkyl phosphates by a common cyclic phosphate intermediate.

D. Edwards, Nicholas H Williams, R. S. Brown, 2009, Journal of the American Chemical Society.

The dinuclear Zn(II) complex catalyzed cyclization of a series of 2-hydroxypropyl aryl phosphate RNA models: progressive change in mechanism from rate-limiting P-O bond cleavage to substrate binding.

R. S. Brown, C. Liu, Zhong-lin Lu, 2007, Journal of the American Chemical Society.

A reductionist biomimetic model system that demonstrates highly effective Zn(II)-catalyzed cleavage of an RNA model.

R. S. Brown, C. Liu, A. A. Neverov, 2007, Inorganic chemistry.

Combination of a dinuclear Zn2+ complex and a medium effect exerts a 10(12)-fold rate enhancement of cleavage of an RNA and DNA model system.

Christopher J. White, R. S. Brown, Mark F. Mohamed, 2006, Journal of the American Chemical Society.

A simple DNase model system comprising a dinuclear Zn(II) complex in methanol accelerates the cleavage of a series of methyl aryl phosphate diesters by 10(11)-10(13).

Christopher J. White, R. S. Brown, C. Liu, 2008, Journal of the American Chemical Society.

Chapter One - Metal Ion-Promoted Leaving Group Assistance in the Light Alcohols

R. S. Brown, 2015 .

Mechanistic studies of La3+- and Zn2+-catalyzed methanolysis of aryl phosphate and phosphorothioate triesters. Development of artificial phosphotriesterase systems.

R. S. Brown, A. A. Neverov, J. S. Tsang, 2005, Organic & biomolecular chemistry.

Catalysis of the methanolysis of activated amides by divalent and trivalent metal ions. The effect of Zn(2+), Co(2+), and La(3+) on the methanolysis of acetylimidazole and its (NH(3))(5)Co(III) complex.

R. S. Brown, A. A. Neverov, P. J. Montoya-Pelaez, 2001, Journal of the American Chemical Society.

Cleavage of models for RNA mediated by a diZn(II) complex of bis[1,4-N1,N1′(1,5,9-triazacyclododecanyl)]butane in methanol and ethanol

R. S. Brown, C. Liu, A. A. Neverov, 2009 .

Carbonic Anhydrases: The Mechanistic, Spectroscopic, and Model Studies

R. S. Brown, 1990 .

Synthesis and physical studies of pyridine and imidazole containing tridentate metal binding ligands

R. S. Brown, J. Huguet, 1980 .

Hydrolysis of neutral phosphate and phosphonate esters catalysed by Co2+-chelates of tris-imidazolyl phosphines

R. S. Brown, M. Zamkanei, 1985 .

ZINC(2+)-CATALYZED DECOMPOSITION OF A TRIS(IMIDAZOL-2-YL)PHOSPHINE. CRYSTAL AND MOLECULAR STRUCTURE OF (BIS(4,5-DIISOPROPYLIMIDAZOL-2-YL)PHOSPHINIC ACID)DICHLOROZINC HYDRATE

R. S. Brown, R. Ball, J. Cocho, 1984 .

Comparison of Cu(II)-promoted leaving group stabilization of the cleavage of a homologous set of phosphate mono-, di-, and triesters in water, methanol, and ethanol.

R. S. Brown, C. Liu, Mark A. R. Raycroft, 2012, Inorganic chemistry.

Demonstration of prominent Cu(II)-promoted leaving group stabilization of the cleavage of a homologous set of phosphate mono-, di-, and triesters in methanol.

R. S. Brown, Christopher I. Maxwell, C. Liu, 2010, Journal of the American Chemical Society.

Equilibrium Formation of Anilides from Carboxylic Acids and Anilinesin Aqueous Acidic Media

R. S. Brown, A. Aman, 1999 .

Kinetic resolution of esters via metal catalyzed methanolysis reactions.

R. S. Brown, Christopher I. Maxwell, A. A. Neverov, 2008, Organic & biomolecular chemistry.

Metal ion promoted transesterifications of carboxylate esters. A structure/activity study of the efficacy of Zn2+ and La3+ to catalyze the methanolysis of some aryl and aliphatic esters.

R. S. Brown, A. A. Neverov, N. Sunderland, 2005, Organic & biomolecular chemistry.

The Hydrolysis of Phthalide, Thiophthalide, and Methyl o-Methoxybenzoate in Highly Alkaline Media. Curvature in the khyd vs [OH-] Profile

R. Mcdonald, R. S. Brown, B. A. Kellogg, 1994 .

1-(1-Ethoxyethyl): an effective protecting group for imidazole nitrogen

R. S. Brown, S. Manoharan, 1988 .

Photoelectron spectra of cyclopropylcarbinyltrimethyltin and allyltrimethyltin

R. S. Brown, D. F. Eaton, T. Traylor, 1974 .

The question of reversible formation of bromonium ions during the course of electrophilic bromination of olefins. 1. Formal transfer of bromine(1+) ion to scavenger olefins from the solvolytically generated bromonium ions of cyclohexene and cyclopentene

R. S. Brown, R. Gedye, K. Kopecky, 1984 .

Crystallographic and biochemical investigation of the lead(II)-catalyzed hydrolysis of yeast phenylalanine tRNA.

A Klug, A. Klug, J. Dewan, 1985, Biochemistry.

Tris(imidazole)-containing phosphine:M2+ complexes as biomimetic catalysts. Importance of a L:M2+−OH− in the catalyzed bimolecular hydrolysis of p-nitrophenyl picolinate

R. S. Brown, M. Zamkanei, J. Cocho, 1984 .

Carbonic anhydrase models. 4. [Tris[(4,5-dimethyl-2-imidazolyl)methyl]phosphine oxide]cobalt(2+), a small-molecule mimic of the spectroscopic properties of cobalt(II) carbonic anhydrase

R. S. Brown, D. Salmon, S. Kusuma, 1982 .

Letter: Very fast zinc-catalyzed hydrolysis of an anhydride. A model for the rate and mechanism of carboxypeptidase A catalysis.

R. S. Brown, J. Eisenach, R. Breslow, 1975, Journal of the American Chemical Society.

The Fates of Bromonium Ions in Solution: A Very Short Lifetime with Many Different Endings

R. S. Brown, 1996 .

Enzyme-like acceleration for the hydrolysis of a DNA model promoted by a dinuclear Zn(II) catalyst in dilute aqueous ethanol.

R. S. Brown, C. Liu, A. A. Neverov, 2008, Journal of the American Chemical Society.

Chloro[2-(dimethylamino)benzyl-κ 2 C 1 , N ][4-(dimethylamino)pyridine-κ N 1 ]palladium(II)

Hoong-Kun Fun, Suchada Chantrapromma, Zhong-Lin Lu, 2006 .

X-ray diffraction study of a new crystal form of the nucleosome core showing higher resolution.

A. Klug, T. Richmond, J. Finch, 1981, Journal of molecular biology.

Bis(pyridine)-based bromonium ions. Molecular structures of bis(2,4,6-collidine)bromonium perchlorate and bis(pyridine)bromonium triflate and the mechanism of the reactions of 1,2-bis(2'-pyridylethynyl)benzenebrominum triflate and bis(pyridine)bromonium triflate with acceptor olefins.

R. S. Brown, A. A. Neverov, H. Feng, 2003, The Journal of organic chemistry.

Stable Bromonium and Iodonium Ions of the Hindered Olefins Adamantylideneadamantane and Bicyclo[3.3.1]nonylidenebicyclo[3.3.1]nonane. X-Ray Structure, Transfer of Positive Halogens to Acceptor Olefins, and ab Initio Studies

R. W. Nagorski, B. Santarsiero, A. J. Bennet, 1994 .

The intramolecular hydrogen bond in malonaldehyde as determined by x-ray photoelectron spectroscopy

R. S. Brown, 1977 .

ELECTROPHILIC BROMINATION OF ETHYLENE AND ETHYLENE-D4. A COMBINED EXPERIMENTAL AND THEORETICAL STUDY

M. Klobukowski, R. S. Brown, T. Koerner, 1998 .

Reversible formation of bromonium ions. Preferential reaction of Br- on the Br+ of the bromonium ion produced from the solvolysis of trans-2-bromocyclohexyl triflate in methanol or acetic acid containing added bromide

R. W. Nagorski, L. Alvarado, R. S. Brown, 1993 .

Long chain ß-aminoethanols as micellar catalysts for the hydrolysis of diphenyl-p-nitrophenyl phosphate. The observation of an unusual enhancement of catalysis in the presence of added polyols

R. S. Brown, H. Ślebocka-tilk, H. Oumar-Mahamat, 1999 .

Trisimidazolylphosphine: M(II); Models for the metal-binding site in carbonic anhydrase

R. S. Brown, 1983 .

Pb(II)-catalysed cleavage of the sugar–phosphate backbone of yeast tRNAPhe—implications for lead toxicity and self-splicing RNA

A. Klug, B. Hingerty, J. Dewan, 1983, Nature.

Study on the transesterification of methyl aryl phosphorothioates in methanol promoted by Cd(II), Mn(II), and a synthetic Pd(II) complex.

D. Edwards, R. S. Brown, A. A. Neverov, 2011, Inorganic chemistry.

Mechanistic Evaluation of the Transfer of Br(+) from Bis(sym-collidine)bromonium Triflate to Acceptor Alkenes.

R. S. Brown, A. A. Neverov, 1998, The Journal of organic chemistry.

Electrophilic Bromination of 7-Norbornylidene-7'-Norbornane. The Observation of an Unusually Large Inverse Deuterium Kinetic Isotope Effect

R. W. Nagorski, R. Mcdonald, R. S. Brown, 1995 .

Stabilization of the tertiary structure of yeast phenylalanine tRNA by [Co(NH3)6]3+. X-ray evidence for hydrogen bonding to pairs of guanine bases in the major groove.

A. Klug, B. Hingerty, R. S. Brown, 1982, Biochimica et biophysica acta.

Attack of zwitterionic ammonium thiolates on a distorted anilide as a model for the acylation of papain by amides. A simple demonstration of a bell-shaped pH/rate profile

R. S. Brown, J. Keillor, 1992 .

The question of reversible formation of bromonium ions during the course of electrophilic bromination of olefins. 2. The crystal and molecular structure of the bromonium ion of adamantylideneadamantane

R. S. Brown, R. Ball, H. Ślebocka-tilk, 1984 .

Solid state NMR study of [epsilon-13C]Lys-bacteriorhodopsin: Schiff base photoisomerization.

S. O. Smith, R. Griffin, J. Herzfeld, 1993, Biophysical journal.

Differing roles for zinc fingers in DNA recognition: structure of a six-finger transcription factor IIIA complex.

S. Harrison, R. S. Brown, R. Nolte, 1998, Proceedings of the National Academy of Sciences of the United States of America.

Hydrolysis of imidazole-containing amide acetals

R. S. Brown, J. Ulan, 1983 .

Development of metal-ion containing catalysts for the decomposition of phosphorothioate esters.

D. Edwards, R. S. Brown, David R. Edwards, 2013, Biochimica et biophysica acta.

Crystallization of pure species of bacterial tRNA for x-ray diffraction studies.

B. Clark, A. Klug, J. Finch, 1972, European journal of biochemistry.

Recent Perspectives Concerning the Mechanism of H3O+‐ and OH‐‐Promoted Amide Hydrolysis

A. J. Bennet, R. S. Brown, H. Ślebocka-tilk, 1993 .

A crystallographic study of metal-binding to yeast phenylalanine transfer RNA.

A Klug, J E Ladner, A. Klug, 1977, Journal of molecular biology.

Protein L18 binds primarily at the junctions of helix II and internal loops A and B in Escherichia coli 5 S RNA. Implications for 5 S RNA structure.

R A Garrett, R. Garrett, N. Larsen, 1989, Journal of molecular biology.

Further refinement of the structure of yeast tRNAPhe.

B. Hingerty, R. S. Brown, A Jack, 1978, Journal of molecular biology.

Europium ion catalyzed methanolysis of esters at neutral pH and ambient temperature. catalytic Involvement of Eu3+(CH3O-)(CH3OH)x.

G. Gibson, R. S. Brown, A. A. Neverov, 2003, Inorganic chemistry.

The prostaglandin endoperoxide nucleus and related bicyclic peroxides. Synthetic and spectroscopic studies

R. S. Brown, R. G. Salomon, D. Coughlin, 1979 .

The hydrolysis of an activated ester by a tris(4,5-di-n-propyl-2-imidazolyl)phosphine-Zn2+ complex in neutral micellar medium as a model for carbonic anhydrase

R. S. Brown, T. Koerner, 2002 .

Acid-Catalyzed Hydration of anti-Sesquinorbornene.

R. S. Brown, H. Ślebocka-tilk, 1996, Journal of Organic Chemistry.

Electrophilic Additions to anti-Sesquinorbornene. Br2 in Methanol and the Addition of Acetic Acid

R. S. Brown, H. Ślebocka-tilk, D. Gallagher, 1996 .

The genome of the Gulf pipefish enables understanding of evolutionary innovations

A. Amores, A. Jones, W. Cresko, 2016, Genome Biology.

Protonation and site of protonation of anilines. Hydration and site of protonation after hydration

P. Kebarle, R. S. Brown, Y. Lau, 1981 .

Substituent effects on .sigma.-.pi. conjugation. Absence of .pi.-electron transmission through cyclopropane rings

R. S. Brown, T. Traylor, 1973 .

Application of photoelectron spectroscopy to intramolecularly hydrogen-bonded systems. Part II. On the n–π* blue shift of carbonyl-containing molecules

R. S. Brown, 1976 .

Correlations between core photoionization energies (EB1s) and gas-phase basicity. A general method for determining sites of protonation and intramolecular ion reorganization energies

F. Jørgensen, R. S. Brown, J. Buschek, 1982 .

DETERMINATION OF CIRCUMSTANCES UNDER WHICH THE CORRELATION OF CORE BINDING ENERGY AND GAS-PHASE BASICITY OR PROTON AFFINITY BREAKS DOWN

R. S. Brown, A. Tse, 1980 .

N1s core binding energies for 2-, 3-, and 4-substituted pyridines determined by X-ray photoelectron spectroscopy. Correlations with theoretical models, substituent parameters, and gas phase basicities

R. S. Brown, A. Tse, 1980 .

The Photoelectron Spectrum of Methyl Tri-t-butylcyclobutadienecarboxylate

R. S. Brown, S. Masamune, 1975 .

A model for the tertiary structure of the 28 residue DNA-binding motif ('zinc finger') common to many eukaryotic transcriptional regulatory proteins.

P Argos, T J Gibson, P. Argos, 1988, Protein engineering.

Structure of yeast phenylalanine transfer RNA at 2.5 A resolution.

A Klug, J E Ladner, B. Clark, 1975, Proceedings of the National Academy of Sciences of the United States of America.

Absence of substantial bending in Xenopus laevis transcription factor IIIA-DNA complexes.

C. Zwieb, R. S. Brown, 1990, Nucleic acids research.

Fourier transform infrared spectrometric detection in size-exclusion chromatographic separation of polar synfuel material

L. T. Taylor, R. S. Brown, D. Hausler, 1981 .

Adsorption complex of filamentous fd virus.

D. Marvin, C. Gray, R. S. Brown, 1981, Journal of molecular biology.

Function of basonuclin in increasing transcription of the ribosomal RNA genes during mouse oogenesis.

G. Kopf, R. S. Brown, H. Tseng, 2001, Development.

An ortho-palladated dimethylbenzylamine complex as a highly efficient turnover catalyst for the decomposition of P=S insecticides. Mechanistic studies of the methanolysis of some P=S-containing phosphorothioate triesters.

R. S. Brown, Zhong-lin Lu, A. A. Neverov, 2005, Organic & biomolecular chemistry.

Biomimetic models for cysteine proteases. 1. Intramolecular imidazole catalysis of thiol ester solvolysis: a model for the deacylation step

R. S. Brown, J. Street, 1985 .

Distorted amides as models for activated peptide N-C=O units. 2. The synthesis, hydrolytic profile, and molecular structure of 3,4-dihydro-2-oxo-1,4-propanoquinoline

B. Santarsiero, Qingping Wang, A. J. Bennet, 1990 .

Potentiometric titration of metal ions in ethanol.

G. Gibson, R. S. Brown, Mark F. Mohamed, 2003, Inorganic chemistry.

Factors Affecting Sensitivity in Lightpipe Gas Chromatography Fourier Transform Infrared Interfaces

R. S. Brown, J. Lennon, 1991 .

Gel permeation chromatography of coal-derived products with on-line infrared detection

L. T. Taylor, R. S. Brown, D. Hausler, 1980 .

La3+-catalyzed methanolysis of O,O-diethyl S-(p-nitrophenyl) phosphorothioate and O,O-diethyl S-phenyl phosphorothioate. Millions-fold acceleration of the destruction of V-agent simulants.

R. S. Brown, A. A. Neverov, J. S. Tsang, 2004, Organic & biomolecular chemistry.

Billion-fold acceleration of the methanolysis of paraoxon promoted by La(OTf)3 in methanol.

R. S. Brown, A. A. Neverov, J. S. Tsang, 2003, Journal of the American Chemical Society.

Identifying proteins using matrix-assisted laser desorption/ionization in-source fragmentation data combined with database searching.

R. S. Brown, R S Brown, D C Reiber, 1998, Analytical chemistry.

Rapid Ni, Zn, and Cu ion-promoted alcoholysis of N,N-bis(2-picolyl)- and N,N-bis((1H-benzimidazol-2-yl)methyl)-p-nitrobenzamides in methanol and ethanol.

R. S. Brown, Mark A. R. Raycroft, A. A. Neverov, 2014, Inorganic chemistry.

Dissociative solvolytic cleavage of methyl (ortho-carboxymethyl)aryl phosphate diesters mediated by Yb3+ in methanol gives a 10(12)-fold rate acceleration attributable to leaving group assistance.

D. Edwards, R. S. Brown, A. A. Neverov, 2009, Journal of the American Chemical Society.

Sequence-specific fragmentation of matrix-assisted laser-desorbed protein/peptide ions.

R. S. Brown, R S Brown, J J Lennon, 1995, Analytical chemistry.

The DB5 capillary column: The search for sensitivity

P. W. Jones, R. S. Brown, K. Pettit, 1991 .

Mechanistic and computational study of a palladacycle-catalyzed decomposition of a series of neutral phosphorothioate triesters in methanol.

N. Mosey, D. Edwards, R. S. Brown, 2010, Journal of the American Chemical Society.

Detectability of phenols and amines by normal phase microbore HPLC-FTIR employing hihgly IR transparent solvents

L. T. Taylor, R. S. Brown, P. G. Amateis, 1984 .

Model for the aspartate proteinases: hydrolysis of a distorted amide catalyzed by dicarboxylic acids capable of forming cyclic anhydrides

R. S. Brown, J. Keillor, V. Somayaji, 1988 .

FURTHER REFINEMENT OF YEAST tRNA PHENYLALANINE

B. Hingerty, R. S. Brown, A. Jack, 1981 .

Xenopus transcription factor IIIA binds primarily at junctions between double helical stems and internal loops in oocyte 5S RNA.

R. Garrett, B. Sproat, R. S. Brown, 1987, The EMBO journal.

Atomic co-ordinates for yeast phenylalanine tRNA.

A Klug, J E Ladner, B. Clark, 1975, Nucleic acids research.

Purification and crystallization of the EcoRV restriction endonuclease.

F. Winkler, A. D'arcy, M. Zabeau, 1985 .

Application of photoelectron spectroscopy to intramolecularly hydrogen-bonded systems. Part IV. π-Systems; the photoelectron spectra of syn- and anti-7-norbornenol

R. S. Brown, 1976 .

Br+ and I+ Transfer from the Halonium Ions of Adamantylideneadamantane to Acceptor Olefins. Halocyclization of 1,ω-Alkenols and Alkenoic Acids Proceeds via Reversibly Formed Intermediates

R. S. Brown, A. A. N. and, 1996 .

A Photoelectron Investigation of the Peroxide Bond

R. S. Brown, 1975 .

Reversible formation of intermediates during H/sub 3/O/sup +/-catalyzed hydrolysis of amides. Observation of substantial /sup 18/O exchange accompanying the hydrolysis of acetanilide and N-cyclohexylacetamide

R. S. Brown, H. Ślebocka-tilk, J. Olekszyk, 1987 .

Hydrolysis of a distorted amide facilitated by diacids: a phenomenological model for the aspartate proteinases

R. S. Brown, V. Somayaji, 1987 .

Molecular structure of 3,4,5-trihydro-2-oxo-1,5-ethanobenzazepine and its reaction with .beta.-amino alcohols as a model for the acylation step of the serine proteases

K. Skorey, R. S. Brown, R. Ball, 1986 .

Correlation between three-dimensional structure and chemical reactivity of transfer RNA.

B. Clark, A. Klug, J. Finch, 1974, Nucleic acids research.

An unprecedented rapid and direct Br+ transfer from the bromonium ion of adamantylideneadamantane to acceptor olefins

B. Santarsiero, A. J. Bennet, M. Klobukowski, 1991 .

Cleavage of an RNA model catalyzed by dinuclear Zn(II) complexes containing rate-accelerating pendants. Comparison of the catalytic benefits of H-bonding and hydrophobic substituents.

R. S. Brown, Mark F. Mohamed, 2010, Journal of Organic Chemistry.

The mechanism of interaction of allylic substituents as determined by photoelectron spectroscopy

R. S. Brown, A. Tse, R. Marcinko, 1979 .

Effect of distortion on the hydrolytic reactivity of amides. 2. N-Pyramidalization: decomposition of N-benzoylaziridines in aqueous media

R. S. Brown, H. Ślebocka-tilk, 1987 .

Leaving group assistance in the La3+-catalyzed cleavage of dimethyl (o-methoxycarbonyl)aryl phosphate triesters in methanol.

D. Edwards, R. S. Brown, G. Garrett, 2009, Journal of the American Chemical Society.

Observation of a very large orbital interaction through four bonds. An alternative model of orbital interactions through bonds

M. Paddon-Row, K. Houk, R. S. Brown, 1981 .

Zn2+-catalyzed methanolysis of phosphate triesters: a process for catalytic degradation of the organophosphorus pesticides paraoxon and fenitrothion.

R. S. Brown, A. A. Neverov, William Desloges, 2004, Inorganic chemistry.

La(3+)-catalyzed methanolysis of phosphate diesters. Remarkable rate acceleration of the methanolysis of diphenyl phosphate, methyl p-nitrophenyl phosphate, and bis(p-nitrophenyl) phosphate.

R. S. Brown, A. A. Neverov, 2001, Inorganic chemistry.

An immobilized ortho-palladated dimethylbenzylamine complex as an efficient catalyst for the methanolysis of phosphorothionate pesticides.

R. S. Brown, Mark F. Mohamed, A. A. Neverov, 2009, Inorganic chemistry.

Palladacycle-promoted solvolytic cleavage of O,O-dimethyl O-aryl phosphorothioates. Converting a phosphorane-like transition state to an observable intermediate.

R. S. Brown, C. Liu, A. A. Neverov, 2011, Inorganic chemistry.

Methanolysis of organophosphorus esters promoted by an M2+ catalyst supported on polystyrene-based copolymers

E. Csaszar, R. S. Brown, Mark F. Mohamed, 2008 .

Experimental and computational determination of Brønsted coefficients for equilibrium transfer of the O,O‐dimethyl phosphorothioyl group between oxyanion nucleophiles

N. Mosey, D. Edwards, R. S. Brown, 2012 .

Unknown peptide sequencing using matrix-assisted laser desorption/ionization and in-source decay.

S. Weinberger, R. S. Brown, R S Brown, 1998, Analytical chemistry.

Reaction of a distorted amide with nucleophilic thiolate-containing zwitterions produced from thiolamines. A model for the acylation step in cysteine proteases and transglutaminases

R. S. Brown, J. Keillor, 1991 .

A calculational and ultraviolet photoelectron spectroscopic study of distorted amides

N. H. Werstiuk, R. S. Brown, Heidi M. Muchall, 1998 .

Electrophilic bromination of deuterated cyclohexenes in acetic acid containing varying [bromide]: kinetics and product studies

R. S. Brown, H. Ślebocka-tilk, C. Y. Zheng, 1993 .

A study of the kinetics of La3+-promoted methanolysis of S-aryl methylphosphonothioates: possible methodology for decontamination of EA 2192, the toxic byproduct of VX hydrolysis.

D. Edwards, R. S. Brown, Basab B. Dhar, 2011, Inorganic chemistry.

The nucleoside sequence of tyrosine tRNA from Bacillus stearothermophilus

R S Brown, J R Rubin, D Rhodes, 1978, Nucleic Acids Res..

Reconstitution of protein-DNA complexes for crystallization.

R. S. Brown, R. M. Conlin, 2001, Methods in molecular biology.

.beta.-Thioxo ketones. 8. X-ray photoelectron-spectroscopic study of the enol-enethiol tautomerism of thioacetylacetone and related .beta.-thioxo ketones

L. Carlsen, R. S. Brown, F. Duus, 1982 .

Pf1 filamentous bacterial virus. X-ray fibre diffraction analysis of two heavy-atom derivatives.

A. Tsugita, J. Armstrong, D. Marvin, 1981, Journal of molecular biology.

The intramolecular hydrogen bond in malonaldehyde as determined by x-ray photoelectron spectroscopy

R. S. Brown, 1977 .

Hydrolyses of 2-trimethylsilyl N1-heterocycles. Involvement of zwitterions in the hydrolysis of 2-(trimethylsilyl)-N-methylimidazole, 2-(trimethylsilyl)pyridine, and 2-((trimethylsilyl)methyl-N-methylimidazole

R. S. Brown, H. Ślebocka-tilk, J. Ulan, 1984 .

HYDROLYSES OF 2-(TRIMETHYLSILYL) N1-HETEROCYCLES. INVOLVEMENT OF ZWITTERIONS IN THE HYDROLYSIS OF 2-(TRIMETHYLSILYL)-N-METHYLIMIDAZOLE, 2-(TRIMETHYLSILYL)PYRIDINE, AND 2-((TRIMETHYLSILYL)METHYL)-N-METHYLIMIDAZOLE

R. S. Brown, H. Ślebocka-tilk, J. Ulan, 1985 .

Applications of a continuous flow probe in FAB mass spectrometry

A. Ashcroft, M. Barber, R. S. Brown, 1987 .

Mono and Dinuclear M2+ Chelates as Catalysts for the Hydrolysis of Organophosphate Triesters.

R. S. Brown, H. Ślebocka-tilk, R. Clewley, 1989 .

Catalytically active models for the active site in carbonic anhydrase

R. S. Brown, J. Huguet, 1980 .

A Photoelectron Investigation of Acyl Silanes: The Photoelectron Spectra of Trimethylsilyl Phenyl Ketone and Phenyl tert-Butyl Ketone

R. S. Brown, 1975 .

Enhanced secretion of glycocholic acid in a specially adapted cell line is associated with overexpression of apparently novel ATP-binding cassette proteins.

B. Scharschmidt, R. S. Brown, S. Lidofsky, 1995, Proceedings of the National Academy of Sciences of the United States of America.