R. Bergman

发表

Oxidative addition of soluble iridium and rhodium complexes to carbon-hydrogen bonds in methane and higher alkanes

R. Periana, A. Janowicz, J. M. Buchanan, 1984 .

Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels.

D. Fiedler, K. Raymond, R. Bergman, 2004, Accounts of chemical research.

Parallel reaction pathways in the cobalt-catalyzed cyclotrimerization of acetylenes

D. R. Mcalister, J. Bercaw, R. Bergman, 1977 .

Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex

E. Wasserman, C. Moore, R. Bergman, 1992, Science.

A physical organic road to organometallic CH oxidative addition reactions

R. Bergman, 1990 .

The thermodynamic driving force for CH activation at iridium

S. Nolan, C. Hoff, R. Bergman, 1988 .

Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution

R. Bergman, B. Arndtsen, T. A. Mobley, 1995 .

CH bond activation in functionalized organic compounds with Cp∗ (PMe3)IrMe(OTf): generation, structural characterization and metal-based rearrangement of the acetone activation product Cp∗ (PMe3)Ir(η3-CH2C(OH)CH2)+OTf−

R. Bergman, B. Arndtsen, 1995 .

Activation of carbon-hydrogen bonds in alkanes and other organic molecules by Ir(I), Rh(I) and Ir(III) complexes

B. H. Weiller, C. Moore, R. Bergman, 1995 .

Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)

A. Janowicz, R. Bergman, 1982 .

Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups

A. Janowicz, R. Bergman, 1983 .

Room temperature generation of reactive intermediates Cp*Zr:O and Cp*2Zr:S: trapping reactions with unsaturated organic molecules and dative ligands

P. Walsh, R. Bergman, M. Carney, 1990 .

Photoinduced N2 loss as a route to long-lived organometallic alkane complexes: A time-resolved IR and NMR study

M. W. George, Amy I Gilson, R. Perutz, 2010 .

Rapid, reversible intramolecular carbon-hydrogen oxidative addition and hydrogen exchange in a heterodinuclear "early-late" transition metal complex

K. I. Goldberg, E. Jacobsen, R. Bergman, 1988 .

A facile, metal- and solvent-free, autoxidative coupling of quinolines with indoles and pyrroles.

J. Ellman, R. Bergman, Mikaël Brasse, 2011, Chemical communications.

Encapsulation and characterization of proton-bound amine homodimers in a water-soluble, self-assembled supramolecular host

Michael D. Pluth, D. Fiedler, K. Raymond, 2009, Proceedings of the National Academy of Sciences.

Chemoselective and Site-Selective Reductions Catalyzed by a Supramolecular Host and a Pyridine-Borane Cofactor.

K. Raymond, R. Bergman, F. Toste, 2021, Journal of the American Chemical Society.

Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

J. Ellman, R. Bergman, D. A. Colby, 2010, Chemical reviews.

Protein-like proton exchange in a synthetic host cavity

C. Perrin, K. Raymond, C. Sgarlata, 2015, Proceedings of the National Academy of Sciences.

Enantioselective catalysis of the aza-Cope rearrangement by a chiral supramolecular assembly.

K. Raymond, R. Bergman, C. J. Brown, 2009, Journal of the American Chemical Society.

Acid Catalysis in Basic Solution: A Supramolecular Host Promotes Orthoformate Hydrolysis

Michael D. Pluth, K. Raymond, R. Bergman, 2007, Science.

Supramolecular catalysis of orthoformate hydrolysis in basic solution: an enzyme-like mechanism.

Michael D. Pluth, K. Raymond, R. Bergman, 2008, Journal of the American Chemical Society.

High-turnover supramolecular catalysis by a protected ruthenium(II) complex in aqueous solution.

K. Raymond, R. Bergman, C. J. Brown, 2011, Journal of the American Chemical Society.

An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation.

J. Ellman, R. Bergman, E. Arceo, 2009, Chemical communications.

A step beyond the Feltham-Enemark notation: spectroscopic and correlated ab initio computational support for an antiferromagnetically coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni).

K. Wieghardt, S. DeBeer, T. Petrenko, 2011, Journal of the American Chemical Society.

Development of ruthenium catalysts for the enantioselective synthesis of P-stereogenic phosphines via nucleophilic phosphido intermediates.

R. Bergman, F. Toste, V. Chan, 2009, Journal of the American Chemical Society.

Making amines strong bases: thermodynamic stabilization of protonated guests in a highly-charged supramolecular host1.

Michael D. Pluth, K. Raymond, R. Bergman, 2007, Journal of the American Chemical Society.

Advances in supramolecular host-mediated reactivity

K. Raymond, Kay T. Xia, R. Bergman, 2020, Nature Catalysis.

Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions.

K. Tan, J. Ellman, R. Bergman, 2001, Journal of the American Chemical Society.

New Regio- and Stereoselective Cascades via Unstabilized Azomethine Ylide Cycloadditions for the Synthesis of Highly Substituted Tropane and Indolizidine Frameworks.

J. Ellman, B. Mercado, R. Bergman, 2016, Journal of the American Chemical Society.

Pt-catalyzed C-C activation induced by C-H activation.

R. Bergman, T. Tilley, Miriam A. Bowring, 2013, Journal of the American Chemical Society.

Reactivity of a Terminal Ti(IV) Imido Complex toward Alkenes and Alkynes: Cycloaddition vs C−H Activation

R. Bergman, R. Andersen, Jennifer L. Polse, 1998 .

Equilibrium isotope effects on noncovalent interactions in a supramolecular host-guest system.

K. Raymond, R. Bergman, J. Mugridge, 2012, Journal of the American Chemical Society.

Encapsulation of protonated diamines in a water-soluble, chiral, supramolecular assembly allows for measurement of hydrogen-bond breaking followed by nitrogen inversion/rotation.

Michael D. Pluth, K. Raymond, R. Bergman, 2008, Journal of the American Chemical Society.

Acceleration of amide bond rotation by encapsulation in the hydrophobic interior of a water-soluble supramolecular assembly.

Michael D. Pluth, K. Raymond, R. Bergman, 2008, The Journal of organic chemistry.

Comparison of the reactivity of (CO)3L2ReOR, (CO)3L2ReOAr and (CO)3L2ReNHAr with carbon dioxide and other electrophiles

R. Bergman, R. D. Simpson, 1992 .

Reaction of Carbon Dioxide and Heterocumulenes with an Unsymmetrical Metal-Metal Bond. Direct Addition of Carbon Dioxide across a Zirconium-Iridium Bond and Stoichiometric Reduction of Carbon Dioxide to Formate

A. Baranger, R. Bergman, T. Hanna, 1995 .

Synthesis and Properties of Seven Ionic Liquids Containing 1-Methyl-3-octylimidazolium or 1-Butyl-4-methylpyridinium Cations

J. Prausnitz, J. Salminen, N. Papaiconomou, 2006 .

Synthesis of isoquinuclidines from highly substituted dihydropyridines via the Diels-Alder reaction.

J. Ellman, R. Bergman, R. M. Martin, 2013, Organic letters.

Source of Rate Acceleration for Carbocation Cyclization in Biomimetic Supramolecular Cages.

Jinghua Guo, Lee‐Ping Wang, Wanli Yang, 2022, Journal of the American Chemical Society.

Rh(I)-catalyzed alkylation of quinolines and pyridines via C-H bond activation.

J. Ellman, R. Bergman, Jared C. Lewis, 2007, Journal of the American Chemical Society.

C-F sp(2) bond functionalization mediated by niobium complexes.

R. Bergman, J. Arnold, T. Gianetti, 2015, Dalton transactions.

Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf).

R. Bergman, T. Tilley, J. Curley, 2012, Dalton transactions.

Insertion of alkynes into zirconium-nitrogen bonds leading to 2,3-diazametallacyclopentenes. Generation and reactivity of Cp2Zr(N2Ph2)

P. Walsh, R. Bergman, F. Hollander, 1992 .

Mechanism and Catalytic Impact of Ir–Ta Heterobimetallic and Ir–P Transition Metal/Main Group Interactions on Alkene Hydrogenation

R. Bergman, D. Ess, Ying Zhang, 2015 .

Heterogeneous Supramolecular Catalysis through Immobilization of Anionic M4L6 Assemblies on Cationic Polymers.

K. Raymond, R. Bergman, H. Miyamura, 2020, Journal of the American Chemical Society.

The Mechanism of a C-H Bond Activation Reaction in Room-Temperature Alkane Solution

J. Yeston, Haw Yang, T. Lian, 1997 .

Mechanistic investigation of the staudinger ligation.

C. Bertozzi, R. Bergman, H. van Halbeek, 2005, Journal of the American Chemical Society.

Physical organic studies of organometallic reactions

R. Bergman, 1980 .

A mechanistic investigation of the carbon-carbon bond cleavage of aryl and alkyl cyanides using a cationic RhIII silyl complex.

Felicia L. Taw, R. Bergman, A. Mueller, 2003, Journal of the American Chemical Society.

Unusually Mild and Selective Hydrocarbon C-H Bond Activation with Positively Charged Iridium(III) Complexes

R. Bergman, B. Arndtsen, 1995, Science.

Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand.

R. Bergman, Trevor D. Lohrey, J. Arnold, 2017, Angewandte Chemie.

Mechanismus der thermischen umwandlung von 3,3′‐Bicyclopropenylen in Benzol‐Derivate

James H. Davis, K. Shea, R. Bergman, 1976 .

Mechanism of the Thermal Conversion of 3,3′‐Bicyclo‐propenyls into Benzene Derivatives

James H. Davis, K. Shea, R. Bergman, 1976 .

Measuring ion-pairing and hydration in variable charge supramolecular cages with microwave microfluidics

Kathleen A. Schwarz, Charles A. E. Little, J. Booth, 2019, Communications Chemistry.

Facile intermolecular activation of carbon-hydrogen bonds in methane and other hydrocarbons and silicon-hydrogen bonds in silanes with the iridium(III) complex Cp*(PMe3)Ir(CH3)(OTf)

R. Bergman, P. Burger, 1993 .

Carbon–fluorine bond cleavage in fluoroarenes via a niobium(III) imido complex: from stoichiometric to catalytic hydrodefluorination

R. Bergman, J. Arnold, T. Gianetti, 2014 .

Dis-assembly of a benzylic CF3 group mediated by a niobium(III) imido complex.

R. Bergman, J. Arnold, T. Gianetti, 2013, Journal of the American Chemical Society.

Diverse Reactivity of a Rhenium(V) Oxo Imido Complex: [2 + 2] Cycloadditions, Chalcogen Metathesis, Oxygen Atom Transfer, and Protic and Hydridic 1,2-Additions.

R. Bergman, Trevor D. Lohrey, J. Arnold, 2020, Inorganic chemistry.

Simultaneously bound guests and chiral recognition: a chiral self-assembled supramolecular host encapsulates hydrophobic guests

Michael D. Pluth, Shannon M. Biros, K. Raymond, 2008 .

Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation.

J. Ellman, R. Bergman, Jared C. Lewis, 2008, Accounts of chemical research.

Supramolecular catalysis in metal-ligand cluster hosts.

K. Raymond, R. Bergman, F. Toste, 2015, Chemical reviews.

Independent mechanisms in the thermal rearrangement of mono- and bicylic 3,4-dimethylenecyclobutene derivatives

T. J. Henry, R. Bergman, 1972 .

Dihydrogen Activation by Titanium Sulfide Complexes.

R. Bergman, R. Andersen, Z. Sweeney, 1999, Organometallics.

Improved scope and diastereoselectivity of C–H activation in an expanded supramolecular host

K. Raymond, R. Bergman, Akos Kokai, 2016 .

Catalytic deprotection of acetals in basic solution with a self-assembled supramolecular "nanozyme".

Michael D. Pluth, K. Raymond, R. Bergman, 2007, Angewandte Chemie.

Supramolecular catalysis of a unimolecular transformation: aza-Cope rearrangement within a self-assembled host.

D. Fiedler, K. Raymond, R. Bergman, 2004, Angewandte Chemie.

Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics.

K. Raymond, R. Bergman, F. Toste, 2019, Journal of the American Chemical Society.

Enzyme-like control of carbocation deprotonation regioselectivity in supramolecular catalysis of the Nazarov cyclization.

Mikael P. Backlund, K. Raymond, R. Bergman, 2011, Angewandte Chemie.

1H NMR chemical shift calculations as a probe of supramolecular host-guest geometry.

K. Raymond, R. Bergman, J. Mugridge, 2011, Journal of the American Chemical Society.

Enantioselective guest binding and dynamic resolution of cationic ruthenium complexes by a chiral metal-ligand assembly.

D. Fiedler, K. Raymond, R. Bergman, 2004, Journal of the American Chemical Society.

Selective C-H bond activation by a supramolecular host-guest assembly.

D. Fiedler, K. Raymond, R. Bergman, 2004, Angewandte Chemie.

Encapsulation of cationic ruthenium complexes into a chiral self-assembled cage.

D. Fiedler, K. Raymond, R. Bergman, 2003, Inorganic chemistry.

Cationic Ir(III) alkyl and hydride complexes: stoichiometric and catalytic CH activation by Cp∗(PMe3)Ir(R)(X) in homogeneous solution

R. Bergman, P. Burger, S. R. Klei, 2002 .

Electronic and medium effects on the rate of arene C [bond] H activation by cationic Ir(III) complexes.

D. Tellers, R. Bergman, B. Arndtsen, 2002, Journal of the American Chemical Society.

Alkylation of Iridium via tandem carbon-hydrogen bond. Activation/decarbonylation of aldehydes. Access to complexes with tertiary and highly hindered metal-carbon bonds

P. J. Alaimo, R. Bergman, and Bruce A. Arndtsen, 2000 .

TRANSFER OF OXYGEN AND SULFUR FROM ORGANIC MOLECULES TO A ZR-IR BOND. EVIDENCE FOR AN UNUSUALLY RAPID ATOM ABSTRACTION REACTION

A. Baranger, R. Bergman, T. Hanna, 1995 .

Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing.

R. Bergman, Trevor D. Lohrey, J. Arnold, 2019, Dalton transactions.

Synthesis of mono-substituted 2,2'-bipyridines.

J. McCusker, J. Cordaro, R. Bergman, 2002, Chemical communications.

Ten‐Membered Ring Enediynes with Remarkable Chemical and Biological Profiles

K. Nicolaou, E. J. Sorensen, R. Minto, 1992 .

Electronic Structures of Rhenium(II) β-Diketiminates Probed by EPR Spectroscopy: Direct Comparison of an Acceptor-Free Complex to Its Dinitrogen, Isocyanide, and Carbon Monoxide Adducts.

David W. Small, G. Rao, R. D. Britt, 2020, Journal of the American Chemical Society.

Electron localization in a mixed-valence diniobium benzene complex

T. Tyliszczak, A. Kilcoyne, D. Shuh, 2014, Chemical science.

Synthesis and reactions of enantiopure (neomenthylcyclopentadienyl)iridium(III) halides with silver salts. A dramatic steric effect on the competition between inter- and intramolecular C-H activation

R. Bergman, Yinong. Ma, 1994 .

IR Flash Kinetic Spectroscopy of C-H Bond Activation of Cyclohexane-d0 and -d12 by Cp*Rh(CO)2 in Liquid Rare Gases: Kinetics, Thermodynamics, and Unusual Isotope Effect

B. H. Weiller, M. Tauber, E. Wasserman, 1994 .

The Quest for Double Vicinal C–H Bond Activation on the (η 5:η 5-Fulvalene)diiridium Platform: Syntheses and Structures of (η 5:η 5-Fulvalene)Ir2(ortho-μ-C6H4)(CO)2 (Ir–Ir) and Related Complexes

K. Vollhardt, R. Bergman, Bolin Zhu, 2019, Synthesis.

Evidence for the Intervention of Different C−H Activating Intermediates in the Irradiation of (η5-C5Me5)(PMe3)IrH2 and the Reaction of (η5-C5Me5)(PMe3)Ir(H)(Cl) with Strong Base. Detection and Spectroscopic Characterization of (η5-C5Me5)(PMe3)Ir(Li)(Cl), an Intermediate in the Dehydrohalogenation Re

A. Golden, R. Bergman, T. H. Peterson, 2001 .

A study of the silanolysis of triphenylsilane and p-methoxyphenol catalysed by (PMe3)4RuH2 and the stoichiometric reactions of (PMe3)4Ru(H)(OC6H4-p-X) (X = Me, OMe) with Ph3SiH

R. Bergman, M. Burn, 1994 .

Synthesis and carbon-hydrogen activation reactions of .eta.5-indenyl(trimethylphosphine)iridium alkyl and hydride complexes

R. Bergman, T. Foo, 1992 .

Alkyl, aryl, hydrido, and acetate complexes of (DMPM)2Ru [DMPM = bis(dimethylphosphino)methane]: reductive elimination and oxidative addition of carbon-hydrogen bonds

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Iridium alkoxide and amide hydride complexes. Synthesis, reactivity, and the mechanism of oxygen-hydrogen and nitrogen-hydrogen reductive elimination

R. Bergman, David S. Glueck, L. N. Winslow, 1991 .

Liquid xenon: an effective inert solvent for carbon-hydrogen oxidative addition reactions

B. H. Weiller, R. Bergman, P. Stoutland, 1989 .

C-C Activation of Organic Small Ring Compounds by Rearrangement of Cycloalkylhydridorhodium Complexes to Rhodacycloalkanes. Synthesis of Metallacyclobutanes, Including One with a Tertiary M-C Bond, by Nucleophilic Addition to π-Allyl

R. Periana, R. Bergman, 1987 .

Isomerization of the Hydridoalkylrhodium Complexes Formed on Oxidative Addition of Rhodium to Alkane C‐H Bonds. Evidence for the Intermediacy of η2‐Alkane Complexes.

R. Periana, R. Bergman, 1987 .

Isomerization of the hydridoalkylrhodium complexes formed on oxidative addition of rhodium to alkane carbon-hydrogen bonds. Evidence for the intermediacy of .eta.2-alkane complexes

R. Periana, R. Bergman, 1986 .

Carbon-carbon activation of organic small ring compounds by arrangement of cycloalkylhydridorhodium complexes to rhodacycloalkanes. Synthesis of metallacyclobutanes, including one with a tertiary metal-carbon bond, by nucleophilic addition to .pi.-allyl complexes

R. Periana, R. Bergman, 1986 .

Rapid intramolecular rearrangement of a hydrido(cyclopropyl)rhodium complex to a rhodacyclobutane. Independent synthesis of the metallacycle by addition of hydride to the central carbon atom of a cationic rhodium .pi.-allyl complex

R. Periana, R. Bergman, 1984 .

Activation of Alkanes with Organotransition Metal Complexes

R. Bergman, 1984, Science.

Oxidative addition of rhodium to alkane carbon-hydrogen bonds: enhancement in selectivity and alkyl group functionalization

R. Periana, R. Bergman, 1984 .

OXIDATIVE ADDITION OF RHODIUM TO ALKANE C-H BONDS: ENHANCEMENT IN SELECTIVITY AND ALKYL GROUP FUNCTIONALIZATION, AND THE FIRST STRUCTURALLY CHARACTERIZED DERIVATIVE OF A C-H INSERTION PRODUCT

R. Bergman, R. A. Periana-Pillai, 1983 .

CARBON-HYDROGEN ACTIVATION IN COMPLETELY SATURATED HYDROCARBONS: DIRECT OBSERVATION OF M + R-H → M(R)(H)

A. Janowicz, R. Bergman, 1982 .

C-H ACTIVATION IN COMPLETELY SATURATED HYDROCARBONS: DIRECT OBSERVATION OF M + R-H -> M(R)(H)

A. Janowicz, R. Bergman, 1981 .

A comprehensive investigation of the chemistry and basicity of a parent amidoruthenium complex.

S. Sklenak, J. R. Fulton, R. Bergman, 2002, Journal of the American Chemical Society.

Synthesis and properties of oxygen-centered tetradecaimido hexatantalum clusters.

R. Bergman, J. Arnold, Laura L. Anderson, 2007, Angewandte Chemie.

Heats of reaction of Cp*(PMe3)Ir(R)(H) (R = C6H5, C6H11, and H) with HCl, CCl4, CBr4, and CH3I : a solution thermochemical study of the C-H insertion reaction

S. Nolan, C. Hoff, J. M. Buchanan, 1987 .

Asymmetric catalytic synthesis of P-stereogenic phosphines via a nucleophilic ruthenium phosphido complex.

R. Bergman, F. Toste, I. Stewart, 2006, Journal of the American Chemical Society.

Aluminium-catalyzed intramolecular hydroamination of aminoalkenes.

R. Bergman, J. Koller, 2010, Chemical communications.

Synthesis and carbon-carbon bond-forming reactions of tungsten, molybdenum, and rhenium enolates

R. Bergman, C. Heathcock, J. J. Doney, 1985 .

Rhenium-catalyzed didehydroxylation of vicinal diols to alkenes using a simple alcohol as a reducing agent.

J. Ellman, R. Bergman, E. Arceo, 2010, Journal of the American Chemical Society.

An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage

G. Schwaab, M. Havenith, K. Raymond, 2020, Proceedings of the National Academy of Sciences.

Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions.

R. Bergman, J. Arnold, Laura L. Anderson, 2006, Organometallics.

Encapsulated water in a supramolecular $Ga_4$$L_6$$^{-12}$ cage is neither ice- nor bulk water-like

G. Schwaab, M. Havenith, K. Raymond, 2020 .

Reassignment of the configuration of salvianolic acid B and establishment of its identity with lithospermic acid B.

J. Ellman, R. Bergman, A. Watzke, 2006, Journal of natural products.

Formation, reactivity, and properties of nondative late transition metal-oxygen and -nitrogen bonds.

J. R. Fulton, R. Bergman, Andrew W. Holland, 2002, Accounts of chemical research.

Group 5 chemistry supported by β-diketiminate ligands.

R. Bergman, S. Hohloch, J. Arnold, 2016, Dalton transactions.

Synthesis and characterization of group 5 imido complexes supported by the 2,6-dichloroaryl β-diketiminato ligand

R. Bergman, J. Arnold, T. Gianetti, 2014 .

Reaction of (bisimido)niobium(V) complexes with organic azides: [3 + 2] cycloaddition and reversible cleavage of β-diketiminato ligands involving nitrene transfer.

R. Bergman, J. Arnold, T. Gianetti, 2014, Journal of the American Chemical Society.

MONOMERIC CYCLOPENTADIENYLNICKEL METHOXO AND AMIDO COMPLEXES : SYNTHESIS, CHARACTERIZATION, REACTIVITY, AND USE FOR EXPLORING THE RELATIONSHIP BETWEEN H-X AND M-X BOND ENERGIES

Patrick L. Holland, P. Holland, S. Nolan, 1997 .

Photo-activation of d(0) niobium imido azides: en route to nitrido complexes.

R. Bergman, J. Arnold, C. Camp, 2016, Chemical communications.

Deconvoluting the Role of Charge in a Supramolecular Catalyst.

K. Raymond, R. Bergman, F. Toste, 2018, Journal of the American Chemical Society.

Synthesis of dihydropyridines and pyridines from imines and alkynes via C-H activation.

J. Ellman, R. Bergman, D. A. Colby, 2008, Journal of the American Chemical Society.

Unstabilized azomethine ylides for the stereoselective synthesis of substituted piperidines, tropanes, and azabicyclo[3.1.0] systems.

J. Ellman, R. Bergman, M. A. Ischay, 2013, Journal of the American Chemical Society.

Aza Cope rearrangement of propargyl enammonium cations catalyzed by a self-assembled "nanozyme".

D. Fiedler, K. Raymond, R. Bergman, 2008, Journal of the American Chemical Society.

Molecular recognition and stabilization of iminium ions in water.

D. Fiedler, K. Raymond, R. Bergman, 2006, Journal of the American Chemical Society.

Applications of Low-Valent Transition Metalates: Development of a Reactive Noncarbonyl Rhenium(I) Anion.

R. Bergman, J. Arnold, Erik T Ouellette, 2022, Accounts of chemical research.

Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of cyclo-P4 Inverted Sandwich Compounds

R. Bergman, L. Maron, J. Arnold, 2014, Journal of the American Chemical Society.

Rapid reduction of nitric oxide to dinitrogen by zirconium(II): Kinetic studies on a reaction controlled by gas-liquid transport

K. McNeill, R. Bergman, 1999 .

Synthesis of a first-row transition metal parent amido complex and carbon monoxide insertion into the amide N-H bond.

R. Bergman, D. J. Fox, 2003, Journal of the American Chemical Society.

Synthesis of pyridines from ketoximes and terminal alkynes via C-H bond functionalization.

J. Ellman, R. Bergman, R. M. Martin, 2012, The Journal of organic chemistry.

A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation.

J. Ellman, R. Bergman, J. Szewczyk, 2001, Angewandte Chemie.

Z-selective, catalytic internal alkyne semihydrogenation under H2/CO mixtures by a niobium(III) imido complex.

R. Bergman, J. Arnold, T. Gianetti, 2011, Journal of the American Chemical Society.

Imidotitanium complexes as hydroamination catalysts: substantially enhanced reactivity from an unexpected cyclopentadienide/amide ligand exchange.

J. S. Johnson, R. Bergman, 2001, Journal of the American Chemical Society.

2,3-Di-propyl-1,4-dehydrobenzene

T. P. Lockhart, R. Bergman, C. Mallon, 1980 .

Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination.

R. Bergman, S. Hohloch, J. Arnold, 2017, Journal of the American Chemical Society.

Ligand-based carbon-nitrogen bond forming reactions of metal dinitrosyl complexes with alkenes and their application to C-H bond functionalization.

Chen Zhao, R. Bergman, Mark R. Crimmin, 2014, Accounts of chemical research.

Synthesis and coordination chemistry of tri-substituted benzamidrazones.

J. Ellman, R. Bergman, Mark R. Crimmin, 2011, Dalton transactions.

Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation.

J. Ellman, R. Bergman, Jessica Y. Wu, 2006, Angewandte Chemie.

Enabling New Modes of Reactivity via Constrictive Binding in a Supramolecular-Assembly-Catalyzed Aza-Prins Cyclization.

David M. Kaphan, K. Raymond, R. Bergman, 2015, Journal of the American Chemical Society.

Pd-catalyzed dynamic kinetic enantioselective arylation of silylphosphines.

R. Bergman, F. Toste, V. Chan, 2007, Journal of the American Chemical Society.

Efficient Bipedal Robots Based on Passive-Dynamic Walkers

G. B. Kauffman, Patrick L. Holland, R. A. Andersen, 2005 .

Facile Rh(III)-Catalyzed Synthesis of Fluorinated Pyridines.

J. Ellman, R. Bergman, Shuming Chen, 2015, Organic letters.

Rhodium-catalyzed synthesis of branched amines by direct addition of benzamides to imines.

J. Ellman, R. Bergman, Kevin D. Hesp, 2012, Organic letters.

Insertion of Nitriles into a Zirconium−Iridium Heterobimetallic Complex: A Mechanistic Study

J. R. Fulton, R. Bergman, and Tracy A. Hanna, 2000 .

Synthesis of Iridium(III) Carboxamides via the Bimetallic Reaction between Cp(PMe(3))IrPh(OH) and [Cp(PMe(3))Ir(Ph)NCR](+).

D. Tellers, R. Bergman, J. Ritter, 1999, Inorganic chemistry.

Rh(I)-catalyzed direct arylation of pyridines and quinolines.

J. Ellman, R. Bergman, Jared C. Lewis, 2008, Journal of the American Chemical Society.

Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes.

J. Ellman, R. Bergman, Y. Lian, 2012, Chemical science.

Rhodium catalyzed chelation-assisted C-H bond functionalization reactions.

J. Ellman, R. Bergman, A. Tsai, 2012, Accounts of chemical research.

Highly diastereoselective synthesis of tetrahydropyridines by a C-H activation-cyclization-reduction cascade.

Simon Duttwyler, A. Rheingold, J. Ellman, 2012, Journal of the American Chemical Society.

Rhodium(III)-catalyzed alkenyl C-H bond functionalization: convergent synthesis of furans and pyrroles.

J. Ellman, R. Bergman, Y. Lian, 2013, Angewandte Chemie.

Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.

J. Ellman, R. Bergman, Mikaël Brasse, 2011, Organic letters.

Surface immobilization of an organo-iridium complex through a carbon–metal bond

C. Sukenik, R. Bergman, M. Anstey, 2011 .

Annulation of aromatic imines via directed C-H activation with Wilkinson's catalyst.

J. Ellman, R. Bergman, R. Thalji, 2001, Journal of the American Chemical Society.

Thermal decomposition of 2H-azirines. Formation of products resulting from carbon-carbon bond cleavage

R. Bergman, L. A. Wendling, 1976 .

Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascade.

J. Ellman, R. Bergman, Y. Lian, 2013, Journal of the American Chemical Society.

Rhodium(III)-Catalyzed Indazole Synthesis by C–H Bond Functionalization and Cyclative Capture

L. Lavis, J. Ellman, R. Bergman, 2013, Journal of the American Chemical Society.

Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization.

J. Ellman, R. Bergman, A. Tsai, 2011, Journal of the American Chemical Society.

Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates.

J. Ellman, R. Bergman, Kevin D. Hesp, 2011, Journal of the American Chemical Society.

Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation.

K. Tan, J. Ellman, R. Bergman, 2002, Journal of the American Chemical Society.

Organometallic chemistry: C–H activation

Robert G. Bergman, R. Bergman, 2007, Nature.

Total synthesis of (+)-lithospermic acid by asymmetric intramolecular alkylation via catalytic C-H bond activation.

K. Tan, J. Ellman, R. Bergman, 2005, Journal of the American Chemical Society.

Intermolecular coupling of alkenes to heterocycles via C-H bond activation.

K. Tan, J. Ellman, R. Bergman, 2004, The Journal of organic chemistry.

Facile Rh(III)-Catalyzed Synthesis of Fluorinated Pyridines.

J. Ellman, R. Bergman, Shuming Chen, 2015, Organic letters.

Solvolytic reactivity of 4-tricyclyl, 1-apocamphyl, and 1-methyl-4-tricyclo[2.2.2.02,6]octyl trifluoromethanesulfonates. Observations on the interaction of the face of the cyclopropane ring with electrophiles and on the interpretation of activation parameters for solvolytic reactions

D. G. Morris, R. Bergman, S. A. Sherrod, 1972 .

Rhodium alkoxide complexes : formation of an unusually strong intermolecular hydrogen bond in (PMe3)3Rh-Otol(HOtol)

S. Nolan, C. Hoff, R. Bergman, 1987 .

Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight.

J. Ellman, R. Bergman, Jared C. Lewis, 2008, Journal of the American Chemical Society.

Functionalization of an iridium–diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources

Allegra L. Liberman-Martin, Micah S. Ziegler, R. Bergman, 2016 .

The Mechanism of Addition of an Ir−OH bond to Ethylene. Catalytic Tandem Activation by Two [η5-Cp*(Ph)IrPMe3]+ Complex Fragments

R. Bergman, J. Ritter, 1997 .

Synthesis and reactivity of an iridium hydroxo complex. Insertion of ethylene into a metal-oxygen bond

K. Woerpel, R. Bergman, K. A. Woerpel, 1993 .

Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity.

L. Overman, R. Bergman, M. Watson, 2007, Journal of the American Chemical Society.

Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization.

J. Ellman, R. Bergman, Jared C. Lewis, 2004, Organic letters.

Synthesis of multicyclic pyridine and quinoline derivatives via intramolecular C-H bond functionalization.

J. Ellman, R. Bergman, Sirilata Yotphan, 2010, Organic letters.

Structural Factors that Influence the Course of Overall [2 + 2] Cycloaddition Reactions between Imidozirconocene Complexes and Heterocumulenes

R. Bergman, Rebecca L. Zuckerman and, 2000 .

Zirconium-mediated metathesis of imines: a study of the scope, longevity, and mechanism of a complicated catalytic system.

R. Bergman, S. Krska, R. Zuckerman, 2000, Journal of the American Chemical Society.

ENHANCEMENT OF A CHEMICAL REACTION RATE BY PROPER ORIENTATION OF REACTING MOLECULES IN THE SOLID STATE

C. Sukenik, N. Mandel, R. Bergman, 1975 .

Reactions of a Uranium(IV) Tertiary Alkyl Bond: Facile Ligand-Assisted Reduction and Insertion of Ethylene and Carbon Monoxide

M. Weydert, R. Bergman, R. Andersen, 1995 .

Reactions of uranium complex (MeC5H4)3U(t-Bu): intermolecular fluorine atom abstraction from fluorocarbons including saturated perfluorocarbons

M. Weydert, R. Bergman, R. Andersen, 1993 .

Phosphine-catalyzed hydration and hydroalkoxylation of activated olefins: use of a strong nucleophile to generate a strong base.

Ian C. Stewart, R. Bergman, F. Toste, 2003, Journal of the American Chemical Society.

Carbon-Carbon bond forming reactions of organotransition metal enolate complexes

R. Bergman, C. Heathcock, G. Slough, 1988 .

Stereoselective Alkylation of α,β-Unsaturated Imines via C-H Bond Activation

J. Ellman, R. Bergman, D. A. Colby, 2006 .

Synthesis of a tricyclic mescaline analogue by catalytic C-H bond activation.

J. Ellman, R. Bergman, K. Ahrendt, 2003, Organic letters.

Formation of planar-chiral alkylphosphine- and aniline-substituted cyclopentadienyl metal complexes and their reactivity toward electrophiles

R. Bergman, G. Lavoie, S. N. Paisner, 2002 .

Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and β-diketiminato ligands.

R. Bergman, J. Arnold, N. Tomson, 2011, Dalton transactions.

Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)Nb(III) Imido Complexes.

R. Bergman, J. Arnold, N. Tomson, 2010, Organometallics.

Platinum-catalyzed phenyl and methyl group transfer from tin to iridium: evidence for an autocatalytic reaction pathway with an unusual preference for methyl transfer.

R. Bergman, Jennifer M Sasaki, R. Finke, 2008, Journal of the American Chemical Society.

Synthesis and reactivity of (pentamethylcyclopentadienyl)iridium bis(thiolate) and thiolate hydride complexes

R. Bergman, D. P. Klein, G. Kloster, 1990 .

Carbon-hydrogen insertion and .pi.-complex formation reactions of (.eta.5-C5Me5)(PMe3)Ir with ethylene: an intra- and intermolecular isotope effect study

R. Bergman, P. Stoutland, 1988 .

Synthesis of an (.eta.3-allyl)(hydrido)iridium complex and its reactions with arenes and alkanes. Sequential intermolecular carbon-hydrogen oxidative addition and hydride-to-alkene migratory insertion reactions

R. Bergman, W. D. Mcghee, 1988 .

Synthesis, insertion and reductive elimination reactions of a hydrido(alkoxy)iridium complex

R. Bergman, L. J. Newman, 1985 .

Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium β-Diketiminate Complex.

R. Bergman, Trevor D. Lohrey, J. Arnold, 2016, Inorganic chemistry.

Carbon-carbon bond formation in dinuclear dialkyl complexes. Reactions of [CpCo(CO)R]2 (R = methyl, ethyl, or 2,2,2-trifluoroethyl) and (C11H10)Co2(CO)2(CH3)2 with carbon monoxide and triphenylphosphine

M. A. White, N. Schore, R. Bergman, 1984 .

Substitution, alkyl-transfer, and thermal decomposition reactions of .eta.5-cyclopentadienyl(triphenylphosphine)dimethylcobalt(III)

R. Bergman, E. R. Evitt, 1980 .

Synthesis, structure, and reactivity of a monomeric pentamethylcyclopentadienyliridium(III) imido complex

R. Bergman, F. Hollander, David S. Glueck, 1989 .

Synthesis and Redox Chemistry of a Tantalum Alkylidene Complex Bearing a Metallaimidazole Ring

R. Bergman, R. Chatterjee, N. Kaltsoyannis, 2017 .

Synthesis, Structures, and Kinetics and Mechanism of Decomposition of Terminal Metal Azide Complexes: Isolated Intermediates in the Formation of Imidometal Complexes from Organic Azides

R. Bergman, G. Proulx, 1996 .

Synthesis and Structure of a Terminal Metal Azide Complex: An Isolated Intermediate in the Formation of Imidometal Complexes from Organic Azides

R. Bergman, G. Proulx, 1995 .

X-ray Crystal Structures of Cp*Ni(PEt3)X [X = Br, O(p-C6H4Me), NH(p-C6H4Me), S(p-C6H4Me), OCH3, CH2C6H5, Me, H, PEt3+]. Understanding Distortions and Trans Influences in Cyclopentadienyl Complexes

P. Holland, Michael E. Smith, R. Bergman, 1997 .

Stereoselective Synthesis of Chiral Zirconocenes from Doubly Substituted, Donor Functionalized Cyclopentadienes via Helical Chelate Complexes

J. Christoffers, R. Bergman, 1995 .

Unusual κ1 coordination of a β-diketiminate ligand in niobium complexes.

R. Bergman, J. Arnold, J. Ziegler, 2016, Dalton transactions.

Generation of low-valent tantalum species by reversible C-H activation in a cyclometallated tantalum hydride complex.

R. Bergman, J. Arnold, Benjamin M Kriegel, 2014, Dalton transactions.

Diniobium inverted sandwich complexes with μ-η6:η6-arene ligands: synthesis, kinetics of formation, and electronic structure.

T. Tyliszczak, D. Shuh, A. Kilcoyne, 2013, Journal of the American Chemical Society.

Use of group 4 bis(sulfonamido) complexes in the intramolecular hydroamination of alkynes and allenes.

R. Bergman, L. Ackermann, Rebecca N. Loy, 2003, Journal of the American Chemical Society.

Synthesis of Novel Group 4 Complexes Bearing the Tropidinyl Ligand: Investigations of Dynamic Behavior, Reactivity, and Catalytic Olefin Polymerization

R. Bergman, C. Mateo, S. Skoog, 2000 .

Synthesis, Structural Characterization, and Reactivity of Novel Zirconium(IV) Complexes Containing the Tropidinyl Ligand

R. Bergman, G. Lavoie, 1997 .

COOPERATIVE REACTIVITY IN THE INTERACTIONS OF X-H BONDS WITH A ZIRCONIUM-IRIDIUM BRIDGING IMIDO COMPLEX

A. Baranger, R. Bergman, 1994 .

Synthesis of an early-late heterobimetallic imido complex: cooperative reactivity with nitrogen-, oxygen-, and sulfur-hydrogen bonds and formation of a novel aminophosphine complex

A. Baranger, R. Bergman, F. Hollander, 1993 .

Scope and mechanism of alkene hydrogenation/isomerization catalyzed by complexes of the type R2E(CH2)2M(CO)(L) (R = Cp, Me, Ph; E = phosphorus, tantalum; M = rhodium, iridium; L = CO, PPh3)

R. Bergman, M. Hostetler, M. Butts, 1993 .

Biaryl Reductive Elimination Is Dramatically Accelerated by Remote Lewis Acid Binding to a 2,2′-Bipyrimidyl–Platinum Complex: Evidence for a Bidentate Ligand Dissociation Mechanism

Daniel S. Levine, Allegra L. Liberman-Martin, Wenjun Liu, 2016 .

Zirconocene-alumoxane (1:1) — a catalyst for the selective dimerization of α-olefins

J. Christoffers, R. Bergman, 1998 .

Insertion of iridium into the carbon-hydrogen bonds of alkenes: the .pi.-complex cannot be an intermediate

R. Bergman, P. Stoutland, 1985 .

Stoichiometric and catalytic H/D incorporation by cationic iridium complexes: a common monohydrido-iridium intermediate.

R. Bergman, M. Skaddan, Cathleen M. Yung, 2004, Journal of the American Chemical Society.

Iridium-catalyzed H/D exchange into organic compounds in water.

R. Bergman, T. Tilley, S. R. Klei, 2002, Journal of the American Chemical Society.

Synthesis and Reactivity of the First Structurally Characterized Heterobimetallic Complex Containing an Unsupported Bridging Sulfur Atom

R. Bergman, J. Kovacs, 1989 .

Mechanism, regiochemistry, and stereochemistry of the insertion reaction of alkynes with methyl(2,4-pentanedionato)(triphenylphosphine)nickel. A cis insertion that leads to trans kinetic products

J. M. Huggins, R. Bergman, 1981 .

Comparison of the Relative Electron-Donating Abilities of Hydridotris(pyrazolyl)borate and Cyclopentadienyl Ligands: Different Interactions with Different Transition Metals

D. Tellers, T. Gunnoe, R. Bergman, 2000 .

Zirconium-mediated conversion of amides to nitriles: a surprising additive effect.

Rebecca T. Ruck, R. Bergman, 2004, Angewandte Chemie.

Stoichiometric and catalytic deuterium and tritium labeling of "unactivated" organic substrates with cationic Ir(III) complexes.

R. Bergman, M. Skaddan, Cathleen M. Yung, 2004, Organic letters.

Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline.

J. Ellman, R. Bergman, Sean H. Wiedemann, 2006, The Journal of organic chemistry.

Cp*MoO2Cl-catalyzed epoxidation of olefins by alkyl hydroperoxides

R. Bergman, M. Trost, 1991 .

Synthesis and chemistry of a dinuclear iridium bis-.mu.-oxo complex. Observation of oxygen transfer and phosphorus-carbon bond cleavage

R. Bergman, W. D. Mcghee, F. Hollander, 1988 .

Reactive 1,4-dehydroaromatics

Robert G. Bergman, R. Bergman, 1973 .

p-Benzyne. Generation as an intermediate in a thermal isomerization reaction and trapping evidence for the 1,4-benzenediyl structure

Robert G. Bergman, R. Bergman, Richard R. M. Jones, 1972 .

Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes.

J. Ellman, R. Bergman, Sean H. Wiedemann, 2004, Organic letters.

Chapter 8: Selective Stoichiometric and Catalytic Reactivity in the Confines of a Chiral Supramolecular Assembly

Michael D. Pluth, K. Raymond, R. Bergman, 2007 .

Rh(I)-catalyzed direct arylation of azines.

J. Ellman, R. Bergman, A. M. Berman, 2010, The Journal of organic chemistry.

Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: a dramatic effect of counteranions on reaction efficiency.

R. Bergman, J. Arnold, Laura L. Anderson, 2005, Journal of the American Chemical Society.

A highly reactive titanium precatalyst for intramolecular hydroamination reactions.

R. Bergman, L. Ackermann, 2002, Organic letters.

Generation, alkyne cycloaddition, arene carbon-hydrogen activation, nitrogen-hydrogen activation and dative ligand trapping reactions of the first monomeric imidozirconocene (Cp2Zr:NR) complexes

P. Walsh, R. Bergman, F. Hollander, 1988 .

An iridium difluoroketene complex: synthesis and isolation.

J. Cordaro, R. Bergman, H. van Halbeek, 2004, Angewandte Chemie.

Catalytic hydroamination of alkynes and norbornene with neutral and cationic tantalum imido complexes.

R. Bergman, J. Arnold, Laura L. Anderson, 2004, Organic letters.

Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors

R. Bergman, F. Toste, A. DiPasquale, 2014, Organometallics.

Preparation and reactivity of terminal gold(I) amides and phosphides

R. Bergman, F. Toste, Sophia L Shevick, 2013 .

Synthesis and reactions of nickel and palladium carbon-bound enolate complexes

R. Bergman, C. Heathcock, E. Burkhardt, 1990 .

Synthesis of .eta.1 oxygen-bound rhodium enolates. Applications to catalytic aldol chemistry

R. Bergman, C. Heathcock, G. Slough, 1989 .

Tungsten and molybdenum 2-oxaallyl [.eta.1-(C)-enolate] complexes: functional group transformations, photochemical aldol reactions, and alkyne/carbon monoxide migratory insertion reactions

R. Bergman, C. Heathcock, E. Burkhardt, 1987 .

Synthesis, structure, and carbon-carbon bond-forming reactions of carbon-bound molybdenum, tungsten, and rhenium enolates. Detection of an .eta.3-oxaallyl intermediate

R. Bergman, C. Heathcock, J. J. Doney, 1985 .

Adduct Formation and Single and Double Deprotonation of Cp*(PMe3)Ir(H)2 with Main Group Metal Alkyls and Aryls: Synthesis and Structure of Three Novel Ir−Al and Ir−Mg Heterobimetallics

Patrick L. Holland, P. Holland, R. Bergman, 1998 .

Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids.

J. Ellman, R. Bergman, Joshua R. Hummel, 2016, The Journal of organic chemistry.

Enantioselective oxidation of di-tert-butyl disulfide with a vanadium catalyst: progress toward mechanism elucidation.

J. Ellman, R. Bergman, S. Blum, 2003, The Journal of organic chemistry.

Living ring-opening polymerization of N-sulfonylaziridines: synthesis of high molecular weight linear polyamines.

R. Bergman, Cameron C. Lee, F. Toste, 2005, Journal of the American Chemical Society.

Synthesis of potent bicyclic bisarylimidazole c-Jun N-terminal kinase inhibitors by catalytic C-H bond activation.

P. Lograsso, J. Ellman, R. Bergman, 2007, Journal of the American Chemical Society.

Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I).

J. Ellman, R. Bergman, Jared C. Lewis, 2006, Journal of the American Chemical Society.

Intermediacy of an N-heterocyclic carbene complex in the catalytic C-H activation of a substituted benzimidazole.

K. Tan, J. Ellman, R. Bergman, 2002, Journal of the American Chemical Society.

Analysis of an unprecedented mechanism for the catalytic hydrosilylation of carbonyl compounds.

Michael D. Pluth, R. Bergman, F. Toste, 2007, Journal of the American Chemical Society.

Variable regiochemistry in the stoichiometric and catalytic hydroamination of alkynes by imidozirconium complexes caused by an unusual dependence of the rate law on alkyne structure and temperature

A. Baranger, P. Walsh, R. Bergman, 1993 .

Stoichiometric and catalytic hydroamination of alkynes and allene by zirconium bisamides Cp2Zr(NHR)2

A. Baranger, P. Walsh, R. Bergman, 1992 .

C-H oxidative addition and reductive elimination reactions in a dinuclear iridium complex

R. Bergman, W. D. Mcghee, F. Hollander, 1988 .

Reaction of alkynes with a methylnickel complex: observation of a cis insertion mechanism capable of giving kinetically controlled trans products

J. M. Huggins, R. Bergman, 1979 .

Silica as a Ligand: Reactivity of the Iridium-Oxygen Bond of Cp*Ir[silica](Ph)(PMe3)

K. Woerpel, R. Bergman, T. Meyer, 1994 .

Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound.

Allegra L. Liberman-Martin, R. Bergman, T. Tilley, 2015, Journal of the American Chemical Society.

The mechanism of hydroamination of allenes, alkynes, and alkenes catalyzed by cyclopentadienyltitanium-imido complexes: a density functional study.

R. Bergman, B. Straub, 2001, Angewandte Chemie.

Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: a dramatic effect of counteranions on reaction efficiency.

R. Bergman, J. Arnold, Laura L. Anderson, 2005, Journal of the American Chemical Society.

Microwave-assisted C-H bond activation: a rapid entry into functionalized heterocycles.

K. Tan, A. Vasudevan, A. Souers, 2003, Organic letters.

DOUBLE GROUP TRANSFER REACTIONS OF AN UNSATURATED TANTALUM METHYLIDENE COMPLEX WITH PYRIDINE N-OXIDES

R. Bergman, J. Arnold, S. M. Mullins, 1999 .

Reactions of Cp2Ta(CH2)(CH3) with Substituted and Unsubstituted Metal Carbonyls (Groups 7, 8, and 9). Evidence for Intermediates Involved in the Carbon−Carbon Bond-Forming Steps of the Reduction and Deoxygenation of CO

R. Bergman, G. Proulx, 1996 .

Reaction of a Tantalum Alkylidene Complex with Dinuclear Metal Carbonyls: Formation of C3 ligands

R. Bergman, G. Proulx, 1993, Science.

Mechanistic investigations of the acid-catalyzed cyclization of a vinyl ortho-quinone methide.

Lee M. Bishop, K. Houk, D. Trauner, 2008, Chemistry.

Asymmetric Catalytic Synthesis of P‐Stereogenic Phosphines via a Nucleophilic Ruthenium Phosphido Complex.

R. Bergman, F. Toste, I. Stewart, 2006 .

Safe Preparation and Purification of Sodium Tetrakis[(3,5-trifluoromethyl)phenyl]borate (NaBArF24): Reliable and Sensitive Analysis of Water in Solutions of Fluorinated Tetraarylborates

R. Bergman, N. Yakelis, Neal A. Yakelis, 2005 .

Deprotonation of the Transition Metal Hydride (η5-C5Me5)(PMe3)IrH2. Synthesis and Chemistry of the Strongly Basic Lithium Iridate (η5-C5Me5)(PMe3)Ir(H)(Li)

R. Bergman, T. H. Peterson, J. T. Golden, 1999 .

The Use of a Planar Chiral Ligand to Effect C−H Activation with Asymmetric Induction at an Iridium Center. Dramatically Different C−H Activation Stereoselectivities for Benzene and Cyclohexane

R. Bergman, T. A. Mobley, 1998 .

Synthesis of trimethylphosphine-substituted (pentamethylcyclopentadienyl)iridium hydride complexes; protonation and deprotonation of (pentamethylcyclopentadienyl)(trimethylphosphine)iridium dihydride

R. Bergman, T. Gilbert, 1985 .

C−C and C−H Bond Activation at Ruthenium(II): The Stepwise Degradation of a Neopentyl Ligand to a Trimethylenemethane Ligand

K. McNeill, R. Bergman, A. B. A. Andersen, 1997 .

Zirconium Bis(Amido) Catalysts for Asymmetric Intramolecular Alkene Hydroamination.

R. Bergman, D. Watson, Melanie Chiu, 2006, Organometallics.

Synthesis, structure, and carbon-carbon bond-forming reactions of carbon-bound molybdenum, tungsten, and rhenium enolates. Detection of an .eta.3-oxaallyl intermediate

R. Bergman, C. Heathcock, J. J. Doney, 1985 .

Synthesis of tantalum fluoride complexes supported by bis(trimethylsilyl)benzamidinate ligands. X-ray structures of [PhC(NSiMe3)2]2TaF3 and [PhC(NSiMe3)2]2TaFPh2

R. Bergman, J. Arnold, J. Hagadorn, 2000 .

Catalytic Dimerization Reactions of α-Olefins and α,ω-Dienes with Cp2ZrCl2/Poly(methylalumoxane): Formation of Dimers, Carbocycles, and Oligomers

J. Christoffers, R. Bergman, 1996 .

Intramolecular B−H Bond Activation from a Dihydridobis(dimethylpyrazolyl)borate Ligand: Formation of a Rhodium(III) Carbene Hydride and a Rare Example of Reverse α-Hydride Migration

R. Bergman, Jake S. Yeston and, 2000 .

Synthesis and reactions of monomeric late transition metal alkoxo, aryloxo and hydroxo complexes

R. Bergman, 1995 .

Dissociation of carbanions from acyl iridium compounds: an experimental and computational investigation.

J. Cordaro, R. Bergman, 2004, Journal of the American Chemical Society.

Mechanistic Investigation of the Reaction of Iridium Dihydride Complexes with Organic Acid Chlorides

R. Bergman, A. Burger, S. N. Paisner, 2000 .

A Useful Method for Preparing Iridium Alkoxides and a Study of Their Catalytic Decomposition by Iridium Cations: A New Mode of β-Hydride Elimination for Coordinatively Saturated Metal Alkoxides

R. Bergman, J. Ritter, 1998 .

M. A. White, N. Schore, R. Bergman, 1984 .

C-H Insertion and π-Complex Formation Reactions of (η5-C5Me5)(PMe3)Ir with Ethylene: An Intra- and Intermolecular Isotope Effect Study.

R. Bergman, P. Stoutland, 1988 .

Synthesis of an (η3-Allyl)(hydrido)iridium Complex and Its Reactions with Arenes and Alkanes. Sequential Intermolecular C-H Oxidative Addition and Hydride-to-Alkene Migratory Insertion Reactions.

R. Bergman, W. D. Mcghee, 1988 .

Preparation and reactions of tetrahydrido (pentamethylcyclopentadienyl)iridium: a novel iridium(V) polyhydride

R. Bergman, T. Gilbert, 1983 .

Synthesis, Structure, and Hydrosilylation Catalysis of a Chiral A-Frame Rhodium(I) Dimer with Cis Diphosphite Ligands

A. Oliver, R. Bergman, Santiago Ini, 2001 .

Synthesis, Characterization, and Reactivity of Aluminum Alkyl/Amide Complexes Supported by Guanidinate and Monoanionic OCO-Pincer Ligands

R. Bergman, Jürgen Koller, 2010 .

Mechanistic study of the oxidative coupling of styrene with 2-phenylpyridine derivatives catalyzed by cationic rhodium(III) via C-H activation.

J. Ellman, R. Bergman, J. Cámpora, 2013, Journal of the American Chemical Society.

One-step synthesis of benzocyclobutenes involving cooligomerization of linear mono- and diacetylenes catalyzed by .eta.5-cyclopentadienylcobalt dicarbonyl

K. Vollhardt, R. Bergman, 1974 .

Hydroalkoxylation catalyzed by a gold(I) complex encapsulated in a supramolecular host.

Z Jane Wang, F Dean Toste, K. Raymond, 2011, Journal of the American Chemical Society.

Engendering reactivity at group 5-heteroatom multiple bonds via π-loading

R. Bergman, J. Arnold, Jade I. Fostvedt, 2022, Chemical science.

[3 + 2] Cycloadditions and Retrocycloadditions of Niobium Imido Complexes: An Experimental and Computational Mechanistic Study.

David W. Small, R. Bergman, J. Arnold, 2022, Inorganic chemistry.

1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes†

R. Bergman, Trevor D. Lohrey, J. Arnold, 2020, Chemical science.

Synthesis of an Iron Parent Amido Complex and a Comparison of Its Reactivity with the Ruthenium Analog

R. Bergman, Daniel J. Fox and, 2004 .

A supramolecular approach to combining enzymatic and transition metal catalysis

Z Jane Wang, F Dean Toste, K. Raymond, 2013, Nature Chemistry.

Reactivity of alkyne tungsten and molybdenum complexes. Heterolytic carbon-hydrogen bond activation in coordinated alkynes

R. Bergman, P. L. Watson, 1980 .

Synthesis of [RuCl2(NO)2(THF)] and its double C-N bond-forming reactions with alkenes.

R. Bergman, Mark R. Crimmin, F. Toste, 2011, Angewandte Chemie.

Regio- and stereoselective 1,2-dihydropyridine alkylation/addition sequence for the synthesis of piperidines with quaternary centers.

Simon Duttwyler, J. Ellman, B. Mercado, 2014, Angewandte Chemie.

Reproducibility in Chemical Research.

R. Bergman, Robert G Bergman, Rick L Danheiser, 2016, Angewandte Chemie.

Enantioselective intramolecular hydroarylation of alkenes via directed C-H bond activation.

J. Ellman, R. Bergman, H. Harada, 2008, The Journal of organic chemistry.

Redox-Initiated Reactivity of Dinuclear β-Diketiminatoniobium Imido Complexes.

R. Bergman, K. Lakshmi, G. Nocton, 2017, Inorganic chemistry.

REACTIONS OF AN IMIDOZIRCONOCENE COMPLEX WITH CYCLOPENTADIENYLMETAL CARBONYL COMPLEXES. C-H ACTIVATION VERSUS OXYGEN ATOM ABSTRACTION

R. Bergman, Sun Yeoul Lee, 1995 .

Cycloaddition and Cycloreversion Reactions of a Monomeric Ti(IV) Oxo Complex with Terminal and Internal Alkynes. A Reversible Oxametallacyclobutene/Hydroxoacetylide Interconversion

R. Bergman, R. Andersen, Jennifer L. Polse, 1995 .

Formation of .alpha.,.beta.-Unsaturated Imines and Successful Trapping of Oxozirconocene in a [4 + 2] Azaoxametallacyclohexene Retrocycloaddition

A. Baranger, P. Walsh, R. Bergman, 1995 .

A Mechanistic Study of the Cycloaddition-Cycloreversion Reactions of Zirconium-Imido Complex Cp2Zr(N-t-Bu)(THF) with Organic Imines and Organic Azides

P. Walsh, R. Bergman, K. Meyer, 1995 .

Monomeric and dimeric zirconocene imido compounds: synthesis, structure, and reactivity

P. Walsh, R. Bergman, F. Hollander, 1993 .

Generation of the highly reactive intermediates Cp*2Zr:O and Cp*2Zr:S: trapping reactions with alkynes, nitriles, and dative ligands

P. Walsh, R. Bergman, M. Carney, 1992 .

A reactive organometallic oxo intermediate, Cp*2Zr=O: generation and subsequent trapping reactions forming alkyne and nitrile addition products

P. Walsh, R. Bergman, M. Carney, 1989 .

Synthesis, exchange reactions, and metallacycle formation in osmium(II) imido systems: formation and cleavage of osmium-nitrogen bonds

R. Bergman, R. Andersen, R. I. Michelman, 1993 .

Monomeric (pentamethylcyclopentadienyl)iridium imido compounds : synthesis, structure, and reactivity

R. Bergman, F. Hollander, David S. Glueck, 1991 .

Selective transformations of organic compounds by imidozirconocene complexes.

R. Bergman, A. P. Duncan, Andrew P. Duncan, 2002, Chemical record.

Carbon-carbon bond activation of R-CN (R = Me, Ar, iPr, tBu) using a cationic Rh(III) complex.

Felicia L. Taw, R. Bergman, P. White, 2002, Journal of the American Chemical Society.

Rearrangements and stereomutations of metallacycles derived from allenes and imidozirconium complexes.

R. Bergman, Z. Sweeney, F. Michael, 2005, Journal of the American Chemical Society.

Synthesis of an η2-N2-Titanium Diazoalkane Complex with Both Imido- and Metal Carbene-Like Reactivity Patterns

R. Bergman, R. Andersen, Jennifer L. Polse, 1998 .

Synthesis, Structure, and Reactivity Studies of an η2-N2-Titanium Diazoalkane Complex. Generation and Trapping of a Carbene Complex Intermediate

R. Bergman, R. Andersen, Jennifer L. Polse, 1996 .

Synthesis of chiral, enantiopure zirconocene imido complexes: highly selective kinetic resolution and stereoinversion of allenes, and evidence for a stepwise cycloaddition/retrocycloaddition reaction mechanism.

R. Bergman, R. Andersen, Z. Sweeney, 2000, Angewandte Chemie.

Stereospecific double alkylation of diphenylacetylene by .eta.5-cyclopentadienyl(triphenylphosphine)dimethylcobalt(III). Evidence for noninterconvertible diastereomeric complexes in cobalt-catalyzed isomerization of alkenes, and comments on factors effecting rates of reductive elimination reactions

R. Bergman, E. R. Evitt, 1978 .

Evidence for the reactive spin state of 1,4-dehydrobenzenes

T. P. Lockhart, R. Bergman, 1981 .

Chiral amide directed assembly of a diastereo- and enantiopure supramolecular host and its application to enantioselective catalysis of neutral substrates.

Chen Zhao, F Dean Toste, Chen Zhao, 2013, Journal of the American Chemical Society.

Preagostic Rh−H Interactions and C−H Bond Functionalization: A Combined Experimental and Theoretical Investigation of Rhodium(I) Phosphinite Complexes

J. Ellman, R. Bergman, Jessica Y. Wu, 2005 .

Cyclopropylmethyl/cyclobutyl rearrangements on surfaces: evidence for transient cation formation near O-covered Mo(110).

C. Friend, R. Bergman, D. Kang, 2007, Journal of the American Chemical Society.

Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis

Simon Duttwyler, J. Ellman, R. Bergman, 2013, Science.

Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives.

R. Bergman, F. Toste, N. Mankad, 2014, Angewandte Chemie.

Unexpected C-C bond cleavage and C-C bond formation observed in the reaction of a cationic iridium complex with heteroatom-substituted cyclopropanes.

R. Bergman, M. Anstey, Juana Du, 2007, Journal of the American Chemical Society.

Generation and rearrangements of the 1-cyclopropylvinyl cation. Comparison of the intermediates formed upon ionization of 1-cyclopropyl-1-iodoethylene and 3,4-pentadien-1-yl iodide

R. Bergman, S. A. Sherrod, 1971 .

Application of the extended Hueckel molecular orbital method to the properties of vinyl cations. Conformational energies of some 1-cyclopropylvinyl cations and a comparison of SN2 displacements at saturated and vinyl carbon

R. Bergman, D. R. Kelsey, 1971 .

Stereochemistry of solvolytic displacement at vinyl carbon. Reactions of 1-cyclopropyl-2-methylvinyl cations formed on silver-catalyzed ionization of cis- and trans-1-cyclopropyl-1-iodopropenes and 3,4-hexadien-1-yl iodide

R. Bergman, D. R. Kelsey, 1971 .

Synthesis and absolute configurations of some optically active cis- and trans-1,2-disubstituted cyclopropanes

R. Bergman, 1969 .

Synthesis and solvolysis of 1-cyclopropyl-1-iodoethylene. Generation of an unusually stable vinyl cation

R. Bergman, S. A. Sherrod, 1969 .

Inversion component in the solvolytic displacement reactions of alkyl-substituted vinyl trifluoromethanesulfonates

R. Bergman, T. Clarke, D. R. Kelsey, 1972 .

Olefinic cyclization at a vinyl cation center. Inversion preference for intramolecular nucleophilic substitution by a double bond

R. Bergman, T. Clarke, 1972 .

Kinetically linear vinyl cations in the solvolysis of stereoisomeric 1-iodo-1-cyclopropylpropenes

R. Bergman, D. R. Kelsey, 1970 .

A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex.

Allegra L. Liberman-Martin, R. Bergman, T. Tilley, 2013, Journal of the American Chemical Society.

Synthesis and investigation of [Cp(PMe(3))Rh(H)(H(2))](+) and its partially deuterated and tritiated isotopomers: evidence for a hydride/dihydrogen structure.

Felicia L. Taw, R. Bergman, P. White, 2002, Journal of the American Chemical Society.

NMR Shifts, Orbitals, and M···H−X Bonding in d8 Square Planar Metal Complexes

E. Oldfield, J. Ellman, R. Bergman, 2006 .

Time-resolved IR spectroscopy in liquid rare gases: direct rate measurement of an intermolecular alkane carbon-hydrogen oxidative addition reaction

B. H. Weiller, E. Wasserman, C. Moore, 1989 .

Electron acceptors promote proton-hydride tautomerism in low valent rhenium β-diketiminates.

R. Bergman, Trevor D. Lohrey, J. Arnold, 2020, Chemical communications.

Kinetic control and multiple mechanisms for C-H bond activation by a Zr=N complex.

R. Bergman, Helen M. Hoyt, 2007, Angewandte Chemie.

Stoichiometric carbon–carbon bond formation mediated by well defined Nb(III) complexes

R. Bergman, J. Arnold, T. Gianetti, 2014 .

Synthesis, crystal and molecular structure, and reactions of a benzodicobaltacyclohexene, a thermally derived mononuclear o-xylylene complex, and an unsymmetrical phosphine-derived dinuclear complex

R. Bergman, F. Hollander, W. Hersh, 1983 .

Parallel reaction pathways in the cobalt-catalyzed cyclotrimerization of acetylenes

D. R. Mcalister, J. Bercaw, R. Bergman, 1977 .

Synthesis of a highly reactive (benzyne)ruthenium complex: C-C, C-H, N-H, and O-H activation reactions

J. Hartwig, R. Bergman, R. Andersen, 1989 .

Carboamination: additions of imine C=N bonds across alkynes catalyzed by imidozirconium complexes.

Rebecca T. Ruck, R. Bergman, S. Krska, 2004, Angewandte Chemie.

Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes.

Rebecca T. Ruck, R. Bergman, 2004, Organometallics.

Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C-H bond activation.

J. Ellman, R. Bergman, Rebecca M. Wilson, 2009, Chemical communications.

Enantioselective synthesis of a PKC inhibitor via catalytic C-H bond activation.

J. Ellman, R. Bergman, Rebecca M. Wilson, 2006, Organic letters.

Highly efficient and enantioselective cyclization of aromatic imines via directed C-H bond activation.

J. Ellman, R. Bergman, R. Thalji, 2004, Journal of the American Chemical Society.

Asymmetric Synthesis of α-Branched Amines via Rh(III)-Catalyzed C–H Bond Functionalization

J. Ellman, R. Bergman, Apiwat Wangweerawong, 2014, Journal of the American Chemical Society.

Mechanism of the rhodium(III)-catalyzed arylation of imines via C-H bond functionalization: inhibition by substrate.

C. Incarvito, A. Rheingold, J. Ellman, 2012, Journal of the American Chemical Society.

Reaction of a bridged binuclear dialkylcobalt complex with carbon monoxide and phosphines. Observation of competing inter- and intramolecular metal to metal methyl transfer

R. Bergman, H. E. Bryndza, 1979 .

Double Cycloaromatization of (Z,Z)-Deca-3,7-diene-1,5,9-triyne: Evidence for the Intermediacy and Diradical Character of 2,6- Didehydronaphthalene.

R. Minto, R. Bergman, K. Bharucha, 1992 .

Structure, synthesis, and chemistry of ruthenium complex (PMe3)4Ru(.eta.2-benzyne). Reactions with arenes, alkenes, and heteroatom-containing organic compounds. Synthesis and structure of a monomeric hydroxide complex

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Supramolecular Ga4L6(12-) Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer.

R. Mathies, K. Raymond, R. Bergman, 2015, Journal of the American Chemical Society.

The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations† †Electronic supplementary information (ESI) available: Kinetics plots are available free of charge. See DOI: 10.1039/c4sc02735c Click here for additional data file.

Chen Zhao, K. Raymond, R. Bergman, 2014, Chemical science.

Insertion of (.eta.5-C5Me5)(PMe3)Ir into the carbon-hydrogen bonds of functionalized organic molecules: a C-H activation route to 2-oxa- and 2-azametallacyclobutanes, potential models for olefin oxidation intermediates

R. Bergman, D. P. Klein, J. Hayes, 1988 .

1,2,3,4,5‐Pentamethylcyclopentadiene

J. Bercaw, P. Seidler, J. Stryker, 2003 .

Carbon monoxide, isocyanide, and nitrile complexes of cationic, d(0) vanadium bisimides: π-back bonding derived from the π symmetry, bonding metal bisimido ligand orbitals.

R. Bergman, F. Toste, H. L. La Pierre, 2012, Inorganic chemistry.

Scope and mechanism of formal S(N)2' substitution reactions of a monomeric imidozirconium complex with allylic electrophiles.

R. Bergman, G. Lalic, J. Krinsky, 2008, Journal of the American Chemical Society.

Zirconium-mediated SN2' substitution of allylic ethers: regio- and stereospecific formation of protected allylic amines.

R. Bergman, G. Lalic, S. Blum, 2005, Journal of the American Chemical Society.

Catalytic C-O bond cleavage of 2-aryloxy-1-arylethanols and its application to the depolymerization of lignin-related polymers.

Lee M. Bishop, J. Ellman, R. Bergman, 2010, Journal of the American Chemical Society.

D. Peters, P. J. Alaimo, R. Bergman, 2001 .

The Stereochemistry of Vicinal Hydride Shift in the 3-Methyl-2-norbornyl Cation. Evidence for the Nonclassical Structure1

R. Bergman, J. A. Berson, A. Remanick, 1965 .

Highly Efficient Aluminum-Catalyzed Hydro-amination/-hydrazination of Carbodiimides

R. Bergman, Jürgen Koller, 2010 .

Controlled Hydrosilylation of Carbonyls and Imines Catalyzed by a Cationic Aluminum Alkyl Complex

R. Bergman, Jürgen Koller, 2012 .

Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis.

David M. Kaphan, K. Raymond, R. Bergman, 2016, Journal of the American Chemical Society.

Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.

Robert G. Bergman, Michael D. Pluth, Kenneth N. Raymond, 2010, Journal of the American Chemical Society.

Addition of Organic 1,3‐Dipolar Compounds across a Heterobinuclear Bond between Early and Late Transition Metals: Mechanism of Nitrogen Loss from an Organoazido Complex To Form a Bridging Imido Complex

A. Baranger, R. Bergman, T. Hanna, 1996 .

Iridium(III) and Rhodium(III) Complexes Bearing Chelating Cyclopentadienyl−Phosphine Ligands as C−H Activation Catalysts for the Deuteration of Hydrocarbons in D2O

R. Bergman, T. Tilley, S. R. Klei, 2002 .

Exceptionally low-temperature carbon--hydrogen/carbon--deuterium exchange reactions of organic and organometallic compounds catalyzed by the Cp*(PMe(3))IrH(ClCH(2)Cl)(+) cation.

R. Bergman, R. Andersen, J. T. Golden, 2001, Journal of the American Chemical Society.

Mechanism and regiochemistry of azametallacyclobutene formation from imidozirconocene complexes and alkynes

R. Bergman, Sun Yeoul Lee, 1995 .

Synthesis, Structural Investigation, and Reactivity of Neutral and Cationic Bis(guanidinato)zirconium(IV) Complexes

R. Bergman, A. Arnold, A. P. Duncan, 2001 .

Synthesis and reactivity of the monomeric late-transition-metal parent amido complex [Ir(Cp*)(PMe3)(Ph)(NH2)].

R. Bergman, Daniela Rais, 2004, Chemistry.

Scope and mechanism of the C-H bond activation reactivity within a supramolecular host by an iridium guest: a stepwise ion pair guest dissociation mechanism.

K. Raymond, R. Bergman, D. Leung, 2006, Journal of the American Chemical Society.

Thermal reactivity of Group 9 transition metal pinacolate complexes: heterocumulene cleavage and CO bond formation

R. Bergman, Andrew W. Holland, 2002 .

Stoichiometric and Catalytic Behavior of Cationic Silyl and Silylene Complexes

R. Bergman, S. R. Klei, and T. Don Tilley, 2002 .

The mechanism of silicon-hydrogen and carbon-hydrogen bond activation by iridium(III): Production of a silylene complex and the first direct observation of Ir(III)/Ir(V) C-H bond oxidative addition and reductive elimination

R. Bergman, T. Tilley, S. R. Klei, 2000 .

Synthesis of metallacyclopentanes containing two metals in the ring. Thermal decomposition to cyclopropane and ligand-induced conversion to stable mononuclear metallacyclopentanones

R. Bergman, K. Theopold, 1980 .

Zirconium-Mediated Imine Metathesis. Synthesis of 2,4-Diaza-1-zirconiacyclobutanes and the Mechanism of Their Reactions with Imines and Alkynes

P. Walsh, R. Bergman, K. Meyer, 1994 .

Generation of Oxozirconocene Complexes from the Reaction of Cp2(THF)ZrN-t-Bu with Organic and Metal Carbonyl Functionalities: Apparently Divergent Behavior of Transient [Cp2ZrO]

R. Bergman, Sun Yeoul Lee, 1996 .

Cobalt-mediated [3 + 2]-annulation reaction of alkenes with alpha,beta-unsaturated ketones and imines.

J. Schomaker, R. Bergman, F. Toste, 2009, Organic letters.

Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins.

Ian C. Stewart, J. Schomaker, R. Bergman, 2008, Journal of the American Chemical Society.

Highly Efficient Aluminum-Catalyzed Ring-Opening Polymerization of Cyclic Carbonates, Lactones, and Lactides, Including a Unique Crystallographic Snapshot of an Intermediate

R. Bergman, Jürgen Koller, 2011 .

The mechanism of hydroamination of allenes, alkynes, and alkenes catalyzed by cyclopentadienyltitanium-imido complexes: a density functional study.

R. Bergman, B. Straub, 2001, Angewandte Chemie.

Generation and trapping of the diphenylhydrazido(2-) complex Cp2Zr(N2Ph2). Insertion of internal alkynes into a metal-nitrogen bond, leading to 2,3-diazametallacyclopentenes

P. Walsh, R. Bergman, F. Hollander, 1990 .

Erratum: Catalytic hydroamination of alkynes and norbornene with neutral and cationic tantalum imido complexes (Organic Letters (2004) 6 (2519))

R. Bergman, J. Arnold, Laura L. Anderson, 2006 .

C-H bond activation of hydrocarbons by an imidozirconocene complex.

R. Bergman, Helen M. Hoyt, F. Michael, 2004, Journal of the American Chemical Society.

Effects of phosphine ligand chelation on the reactivity of monomeric parent amido ruthenium complexes: synthesis and reactivity of such a complex bearing monodentate ligands.

R. Bergman, Andrew W. Holland, 2002, Journal of the American Chemical Society.

CARBON-CARBON BOND CLEAVAGE AND IMINOCARBENE FORMATION IN THE THERMAL DECOMPOSITION OF 2H-AZIRINES

R. Bergman, L. A. Wendling, 1974 .

Synthesis of an optically active cyclopropene and kinetics of its thermal racemization in the gas phase. Intermediacy of a vinylcarbene

E. York, R. Bergman, W. Dittmar, 1973 .

Synthesis and cyclization reactions of alkynyl (.eta.5-cyclopentadienyltricarbonylmolybdenum and -tungsten) complexes

R. Bergman, P. L. Watson, 1979 .

Synthesis, Structure, and Reactivity of η2-N2-Aryldiazoalkane Titanium Complexes: Cleavage of the N−N Bond

G. Ball, R. Bergman, Jennifer L. Polse, 1998 .

Highly selective supramolecular catalyzed allylic alcohol isomerization.

K. Raymond, R. Bergman, D. Leung, 2007, Journal of the American Chemical Society.

A phosphorus-carbon bond cleavage reaction of coordinated trimethylphosphine in (PMe3)4Ru(OC6H4Me)2

J. Hartwig, R. Bergman, R. Andersen, 1990 .

Nitrous Oxide Mediated Oxygen Atom Insertion into a Ruthenium−Hydride Bond. Synthesis and Reactivity of the Monomeric Hydroxoruthenium Complex (DMPE)2Ru(H)(OH)

R. Bergman, Anne W. Kaplan and, 1997 .

H2 Activation and Direct Access to Terminal Nitride and cyclo-P3 Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate.

G. Rao, R. D. Britt, R. Bergman, 2019, Inorganic chemistry.

Heterotetrametallic Re-Zn-Zn-Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate.

R. Bergman, L. Maron, Trevor D. Lohrey, 2019, Journal of the American Chemical Society.

Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.

J. Ellman, R. Bergman, Mikaël Brasse, 2011, Organic letters.

Synthesis and chemistry of ruthenium hydrido aryloxides and arylamides. An investigation of structure, nitrogen-hydrogen and oxygen-hydrogen elimination processes, proton-catalyzed exchange reactions, and relative Ru-X bond strengths

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Preparation of monomeric (.eta.6-arene)OsNR complexes and their exchange reactions with amines, alcohols, and thiols

R. Bergman, R. Andersen, R. I. Michelman, 1991 .

Synthetic and Mechanistic Studies of Strained Heterocycle Opening Reactions Mediated by Zirconium(IV) Imido Complexes.

Rebecca T. Ruck, R. Bergman, S. Blum, 2005, Organometallics.

Epoxide-opening and group-transfer reactions mediated by monomeric zirconium imido complexes.

P. Walsh, R. Bergman, S. Blum, 2003, Journal of the American Chemical Society.

Synthesis of Alkyltantalocene Oxide, Sulfide, and Imide Derivatives: Stereospecific Heteroatom and -group Transfers from Oxiranes, Thiiranes, and Aziridines to Methyltantalocene

R. Bergman, G. Proulx, 1996 .

Stereospecific Heteroatom and Hetero Group Transfer from Oxiranes, Thiiranes, and Aziridines by a Simple Alkyl Tantalocene

R. Bergman, G. Proulx, 1994 .

Synthesis and characterization of [(.eta.5-C5H5)V(CO)3H]-, a new anionic vanadium carbonyl hydride, and a study of its reduction reaction with organic halides. Observation of a free-radical chain process having an extremely rapid metal-to-carbon hydrogen transfer step

R. Bergman, W. Jones, R. J. Kinney, 1978 .

Synthesis and Reactivity of Bridging Imido and Imido-Oxo Complexes of Iridium. Water-Catalyzed and -Uncatalyzed Dimerization of Terminal Iridium Imido Complexes

R. Bergman, D. Dobbs, 1994 .

Tantalum-Mediated Cleavage of an NN Bond in an Organic Diazene (Azoarene) To Produce an Imidometal (MNR) Complex: An η2-Diazene Complex Is Not an Intermediate.

R. Bergman, M. A. Aubart, 1999 .

Inter- and intramolecular carbon-hydrogen bond forming and cleavage reactivity of two different types of poly(trimethylphosphine)ruthenium intermediates

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Reactivity of a titanium dinitrogen complex supported by guanidinate ligands: investigation of solution behavior and a novel rearrangement of guanidinate ligands.

R. Bergman, J. Arnold, A. P. Duncan, 2001, Inorganic chemistry.

Nucleophilic substitution catalyzed by a supramolecular cavity proceeds with retention of absolute stereochemistry.

Chen Zhao, F Dean Toste, Chen Zhao, 2014, Journal of the American Chemical Society.

Asymmetric induction in reactions employing enolates generated from cyclic organo transition metal acyl complexes

R. Bergman, K. Theopold, P. Becker, 1982 .

Photochemistry of η5 cylclopentadienylcobalt) tricarbonyl, tris(η5-cyclopentadienylcobalt monocarbonyl) and tetra(η5-cyclopentadienylcobalt) dicarbonyl*

K. Peter, C. Vollhardt, J. Bercaw, 1975 .

Competition between sulfur extrusion and thermal synthesis of thienocyclobutadiene in the pyrolysis of cis- and trans-1,2-diethynylthiiranes. Dimerization of the rearrangement product to bisthienocyclooctatetraene

K. Vollhardt, R. Bergman, 1973 .

Reaction of η5-cyclopentadienylbis(triphenylphosphine)cobalt(I) with alkadiynes. Preparation and reactions of bicyclic cobalt metallocycles and a stable trimethylsilyl-substituted mono-complexed alkadiyne. Comments on the mechanism of cobalt-catalyzed alkyne cooligomerization

R. Bergman, E. R. Evitt, L. P. M. Bushnell, 1978 .

Synthesis and reactions of (.eta.5-cyclopentadienyl)tricarbonylhydridovanadate. A comparative mechanistic study of its organic halide reduction reactions with those of tri-n-butyltin hydride

R. Bergman, W. Jones, R. J. Kinney, 1978 .

Binuclear Metallacycles: Organometallic Ring Systems Containing Two Metal Centers

R. Bergman, K. Theopold, W. Hersh, 1982 .

An x-ray photoelectron spectroscopic study of transition metal .mu.-methylene complexes and related compounds

C. Eyermann, W. L. Jolly, R. Bergman, 1982 .

Synthesis, molecular structure, and thermal chemistry of (.eta.5-cyclopentadienyl)dicarbonylrhenacyclopentane

R. Bergman, G. K. Yang, Gilbert K. Yang, 1985 .

Characterization and evidence for alkylation of hydridodicarbonylcyclopentadienylrhenate(1-) ion [CpRe(CO)2H-] in the conversion of dihydrodicarbonylcyclopentadienylrhenium [CpRe(CO)2H2] to CpRe(CO)2R2. Synthesis of a rhenacyclopentane and its thermolysis to methylcyclopropane

R. Bergman, G. K. Yang, 1983 .

Proton-mediated chemistry and catalysis in a self-assembled supramolecular host.

Robert G. Bergman, Michael D. Pluth, Kenneth N. Raymond, 2009, Accounts of chemical research.

Reversible CH activation of an N-methyl group in a bis-Zr(IV) diazametallacycle: generation of an end-on, side-on coordinated bridging alkylideneamido ligand

R. Bergman, S. Krska, R. Zuckerman, 1999 .

Synthesis and reactivity of Cp2Ta(CH2)2Ir-CO)2 : an early-late heterobimetallic complex that catalytically hydrogenates, isomerizes, and hydrosilates alkenes

R. Bergman, M. Hostetler, 1990 .

Mechanisms of allene stereoinversion by imidozirconium complexes.

R. Bergman, Z. Sweeney, F. Michael, 2003, Journal of the American Chemical Society.

Mechanistic Investigation of Cycloreversion/Cycloaddition Reactions between Zirconocene Metallacycle Complexes and Unsaturated Organic Substrates.

R. Bergman, R. Zuckerman, 2001, Organometallics.

Use of Steric Hindrance and a Metallacyclobutene Resting State to Develop Robust and Kinetically Characterizable Zirconium-Based Imine Metathesis Catalysts

R. Bergman, S. Krska, R. Zuckerman, 1998 .

Reactivity of Zirconocene Azametallacyclobutenes: Insertion of Aldehydes, Carbon Monoxide, and Formation of alpha,beta-Unsaturated Imines. Formation and Trapping of [Cp(2)Zr=O] in a [4 + 2] Retrocycloaddition(1).

A. Baranger, R. Bergman, T. Hanna, 1996, The Journal of organic chemistry.

Aromatic and aldehyde carbon-hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C-H oxidative addition

Felicia L. Taw, R. Bergman, M. Brookhart, 2004 .

A transition-metal-based method for 1,2-diamination of alkenes. Synthesis of cobalt dinitrosoalkanes from alkenes, nitric oxide, and (.eta.5-cyclopentadienyl)(nitrosyl)cobalt dimer and their reduction to primary vicinal diamines

R. Bergman, P. Becker, 1983 .

A new method for 1,2-diamination of alkenes using cyclopentadienylnitrosylcobalt dimer/NO/LiAlH4

M. A. White, R. Bergman, P. Becker, 1980 .

Regio- and Diastereoselective Synthesis of Highly Substituted, Oxygenated Piperidines from Tetrahydropyridines.

J. Ellman, B. Mercado, R. Bergman, 2015, The Journal of organic chemistry.

Rhodium-Catalyzed Direct C—H Addition of 3,4-Dihydroquinazolines to Alkenes and Their Use in the Total Synthesis of Vasicoline.

J. Ellman, R. Bergman, Sean H. Wiedemann, 2006 .

Annulation of aromatic imines via directed C-H bond activation.

J. Ellman, R. Bergman, R. Thalji, 2005, The Journal of organic chemistry.

A Nanovessel-Catalyzed Three-Component Aza-Darzens Reaction.

K. Raymond, R. Bergman, F. Toste, 2020, Journal of the American Chemical Society.

A Dramatic Difference in the Reactivities of Alkoxido‐ and Aryloxidorhenium Complexes in Insertion Reactions

R. Bergman, R. D. Simpson, 1992 .

Chemical reduction of .eta.5-cyclopentadienyldicarbonylrhodium. Crystal and molecular structure of an anionic trinuclear rhodium cluster with "semi-triple-bridging" carbonyl ligands

M. A. White, R. Bergman, W. Jones, 1978 .

Chemical and electrochemical reduction of .eta.5-cyclopentadienyldicarbonylcobalt(I) and .eta.5-cyclopentadienyl(triphenylphosphine)carbonylcobalt(I). Synthesis, crystal structure, and chemistry of sodium and bis(triphenylphosphine)iminium bis(.eta.5-cyclopentadienyl)di-.mu.-carbonyl-dicobaltate

N. Schore, R. Bergman, C. S. Ilenda, 1977 .

Isolation of unstable bis(.eta.5-cyclopentadienylcobalt) tricarbonyl from the irradiation of .eta.5-cyclopentadienylcobalt dicarbonyl. Thermal reactions of this binuclear complex leading to starting material and trinuclear and tetranuclear cobalt(I) complexes

K. Vollhardt, J. Bercaw, R. Bergman, 1974 .

Synthesis and reactions of a binuclear cobalt bridging methylene (.mu.-CH2) complex. Conversion to .mu.-CH2 rhodium/cobalt and rhodium/rhodium complexes and methylene transfer to ethylene involving activation by a second metal complex

R. Bergman, K. Theopold, 1981 .

A kinetic and x-ray diffraction study of the solid state rearrangement of methyl p-dimethylaminobenzenesulfonate. Reaction rate enhancement due to proper orientation in a crystal

C. Sukenik, N. Mandel, R. Bergman, 1977 .

Vanadium bisimide bonding investigated by X-ray crystallography, 51V and 13C nuclear magnetic resonance spectroscopy, and V L(3,2)-edge X-ray absorption near-edge structure spectroscopy.

T. Tyliszczak, D. Shuh, R. Bergman, 2013, Inorganic chemistry.

Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the beta-Diketiminato Ligand.

R. Bergman, J. Arnold, N. Tomson, 2010, Organometallics.

An unusally diverse array of products formed upon carbonylation of a dialkylniobium complex.

R. Bergman, J. Arnold, N. Tomson, 2008, Journal of the American Chemical Society.

Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes.

R. Bergman, J. Arnold, Benjamin M Kriegel, 2016, Journal of the American Chemical Society.

Regioselective [2+2] and [4+2] cycloaddition reactivity in an asymmetric niobium(bisimido) moiety towards unsaturated organic molecules.

R. Bergman, J. Arnold, T. Gianetti, 2015, Chemical communications.

COMPARATIVE REACTIVITIES OF TWO ISOELECTRONIC TRANSITION METAL HYDRIDES WITH TRANSITION METAL CARBONYLS AND ALKYLS

J. M. Huggins, R. Bergman, W. Jones, 2013 .

Synthesis and reaction chemistry of a new class of .mu.-alkylidene dicobalt complexes. Crystal and molecular structure of (.mu.-methylene)bis[.eta.5-(methylcyclopentadienyl)carbonylcobalt]

R. Bergman, K. Theopold, 1983 .

Synthesis, crystal and molecular structure, and reactions of the bridging vinylidenedicobalt complex (.mu.-CCH2)(CpCoCO)2. Reaction with molybdenum hydrides to give a heteronuclear cluster complex

E. Jacobsen, R. Bergman, 1984 .

Structure and reactions of oxametallacyclobutanes and oxametallacyclobutenes of ruthenium

J. Hartwig, R. Bergman, R. Andersen, 1991 .

A supramolecular microenvironment strategy for transition metal catalysis

David M. Kaphan, Robert G. Bergman, F. Dean Toste, 2015, Science.

Origins of large rate enhancements in the Nazarov cyclization catalyzed by supramolecular encapsulation.

K. Raymond, R. Bergman, Courtney J. Hastings, 2014, Chemistry.

Stabilization of reactive organometallic intermediates inside a self-assembled nanoscale host.

D. Fiedler, K. Raymond, R. Bergman, 2006, Angewandte Chemie.

Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts.

K. Raymond, R. Bergman, F. Toste, 2018, Accounts of chemical research.

A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length.

K. Raymond, R. Bergman, F. Toste, 2019, Journal of the American Chemical Society.

Conformational Selection as the Mechanism of Guest Binding in a Flexible Supramolecular Host.

David M. Kaphan, K. Raymond, R. Bergman, 2017, Journal of the American Chemical Society.

Selective monoterpene-like cyclization reactions achieved by water exclusion from reactive intermediates in a supramolecular catalyst.

F Dean Toste, K. Raymond, R. Bergman, 2012, Journal of the American Chemical Society.

Encapsulated guest-host dynamics: guest rotational barriers and tumbling as a probe of host interior cavity space.

K. Raymond, R. Bergman, J. Mugridge, 2010, Journal of the American Chemical Society.

Structural consequences of anionic host-cationic guest interactions in a supramolecular assembly.

Michael D. Pluth, A. Oliver, S. Teat, 2009, Inorganic chemistry.

The hydrophobic effect drives the recognition of hydrocarbons by an anionic metal-ligand cluster.

Shannon M. Biros, K. Raymond, R. Bergman, 2007, Journal of the American Chemical Society.

Complete determination of the stereochemistry of a 3,5-dialkylpyrazoline thermal decomposition. Synthesis, absolute configuration, and pyrolysis of (+)-(3R,5R)- and (+)-(3R,5S)-3-ethyl-5-methyl-1-pyrazolines

R. Bergman, T. Clarke, L. A. Wendling, 1977 .

Solvent and pressure effects on the motions of encapsulated guests: tuning the flexibility of a supramolecular host.

Jeffrey S. Mugridge, Achim Zahl, Rudi van Eldik, 2013, Journal of the American Chemical Society.

Highly selective supramolecular catalyzed allylic alcohol isomerization.

K. Raymond, R. Bergman, D. Leung, 2007, Journal of the American Chemical Society.

Supramolecular catalysis of unimolecular rearrangements: substrate scope and mechanistic insights.

D. Fiedler, K. Raymond, R. Bergman, 2006, Journal of the American Chemical Society.

Impact of Host Flexibility on Selectivity in a Supramolecular Host-Catalyzed Enantioselective aza-Darzens Reaction.

K. Raymond, Nicholas S. Settineri, R. Bergman, 2022, Journal of the American Chemical Society.

Does size really matter? The steric isotope effect in a supramolecular host-guest exchange reaction.

K. Raymond, R. Bergman, J. Mugridge, 2010, Angewandte Chemie.

Spectroscopic, Magnetic, and Computational Investigations on a Series of Rhenium(III) Cyclopentadienide diketiminate Halide and Pseudohalide Complexes

R. Bergman, L. Maron, Trevor D. Lohrey, 2021, Organometallics.

Inter- and intramolecular insertion of rhenium into carbon-hydrogen bonds

R. Bergman, T. Wenzel, 1986 .

Synthesis and comparative chemistry of the early-late transition metal heterobimetallacycles CpCp′Ta(CH2)2Ir(CO)(L) and their main-group element-late transition metal analogues R2P(CH2)2Ir(CO)(L)

R. Bergman, M. Hostetler, M. Butts, 1992 .

METHANE-PRODUCING HYDROGENOLYSIS OF (n5 -CYCLOPENTADIENYL) - (TRIPHENYLPHOSPHINE)DIMETHYLCOBALT(III). AN AUTOCATALYTIC MECHANISM INVOLVING A BINUCLEAR METAL DIHYDRIDE/METAL DIALKYL REACTION AS A CRITICAL STEP

A. Janowicz, R. Bergman, 1981 .

Reactions of (.eta.5-cyclopentadienyl)cobalt(III) alkyls with cobalt(I) phosphines and iron carbonyls. Evidence for direct .eta.5-cyclopentadienyl and trimethylphosphine group transfer between metal centers

R. Bergman, H. E. Bryndza, 1980 .

REVERSIBLE METAL-TO-METAL METHYL TRANSFER IN n5-CYCLOPENTADIENYL(TRIPHENYLPHOSPHINE)DIMETHYLCOBALT(III)

R. Bergman, E. R. Evitt, H. E. Bryndza, 1980 .

Intramolecular Double C-H Activation in FvM 2 (en) 4 (Fv=fulvalene; M=Ir, Rh; en=ethylene)

Jin Ho Kim, K. Vollhardt, R. Bergman, 2004 .

Synthesis of trimethylphosphine-substituted (pentamethylcyclopentadienyl)iridium hydride complexes; protonation and deprotonation of (pentamethylcyclopentadienyl)(trimethylphosphine)iridium dihydride

R. Bergman, T. Gilbert, 1985 .

(Pentamethylcyclopentadienyl)iridium polyhydride complexes: synthesis of intermediates in the mechanism of formation of (pentamethylcyclopentadienyl)iridium tetrahydride and the preparation of several iridium(V) compounds

R. Bergman, T. Gilbert, F. Hollander, 1985 .

Synthesis of bridging iridium bis(imido) and imido-oxo complexes. Imide and oxygen transfer reactions and hydrogenation of an imido ligand

R. Bergman, D. Dobbs, 1993 .

PHOSPHINE SUBSTITUTION IN n5-CYCLOPENTADIENYL-BIS-TRIPHENYLPHOSPHINECOBALT (I): EVIDENCE FOR A DISSOCIATIVE MECHANISM

A. Janowicz, R. Bergman, H. E. Bryndza, 1981 .

A Diverse Array of C-C Bonds Formed at a Tantalum Metal Center.

R. Bergman, J. Arnold, Michael A. Boreen, 2021, Inorganic chemistry.

Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand.

Daniel S. Levine, Allegra L. Liberman-Martin, Micah S. Ziegler, 2016, Chemical communications.

Unusual Ar-H/Rh-H J(HH) NMR coupling in complexes of rhodium(III): experimental evidence and theoretical support for an eta1-arene structure.

U. Rothlisberger, A. Magistrato, R. Bergman, 2004, Journal of the American Chemical Society.

Enthalpy-entropy compensation reveals solvent reorganization as a driving force for supramolecular encapsulation in water.

K. Raymond, R. Bergman, D. Leung, 2008, Journal of the American Chemical Society.

Synthesis of monomeric ruthenium hydroxo complexes (PMe3)4Ru(R)(OH) (R = H, Me) and a unique dimeric ruthenium hydroxo-water complex [trans-Ru(H)(OH)(DMPE)2.cntdot.H2O]2

J. Hartwig, R. Bergman, F. Hollander, 1993 .

Synthesis and reactions of a dimetallacyclohexene. Thermal conversion to an o-xylylene complex and phosphine-induced conversion to free o-xylylene and a new reactive dinuclear cobalt complex

R. Bergman, W. Hersh, 1981 .

Inter- and intramolecular oxidative addition of phosphine, methane, alkane, and alkene carbon-hydrogen bonds to rhenium

P. Seidler, R. Bergman, T. Wenzel, 1985 .

[(TMEDA)Co(NO)2][BPh4]: A versatile synthetic entry point to four and five coordinate {Co(NO)2}10 complexes

K. Wieghardt, R. Bergman, Mark R. Crimmin, 2011 .

Inter- and intramolecular oxidative addition of phosphine, methane, alkane, and alkene carbon-hydrogen bonds to rhenium

P. Seidler, R. Bergman, T. Wenzel, 1985 .

Synthesis of trinuclear alkylidyne complexes from dinuclear alkyne complexes and metal hydrides. CIDNP evidence for vinyl radical intermediates in the hydrogenolysis of these clusters

J. Frommer, P. Seidler, R. Bergman, 1983 .

Rate and equilibrium study of the reversible oxidative addition of silanes to the iridium center in Cp2Ta(.mu.-CH2)2Ir(CO)2 and of alkene hydrosilylation/isomerization catalyzed by this system

R. Bergman, M. Hostetler, M. Butts, 1993 .

Application of the E-C Approach to Understanding the Bond Energies Thermodynamics of Late-Metal Amido, Aryloxo and Alkoxo Complexes: An Alternative to pπ/dπ Repulsion

Patrick L. Holland, P. Holland, R. Bergman, 1999 .

Cyclopentadienyl and Imide Ligand Transfer from Zirconium to Iridium: Can Early Transition Metal Imido Compounds Be Used as Imide Transfer Reagents?

P. Holland, R. Bergman, R. Andersen, 1998 .

Heteroatom exchange reactions in imidoosmium(II) systems : cleavage of Os-N multiple bonds and formation of Os-X bonds (X = O, S, C)

G. Ball, R. Bergman, R. Andersen, 1994 .

Computational Study of Methane Activation by TpRe(CO)2 and CpRe(CO)2 with a Stereoelectronic Comparison of Cyclopentadienyl and Scorpionate Ligands

Thomas R. Klinckman, T. Cundari, T. Gunnoe, 2003 .

Binding of chlorohydrocarbons to metal centers: quantitative evaluation of relative binding constants and structural characterization of the first isolable transition metal-chloromethane adduct.

D. Tellers, R. Bergman, 2001, Journal of the American Chemical Society.

SYNTHESIS AND CHEMISTRY OF A BRIDGING VINYLIDENEDICOBALT COMPLEX. EVIDENCE FOR A NONCHAIN RADICAL MECHANISM IN ITS REACTION WITH METAL HYDRIDES TO GIV HETERONUCLEAR CLUSTERS

E. Jacobsen, R. Bergman, 1985 .

A rational synthesis of organometallic bridging sulfur dimers and their conversion into homo- and heterometallic cubane complexes. Evidence for a mechanism involving dimerization of doubly unsaturated dinuclear intermediates

R. Bergman, D. Dobbs, 1992 .

Direct observation of alkyl/nitrosyl migratory insertion in an organotransition metal complex

M. A. White, R. Bergman, W. Weiner, 1981 .

Some problems in the oxidative addition and binding of an ethylene to a transition-metal center

R. Hoffmann, R. Bergman, P. Stoutland, 1986 .

Synthesis, structure, and exchange reactions of rhenium alkoxide and aryloxide complexes. Evidence for both proton and hydrogen atom transfer in the exchange transition state

R. Bergman, R. D. Simpson, 1993 .

An Observable Silene/Silylene Rearrangement in a Cationic Iridium Complex

R. Bergman, S. R. Klei, and T. Don Tilley, 2001 .

Synthesis, X-ray Structure Determination, and Reactions of (Pentamethylcyclopentadienyl)(nitrosyl)ruthenium η2-Arene Complexes

R. Bergman, Christopher D. Tagge, 1996 .

Facile Activation of Triarylboranes by Rhenium(V) Oxo Imido Complexes.

R. Bergman, Trevor D. Lohrey, J. Arnold, 2020, Inorganic chemistry.

Olefination and group transfer reactions of an electron deficient tantalum methylidene complex.

R. Bergman, J. Arnold, S. M. Mullins, 2006, Dalton transactions.

Silicon−Hydrogen Bond Activation and Formation of Silane Complexes Using a Cationic Rhodium(III) Complex

Felicia L. Taw, R. Bergman, M. Brookhart, 2004 .

Reactions of Cp*(PMe3)Ir(Me)OTf with Silanes: Role of Base-Free Silylene Complexes in Rearrangements of the Resulting Silicon-Based Ligands

R. Bergman, T. Tilley, S. R. Klei, 2002 .

Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal-carbon bonds.

R. Bergman, Trevor D. Lohrey, J. Arnold, 2019, Chemical communications.

Mechanistic Investigations of Cp-Loss Reactions in an Early-Late Heterobimetallic Complex. Isolation of a Cationic Tantalum-Palladium Compound with a Free Cyclopentadienyl Counteranion

R. Bergman, M. Butts, 1994 .

New routes to transition metal-carbido species: synthesis and characterization of the carbon-centered trigonal prismatic clusters [W(6)CCl(18)](n)(-) (n = 1, 2, 3).

J. Long, R. Bergman, N. Crawford, 2003, Journal of the American Chemical Society.

Synthesis and chemistry of a bridging vinylidenedicobalt complex. Evidence for a nonchain radical mechanism in its reaction with metal hydrides to give heteronuclear clusters

E. Jacobsen, R. Bergman, 1985 .

Use of isotope crossover experiments in investigating carbon-carbon bond-forming reactions of binuclear dialkylcobalt complexes

R. Bergman, 1980 .

Late Transition-Metal Sulfido Complexes: Reactivity Studies and Mechanistic Analysis of Their Conversion into Metal-Sulfur Cubane Complexes

R. Bergman, D. Dobbs, 1994 .

Platinum Group Thiophenoxyimine Complexes: Syntheses and Crystallographic/Computational Studies

R. Bergman, J. Krinsky, A. Arnold, 2007 .

Interconversion of a 3,3-Dimethylruthenacyclobutane and a Methyl(2-methallyl)ruthenium Complex: The First Direct Observation of Reversible .beta.-Methyl Elimination/Migratory Insertion

K. McNeill, R. Bergman, R. Andersen, 1995 .

Oxygen- and carbon-bound ruthenium enolates: migratory insertion, reductive elimination, .beta.-hydrogen elimination, and cyclometalation reactions

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Mechanism of the carbon-carbon cleavage of acetone by the ruthenium benzyne complex (PMe3)4Ru(.eta.2-C6H4): formation and reactivity of an oxametallacyclobutane complex

J. Hartwig, R. Bergman, R. Andersen, 1990 .

Generation, dative ligand trapping, and nitrogen-nitrogen bond cleavage reactions of the first monomeric .eta.1-hydrazido zirconocene complex, (Cp2Zr:NNPh2). A zirconium mediated synthesis of indoles

P. Walsh, R. Bergman, M. Carney, 1991 .

Direct evidence for solvent coordination in migratory CO insertion

M. Wax, R. Bergman, 1981 .

Mechanism of the reaction between organo transition metal alkyls and hydrides. A model for the aldehyde-forming step in the oxo process

R. Bergman, W. Jones, 1979 .

A structural, kinetic and thermodynamic study of the reversible thermal carbon-hydrogen bond activation/reductive elimination of alkanes at iridium

J. M. Buchanan, J. Stryker, R. Bergman, 1986 .

Vinylmethylene and the ring opening of cyclopropene. Ab initio generalized valence bond and configuration interaction studies

W. Goddard, James H. Davis, R. Bergman, 1976 .

Electrophilic cleavage of rhenium-oxygen bonds by Broensted and Lewis acids

R. Bergman, R. D. Simpson, 1992 .

Rapid racemization of an optically active cyclopropene derivative via ring opening, bond rotation, and ring closure

E. York, R. Bergman, W. Dittmar, 1972 .

Chemistry of methylnorbornyl cations. VI. The stereochemistry of vicinal hydride shift. Evidence for the nonclassical structure of 3-methyl-2-norbornyl cations

R. Bergman, J. A. Berson, A. Remanick, 1967 .

High-precision measurement of isotope effects on noncovalent host-guest interactions.

K. Raymond, R. Bergman, J. Mugridge, 2010, Journal of the American Chemical Society.

High performance liquid chromatography for facile analytical separation of the enantiomers of chiral organometallic complexes

R. Bergman, S. N. Paisner, 2001 .

Oxygen-centered hexatantalum tetradecaimido cluster complexes.

R. Bergman, J. Arnold, Laura L. Anderson, 2008, Inorganic chemistry.

Vinylmethylene: theoretical investigations

W. Goddard, James H. Davis, R. Bergman, 1977 .

The acid hydrolysis mechanism of acetals catalyzed by a supramolecular assembly in basic solution.

Michael D. Pluth, K. Raymond, R. Bergman, 2009, The Journal of organic chemistry.

Synthesis of a doubly alkylated binuclear cobalt carbonyl complex. Generation of acetone, a process involving the formation of two new carbon-carbon bonds, in its thermal decomposition

N. Schore, R. Bergman, C. S. Ilenda, 1976 .

Evidence for the Formation of Free 16-Electron Species Rather than Solvate Complexes in the Ultraviolet Irradiation of CpCo(CO)2 in Liquefied Noble Gas Solvents

C. Moore, R. Bergman, A. Bengali, 1995 .

IR flash kinetic spectroscopy of transients generated by irradiation of cyclopentadienylcobalt dicarbonyl in the gas phase and in solution.

E. Wasserman, C. Moore, R. Bergman, 1988, Journal of the American Chemical Society.

Theoretical study of the rhenium–alkane interaction in transition metal–alkane σ-complexes

Rustam Z. Khaliullin, M. Head‐Gordon, R. Z. Khaliullin, 2007, Proceedings of the National Academy of Sciences.

IR Flash Kinetic Spectroscopy of Transients Generated by Irradiation of (η5-C5H5)Co(CO)2 in the Gas Phase and in Solution.

E. Wasserman, C. Moore, R. Bergman, 1988 .

Detection of cyclobutadienocyclopentadienyl anion

R. Breslow, R. Bergman, W. Washburn, 1969 .

Multiple mechanisms in the thermal and photochemical decomposition of 2,3-diazabicyclo[3.1.0]hex-2-enes

R. Bergman, G. Hammond, David F. Aton, 1972 .

On the nature of diradical intermediates formed during the thermal and photochemical decomposition of bicyclic azo-compounds

R. Bergman, P. B. Condit, 1971 .

The synthesis of olefin, carbonyl and thiolate complexes of platinum(IV) in the [η5-C5Me5)Pt(IV)] system. Crystal and molecular structure of (η2-C5Me5)PtMe2[S(p-CH3(C6H4]

R. Bergman, W. A. Howard, 1998 .

A direct, biomass-based synthesis of benzoic acid: formic acid-mediated deoxygenation of the glucose-derived materials quinic acid and shikimic acid.

J. Ellman, R. Bergman, E. Arceo, 2010, ChemSusChem.

KINETIC EVIDENCE FOR THE FORMATION OF DISCRETE 1,4-DEHYDROBENZENE INTERMEDIATES. TRAPPING BY INTER- AND INTRAMOLECULAR HYDROGEN ATOM TRANSFER AND OBSERVATION OF HIGH-TEMPERATURE CIDNP

Robert G. Bergman, Paul B. Comita, Thomas P. Lockhart, 1981 .

The stereoselective formation of bicyclic enamines with bridgehead unsaturation via tandem C-H bond activation/alkenylation/electrocyclization.

J. Ellman, R. Bergman, Sirilata Yotphan, 2008, Journal of the American Chemical Society.

Synthesis of dialkylruthenium nitrosyls and thermal conversion to ruthenium oximate, carboxamide, and cyano complexes

R. Bergman, Mark D. Seidler, 1984 .

KINETICS AND MECHANISM OF THE FORMATION OF NITROSOALKANE COMPLEXES BY MIGRATORY INSERTION OF COORDINATED NITRIC OXIDE INTO COBALT-CARBON BONDS

R. Bergman, W. Weiner, 1983 .

Direct Michael addition of alkenes via a cobalt-dinitrosyl mediated vinylic C-H functionalization reaction.

Chen Zhao, R. Bergman, F. Toste, 2011, Journal of the American Chemical Society.

Cobalt-mediated, enantioselective synthesis of C(2) and C(1) dienes.

J. Schomaker, R. Bergman, Mark R. Crimmin, 2010, Journal of the American Chemical Society.

Synthesis of dialkyl- and alkyl(acyl)rhenium complexes by alkylation of anionic rhenium complexes at the metal center. Mechanism of a double carbonylation reaction that proceeds via the formation of free methyl radicals in solution

K. I. Goldberg, R. Bergman, 1989 .

Stereochemistry of olefinic cyclization and solvolytic displacement at vinyl carbon

R. Bergman, T. Clarke, 1974 .

Application of Daugulis copper-catalyzed direct arylation to the synthesis of 5-aryl benzotriazepines.

J. Ellman, R. Bergman, Sirilata Yotphan, 2009, Organic letters.

Formation of 1,4-pentadiene and vinylcyclopropane in the thermal and photochemical decomposition of 2,3-diazabicyclo[3.2.0]hept-2-ene

R. Bergman, D. White, P. B. Condit, 1972 .

Base-catalyzed rearrangement of 3-bromobicyclo[3.2.1]octa-2,6-diene to endo-6-ethynylbicyclo[3.1.0]hex-2-ene. Possible intermediacy of a homoconjugated carbene

R. Bergman, V. Rajadhyaksha, 1970 .

THE SYNTHESIS, ABSOLUTE CONFIGURATION, AND STEREOCHEMISTRY OF THERMAL DECOMPOSITION OF (+)-(3R,5R)- AND (+)-(3R,5S)-3-ETHYL-5-METHYL-1-PYRAZOLINES

R. Bergman, T. Clarke, L. A. Wendling, 1975 .

Evidence against the involvement of 0,0-diradical intermediates in the pyrolysis of five-membered ring azo compounds

R. Bergman, D. White, P. B. Condit, 1972 .

Chemistry of methylnorbornyl cations. I. Introduction and general survey

R. Bergman, J. A. Berson, A. Remanick, 1967 .

Enantioselective Kinetic Resolution/Desymmetrization of Para-Quinols: A Case Study in Boronic-Acid-Directed Phosphoric Acid Catalysis.

Ying He, R. Bergman, F. Toste, 2019, Advanced synthesis & catalysis.

Annulation of Aromatic Imines via Directed C—H Bond Activation.

J. Ellman, R. Bergman, R. Thalji, 2005 .

Reductive elimination leading to transient (.eta.5-C5Me5)Ru(NO). Trapping, dimerization and oxidative addition reactions of this intermediate and the effect of structural variation on its generation

R. Bergman, Jeffrey Chang, 1987 .

Reductive Elimination Leading to Transient (η5-C5Me5)Ru(NO). Trapping, Dimerization, and Oxidative Addition Reactions of This Intermediate and the Effect of Structural Variation on Its Generation.

R. Bergman, J. Chang, 1987 .

Synthesis and Chemistry of the Aryliridium(III) Fluorides Cp'Ir(PMe3)(Aryl)F: High Reactivity due to Surprisingly Easy Ir-F Ionization

R. Bergman, P. Burger, John E. Veltheer, 1995 .

Evidence for the reactive spin state of 1,4-dehydrobenzenes

T. P. Lockhart, R. Bergman, 1981 .

Chemistry of methylnorbornyl cations. III. Configurational correlation of 2,3- and 2,7-substituted norbornyl derivatives by way of 3-substituted nortricyclenes

R. Bergman, J. A. Berson, 1967 .

Chemistry of methylnorbornyl cations. II. Sources and identification of sixteen of the methylnorbornanols

R. Bergman, J. A. Berson, D. Houston, 1967 .

The consequences of σ and π conjugative interactions in mono‐, di‐ and triacetylenes. A photoelectron spectroscopic investigation

K. Vollhardt, E. Heilbronner, R. Bergman, 1975 .

An azo compound route to spiropentane thermolysis intermediates. Formation of vibrationally excited organic molecules in the thermal decomposition of pyrazolines, and evidence concerning the distribution of excess energy in reaction products

R. Bergman, K. Shen, 1977 .

LASER-POWERED HOMOGENEOUS DISSOCIATION OF TETRALIN

C. Moore, R. Bergman, P. Comita, 1981 .

Flow pyrolysis and direct and silicon tetrafluoride-sensitized laser-induced decomposition of tetralin. Identification of retro-[2 + 4] cleavage as the primary homogeneous thermal decomposition channel

C. Moore, R. Bergman, P. Comita, 1980 .

(N,N‐chelate)(Olefin) Platinum (O) Complexes

R. Bergman, F. Ruffo, A. Panunzi, 2007 .

Synthesis and thermal rearrangement of a potential butalene-anthracene adduct

G. C. Johnson, R. Bergman, 1979 .

Effect of surfactant micelles on the stereochemistry and rate of "amsylate" solvolytic displacement reactions in water

C. Sukenik, R. Bergman, 1976 .

Sub-Picosecond IR Study of the Reactive Intermediate in an Alkane C−H Bond Activation Reaction by CpRh(CO)2

J. Yeston, T. Lian, H. Ghosh, 1998 .

ULTRAFAST DYNAMICS OF CP*M(CO)2 (M = IR, RH) IN SOLUTION : THE ORIGIN OF THE LOW QUANTUM YIELDS FOR C-H BOND ACTIVATION

T. Lian, C. Harris, R. Bergman, 1996 .

Synthesis, structure and reactivity of (.eta.5-cyclopentadienyl)nitrosylcobalt

R. Bergman, F. Hollander, W. Weiner, 1984 .

Diastereomeric and isotopic scrambling in (hydrido)alkyliridium complexes. Evidence for the presence of a common `alkane complex` intermediate

R. Bergman, T. A. Mobley, C. Schade, 1995 .

Catalysis of 6pi electrocyclizations.

Lee M. Bishop, D. Trauner, R. Bergman, 2008, Angewandte Chemie.

Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature.

R. Bergman, T. Tilley, J. Suh, 2003, The Journal of organic chemistry.

Disambiguation of Metal and Brønsted Acid Catalyzed Pathways for Hydroarylation with Platinum(II) Catalysts

R. Bergman, T. Tilley, Miriam A. Bowring, 2011 .

Synthesis of Fischer Carbene Complexes of Iridium by C−H Bond Activation of Methyl and Cyclic Ethers: Evidence for Reversible α-Hydrogen Migration

R. Bergman, B. Arndtsen, P. Burger, 1996 .

Catalysis of 6p Electrocyclizations

Lee M. Bishop, D. Trauner, R. Bergman, 2008 .

Application of physical organic methods to the investigation of organometallic reaction mechanisms.

K. Tan, R. Bergman, S. Blum, 2003, The Journal of organic chemistry.

Kinetics of racemization and cis-trans isomerization of the optically active 1-ethyl-2-methylcyclopropanes in the gas phase. An estimate of relative rates of bond rotation and ring closure in diradical intermediates

R. Bergman, W. Carter, 1969 .

Photoelectron Spectra of 2,5-Dehydrotropylidene, 3,6-Dehydrooxepin, and Fulvenallene

W. Thiel, K. Vollhardt, A. Schweig, 1979 .

Activation of the C-H Bonds in Neopentane and Neopentane-d12 by (.eta.5-C5(CH3)5)Rh(CO)2: Spectroscopic and Temporal Resolution of Rhodium-Krypton and Rhodium-Alkane Complex Intermediates

C. Moore, R. Bergman, A. Bengali, 1994 .

THEORY AND APPLICATION OF PHOTOELECTRON SPECTROSCOPY. 80. PHOTOELECTRON SPECTRA OF 2,5-DEHYDROTROPYLIDENE, 3,6-DEHYDROOXEPIN, AND FULVENALLENE

W. Thiel, K. Vollhardt, A. Schweig, 1980 .

Stereochemistry of the Cope rearrangement and mechanism of thermal aromatization of 3,3'-bicyclopropenyls

James H. Davis, K. Shea, R. Bergman, 1977 .

Mechanisms of energy storage and release. Chemiluminescent valence isomerizations. Evidence for a Dewar benzene intermediate in a biscyclopropenyl to benzene rearrangement

N. Turro, James H. Davis, K. Shea, 1975 .

Reaction of Organic Disulfides with Cobalt-Centered Metal Radicals. Use of the E- and C-Based Dual-Parameter Substituent Model and Quantitative Solvent Effect Analyses To Compare Outer-Sphere and Inner-Sphere Electron-Transfer Processes

R. Bergman, Mark A. Aubart and, 1998 .

Cycloaddition and Nucleophilic Substitution Reactions of the Monomeric Titanocene Sulfido Complex (η5-C5Me5)2(C5H5N)TiS

R. Bergman, R. Andersen, Z. Sweeney, 1998 .

Organometallic CO substitution kinetics in liquid Xe by fast time-resolved IR spectroscopy

B. H. Weiller, E. Wasserman, C. Moore, 1993 .

Femtosecond IR Studies of Alkane C-H Bond Activation by Organometallic Compounds

Haw Yang, T. Lian, C. Harris, 1996, Ultrafast Phenomena.

Special team helps patients awaiting trial.

R. Bergman, 1972, Hospital & community psychiatry.

The Effect of Alkane Structure on Rates of Photoinduced C−H Bond Activation by Cp*Rh(CO)2 in Liquid Rare Gas Media: An Infrared Flash Kinetics Study

J. Yeston, B. McNamara, C. Moore, 1999 .

Reversible carbon-hydrogen bond insertion/reductive elimination in (.eta.5-pentamethylcyclopentadienyl)(trimethylphosphine)iridium complexes. Use in determining relative metal-carbon bond energies and thermally activating methane

J. M. Buchanan, C. Kovac, J. Stryker, 1984 .

Synthesis and C−H Activation Reactions of Cyclometalated Complexes of Ir(III): Cp*(PMe3)Ir(CH3)+Does Not Undergo Intermolecular C−H Activation in Solution via a Cyclometalated Intermediate

R. Bergman, Hans F. Luecke, 1997 .

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R. Bergman, 2012 .

Chemistry of methylnorbornyl cations. IV. Ratios of rates of nucleophilic capture of the cations at Wagner-Meerwein-related sites

R. Bergman, J. A. Berson, A. W. Mcrowe, 1967 .

Elimination of R-H from iridium acyl hydrides without loss of CO: evidence for the intervention of metal cation/carbanion pairs.

J. Cordaro, R. Bergman, 2004, Journal of the American Chemical Society.

Heterobimetallic-Mediated Dinitrogen Functionalization: N-C Bond Formation at Rhenium-Group 9 Diazenido Complexes.

R. Bergman, J. Arnold, Erik T Ouellette, 2022, Inorganic chemistry.

Activation of Organic Disulfides by a Paramagnetic Heterobimetallic Tantalum/Cobalt Complex and a Comparison of Their Reactions with Cobaltocene. Evidence for a Dependence of Mechanism on the Electronic Properties of the Disulfide

R. Bergman, M. A. Aubart, 1996 .

Reactivity of a parent amidoruthenium complex: a transition metal amide of exceptionally high basicity.

J. R. Fulton, R. Bergman, M W Bouwkamp, 2000, Journal of the American Chemical Society.

SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF LATE TRANSITION METAL PARENT AMIDO (LNM-NH2) COMPLEXES : AN ACID/CONJUGATE BASE METATHESIS APPROACH

R. Bergman, J. Ritter, A. Kaplan, 1998 .

Synthesis, structural characterization, and quantitative basicity studies of lithium zirconimidate complexes.

R. Bergman, H. van Halbeek, Melanie Chiu, 2008, Angewandte Chemie.

Conversion of epoxides to rhodium enolates: Direct evidence for a mechanism involving initial C-H activation

R. Bergman, Jianxin Wu, 1989 .

Conversion of Epoxides to Rhodium Enolates: Direct Evidence for a Mechanism Involving Initial C-H Activation.

R. Bergman, Jianxin Wu, 1990 .

3,6-dehydrooxepin, a furocyclobutadiene

K. Vollhardt, R. Bergman, 1972 .

Activation of carbon-hydrogen bonds in alkanes and other organic molecules using organotransition metal complexes

R. Bergman, 1991 .

Photochemical Reactivity of Group 9 Metal Pinacolate Complexes

R. Bergman, Andrew W. Holland, A. Glueck, 2001 .

Reductions of a Rhenium(III) Terminal Oxo Complex by Isocyanides and Carbon Monoxide

R. Bergman, Trevor D. Lohrey, J. Arnold, 2018, Organometallics.

Asymmetric synthesis of (-)-incarvillateine employing an intramolecular alkylation via Rh-catalyzed olefinic C-H bond activation.

J. Ellman, R. Bergman, A. Tsai, 2008, Journal of the American Chemical Society.

C-H bond activation by a rare cationic iridium dinitrogen complex. An important electronic effect in the chemistry of the hydridotris(pyrazolyl)borate ligand

D. Tellers, R. Bergman, 2000 .

The neighboring group effect of fluorine in the tritium labeling of organic substrates with [Cp*(PMe3)IrMe(CH2Cl2)]+[BArf]−, a cationic iridium(III) complex

R. Bergman, M. Skaddan, 2006 .

Mechanistic study of ligand substitution processes in TpIr(III) complexes

D. Tellers, R. Bergman, 2001 .

Examination of the hydrogen-bonding networks in small water clusters (n = 2-5, 13, 17) using absolutely localized molecular orbital energy decomposition analysis.

M. Head‐Gordon, Erika A Cobar, R. Bergman, 2012, Physical chemistry chemical physics : PCCP.

Rh(I)‐Catalyzed Alkylation of Quinolines and Pyridines via C—H Bond Activation.

J. Ellman, R. Bergman, Jared C. Lewis, 2007 .

Thermal conversion of 1-methyl-1,2-diethynylcyclopropane to 2-methylbicyclo[3.2.0]hepta-1,4,6-triene

R. Bergman, M. D'Amore, 1969 .

Synthesis, Structure, and Reactivity of the Remarkably Stable Early-Late Binuclear Metal Hydride Cp2Ta(.mu.-CH2)2Ir(Cp*)(H). A Warning Concerning Catalyst Identification in Homogeneous Catalytic Reactions

R. Bergman, M. Butts, 1994 .

Addendum to structure and reactivity of early-late heterobimetallic complexes.

R. Bergman, P. Kalck, N. Wheatley, 2001, Chemical reviews.

Synthesis of alkylruthenium nitrosyl complexes. Migratory insertion to coordinated nitric oxide and the mechanism of the conversion of the resultant nitrosoalkyl compounds to oximate, carboxamide, and cyano compounds

R. Bergman, Jeffrey Chang, Mark D. Seidler, 1989 .

Heats of Reaction of Cp*(PMe3)Ir(R)(H) (R: C6H5, C6H11, and H) with HCl, CCl4, CBr4, and CH3I. A Solution Thermochemical Study of the C-H Insertion Reaction.

S. Nolan, C. Hoff, J. M. Buchanan, 1987 .

Insertion reactions of carbon monoxide and carbon dioxide with ruthenium benzyl, arylamido, and aryloxide complexes: a comparison of the reactivity of ruthenium-carbon, ruthenium-nitrogen, and ruthenium-oxygen bonds

J. Hartwig, R. Bergman, R. Andersen, 1991 .

Lawrence Berkeley National Laboratory Recent Work Title ACTIVATION OF ALKANES IN HOMOGENEOUS SOLUTION USING ORGANOTRANSITION METAL COMPLEXES Permalink

R. Bergman, Ketal Cokplexes, 2013 .

Stereochemistry of metallacycle formation in the double alkylation of bis(triphenylphosphine)nitrogen(1+) bis(.eta.5-cyclopentadienyl)-di-.mu.-carbonyldicobaltate with .alpha.,.gamma.-diiodoalkanes

R. Bergman, Gilbert K. Yang, 1983 .

Comments on “Methyl phenylacetate enolate generated with the P4-tBu Schwesinger base: ‘naked’ or not?”

O. Melnyk, R. Bergman, H. Gras-masse, 2003 .

Effect of polymer attachment on the equilibrium acidity of an organotransition metal hydride and an organic carboxylic acid. Synthesis and properties of a polymer-supported metal anion

J. Frommer, R. Bergman, 1980 .

exo Vicinal Hydride Shift in the 3-endo-Methyl-2-norbornyl Cation1

R. Bergman, J. A. Berson, J. H. Hammons, 1965 .

References and Notes

A. H. Klahn, R C Dunn, X. Xie, 2022 .

σ or π? Bonding interactions in a series of rhenium metallotetrylenes.

R. Bergman, L. Maron, Trevor D. Lohrey, 2021, Dalton transactions.

Insertion of iridium into the carbon-hydrogen bonds of alkenes: the .pi.-complex cannot be an intermediate

R. Bergman, P. Stoutland, 1985 .

Mechanism of ligand substitution in an iridium amide complex

R. Bergman, David S. Glueck, 1991 .

Synthesis of Organometallic Heterodinuclear µ-Oxo Complexes by Extrusion of Alkenes from Zirconium/Tungsten Oxaalkyl Complexes

E. Jacobsen, R. Bergman, M. Trost, 1986 .

Synthesis of Organometallic Heterodinuclear μ-Oxo Complexes by Extrusion of Alkenes from Zirconium/Tungsten Oxaalkyl Complexes.

E. Jacobsen, R. Bergman, M. Trost, 1987 .

Reversible exchange of (.eta.5-cyclopentadienyl)(dinitrosoalkane)cobalt complexes with alkenes. Kinetic and spectroscopic evidence for cyclopentadienyldinitrosylcobalt as a reactive intermediate

R. Bergman, P. Becker, 1983 .

Supramolecular catalysis in metal-ligand cluster hosts.

K. Raymond, R. Bergman, F. Toste, 2015, Chemical reviews.

Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation.

J. Ellman, R. Bergman, Jared C. Lewis, 2008, Accounts of chemical research.

Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

J. Ellman, R. Bergman, D. A. Colby, 2010, Chemical reviews.

Rhodium-catalyzed synthesis of branched amines by direct addition of benzamides to imines.

J. Ellman, R. Bergman, Kevin D. Hesp, 2012, Organic letters.

Mechanism of the rhodium(III)-catalyzed arylation of imines via C-H bond functionalization: inhibition by substrate.

C. Incarvito, A. Rheingold, J. Ellman, 2012, Journal of the American Chemical Society.

Catalysis of 6pi electrocyclizations.

Lee M. Bishop, D. Trauner, R. Bergman, 2008, Angewandte Chemie.

A supramolecular microenvironment strategy for transition metal catalysis

David M. Kaphan, K. Raymond, R. Bergman, 2015, Science.

The acid hydrolysis mechanism of acetals catalyzed by a supramolecular assembly in basic solution.

Michael D. Pluth, K. Raymond, R. Bergman, 2009, Journal of Organic Chemistry.

Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts.

K. Raymond, R. Bergman, F. Toste, 2018, Accounts of chemical research.

Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.

Michael D. Pluth, K. Raymond, R. Bergman, 2010, Journal of the American Chemical Society.

Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound.

Allegra L. Liberman-Martin, R. Bergman, T. Tilley, 2015, Journal of the American Chemical Society.

Rhenium-catalyzed didehydroxylation of vicinal diols to alkenes using a simple alcohol as a reducing agent.

J. Ellman, R. Bergman, E. Arceo, 2010, Journal of the American Chemical Society.

Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand.

R. Bergman, Trevor D. Lohrey, J. Arnold, 2017, Angewandte Chemie.

DETERMINATION OF THE REACTIVE SPIN STATE OF 1,4-DEHYDROBENZENES

Robert G. Bergman, Thomas P. Lockhart, T. P. Lockhart, 1980 .

Encapsulation and characterization of proton-bound amine homodimers in a water-soluble, self-assembled supramolecular host

Michael D. Pluth, D. Fiedler, K. Raymond, 2009, Proceedings of the National Academy of Sciences.

An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation.

J. Ellman, R. Bergman, E. Arceo, 2009, Chemical communications.

A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation.

J. Ellman, R. Bergman, J. Szewczyk, 2001, Angewandte Chemie.

Synthesis of multicyclic pyridine and quinoline derivatives via intramolecular C-H bond functionalization.

J. Ellman, R. Bergman, Sirilata Yotphan, 2010, Organic letters.

Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization.

J. Ellman, R. Bergman, Jared C. Lewis, 2004, Organic letters.

Synthesis of Tertiary and Other Sterically Demanding Alkyl and Aryl Complexes of Iridium by Aldehyde C−H Bond Activation

Peter J. Alaimo, R. Bergman, B. Arndtsen, 1997 .

NITROUS OXIDE MEDIATED SYNTHESIS OF MONOMERIC HYDROXORUTHENIUM COMPLEXES. REACTIVITY OF (DMPE)2RU(H)(OH) AND THE SYNTHESIS OF A SILICA-BOUND RUTHENIUM COMPLEX

R. Bergman, Anne W. Kaplan and, 1998 .

Catalytic C-O bond cleavage of 2-aryloxy-1-arylethanols and its application to the depolymerization of lignin-related polymers.

Lee M. Bishop, J. Ellman, R. Bergman, 2010, Journal of the American Chemical Society.

Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids.

J. Ellman, R. Bergman, Joshua R. Hummel, 2016, The Journal of organic chemistry.

Rhodium(III)‐Catalyzed Indazole Synthesis by C—H Bond Functionalization and Cyclative Capture.

L. Lavis, J. Ellman, R. Bergman, 2013 .

Executive compensation and transparency

Allen J. Bard, Robert G. Bergman, Gerard Parkin, 2004 .

Molecular Recognition of Iminium Ions in Water

D. Fiedler, R. Bergman, Raymond, 2008 .

Theoretical study of the rhenium-alkane interaction in transition metal-alkane sigma-complexes.

Rustam Z. Khaliullin, M. Head‐Gordon, Erika A Cobar, 2006, Proceedings of the National Academy of Sciences of the United States of America.

Cationic Ir(III) Alkyl and Hydride Complexes: Stoichiometric and Catalytic C—H Activation by Cp*(PMe3)Ir(R)(X) in Homogeneous Solution

R. Bergman, P. Burger, S. R. Klei, 2003 .

Isolation of a Dicationic Platinum Complex with Two Accessible Coordination Sites

R. Bergman, T. Tilley, Miriam A. Bowring, 2013 .

Simultaneously bound guests and chiral recognition: a chiral self-assembled supramolecular host encapsulates hydrophobic guests

Michael D. Pluth, Shannon M. Biros, K. Raymond, 2008 .

Direct Michael Addition of Alkenes via a Cobalt‐Dinitrosyl Mediated Vinylic C—H Functionalization Reaction.

Chen Zhao, R. Bergman, F. Toste, 2011 .

Formation of dinuclear rhodium dialkyl complexes by alkylation of a new dinuclear dianion and by nucleophilic addition of alkyllithium reagents across a metal-metal double bond

R. Bergman, M. Krause, 1985 .