E. Negishi

发表

Recent advances in efficient and selective synthesis of di-, tri-, and tetrasubstituted alkenes via Pd-catalyzed alkenylation-carbonyl olefination synergy.

H. Hattori, E. Negishi, Zhihong Huang, 2008, Accounts of chemical research.

2.19 – Vinyl- and Arylmetals

E. Negishi, Danièle Choueiry, 1995 .

Palladium-catalyzed or -promoted reductive carbon−carbon coupling. Effects of phosphines and carbon ligands

K. Akiyoshi, E. Negishi, Tamotsu Takahashi, 1987 .

Highly stereoselective and efficient synthesis of ω-heterofunctional di- and trienoic esters for Horner–Wadsworth–Emmons reaction via alkyne hydrozirconation and Pd-catalyzed alkenylation

E. Negishi, Zhihong Huang, Guangwei Wang, 2009 .

Strictly Regiocontrolled α-Monosubstitution of Cyclic Carbonyl Compounds with Alkynyl and Alkyl Groups via Pd-Catalyzed Coupling of Cyclic α-Iodoenones with Organozincs.

E. Negishi, Ze Tan, Show-Yee Liou, 2000 .

Metal promoted cyclization. 7. Zirconium-promoted bicyclization of enynes

J. Tour, E. Negishi, Joseph A. Miller, 1985 .

Le palladium, magique des chimistes

E. Negishi, R. Heck, Akira Suzuki, 2010 .

A selective procedure for α-alkenylation of enones involving Pd-catalyzed alkenyl-alkenyl coupling and its application to a convergent and efficient synthesis of nakienone B

E. Negishi, M. Pour, 1996 .

Highly stereoselective and general synthesis of (z)-3-methyl-2-alken-1-ols via palladium-catalyzed cross coupling of (z)-3-iodo-2-buten-1-ol with organozincs and other organometals

E. Negishi, M. Ay, Yu. V. Gulevich, 1993 .

Strictly regio-controlled method for α-alkenylation of cyclic ketones via palladium-catalyzed cross coupling

E. Negishi, Z. Owczarczyk, D. Swanson, 1991 .

Highly selective synthesis of vitamin A and its derivatives. Critical comparison of some known palladium-catalyzed alkenyl-alkenyl coupling reactions

E. Negishi, Z. Owczarczyk, 1991 .

Effects of organometals on the palladium-catalyzed tandem carbopalladation-cross coupling for preparing stereodefined exocyclic alkenes

F. Lamaty, E. Negishi, Yumiki Noda, 1990 .

Controlled carbometalation as a new tool for carbon-carbon bond formation and its application to cyclization

E. Negishi, 1987 .

Zirconium-promoted Bicyclization of Enynes

E. Negishi, 1985 .

Selective carbon-carbon bond formation via transition metal catalysis. 4. A novel approach to cross-coupling exemplified by the nickel-catalyzed reaction of alkenylzirconium derivatives with aryl halides

E. Negishi, D. Horn, 1977 .

Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a “zirconocene” equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes☆

E. Negishi, Tamotsu Takahashi, F. Cederbaum, 1986 .

Alkene and Alkyne Complexes of Zirconocene. Their Preparation, Structure, and Novel Transformations.

E. Negishi, Tamotsu Takahashi, 1998 .

A quarter of a century of explorations in organozirconium chemistry.

E. Negishi, 2005, Dalton transactions.

Zirconium-catalyzed enantioselective carboalumination of "unactivated" alkenes as a new synthetic tool for asymmetric carboncarbon bond formation

E. Negishi, Shouquan Huo, 2002 .

Asymmetric Synthesis of Chiral Cyclopentanes Bearing an All-Carbon Quaternary Stereocenter by Zirconium-Catalyzed Double Carboalumination.

E. Negishi, Chuan Wang, Yasuhiko Tomonari, 2017, Angewandte Chemie.

A highly efficient and selective synthesis of lissoclinolide featuring hydrogen transfer hydrozirconation,trans-selective Pd-catalyzed cross coupling of alkenylzirconiums with 1,1-dibromoalkenes and Ag-catalyzed lactonization providing(Z)-γ-alkylidenebutenolides

E. Negishi, Caiding Xu, 1999 .

A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides

S. Baba, E. Negishi, 1976 .

Handbook of organopalladium chemistry for organic synthesis

E. Negishi, 2002 .

Palladium‐ or Nickel‐Catalyzed Cross‐Coupling Reactions with Organozincs and Related Organometals

E. Negishi, Zhihong Huang, Guangwei Wang, 2009 .

Convenient method for the tertiary alkyl-alkynyl coupling via organoalanes

S. Baba, E. Negishi, 1975 .

Metal‐Promoted Cyclization. Part 18. Novel Cyclialkylation Reactions of (ω‐Halo‐1‐alkenyl)metal Derivatives. Synthetic Scope and Mechanism.

J. Tour, H. Sawada, E. Negishi, 1988 .

Metal promoted cyclization. 18. Novel cyclialkylation reactions of (.omega.-halo-1-alkenyl)metal derivatives. Synthetic scope and mechanism

J. Tour, H. Sawada, E. Negishi, 1988 .

Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes

E. Negishi, D. Horn, Tadao Yoshida, 1985 .

Zirconium-catalyzed allylalumination and benzylalumination of alkynes

E. Negishi, Joseph A. Miller, 1984 .

Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides

E. Negishi, N. Okukado, A. King, 1977 .

Highly general stereo-, regio-, and chemo-selective synthesis of terminal and internal conjugated enynes by the Pd-catalysed reaction of alkynylzinc reagents with alkenyl halides

E. Negishi, N. Okukado, A. King, 1977 .

Diastereoselective, Enantioselective, and Regioselective Carboalumination Reactions Catalyzed by Zirconocene Derivatives

E. Negishi, Ze Tan, 2006 .

A genealogy of Pd-catalyzed cross-coupling

E. Negishi, 2002 .

Palladium- or nickel-catalyzed cross coupling. A new selective method for carbon-carbon bond formation

E. Negishi, 1982 .

Organometallics in organic synthesis

E. Negishi, 1980 .

Conversion of non-conjugated dienes into conjugated diene-zirconocenes via multipositional regioisomerization

E. Negishi, J. Maye, 1993 .

Pd‐Catalyzed Cross‐Coupling with Organometals Containing Zn, Al, Zr, and so on – The Negishi Coupling and Its Recent Advances

E. Negishi, Shiqing Xu, Akimichi Oda, 2013 .

Trimethylaluminum–Dichlorobis(η5‐cyclopentadienyl)zirconium

E. Negishi, Danièle Choueiry, 2001 .

On the regiochemistry of cyclialkylation of regiodefined 4-halo-1-alkenylmetals producing cyclobutenes

E. Negishi, Fang Liu, 1997 .

Cyclization reactions of ω-tosyloxy-1-alkynyl- and ω-tosyloxy-1-alkenylborates and their ω-halo analogues†

J. A. Morrison, E. Negishi, L. D. Boardman, 1992 .

Enantioselective synthesis of chiral isotopomers of 1-alkanols by a ZACA-Cu-catalyzed cross-coupling protocol.

E. Negishi, Shiqing Xu, Akimichi Oda, 2014, Chemistry.

Palladium‐ or Nickel‐Catalyzed Cross‐Coupling with Organometals Containing Zinc, Magnesium, Aluminum, and Zirconium

E. Negishi, Fang Liu, 2007 .

E. Negishi, N. Okukado, A. King, 1977 .

SELECTIVE CARBON‐CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 30. A SELECTIVE AND CONVENIENT SYNTHESIS OF β,β‐DIALKYL‐SUBSTITUTED ALKENYLBORANES AND ALKENYLZIRCONIUMS VIA CARBOALUMINATION OF ALKYNES

E. Negishi, L. D. Boardman, 1983 .

Highly efficient asymmetric synthesis of fluvirucinine A1 via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)-lipase-catalyzed acetylation tandem process.

E. Negishi, B. Liang, 2008, Organic letters.

Formation of Carbon ? Carbon and Carbon ? Heteroatom Bonds via Organoboranes and Organoborates

E. Negishi, M. Idacavage, 2004 .

Palladium-catalyzed alkynylation.

E. Negishi, L. Anastasia, 2003, Chemical reviews.

Dielectric Slowing Down toward the Magnetically Ordered State in a Polar Conductor (EDT-TTFVO)2FeBr4

T. Sugimoto, E. Negishi, Takuya Matsumoto, 2007 .

Cyclic cascade carbopalladation reactions as a route to benzene and fulvene derivatives

E. Negishi, M. Ay, Z. Owczarczyk, 1992 .

trans‐Dichlorobis(triphenylphosphine)palladium(II)

E. Negishi, S. Mohan, 2008 .

Palladium‐Catalyzed Cross‐Coupling Reactions with Zinc, Boron, and Indium Exhibiting High Turnover Numbers (TONs): Use of Bidentate Phosphines and Other Critical Factors in Achieving High TONs.

E. Negishi, Zhihong Huang, M. Qian, 2005 .

Highly stereoselective synthesis of (1E)-2-methyl-1,3-dienes by palladium-catalyzed trans-selective cross-coupling of 1,1-dibromo-1-alkenes with alkenylzinc reagents.

E. Negishi, Xingzhong Zeng, M. Qian, 2004, Angewandte Chemie.

Clean inversion of configuration in the Pd-catalyzed cross-coupling of 2-bromo-1,3-dienes.

E. Negishi, Xingzhong Zeng, M. Qian, 2003, Journal of the American Chemical Society.

A novel, selective, and efficient route to carotenoids and related natural products via Zr-catalyzed carboalumination and Pd- and Zn-catalyzed cross coupling.

E. Negishi, F. Zeng, 2001, Organic letters.

An efficient and stereoselective synthesis of xerulin via Pd-catalyzed cross coupling and lactonization featuring (E)-lodobromoethylene as a novel two-carbon synthon.

A. Alimardanov, E. Negishi, C. Xu, 2000, Organic letters.

Intermolecular trapping of acylpalladium and related acylmetal derivatives with active C–H compounds

H. Makabe, E. Negishi, Show-Yee Liou, 1999 .

Palladium-catalyzed highly diastereoselective cyclic carbopalladation-carbonylative esterification tandem reaction of iododienes and iodoarylalkenes.

C. Copéret, E. Negishi, 1999, Organic Letters.

Palladium‐Catalyzed Carbonylative Cyclization Cascades with Iododienes and ‐trienes

C. Copéret, E. Negishi, S. Ma, 1996 .

Cyclic carbopalladation of alkynes terminated by carbonylative amidation

C. Copéret, E. Negishi, T. Sugihara, 1996 .

Palladium-Catalyzed Cyclization of 1-Iodo-Substituted 1,4-, 1,5-, and 1,6-Dienes as Well as of 5-Iodo-1,5-dienes in the Presence of Carbon Monoxide

J. Tour, C. Copéret, E. Negishi, 1996 .

Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes

J. Tour, C. Copéret, E. Negishi, 1996 .

Palladium-Catalyzed Cyclization of .omega.-Haloallenes. A New General Route to Common, Medium, and Large Ring Compounds via Cyclic Carbopalladation

E. Negishi, S. Ma, 1995 .

Termination of carbopalladation of alkynes via carbonylative amidation producing lactams

C. Copéret, E. Negishi, T. Sugihara, 1995 .

Acylpalladation of Internal Alkynes and Palladium-Catalyzed Carbonylation of (Z)-.beta.-Iodoenones and Related Derivatives Producing .gamma.-Lactones and .gamma.-Lactams

C. Copéret, E. Negishi, T. Sugihara, 1995 .

Facile Formation of Seven- and Eight-Membered Cycloalkenes via Catalytic and Cyclic Carbopalladation of Allenes

E. Negishi, S. Ma, 1994 .

Deferred Carbonylative Esterification in the Pd-Catalyzed Cyclic Carbometalation-Carbonylation Cascade

C. Copéret, E. Negishi, Z. Owczarczyk, 1994 .

Palladium-catalyzed carbonylative cyclization via trapping of acylpalladium derivatives with internal enolates. Its scope and factors affecting the C-to-O ratio

J. Tour, C. Copéret, E. Negishi, 1994 .

Selective synthesis of benzene derivatives via palladium-catalyzed cascade carbometallation of alkynes

E. Negishi, M. Ay, T. Sugihara, 1993 .

Palladium-catalyzed carbonylative cyclization of o-allylbenzyl halides to produce benzo-annulated enol lactones and/or bicyclo[3.3.0]hept-3-en-6-ones. An efficient route to U-68,215

E. Negishi, I. Shimoyama, Guangzhong. Wu, 1991 .

Synthesis of enol esters and enol lactones via palladium-catalyzed carbonyiation of ary land alkenyl halides

E. Negishi, Y. Zhang, I. Shimoyama, 1990 .

Carbonylative cyclization via intramolecular trapping of acylmetal derivatives by carbon nucleophiles catalyzed by late transition metals

E. Negishi, Y. Zhang, I. Shimoyama, 1989 .

Metal-promoted cyclization. 25. Palladium-catalyzed cascade carbometalation of alkynes and alkenes as an efficient route to cyclic and polycyclic structures

E. Negishi, Y. Zhang, 1989 .

Metal-promoted cyclization. 21. Palladium-catalyzed procedures for [3 + 2] annulation via intramolecular alkenylpalladation and arylpalladation

E. Negishi, Y. Zhang, B. O'connor, 1988 .

Palladium-catalyzed cyclic acylmetalation of allylic electrophiles as a route to cyclopentenone derivatives

J. Tour, E. Negishi, Guangzhong. Wu, 1988 .

Palladium- or nickel-catalyzed reactions of alkenylmetals with unsaturated organic halides as a selective route to arylated alkenes and conjugated dienes: scope, limitations, and mechanism

S. Baba, E. Negishi, Tamotsu Takahashi, 1987 .

‘Bis(triphenylphosphine)palladium:’ its generation, characterization, and reactions

K. Akiyoshi, E. Negishi, Tamotsu Takahashi, 1986 .

Highly selective synthesis of allylated arenes and diarylmethanes via palladium-catalyzed cross coupling involving benzylic derivatives

E. Negishi, H. Matsushita, N. Okukado, 1981 .

Apparent endo-mode cyclic carbopalladation with inversion of alkene configuration via exo-mode cyclization-cyclopropanation rearrangement

F. Lamaty, E. Negishi, Z. Owczarczyk, 1992 .

Highly stereo- and regiocontrolled cyclopentannulation via allylphosphonate conjugate addition and hydroboration-oxidation-elimination. Synthesis of pentalenic acid with virtually complete stereo- and regiocontrol

E. Negishi, Gilbert Agnel, 1991 .

Synthesis of benzofurans, tetrahydrobenzopyrans, and related cyclic ethers via cyclic carbopalladation

E. Negishi, A. Silveira, Thinh Nguyen, 1989 .

Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation

E. Negishi, Jyawei Cheng, Fen-Tair Luo, 1988 .

Efficient synthesis of carbobicyclic and carbopolycyclic compounds via intramolecular carbopalladation catalyzed by palladium-phosphine complexes

E. Negishi, Y. Zhang, B. O'connor, 1988 .

Transition Metal-Catalyzed Organometallic Reactions that Have Revolutionized Organic Synthesis

E. Negishi, 2007 .

Highly satisfactory alkynylation of alkenyl halides via Pd-catalyzed cross-coupling with alkynylzincs and its critical comparison with the sonogashira alkynylation.

E. Negishi, M. Qian, L. Anastasia, 2003, Organic letters.

Selective Intermolecular Coupling of Alkynes with Nitriles and Ketones via β,β‘ Carbon−Carbon Bond Cleavage of Zirconacyclopentenes

C. Xi, E. Negishi, K. Nakajima, 1998 .

Facile cleavage of the CβCβ′ bond of zirconacyclopentenes. Convenient method for selectively coupling alkynes with alkynes, nitriles, and aldehydes

E. Negishi, Tamotsu Takahashi, R. Hara, 1993 .

Metal-promoted cyclization. 19. Novel bicyclization of enynes and diynes promoted by zirconocene derivatives and conversion of zirconabicycles into bicyclic enones via carbonylation

J. Tour, E. Negishi, Tamotsu Takahashi, 1989 .

One-pot conversion of alkynes and alkenes into one-carbon homologated aldehydes via hydrozirconation-isocyanide insertion-hydrolysis

E. Negishi, D. Swanson, S. Miller, 1988 .

Magical power of transition metals: past, present, and future (Nobel Lecture).

E. Negishi, 2011, Angewandte Chemie.

Complete reversal of regiochemistry in cyclic acylpalladation. Novel synthesis of quinones.

J. Tour, E. Negishi, 1986 .

A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling

E. Negishi, Fen-Tair Luo, H. Matsushita, 1982 .

Palladium-catalyzed acylation of organozincs and other organometallics as a convenient route to ketones☆

E. Negishi, Joseph A. Miller, Fen-Tair Luo, 1983 .

Palladium-catalyzed cross-coupling reaction of homoallylic or homopropargylic organozincs with alkenyl halides as a new selective route to 1,5-dienes and 1,5-enynes

E. Negishi, Makoto Kobayashi, Louis F. Valente, 1980 .

Zipper-mode cascade carbometallation for construction of polycyclic structures

E. Negishi, 1992 .

Catalytic and selective conversion of (Z)-2-en-4-ynoic acids to either 2H-pyran-2-ones in the presence of ZnBr2 or (Z)-5-alkylidenefuran-2(5H)-ones in the presence of Ag2CO3

E. Negishi, L. Anastasia, Caiding Xu, 2002 .

Conversion of methyl ketones into terminal acetylenes and (E)-trisubstituted olefins of terpenoid origin

E. Negishi, A. King, A. Silveira, 1980 .

Highly Efficient and Selective Procedures for the Synthesis of γ-Alkylidenebutenolides via Palladium-Catalyzed Ene-Yne Coupling and Palladium- or Silver Catalyzed Lactonization of (Z)-2-En-4-ynoic Acids. Synthesis of Rubrolides A, C, D, and E

E. Negishi, Matin Kotora, 1997 .

Regio- and stereoselective synthesis of ?-alkylidenebutenolides and related compounds

E. Negishi, M. Kotora, 1997 .

Palladium-catalyzed carbonylative cyclization via trapping of acylpalladium derivatives with internal enolates. Its scope and factors affecting the C-to-O ratio

J. Tour, C. Copéret, E. Negishi, 1994 .

Palladium-catalyzed reaction of organoalanes and organozincs with .alpha.,.beta.-unsaturated acetals and orthoesters as conjugate addition equivalents

E. Negishi, S. Chatterjee, 1985 .

CATALYTIC GENERATION AND TRAPPING OF ACYLMETALS CONTAINING NI AND CU WITH ENOLATES

H. Makabe, E. Negishi, Y. Zhang, 1998 .

1,4- and 1,5-Diketones via palladium-catalyzed allylation of potassium enoxyborates

E. Negishi, Fen-Tair Luo, A. Silveira, 1983 .

Zirconium-catalyzed and zirconium-promoted cyclization reactions of non-conjugated dienes with alkylmagnesium halides to give cycloalkylmethylmagnesium derivatives☆

E. Negishi, Tamotsu Takahashi, Danièle Choueiry, 1998 .

Zirconium-catalyzed carboalumination of alkynes and enynes as a route to aluminacycles and their conversion to cyclic organic compounds

Arkadij M. Elizarov, J. Montchamp, E. Negishi, 1998 .

Multiple Mechanistic Pathways for Zirconium-Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C−H Activation

E. Negishi, D. Kondakov, Tamotsu Takahashi, 1996 .

Zirconium-Catalyzed Enantioselective Alkylalumination of Monosubstituted Alkenes Proceeding via Noncyclic Mechanism

E. Negishi, D. Kondakov, 1996 .

Diastereoselective zirconocene-promoted bicyclization-carbonylation of allylically methyl-substituted enynes. Synthesis of (+)-iridomyrmecin

E. Negishi, Z. Owczarczyk, Gilbert Agnel, 1992 .

Remarkably pair- and regioselective carbon-carbon bond-forming reaction of zirconacyclopentane derivatives with Grignard reagents

E. Negishi, Tamotsu Takahashi, T. Seki, 1991 .

Organozirconium Compounds in Organic Synthesis

E. Negishi, Tamotsu Takahashi, 1988 .

Zirconium-promoted bicyclization of enynes. Effects of enyne structure

E. Negishi, Tamotsu Takahashi, D. Swanson, 1987 .

Clean and convenient procedure for converting primary alkyl iodides and .alpha.,.omega.-diiodoalkanes into the corresponding alkyllithium derivatives by treatment with tert-butyllithium

E. Negishi, D. Swanson, C. Rousset, 1990 .

Patterns of Stoichiometric and Catalytic Reactions of Organozirconium and Related Complexes of Synthetic Interest

E. Negishi, Tamotsu Takahashi, 1994 .

By Addition of Olefinic and Acetylenic Linkages (Carboboration)

E. Negishi, 2007 .

Metal-promoted cyclization. 28. Regioselective and diastereoselective alkyl-alkene and alkene-alkene coupling promoted by zirconocene and hafnocene

E. Negishi, Tamotsu Takahashi, T. Seki, 1989 .

Di‐n‐butylbis(cyclopentadienyl)zirconium

E. Negishi, T. Novák, 2005 .

An odyssey from stoichiometric carbotitanation of alkynes to zirconium-catalysed enantioselective carboalumination of alkenes

E. Negishi, D. Kondakov, 1996 .

Stoichiometric reactions of nonconjugated dienes with zirconocene derivatives. Further delineation of the scope of bicyclization and observation of novel multipositional alkene regioisomerization

E. Negishi, Danièle Choueiry, J. Maye, 1995 .

Reaction of 3-zircona-1-cyclopentenes and zirconacyclopentanes with aldehydes. A selective and convenient synthesis of 4-penten-1-ols, (Z)-5-iodo-4-penten-1-ols, and related alkanols

C. Copéret, E. Negishi, Tamotsu Takahashi, 1994 .

Convenient synthesis of diene-zirconocenes and regioselective partial reduction of the more highly substituted double bonds of conjugated dienes via complexation with zirconocenes and protonolysis

E. Negishi, J. Maye, 1993 .

Factors Affecting the Unusual Reactivity Order in the β-Hydrogen Abstraction of Dialkylzirconocenes

E. Negishi, Tamotsu Takahashi, N. Suzuki, 1992 .

Novel head-to-tail alkyl-alkene or alkene-alkene coupling via zirconium-catalyzed reaction of alkylmagnesium derivatives with monosubstituted alkenes

E. Negishi, Tamotsu Takahashi, N. Suzuki, 1992 .

Zirconium-catalyzed, highly regioselective hydrosilation reaction of alkenes and X-ray structures of silyl(hydrido)zirconocene derivatives

P. Fanwick, E. Negishi, Tamotsu Takahashi, 1991 .

Catalytic Hydrogenation of Alkenes Using Zirconocene–Alkene Complexes

E. Negishi, Tamotsu Takahashi, N. Suzuki, 1991 .

A general and convenient procedure for the preparation of zirconocene complexes of alkenes and conjugated dienes

E. Negishi, D. Swanson, 1991 .

Novel zirconocene-promoted carbon-carbon bond formation via a 1,2-migration reaction of alkynylzirconium derivatives

E. Negishi, K. Takagi, C. Rousset, 1991 .

Reaction of Dimethylzirconocene with Alkylmagnesium Halides as a Potentially General Method for Preparing Zirconocene-Alkene Complexes

E. Negishi, Tamotsu Takahashi, T. Seki, 1990 .

Selective skeletal rearrangement by carbon–carbon bond activation

E. Negishi, Tamotsu Takahashi, T. Seki, 1990 .

Nondissociative mechanism for decomposition of dialkylzirconocenes to produce alkene–zirconocene–phosphine complexes

E. Negishi, Tamotsu Takahashi, D. Swanson, 1990 .

Stereoselective synthesis of exocyclic alkenes via zirconium-promoted alkyl-diene coupling

E. Negishi, S. Miller, 1989 .

Zirconocene–Alkene Complexes. An X-Ray Structure and a Novel Preparative Method

E. Negishi, Tamotsu Takahashi, Y. Uchida, 1989 .

Preparation of a hafnocene–ethylene complex from bis(η5-cyclopentadienyl)hafnacyclopentane and its characterization

E. Negishi, Tamotsu Takahashi, Y. Uchida, 1989 .

Zirconocene-promoted stereoselective bicyclization of 1,6- and 1,7-dienes to produce trans-zirconabicyclo[3.3.0]octanes and cis-zirconabicyclo[4.3.0]nonanes

F. Lamaty, E. Negishi, D. Swanson, 1989 .

Metal-promoted cyclization. 17. A novel bicyclization methodology via cyclialkylation of .omega.-halo-1-metallo-1-alkynes containing aluminum and zinc

J. Tour, H. Sawada, E. Negishi, 1988 .

Zirconacyclopropanes and Zirconacyclopropenes. Their Synthesis, Characterization, and Reactions

E. Negishi, Tamotsu Takahashi, D. Swanson, 1987 .

Selective carbon-carbon bond formation via transition metal catalysis. 31. Controlled carbometalation. 15. Zirconium-promoted carbozincation of alkynes

E. Negishi, D. Horn, Tadao Yoshida, 1983 .

Bimetallic catalytic systems containing Ti, Zr, Ni, and Pd. Their applications to selective organic syntheses

E. Negishi, 1981 .

Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

E. Negishi, D. Horn, 2002 .

Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins

E. Negishi, D. Horn, N. Okukado, 1978 .

Alkyne elementometalation-Pd-catalyzed cross-coupling. Toward synthesis of all conceivable types of acyclic alkenes in high yields, efficiently, selectively, economically, and safely: "green" way.

E. Negishi, Guangwei Wang, Zhao-Qin Xu, 2010, The Journal of organic chemistry.

Highly Efficient and Selective Procedures for the Synthesis of γ- Alkylidenebutenolides via Palladium-Catalyzed Ene-Yne Coupling and Palladium- or Silver-Catalyzed Lactonization of (Z)-2-En-4-ynoic Acids. Synthesis of Rubrolides A, C, D, and E

E. Negishi, M. Kotora, 1997 .

Conversion of methyl ketones into terminal acetylenes and (E)-trisubstituted olefins of terpenoid origin

E. Negishi, A. King, A. Silveira, 1980 .

Catalytic and Selective Conversion of (Z)‐2‐En‐4‐ynoic Acids to Either 2H‐Pyran‐2‐ones in the Presence of ZnBr2 or (Z)‐5‐Alkylidenefuran‐2(5H)‐ones in the Presence of Ag2CO3.

E. Negishi, L. Anastasia, Caiding Xu, 2002 .

Efficient and diastereoselective synthesis of (+)-Goniobutenolide A via palladium-catalyzed ene-yne cross coupling-lactonization cascade

E. Negishi, M. Kotora, 1996 .

Novel and selective α-substitution of ketones and other carbonyl compounds based on Pd-catalyzed cross coupling of α,β-unsaturated carbonyl derivatives containing α-halogen or α-metal groups ☆

E. Negishi, 1999 .

Palladium‐Catalyzed Tandem and Cascade Carbopalladation of Alkynes and 1,1‐Disubstituted Alkenes Terminated by Carbonylative Reactions

C. Copéret, E. Negishi, 2003 .

Metal promoted cyclization. 9. Controlled and catalytic acylpalladation. A novel route to cyclopentenone and cyclohexenone derivatives

J. Tour, E. Negishi, 1985 .

Selective carbon-carbon bond formation via transition metal catalysis. 37. Controlled carbometalation. 16. Novel syntheses of .alpha.,.beta.-unsaturated cyclopentenones via allylzincation of alkynes

E. Negishi, Joseph A. Miller, 1983 .

Convenient preparative method of α,β-disubstituted cyclopentenone by zirconium promoted intermolecular coupling of an alkyne, EtMgBr (or ethylene) and CO

Y. Nishihara, E. Negishi, Tamotsu Takahashi, 1997 .

Regio- and Stereoselective Synthesis of γ-Alkylidenebutenolides and Related Compounds.

E. Negishi, M. Kotora, 1997 .

Metal-promoted cyclization. 3. Highly selective synthesis of .alpha.-alkylidenetetrahydrofurans and .gamma.-alkylidenebutyrolactones via intramolecular opening of epoxysilanes

E. Negishi, Fen-Tair Luo, 1983 .

Inhibition of reductive elimination of diorganopalladium species by formation of tetraorganopalladates

K. Akiyoshi, E. Negishi, Tamotsu Takahashi, 1987 .

Palladium-catalyzed trans-selective alkynylation-alkylation tandem process for the synthesis of (E)-3-alkyl-1-trialkylsilyl-3-alken-1-ynes

E. Negishi, Ji-cheng Shi, Xingzhong Zeng, 2005 .

Development of a Method for the Synthesis of a-Substituted a,b-Unsaturated Lactones Based on Stille-Type Pd-catalyzed Carbonylation of (Z)-w-Iodoalkenols. An Efficient and Selective Synthesis of (+)-Hamabiwa-lactone B

E. Negishi, Baiqiao Liao, 2000 .

Palladium-Catalyzed Cyclization via Carbopalladation and Acylpalladation

E. Negishi, Guangwei Wang, Gangguo Zhu, 2007 .

Titanium-catalyzed cascade carboalumination of 2-alkyl-substituted dienes and related trienes

E. Negishi, D. Kondakov, S. Wang, 1996 .

Migratory insertion reactions of organometallics. 3. Carbon-carbon bond forming reactions of organotransition metals with .alpha.- or .gamma.-haloorganolithium reagents

K. Akiyoshi, E. Negishi, K. Takagi, 1989 .

Ethylzincation of Monosubstituted Alkenes Catalyzed by EtMgBr−Cl2ZrCp2 and Palladium-Catalyzed Cross Coupling of the Resultant Diisoalkylzinc Derivatives

E. Negishi, S. Gagneur, and Jean-Luc Montchamp, 2000 .

Highly(≥98%) Stereo- and Regioselective Trisubstituted Alkene Synthesis of Wide Applicability via 1-Halo-1-alkyne Hydroboration-Tandem Negishi-Suzuki Coupling or Organoborate Migratory Insertion Protocol.

E. Negishi, Honghua Rao, Shiqing Xu, 2011, Advanced synthesis & catalysis.

General discussions, organometallics of main group metals in organic synthesis

E. Negishi, 1980 .

A novel highly enantio- and diastereoselective synthesis of vitamin E side-chain

E. Negishi, Shiqing Xu, Yohei Matsueda, 2015 .

A convenient and asymmetric protocol for the synthesis of natural products containing chiral alkyl chains via Zr-catalyzed asymmetric carboalumination of alkenes. Synthesis of phytol and vitamins E and K.

E. Negishi, S. Huo, 2001, Organic letters.

Palladium-catalyzed cross-coupling reaction of alkynylzincs with benzylic electrophiles

E. Negishi, M. Qian, 2005 .

An efficient and general route to reduced polypropionates via Zr-catalyzed asymmetric CC bond formation.

E. Negishi, Ze Tan, T. Novák, 2004, Proceedings of the National Academy of Sciences of the United States of America.

Efficient and selective synthesis of siphonarienolone and related reduced polypropionates via Zr-catalyzed asymmetric carboalumination.

E. Negishi, Ze Tan, M. Magnin-Lachaux, 2004, Organic letters.

Selective carbon-carbon bond formation via transition metal catalysis. 29. A highly regio- and stereospecific palladium-catalyzed allylation of enolates derived from ketones

E. Negishi, R. John, H. Matsushita, 2002 .

Total synthesis of (+)-scyphostatin featuring an enantioselective and highly efficient route to the side-chain via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA).

E. Negishi, Guangwei Wang, Zhao-Qin Xu, 2010, Chemical communications.

A novel regiospecific aryl ketone synthesis by the reaction of arylborate anions with acyl chlorides

E. Negishi, R. E. Merrill, A. Abramovitch, 1975 .

Novel and regioselective aromatic double substitution involving borate anions and a regio- and stereo-selective route to dihydroaromatic derivatives

E. Negishi, R. E. Merrill, 1974 .

Novel synthesis of an ω-alkynylorganometallic reagent via triple bond isomerization with potassium 3-aminopropylamide: ω-(9-borabicyclo[3.3.1]nonan-9-yl)alkl-1-ynes

E. Negishi, C. Brown, 1977 .

An intramolecular Michael reaction involving borate complexes. A novel synthesis of -hydroxycarboxylic acids.

E. Negishi, T. Yoshida, 1973, Journal of the American Chemical Society.

Palladium-catalyzed reactions of allylic electrophiles with organometallic reagents. A regioselective 1,4-elimination and a regio- and stereoselective reduction of allylic derivatives

E. Negishi, H. Matsushita, 1982 .

A convenient procedure for hydrozirconation of alkynes with iso-BuZrCp2Cl generated in situ by treatment of Cp2ZrCl2 with tert-butylmagnesium chloride

N. Thinh, E. Negishi, Yumiki Noda, 1991 .

The origin of the configurational instability of 1-silyl-1-alkenyllithiums and related alkenylmetals

E. Negishi, Tamotsu Takahashi, 1986 .

Metal promoted cyclization. 5. Mechanistic duality in cyclialkylation of alkenylmetal derivatives

H. Sawada, E. Negishi, V. Bagheri, 1984 .

Novel silicon-promoted cycloalkylation of alkenylmetal derivatives

J. Tour, H. Sawada, E. Negishi, 1983 .

Titanium-Catalyzed Cascade Carboalumination of Dienes and Trienes

E. Negishi, D. Kondakov, Shan Wang, 1994 .

Zirconium-Catalyzed Asymmetric Carboalumination of Unactivated Terminal Alkenes.

E. Negishi, Shiqing Xu, 2016, Accounts of chemical research.

Catalytic enantioselective synthesis of chiral organic compounds of ultra-high purity of >99% ee

E. Negishi, Shiqing Xu, 2015, Proceedings of the Japan Academy. Series B, Physical and biological sciences.

A palladium-catalyzed stereospecific substitution reaction of homoallylzincs with .beta.-bromo-substituted .alpha.,.beta.-unsaturated carbonyl derivatives. A highly selective synthesis of mokupalide

E. Negishi, Makoto Kobayashi, 1980 .

Palladium-catalyzed cross-coupling reaction of homoallylic or homopropargylic organozincs with alkenyl halides as a new selective route to 1,5-dienes and 1,5-enynes

E. Negishi, Makoto Kobayashi, Louis F. Valente, 1980 .

A selective method for the synthesis of stereodefined exocyclic alkenes via allylmetalation of propargyl alcohols

E. Negishi, Y. Zhang, F. Cederbaum, 1986 .

Stereo- and regioselective routes to allylic silanes☆

E. Negishi, Fen-Tair Luo, C. Rand, 1982 .

A versatile and selective route to difunctional trisubstituted (E)-alkene synthons via zirconium-catalyzed carboalumination of alkynes

E. Negishi, D. Horn, C. Rand, 1981 .

A novel intermolecular transfer reaction of alkenyltrialkylborates with aqueous bases and its application to the protonolysis of alkenylboron derivatives

E. Negishi, K. Chiu, 1976 .

A stereoselective synthesis of disubstituted trans-alkenes by the reaction of trans-alkenyl trialkylaluminates with alkyl halides and sulfonates

S. Baba, E. Negishi, D. Horn, 1976 .

Stereoselective synthesis of β-hydroxy substituted trans-alkenes by the reaction of trans-alkenyltrialkylaluminates with epoxides

S. Baba, E. Negishi, A. King, 1976 .

Novel stereoselective alkenyl–aryl coupling via nickel-catalysed reaction of alkenylanes with aryl halides

S. Baba, E. Negishi, 1976 .

Selective synthesis of epolactaene featuring efficient construction of methyl (Z)-2-iodo-2-butenoate and (2R,3S,4S)-2-trimethylsilyl-2,3-epoxy-4-methyl- gamma-butyrolactone.

E. Negishi, Ze Tan, 2006, Organic letters.

Anti-Carbometalation of Homopropargyl Alcohols and Their Higher Homologues via Non-Chelation-Controlled Syn-Carbometalation and Chelation-Controlled Isomerization†

E. Negishi, S. M. and, 1997 .

Controlled carbometalation as a new tool for carbon-carbon bond formation and its application to cyclization

E. Negishi, 1987 .

Reaction of alkenes and dienes with t-butylmagnesium halides and zirconocene dihalides. A convenient procedure for hydrozirconation and a novel t-butylzirconation of conjugated alkenes

E. Negishi, Joseph A. Miller, Tadao Yoshida, 1984 .

Crystal Structures, and Electrical Conducting and Magnetic Properties in the Plate Crystals of (Ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)2·MX4 (M=Fe, Ga, X=Br; M=Fe, X=C1) Salts

H. Matsui, T. Sugimoto, E. Negishi, 2002 .

Catalytic, efficient, and syn-selective construction of deoxypolypropionates and other chiral compounds via Zr-catalyzed asymmetric carboalumination of allyl alcohol.

E. Negishi, Ze Tan, T. Novák, 2006, Journal of the American Chemical Society.

All-catalytic, efficient, and asymmetric synthesis of alpha,omega-diheterofunctional reduced polypropionates via "one-pot" Zr-catalyzed asymmetric carboalumination-Pd-catalyzed cross-coupling tandem process.

E. Negishi, Ze Tan, T. Novák, 2005, Journal of the American Chemical Society.

Metal-promoted cyclization. 26. Palladium-catalyzed cyclization of benzyl halides and related electrophiles containing alkenes and alkynes as a novel route to carbocycles

F. Lamaty, E. Negishi, Guangzhong. Wu, 1989 .

Nonconcerted Paths for Reactions of Alkene-Zirconocene Complexes

E. Negishi, Tamotsu Takahashi, Danièle Choueiry, 1994 .

An efficient and selective synthesis of nakienone A involving a novel protocol for α-alkenylation of ketones via palladium-catalyzed alkenyl-alkenyl coupling

E. Negishi, M. Pour, 1997 .

Widely applicable synthesis of enantiomerically pure tertiary alkyl-containing 1-alkanols by zirconium-catalyzed asymmetric carboalumination of alkenes and palladium- or copper-catalyzed cross-coupling.

E. Negishi, Guangwei Wang, Shiqing Xu, 2013, Chemistry, an Asian journal.

Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds

C. Copéret, E. Negishi, Show-Yee Liou, 1996 .

ONE-STEP CONSTRUCTION OF FUSED TRICYCLIC AND TETRACYCLIC STRUCTURES FROM ACYCLIC PRECURSORS VIA CYCLIC CARBOPALLADATION

E. Negishi, Y. Zhang, Guangzhong. Wu, 1990 .

ZIRCONIUM-CATALYZED ENANTIOSELECTIVE METHYLALUMINATION OF MONOSUBSTITUTED ALKENES

E. Negishi, D. Kondakov, 1995 .

Highly Enantiospecific Borylation for Chiral α-Amino Tertiary Boronic Esters.

E. Negishi, Xu‐Heng Yang, Qingqing Qi, 2018, Angewandte Chemie.

Stereoselective synthesis of partially substituted 1,2,3-butatriene derivatives via hydroboration

E. Negishi, Robin M. Williams, Takao Yoshida, 1974 .

Search for highly efficient, stereoselective, and practical synthesis of complex organic compounds of medicinal importance as exemplified by the synthesis of the C21-C37 fragment of amphotericin B.

E. Negishi, Guangwei Wang, F. Zeng, 2013, Chemistry.

Highly stereoselective total synthesis of fully hydroxy-protected mycolactones A and B and their stereoisomerization upon deprotection.

E. Negishi, Guangwei Wang, Ning Yin, 2011, Chemistry.

Stereoselective synthesis of the side chains of mycolactones A and B featuring stepwise double substitutions of 1,1-dibromo-1-alkenes.

E. Negishi, Guangwei Wang, M. Qian, 2006, Angewandte Chemie.

Efficient and selective synthesis of 6,7-Dehydrostipiamide via Zr-catalyzed asymmetric carboalumination and Pd-catalyzed cross-coupling of organozincs.

E. Negishi, Xingzhong Zeng, F. Zeng, 2004, Organic letters.

1,4-Pentenyne as a five-carbon synthon for efficient and selective syntheses of natural products containing 2,4-dimethyl-1-penten-1,5-ylidene and related moieties by means of Zr-catalyzed carboalumination of alkynes and alkenes.

E. Negishi, Gangguo Zhu, 2008, Chemistry.

Widely applicable Pd-catalyzed trans-selective monoalkylation of unactivated 1,1-dichloro-1-alkenes and Pd-catalyzed second substitution for the selective synthesis of E or Z trisubstituted alkenes.

E. Negishi, Ze Tan, 2006, Angewandte Chemie.

Palladium-catalyzed reactions of allylic electrophiles with organometallic reagents. A regioselective 1,4-elimination and a regio- and stereoselective reduction of allylic derivatives

E. Negishi, H. Matsushita, 1982 .

One-Step Homologation for the Catalytic Asymmetric Synthesis of Deoxypropionates.

E. Negishi, Haijun Li, Shiqing Xu, 2017, Chemistry.

Highly Efficient, Convergent, and Enantioselective Synthesis of Phthioceranic Acid.

E. Negishi, Haijun Li, Shiqing Xu, 2015, Angewandte Chemie.

Strictly regio- and stereo-controlled α-alkenylation of bicyclic enone derivatives via palladium-catalyzed cross coupling and its application to a formal synthesis of (±)-carbacyclin

E. Negishi, M. Kotora, M. Pour, 1998 .

Palladium‐Catalyzed Synthesis of 1,4‐Dienes by Allylation of Alkenylalanes:α‐Farnesene

E. Negishi, H. Matsushita, 2003 .

(2E)-1-TRIMETHYLSILYL-3,7-DIMETHYL-2,6-OCTADIENE (GERANYLTRIMETHYLSILANE)

E. Negishi, Fen-Tair Luo, 1986 .

Pd(0) and Pd(II) Complexes Containing Phosphorus and Other Group 15 Atom Ligands

E. Negishi, Danièle Choueiry, 2003 .

Catalytic Generation and Trapping of Acylmetals Containing Ni and Cu with Enolates.

H. Makabe, E. Negishi, Y. Zhang, 1998 .

Highly regio- and stereoselective synthesis of (Z)-trisubstituted alkenes via propyne bromoboration and tandem Pd-catalyzed cross-coupling.

E. Negishi, Chao Wang, Zhao-Qin Xu, 2009, Organic letters.

Highly Selective Methods for α-Alkenylation and α-Arylation of Ketones via Palladium- or Nickel-Catalyzed Cross Coupling

K. Akiyoshi, E. Negishi, 1987 .

AlCl3-Promoted Facile E-to-Z Isomerization Route to (Z)-2-Methyl-1-buten-1,4-ylidene Synthons for Highly Efficient and Selective (Z)-Isoprenoid Synthesis.

E. Negishi, Guangwei Wang, 2009, European journal of organic chemistry.

Zirconium-catalyzed asymmetric carboalumination (ZACA reaction) of 1,4-dienes

E. Negishi, Ze Tan, Ji-cheng Shi, 2006 .

An efficient and general method for the synthesis of alpha,omega-difunctional reduced polypropionates by Zr-catalyzed asymmetric carboalumination: synthesis of the scyphostatin side chain.

E. Negishi, Ze Tan, 2004, Angewandte Chemie.

A New Protocol for the Enantioselective Synthesis of Methyl‐Substituted Alkanols and Their Derivatives through a Hydroalumination/Zirconium‐Catalyzed Alkylalumination Tandem Process

E. Negishi, Ji-cheng Shi, Shouquan Huo, 2002 .

Selective carbon-carbon bond formation via transition-metal catalysis. 34. Countercation effects on the palladium-catalyzed allylation of enolates

E. Negishi, R. John, 1983 .

Selective carbon-carbon bond formation via transition metal catalysis. 29. A highly regio- and stereospecific palladium-catalyzed allylation of enolates derived from ketones

E. Negishi, R. John, H. Matsushita, 1982 .

Stereoselective cyclic carbolithiation of alkyne derivatives. A stereoselective synthesis of exocyclic alkenes

E. Negishi, Guangzhong. Wu, Fredrick E Cederbaum, 1990 .

Cyclic Carboalumination of Alkynylsilanes Forming Exocyclic Alkenes

E. Negishi, Joseph A. Miller, 1984 .

Principle of Activation of Electrophiles by Electrophiles through Dimeric Association—Two Are Better than One

E. Negishi, 1999 .

Use of InCl(3) as a cocatalyst and a Cl(2)Pd(DPEphos)-P(2-furyl)(3) catalyst system for one-pot hydrometalation-cross-coupling and carbometalation-cross-coupling tandem processes.

E. Negishi, Zhihong Huang, M. Qian, 2004, Organic letters.

A mild and selective synthesis of cyclopropene and cyclopropane derivatives via cycliallylation of alkenyllithiums

E. Negishi, A. Stoll, 1985 .

Synthesis of α-iodo-α,β-unsaturated ketones by the reaction of α-silyl-α,β-unsaturated ketones with ICl or IClAlCl3

A. Alimardanov, E. Negishi, 1999 .

Selective carbon-carbon bond formation via transition-metal catalysis. Part 18. Palladium-catalyzed stereo- and regiospecific coupling of allylic derivatives with alkenyl- and arylmetals. A highly selective synthesis and 1,4-dienes

E. Negishi, H. Matsushita, 1981 .

Pd-catalyzed selective tandem arylation–alkylation of 1,1-dihalo-1-alkenes with aryl- and alkylzinc derivatives to produce α-alkyl-substituted styrene derivatives

E. Negishi, Ji-cheng Shi, 2003 .

Anti-hydroalumination of Homo- and bishomopropargyl alcohols

E. Negishi, S. Ma, Fang Liu, 1997 .

Fundamental Properties of Palladium and Patterns of the Reactions of Palladium and Its Complexes

E. Negishi, 2003 .

Highly selective synthesis of conjugated dienoic and trienoic esters via alkyne elementometalation–Pd-catalyzed cross-coupling

E. Negishi, Guangwei Wang, S. Mohan, 2011, Proceedings of the National Academy of Sciences.

A Highly Efficient, Selective, and General Method for the Synthesis of Conjugated (all-E)-Oligoenes of the (CHCH)n Type via Iterative Hydrozirconation−Palladium-Catalyzed Cross-Coupling

E. Negishi, Fanxing Zeng and, 2002 .

Stereoselective Synthesis of Exocyclic Alkenes by Cu‐Catalyzed Allylmagnesiation, Pd‐Catalyzed Alkylation, and Ru‐Catalyzed Ring‐Closing Metathesis: Highly Stereoselective Synthesis of (Z)‐ and (E)‐γ‐Bisabolenes

E. Negishi, L. Anastasia, Yves Dumond, 2001 .

Zirconium-catalyzed methylalumination of heterosubstituted arylethynes. Factors affecting the regio-, stereo-, and chemoselectivities.

E. Negishi, Guangwei Wang, Gangguo Zhu, 2007, Journal of organometallic chemistry.

Fully reagent-controlled asymmetric synthesis of (-)-spongidepsin via the Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction).

E. Negishi, Gangguo Zhu, 2007, Organic letters.

Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes: ZACA–Lipase-Catalyzed Acetylation Synergy

E. Negishi, Zhihong Huang, Ze Tan, 2007 .

Palladium‐ or Nickel‐Catalyzed Cross‐Coupling with Organometals Containing Zinc, Aluminum, and Zirconium: The Negishi Coupling

E. Negishi, Zhihong Huang, Ze Tan, 2005 .

A convenient synthesis of unsymmetrical bibenzyls homoallylarenes, and homopropargylarenes via palladium-catalyzed cross coupling☆

E. Negishi, Makoto Kobayashi, H. Matsushita, 1983 .

Highly stereoselective synthesis of (1E)-2-methyl-1,3-dienes by palladium-catalyzed trans-selective cross-coupling of 1,1-dibromo-1-alkenes with alkenylzinc reagents.

E. Negishi, Xingzhong Zeng, M. Qian, 2004, Angewandte Chemie.

Selective carbon-carbon bond formation via transition-metal catalysis. 33. Palladium-catalyzed cross-coupling reaction of .alpha.-heterosubstituted alkenylmetals. A stereoselective route to heterosubstituted dienes suitable for the Diels-Alder reaction

E. Negishi, Fen-Tair Luo, 1983 .

Highly stereoselective synthesis of exocyclic alkenes via cyclialkylation

E. Negishi, V. Bagheri, Y. Zhang, 1987 .

PALLADIUM- OR NICKEL-CATALYZED CROSS COUPLING INVOLVING PROXIMALLY HETEROFUNCTIONAL REAGENTS

E. Negishi, 1983 .

Highly regioselective generation of “thermodynamic” enolates and their direct characterization by NMR☆

E. Negishi, S. Chatterjee, 1983 .

Vinylic organoboranes. 6. A general synthesis of (E)-disubstituted-alkenes or ketones via the (E)-(1-substituted-1-alkenyl)boronic esters

E. Negishi, H. Brown, D. Basavaiah, 1986 .

A novel, highly selective, and general methodology for the synthesis of 1,5-diene-containing oligoisoprenoids of all possible geometrical combinations exemplified by an iterative and convergent synthesis of coenzyme Q(10).

E. Negishi, Show-Yee Liou, Shouquan Huo, 2002, Organic letters.

A novel regiospecific aryl ketone synthesis by the reaction of arylborate anions with acyl chlorides

E. Negishi, R. E. Merrill, A. Abramovitch, 1975 .

A selective synthesis of alkenylmercuric chlorides via alkenylalanes

E. Negishi, K. Jadhav, N. Daotien, 1982 .

Nickel- or palladium-catalyzed cross coupling. 28. A selective synthesis of a mixture of C-15 epimers of (.+-.)-11-deoxyprostaglandin E2 methyl ester

E. Negishi, Fen-Tair Luo, 1985 .

POTASSIUM (2-METHYL-l-CYCLOHEXENYLOXY)TRIETHYLBORATE

E. Negishi, S. Chatterjee, 1986 .

Palladium-catalyzed allylation of lithium 3-alkenyl-1-cyclopentenolates-triethylborane and its application to a selective synthesis of methyl (z)-jasmonate1

E. Negishi, Fen-Tair Luo, 1985 .

anti-Stereospecificity in the palladium-catalysed reactions of alkenyl- or aryl-metal derivatives with allylic electrophiles

E. Negishi, H. Matsushita, 1982 .

Scope of the palladium-catalyzed coupling reaction of organometallics with allylic electrophiles. Effect of the leaving group☆

E. Negishi, H. Matsushita, S. Chatterjee, 1981 .

A selective and convenient synthesis of β, β-dialkyl-substituted alkenylbroanes and alkenylzirconiums via carboalumination of alkynes1

E. Negishi, L. D. Boardman, 1982 .

A novel synthesis of cyclopentenones and cyclohexenones via cycliacylation of lithioalkenylcarboxamides

H. Sawada, E. Negishi, A. Stoll, 1986 .

A method for the preparation of terminal and internal conjugated diynes via palladium-catalyzed cross-coupling

E. Negishi, S. F. Lovich, Fen-Tair Luo, 1984 .

Novel 1,2-migration reactions of organometals containing aluminum, zinc, and other main-group metals with .alpha.-haloorganolithiums

K. Akiyoshi, E. Negishi, 1988 .

Highly enantioselective synthesis of γ-, δ-, and ε-chiral 1-alkanols via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)–Cu- or Pd-catalyzed cross-coupling

E. Negishi, Shiqing Xu, Akimichi Oda, 2014, Proceedings of the National Academy of Sciences.

Syntheses of Chiral Heterocyclic Compounds via Zirconium-Catalyzed Asymmetric Carboalumination of Alkynes (ZACA Reaction)

E. Negishi, Shiqing Xu, 2014 .

Efficient and selective synthesis of (S,R,R,S,R,S)-4,6,8,10,16,18-hexamethyl-docosane via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction).

E. Negishi, Gangguo Zhu, B. Liang, 2008, Organic letters.

Zirconium‐Catalyzed Asymmetric Carboalumination of Unactivated Terminal Alkenes

E. Negishi, Shiqing Xu, 2016 .

ZACA Reaction: Zr-Catalyzed Asymmetric Carboalumination of Alkenes

E. Negishi, Ze Tan, T. Novák, 2010 .

Zirconium-Catalyzed Enantioselective Alkylalumination of Monosubstituted Alkenes Proceeding via Noncyclic Mechanism.

E. Negishi, D. Kondakov, 1996 .

Zirconium-Catalyzed Enantioselective Methylalumination of Monosubstituted Alkenes.

E. Negishi, D. Kondakov, 1996 .

Zirconium-Catalyzed Carboalumination of Alkynes and Enynes as a Route to Aluminacycles and Their Conversion to Cyclic Organic Compounds.

Arkadij M. Elizarov, J. Montchamp, E. Negishi, 1998 .

Organozirconium Compounds in Organic Synthesis

E. Negishi, Tamotsu Takahashi, 1988 .

Zirconium catalyzed CC bond formation reaction of conjugated diynes with EtMgBr

E. Negishi, Tamotsu Takahashi, Danièle Choueiry, 1993 .

Diastereoselective Zirconocene‐Promoted Bicyclization‐Carbonylation of Allylically Methyl‐Substituted Enynes. Synthesis of (+)‐Iridomyrmecin.

E. Negishi, Z. Owczarczyk, Gilbert Agnel, 1992 .

Zr-promoted ‘pair’-selective and regioselective synthesis of penta-substituted benzene derivatives

E. Negishi, Yves Dumond, 2004 .

Highly(≥98%) Selective Trisubstituted Alkene Synthesis of Wide Applicability via Fluoride-Promoted Pd-Catalyzed Cross-Coupling of Alkenylboranes.

E. Negishi, Tomáš Tobrman, Honghua Rao, 2010, Israel journal of chemistry.

Arylethyne Bromoboration-Negishi Coupling Route to E- or Z-Aryl-Substituted Trisubstituted Alkenes of ≥98% IsomericPurity. New Horizon in the Highly Selective Synthesis of Trisubstituted Alkenes.

E. Negishi, Chao Wang, Zhao-Qin Xu, 2010, Advanced synthesis & catalysis.

Hydrogen Transfer Hydrozirconation of Alkenes with iBuZrCp2Cl Catalyzed by Lewis-Acidic Metal Compounds Containing Al, Zn, Si, Ag, and Pd

H. Makabe, E. Negishi, 1999 .

Multiple Mechanistic Pathways for Zirconium‐Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C‐H Activation.

E. Negishi, D. Kondakov, Tamotsu Takahashi, 1997 .

Facile and reversible displacement of η-C5H5 from Zr by organolithiums; formation of (η5-cyclopentadienyl) trialkylzirconiums and their reactions eith electrophiles and alkenes

E. Negishi, D. Kondakov, 1996 .

Remarkably “Pair”‐Selective and Regioselective Carbon‐Carbon Bond Forming Reaction of Zirconacyclopentane Derivatives with Grignard Reagents.

E. Negishi, Tamotsu Takahashi, T. Seki, 1991 .

Zirconium-Promoted Bicyclization of Enynes. Effects of Enyne Structure.

E. Negishi, Tamotsu Takahashi, D. Swanson, 1987 .

(−)‐Dichlorobis[(1,2,3,3a,7a‐η)‐1‐[(1S,‐2S,5R)‐5‐methyl‐2‐(1‐methylethyl)]cyclohexyl‐1H‐inden‐1‐yl]zirconium and Its (+)‐(1R,2R,5S)‐Isomer

E. Negishi, Shouquan Huo, 2003 .

A general method for the synthesis of E and/or Z oligoisoprenoids based on Pd-catalyzed homoallyl-alkenyl and homopropargyl-alkenyl cross coupling and Zr-catalyzed carboalumination

E. Negishi, Show-Yee Liou, Shouquan Huo, 2000 .

Carbon-carbon bond formation by the reaction of organolithiums with α-lithiated cyclic enol ethers. Stereoselective synthesis of β- and γ-hydroxy DI- and tri-substituted alkenes

E. Negishi, Thinh Nguyen, 1991 .

Clean and Convenient Procedure for Converting Primary Alkyl Iodides and α,ω-Diiodoalkanes into the Corresponding Alkyllithium Derivatives by Treatment with tert-Butyllithium.

E. Negishi, D. Swanson, C. Rousset, 1991 .

A novel hydrogen transfer hydroalumination of alkenes with triisobutylaluminum catalyzed by Pd and other late transition metal complexes

H. Makabe, E. Negishi, S. Gagneur, 2001 .

E. Negishi, Shouquan Huo, S. Huo, 2001, Organic letters.

Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd(tBu3P)2.

E. Negishi, Ji-cheng Shi, Xingzhong Zeng, 2003, Organic letters.

A strictly "pair"-selective synthesis of conjugated diynes via Pd-catalyzed cross coupling of 1,3-diynylzincs: a superior alternative to the Cadiot-Chodkiewicz reaction.

E. Negishi, C. Xu, M. Hata, 2000, Organic letters.

Direct Synthesis of Terminal Alkynes via Pd-Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations

E. Negishi, M. Kotora, Chun-xiao Xu, 1997 .

Highly efficient and selective synthesis of conjugated triynes and higher oligoynes of biological and materials chemical interest via palladium-catalyzed alkynyl-alkenyl coupling.

E. Negishi, E. Métay, Qian Hu, 2006, Organic letters.

(E)‐1‐Bromo‐2‐iodoethylene

E. Negishi, F. Zeng, 2003 .

A Strictly “Pair”‐Selective Synthesis of Conjugated Diynes via Pd‐Catalyzed Cross Coupling of 1,3‐Diynylzincs: A Superior Alternative to the Cadiot‐Chodkiewicz Reaction.

E. Negishi, Caiding Xu, M. Hata, 2001 .

A method for the preparation of terminal and internal conjugated diynes via palladium-catalyzed cross-coupling

E. Negishi, S. F. Lovich, Fen-Tair Luo, 1984 .

Direct Synthesis of Terminal Alkynes via Pd‐Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations.

E. Negishi, M. Kotora, Chun-xiao Xu, 1998 .

Direct synthesis of heteroarylethynes via palladium-catalyzed coupling of heteroaryl halides with ethynylzinc halides. Its application to an efficient synthesis of a thiophenelactone from Chamaemelum nobile L

E. Negishi, M. Kotora, Ze Tan, 1997 .

Synthesis and Reactivity of Zirconocene Derivatives

E. Negishi, Shouquan Huo, 2003 .

Conversion of Methyl Ketones into Terminal Alkynes: (E)‐Buten‐3‐ynyl‐2,6,6‐trimethyl‐1‐cyclohexene

J. Tour, E. Negishi, A. King, 2003 .

Some newer aspects of organozirconium chemistry of relevance to organic synthesis. Zr-Catalyzed enantioselective carbometallation

E. Negishi, 2001 .

A dielectric metal λ-(BEDT-TSF)2FeCl4

H. Matsui, E. Negishi, N. Toyota, 2003 .

Evidence of the first-order nature of the metal-insulator phase transition in λ-(BEDT-TSF)2FeCl4

Masashi Watanabe, E. Negishi, N. Toyota, 2003 .

Anomalous Splitting of 1H-NMR Spectra in λ-(BEDT-TSF)2FeCl4

H. Matsui, E. Negishi, N. Toyota, 2002 .

Ferromagnetic ordering in a new nickel polyborate NiB12O14(OH)10.

Tao Yang, Jianhua Lin, H. Nojiri, 2006, Dalton transactions.

Carbon-carbon bond formation via opening of epoxysilanes with organometals containing lithium and copper

E. Negishi, Joseph A. Miller, Y. Zhang, 1989 .

A Selective and Efficient Synthesis of (E)-4-Methyl-3-alken-1-ols via Zirconium-Catalyzed Carboalumination of Terminal Alkynes

E. Negishi, Makoto Kobayashi, A. Silveira, 1980 .

A HIGHLY EFFICIENT CHEMO-, REGIO-, AND STEREOSELECTIVE SYNTHESIS OF (7E,9Z)-DODECADIEN-1-YL ACETATE, A SEX PHEROMONE OF LOBESIA BOTRANA, VIA A FUNCTIONALIZED ORGANOBORATE

E. Negishi, A. Abramovitch, 1977 .

Palladium‐Catalyzed Alkenylation by the Negishi Coupling

E. Negishi, Zhihong Huang, Guangwei Wang, 2006 .

Enantioselective two-dimensional high-performance liquid chromatographic determination of N-methyl-D-aspartic acid and its analogues in mammals and bivalves.

K. Hamase, W. Lindner, E. Negishi, 2012, Journal of chromatography. A.

5.8.2.11.3. by Transmetallation from Other Metal Organometallics to Metal Halides

E. Negishi, 2007 .

Acylpalladation of Internal Alkynes and Palladium-Catalyzed Carbonylation of (Z)-β-Iodoenones and Related Derivatives Producing γ-Lactones and γ-Lactams.

C. Copéret, E. Negishi, T. Sugihara, 1995 .

Catalysis with d-Block Transition Metals for Green Organic Synthesis and a Sustainable World

E. Negishi, 2011 .

Palladium‐Catalyzed Cross‐Coupling Reactions with Zinc, Boron, and Indium Exhibiting High Turnover Numbers (TONs): Use of Bidentate Phosphines and Other Critical Factors in Achieving High TONs.

E. Negishi, Zhihong Huang, M. Qian, 2005 .

Metal-Promoted Cyclization. Part 29. Carbonylative Cyclization via Intramolecular Trapping of Acylmetal Derivatives by Carbon Nucleophiles Catalyzed by Late Transition Metals.

E. Negishi, Y. Zhang, I. Shimoyama, 1990 .

Palladium-Catalyzed Carbonylative Cyclization Cascade with Iododienes and -trienes.

C. Copéret, E. Negishi, S. Ma, 1997 .

Selective Synthesis of Benzene Derivatives via Palladium-Catalyzed Cascade Carbometalation of Alkynes.

E. Negishi, M. Ay, T. Sugihara, 1993 .

Palladium-Catalyzed Cyclization of ω-Haloallenes. A New General Route to Common, Medium, and Large Ring Compounds via Cyclic Carbopalladation.

E. Negishi, S. Ma, 1995 .

Palladium‐Catalyzed Carbonylative Cyclization of o‐Allylbenzyl Halides to Produce Benzo‐Annulated Enol Lactones and/or Bicyclo(3.3.0)hept‐3‐ en‐6‐ones. An Efficient Route to U‐68,215.

E. Negishi, I. Shimoyama, Guangzhong. Wu, 1992 .

Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2- alkenylbenzenes.

J. Tour, C. Copéret, E. Negishi, 2010 .

Termination of Carbopalladation of Alkynes via Carbonylative Amidation Producing Lactams.

C. Copéret, E. Negishi, T. Sugihara, 1995 .

(E)‐1‐Bromo‐4‐trimethylsilyl‐1‐buten‐3‐yne and (E)‐1‐Bromo‐4‐(tert‐butyldimethylsilyl)‐1‐buten‐3‐yne

E. Negishi, F. Zeng, 2003 .

Synthesis of Enol Esters and Enol Lactones via Palladium-Catalyzed Carbonylation of Aryl and Alkenyl Halides.

E. Negishi, Y. Zhang, I. Shimoyama, 1991 .

Nickel- or Palladium-Catalyzed Cross Coupling. Part 31. Palladium- or Nickel-Catalyzed Reactions of Alkenylmetals with Unsaturated Organic Halides as a Selective Route to Arylated Alkenes and Conjugated Dienes: Scope, Limitations, and

S. Baba, E. Negishi, Tamotsu Takahashi, 1987 .

Deferred Carbonylative Esterification in the Pd-Catalyzed Cyclic Carbometalation-Carbonylation Cascade.

C. Copéret, E. Negishi, Z. Owczarczyk, 1995 .

Metal-Promoted Cyclization. Part 21. Palladium-Catalyzed Procedures for (3 + 2)Annulation via Intramolecular Alkenylpalladation and Arylpalladation.

E. Negishi, Y. Zhang, B. O'connor, 1989 .

Palladium-Catalyzed Cyclic Acylmetalation of Allylic Electrophiles as a Route to Cyclopentenone Derivatives.

J. Tour, E. Negishi, Guangzhong. Wu, 1989 .

Metal-Promoted Cyclization. Part 25. Palladium-Catalyzed Cascade Carbometalation of Alkynes and Alkenes as an Efficient Route to Cyclic and Polycyclic Structures.

E. Negishi, Y. Zhang, 1989 .

SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 20. HIGHLY SELECTIVE SYNTHESIS OF ALLYLATED ARENES AND DIARYLMETHANES VIA PALLADIUM-CATALYZED CROSS COUPLING INVOLVING BENZYLIC DERIVATIVES

E. Negishi, H. Matsushita, N. Okukado, 1981 .

Palladium‐Catalyzed Cyclization of 1‐Iodo‐Substituted 1,4‐, 1,5‐, and 1,6‐Dienes as well as of 5‐Iodo‐1,5‐dienes in the Presence of Carbon Monoxide.

J. Tour, C. Copéret, E. Negishi, 1996 .

An Efficient and Stereoselective Synthesis of Xerulin via Pd-Catalyzed Cross Coupling and Lactonization Featuring (E)-Iodobromoethylene as a Novel Two-Carbon Synthon.

A. Alimardanov, E. Negishi, Caiding Xu, 2000 .

Palladium-Catalyzed Highly Diastereoselective Cyclic Carbopalladation—Carbonylative Esterification Tandem Reaction of Iododienes and Iodoarylalkenes.

C. Copéret, E. Negishi, 1999 .

Facile Formation of Seven- and Eight-Membered Cycloalkenes via Catalytic and Cyclic Carbopalladation of Allenes.

E. Negishi, S. Ma, 1995 .

Synthesis of Biaryls via Palladium‐Catalyzed Cross‐Coupling: 2‐Methyl‐4′‐Nitrobiphenyl

E. Negishi, Tamotsu Takahashi, A. King, 2003 .

Metal-Promoted Cyclization. Part 22. Synthesis of Benzofurans, Tetrahydrobenzopyrans, and Related Cyclic Ethers via Cyclic Carbopalladation.

E. Negishi, A. Silveira, Thinh Nguyen, 1989 .

Catalysis in Organic Synthesis : edited by W.H. Jones Academic Press, New York, 1980, ix + 314 pages, $ 29.50.

E. Negishi, 1980 .

Synthesis of cyclopentanol derivatives via palladium-catalyzed cyclic allylmetallation-dehydrometallation

S. Iyer, E. Negishi, C. Rousset, 1989 .

Apparent Endo-Mode Cyclic Carbopalladation with Inversion of Alkene Configuration via Exo-Mode Cyclization-Cyclopropanation-Rearrangement.

F. Lamaty, E. Negishi, Z. Owczarczyk, 1993 .

Highly Stereo- and Regiocontrolled Cyclopentannulation via Allylphosphonate Conjugate Addition and Hydroboration-Oxidation- Elimination. Synthesis of Pentalenic Acid with Virtually Complete Stereo- and Regiocontrol.

E. Negishi, Gilbert Agnel, 1991 .

Efficient Synthesis of Carbobicyclic and Carbopolycyclic Compounds via Intramolecular Carbopalladation Catalyzed by Palladium-Phosphine Complexes.

E. Negishi, Y. Zhang, B. O'connor, 1988 .

Pd- and Ni-catalyzed cross-coupling reactions in the synthesis of organic electronic materials

A. Wei, E. Negishi, Shiqing Xu, 2014, Science and technology of advanced materials.

Transition Metal Catalyzed Organometallic Reactions that Have Revolutionized Organic Synthesis

E. Negishi, 2007 .

Palladium-Catalyzed Cross-Coupling of Alkynylzincs with Allylic Electrophiles: An Efficient and Selective Synthesis of Stereo- and Regio-Defined 1,4-Enynes.

E. Negishi, M. Qian, 2005 .

Strictly pair -selective and economical synthesis of conjugated diynes via Pd-catalyzed reaction of terminal alkynes with 1,1-dichloroethylene, elimination with LDA, and subsequent transformations

E. Negishi, M. Qian, 2003 .

A new protocol for the enantioselective synthesis of methyl-substituted alkanols and their derivatives through a hydroalumination/ zirconium-catalyzed alkylalumination tandem process.

E. Negishi, Ji-cheng Shi, Shouquan Huo, 2002, Angewandte Chemie.

Carbometalation Reactions of Diphenylacetylene and Other Alkynes with Methylalanes and Titanocene Derivatives

E. Negishi, D. Horn, and Denis Y. Kondakov, 1997 .

Metal-promoted cyclization: VI. Palladium-catalyzed cyclization via intramolecular allylation of alkenylmetals

E. Negishi, S. Chatterjee, 1985 .

A Selective Synthesis of (E)-2-Methyl-1-alkenyl Iodides via Zirconium-Catalyzed Carboalumination

E. Negishi, D. Horn, N. Okukado, 1979 .

By Oxidative Addition

E. Negishi, T. Takahashi, 2003 .

Highly Satisfactory Alkynylation of Alkenyl Halides via Pd‐Catalyzed Cross‐Coupling with Alkynylzincs and Its Critical Comparison with the Sonogashira Alkynylation.

E. Negishi, M. Qian, L. Anastasia, 2003 .

Overview of the Negishi Protocol with Zn, Al, Zr, and Related Metals

E. Negishi, 2003 .

Efficient and stereoselective synthesis of yellow scale pheromone via alkyne haloboration, Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction), and Pd-catalyzed tandem Negishi coupling.

E. Negishi, Zhao-Qin Xu, 2008, Organic letters.

Palladium-Catalyzed Carbon—Carbon Cross-Coupling. Overview of the Negishi Protocol with Zn, Al, Zr, and Related Metals

E. Negishi, 2003 .

Metallic conductivity and ferromagnetic interaction of iron(III) d spins in the needle crystals of (ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)(2).FeBr(4) salt.

T. Sugimoto, E. Negishi, K. Murata, 2002, Inorganic chemistry.

Design and synthesis of a novel pre-column derivatization reagent with a 6-methoxy-4-quinolone moiety for fluorescence and tandem mass spectrometric detection and its application to chiral amino acid analysis.

A. Ojida, K. Hamase, S. Ohtsuki, 2015, Journal of pharmaceutical and biomedical analysis.

Enantiomerically pure zirconium and hafnium complexes containing a chiral cyclopentadiene derivative prepared from (−)-β-pinene

S. Iyer, E. Negishi, C. Rousset, 1997 .

Metal-Promoted Cyclization. Part 20. Palladium-Catalyzed Cyclization of Alkenyl and Aryl Halides Containing α,β-Unsaturated Carbonyl Groups via Intramolecular Carbopalladation.

E. Negishi, Fen-Tair Luo, Y. Zhang, 1989 .

Selective carbon-carbon bond formation via transition metal catalysis. 23. Highly selective and convenient method for the synthesis of 1,5-enynes and 1,5-dienes by the reaction of 1,3-dilithiopropargyl phenyl sulfide with allylic halides

E. Negishi, C. Rand, K. Jadhav, 1981 .

1‐Chloro‐2‐iodoethylene

C. Copéret, E. Negishi, 2001 .

(E)-2-PHENYL-1-PROPENYLDIMETHYLALUMINUM

E. Negishi, D. Horn, 1986 .

SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 23. HIGHLY SELECTIVE AND CONVENIENT METHOD FOR THE SYNTHESIS OF 1,5-ENYNES AND 1,5-DIENES BY THE REACTION OF 1,3-DILITHIOPROPARGYL PHENYL SULFIDE WITH ALLYLIC HALI

E. Negishi, C. Rand, K. Jadhav, 1982 .

Dielectric ordering and colossal magnetodielectricity in the antiferromagnetic insulating state of l-ÑBEDT-TSFÖ2FeCl4

H. Matsui, Takehiko Mori, Masashi Watanabe, 2005 .

Specific heat studies for ?-(BEDT-TSF) 2FeCl 4

E. Negishi, N. Toyota, Y. Ishizaki, 2003 .

Historical Background of Organopalladium Chemistry

E. Negishi, 2003 .

Highly satisfactory procedures for the Pd-catalyzed cross coupling of aryl electrophiles with in situ generated alkynylzinc derivatives.

E. Negishi, L. Anastasia, Negishi Ei, 2001, Organic letters.

By Isomerization and Displacement

E. Negishi, 2007 .

By Pyrolytic Elimination of H2

E. Negishi, 2007 .

Controlled Carbometalation. Part 20. Carbometalation Reaction of Alkynes with Organoalane‐Zirconocene Derivatives as a Route to Stereo‐ and Regiodefined Trisubstituted Alkenes.

E. Negishi, D. Horn, Tadao Yoshida, 2002 .

Total synthesis of (+)-scyphostatin featuring an enantioselective and highly efficient route to the side-chain via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA).

E. Negishi, Guangwei Wang, Zhao-Qin Xu, 2010, Chemical communications.

Magical power of transition metals: past, present, and future (Nobel Lecture).

E. Negishi, 2011, Angewandte Chemie.

Asymmetric Synthesis of Chiral Cyclopentanes Bearing an All-Carbon Quaternary Stereocenter by Zirconium-Catalyzed Double Carboalumination.

E. Negishi, Chuan Wang, Yasuhiko Tomonari, 2017, Angewandte Chemie.

Enantioselective synthesis of chiral isotopomers of 1-alkanols by a ZACA-Cu-catalyzed cross-coupling protocol.

E. Negishi, Shiqing Xu, Akimichi Oda, 2014, Chemistry.

An Efficient and General Method for the Synthesis of α,ω‐Difunctional Reduced Polypropionates by Zr‐Catalyzed Asymmetric Carboalumination: Synthesis of the Scyphostatin Side Chain (I).

E. Negishi, Ze Tan, 2004 .

An efficient and general method for the synthesis of alpha,omega-difunctional reduced polypropionates by Zr-catalyzed asymmetric carboalumination: synthesis of the scyphostatin side chain.

E. Negishi, Ze Tan, 2004, Angewandte Chemie.

An Odyssey from Stoichiometric Carbotitanation of Alkynes to Zirconium‐ Catalyzed Enantioselective Carboalumination of Alkenes

E. Negishi, D. Kondakov, 1997 .

NOVEL STEREOSELECTIVE ALKENYL-ARYL COUPLING VIA NICKEL-CATALYZED REACTION OF ALKENYLALANES WITH ARYL HALIDES

S. Baba, E. Negishi, 1976 .

Regio- and stereoselective synthesis of ?-alkylidenebutenolides and related compounds

E. Negishi, M. Kotora, 1997 .

Nonlinear electrical trnasport in ?-(BEDT-TSF) 2FeCl 4 under magnetic field

H. Matsui, E. Negishi, N. Toyota, 2003 .

Antiferromagnetic resonance in ?-(BEDT-TSF) 2FeCl 4

H. Matsui, E. Negishi, K. Koyama, 2003 .

Antiferromagnetic resonance in λ-(BEDT-TSF) 2 FeCl 4

H. Matsui, E. Negishi, K. Koyama, 2003 .

Establishment of a Two-Dimensional HPLC-MS/MS Method Combined with DCl/D 2 O Hydrolysis for the Determination of Trace Amounts of D-Amino Acid Residues in Proteins

H. Masaki, T. Ueda, H. Homma, 2015 .