T. Gunnoe

发表

A Generalized Synthetic Strategy for Transition Metal Doped Brookite-Phase TiO2 Nanorods.

Jennifer D Lee, Shuang Li, C. Murray, 2019, Journal of the American Chemical Society.

Electrophilic Rh-I catalysts for arene H/D exchange in acidic media: Evidence for an electrophilic aromatic substitution mechanism

W. Goddard, Robert J Nielsen, T. Gunnoe, 2017 .

Oxygen Atom Insertion into Iron(II) Phenyl and Methyl Bonds: A Key Step for Catalytic Hydrocarbon Functionalization

T. Cundari, T. Gunnoe, Jiajun Mei, 2014 .

Catalytic oxy-functionalization of methane and other hydrocarbons: fundamental advancements and new strategies.

T. Gunnoe, Joanna R. Webb, T. Bolaño, 2011, ChemSusChem.

Activation of carbon-hydrogen bonds and dihydrogen by 1,2-CH-addition across metal-heteroatom bonds.

T. Cundari, T. Gunnoe, Joanna R. Webb, 2013, Dalton transactions.

Metal‐Mediated Carbon–Hydrogen Bond Activation

T. Gunnoe, 2010 .

Theory of late-transition-metal alkyl and heteroatom bonding: analysis of Pt, Ru, Ir, and Rh complexes.

T. Gunnoe, D. Ess, Deepa Devarajan, 2012, Inorganic chemistry.

Introduction: Alkane C–H Activation by Single-Site Metal Catalysis

T. Gunnoe, 2012 .

Facile and Regioselective C–H Bond Activation of Aromatic Substrates by an Fe(II) Complex Involving a Spin-Forbidden Pathway

T. Cundari, T. Gunnoe, D. Ess, 2013 .

Selective monooxidation of light alkanes using chloride and iodate.

J. Groves, R. Periana, T. Gunnoe, 2014, Journal of the American Chemical Society.

Combined experimental and computational study of W(II), Ru(II), Pt(IV) and Cu(I) amine and amido complexes using 15N NMR spectroscopy

Samuel A. Delp, T. Cundari, T. Gunnoe, 2009 .

Combined Furan C–H Activation and Furyl Ring-Opening by an Iron(II) Complex

T. Gunnoe, S. Kalman, M. Sabat, 2016 .

Ru(II) catalysts supported by hydridotris(pyrazolyl)borate for the hydroarylation of olefins: reaction scope, mechanistic studies, and guides for the development of improved catalysts.

T. Cundari, Zhuofeng Ke, T. Gunnoe, 2009, Accounts of chemical research.

Rhodium bis(quinolinyl)benzene complexes for methane activation and functionalization.

W. Goddard, Robert J Nielsen, T. Gunnoe, 2015, Chemistry.

DFT Virtual Screening Identifies Rhodium−Amidinate Complexes As Potential Homogeneous Catalysts for Methane-to-Methanol Oxidation

W. Goddard, Robert J Nielsen, T. Gunnoe, 2014 .

The para-substituent effect and pH-dependence of the organometallic Baeyer-Villiger oxidation of rhenium-carbon bonds.

W. Goddard, R. Periana, Robert J Nielsen, 2012, Dalton transactions.

Rhodium and Iridium Complexes Bearing “Capping Arene” Ligands: Synthesis and Characterization

W. Goddard, C. Musgrave, D. Dickie, 2021, Organometallics.

Functionalization of rhenium aryl bonds by O-atom transfer

W. Goddard, R. Periana, Robert J Nielsen, 2011 .

Formation of Hydroxyindenyl and Vinylidene Ligands by Reaction of Internal Alkynes with Cp*Fe(CO)(NCMe)Ph

T. Gunnoe, S. Kalman, M. Sabat, 2014 .

Reactivity of TpRu(L)(NCMe)R (L = CO, PMe3; R = Me, Ph) systems with isonitriles : Experimental and computational studies toward the intra-and intermolecular hydroarylation of isonitriles

T. Cundari, T. Gunnoe, John P. Lee, 2007 .

Chemistry Surrounding Group 7 Complexes that Possess Poly(pyrazolyl)borate Ligands

Marty Lail, T. Gunnoe, K. Pittard, 2008 .

Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex.

T. Gunnoe, P. Boyle, J. L. Petersen, 2008, Inorganic chemistry.

Reductive C–C Coupling from Molecular Au(I) Hydrocarbyl Complexes: A Mechanistic Study

D. Dickie, T. Gunnoe, Jesús Campos, 2021, Journal of the American Chemical Society.

Pt(II) and Pt(IV) amido, aryloxide, and hydrocarbyl complexes: synthesis, characterization, and reaction with dihydrogen and substrates that possess C-H bonds.

T. Cundari, T. Gunnoe, M. Sabat, 2011, Inorganic chemistry.

Octahedral Ru(II) amido complexes TpRu(L)(L')(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L' = P(OMe)3 or PMe3 or L = CO and L' = PPh3; R = H, Ph, or tBu): synthesis, characterization, and reactions with weakly acidic C-H bonds.

K. Jayaprakash, T. Gunnoe, P. Boyle, 2003, Inorganic chemistry.

Mechanistic studies of ethylene hydrophenylation catalyzed by bipyridyl Pt(II) complexes.

T. Cundari, T. Gunnoe, Bradley A. McKeown, 2011, Journal of the American Chemical Society.

Studies of C–H Activation and Functionalization: Combined Computational and Experimental Efforts to Elucidate Mechanisms, Principles, and Catalysts

J. Groves, T. Gunnoe, Bradley A. McKeown, 2021 .

High Selectivity Towards Formate Production by Electrochemical Reduction of Carbon Dioxide at Copper-Bismuth Dendrites.

Yin Xu, G. Zangari, T. Gunnoe, 2018, ChemSusChem.

Electrochemical Reduction of Carbon Dioxide to Syngas and Formate at Dendritic Copper–Indium Electrocatalysts

G. Zangari, T. Gunnoe, Z. Hoffman, 2017 .

Nano-Apples and Orange-Zymes

Huimin Zhao, T. Gunnoe, S. Scott, 2020 .

Intramolecular Hydroalkoxylation and Hydroamination of Alkynes Catalyzed by Cu(I) Complexes Supported by N-Heterocyclic Carbene Ligands

Mark J. Pouy, Samuel A. Delp, T. Cundari, 2012 .

Phosphine and N-heterocyclic carbene ligands on Pt(II) shift selectivity from ethylene hydrophenylation toward benzene vinylation

T. Gunnoe, D. Ess, Bradley A. McKeown, 2015 .

1,2-Addition of dihydrogen across rhodium(III)-OMe bonds.

T. Gunnoe, D. Ess, Deepa Devarajan, 2014, Inorganic chemistry.

Aerobic Epoxidation of Olefin by Platinum Catalysts Supported on Mesoporous Silica Nanoparticles

B. Trewyn, T. Gunnoe, Michael S. Webster-Gardiner, 2016 .

Theoretical study of reductive functionalization of methyl ligands of group 9 complexes supported by two bipyridyl ligands: A key step in catalytic hydrocarbon functionalization

J. Groves, T. Cundari, T. Gunnoe, 2014 .

Manganese Catalyzed Partial Oxidation of Light Alkanes

W. Goddard, J. Goldberg, J. Groves, 2022, ACS Catalysis.

Advances in Group 10 Transition-Metal-Catalyzed Arene Alkylation and Alkenylation.

T. Gunnoe, Weihao Zhu, 2021, Journal of the American Chemical Society.

Net hydrogenation of Pt-NHPh bond is catalyzed by elemental Pt.

T. Cundari, T. Gunnoe, Joanna R. Webb, 2010, Journal of the American Chemical Society.

Synthesis of RhIII Anilido, Hydroxide, and Methoxide Complexes

T. Gunnoe, M. Sabat, T. Bolaño, 2015 .

DFT study of group 8 catalysts for the hydrophenylation of ethylene: Influence of ancillary ligands and metal identity

T. Cundari, T. Gunnoe, Glenn R. Morello, 2012 .

Density functional theory study of oxygen-atom insertion into metal-methyl bonds of iron(II), ruthenium(II), and osmium(II) complexes: study of metal-mediated C-O bond formation.

T. Cundari, T. Gunnoe, Jiajun Mei, 2014, Inorganic chemistry.

Cover Picture: Catalytic Oxy‐Functionalization of Methane and Other Hydrocarbons: Fundamental Advancements and New Strategies (ChemSusChem 1/2011)

T. Gunnoe, Joanna R. Webb, T. Bolaño, 2011 .

Novel insecticide polymer chemistry to reduce the enzymatic digestion of a protein pesticide, trypsin modulating oostatic factor (TMOF).

T. Gunnoe, R. Roe, Hongyan Shen, 2009 .

Catalytic Synthesis of Superlinear Alkenyl Arenes Using a Rh(I) Catalyst Supported by a "Capping Arene" Ligand: Access to Aerobic Catalysis.

W. Goddard, Junqi Chen, D. Dickie, 2018, Journal of the American Chemical Society.

Immobilization of “Capping Arene” Cobalt(II) Complexes on Ordered Mesoporous Carbon for Electrocatalytic Water Oxidation

W. Goddard, C. Musgrave, Cheng-Jun Sun, 2021, ACS Catalysis.

Enhanced activity of an insecticidal protein, trypsin modulating oostatic factor (TMOF), through conjugation with aliphatic polyethylene glycol.

B. Bissinger, T. Gunnoe, R. Roe, 2012, Pest management science.

Activation of carbon-hydrogen bonds via 1,2-addition across M-X (X = OH or NH(2)) bonds of d(6) transition metals as a potential key step in hydrocarbon functionalization: a computational study.

T. Cundari, T. Gunnoe, Thomas V. Grimes, 2007, Journal of the American Chemical Society.

Functionalization of RhIII–Me Bonds: Use of “Capping Arene” Ligands to Facilitate Me–X Reductive Elimination

W. Goddard, C. Musgrave, Junqi Chen, 2021, Organometallics.

Capping Arene Ligated Rhodium-Catalyzed Olefin Hydrogenation: A Model Study of the Ligand Influence on a Catalytic Process That Incorporates Oxidative Addition and Reductive Elimination

W. Goddard, C. Musgrave, D. Dickie, 2022, Organometallics.

Advances in Rhodium-Catalyzed Oxidative Arene Alkenylation.

T. Gunnoe, Weihao Zhu, 2020, Accounts of chemical research.

PtII-Catalyzed Hydrophenylation of α-Olefins: Variation of Linear/Branched Products as a Function of Ligand Donor Ability

T. Cundari, T. Gunnoe, Bradley A. McKeown, 2014 .

Selective CH functionalization of methane, ethane, and propane by a perfluoroarene iodine(III) complex.

J. Groves, R. Periana, T. Gunnoe, 2014, Angewandte Chemie.

Partial oxidation of light alkanes by periodate and chloride salts.

J. Groves, T. Gunnoe, S. Kalman, 2015, Dalton transactions.

Cu(II) carboxylate arene C─H functionalization: Tuning for nonradical pathways

S. Chen, Junqi Chen, D. Dickie, 2022, Science advances.

Effects of Additives on Catalytic Arene C–H Activation: Study of Rh Catalysts Supported by Bis-phosphine Pincer Ligands

D. Dickie, Sen Zhang, Chang Liu, 2020 .

Synthesis and Reactivity of a Coordinatively Unsaturated Ruthenium(II) Parent Amido Complex: Studies of X-H Activation (X = H or C)

T. Cundari, K. Jayaprakash, T. Gunnoe, 2004 .

Transition-Metal-Mediated Nucleophilic Aromatic Substitution with Acids

W. Goddard, Robert J Nielsen, T. Gunnoe, 2016 .

Long-range C-H bond activation by Rh(III)-carboxylates.

W. Goddard, Robert J Nielsen, T. Gunnoe, 2014, Journal of the American Chemical Society.

Transition-Metal-Catalyzed Arene Alkylation and Alkenylation: Catalytic Processes for the Generation of Chemical Intermediates

T. Gunnoe, W. Schinski, Xiaofan Jia, 2020 .

Transition Metal Mediated C–H Activation and Functionalization: The Role of Poly(pyrazolyl)borate and Poly(pyrazolyl)alkane Ligands

T. Cundari, T. Gunnoe, Bradley A. McKeown, 2016 .

Reductive Functionalization of a Rhodium(III)–Methyl Bond in Acidic Media: Key Step in the Electrophilic Functionalization of Methane

T. Cundari, T. Gunnoe, Matthew E. O’Reilly, 2014 .

Variable pathways for oxygen atom insertion into metal-carbon bonds: the case of Cp*W(O)2(CH2SiMe3).

Cody R. Freitag, T. Cundari, T. Gunnoe, 2013, Journal of the American Chemical Society.

Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds.

Mark J. Pouy, J. Groves, T. Cundari, 2012, Journal of the American Chemical Society.

Transition metal catalyzed hydroarylation of olefins using unactivated substrates: Recent developments and challenges

T. Gunnoe, Bradley A. McKeown, Jeremy R. Andreatta, 2011 .

Hydroarylation of Unactivated Olefins Catalyzed by Platinum(II) Complexes

T. Gunnoe, Bradley A. McKeown, Nicholas A. Foley, 2008 .

PtII-Catalyzed Ethylene Hydrophenylation: Influence of Dipyridyl Chelate Ring Size on Catalyst Activity and Longevity

T. Cundari, T. Gunnoe, Bradley A. McKeown, 2013 .

Studies of the decomposition of the ethylene hydrophenylation catalyst TpRu(CO)(NCMe)Ph

T. Cundari, T. Gunnoe, Bradley A. McKeown, 2017 .

A rhodium catalyst for single-step styrene production from benzene and ethylene

T. Cundari, T. Gunnoe, Michael S. Webster-Gardiner, 2015, Science.

Reaction of a Tungsten(II) Methylene Complex with Excess Base To Form a C3H5-Bridged Dimer

T. Gunnoe, P. White, J. L. Templeton, 1997 .

Protonation of N-heterocyclic carbene ligand coordinated to copper(I) : Coordination mode of imidazolium cation as a function of counterion as determined by solid-state structures

T. Gunnoe, P. Boyle, J. L. Petersen, 2006 .

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes.

Samuel A. Delp, T. Gunnoe, Colleen Munro-Leighton, 2008, Chemical communications.

Mechanistic Studies of Single-Step Styrene Production Catalyzed by Rh Complexes with Diimine Ligands: An Evaluation of the Role of Ligands and Induction Period

Robert J. Davis, Junqi Chen, D. Dickie, 2019, ACS Catalysis.

Brønsted acid-catalysed intramolecular hydroamination of unactivated alkenes: metal triflates as an in situ source of triflic acid.

Junqi Chen, T. Gunnoe, Bradley A. McKeown, 2017, Dalton transactions.

Ethylene Dimerization and Oligomerization Using Bis(phosphino)boryl Supported Ni Complexes.

D. Dickie, T. Gunnoe, Pablo Ríos, 2022, Journal of the American Chemical Society.

Oxy-functionalization of Group 9 and 10 transition metal methyl ligands: use of pyridine-based hemi-labile ligands.

T. Cundari, T. Gunnoe, Bruce M. Prince, 2014, Dalton transactions.

Control of Olefin Hydroarylation Catalysis via a Sterically and Electronically Flexible Platinum(II) Catalyst Scaffold

T. Cundari, R. Crabtree, T. Gunnoe, 2013 .

Chemistry surrounding monomeric copper(I) methyl, phenyl, anilido, ethoxide, and phenoxide complexes supported by N-heterocyclic carbene ligands: reactivity consistent with both early and late transition metal systems.

Samuel A. Delp, T. Cundari, T. Gunnoe, 2006, Inorganic chemistry.

Insights into the Speciation of Cu in the Cu-H-Mordenite Catalyst for the Oxidation of Methane to Methanol

Robert J. Davis, T. Gunnoe, C. Paolucci, 2019, ACS Catalysis.

Ruthenium(II) complexes possessing the η6-p-cymene ligand

T. Gunnoe, P. Boyle, J. L. Petersen, 2008 .

Comparison of the Relative Electron-Donating Abilities of Hydridotris(pyrazolyl)borate and Cyclopentadienyl Ligands: Different Interactions with Different Transition Metals

D. Tellers, T. Gunnoe, R. Bergman, 2000 .

Proton or Metal? The H/D Exchange of Arenes in Acidic Solvents

W. Goddard, T. Gunnoe, Michael S. Webster-Gardiner, 2015 .

Arene C–H activation using Rh( i ) catalysts supported by bidentate nitrogen chelates

W. Goddard, Robert J Nielsen, T. Gunnoe, 2015 .

Carbon-oxygen bond formation via organometallic Baeyer-Villiger transformations: a computational study on the impact of metal identity.

T. Cundari, T. Gunnoe, Joanna R. Webb, 2012, Journal of the American Chemical Society.

Non-redox Oxy-Insertion via Organometallic Baeyer–Villiger Transformations: A Computational Hammett Study of Platinum(II) Complexes

T. Cundari, T. Gunnoe, Travis M. Figg, 2011 .

Organic Electrosynthesis: When Is It Electrocatalysis?

V. Stamenkovic, T. Gunnoe, A. Dey, 2020 .

Reactions of a Ru(II) Phenyl Complex with Substrates that Possess C-N or C-O Multiple Bonds: C-C Bond Formation, N-H Bond Cleavage, and Decarbonylation Reactions

Nathan J. DeYonker, T. Cundari, N. DeYonker, 2006 .

anti‐Markovnikov Hydroamination and Hydrothiolation of Electron‐Deficient Vinylarenes Catalyzed by Well‐Defined Monomeric Copper(I) Amido and Thiolate Complexes.

Samuel A. Delp, T. Gunnoe, Colleen Munro-Leighton, 2008 .

Addition of N−H and O−H Bonds of Amines and Alcohols to Electron-Deficient Olefins Catalyzed by Monomeric Copper(I) Systems: Reaction Scope, Mechanistic Details, and Comparison of Catalyst Efficiency

Samuel A. Delp, T. Gunnoe, Colleen Munro-Leighton, 2007 .

Anti-markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems.

T. Gunnoe, Colleen Munro-Leighton, Elizabeth D. Blue, 2006, Journal of the American Chemical Society.

Reactions of TpRu(CO)(NCMe)(Ph) with electron-rich olefins: examples of stoichiometric C-S, C-O and C-H bond cleavage.

Marty Lail, T. Gunnoe, J. L. Petersen, 2006, Chemical communications.

Noncovalent Immobilization of Pentamethylcyclopentadienyl Iridium Complexes on Ordered Mesoporous Carbon for Electrocatalytic Water Oxidation

W. Goddard, Hua Zhou, C. Musgrave, 2021, Small Science.

Electrocatalytic Water Oxidation by a Trinuclear Copper(II) Complex

W. Goddard, J. Granwehr, D. Dickie, 2021, ACS Catalysis.

2,2,2-Tris(pyrazolyl)ethoxide (Ep(OX)) ruthenium(II) complexes, (Ep(OX))RuCl(L)(L'): synthesis, structure, and reactivity.

T. Gunnoe, M. Sabat, B. Quillian, 2013, Inorganic chemistry.

Coordination chemistry of 4-methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,1]heptane: preparation and characterization of Ru(II) complexes.

T. Cundari, T. Gunnoe, M. Sabat, 2012, Inorganic chemistry.

Ligand-modulated stereo- and regioselective tandem addition reactions of rhenium-bound naphthalene.

T. Gunnoe, M. Sabat, W. Harman, 2002, Journal of the American Chemical Society.

Dihapto Binding of Aromatic Molecules by π-Basic Transition Metal Complexes: Development of Alternatives to the {Os(NH3)5}2+ Fragment

T. Gunnoe, W. Harman, B. C. Brooks, 2000 .

To Err is Human; To Reproduce Takes Time

P. Fornasiero, C. Crudden, T. Gunnoe, 2022, ACS Catalysis.

Hydrophenylation of ethylene using a cationic Ru(II) catalyst: comparison to a neutral Ru(II) catalyst

T. Cundari, T. Gunnoe, M. Sabat, 2014 .

Cleavage of X-H bonds (X = N, o, or C) by copper(I) alkyl complexes to form monomeric two-coordinate copper(I) systems.

T. Gunnoe, J. L. Petersen, Colleen Munro-Leighton, 2005, Inorganic chemistry.

Synthesis, solid-state crystal structure, and reactivity of a monomeric copper(I) anilido complex.

T. Gunnoe, P. White, P. Boyle, 2003, Journal of the American Chemical Society.

Reactions of (PCP)Ru(CO)(NHPh)(PMe3) (PCP = 2,6-(CH2PtBu2)2C6H3) with substrates that possess polar bonds.

T. Gunnoe, J. L. Petersen, Jubo Zhang, 2005, Inorganic chemistry.

Addition of arenes to ethylene and propene catalyzed by ruthenium.

Marty Lail, T. Gunnoe, B. N. Arrowood, 2003, Journal of the American Chemical Society.

C-H activation of pyrazolyl ligands by Ru(II).

T. Cundari, T. Gunnoe, M. Sabat, 2014, Inorganic chemistry.

Catalytic Hydrogenolysis of the Pt−OPh Bond of a Molecular Pt(II) Complex using Silica Supported Pd, Rh and Pt Nanoparticles

Robert J. Davis, D. Dickie, T. Gunnoe, 2022, ChemCatChem.

Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

W. Goddard, Junqi Chen, D. Dickie, 2020, Organometallics.

Selective Photo‐Oxygenation of Light Alkanes Using Iodine Oxides and Chloride

J. Goldberg, J. Groves, T. Gunnoe, 2019, ChemCatChem.

Aerobic Partial Oxidation of Alkanes Using Photodriven Iron Catalysis.

J. Goldberg, J. Groves, Yuan Cao, 2021, Inorganic chemistry.

Platinum(II)-Catalyzed Ethylene Hydrophenylation: Switching Selectivity between Alkyl- and Vinylbenzene Production

T. Cundari, T. Gunnoe, Bradley A. McKeown, 2013 .

Octahedral [TpRu(PMe3)2OR]n+ Complexes (Tp = hydridotris(pyrazolyl)borate; R = H or Ph; n = 0 or 1): Reactions at Ru(II) and Ru(III) Oxidation States with Substrates that Possess Carbon-Hydrogen Bonds

T. Cundari, T. Gunnoe, Thomas V. Grimes, 2006 .

Mechanistic Studies of Styrene Production from Benzene and Ethylene Using [(η2-C2H4)2Rh(μ-OAc)]2 as Catalyst Precursor: Identification of a Bis-RhI Mono-CuII Complex As the Catalyst

W. Goddard, C. Musgrave, D. Dickie, 2021 .

Synthesis, Spectroscopy, and Solid-State Structural Characterization of the Hexanuclear Copper Macrocycle [Cu6Cl6(μ-PCHP)6]†

T. Gunnoe, N. R. Brooks, Elizabeth D. Blue, 2002 .

Combined Experimental and Computational Studies on the Nature of Aromatic C-H Activation by Octahedral Ruthenium(II) Complexes: Evidence for σ-Bond Metathesis from Hammett Studies

T. Cundari, N. DeYonker, T. Gunnoe, 2007 .

Hyperdistorted Tungsten Allyl Complexes and Their Stereoselective Deprotonation to Form Dihapto-Coordinated Dienes

T. Gunnoe, M. Sabat, W. Harman, 2011 .

Role of Axial Ligation in Gating the Reactivity of Dimethylplatinum(III) Diimine Radical Cations

D. Dickie, T. Gunnoe, J. Dempsey, 2021 .

Stereoselective Dihapto-Binding of Prochiral Aromatic Compounds by {TpRe(CO)(PMe3)}: Synthesis, Characterization, Stability, and Enantiofacial Discrimination (Tp = Hydrido(tris)pyrazolylborate)

T. Gunnoe, W. Harman, and Michal Sabat, 2000 .

Reactions of TpRe(CO)2(THF) with Aromatic Molecules (Tp = Hydridotris(pyrazolyl)borate)

T. Gunnoe, W. Harman, and Michal Sabat, 1998 .

Computational Study of Methane Activation by TpRe(CO)2 and CpRe(CO)2 with a Stereoelectronic Comparison of Cyclopentadienyl and Scorpionate Ligands

Thomas R. Klinckman, T. Cundari, T. Gunnoe, 2003 .

Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3): impact of ancillary ligand l on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene.

Marty Lail, T. Cundari, T. Gunnoe, 2007, Journal of the American Chemical Society.

Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond.

Marty Lail, T. Cundari, T. Gunnoe, 2005, Journal of the American Chemical Society.

Experimental and Computational Studies of Ruthenium(II)-Catalyzed Addition of Arene C-H Bonds to Olefins

Marty Lail, T. Cundari, T. Gunnoe, 2004 .

PtII and RhIII Hydrocarbyl Complexes Bearing Coordinated Oxygen Atom Delivery Reagents

T. Cundari, T. Gunnoe, M. Sabat, 2013 .

A Promising New Dearomatization Agent: Crystal Structure, Synthesis, and Exchange Reactions of the Versatile Complex TpRe(CO)(1-methylimidazole)(η2-benzene) (Tp = Hydridotris(pyrazolyl)borate)

T. Gunnoe, W. Harman, B. C. Brooks, 2001 .

Interfacial and intrafacial linkage isomerizations of rhenium complexes with aromatic molecules.

T. Gunnoe, W. Harman, L. Friedman, 2001, Journal of the American Chemical Society.

Stepwise oxidation of benzylamine coordinated to the [Tp'W(CO)(PhC2Me)]+ moiety

T. Gunnoe, P. White, J. L. Templeton, 1996 .

Electrophilic Tungsten(II) Methylene Carbene Complexes: Adduct Formation, Methylene Transfer, and Catalysis of Aziridine Formation from Imines and Ethyl Diazoacetate

T. Gunnoe, P. White, J. L. Templeton, 1997 .

Polymers for the stabilization and delivery of proteins topically and per os to the insect hemocoel through conjugation with aliphatic polyethylene glycol.

B. Bissinger, T. Gunnoe, R. Roe, 2014, Pesticide biochemistry and physiology.

DFT Mechanistic Study of Methane Mono-Esterification by Hypervalent Iodine Alkane Oxidation Process

W. Goddard, J. Groves, Robert J Nielsen, 2019, The Journal of Physical Chemistry C.

Reductive functionalization of a rhodium(III)-methyl bond by electronic modification of the supporting ligand.

J. Groves, T. Cundari, C. Hoff, 2014, Dalton transactions.

Metal-free amidation of ether sp3 C–H bonds with sulfonamides using PhI(OAc)2

R. Crabtree, T. Gunnoe, Jesús Campos, 2014 .

Electron-Deficient Ru(II) Complexes as Catalyst Precursors for Ethylene Hydrophenylation

D. Dickie, T. Gunnoe, W. Harman, 2022, Inorganics.

Oxidative Alkenylation of Arenes Using Supported Rh Materials: Evidence that Active Catalysts are Formed by Rh Leaching

Sen Zhang, T. Gunnoe, Yulu Zhang, 2020 .

Rhodium-Catalyzed Arene Alkenylation Using Only Dioxygen as the Oxidant

T. Gunnoe, Weihao Zhu, 2020 .

Synthesis of Stilbenes by Rhodium-Catalyzed Aerobic Alkenylation of Arenes via C-H Activation.

T. Gunnoe, Shunyan Gu, Xiaofan Jia, 2020, Journal of the American Chemical Society.

Rhodium-Catalyzed Alkenylation of Toluene Using 1-Pentene: Regioselectivity To Generate Precursors for Bicyclic Compounds

Junqi Chen, T. Gunnoe, Michael S. Webster-Gardiner, 2019, Organometallics.

Styrene Production from Benzene and Ethylene Catalyzed by Palladium(II): Enhancement of Selectivity toward Styrene via Temperature-dependent Vinyl Ester Consumption

Sen Zhang, Chang Liu, T. Gunnoe, 2019, Organometallics.

Oxidative Hydrophenylation of Ethylene Using a Cationic Ru(II) Catalyst: Styrene Production with Ethylene as the Oxidant

T. Cundari, T. Gunnoe, J. B. Gary, 2017 .

Catalytic Synthesis of "Super" Linear Alkenyl Arenes Using an Easily Prepared Rh(I) Catalyst.

Junqi Chen, T. Gunnoe, Michael S. Webster-Gardiner, 2017, Journal of the American Chemical Society.

Mechanistic Studies of Single-Step Styrene Production Using a Rhodium(I) Catalyst.

T. Cundari, T. Gunnoe, Michael S. Webster-Gardiner, 2017, Journal of the American Chemical Society.

A Rhodium Catalyst for Single‐Step Styrene Production from Benzene and Ethylene.

T. Cundari, T. Gunnoe, Michael S. Webster-Gardiner, 2015 .

Catalytic Hydroarylation of Ethylene Using TpRu(L)(NCMe)Ph (L = 2,6,7-Trioxa-1-phosphabicyclo[2,2,1]heptane): Comparison to TpRu(L′)(NCMe)Ph Systems (L′ = CO, PMe3, P(pyr)3, or P(OCH2)3CEt)

T. Cundari, T. Gunnoe, M. Sabat, 2012 .

Aromatic C-H Activation and Catalytic Hydrophenylation of Ethylene by TpRu{P(OCH2)3CEt} (NCMe)Ph

T. Cundari, Zhuofeng Ke, T. Gunnoe, 2008 .

Combined Experimental and Computational Study of TpRu{P(pyr)3}(NCMe)Me (pyr = N-pyrrolyl): Inter- and Intramolecular Activation of C−H Bonds and the Impact of Sterics on Catalytic Hydroarylation of Olefins

Marty Lail, T. Cundari, T. Gunnoe, 2007 .

Mechanism of Hydrocarbon Functionalization by an Iodate/Chloride System: The Role of Ester Protection

W. Goddard, J. Goldberg, J. Groves, 2018 .

Organometallic Complexes Anchored to Conductive Carbon for Electrocatalytic Oxidation of Methane at Low Temperature.

A. Herring, C. Ngo, S. Pylypenko, 2016, Journal of the American Chemical Society.

Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nanorod surface

W. Goddard, Yi-sheng Liu, Jinghua Guo, 2020, Nature Catalysis.

Synthesis and Reactivity of the Octahedral d6 Parent Amido Complexes TpRu(L)(L‘)(NH2) (Tp = Hydridotris(pyrazolyl)borate; L = L‘ = PMe3, P(OMe)3; L = CO, L‘ = PPh3) and [TpRu(PPh3)(NH2)2][Li]

K. Jayaprakash, T. Gunnoe, and David M. Conner, 2001 .

Preparation of the octahedral d(6) amido complex TpRu(CO)(PPh(3))(NHPh) (Tp = Hydridotris(pyrazolyl)borate): solid-state structural characterization and reactivity.

K. Jayaprakash, T. Gunnoe, P. Boyle, 2001, Inorganic chemistry.

Partial Oxidation of Methane Enabled by Decatungstate Photocatalysis Coupled to Free Radical Chemistry

W. Goddard, J. Groves, C. Musgrave, 2023, ACS Catalysis.

INVISIBLE PROTEINS: NOVEL DELIVERY SYSTEM FOR THE STABILIZATION AND ENHANCED ACTIVITY OF PROTEIN INSECTICIDES

H. Shen, B. Bissinger, T. Gunnoe, 2009 .

Ligand Lone-Pair Influence on Hydrocarbon C-H Activation. A Computational Perspective

W. Goddard, T. Cundari, R. Periana, 2010 .

Hydrogen-deuterium exchange between TpRu(PMe3)(L)X (L = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: evidence for metal-mediated processes.

Marty Lail, T. Cundari, T. Gunnoe, 2006, Journal of the American Chemical Society.

Reaction Mechanism Underlying Pd(II)-Catalyzed Oxidative Coupling of Ethylene and Benzene to Form Styrene: Identification of a Cyclic Mono-PdII Bis-CuII Complex as the Active Catalyst

W. Goddard, C. Musgrave, D. Dickie, 2022, Organometallics.

The Changing Landscape of Hydrocarbon Feedstocks for Chemical Production: Implications for Catalysis: Proceedings of a Workshop

J. Alper, M. Flytzani-Stephanopoulos, A. Bell, 2016 .

A Meeting of Metals—A Joint Virtual Issue between Organometallics and ACS Catalysis on First-Row Transition Metal Complexes

P. Chirik, T. Gunnoe, 2015 .

Rhodium-Catalyzed Alkenylation of Arenes with Multi-Substituted Olefins: Comparison of Selectivity and Reaction Rate as a Function of Olefin Identity

W. Goddard, C. Musgrave, T. Gunnoe, 2023, Organometallics.

Alkylation of Arenes Without Chelation Assistance: Transition Metal Catalysts with d6 Electron Configurations

T. Cundari, T. Gunnoe, Bradley A. McKeown, 2017 .

Dihapto Coordination of Aromatic Molecules by the Asymmetric π-Bases {TpRe(CO)(L)} (Tp = hydridotris(pyrazolyl)borate; L = tBuNC, PMe3, pyridine, 1-methylimidazole, or NH3)

T. Gunnoe, W. Harman, B. C. Brooks, 2001 .

Rhenium(I) Terpyridine π-Bases: Reversible η2-Coordination of Ketones, Aldehydes, and Olefins in the Terpyridine Plane

T. Gunnoe, W. Harman, L. E. Helberg, 1999 .

Synthesis of the Five-Coordinate Ruthenium (II) Complexes [(PCP)Ru(CO)(L)][BAr'4] {PCP = 2,6-(CH2PtBu2)2 C6H3, BAr'4 = 3,5-(CF3)2C6H3, L= ɳ1-CICH2CI, ɳ 1-N2, or μ-Cl-Ru(PCP)(CO)}: Reactions with Phenyldiazomethane and Phenylacetylene

C. Day, T. Cundari, T. Gunnoe, 2005 .

Activation of sp3 carbon-hydrogen bonds by a ruthenium(II) complex and subsequent metal-mediated C-C and C-N bond formation.

T. Cundari, T. Gunnoe, P. Boyle, 2008, Angewandte Chemie.

Ruthenium(II)-Mediated Carbon-Carbon Bond Formation between Acetonitrile and Pyrrole: Combined Experimental and Computational Study

T. Cundari, T. Gunnoe, J. L. Petersen, 2005 .

Pd(II) and Rh(I) Catalytic Precursors for Arene Alkenylation: Comparative Evaluation of Reactivity and Mechanism Based on Experimental and Computational Studies.

W. Goddard, C. Musgrave, T. Gunnoe, 2023, Journal of the American Chemical Society.

Ru(II) Catalysts Supported by Hydridotris(pyrazolyl)borate for the Hydroarylation of Olefins: Reaction Scope, Mechanistic Studies, and Guides for the Development of Improved Catalysts

T. Cundari, Zhuofeng Ke, T. Gunnoe, 2009 .

Developments in Catalytic Aromatic C—H Transformations — Promising Tools for Organic Synthesis

T. Gunnoe, L. A. Goj, 2005 .

Conversions of Ruthenium(III) Alkyl Complexes to Ruthenium(II) through Ru-Calkyl Bond Homolysis

T. Cundari, T. Gunnoe, K. Barakat, 2005 .

Radical Polymerization of Styrene and Methyl Methacrylate with Ruthenium(II) Complexes

T. Gunnoe, P. Boyle, B. N. Arrowood, 2003 .

Synthesis of the RuIV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf]2 (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d4 imido complex: computational study of RuIV-imido bonding.

K. Jayaprakash, T. Gunnoe, David P. White, 2002, Chemical Communications.

Long-range C-H bond activation by Rh(III)-carboxylates.

T. Gunnoe, Ross Fu, M. Sabat, 2014, Journal of the American Chemical Society.

Activation of carbon-hydrogen bonds and dihydrogen by 1,2-CH-addition across metal-heteroatom bonds.

T. Cundari, T. Gunnoe, Joanna R. Webb, 2013, Dalton transactions.

Addition of S-H bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes.

Samuel A. Delp, T. Gunnoe, P. Boyle, 2007, Inorganic chemistry.