P. J. Toscano

发表

ON the interconfigurational 4fn↔4fn-15d1 optical transitions of Ce3+ and Pr3+ in Ca9R3+ (PO4)7 [R3+=Al, Ga, Sc, Lu, Y, Gd, La]

S. Camardello, P. J. Toscano, A. Srivastava, 2016 .

Optical spectroscopy, thermal quenching and electron–vibrational interaction of the octahedrally coordinated Eu2+ ion in CaAl2B2O7 and BaAl2B2O7

M. Brik, S. Camardello, P. J. Toscano, 2014 .

The structure of a B12 coenzyme: methylcobalamin studies by x-ray and NMR methods

M. Summers, J. Glusker, L. Marzilli, 1985 .

An extensive trans-effect series: the reaction of coordinated trimethyl phosphite

L. Marzilli, P. J. Toscano, 1979 .

An unusually long cobalt-carbon bond. Molecular structure of trans-bis(dimethylglyoximato)(isopropyl)(pyridine)cobalt(III). Implications with regard to the conformational trigger mechanism of cobalt-carbon bond cleavage in coenzyme B12

L. Marzilli, P. J. Toscano, L. Randaccio, 1979 .

Structural and spectroscopic evidence that cobalt to carbon bond lengths are influenced by conformational effects in cobaloximes. The longest cobalt-carbon bond in a vitamin B12 model: trans-bis(dimethylglyoximato)(isopropyl)(triphenylphosphine)cobalt(III)

L. Marzilli, P. J. Toscano, L. Randaccio, 1980 .

Angular distortions at the carbon bound to cobalt in coenzyme B12 models. Implications with regard to cobalt-carbon bond cleavage in coenzyme B12 and other alkylcobalamins

L. Marzilli, P. J. Toscano, L. Randaccio, 1981 .

A very long cobalt to nitrogen bond in a coenzyme B12 model. Relevance to the role of the 5,6-dimethylbenzimidazole in cobalt-carbon bond cleavage in coenzyme B12

M. Summers, L. Marzilli, P. J. Toscano, 1983 .

The 2,2,2-trifluoroethyl ligand: a structural "reporter" group for its carbanion character in organometallic compounds

M. Summers, L. Marzilli, D. Liotta, 1985 .

Organocobalt B12 models: axial ligand effects on the structural and coordination chemistry of cobaloximes

M. Summers, L. Marzilli, P. J. Toscano, 1985 .

Correlation of rate, spectroscopic, and structural data for (pyridine)- or (triphenylphosphine)bis(dimethylglyoximato)organocobalt complexes

M. Summers, L. Marzilli, P. J. Toscano, 1985 .

Cobalt-carbon bond disruption enthalpies: the first reliable measurement of a Co-methyl BDE via solution thermochemical methods

P. J. Toscano, A. Seligson, Matthew T. Curran, 1989 .

Reactions of Other Addenda

P. J. Toscano, P. Toscano, 2007 .

Synthesis and characterization of titanium complexes containing the 1-(3-butenyl)-2,3,4,5-tetramethylcyclopentadienyl ligand

J. Okuda, P. J. Toscano, K. E. D. Plooy, 1995 .

A novel approach to the preparation of pentacarbonyl(dialkylaminofluorocarbene)chromium compounds. Confirmation of structure by single crystal X-ray diffraction

P. J. Toscano, J. Welch, E. Keskeny, 1993 .

Allium chemistry: synthesis, natural occurrence, biological activity, and chemistry of Se-alk(en)ylselenocysteines and their gamma-glutamyl derivatives and oxidation products.

H. Thompson, W. Jiang, M. Birringer, 2001, Journal of Agricultural and Food Chemistry.

Electrically conductive metallomacrocyclic assemblies. High-resolution solid-state NMR spectroscopy as a probe of local architecture and electronic structure in phthalocyanine molecular and macromolecular "metals".

T. Marks, P. J. Toscano, 1986, Journal of the American Chemical Society.

Low Temperature Metal Organic Chemical Vapor Deposition (LTMOCVD) of Electronic Materials

A. Kaloyeros, R. Rizk, P. J. Toscano, 1989 .

Solid-State 19F NMR Investigation of Hexafluorobenzene Sorption to Soil Organic Matter

W. Hou, P. J. Toscano, J. A. Rice, 2000 .

The effect of sulfur on CVD performance of Pd(II) β-diketonate precursors and the completion of a structural trans-influence series: synthesis and structural characterization of Pd(S,S-tmhd)2

P. J. Toscano, J. Welch, K. Bousman, 2004 .

Investigations into the preparation of sila-β-diketones via 2-trimethylsilyl-1,3-dithianes: structural characterization of a second polymorph of bis(2,2,6,6-tetramethyl-2-sila-3,5-heptanedionato)copper(II)

S. Higashiya, K. Banger, P. J. Toscano, 2004 .

Structural investigations of copper(II) complexes containing unsymmetrical β-diketonate and monothio-β-diketonate ligands

P. J. Toscano, J. Welch, M. Delarosa, 2003 .

Facile synthesis of a novel class of organometalloid-containing ligands, the sila-β-diketones: preparation and physical and structural characterization of the copper(II) complexes, Cu[R′C(O)CHC(O)SiR3]2

S. Higashiya, K. Banger, P. J. Toscano, 2003 .

Thermal and structural characterization of a series of homoleptic Cu(II) dialkyldithiocarbamate complexes: bigger is only marginally better for potential MOCVD performance

K. Banger, P. J. Toscano, J. Welch, 2003 .

The 2,2,6,6-Tetramethyl-2-Sila-3,5-Heptanedione Route to the Chemical Vapor Deposition of Copper for Gigascale Interconnect Applications

E. Eisenbraun, A. Kaloyeros, K. Banger, 2000 .

SYNTHESIS AND CHARACTERIZATION OF POLYFLUORINATED β-DIKETONATE TRANSITION METAL COMPLEXES1,2

E. Eisenbraun, A. Kaloyeros, P. J. Toscano, 1996 .

Inhibition of dipeptidyl peptidase IV by fluoroolefin-containing N-peptidyl-O-hydroxylamine peptidomimetics.

P. J. Toscano, J. Welch, J. Lin, 1998, Proceedings of the National Academy of Sciences of the United States of America.

The synthesis of 2,3-dideoxy-2-fluoro-3-C-methylpentose-containing nucleosides via [3,3]-sigmatropic rearrangements.

P. J. Toscano, J. Welch, K. Araki, 1993, Carbohydrate research.

Stereocontrolled Synthesis of Methyl αR,2S,3R-3-(l-Acetoxyethyl)-1- (4-methoxyphenyl)-4-oxoazetidine-2-carboxylate

P. J. Toscano, J. Welch, J. Nyitrai, 1995 .

Supported organoactinides. Surface chemistry and catalytic properties of alumina-bound (cyclopentadienyl)-and (pentamethylcyclopentadienyl)thorium and -uranium hydrocarbyls and hydrides

T. Marks, Guoxing Xiong, P. J. Toscano, 1985 .

Improved synthesis and isolation of a flexible linear NSNN tetradentate ligand and the crystal structure of its stereospecific dinitrocobalt(III) complex

P. J. Toscano, A. White, L. M. Engelhardt, 1990 .

Dioxygen-copper reactivity and functional modeling of hemocyanins. Reversible binding of O2 and CO to dicopper(I) complexes [CuI2(L)]2+ (L = dinucleating ligand) and the structure of a bis(carbonyl) adduct, [CuI2(L)(CO)2]2+

K. Karlin, J. Zubieta, A. Farooq, 1992 .

Cobalt(III) complexes of stereospecific linear NSNN tetradentate ligands. Synthesis and characterization of ternary amino acid complexes containing tetradentate ligands with terminal amine donors

J. Zubieta, P. J. Toscano, T. Nicholson, 1993 .

SYNTHESIS, CHARACTERIZATION, AND REACTIONS OF MONOMERIC TITANIUM COMPLEXES CONTAINING A CHELATING BIS(PHENOLATE) LIGAND [1, 2]

E. Schermerhorn, J. Zubieta, P. J. Toscano, 1998 .

[(CH3)5C5]2Th(CH3)2/silica surface chemistry: high-resolution 13C CPMAS NMR evidence for alkylation of surface silicon sites

T. Marks, P. J. Toscano, 1986 .

Supported Organoactinides. High-Resolution Solid-State 13C NMR Studies of Catalytically Active, Alumina-Bound (Pentamethylcyclopentadienyl)thorium Methyl and Hydride Complexes

T. Marks, P. J. Toscano, P. Toscano, 1985 .

Structural investigations of copper(II) complexes containing fluorine-substituted β-diketonate ligands

S. Higashiya, K. Banger, P. J. Toscano, 2003 .

Coordination of ethynylpyridine ligands with copper(I): x-ray structure of a novel triple-helical, tricuprous complex

C. P. Horwitz, P. J. Toscano, K. T. Potts, 1993 .

L. Marzilli, P. J. Toscano, P. Toscano, 2007 .

A convenient preparation and the molecular structure of trans-bis(dimethylglyoximato)(trifluoromethyl)(pyridine)cobalt(III): a cobaloxime with a very short CoC(sp3) bond

J. Zubieta, P. J. Toscano, L. Konieczny, 1989 .

Phosphorus-31 NMR spectra of cobaloximes: Influence of electronic and steric effects of axial ligands

L. Marzilli, P. J. Toscano, R. W. Crecely, 1980 .

Novel square pyramidal copper(II) complexes of the stereospecific linear NSNN tetradentate ligand, N-[(2-pyridyl)methyl]-2-[(2-aminoethyl)thio]acetamide (pygeH). The crystal structures of [Cu(pyge)X] (X = Br, N3)

J. Zubieta, P. J. Toscano, Shun-Shun Liu, 1990 .

Solid State and Solution Characterization of Chiral, Conformationally Mobile Tripodal Ligands

P. J. Toscano, J. Canary, Y. Chiu, 1998 .

The synthesis and crystal structure of [Cr(acacen)py2] [ZnCl3py]

E. Zangrando, P. J. Toscano, S. Geremia, 1994 .

Synthesis, characterization, and reactivity of novel organochromium(III) porphyrin complexes

P. J. Toscano, P. T. Dimauro, H. Brand, 1993 .

Synthesis, characterization and stereochemical preferences of cobalt(II) ternary amino acid complexes containing N-((2-pyridyl)methyl)- 2((2-aminoethyl)thio)acetamide, a stereospecific linear NSNN tetradentate ligand

J. Zubieta, P. J. Toscano, T. Hsieh, 1991 .

The first metal complex containing a silylated β-diketonate ligand: bis(2,2,6,6-tetramethyl-2-sila-3,5-heptanedionato) copper(II)

E. Eisenbraun, A. Kaloyeros, K. Banger, 2001 .

Preparation and Characterization of Half-Sandwich (Pentamethylcyclopentadienyl)(triflato)titanium(IV) Complexes: Solid-State Structural Motifs and Catalysis Studies

P. J. Toscano, J. Welch, Silvana C. Ngo, 2002 .

The Effect of Grain Boundaries and Substrate Interactions with Hydrogen on the CVD Growth of Device-Quality Copper.

E. Eisenbraun, A. Kaloyeros, W. Lanford, 1991 .

Cobaloximes Containing Phosphorus-Donor Ligands

L. Marzilli, P. J. Toscano, L. Randaccio, 1982 .

Synthesis of fluorinated α-sila-β-diketones and their copper(II) complexes

S. Higashiya, K. Banger, P. J. Toscano, 2003 .

Organocobalt B12 Models. Structures of trans-bis(glyoximato)(alkyl)(pyridine)cobalt(III), with Alkyl = Me, Et, i-Pr

E. Zangrando, P. J. Toscano, L. Randaccio, 1985 .

AN EXTENSIVE TRANS-EFFECT SERIES: THE REACTION OF COORDINATED TRIMETHYL PHOSPHITE

L. Marzilli, P. J. Toscano, 1979 .

Organocobalt B12 models. An assessment of the cis effect using bis(glyoximato) as a sterically minimal equatorial atom set. Structures of trans-bis(glyoximato)methyl(L)cobalt(III) with L = triphenylphosphine and trimethyl phosphite

L. Marzilli, P. J. Toscano, L. Randaccio, 1983 .

On the correlation between bond lengths, chemical shifts, and cone angles in octahedral cobaloximes containing P-donor ligands. Crystal structure of trans-chlorobis(dimethylglyoximato)(phosphite)cobalt(III) complexes with phosphite = P(OMe)2Ph and P(OMe)Ph2

P. J. Toscano, L. Randaccio, N. Bresciani-Pahor, 1982 .

Synthesis and solution and solid-state studies of cobaloxime complexes containing alkylated 6-aminopurine ligands. Molecular and crystal structure of the complex with N(7)-bound 3-benzyladenine and dimethyl phosphonate as the axial ligands

T. Kistenmacher, L. Marzilli, P. J. Toscano, 1981 .

Monomeric four-coordinate vanadium(V) oxo complexes containing a labile ligand: synthesis and X-ray structural characterization of [(C23H30O2)V(O)Cl]

E. Schermerhorn, J. Zubieta, P. J. Toscano, 1991 .

Reactions of Halogen Compounds of the Group IVB Elements

P. J. Toscano, P. Toscano, 2007 .

Perthio- and perseleno-1,3-butadienes, -but-1-ene-3-ynes, and -[3]-cumulenes: one-step syntheses from 1,4-dilithio-1,3-butadiyne.

P. J. Toscano, E. Block, M. Thiruvazhi, 2003, Organic letters.

Synthesis of mono- and difluoroacetyltrialkylsilanes and the corresponding enol silyl ethers.

W. H. Kelly, S. Higashiya, W. Chung, 2004, The Journal of organic chemistry.

Synthesis and characterization of diphenylglyoximato cobalt(III) complexes. The molecular structures of trans-bis(diphenylglyoximato)(alkyl)(pyridine)cobalt(III), with alkyl=CH2SiMe3, CH2CMe3 and CF3

E. Schermerhorn, J. Zubieta, P. J. Toscano, 2003 .

Synthesis and physical and structural characterization of Ag(I) complexes supported by non-fluorinated β-diketonate and related ancillary ligands

K. Banger, P. J. Toscano, J. Welch, 2002 .

Reactions at a Group VA Metal Center

P. J. Toscano, 2007 .

Allium Chemistry: Structure, Synthesis, Natural Occurrence in Onion (Allium cepa), and Reactions of 2,3-Dimethyl-5,6-dithiabicyclo[2.1.1]hexane S-Oxides

P. J. Toscano, T. Bayer, E. Block, 1996 .

Total Synthesis of Thiarubrine B [3-(3-Buten-1-ynyl)-6-(1,3-pentadiynyl)-1,2-dithiin], the Antibiotic Principle of Giant Ragweed (Ambrosia trifida)

P. J. Toscano, E. Block, M. Thiruvazhi, 1994 .

Reactions of Other Halogen‐Containing Compounds

P. J. Toscano, 2007 .

Physical and Structural Characterization of Ce(IV) β-Diketonate Complexes: Evidence for Geometrical Isomers in the Solid-State

P. J. Toscano, J. Welch, M. Delarosa, 2002 .

Protonation sites in a heteropolyvanadate of phosphorus: X-ray crystal structure of (Me3NH)4(NH4)[H4PV14O42]

J. Zubieta, P. J. Toscano, M. I. Khan, 1992 .

Optical spectroscopy, thermal quenching and electron–vibrational interaction of the octahedrally coordinated Eu2+ ion in SrAl2B2O7

M. Brik, S. Camardello, P. J. Toscano, 2014 .

The synthesis and isolation of the stereospecific ligand, N-(2-aminoethyl)-2-[(2-aminoethyl)thio]acetamide (egeH). Comparison of the crystal structure of [Co(ege)(NO2)2] ·4H2O with related systems

P. J. Toscano, B. Skelton, A. White, 1990 .

COBALT(III) COMPLEXES OF STEREOSPECIFIC LINEAR NSNN TETRADENTATE LIGANDS. 1. SYNTHESIS OF LIGANDS THAT ADOPT THE CIS-β COORDINATION GEOMETRY

L. Marzilli, P. J. Toscano, 1984 .

Cobalt complexes with bulky perfluorinated alkyl ligands. Synthesis, characterization, and molecular structure of trans-bis(dimethylglyoximato)(pyridine)(F-isopropyl)cobalt(III)

J. Zubieta, P. J. Toscano, Shun-Shun Liu, 1990 .

Structural aspects of a vitamin B12 model. Crystal and molecular structure of trans-cyanobis(dimethylglyoximato)(trimethyl phosphite)-cobalt(III)

P. J. Toscano, L. Randaccio, M. Calligaris, 1982 .