J. Hartwig

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Multistep One-Pot Reactions Combining Biocatalysts and Chemical Catalysts for Asymmetric Synthesis

C. Denard, J. Hartwig, Huimin Zhao, 2013 .

Cooperative asymmetric reactions combining photocatalysis and enzymatic catalysis

J. Hartwig, Huimin Zhao, Zachary C Litman, 2018, Nature.

Synthesis and Late-Stage Functionalization of Complex Molecules through C–H Fluorination and Nucleophilic Aromatic Substitution

J. Hartwig, P. Fier, 2014, Journal of the American Chemical Society.

Palladium‐Catalyzed Amination of Aryl Halides

S. Shekhar, J. Hartwig, Rebecca A. Green, 2019, Organic Reactions.

Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides.

J. Hartwig, Chao-Yuan Chen, Z. Weng, 2012, Organometallics.

Synthesis of Anilines

S. Shekhar, J. Hartwig, Q. Shen, 2007 .

Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles.

J. Hartwig, M. Chen, 2016, Angewandte Chemie.

Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones.

J. Hartwig, M. Chen, 2014, Angewandte Chemie.

Sterically controlled alkylation of arenes through iridium-catalyzed C-H borylation.

J. Hartwig, Daniel W. Robbins, 2013, Angewandte Chemie.

Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions

David W. Small, J. Hartwig, Y. Nakao, 2020, Nature Chemistry.

Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts.

J. Hartwig, Xingyu Jiang, Zhiheng He, 2019, Journal of the American Chemical Society.

Iridium-catalyzed C-H borylation of heteroarenes: scope, regioselectivity, application to late-stage functionalization, and mechanism.

J. Hartwig, M. Larsen, 2014, Journal of the American Chemical Society.

Palladium-Catalyzed C−O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination To Form the C−O Bond in Diaryl Ethers

C. Incarvito, J. Hartwig, A. Rheingold, 1999 .

Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydrobo-ration of Disubstituted Alkenes.

P. Liu, J. Hartwig, Peng Liu, 2020, Journal of the American Chemical Society.

Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides.

J. Hartwig, 2008, Accounts of chemical research.

Carbon–heteroatom bond formation catalysed by organometallic complexes

J. Hartwig, 2008, Nature.

Cooperative tandem catalysis by an organometallic complex and a metalloenzyme.

Huimin Zhao, Carl A Denard, C. Denard, 2014, Angewandte Chemie.

Development of a One-Pot Tandem Reaction Combining Ruthenium-Catalyzed Alkene Metathesis and Enantioselective Enzymatic Oxidation To Produce Aryl Epoxides

C. Denard, J. Hartwig, Huimin Zhao, 2015 .

Cooperative Tandem Catalysis by an Organometallic Complex and a Metalloenzyme.

C. Denard, J. Hartwig, Huimin Zhao, 2014 .

Iridium-catalyzed oxidative olefination of furans with unactivated alkenes.

C. Sevov, J. Hartwig, 2014, Journal of the American Chemical Society.

Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium.

Jesse W. Tye, J. Hartwig, 2009, Journal of the American Chemical Society.

Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile

J. Hartwig, D. M. Peacock, Casey B. Roos, 2016, ACS central science.

Conversion of 1,3-disubstituted arenes to chiral α,α-diaryl methylammonium chlorides using arene borylation

J. Hartwig, B. Timothy, Boebel Timothy, 2008 .

Iridium-Catalyzed Silylation of C-H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis.

J. Hartwig, Caleb Karmel, Zhewei Chen, 2019, Journal of the American Chemical Society.

Synthesis and reactivity of compounds containing ruthenium-carbon, -nitrogen, and -oxygen bonds

J. Hartwig, 1990 .

Synthesis of difluoromethyl ethers with difluoromethyltriflate.

J. Hartwig, P. Fier, 2013, Angewandte Chemie.

Copper-Mediated Perfluoroalkylation of Heteroaryl Bromides with (phen)CuRF

J. Hartwig, P. Fier, Michael G. Mormino, 2014, Organic letters.

Palladium‐Catalyzed Amination of Aryl Halides and Related Reactions

J. Hartwig, 2003 .

Development of catalysts for the hydroamination of olefins

J. Hartwig, 2004 .

Palladium-Catalyzed Intermolecular α-Arylation of Zinc Amide Enolates under Mild Conditions

J. Hartwig, D. Culkin, T. Hama, 2006 .

Discovery and understanding of transition-metal-catalyzed aromatic substitution reactions

J. Hartwig, 2006 .

Diastereo- and Enantioselective Iridium-Catalyzed Allylation of Cyclic Ketone Enolates: Synergetic Effect of Ligands and Barium Enolates

J. Hartwig, Wenyong Chen, M. Chen, 2014, Journal of the American Chemical Society.

Evolution of C-H Bond Functionalization from Methane to Methodology.

J. Hartwig, 2016, Journal of the American Chemical Society.

Selective, Nickel‐Catalyzed Hydrogenolysis of Aryl Ethers.

J. Hartwig, A. Sergeev, 2011 .

Direct, intermolecular, enantioselective, iridium-catalyzed allylation of carbamates to form carbamate-protected, branched allylic amines.

D. Weix, J. Hartwig, D. Marković, 2009, Organic letters.

Iridium-catalyzed regio- and enantioselective N-allylation of indoles.

J. Hartwig, L. Stanley, 2009, Angewandte Chemie.

Polaron delocalization in ladder macromolecular systems.

T. Goodson, J. Hartwig, X. Yan, 2005, Journal of the American Chemical Society.

Enantioselective α-functionalizations of ketones via allylic substitution of silyl enol ethers

J. Hartwig, Zhiheng He, 2018, Nature Chemistry.

Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes.

J. Hartwig, L. Stanley, 2009, Journal of the American Chemical Society.

Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids.

J. Hartwig, Y. Yamashita, A. Gopalarathnam, 2007, Journal of the American Chemical Society.

Enantioselective iridium-catalyzed allylic amination of ammonia and convenient ammonia surrogates.

Mark J. Pouy, D. Weix, J. Hartwig, 2007, Organic letters.

The allyl intermediate in regioselective and enantioselective iridium-catalyzed asymmetric allylic substitution reactions.

J. Hartwig, D. Marković, S. Madrahimov, 2009, Journal of the American Chemical Society.

Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex.

J. Hartwig, Toshimichi Ohmura, 2002, Journal of the American Chemical Society.

Enantioselective, iridium-catalyzed monoallylation of ammonia.

Mark J. Pouy, J. Hartwig, L. Stanley, 2009, Journal of the American Chemical Society.

Effects of catalyst activation and ligand steric properties on the enantioselective allylation of amines and phenoxides.

J. Hartwig, A. Leitner, C. Shu, 2005, Organic letters.

Editing the stereochemical elements in an iridium catalyst for enantioselective allylic amination.

J. Hartwig, A. Leitner, C. Shu, 2004, Proceedings of the National Academy of Sciences of the United States of America.

Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity.

C. Incarvito, J. Hartwig, C. Kiener, 2003, Journal of the American Chemical Society.

A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis.

Mark J. Pouy, S. Shekhar, J. Hartwig, 2005, Journal of the American Chemical Society.

Enantioselective allylation of aromatic amines after in situ generation of an activated cyclometalated iridium catalyst.

J. Hartwig, A. Leitner, C. Shu, 2004, Angewandte Chemie.

Resting state and kinetic studies on the asymmetric allylic substitutions catalyzed by iridium-phosphoramidite complexes.

J. Hartwig, D. Marković, 2007, Journal of the American Chemical Society.

Mechanistically driven development of iridium catalysts for asymmetric allylic substitution.

J. Hartwig, L. Stanley, 2010, Accounts of chemical research.

Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands.

J. Hartwig, N. Saper, 2017, Journal of the American Chemical Society.

Fragmentation of Lignin Samples with Commercial Pd/C under Ambient Pressure of Hydrogen

D. Wemmer, J. Hartwig, J. D. Webb, 2016 .

Iridium-Catalyzed, Silyl-Directed, peri -Borylation of C−H Bonds in Fused Polycyclic Arenes and Heteroarenes

J. Hartwig, Bo Su, 2018, Angewandte Chemie.

Femtosecond excitation energy transport in triarylamine dendrimers.

T. Goodson, J. Hartwig, O. Varnavski, 2002, Journal of the American Chemical Society.

Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates

J. Hartwig, Blake C. Hamann and, 1998 .

Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents

J. Hartwig, J. Louie, 1995 .

Generation, Characterization, and Tunable Reactivity of Organometallic Fragments Bound to a Protein Ligand.

D. Clark, J. Hartwig, H. M. Key, 2015, Journal of the American Chemical Society.

Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds.

J. Hartwig, Dale R. Pahls, Carolyn S. Wei, 2009, Chemical communications.

PALLADIUM-CATALYZED SYNTHESIS OF PURE, REGIODEFINED POLYMERIC TRIARYLAMINES

J. Hartwig, F. Goodson, A. Hauck, 1999 .

Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

J. Hartwig, E. Simmons, 2012, Nature.

Ligandless, anionic, arylpalladium halide intermediates in the Heck reaction.

J. Hartwig, Brad P. Carrow, 2010, Journal of the American Chemical Society.

Air Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium-Catalyzed C−C, C−N, and C−O Bond-Forming Cross-Couplings

J. Hartwig, Noriyasu Kataoka, Quinetta Shelby, 2002 .

Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes.

J. Hartwig, M. Utsunomiya, 2003, Journal of the American Chemical Society.

Palladium-Catalyzed Arylation of Fluoroalkylamines.

J. Hartwig, Andrew T. Brusoe, 2015, Journal of the American Chemical Society.

One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination.

J. Hartwig, Alexandra E. Strom, Alexandra E Strom, 2013, The Journal of organic chemistry.

High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands.

S. Stauffer, J. Hartwig, S. Hauck, 2000, Organic letters.

Cu(I)-amido complexes in the Ullmann reaction: reactions of Cu(I)-amido complexes with iodoarenes with and without autocatalysis by CuI.

J. Hartwig, R. Giri, 2010, Journal of the American Chemical Society.

Sterically controlled, palladium-catalyzed intermolecular amination of arenes.

J. Hartwig, Zachary C Litman, Yichen Tan, 2013, Journal of the American Chemical Society.

Ruthenium-catalyzed regiospecific borylation of methyl C-H bonds.

C. Incarvito, J. Hartwig, J. D. Lawrence, 2006, Journal of the American Chemical Society.

Oxidative addition of phenyl bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for addition to Pd(BINAP).

S. Shekhar, J. Hartwig, P. Ryberg, 2006, Organic letters.

Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols.

J. Hartwig, Q. Shen, M. A. Fernández-Rodríguez, 2006, Chemistry.

Metal Complexes as Catalysts for CarbonHeteroatom Cross-Coupling Reactions

J. Hartwig, 2003 .

Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent.

J. Hartwig, S. Lee, M. Jørgensen, 2001, Organic letters.

Origin of the Difference in Reactivity between Ir Catalysts for the Borylation of C-H Bonds.

J. Hartwig, M. Larsen, Alessandro Bismuto, 2019, Journal of the American Chemical Society.

Carbon−Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides

J. Hartwig, 1998 .

Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C-N Bond Formation with a Commercial Ligand.

J. Hartwig, S. Hauck, K. H. Shaughnessy, 1999, The Journal of organic chemistry.

A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)].

J. Hartwig, P. Fier, Nichole D. Litvinas, 2012, Angewandte Chemie.

In Praise of Basic Research as a Vehicle to Practical Applications: Palladium-Catalyzed Coupling to Form Carbon-Nitrogen Bonds.

S. Buchwald, J. Hartwig, 2020, Israel journal of chemistry.

Cross-Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate-Determining Deprotonation of Bound Hydrazine.

J. Hartwig, S. Zuend, H. Shinde, 2020, Angewandte Chemie.

Unusual Electronic Effects of Ancillary Ligands on the Perfluoroalkylation of Aryl Iodides and Bromides Mediated by Copper(I) Pentafluoro-ethyl Complexes of Substituted Bipyridines.

J. Hartwig, Michael G. Mormino, Eric D Kalkman, 2019, Journal of the American Chemical Society.

Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles.

J. Hartwig, C. Cheng, Johannes Morstein, 2016, Organic letters.

Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex

J. Hartwig, Rebecca A. Green, S. Ge, 2014, Journal of the American Chemical Society.

C(sp3)-O bond-forming reductive elimination of ethers from bisphosphine-ligated benzylpalladium(II) aryloxide complexes.

J. Hartwig, Seth L. Marquard, 2011, Angewandte Chemie.

C(sp(3))-N bond-forming reductive elimination of amines: reactions of bisphosphine-ligated benzylpalladium(II) diarylamido complexes.

J. Hartwig, Seth L. Marquard, Devon C. Rosenfeld, 2010, Angewandte Chemie.

Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides

J. Hartwig, 2009 .

Structural Characterization and Simple Synthesis of {Pd[P(o-Tol)3]2}. Spectroscopic Study and Structural Characterization of the Dimeric Palladium(II) Complexes Obtained by Oxidative Addition of Aryl Bromides and Their Reactivity with Amines

J. Hartwig, F. Paul, J. Patt, 1995 .

Carbon−Sulfur Bond-Forming Reductive Elimination Involving sp-, sp2-, and sp3-Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation

D. Barañano, I. Guzei, J. Hartwig, 1998 .

Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes.

M. Yamashita, J. Hartwig, 2004, Journal of the American Chemical Society.

Palladium‐Catalyzed Synthesis of Aryl Ethers and Related Compounds Containing S and Se

J. Hartwig, 2003 .

Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles.

S. Shekhar, J. Hartwig, Q. Shen, 2005, Angewandte Chemie.

A General and Long‐Lived Catalyst for the Palladium‐Catalyzed Coupling of Aryl Halides with Thiols.

J. Hartwig, Q. Shen, M. A. Fernández-Rodríguez, 2006 .

Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides.

C. Incarvito, J. Hartwig, Z. Weng, 2007, Angewandte Chemie.

Alpha-arylation of esters catalyzed by the Pd(I) dimer {[P(t-Bu)3]PdBr}2.

J. Hartwig, T. Hama, 2008, Organic letters.

Palladium-Catalyzed α-Arylation of Esters

J. Hartwig, T. Hama, 2008 .

Pd-catalyzed alpha-arylation of trimethylsilyl enol ethers with aryl bromides and chlorides: a synergistic effect of two metal fluorides as additives.

J. Hartwig, W. Su, X. Liao, 2006, Angewandte Chemie.

Carbon−Nitrogen-Bond-Forming Reductive Elimination of Arylamines from Palladium(II) Phosphine Complexes

J. Hartwig, M. Driver, 1997 .

Electronic effects on reductive elimination to form carbon-carbon and carbon-heteroatom bonds from palladium(II) complexes.

J. Hartwig, 2007, Inorganic chemistry.

Unparalleled Rates for the Activation of Aryl Chlorides . Coupling with Amines and Boronic Acids in Minutes at Room Temperature

J. Hartwig, R. Kuwano, J. Stambuli, 2002 .

Air‐Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium‐Catalyzed C—C, C—N, and C—O Bond‐Forming Cross‐Couplings.

J. Hartwig, Noriyasu Kataoka, Quinetta Shelby, 2003 .

Carbon−Carbon Bond-Forming Reductive Elimination from Arylpalladium Complexes Containing Functionalized Alkyl Groups. Influence of Ligand Steric and Electronic Properties on Structure, Stability, and Reactivity

J. Hartwig, D. Culkin, 2004 .

Highly reactive, general and long-lived catalysts for palladium-catalyzed amination of heteroaryl and aryl chlorides, bromides, and iodides: scope and structure-activity relationships.

T. Ogata, J. Hartwig, Q. Shen, 2008, Journal of the American Chemical Society.

Palladium-catalyzed alpha-arylation of esters with chloroarenes.

J. Hartwig, T. Hama, 2008, Organic letters.

Palladium‐Catalyzed Synthesis of Arylamines from Aryl Halides. Mechanistic Studies Lead to Coupling in the Absence of Tin Reagents.

J. Hartwig, J. Louie, 1995 .

Carbon-Heteroatom Bond-Forming Reductive Elimination. Mechanism, Importance of Trapping Reagents, and Unusual Electronic Effects during Formation of Aryl Sulfides

D. Barañano, J. Hartwig, 1995 .

Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature.

Amy H. Roy, J. Hartwig, A. H. Roy, 2003, Journal of the American Chemical Society.

Palladium-catalyzed formation of carbon-nitrogen bonds. Reaction intermediates and catalyst improvements in the hetero cross-coupling of aryl halides and tin amides

J. Hartwig, F. Paul, J. Patt, 1994 .

Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II).

M. Yamashita, C. Incarvito, J. Hartwig, 2006, Journal of the American Chemical Society.

Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles

J. Hartwig, D. Culkin, 2003 .

Cyanation of arenes via iridium-catalyzed borylation.

J. Hartwig, X. Liao, Carl W. Liskey, 2010, Journal of the American Chemical Society.

Catalytic Silylation of Unactivated C-H Bonds.

J. Hartwig, C. Cheng, 2015, Chemical reviews.

Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts

J. Hartwig, Rebecca A. Green, 2014, Organic letters.

Resting state and elementary steps of the coupling of aryl halides with thiols catalyzed by alkylbisphosphine complexes of palladium.

J. Hartwig, E. Álvaro, 2009, Journal of the American Chemical Society.

C-H activation for the construction of C-B bonds.

J. Hartwig, I. Mkhalid, T. Marder, 2010, Chemical reviews.

On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes.

J. Hartwig, E. Simmons, 2012, Angewandte Chemie.

Catalyst-Controlled Site-Selective Bond Activation.

J. Hartwig, 2017, Accounts of chemical research.

Copper-mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride.

J. Hartwig, Ruth Dorel, Philip Boehm, 2019, Chemistry.

Palladium‐Catalyzed Amination of Aryl Halides and Sulfonates

J. Hartwig, 2004 .

Zinc trimethylsilylamide as a mild ammonia equivalent and base for the amination of aryl halides and triflates.

J. Hartwig, D. Lee, 2005, Organic letters.

Selective functionalization of alkanes by transition-metal boryl complexes

J. Hartwig, K. Waltz, Karen M. Waltz, 1997 .

Transition Metal-Catalyzed Addition of Amines to Acrylic Acid Derivatives. A High-Throughput Method for Evaluating Hydroamination of Primary and Secondary Alkylamines

J. Hartwig, Motoi Kawatsura and, 2001 .

Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex

Jing Zhao, J. Hartwig, A. Goldman, 2005, Science.

Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion

P. Messersmith, J. Hartwig, A. Uliana, 2020, Chem.

Iridium-catalyzed, intermolecular hydroetherification of unactivated aliphatic alkenes with phenols.

C. Sevov, J. Hartwig, 2013, Journal of the American Chemical Society.

Mechanistic Investigation of the Iron-Catalyzed Azidation of Alkyl C(sp3)-H Bonds with Zhdankin's λ3-Azidoiodane.

J. Hartwig, R. Chatterjee, Alexander Fawcett, 2021, Journal of the American Chemical Society.

Diverse functionalization of strong alkyl C–H bonds by undirected borylation

J. Hartwig, Erik A. Romero, Bo Su, 2020, Science.

Iridium-Catalyzed, β-Selective C(sp3)-H Silylation of Aliphatic Amines To Form Silapyrrolidines and 1,2-Amino Alcohols.

J. Hartwig, Taegyo Lee, Bo Su, 2018, Journal of the American Chemical Society.

Approaches to catalyst discovery. New carbon–heteroatom and carbon–carbon bond formation

J. Hartwig, 1999 .

Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand.

J. Hartwig, Caleb Karmel, Camille Z Rubel, 2019, Angewandte Chemie.

A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds.

Zhangjie Shi, J. Hartwig, Taigang Zhou, 2017, Angewandte Chemie.

Pd-Catalyzed α-Arylation of α,α-Difluoroketones with Aryl Bromides and Chlorides. A Route to Difluoromethylarenes

J. Hartwig, S. Ge, W. Chaładaj, 2014, Journal of the American Chemical Society.

Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines.

J. Hartwig, G. Vo, 2009, Journal of the American Chemical Society.

Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides.

Jesse W. Tye, C. Incarvito, J. Hartwig, 2008, Journal of the American Chemical Society.

Effects of Bases and Halides on the Amination of Chloroarenes Catalyzed by Pd(PtBu3)2.

S. Shekhar, J. Hartwig, 2007, Organometallics.

Palladium-Catalyzed r-Arylation of Carbonyl Compounds and

J. Hartwig, Nitriles A. Culkin, 2003 .

Anti-Markovnikov hydroheteroarylation of unactivated alkenes with indoles, pyrroles, benzofurans, and furans catalyzed by a nickel-N-heterocyclic carbene system.

M. Takeuchi, J. Hartwig, Y. Nakao, 2015, Journal of the American Chemical Society.

Palladium-Catalyzed Direct α-Arylation of Ketones. Rate Acceleration by Sterically Hindered Chelating Ligands and Reductive Elimination from a Transition Metal Enolate Complex

J. Hartwig, B. Hamann, 1997 .

Nickel-Catalyzed Anti-Markovnikov Hydroarylation of Unactivated Alkenes with Unactivated Arenes Facilitated by non-Covalent Interactions

J. Hartwig, Y. Nakao, D. Small, 2019 .

A Route to Pdo from PdII Metallacycles in Animation and Cross-Coupling Chemistry†

J. Hartwig, J. Louie, 1996 .

Copper‐Catalyzed Dehydrogenative Amidation of Light Alkanes

P. Pérez, J. Hartwig, Riccardo Gava, 2021, Angewandte Chemie.

Meta halogenation of 1,3-disubstituted arenes via iridium-catalyzed arene borylation.

J. Hartwig, X. Liao, Jaclyn M. Murphy, 2007, Journal of the American Chemical Society.

Iridium-catalyzed C-H borylation of cyclopropanes.

J. Hartwig, Carl W. Liskey, 2013, Journal of the American Chemical Society.

Trimethylphosphate as a Methylating Agent for Cross Coupling: A Slow-Release Mechanism for the Methylation of Arylboronic Esters.

J. Hartwig, Haoquan Li, Zhiheng He, 2018, Journal of the American Chemical Society.

Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C-O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments.

J. Hartwig, J. D. Webb, Fang Gao, 2016, Angewandte Chemie.

Regiodefined Poly(N-arylaniline)s and Donor−Acceptor Copolymers via Palladium-Mediated Amination Chemistry

J. Hartwig, F. Goodson, 1998 .

Nickel-catalyzed asymmetric α-arylation and heteroarylation of ketones with chloroarenes: effect of halide on selectivity, oxidation state, and room-temperature reactions.

J. Hartwig, S. Ge, Shaozhong Ge, 2011, Journal of the American Chemical Society.

Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes.

J. Hartwig, M. Hall, C. Jiménez-Hoyos, 2010, Journal of the American Chemical Society.

Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes.

J. Hartwig, Brad P. Carrow, Fabiola Barrios-Landeros, 2009, Journal of the American Chemical Society.

Reductive elimination of aryl halides upon addition of hindered alkylphosphines to dimeric arylpalladium(II) halide complexes

J. Hartwig, A. H. Roy, 2004 .

Alkyl, aryl, hydrido, and acetate complexes of (DMPM)2Ru [DMPM = bis(dimethylphosphino)methane]: reductive elimination and oxidative addition of carbon-hydrogen bonds

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Tertiary building units: synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1).

M. Eddaoudi, O. Yaghi, Jaheon Kim, 2001, Journal of the American Chemical Society.

Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes.

J. Hartwig, T. Boebel, 2008, Journal of the American Chemical Society.

Autocatalytic oxidative addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br).

J. Hartwig, Brad P. Carrow, Fabiola Barrios-Landeros, 2008, Journal of the American Chemical Society.

Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides.

J. Hartwig, Q. Shen, 2006, Journal of the American Chemical Society.

Adsorption of butachlor to soils

J. Hartwig, Tatsuo Sato, Shigeru Kohnosu, 1987 .

Palladium-Catalyzed, Enantioselective α-Arylation of α-Fluorooxindoles.

J. Hartwig, M. Chen, S. Ge, 2016, Organic letters.

Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres.

M. Yamashita, J. Hartwig, Jose V Cuevas Vicario, 2003, Journal of the American Chemical Society.

Electronic and Steric Effects on the Reductive Elimination of Diaryl Ethers from Palladium(II)

J. Hartwig, G. Mann, Quinetta Shelby, 2003 .

Systematic Variation of Bidentate Ligands Used in Aryl Halide Amination. Unexpected Effects of Steric, Electronic, and Geometric Perturbations

J. Hartwig, B. Hamann, 1998 .

Iridium‐Catalyzed C—H Coupling Reaction of Heteroaromatic Compounds with Bis(pinacolato)diboron: Regioselective Synthesis of Heteroarylboronates.

N. Miyaura, J. Hartwig, J. Takagi, 2002 .

Iridium-catalyzed C–H coupling reaction of heteroaromatic compounds with bis(pinacolato)diboron: regioselective synthesis of heteroarylboronates

N. Miyaura, J. Hartwig, J. Takagi, 2002 .

Intermolecular migratory insertion of unactivated olefins into palladium-nitrogen bonds. Steric and electronic effects on the rate of migratory insertion.

Patrick S. Hanley, J. Hartwig, 2011, Journal of the American Chemical Society.

Distinct electronic effects on reductive eliminations of symmetrical and unsymmetrical bis-aryl platinum complexes.

S. Shekhar, J. Hartwig, 2004, Journal of the American Chemical Society.

Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes

M. Driess, J. Hartwig, Bijie Li, 2014, Journal of the American Chemical Society.

Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification.

J. Hartwig, Ankit Sharma, 2013, Journal of the American Chemical Society.

Polysilylether: A Degradable Polymer from Biorenewable Feedstocks.

M. Hillmyer, J. Hartwig, C. Cheng, 2016, Angewandte Chemie.

Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.

J. Hartwig, R. Kuwano, M. Utsunomiya, 2002, The Journal of organic chemistry.

Mechanism of Ni-Catalyzed Oxidations of Unactivated C(sp3)-H Bonds.

J. Hartwig, Yehao Qiu, 2020, Journal of the American Chemical Society.

Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles

J. Hartwig, D. Culkin, 2003 .

Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates.

J. Hartwig, Sunwoo Lee, M. Jørgensen, 2002, Journal of the American Chemical Society.

Palladium-Catalyzed α-Arylation of Esters and Protected Amino Acids

J. Hartwig, Sunwoo Lee, and Neil A. Beare, 2001 .

C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates.

J. Hartwig, D. Culkin, 2001, Journal of the American Chemical Society.

Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation: Dissecting the Importance of Chelation and Steric Hindrance

J. Hartwig, Motoi Kawatsura and, 1999 .

Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles

J. Hartwig, K. H. Shaughnessy, B. Hamann, 1998 .

A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides.

J. Hartwig, T. Tsubogo, Nichole D. Litvinas, 2011, Angewandte Chemie.

A Simple, Multidimensional Approach to High-Throughput Discovery of Catalytic Reactions

John F. Hartwig, J. Hartwig, Daniel W. Robbins, 2011, Science.

A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation.

J. Hartwig, A. Sergeev, J. D. Webb, 2012, Journal of the American Chemical Society.

Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates.

S. Shekhar, J. Hartwig, Devon C. Rosenfeld, 2006, Organic letters.

Ruthenium-Catalyzed Hydroamination of Unactivated Terminal Alkenes with Stoichiometric Amounts of Alkene and an Ammonia Surrogate by Sequential Oxidation and Reduction.

J. Hartwig, Senjie Ma, Christopher Hill, 2020, Journal of the American Chemical Society.

Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides, and Iodides: Scope and Structure—Activity Relationships.

T. Ogata, J. Hartwig, Q. Shen, 2008 .

Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines

J. Hartwig, Motoi Kawatsura and, 2000 .

Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling.

J. Hartwig, Sophie I. Arlow, Sophie I Arlow, 2016, Angewandte Chemie.

Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes.

J. Hartwig, Yumeng Xi, 2017, Journal of the American Chemical Society.

Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers.

J. Hartwig, D. Blakemore, J. Kohrt, 2016, Angewandte Chemie.

Iridium-Catalyzed Enantioselective Allylic Substitution of Aliphatic Esters with Silyl Ketene Acetals as the Ester Enolates.

J. Hartwig, Xingyu Jiang, 2017, Angewandte Chemie.

Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes.

S. Buchwald, E. Strieter, S. Shekhar, 2006, Journal of the American Chemical Society.

Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides.

J. Hartwig, M. Chen, 2015, Journal of the American Chemical Society.

Copper(I) enolate complexes in α-arylation reactions: synthesis, reactivity, and mechanism.

J. Hartwig, Zheng Huang, 2012, Angewandte Chemie.

Copper(I) phenoxide complexes in the etherification of aryl halides.

Jesse W. Tye, J. Hartwig, R. Giri, 2010, Angewandte Chemie.

Hydrocarbon synthesis: Ringing the chains.

J. Hartwig, 2011, Nature chemistry.

Regioselectivity of the borylation of alkanes and arenes.

J. Hartwig, 2011, Chemical Society reviews.

Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation.

J. Hartwig, E. Simmons, 2010, Journal of the American Chemical Society.

Rhodium-Catalyzed Intermolecular C–H Silylation of Arenes with High Steric Regiocontrol

J. Hartwig, C. Cheng, 2014, Science.

Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate.

N. Miyaura, J. Hartwig, J. Takagi, 2002, Journal of the American Chemical Society.

Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes.

J. Hartwig, David Balcells, Alexandra E. Strom, 2016, ACS catalysis.

Selective C-H Fluorination of Pyridines and Diazines Inspired by a Classic Amination Reaction

J. Hartwig, P. Fier, 2013, Science.

Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation.

J. Hartwig, Sarah Yunmi Lee, 2016, Journal of the American Chemical Society.

Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions

J. Hartwig, John F Hartwig, Konstantin Troshin, 2017, Science.

Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines.

J. Hartwig, Björn Schlummer, 2002, Organic letters.

Transition Metal Catalyzed Synthesis of Arylamines and Aryl Ethers from Aryl Halides and Triflates: Scope and Mechanism.

J. Hartwig, 1998, Angewandte Chemie.

Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes through Catalytic Regioselective Hydroboration.

J. Hartwig, Yumeng Xi, 2016, Journal of the American Chemical Society.

A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols.

J. Hartwig, Q. Shen, M. A. Fernández-Rodríguez, 2006, Journal of the American Chemical Society.

Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity.

J. Hartwig, J. Zhou, 2008, Journal of the American Chemical Society.

Palladium-catalyzed amination of aromatic C-H bonds with oxime esters.

J. Hartwig, John F Hartwig, Yichen Tan, 2010, Journal of the American Chemical Society.

Site-Selective C-H Fluorination of Pyridines and Diazines with AgF2

J. Hartwig, P. Fier, 2018, Organic Syntheses.

Selective C—H Fluorination of Pyridines and Diazines Inspired by a Classic Amination Reaction.

J. Hartwig, P. Fier, 2014 .

Palladium-Catalyzed C−N(sp2) Bond Formation: N-Arylation of Aromatic and Unsaturated Nitrogen and the Reductive Elimination Chemistry of Palladium Azolyl and Methyleneamido Complexes

J. Hartwig, G. Mann, C. Fernández-Rivas, 1998 .

Direct Observation of Diastereomeric α-C-Bound Enolates during Enantioselective α-Arylations: Synthesis, Characterization, and Reactivity of Arylpalladium Fluorooxindole Complexes.

J. Hartwig, Eric D. Kalkman, 2021, Journal of the American Chemical Society.

Synthesis, Characterization, and Reactivity of Palladium Fluoroenolate Complexes.

J. Hartwig, Sophie I. Arlow, 2017, Journal of the American Chemical Society.

Copper-mediated difluoromethylation of aryl and vinyl iodides.

J. Hartwig, P. Fier, 2012, Journal of the American Chemical Society.

Palladium-Catalyzed Cross-Coupling of Ethyl Bromodifluoroacetate with Aryl Bromides or Triflates and Cross-Coupling of Ethyl Bromofluoroacetate with Aryl Iodides.

J. Hartwig, X. Liao, Yahu A. Liu, 2017, Organic letters.

Pd-Catalyzed α-Arylation of Trimethylsilyl Enolates of α,α-Difluoroacetamides

J. Hartwig, S. Ge, Michael G. Mormino, 2014, Journal of the American Chemical Society.

A C-H borylation approach to Suzuki-Miyaura coupling of typically unstable 2-heteroaryl and polyfluorophenyl boronates.

J. Hartwig, Daniel W. Robbins, 2012, Organic letters.

Direct Arylation of Simple Arenes with Aryl Bromides by Synergistic Silver and Palladium Catalysis.

J. Hartwig, Sarah Yunmi Lee, Adrian Tlahuext‐Aca, 2021, ACS catalysis.

Site-Selective Silver-Catalyzed C-H Bond Deuteration of Five-Membered Aromatic Heterocycles and Pharmaceuticals.

J. Hartwig, Adrian Tlahuext‐Aca, 2021, ACS catalysis.

Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species.

J. Hartwig, Yichen Tan, 2011, Journal of the American Chemical Society.

Copper-mediated fluorination of aryl iodides.

J. Hartwig, P. Fier, 2012, Journal of the American Chemical Society.

Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes.

J. Hartwig, Yumeng Xi, Jing Zhang, 2016, Angewandte Chemie.

Rhodium phosphine-π-arene intermediates in the hydroamination of alkenes.

J. Hartwig, S. Madrahimov, Zhijian Liu, 2011, Journal of the American Chemical Society.

Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex.

J. Hartwig, Lisa D. Julian, 2010, Journal of the American Chemical Society.

Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines.

J. Hartwig, Zhijian Liu, 2008, Journal of the American Chemical Society.

Synthesis of heteroaromatic trifluoromethyl ethers with trifluoromethyl triflate as the source of the trifluoromethoxy group.

J. Hartwig, Qing-Wei Zhang, 2018, Chemical communications.

Transition-Metal-Catalyzed Selective Functionalization of C(sp3 )-H Bonds in Natural Products.

J. Hartwig, Rashad R. Karimov, 2018, Angewandte Chemie.

Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation.

C. E. Webster, J. Hartwig, M. Hall, 2003, Journal of the American Chemical Society.

Functionalization of Alkanes by Isolated Transition Metal Boryl Complexes

J. Hartwig, Karen M. Waltz and, 2000 .

Oxidative Addition of Aryl Sulfonates to Palladium(0) Complexes of Mono- and Bidentate Phosphines. Mild Addition of Aryl Tosylates and the Effects of Anions on Rate and Mechanism

Amy H. Roy, J. Hartwig, A. H. Roy, 2004 .

From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction.

F. Meier, M. Driess, M. Kaupp, 2013, Journal of the American Chemical Society.

Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands.

M. Driess, J. Hartwig, A. Brück, 2012, Angewandte Chemie.

Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations.

J. Hartwig, S. Lee, Sunwoo Lee and, 2001, The Journal of organic chemistry.

Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.

J. Hartwig, X. Liao, Z. Weng, 2008, Journal of the American Chemical Society.

Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds†‡

J. Hartwig, C. Richers, V. Laserna, 2020, Chemical science.

Palladium-catalyzed equilibrium addition of acidic OH groups across dienes.

J. Hartwig, M. Kawatsura, M. Utsunomiya, 2003, Angewandte Chemie.

Iridium-catalyzed, intermolecular hydroamination of unactivated alkenes with indoles.

C. Sevov, J. Hartwig, J. Zhou, 2014, Journal of the American Chemical Society.

Migratory insertion of alkenes into metal-oxygen and metal-nitrogen bonds.

Patrick S. Hanley, J. Hartwig, 2013, Angewandte Chemie.

Enantioselective Borylation of Aromatic C-H Bonds with Chiral Dinitrogen Ligands.

Zhangjie Shi, J. Hartwig, Taigang Zhou, 2017, Angewandte Chemie.

Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature.

J. Hartwig, R. Kuwano, J. Stambuli, 2002, Angewandte Chemie.

Unusual in Situ Ligand Modification to Generate a Catalyst for Room Temperature Aromatic C−O Bond Formation

John F. Hartwig, A. Mann, J. Hartwig, 2000 .

Mechanistic studies on direct arylation of pyridine N-oxide: evidence for cooperative catalysis between two distinct palladium centers.

J. Hartwig, Fabiola Barrios-Landeros, Yichen Tan, 2012, Journal of the American Chemical Society.

Direct measurement of the thermodynamics of vinylarene hydroamination.

J. Hartwig, Norio Sakai, Adam M. Johns, 2006, Journal of the American Chemical Society.

One-pot synthesis of unsymmetrical diaryl thioethers by palladium-catalyzed coupling of two aryl bromides and a thiol surrogate.

J. Hartwig, M. A. Fernández-Rodríguez, 2010, Chemistry.

Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts.

J. Hartwig, Rebecca A. Green, 2015, Angewandte Chemie.

Palladium-catalyzed oxidation of β-C(sp3)-H bond of primary alkylamines through a rare four-membered palladacycle intermediate.

J. Hartwig, Bo Su, S. Zuend, 2020, Journal of the American Chemical Society.

Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates.

J. Hartwig, M. Ueda, 2010, Organic letters.

Palladium Alkoxides: Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III)

J. Hartwig, G. Mann, 1996 .

Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine.

M. Driess, J. Hartwig, Q. Li, 2014, Angewandte Chemie.

A Second-Generation Catalyst for Aryl Halide Amination: Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by (DPPF)PdCl2

John F. Hartwig, J. Hartwig, Michael S. Driver, 1996 .

Catalytic organometallic reactions of ammonia.

J. Hartwig, Jessica L. Klinkenberg, 2011, Angewandte Chemie.

Catalysis with Platinum-Group Alkylamido Complexes. The Active Palladium Amide in Catalytic Aryl Halide Aminations As Deduced from Kinetic Data and Independent Generation

J. Hartwig, J. Louie, F. Paul, 1996 .

Iridium‐Catalyzed Direct Borylation of Five‐Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions

N. Miyaura, J. Hartwig, J. Takagi, 2003 .

A stoichiometric aromatic CbondH borylation catalyzed by iridium(i)/2,2'-bipyridine complexes at room temperature.

N. Miyaura, J. Hartwig, J. Takagi, 2002, Angewandte Chemie.

Synthesis, structure, theoretical studies, and Ligand exchange reactions of monomeric, T-shaped arylpalladium(II) halide complexes with an additional, weak agostic interaction.

C. Incarvito, M. Bühl, J. Hartwig, 2004, Journal of the American Chemical Society.

Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups.

M. Hillmyer, Chulsung Bae, J. Hartwig, 2005, Angewandte Chemie.

Catalytic Hydroxylation of Polyethylenes

J. Hartwig, Q. Li, Sunwoo Lee, 2005, ACS central science.

Energetics and Mechanism of Alkylamine N−H Bond Cleavage by Palladium Hydroxides: N−H Activation by Unusual Acid−Base Chemistry

J. Hartwig, M. Driver, 1997 .

Iridium-catalyzed intermolecular hydroamination of unactivated aliphatic alkenes with amides and sulfonamides.

C. Sevov, J. Hartwig, J. Zhou, 2012, Journal of the American Chemical Society.

Regioselective and enantioselective iridium-catalyzed allylation of enamines.

D. Weix, J. Hartwig, 2007, Journal of the American Chemical Society.

N-H activation of hydrazines by iridium(I). Double N-H activation to form iridium aminonitrene complexes.

J. Hartwig, Zheng Huang, J. Zhou, 2010, Journal of the American Chemical Society.

Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides.

J. Hartwig, M. Utsunomiya, M. Hooper, 2003, The Journal of organic chemistry.

Regiospecific Functionalization of Methyl C—H Bonds of Alkyl Groups in Reagents with Heteroatom Functionality.

Chulsung Bae, J. Hartwig, Makoto Takahashi, 2005 .

Iridium-catalyzed regio- and enantioselective allylation of ketone enolates.

J. Hartwig, T. Graening, 2005, Journal of the American Chemical Society.

Synthesis, Structure, and Reactivity of [Cp2Ti(HBcat)(PMe3)]: A Monoborane σ Complex†‡

J. Hartwig, C. Muhoro, 1997 .

Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt.

Nicole L. Wagner, M. Hillmyer, J. Hartwig, 2002, Journal of the American Chemical Society.

Iridium-catalyzed, diastereoselective dehydrogenative silylation of terminal alkenes with (TMSO)2MeSiH.

J. Hartwig, C. Cheng, E. Simmons, 2013, Angewandte Chemie.

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

J. Hartwig, M. Larsen, 2016, ACS central science.

Palladium-catalyzed asymmetric allylic alkylations of polynitrogen-containing aromatic heterocycles.

B. Trost, J. Hartwig, D. Thaisrivongs, 2011, Journal of the American Chemical Society.

Iridium-Catalyzed Silylation of Unactivated C-H Bonds.

J. Hartwig, Erik A. Romero, 2019, Tetrahedron.

Rhodium-Catalyzed Regioselective Silylation of Alkyl C-H Bonds for the Synthesis of 1,4-Diols.

J. Hartwig, Bijie Li, Caleb Karmel, 2018, Journal of the American Chemical Society.

Traceless Silylation of β-C(sp3)-H Bonds of Alcohols via Perfluorinated Acetals.

J. Hartwig, Ala Bunescu, T. W. Butcher, 2017, Journal of the American Chemical Society.

Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives.

J. Hartwig, Zhijian Liu, Adam M. Johns, 2007, Angewandte Chemie.

Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions.

S. Stauffer, J. Hartwig, K. H. Shaughnessy, 2001, Journal of the American Chemical Society.

Borylation and silylation of C-H bonds: a platform for diverse C-H bond functionalizations.

J. Hartwig, 2012, Accounts of chemical research.

Catalyzed carbon-heteroatom bond formation

A. Yudin, J. Hartwig, 2011 .

Kumada coupling of aryl and vinyl tosylates under mild conditions.

J. Hartwig, A. H. Roy, Michael E. Limmert, 2005, The Journal of organic chemistry.

Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines.

J. Hartwig, A. Takemiya, 2006, Journal of the American Chemical Society.

A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes.

C. Incarvito, J. Hartwig, M. Utsunomiya, 2006, Journal of the American Chemical Society.

Arenes to anilines and aryl ethers by sequential iridium-catalyzed borylation and copper-catalyzed coupling.

J. Hartwig, C. C. Tzschucke, Jaclyn M. Murphy, 2007, Organic letters.

Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent.

J. Hartwig, A. Takemiya, 2006, Journal of the American Chemical Society.

A general, efficient, and functional-group-tolerant catalyst system for the palladium-catalyzed thioetherification of aryl bromides and iodides.

J. Hartwig, M. A. Fernández-Rodríguez, 2009, The Journal of organic chemistry.

Direct Observation of β-Aryl Eliminations from Rh(I) Alkoxides

C. Incarvito, J. Hartwig, Pinjing Zhao, 2006 .

Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers

J. Hartwig, A. Sergeev, 2011, Science.

Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans.

J. Hartwig, C. Shu, 2004, Angewandte Chemie.

Iridium-catalyzed intermolecular asymmetric hydroheteroarylation of bicycloalkenes.

C. Sevov, J. Hartwig, 2013, Journal of the American Chemical Society.

A decarboxylative approach for regioselective hydroarylation of alkynes.

J. Hartwig, Jing Zhang, Pinjing Zhao, 2016, Nature chemistry.

Palladium-Catalyzed α-Arylation of Carboxylic Acids and Secondary Amides via a Traceless Protecting Strategy.

J. Hartwig, Zhiheng He, 2019, Journal of the American Chemical Society.

Enantioselective total syntheses of (-)-taiwaniaquinone H and (-)-taiwaniaquinol B by iridium-catalyzed borylation and palladium-catalyzed asymmetric α-arylation.

J. Hartwig, L. Stanley, X. Liao, 2011, Journal of the American Chemical Society.

Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes.

J. Hartwig, Joseph S. Bair, O. Eisenstein, 2014, Journal of the American Chemical Society.

Palladium-Catalyzed Methylation of Aryl, Heteroaryl, and Vinyl Boronate Esters.

J. Hartwig, Alexander M. Haydl, 2019, Organic letters.

Iridium-Catalyzed, Silyl-Directed, peri-Borylation of C-H Bonds in Fused Polycyclic Arenes and Heteroarenes.

J. Hartwig, Bo Su, 2018, Angewandte Chemie.

Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C-H Bonds.

J. Hartwig, M. Larsen, S. Cho, 2016, Journal of the American Chemical Society.

Iridium-catalyzed diborylation of benzylic C–H bonds directed by a hydrosilyl group: synthesis of 1,1-benzyldiboronate esters

J. Hartwig, S. Cho, 2014 .

Iridium-catalyzed borylation of secondary benzylic C-H bonds directed by a hydrosilane.

J. Hartwig, S. Cho, 2013, Journal of the American Chemical Society.

Iridium-catalyzed borylation of secondary C-H bonds in cyclic ethers.

J. Hartwig, Carl W. Liskey, 2012, Journal of the American Chemical Society.

Iridium-catalyzed, silyl-directed borylation of nitrogen-containing heterocycles.

J. Hartwig, Daniel W. Robbins, T. Boebel, 2010, Journal of the American Chemical Society.

Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes.

N. Miyaura, J. Hartwig, M. Hapke, 2005, Journal of the American Chemical Society.

Palladium‐Catalyzed Amination of Aromatic C—H Bonds with Oxime Esters.

J. Hartwig, Yichen Tan, 2010 .

Palladium-catalyzed arylation of trimethylsilyl enolates of esters and imides. High functional group tolerance and stereoselective synthesis of alpha-aryl carboxylic acid derivatives.

J. Hartwig, Xiaoxiang Liu, 2004, Journal of the American Chemical Society.

Oxidation of Hindered Allylic C-H Bonds with Applications to the Functionalization of Complex Molecules.

J. Hartwig, Zachary C Litman, Ankit Sharma, 2017, ACS catalysis.

General N−H Activation of Primary Alkylamines by a Late Transition-Metal Complex

J. Hartwig, M. Driver, 1996 .

A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes.

J. Hartwig, U. Nettekoven, 2002, Journal of the American Chemical Society.

PALLADIUM-CATALYZED FORMATION OF DIARYL ETHERS FROM ARYL BROMIDES. ELECTRON POOR PHOSPHINES ENHANCE REACTION YIELDS

J. Hartwig, G. Mann, 1997 .

Palladium Alkoxides: Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III).

J. Hartwig, G. Mann, 1997 .

Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides.

J. Hartwig, Q. Shen, 2007, Journal of the American Chemical Society.

[(CyPF-(t)Bu)PdCl2]: an air-stable, one-component, highly efficient catalyst for amination of heteroaryl and aryl halides.

J. Hartwig, Q. Shen, 2008, Organic letters.

Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes

J. Hartwig, T. Boebel, 2008 .

Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds.

J. Hartwig, Naofumi Tsukada, 2005, Journal of the American Chemical Society.

Intermolecular insertion of ethylene and octene into a palladium-amide bond. Spectroscopic evidence for an ethylene amido intermediate.

Patrick S. Hanley, J. Hartwig, D. Marković, 2010, Journal of the American Chemical Society.

Catecholborane Bound to Titanocene. Unusual Coordination of Ligand σ-Bonds

Xiaoming He, J. Hartwig, F. Maseras, 1996 .

Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran.

J. Hartwig, Wenyong Chen, 2012, Journal of the American Chemical Society.

Palladium-catalyzed α-arylation of zinc enolates of esters: reaction conditions and substrate scope.

J. Hartwig, S. Ge, T. Hama, 2013, The Journal of organic chemistry.

Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions.

J. Hartwig, Brad P. Carrow, 2011, Journal of the American Chemical Society.

Transition Metal Catalyzed Addition of Amines to Acrylic Acid Derivatives. A High-Throughput Method for Evaluating Hydroamination of Primary and Secondary Alkylamines.

J. Hartwig, M. Kawatsura, 2001 .

Understanding the coupling of heteroaromatic substrates: Synthesis, structures, and reductive eliminations of heteroarylpalladium amido complexes

J. Hartwig, Mark W. Hooper and, 2003 .

Acceptorless, Neat, Ruthenium-Catalyzed Dehydrogenative Cyclization of Diols to Lactones

J. Hartwig, Jing Zhao and, 2005 .

A Continuum Resulting from Equilibrium between Two Structural Extremes in Tungstenocene and Niobocene Boryl and Hydridoborate Complexes. .pi.-Bonding in a d2 Boryl System and the First d0 Boryl Complex

J. Hartwig, S. D. Gala, 1994 .

Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand.

J. Hartwig, Caleb Karmel, Camille Z Rubel, 2020, Angewandte Chemie.

Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions.

N. Miyaura, J. Hartwig, J. Takagi, 2004 .

Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent.

N. Miyaura, J. Hartwig, Tatsuo Ishiyama, 2003, Chemical communications.

Undirected, Homogeneous CH Bond Functionalization: Challenges and Opportunities

J. Hartwig, M. Larsen, 2016 .

Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity.

J. Hartwig, M. Larsen, Conner V Wilson, 2015, Journal of the American Chemical Society.

Mechanism of the rhodium-catalyzed silylation of arene C-H bonds.

J. Hartwig, C. Cheng, 2014, Journal of the American Chemical Society.

A Stoichiometric Aromatic C—H Borylation Catalyzed by Iridium(I)/2,2′‐Bipyridine Complexes at Room Temperature.

N. Miyaura, J. Hartwig, J. Takagi, 2002 .

Iridium-Catalyzed Allylic Substitution

Mark J. Pouy, J. Hartwig, 2011 .

Mechanism of aryl chloride amination: base-induced oxidative addition.

J. Hartwig, L. Alcazar-Roman, John F. Hartwig, 2001, Journal of the American Chemical Society.

Mechanistic Studies of the Palladium-Catalyzed Amination of Aryl Halides and the Oxidative Addition of Aryl Bromides to Pd(BINAP)2 and Pd(DPPF)2: An Unusual Case of Zero-Order Kinetic Behavior and Product Inhibition

I. Guzei, J. Hartwig, A. Rheingold, 2000 .

Combining Rh-Catalyzed Diazocoupling and Enzymatic Reduction To Efficiently Synthesize Enantioenriched 2-Substituted Succinate Derivatives

C. Denard, J. Hartwig, Huimin Zhao, 2017 .

Influences on the Relative Rates for C−N Bond-Forming Reductive Elimination and β-Hydrogen Elimination of Amides. A Case Study on the Origins of Competing Reduction in the Palladium-Catalyzed Amination of Aryl Halides

D. Barañano, J. Hartwig, F. Paul, 1996 .

Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands.

J. Hartwig, N. Beare, 2002, The Journal of organic chemistry.

Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through pi-Arene Complexes.

J. Hartwig, J. Takaya, 2005, Journal of the American Chemical Society.

Intermolecular, markovnikov hydroamination of vinylarenes with alkylamines.

J. Hartwig, M. Utsunomiya, 2003, Journal of the American Chemical Society.

Iridium-catalyzed H/D exchange at vinyl groups without olefin isomerization.

J. Hartwig, J. Zhou, 2008, Angewandte Chemie.

Kumada coupling of aryl and vinyl tosylates under mild conditions.

J. Hartwig, A. H. Roy, Michael E. Limmert, 2005, The Journal of organic chemistry.

Iridium-catalyzed regio- and enantioselective N-allylation of indoles.

J. Hartwig, L. Stanley, 2009, Angewandte Chemie.

Desymmetrization of difluoromethylene groups by C–F bond activation

W. Amberg, J. Hartwig, J. L. Yang, 2020, Nature.

Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study.

S. Stauffer, J. Hartwig, 2003, Journal of the American Chemical Society.

Metal-Catalyzed Azidation of Tertiary C–H Bonds Suitable for Late-Stage Functionalization

J. Hartwig, Ankit Sharma, 2014, Nature.

Palladium-catalyzed gamma-arylation of alpha,beta-unsaturated esters from silyl ketene acetals.

J. Hartwig, David S. Huang, 2010, Angewandte Chemie.

Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones.

J. Hartwig, M. Chen, 2014, Angewandte Chemie.

A Multicatalytic Approach to the Hydroaminomethylation of α-Olefins.

J. Hartwig, Jeffrey C. Holder, Steven Hanna, 2019, Angewandte Chemie.

Accurate Borane Sequential Bond Dissociation Energies by High-Level ab Initio Computational Methods

J. Hartwig, P. Rablen, 1996 .

Palladium-Catalyzed Amination of Aryl Halides: Mechanism and Rational Catalyst Design

J. Hartwig, 1997 .

Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos.

J. Hartwig, G. Vo, 2008, Angewandte Chemie.

Palladium-Catalyzed α-Arylation of Esters and Amides under More Neutral Conditions

J. Hartwig, D. Culkin, Xiaoxiang Liu, 2003 .

Generation of reactivity from typically stable ligands: CbondC bond-forming reductive elimination from aryl palladium(II) complexes of malonate anions.

J. Hartwig, Joanna P. Wolkowski, 2002, Angewandte Chemie.

Synthesis, Characterization, and Reactivity of Arylpalladium Cyanoalkyl Complexes: Selection of Catalysts for the α-Arylation of Nitriles

J. Hartwig, D. Culkin, 2002 .

Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery.

S. Stauffer, J. Hartwig, J. Stambuli, 2001, Journal of the American Chemical Society.

Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia.

J. Hartwig, Alexandra E. Strom, Justin Y. Wang, 2018, Journal of the American Chemical Society.

Directly observed transmetalation from boron to rhodium. beta-aryl elimination from Rh(I) arylboronates and diarylborinates.

C. Incarvito, J. Hartwig, Pinjing Zhao, 2007, Journal of the American Chemical Society.

Chemoselective, Enzymatic C-H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor.

Paweł Dydio, D. Clark, J. Hartwig, 2017, Journal of the American Chemical Society.

Iridium-catalyzed silylation of aryl C-H bonds.

J. Hartwig, C. Cheng, 2015, Journal of the American Chemical Society.

Late Stage Azidation of Complex Molecules

J. Hartwig, Ankit Sharma, Rashad R. Karimov, 2016, ACS central science.

Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C-H Bonds.

J. Hartwig, Bo Su, 2017, Journal of the American Chemical Society.

Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds.

J. Hartwig, Taegyo Lee, 2016, Angewandte Chemie.

Iridium‐Catalyzed Regioselective Silylation of Aromatic and Benzylic C—H Bonds Directed by a Secondary Amine.

M. Driess, J. Hartwig, Q. Li, 2015 .

Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols.

M. Driess, J. Hartwig, Bijie Li, 2014, Journal of the American Chemical Society.

Rhodium-catalyzed enantioselective silylation of arene C-H bonds: desymmetrization of diarylmethanols.

J. Hartwig, Taegyo Lee, T. Wilson, 2015, Journal of the American Chemical Society.

Iridium-Catalyzed Silylation of C-H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis.

J. Hartwig, Caleb Karmel, Zhewei Chen, 2019, Journal of the American Chemical Society.

Site-selective oxidation, amination and epimerization reactions of complex polyols enabled by transfer hydrogenation.

J. Hartwig, Christopher Hill, 2017, Nature chemistry.

An artificial metalloenzyme with the kinetics of native enzymes

D. S. Clark, D. Clark, J. Hartwig, 2016, Science.

Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand.

M. Bühl, J. Hartwig, J. Stambuli, 2002, Journal of the American Chemical Society.

Oxidative Addition of Aryl Bromide after Dissociation of Phosphine from a Two-Coordinate Palladium(0) Complex, Bis(tri-o-tolylphosphine)Palladium(0)

J. Hartwig, F. Paul, 1995 .

Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles.

J. Hartwig, M. Chen, 2016, Angewandte Chemie.

Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones.

J. Hartwig, M. Chen, 2014, Angewandte Chemie.

Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines.

J. Hartwig, S. Herzon, 2007, Journal of the American Chemical Society.

Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols.

J. Hartwig, S. Ueno, 2008, Angewandte Chemie.

Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides.

J. Hartwig, F. López, Toshimichi Ohmura, 2003, Journal of the American Chemical Society.

Organotransition Metal Chemistry: From Bonding to Catalysis

J. Hartwig, 2009 .

Insertions of Ketones and Nitriles into Organorhodium(I) Complexes and β-Hydrocarbyl Eliminations from Rhodium(I) Alkoxo and Iminyl Complexes

J. Hartwig, Pinjing Zhao, 2008 .

Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis.

J. Hartwig, Xingyu Jiang, Jason J Beiger, 2017, Journal of the American Chemical Society.

Directly-Observed β-Hydrogen Elimination of a Late Transition Metal Amido Complex and Unusual Fate of Imine Byproducts

J. Hartwig, 1996 .

Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes

M. Driess, J. Hartwig, B. L. Tran, 2014, Journal of the American Chemical Society.

Efficient Synthesis of α‐Aryl Esters by Room‐Temperature Palladium‐Catalyzed Coupling of Aryl Halides with Ester Enolates.

M. Joergensen, J. Hartwig, Sunwoo Lee, 2003 .

Palladium-Catalyzed α-Arylation of Azlactones to Form Quaternary Amino Acid Derivatives

J. Hartwig, Xiaoxiang Liu, 2003 .

Synthesis of a highly reactive (benzyne)ruthenium complex: C-C, C-H, N-H, and O-H activation reactions

J. Hartwig, R. Bergman, R. Andersen, 1989 .

True Metal-Catalyzed Hydroboration with Titanium

Xiaoming He, J. Hartwig, 1996 .

Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones.

J. Hartwig, Wenyong Chen, 2014, Journal of the American Chemical Society.

Hydroaminoalkylation of unactivated olefins with dialkylamines.

J. Hartwig, S. Herzon, 2008, Journal of the American Chemical Society.

Enantioselective Functionalization of Allylic C—H Bonds Following a Strategy of Functionalization and Diversification.

J. Hartwig, Ankit Sharma, 2014 .

Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions.

J. Hartwig, M. Kawatsura, O. Loeber, 2001, Journal of the American Chemical Society.

Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydroboration and Dehydroboration.

J. Hartwig, T. W. Butcher, Steven Hanna, 2022, Organic letters.

Structure, synthesis, and chemistry of ruthenium complex (PMe3)4Ru(.eta.2-benzyne). Reactions with arenes, alkenes, and heteroatom-containing organic compounds. Synthesis and structure of a monomeric hydroxide complex

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Palladium-Catalyzed Oxidative Dehydrosilylation for Contra-Thermodynamic Olefin Isomerization

J. Hartwig, T. W. Butcher, Steven Hanna, 2020 .

Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization.

J. Hartwig, T. W. Butcher, Steven Hanna, 2019, Organic letters.

Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products.

S. Shekhar, J. Hartwig, Brian M. Trantow, 2006, Journal of the American Chemical Society.

A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism.

J. Hartwig, Y. Nakao, M. Kawatsura, 2002, Journal of the American Chemical Society.

Catalytic Organometallic Reactions of Ammonia

J. Hartwig, Jessica L. Klinkenberg, 2011 .

Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides.

J. Hartwig, S. Ge, Shaozhong Ge, 2012, Angewandte Chemie.

Zinc trimethylsilylamide as a mild ammonia equivalent and base for the amination of aryl halides and triflates.

J. Hartwig, D. Lee, 2005, Organic letters.

Slow reductive elimination from arylpalladium parent amido complexes.

J. Hartwig, Jessica L. Klinkenberg, 2010, Journal of the American Chemical Society.

Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex.

J. Hartwig, P. Fier, Jingwei Luo, 2013, Journal of the American Chemical Society.

One-pot synthesis of arylboronic acids and aryl trifluoroborates by Ir-catalyzed borylation of arenes.

J. Hartwig, C. C. Tzschucke, Jaclyn M. Murphy, 2007, Organic letters.

Rhodium boryl complexes in the catalytic, terminal functionalization of alkanes.

C. E. Webster, Kevin S. Cook, C. Incarvito, 2005, Journal of the American Chemical Society.

Hydrocarbon Functionalization by Transition Metal Boryls

Xiaoming He, J. Hartwig, K. Waltz, 1995 .

Mechanism of beta-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands.

J. Hartwig, J. Zhao, H. Hesslink, 2001, Journal of the American Chemical Society.

Isolated Ir(V) boryl complexes and their reactions with hydrocarbons.

J. Hartwig, K. Kawamura, K. Kawamura, 2001, Journal of the American Chemical Society.

Tropene derivatives by sequential intermolecular and transannular, intramolecular palladium-catalyzed hydroamination of cycloheptatriene.

J. Hartwig, Norio Sakai, A. Ridder, 2006, Journal of the American Chemical Society.

Palladium-catalyzed addition of mono- and dicarbonyl compounds to conjugated dienes.

J. Hartwig, A. Leitner, J. Larsen, 2004, The Journal of organic chemistry.

Catalytic Asymmetric Addition of an Amine N-H Bond Across Internal Alkenes

J. Hartwig, Yumeng Xi, Senjie Ma, 2020, Nature.

Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes.

J. Hartwig, R. Kuwano, M. Kawatsura, 2003, Journal of the American Chemical Society.

Enantioselective hydroamination of unactivated terminal alkenes.

J. Hartwig, Yumeng Xi, H. Fan, 2022, Chem.

Raising the Bar for the "Perfect Reaction"

J. Hartwig, 2002, Science.

A phosphorus-carbon bond cleavage reaction of coordinated trimethylphosphine in (PMe3)4Ru(OC6H4Me)2

J. Hartwig, R. Bergman, R. Andersen, 1990 .

Distinct thermodynamics for the formation and cleavage of N-H bonds in aniline and ammonia. Directly-observed reductive elimination of ammonia from an isolated amido hydride complex.

T. Emge, Jing Zhao, C. Incarvito, 2003, Journal of the American Chemical Society.

Nickel- vs Palladium-Catalyzed Synthesis of Protected Phenols from Aryl Halides

J. Hartwig, G. Mann, 1997 .

Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands: Evidence for the Reaction of Iodoarenes with Ligated Anionic CuI Intermediates.

J. Hartwig, Marc Font, R. Giri, 2018, Journal of the American Chemical Society.

Synthesis and chemistry of ruthenium hydrido aryloxides and arylamides. An investigation of structure, nitrogen-hydrogen and oxygen-hydrogen elimination processes, proton-catalyzed exchange reactions, and relative Ru-X bond strengths

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Catalytic hydroxylation of polypropylenes.

M. Hillmyer, Chulsung Bae, J. Hartwig, 2005, Journal of the American Chemical Society.

Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature.

T. Ogata, J. Hartwig, 2008, Journal of the American Chemical Society.

Inter- and intramolecular carbon-hydrogen bond forming and cleavage reactivity of two different types of poly(trimethylphosphine)ruthenium intermediates

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Directly observed reductive elimination of aryl halides from monomeric arylpalladium(II) halide complexes.

Amy H. Roy, J. Hartwig, A. H. Roy, 2003, Journal of the American Chemical Society.

Mechanism of the Iridium-Catalyzed Silylation of Aromatic C-H Bonds.

J. Hartwig, Caleb Karmel, 2020, Journal of the American Chemical Society.

Synthetic chemistry: Recipes for excess

J. Hartwig, 2005, Nature.

Mild palladium-catalyzed selective monoarylation of nitriles.

J. Hartwig, Lingyun Wu, 2005, Journal of the American Chemical Society.

Oxalohydrazide Ligands for Copper-Catalyzed C-O Coupling Reactions with High Turnover Numbers.

J. Hartwig, Ritwika Ray, 2020, Angewandte Chemie.

Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes.

J. Hartwig, C. Krug, 2002, Journal of the American Chemical Society.

A Heck-Type Reaction Involving Carbon−Heteroatom Double Bonds. Rhodium(I)-Catalyzed Coupling of Aryl Halides with N-Pyrazyl Aldimines

J. Hartwig, A. Ishiyama, 2000 .

A Heck‐Type Reaction Involving Carbon—Heteroatom Double Bonds. Rhodium(I)‐Catalyzed Coupling of Aryl Halides with N‐Pyrazyl Aldimines.

J. Hartwig, Tatsuo Ishiyama, 2001 .

Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C—H Bonds.

J. Hartwig, Naofumi Tsukada, 2005 .

σ-Borane Complexes of Manganese and Rhenium

J. Hartwig, Sabine Schlecht and, 2000 .

Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands.

J. Hartwig, Fabiola Barrios-Landeros, 2005, Journal of the American Chemical Society.

A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines by Three-Coordinate Intermediates

J. Hartwig, M. Driver, 1995 .

Assessment of the Electronic Factors Determining the Thermodynamics of "Oxidative Addition" of C-H and N-H Bonds to Ir(I) Complexes.

J. Hartwig, K. Krogh-Jespersen, A. Goldman, 2016, Journal of the American Chemical Society.

Structure and reactions of oxametallacyclobutanes and oxametallacyclobutenes of ruthenium

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Time-resolved IR studies on the mechanism for the functionalization of primary C-H bonds by photoactivated Cp*W(CO)3(Bpin).

Karma R. Sawyer, C. E. Webster, M. Kling, 2010, Journal of the American Chemical Society.

Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion.

J. Hartwig, Wenyong Chen, 2013, Journal of the American Chemical Society.

Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis.

J. Hartwig, Xingyu Jiang, Philip Boehm, 2018, Journal of the American Chemical Society.

Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones.

J. Hartwig, Xingyu Jiang, Wenyong Chen, 2016, Angewandte Chemie.

Control of Diastereoselectivity for Iridium‐Catalyzed Allylation of a Prochiral Nucleophile with a Phosphate Counterion.

J. Hartwig, Wenyong Chen, 2013 .

Origins of Regioselectivity in Iridium Catalyzed Allylic Substitution.

J. Hartwig, Q. Li, S. Madrahimov, 2015, Journal of the American Chemical Society.

Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes.

J. Hartwig, S. Madrahimov, 2012, Journal of the American Chemical Society.

Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates.

J. Hartwig, L. Stanley, M. Ueda, 2010, Journal of the American Chemical Society.

Iridium‐Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α‐Alkoxy Ketones.

J. Hartwig, Xingyu Jiang, Wenyong Chen, 2016 .

Catalytic deconstruction of waste polyethylene with ethylene to form propylene

A. Bell, J. Hartwig, Liang Qi, 2022, Science.

Palladium-catalyzed α-arylation for the addition of small rings to aromatic compounds

J. Hartwig, Zhiheng He, 2019, Nature Communications.

Recent advances in the discovery of organometallic catalysts using high-throughput screening assays.

J. Hartwig, James P Stambuli, John F Hartwig, 2003, Current opinion in chemical biology.

A Short Synthesis of Tetraalkoxydiborane(4) Reagents

J. Hartwig, K. Waltz, N. R. Anastasi, 2003 .

Reductive elimination from arylpalladium cyanide complexes.

J. Hartwig, Jessica L. Klinkenberg, 2012, Journal of the American Chemical Society.

Iridium‐Catalyzed Diastereoselective Dehydrogenative Silylation of Terminal Alkenes with (TMSO)2MeSiH.

J. Hartwig, C. Cheng, E. Simmons, 2014 .

Synthesis of monomeric ruthenium hydroxo complexes (PMe3)4Ru(R)(OH) (R = H, Me) and a unique dimeric ruthenium hydroxo-water complex [trans-Ru(H)(OH)(DMPE)2.cntdot.H2O]2

J. Hartwig, R. Bergman, F. Hollander, 1993 .

Transition metal boryl complexes: structure and reactivity of CpFe(CO)2Bcat and CpFe(CO)2BPh2

J. Hartwig, S. Huber, 1993 .

Rhodium silyl boryl hydride complexes: comparison of bonding and the rates of elimination of borane, silane, and dihydrogen.

C. E. Webster, Kevin S. Cook, C. Incarvito, 2004, Angewandte Chemie.

Effect of Ligand Structure on the Electron Density and Activity of Iridium Catalysts for the Borylation of Alkanes.

J. Hartwig, M. Larsen, Raphael J. Oeschger, 2020, ACS catalysis.

Reactivity of Tungstenocene with BB and BH Bonds versus CH Bonds

Xiaoming He, J. Hartwig, 1996 .

Oxygen- and carbon-bound ruthenium enolates: migratory insertion, reductive elimination, .beta.-hydrogen elimination, and cyclometalation reactions

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Mechanism of the carbon-carbon cleavage of acetone by the ruthenium benzyne complex (PMe3)4Ru(.eta.2-C6H4): formation and reactivity of an oxametallacyclobutane complex

J. Hartwig, R. Bergman, R. Andersen, 1990 .

C−H Activation and Functionalization of Unsaturated Hydrocarbons by Transition-Metal Boryl Complexes

J. Hartwig, K. Waltz, C. Muhoro, 1999 .

One-pot synthesis of unsymmetrical diaryl thioethers by palladium-catalyzed coupling of two aryl bromides and a thiol surrogate.

J. Hartwig, M. A. Fernández-Rodríguez, 2010, Chemistry.

The Largest Discrete Oligo(m-aniline). An Exponential Growth Strategy Using Palladium-Catalyzed Amination of Aryl Sulfonates

J. Hartwig, J. Louie, 1998 .

A Fluorescence-Based Assay for High-Throughput Screening of Coupling Reactions. Application to Heck Chemistry

John F. Hartwig, J. Hartwig, K. H. Shaughnessy, 1999 .

Enantioselective Synthesis of Tertiary Allylic Fluorides by Iridium-Catalyzed Allylic Fluoroalkylation.

J. Hartwig, T. W. Butcher, 2018, Angewandte Chemie.

Identification of an Activated Catalyst in the Iridium‐Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity.

C. Incarvito, J. Hartwig, C. Kiener, 2004 .

Regioselective and enantioselective iridium-catalyzed allylation of enamines.

D. Weix, J. Hartwig, 2007, Journal of the American Chemical Society.

Iridium‐Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides.

J. Hartwig, M. Chen, 2016 .

Synthesis, Structure, and Reactivity of a Palladium Hydrazonato Complex: A New Type of Reductive Elimination Reaction To Form C-N Bonds and Catalytic Arylation of Benzophenone Hydrazone.

J. Hartwig, 1998, Angewandte Chemie.

Reductive elimination of aryl halides from palladium(II).

Amy H. Roy, J. Hartwig, A. H. Roy, 2001, Journal of the American Chemical Society.

Artificial Biosynthetic Pathway for an Unnatural Terpenoid with an Iridiumcontaining P450

J. Keasling, A. Mukhopadhyay, J. Hartwig, 2020 .

Site-Selective Functionalization of (sp3)C-H Bonds Catayzed by Artificial Metalloenzymes Containing an Iridium-Porphyrin Cofactor.

D. Clark, J. Hartwig, Zhennan Liu, 2019, Angewandte Chemie.

Noble-Metal Substitution in Hemoproteins: An Emerging Strategy for Abiological Catalysis.

J. Hartwig, S. Natoli, 2019, Accounts of chemical research.

Abiological catalysis by artificial haem proteins containing noble metals in place of iron

Paweł Dydio, D. Clark, J. Hartwig, 2016, Nature.

Tetraazacyclophanes by Palladium-Catalyzed Aromatic Amination. Geometrically Defined, Stable, High-Spin Diradicals

J. Hartwig, S. Hauck, A. Lakshmi, 1999 .

Discrete High Molecular Weight Triarylamine Dendrimers Prepared by Palladium-Catalyzed Amination

J. Hartwig, A. Fry, J. Louie, 1997 .

A photochemical source of dibromo- and dichlorocarbene

R. Moss, J. Hartwig, Maitland Jones, 1986 .

Regioselective borylation of the C-H bonds in alkylamines and alkyl ethers. Observation and origin of high reactivity of primary C-H bonds beta to nitrogen and oxygen.

J. Hartwig, Q. Li, Carl W. Liskey, 2014, Journal of the American Chemical Society.

β-Aryl Eliminations from Rh(I) Iminyl Complexes

J. Hartwig, Pinjing Zhao, 2005 .

Broensted Acid-Catalyzed Intramolecular Hydroamination of Protected Alkenylamines. Synthesis of Pyrrolidines and Piperidines.

J. Hartwig, B. Schlummer, 2002 .

Sterically controlled iodination of arenes via iridium-catalyzed C-H borylation.

J. Hartwig, B. Partridge, 2013, Organic letters.

Palladium-Catalyzed Enantioselective α-Arylation of α-Fluoroketones.

J. Hartwig, J. Zhou, S. Ge, 2016, Journal of the American Chemical Society.

Unnatural Biosynthesis by an Engineered Microorganism with Heterologously Expressed Natural Enzymes and an Artificial Metalloenzyme

J. Keasling, D. Clark, A. Mukhopadhyay, 2021, Nature Chemistry.

Transmetalation, Involving Organotin Aryl, Thiolate, and Amide Compounds. An Unusual Type of Dissociative Ligand Substitution Reaction

J. Hartwig, J. Louie, 1995 .

Progress, Challenges, and Opportunities with Artificial Metalloenzymes in Biosynthesis.

D. Clark, J. Hartwig, B. Bloomer, 2022, Biochemistry.

Assembly and Evolution of Artificial Metalloenzymes within E. coli Nissle 1917 for Enantioselective and Site-Selective Functionalization of C─H and C═C Bonds.

Z. Liu, J. Keasling, D. Clark, 2022, Journal of the American Chemical Society.

Report of the Basic Energy Sciences Roundtable on Chemical Upcycling of Polymers

Maureen C. McCann, Christopher J. Ellison, Dion Vlachos, 2019 .

Regiospecific functionalization of methyl C-H bonds of alkyl groups in reagents with heteroatom functionality.

Chulsung Bae, J. Hartwig, Makoto Takahashi, 2004, Journal of the American Chemical Society.

DNA binding properties of [Pt(NH3)(C6H11NH2)Cl2], a metabolite of an orally active platinum anticancer drug

S. Lippard, J. Hartwig, 1992 .

Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate

J. Hartwig, J. Louie, M. Driver, 1997 .

Complete integration of carbene-transfer chemistry into biosynthesis

J. H. Pereira, J. Keasling, C. Petzold, 2023, Nature.

Titanocene Borane σ-Complexes

J. Hartwig, Clare N. Muhoro, Xiaoming He, 1999 .

Copper-Catalyzed Defluorinative Borylation and Silylation of gem-Difluoroallyl Groups.

J. Hartwig, J. L. Yang, T. W. Butcher, 2020, Organic letters.

Abiotic reduction of ketones with silanes catalyzed by carbonic anhydrase through an enzymatic zinc hydride

D. Clark, J. Hartwig, Pengfei Ji, 2021, Nature Chemistry.

Boryls Bound to Iron Carbonyl. Structure of a Rare Bis(boryl) Complex, Synthesis of the First Anionic Boryl, and Reaction Chemistry That Includes the Synthetic Equivalent of Boryl Anion Transfer

Xiaoming He, J. Hartwig, 1996 .

Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C-H Bonds.

J. Hartwig, Taegyo Lee, 2017, Journal of the American Chemical Society.

Catalytic undirected borylation of tertiary C–H bonds in bicyclo[1.1.1]pentanes and bicyclo[2.1.1]hexanes

J. Hartwig, D. Volochnyuk, S. Ryabukhin, 2023, Nature Chemistry.

Iridium‐Catalyzed, Intermolecular Hydroamination of Unactivated Alkenes with Indoles.

C. Sevov, J. Hartwig, J. Zhou, 2014 .

Transition-Metal-Catalyzed Monofluoroalkylation: Strategies for the Synthesis of Alkyl Fluorides by C-C Bond Formation.

W. Amberg, J. Hartwig, T. W. Butcher, 2021, Angewandte Chemie.

Carbon(sp3)-nitrogen bond-forming reductive elimination from phosphine-ligated alkylpalladium(II) amide complexes: A DFT study

T. Cundari, J. Hartwig, Q. Jiang, 2019, Tetrahedron.

Palladium‐Catalyzed Arylation of Fluoroalkylamines.

J. Hartwig, Andrew T. Brusoe, 2015 .

Mechanistic Studies on Oxidative Addition of Aryl Halides and Triflates to Pd(BINAP)2 and Structural Characterization of the Product from Aryl Triflate Addition in the Presence of Amine

J. Hartwig, Luis M. Alcazar-Roman and, 2002 .

Directed Evolution of Artificial Metalloenzymes in Whole Cells.

J. Hartwig, Zhennan Liu, Y. Gu, 2021, Angewandte Chemie.

Beyond Iron: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse Alkenes

D. Clark, J. Hartwig, Zhennan Liu, 2017, ACS central science.

Mechanistic and structural characterization of an iridium-containing cytochrome reveals kinetically relevant cofactor dynamics

J. H. Pereira, P. Adams, D. Clark, 2023, Nature Catalysis.

Structural and Reaction Chemistry of Tungstenocene Boryl Complexes

Xiaoming He, J. Hartwig, 1996 .

gem-Difluoroallylation of Aryl Halides and Pseudo Halides with Difluoroallylboron Reagents in High Regioselectivity.

J. Hartwig, J. L. Yang, S. Sakamoto, 2021, Angewandte Chemie.

Reductive Elimination to Form C(sp3)–N Bonds from Palladium(II) Primary Alkyl Complexes

T. Cundari, J. Hartwig, Q. Jiang, 2018, Organometallics.

Insertion reactions of carbon monoxide and carbon dioxide with ruthenium benzyl, arylamido, and aryloxide complexes: a comparison of the reactivity of ruthenium-carbon, ruthenium-nitrogen, and ruthenium-oxygen bonds

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Ruthenium-Catalyzed, Chemoselective and Regioselective Oxidation of Polyisobutene.

J. Hartwig, A. Uliana, Katerina G. Malollari, 2021, Journal of the American Chemical Society.

Carbon-oxygen bond formation between a terminal alkoxo ligand and a coordinated olefin. Evidence for olefin insertion into a rhodium alkoxide.

C. Incarvito, J. Hartwig, Pinjing Zhao, 2006, Journal of the American Chemical Society.

First Transition Metal-Boryl Bond Energy and Quantitation of Large Differences in Sequential Bond Dissociation Energies of Boranes

S. Nolan, J. Hartwig, P. Rablen, 1994 .

Synthesis and DNA binding properties of a cisplatin analog containing a tethered dansyl group

S. Lippard, J. Hartwig, P. Pil, 1992 .

Sequential Xanthalation and O-Trifluoromethylation of Phenols: A Procedure for the Synthesis of Aryl-trifluoromethyl Ethers.

J. Hartwig, Y. Lian, Makoto Yoritate, 2019, The Journal of organic chemistry.

Discovery of the Azaserine Biosynthetic Pathway Uncovers a Biological Route for α-Diazoester Production.

J. Keasling, E. Balskus, J. Hartwig, 2023, Angewandte Chemie.

Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates J. Am. Chem. Soc. 1998, 120, 7369−7370

J. Hartwig, Blake C. Hamann and, 1998 .

Thermal, catalytic, regiospecific functionalization of alkanes

Hartwig, S. Schlecht, J. Hartwig, 2000, Science.

Remote Hydroamination of Disubstituted Alkenes by a Combination of Isomerization and Regioselective N-H Addition.

J. Hartwig, Yumeng Xi, H. Fan, 2023, Journal of the American Chemical Society.

Progression of Hydroamination Catalyzed by Late Transition-Metal Complexes from Activated to Unactivated Alkenes.

J. Hartwig, Senjie Ma, 2023, Accounts of chemical research.

Palladium‐Catalyzed Arylation of Trimethylsilyl Enolates of Esters and Imides. High Functional Group Tolerance and Stereoselective Synthesis of α‐Aryl Carboxylic Acid Derivatives.

J. Hartwig, Xiaoxiang Liu, 2004 .

Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation: Dissecting the Importance of Chelation and Steric Hindrance.

J. Hartwig, M. Kawatsura, 1999 .

Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions.

J. Hartwig, D. Culkin, Xiaoxiang Liu, 2003, Journal of the American Chemical Society.

Pd‐Catalyzed α‐Arylation of Trimethylsilyl Enol Ethers with Aryl Bromides and Chlorides: A Synergistic Effect of Two Metal Fluorides as Additives

J. Hartwig, W. Su, X. Liao, 2006 .

Cyanation of Arenes via Iridium‐Catalyzed Borylation.

J. Hartwig, X. Liao, Carl W. Liskey, 2011 .

Transfer of amido groups from isolated rhodium(I) amides to alkenes and vinylarenes.

J. Hartwig, Pinjing Zhao, C. Krug, 2005, Journal of the American Chemical Society.

Iridium-Catalyzed, Site-Selective Silylation of Secondary C(sp3)-H Bonds in Secondary Alcohols and Ketones.

J. Hartwig, Bo Su, Makoto Yoritate, 2023, Journal of the American Chemical Society.

A C-H borylation approach to Suzuki-Miyaura coupling of typically unstable 2-heteroaryl and polyfluorophenyl boronates.

J. Hartwig, Daniel W. Robbins, 2012, Organic letters.

Iridium-catalyzed C-H borylation of heteroarenes: scope, regioselectivity, application to late-stage functionalization, and mechanism.

J. Hartwig, M. Larsen, 2014, Journal of the American Chemical Society.

Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions.

J. Hartwig, Brad P. Carrow, 2011, Journal of the American Chemical Society.

Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers.

J. Hartwig, D. Blakemore, J. Kohrt, 2016, Angewandte Chemie.

Copper-Mediated Perfluoroalkylation of Heteroaryl Bromides with (phen)CuRF

J. Hartwig, P. Fier, Michael G. Mormino, 2014, Organic letters.

Trifluoromethylation of Arylsilanes with [(phen)CuCF3 ].

J. Hartwig, C. Cheng, Johannes Morstein, 2016, Angewandte Chemie.

Copper-Catalyzed Defluorinative Borylation and Silylation of gem-Difluoroallyl Groups.

J. Hartwig, J. L. Yang, T. W. Butcher, 2020, Organic letters.

Pyrrole Functionalization by Copper‐Catalyzed Nitrene Transfer Reactions

M. M. Díaz‐Requejo, P. Pérez, J. Hartwig, 2020, Israel Journal of Chemistry.

Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates.

J. Hartwig, M. Ueda, 2010, Organic letters.

Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands: Evidence for the Reaction of Iodoarenes with Ligated Anionic CuI Intermediates.

J. Hartwig, Marc Font, R. Giri, 2018, Journal of the American Chemical Society.

Cross-coupling by a noncanonical mechanism involving the addition of aryl halide to Cu(II)

G. Rao, J. Hartwig, S. Fantasia, 2023, Science.

From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction.

F. Meier, M. Driess, M. Kaupp, 2013, Journal of the American Chemical Society.

Copper(I) enolate complexes in α-arylation reactions: synthesis, reactivity, and mechanism.

J. Hartwig, Zheng Huang, 2012, Angewandte Chemie.

Cooperative asymmetric reactions combining photocatalysis and enzymatic catalysis

J. Hartwig, Huimin Zhao, Yajie Wang, 2018, Nature.

Catalytic, Regiospecific End-Functionalization of Alkanes: Rhenium-Catalyzed Borylation under Photochemical Conditions.

Hartwig, J. Hartwig, Huiyuan Chen, 1999, Angewandte Chemie.

Cyanation of arenes via iridium-catalyzed borylation.

J. Hartwig, X. Liao, Carl W. Liskey, 2010, Journal of the American Chemical Society.

Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates.

J. Hartwig, L. Stanley, M. Ueda, 2010, Journal of the American Chemical Society.

Diastereo- and Enantioselective Iridium-Catalyzed Allylation of Cyclic Ketone Enolates: Synergetic Effect of Ligands and Barium Enolates

J. Hartwig, Wenyong Chen, M. Chen, 2014, Journal of the American Chemical Society.

Hydroaminoalkylation of unactivated olefins with dialkylamines.

J. Hartwig, S. Herzon, 2008, Journal of the American Chemical Society.

Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones.

J. Hartwig, M. Chen, 2014, Angewandte Chemie.

Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex.

J. Hartwig, Toshimichi Ohmura, 2002, Journal of the American Chemical Society.

Metal-catalyzed Azidation of Tertiary C–h Bonds Suitable for Late-stage Functionalization Hhs Public Access Supplementary Material

J. Hartwig, Ankit Sharma, J. F. H. Conceived, 2022 .

Mechanistic studies on direct arylation of pyridine N-oxide: evidence for cooperative catalysis between two distinct palladium centers.

J. Hartwig, Fabiola Barrios-Landeros, Yichen Tan, 2012, Journal of the American Chemical Society.

Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands.

J. Hartwig, N. Saper, 2017, Journal of the American Chemical Society.

Metal Complexes as Catalysts for Carbon—Heteroatom Cross‐Coupling Reactions

J. Hartwig, 2004 .

Catalytic Hydroxylation of Polyethylenes

J. Hartwig, Q. Li, Sunwoo Lee, 2005, ACS central science.

Palladium‐Catalyzed Amination of Aryl Halides and Sulfonates

J. Hartwig, 2004 .

Relative rates for the amination of η3-allyl and η3-benzyl complexes of palladium

Jesse W. Tye, J. Hartwig, Adam M. Johns, 2006 .

Rhodium phosphine-π-arene intermediates in the hydroamination of alkenes.

J. Hartwig, S. Madrahimov, Zhijian Liu, 2011, Journal of the American Chemical Society.

Mechanism of the rhodium-catalyzed silylation of arene C-H bonds.

J. Hartwig, C. Cheng, 2014, Journal of the American Chemical Society.

Iridium‐Catalyzed C—H Borylation of Cyclopropanes.

J. Hartwig, Carl W. Liskey, 2013 .

Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds.

J. Hartwig, Dale R. Pahls, Carolyn S. Wei, 2009, Chemical communications.

Iridium-catalyzed, diastereoselective dehydrogenative silylation of terminal alkenes with (TMSO)2MeSiH.

J. Hartwig, C. Cheng, E. Simmons, 2013, Angewandte Chemie.

One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination.

J. Hartwig, Alexandra E Strom, 2013, The Journal of organic chemistry.