T. Tsuchiya

发表

Reduction of Endohedral Metallofullerenes: A Convenient Method for Isolation

S. Nagase, K. Kadish, T. Tsuchiya, 2004 .

Host-guest complexation of endohedral metallofullerene with azacrown ether and its application.

K. Ohkubo, S. Fukuzumi, S. Nagase, 2006, Journal of the American Chemical Society.

Selective extraction and purification of endohedral metallofullerene from carbon soot.

Y. Lian, S. Nagase, T. Tsuchiya, 2006, The journal of physical chemistry. B.

Yb@C2n (n = 40, 41, 42): new fullerene allotropes with unexplored electrochemical properties.

Xing Lu, S. Nagase, Z. Slanina, 2010, Journal of the American Chemical Society.

Where does the metal cation stay in Gd@C2v(9)-C82? A single-crystal X-ray diffraction study.

Xing Lu, S. Nagase, Z. Slanina, 2012, Inorganic chemistry.

X-ray structures of Sc2C2@C2n (n = 40-42): in-depth understanding of the core-shell interplay in carbide cluster metallofullerenes.

Xing Lu, S. Nagase, Z. Slanina, 2012, Inorganic chemistry.

Dichlorophenyl derivatives of La@C(3v)(7)-C(82): endohedral metal induced localization of pyramidalization and spin on a triple-hexagon junction.

Xing Lu, S. Nagase, Z. Slanina, 2010, Angewandte Chemie.

Structure determination of a missing-caged metallofullerene: Yb@C74 (II) and the dynamic motion of the encaged ytterbium ion

Z. Gu, Zujin Shi, C. Hao, 2006 .

Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C82 and its carbene derivative.

Takeshi Akasaka, Takahiro Tsuchiya, Takatsugu Wakahara, 2007, Angewandte Chemie.

Synthesis of silylene-bridged endohedral metallofullerene Lu3N@I(h)-C80.

S. Nagase, A. Balch, M. Olmstead, 2012, Journal of the American Chemical Society.

Chemical reactivity of sc3n @ c80 and la2 @ c80.

S. Nagase, T. Tsuchiya, T. Wakahara, 2005, Journal of the American Chemical Society.

13C NMR spectroscopic study of scandium dimetallofullerene, Sc2@C84 vs. Sc2C2@C82.

S. Nagase, T. Tsuchiya, T. Wakahara, 2006, Chemical communications.

Unexpected formation of a Sc3C2@C80 bisfulleroid derivative.

Y. Rubin, S. Nagase, Z. Slanina, 2012, Journal of the American Chemical Society.

In-depth understanding of π-electron systems: New vistas in fullerene endohedrals

S. Nagase, T. Tsuchiya, T. Akasaka, 2010 .

Exceptional chemical properties of Sc@C(2v)(9)-C82 probed with adamantylidene carbene.

Xing Lu, T. Tsuchiya, T. Akasaka, 2012, Journal of the American Chemical Society.

Bis-silylation of Lu3N@I(h)-C80: considerable variation in the electronic structures.

S. Nagase, T. Tsuchiya, T. Akasaka, 2012, Organic letters.

Enantioselective synthesis of endohedral metallofullerenes.

S. Nagase, N. Martín, Z. Slanina, 2011, Journal of the American Chemical Society.

Regioselective bis-functionalization of endohedral dimetallofullerene, La2@C80: extremal La-La distance.

S. Nagase, Z. Slanina, T. Tsuchiya, 2011, Journal of the American Chemical Society.

Synthesis and charge-transfer chemistry of La2@I(h)-C80/Sc3N@I(h)-C80-zinc porphyrin conjugates: impact of endohedral cluster.

D. Guldi, S. Nagase, N. Martín, 2011, Journal of the American Chemical Society.

Thermal carbosilylation of endohedral dimetallofullerene La(2)@I(h)-C(80) with silirane.

S. Nagase, Z. Slanina, T. Tsuchiya, 2010, Journal of the American Chemical Society.

Two regioisomers of endohedral pyrrolidinodimetallofullerenes M2@I(h)-C80(CH2)2NTrt (M = La, Ce; Trt = trityl): control of metal atom positions by addition positions.

S. Nagase, T. Tsuchiya, T. Akasaka, 2009, Chemistry.

Missing metallofullerene with C80 cage.

S. Nagase, Z. Slanina, T. Tsuchiya, 2009, Journal of the American Chemical Society.

Structural characterization of Y@C82

Y. Lian, S. Nagase, K. Kadish, 2005 .

Endohedral metallofullerenes-filled fullerene derivatives towards multifunctional reaction center mimics.

D. Guldi, L. Echegoyen, T. Tsuchiya, 2012, Chemistry.

Electron donor-acceptor interactions in regioselectively synthesized exTTF(2)-C(70)(CF(3))(10) dyads.

S. Strauss, D. Guldi, M. Herranz, 2010, Chemistry.

Donor-acceptor conjugates of lanthanum endohedral metallofullerene and pi-extended tetrathiafulvalene.

D. Guldi, S. Nagase, M. Herranz, 2010, Journal of the American Chemical Society.

Location of the yttrium atom in Y@C82 and its influence on the reactivity of cage carbons.

Xing Lu, S. Nagase, Z. Slanina, 2009, Journal of the American Chemical Society.

S-heterocyclic carbene with a disilane backbone.

S. Nagase, G. Rahman, T. Tsuchiya, 2005, Angewandte Chemie.

Fundamental Investigations on Additive Manufacturing Method by Selective Solidification Using Electrical Discharge

K. Furutani, T. Tsuchiya, H. Yamagishi, 2019, Journal of The Japan Society of Electrical Machining Engineers.

Synthesis and Photoinduced Electron-Transfer Reactions in a La2 @Ih -C80 -Phenoxazine Conjugate.

D. Guldi, S. Nagase, Wei-wei Wang, 2017, ChemPlusChem.

Coordinative interactions between porphyrins and C60, La@C82, and La2@C80.

D. Guldi, S. Nagase, Azusa Oshima, 2013, Chemistry.

Current progress on the chemical functionalization and supramolecular chemistry of M@C82.

Xing Lu, S. Nagase, T. Tsuchiya, 2011, Nanoscale.

Synthesis of Endohedral Metallofullerene Glycoconjugates by Carbene Addition

T. Tsuchiya, Y. Maeda, T. Akasaka, 2011, Molecules.

The effect of atomic nitrogen on the C(60) cage.

S. Nagase, M. Ata, O. Ito, 2010, Chemical communications.

Highly regioselective synthesis of bis-aziridino[60]fullerene with sulfilimine.

S. Nagase, Z. Slanina, T. Tsuchiya, 2011, Chemistry, an Asian journal.

A co-crystal composed of the paramagnetic endohedral metallofullerene La@C82 and a nickel porphyrin with high electron mobility.

S. Nagase, Lu Wang, T. Tsuchiya, 2012, Angewandte Chemie.

Photo-labeling of C60 with 3-trifluoromethyl-3-phenyldiazirine

T. Tsuchiya, T. Wakahara, T. Akasaka, 2007 .

The Bingel monoadducts of La@C82: synthesis, characterization, and electrochemistry.

Y. Lian, S. Nagase, T. Tsuchiya, 2006, Chemistry.

Structural evolution of [2+1] cycloaddition derivatives of single-wall carbon nanotubes: From open structure to closed three-membered ring structure with increasing tube diameter

Zhengxiang Gao, S. Nagase, H. Ye, 2005 .

Nitrated benzyne derivatives of La@C(82): addition of NO(2) and its positional directing effect on the subsequent addition of benzynes.

Xing Lu, S. Nagase, H. Sawa, 2010, Angewandte Chemie.

2D NMR characterization of the La@C82 anion.

S. Nagase, T. Tsuchiya, T. Wakahara, 2005, Angewandte Chemie.

Synthesis and structure-activity relationships of tetrazolato-bridged dinuclear platinum(II) complexes: A small modification at tetrazole C5 markedly influences the in vivo antitumor efficacy.

K. Hiramoto, T. Tsuchiya, S. Harusawa, 2019, Journal of inorganic biochemistry.

Unsaturated thiacrown ethers: synthesis, physical properties, and formation of a silver complex.

T. Tsuchiya, T. Shimizu, N. Kamigata, 2001, Journal of the American Chemical Society.

Synthesis and structures of 15- and 18-membered unsaturated selenacrown ethers and their complexation with silver trifluoroacetate.

Toshio Shimizu, T. Tsuchiya, M. Kawaguchi, 2003, Organic letters.

Preparation, Characterization, and Electrochemical Properties of Selenylfullerenes

S. Nagase, T. Tsuchiya, Y. Maeda, 2009 .

Synthesis of selenylfullerene with selenium-containing dibenzo[b,g]cyclooctane moiety

S. Nagase, T. Tsuchiya, Y. Maeda, 2008 .

Paddlewheel Complexes with Azulenes: Electronic Interaction between Metal Centers and Equatorial Ligands.

K. Ohkubo, S. Noro, T. Tsuchiya, 2019, ChemPlusChem.

Stereochemistry, Stereodynamics, and Redox and Complexation Behaviors of 2,2'-Diaryl-1,1'-Biazulenes.

T. Tsuchiya, Hiroyasu Sato, K. Yoza, 2019, ChemPlusChem.

[2+1] Cycloaddition of nitrene onto C60 revisited: interconversion between an aziridinofullerene and an azafulleroid.

S. Nagase, Xingfa Gao, H. Morita, 2008, Angewandte Chemie.

Photochemical addition of C60 with siliranes: synthesis and characterization of carbosilylated and hydrosilylated C60 derivatives.

S. Nagase, Xingfa Gao, T. Tsuchiya, 2010, Journal of the American Chemical Society.

Unsaturated selenacrown ethers: synthesis, structure, and formation of silver complexes.

Toshio Shimizu, T. Tsuchiya, M. Kawaguchi, 2005, The Journal of organic chemistry.

A self-regulatory host in an oscillatory guest motion: complexation of fullerenes with a short-spaced cyclic dimer of an organorhodium porphyrin.

T. Aida, T. Tsuchiya, T. Akasaka, 2006, Angewandte Chemie.

Molecular transformations of unsaturated thiacrown ethers.

Toshio Shimizu, T. Tsuchiya, K. Hirabayashi, 2008, The Journal of organic chemistry.

Formation and structures of mercury complexes of 18-membered unsaturated and saturated thiacrown ethers.

Toshio Shimizu, T. Tsuchiya, K. Hirabayashi, 2003, The Journal of organic chemistry.

Silver complexes with unsaturated thiacrown ethers: inclusion behavior of conformationally restricted macrocycles.

Toshio Shimizu, T. Tsuchiya, K. Hirabayashi, 2002, The Journal of organic chemistry.

Construction of Supramolecular Systems Based on Endohedral Metallofullerenes

S. Nagase, T. Tsuchiya, T. Akasaka, 2009 .

Supramolecular complexes of La@C82 with unsaturated thiacrown ethers.

S. Nagase, Toshio Shimizu, T. Tsuchiya, 2006, Chemical communications.

Photodeoxygenation and α-Cleavage Reactions of Selenoxides

T. Tsuchiya, T. Hasegawa, Y. Yamazaki, 2003 .

Synthesis and characterization of a bisadduct of La@C82.

S. Nagase, T. Tsuchiya, T. Wakahara, 2006, Journal of the American Chemical Society.

Structural determination of metallofullerene Sc3C82 revisited: a surprising finding.

Takeshi Akasaka, Takahiro Tsuchiya, Takatsugu Wakahara, 2005, Journal of the American Chemical Society.

Analysis of lanthanide-induced NMR shifts of the Ce@C82 anion.

Y. Lian, S. Nagase, K. Kadish, 2006, Journal of the American Chemical Society.

X-ray induced luminescence spectroscopy for DNA damaging intermediates aided by a monochromatic synchrotron radiation

Issei Suzuki, T. Tsuchiya, K. Fujii, 2021, International journal of radiation biology.

A molecular Ce2@I(h)-C80 switch--unprecedented oxidative pathway in photoinduced charge transfer reactivity.

Takeshi Akasaka, Takahiro Tsuchiya, Lai Feng, 2010, Journal of the American Chemical Society.

Synthesis and characterization of the D5h isomer of the endohedral dimetallofullerene Ce2@C80: two-dimensional circulation of encapsulated metal atoms inside a fullerene cage.

Takeshi Akasaka, Takahiro Tsuchiya, Michio Yamada, 2009, Chemistry.

Location of the metal atoms in Ce2@C78 and its bis-silylated derivative.

Takeshi Akasaka, Takahiro Tsuchiya, Takatsugu Wakahara, 2008, Chemical communications.

Centrifugal purification of chemically modified single-walled carbon nanotubes

Y. Lian, T. Tsuchiya, T. Wakahara, 2005 .

Sm@C74: Computed Relative Isomeric Populations

L. Adamowicz, Shyi-Long Lee, S. Nagase, 2014 .

Selective interaction of large or charge-transfer aromatic molecules with metallic single-wall carbon nanotubes: critical role of the molecular size and orientation.

Zhengxiang Gao, S. Nagase, W. Mei, 2006, Journal of the American Chemical Society.

Large-scale separation of metallic and semiconducting single-walled carbon nanotubes.

Makoto Kanda, Jing Lu, Nobutsugu Minami, 2005, Journal of the American Chemical Society.

Nanorods of endohedral metallofullerene derivative.

S. Iijima, K. Suenaga, S. Nagase, 2008, Journal of the American Chemical Society.

The long-believed Sc2@C(2v)(17)-C84 is actually Sc2C2@C(2v)(9)-C82: unambiguous structure assignment and chemical functionalization.

Xing Lu, S. Nagase, Z. Slanina, 2012, Angewandte Chemie.

Chemical understanding of carbide cluster metallofullerenes: a case study on Sc2C2@C2v(5)-C80 with complete X-ray crystallographic characterizations.

Zdenek Slanina, Xing Lu, Takeshi Akasaka, 2012, Journal of the American Chemical Society.

Sc2@C3v(8)-C82 vs. Sc2C2@C3v(8)-C82: drastic effect of C2 capture on the redox properties of scandium metallofullerenes.

Xing Lu, S. Nagase, Z. Slanina, 2012, Chemical communications.

Structural elucidation and regioselective functionalization of an unexplored carbide cluster metallofullerene Sc2C2@C(s)(6)-C82.

Zdenek Slanina, Xing Lu, Takeshi Akasaka, 2011, Journal of the American Chemical Society.

Sc2C2@C80 rather than Sc2@C82: templated formation of unexpected C2v(5)-C80 and temperature-dependent dynamic motion of internal Sc2C2 cluster.

Zdenek Slanina, Xing Lu, Takeshi Akasaka, 2011, Journal of the American Chemical Society.

Regioselective exohedral functionalization of La@C82 and its 1,2,3,4,5-pentamethylcyclopentadiene and adamantylidene adducts.

S. Nagase, Z. Slanina, T. Tsuchiya, 2010, Chemistry.

A singly bonded derivative of endohedral metallofullerene: La@C82CBr(COOC2H5).

S. Nagase, T. Tsuchiya, T. Wakahara, 2005, Journal of the American Chemical Society.

Reversible and regioselective reaction of La@C82 with cyclopentadiene.

S. Nagase, H. Nakajima, T. Tsuchiya, 2005, Journal of the American Chemical Society.

Bis-carbene adducts of non-IPR La2@C72: localization of high reactivity around fused pentagons and electrochemical properties.

Xing Lu, S. Nagase, H. Sawa, 2008, Angewandte Chemie.

New vistas in fullerene endohedrals: Functionalization with compounds from main group elements

S. Nagase, T. Tsuchiya, T. Akasaka, 2010 .

Retro-reaction of singly bonded La@C82 derivatives.

S. Nagase, T. Tsuchiya, T. Akasaka, 2010, Chemical communications.

Synthesis and characterization of exohedrally silylated M@C82 (M = Y and La).

Y. Lian, S. Nagase, T. Tsuchiya, 2005, The journal of physical chemistry. B.

Isolation and characterization of a carbene derivative of La@C82.

S. Nagase, Kazunori Yamamoto, T. Tsuchiya, 2004, Journal of the American Chemical Society.

Chemical understanding of a non-IPR metallofullerene: stabilization of encaged metals on fused-pentagon bonds in La2@C72.

Zdenek Slanina, Xing Lu, Takeshi Akasaka, 2008, Journal of the American Chemical Society.

La@C72 having a non-IPR carbon cage.

S. Nagase, G. Rahman, Z. Slanina, 2006, Journal of the American Chemical Society.

Covalently linked porphyrin-La@C82 hybrids: structural elucidation and investigation of intramolecular interactions.

D. Guldi, S. Nagase, N. Martín, 2011, Angewandte Chemie.

Semi-metallic single-component crystal of soluble La@C82 derivative with high electron mobility.

S. Nagase, Lu Wang, T. Tsuchiya, 2011, Journal of the American Chemical Society.

Synthesis and structural characterization of endohedral pyrrolidinodimetallofullerene: La2@C80(CH2)2NTrt.

S. Nagase, T. Tsuchiya, T. Wakahara, 2006, Journal of the American Chemical Society.

Addition of adamantylidene to La2@C78: isolation and single-crystal X-ray structural determination of the monoadducts.

Zdenek Slanina, Takeshi Akasaka, Takahiro Tsuchiya, 2008, Journal of the American Chemical Society.

Missing metallofullerene La@C74.

S. Nagase, G. Rahman, Kazunori Yamamoto, 2005, Journal of the American Chemical Society.

Radical derivatives of insoluble La@C74: X-ray structures, metal positions, and isomerization.

Xing Lu, S. Nagase, Z. Slanina, 2011, Angewandte Chemie.

Anisotropic magnetic behavior of anionic Ce@C82 carbene adducts.

S. Nagase, Z. Slanina, T. Tsuchiya, 2009, Journal of the American Chemical Society.

Radical coupling reaction of paramagnetic endohedral metallofullerene La@C82.

S. Nagase, Z. Slanina, T. Tsuchiya, 2008, Journal of the American Chemical Society.

Does Gd@C82 have an anomalous endohedral structure? Synthesis and single crystal X-ray structure of the carbene adduct.

S. Nagase, Z. Slanina, Kazunori Yamamoto, 2008, Journal of the American Chemical Society.

Chemical reactivities of the cation and anion of M@C82 (M = Y, La, and Ce).

Y. Lian, S. Nagase, Kazunori Yamamoto, 2005, Journal of the American Chemical Society.

Regioselective cycloaddition of La2@I(h)-C80 with tetracyanoethylene oxide: formation of an endohedral dimetallofullerene adduct featuring enhanced electron-accepting character.

S. Nagase, Z. Slanina, T. Tsuchiya, 2011, Journal of the American Chemical Society.

Chemical Modification of Endohedral Metallofullerene La@C82 with 3-chloro-3-phenyldiazirine

S. Nagase, Z. Slanina, T. Tsuchiya, 2010 .

Isolation, characterization, and theoretical study of La2@C78.

Masahiro Kondo, Takeshi Akasaka, Takahiro Tsuchiya, 2004, Journal of the American Chemical Society.

Stable radical anions inside fullerene cages: formation of reversible electron transfer systems.

D. Guldi, S. Nagase, T. Tsuchiya, 2011, Journal of the American Chemical Society.

Chemical reactivity and redox property of Sc3@C82

S. Nagase, K. Kadish, T. Tsuchiya, 2004 .

Characterization of Ce@C82 and its anion.

S. Nagase, Kazunori Yamamoto, K. Kadish, 2004, Journal of the American Chemical Society.

Characterization of the bis-silylated endofullerene Sc3N@C80.

S. Nagase, T. Tsuchiya, T. Wakahara, 2006, Journal of the American Chemical Society.

Synthesis and Properties of Twisted and Helical Azulene Oligomers and Azulene-Based Polycyclic Hydrocarbons.

T. Tsuchiya, Y. Mazaki, Makoto Higashibeppu, 2023, ChemistryOpen.

Spectroscopic and theoretical study of endohedral dimetallofullerene having a non-IPR fullerene cage: Ce2@C72.

S. Nagase, T. Tsuchiya, T. Wakahara, 2008, The journal of physical chemistry. A.

Two-dimensional hopping motion of encapsulated La atoms in silylated La(2)@C(80).

S. Nagase, T. Tsuchiya, T. Wakahara, 2007, Chemical communications.

Tuning of electronic properties of single-walled carbon nanotubes under homogenous conditions.

H. Kataura, S. Nagase, S. Takeuchi, 2009, Chemphyschem : a European journal of chemical physics and physical chemistry.

Spin-site exchange system constructed from endohedral metallofullerenes and organic donors.

K. Ohkubo, S. Fukuzumi, S. Nagase, 2006, Journal of the American Chemical Society.

Positional control of encapsulated atoms inside a fullerene cage by exohedral addition.

S. Nagase, T. Tsuchiya, T. Wakahara, 2005, Journal of the American Chemical Society.

Isolation and characterization of carbene derivatives of La@C82(Cs).

S. Nagase, Z. Slanina, T. Tsuchiya, 2008, The journal of physical chemistry. A.

Metal atoms collinear with the spiro carbon of 6,6-open adducts, M2@C80(Ad) (M = La and Ce, Ad = adamantylidene).

S. Nagase, T. Tsuchiya, T. Wakahara, 2008, Journal of the American Chemical Society.

Organosulfur-Based Fullerene Materials

D. Guldi, S. Nagase, M. Herranz, 2011 .

Preparation of transparent and conductive thin films of metallic single-walled carbon nanotubes

S. Nagase, Tetsuo Shimizu, M. Kanda, 2008 .

C60(OH)n-ASSISTED DISPERSION OF SINGLE-WALLED CARBON NANOTUBES

S. Nagase, T. Okazaki, T. Tsuchiya, 2008 .

EXTRACTION OF METALLIC NANOTUBES OF ZEOLITE-SUPPORTED SINGLE-WALLED CARBON NANOTUBES SYNTHESIZED FROM ALCOHOL

S. Nagase, S. Maruyama, Y. Miyauchi, 2007 .

Simple purification and selective enrichment of metallic SWCNTs produced using the arc-discharge method

Y. Lian, S. Nagase, M. Kanda, 2008 .

Chemical understanding of a non-IPR metallofullerene: stabilization of encaged metals on fused-pentagon bonds in La2@C72.

Xing Lu, S. Nagase, H. Sawa, 2008, Journal of the American Chemical Society.

Addition of adamantylidene to La2@C78: isolation and single-crystal X-ray structural determination of the monoadducts.

S. Nagase, H. Sawa, Z. Slanina, 2008, Journal of the American Chemical Society.

Location of the yttrium atom in Y@C82 and its influence on the reactivity of cage carbons.

Xing Lu, S. Nagase, Z. Slanina, 2009, Journal of the American Chemical Society.

Synthesis and charge-transfer chemistry of La2@I(h)-C80/Sc3N@I(h)-C80-zinc porphyrin conjugates: impact of endohedral cluster.

D. Guldi, S. Nagase, N. Martín, 2011, Journal of the American Chemical Society.

Semi-metallic single-component crystal of soluble La@C82 derivative with high electron mobility.

S. Nagase, Lu Wang, T. Tsuchiya, 2011, Journal of the American Chemical Society.

Bis-carbene adducts of non-IPR La2@C72: localization of high reactivity around fused pentagons and electrochemical properties.

Xing Lu, S. Nagase, H. Sawa, 2008, Angewandte Chemie.

The effect of atomic nitrogen on the C(60) cage.

S. Nagase, M. Ata, O. Ito, 2010, Chemical communications.