A. Weller

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Computational Studies of the Solid-State Molecular Organometallic (SMOM) Chemistry of Rh s-Alkane Complexes

Andrés G. Algarra, Arron L. Burnage, M. Iannuzzi, 2020 .

Modulation of σ-Alkane Interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) Systems by Variation of the Chelating Phosphine and Alkane: Access to η2,η2-σ-Alkane Rh(I), η1-σ-Alkane Rh(III) Complexes, and Alkane Encapsulation.

S. Coles, G. Tizzard, S. Macgregor, 2018, Journal of the American Chemical Society.

Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex

A. Whitwood, S. Macgregor, B. Tegner, 2022, Organometallics.

Solid–State Molecular Organometallic Catalysis in Gas/Solid Flow (Flow-SMOM) as Demonstrated by Efficient Room Temperature and Pressure 1-Butene Isomerization

A. Weller, A. Martı́nez-Martı́nez, Samantha K. Furfari, 2020, ACS catalysis.

Controlling Structure and Reactivity in Cationic Solid-State Molecular Organometallic Systems Using Anion Templating

T. Krämer, S. Macgregor, A. Weller, 2018, Organometallics.

Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]

A. L. Thompson, T. Krämer, S. Macgregor, 2017 .

Selective C-H Activation at a Molecular Rhodium Sigma-Alkane Complex by Solid/Gas Single-Crystal to Single-Crystal H/D Exchange.

A. L. Thompson, G. Buntkowsky, T. Gutmann, 2016, Journal of the American Chemical Society.

Ruthenium (II) complexes of the chelating phosphine borane H2ClB · dppm

C. Frost, G. Kociok‐Köhn, M. Willis, 2005 .

[Cp2ZrMe(12-mu-Me-1-closo-CB11HMe10)]: a transition metal complex of a highly-methylated carborane anion.

A. Weller, J. Rourke, M. Ingleson, 2003, Chemical communications.

Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site species

A. Weller, S. Pike, Sebastian D. Pike, 2015, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[Rh7(PiPr3)6H18][BArF4]2: A Molecular Rh(111) Surface Decorated with 18 Hydrogen Atoms

E. McInnes, J. Warren, Jennifer C. Green, 2007 .

Bis(phosphine)boronium salts. Synthesis, structures and coordination chemistry.

A. Weller, Rowan D. Young, Indrek Pernik, 2013, Dalton transactions.

Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C–H anagostic interactions and B–H agostic bonds†

Arron L. Burnage, S. Macgregor, A. Weller, 2021, Chemical science.

Diphosphine mono-sulfides: readily available chiral monophosphines

C. Frost, G. Kociok‐Köhn, M. Willis, 2003 .

Relative binding affinities of fluorobenzene ligands in cationic rhodium bisphosphine η6–fluorobenzene complexes probed using collision-induced dissociation

J. S. McIndoe, A. Weller, Indrek Pernik, 2015 .

Oligomeric aminoborane precursors for the chemical vapour deposition growth of few-layer hexagonal boron nitride

J. Warner, H. Bhaskaran, Xiaochen Wang, 2017 .

Selectivity of Rh⋅⋅⋅H−C Binding in a σ‐Alkane Complex Controlled by the Secondary Microenvironment in the Solid State

Arron L. Burnage, S. Macgregor, B. Tegner, 2020, Chemistry.

The Catalytic Dehydrocoupling of Amine–Boranes and Phosphine–Boranes

A. Weller, T. Hooper, H. Johnson, 2015 .

Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B·NH3 as probed by experiment and computation

Andrés G. Algarra, Amit Kumar, S. Macgregor, 2014 .

Mechanistic studies of the dehydrocoupling and dehydropolymerization of amine-boranes using a [Rh(Xantphos)]⁺ catalyst.

I. Manners, A. Weller, G. Lloyd‐Jones, 2014, Journal of the American Chemical Society.

Monomeric and oligomeric amine-borane sigma-complexes of rhodium. intermediates in the catalytic dehydrogenation of amine-boranes.

Xinzheng Yang, M. Hall, A. Weller, 2009, Journal of the American Chemical Society.

Ligand design: the two faces of carboranes.

A. Weller, 2011, Nature chemistry.

Correction to Rh–POP Pincer Xantphos Complexes for C–S and C–H Activation. Implications for Carbothiolation Catalysis

Peng Ren, M. Willis, A. Weller, 2015 .

Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination

M. Willis, A. Weller, G. Lloyd‐Jones, 2012 .

Catching the first oligomerization event in the catalytic formation of polyaminoboranes: H3B·NMeHBH2·NMeH2 bound to iridium.

I. Manners, A. Weller, M. Haddow, 2011, Journal of the American Chemical Society.

The influence of phosphine cone angle on the synthesis and structures of [Rh(PR3)(Binor–S)]+ complexes that show C–C sigma interactions

A. Weller, Adrian B. Chaplin, 2013 .

Rhodium Cyclopentyl Phosphine Complexes of Wide-Bite-Angle Ligands DPEphos and Xantphos

A. Weller, Adrian B. Chaplin, Romaeo Dallanegra, 2012 .

Exploring (Ph2PCH2CH2)2E ligand space (E = O, S, PPh) in RhI alkene complexes as potential hydroacylation catalysts

M. Willis, A. Weller, Adrian B. Chaplin, 2011 .

A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H.

A. Weller, Adrian B. Chaplin, 2011, Acta crystallographica. Section C, Crystal structure communications.

Cationic iridium complexes of the Xantphos ligand. Flexible coordination modes and the isolation of the hydride insertion product with an alkene

A. Weller, Adrian B. Chaplin, Ashley J. Pontiggia, 2011 .

{Rh(PiBu3)2}+ Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I – An Experimental Approach

A. Weller, N. Rees, Adrian B. Chaplin, 2011 .

[B(3,5-C6H3Cl2)4]― as a Useful Anion for Organometallic Chemistry

A. Weller, Adrian B. Chaplin, 2010 .

Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines

A. Weller, Adrian B. Chaplin, Romaeo Dallanegra, 2010 .

Reversible Encapsulation of Xenon and CH2Cl2 in a Solid‐State Molecular Organometallic Framework (Guest@SMOM)

A. Weller, A. Martı́nez-Martı́nez, N. Rees, 2019, Angewandte Chemie.

Encapsulation of Crabtree's Catalyst in Sulfonated MIL‐101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment

Jianliang Xiao, L. Brammer, M. Rosseinsky, 2018, Angewandte Chemie.

{Rh(PiBu3)2}+ Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part II – Computational Analysis of Pathways for Haptotropic Migration†

A. Weller, Adrian B. Chaplin, J. McGrady, 2011 .

C-C activation in the solid state in an organometallic σ-complex.

Jennifer C. Green, A. Weller, Adrian B. Chaplin, 2011, Journal of the American Chemical Society.

Silver phosphanes partnered with carborane monoanions: synthesis, structures and use as highly active Lewis acid catalysts in a hetero-Diels-Alder reaction.

C. Frost, A. Weller, M. Mahon, 2002, Chemistry.

Simultaneous Orthogonal Methods for the Real-Time Analysis of Catalytic Reactions

J. S. McIndoe, A. Weller, L. Yunker, 2016 .

Rhodium-Catalyzed Selective Partial Hydrogenation of Alkynes

A. Oliver, J. S. McIndoe, A. Weller, 2015 .

A General, Rhodium-Catalyzed, Synthesis of Deuterated Boranes and N-Methyl Polyaminoboranes.

I. Manners, A. Weller, G. Whittell, 2018, Chemistry.

Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex

A. Whitwood, S. Macgregor, B. Tegner, 2022, Organometallics.

Fluoroarene Complexes with Small Bite Angle Bisphosphines: Routes to Amine–Borane and Aminoborylene Complexes

S. Macgregor, A. Weller, Alasdair I. McKay, 2017 .

The Simplest Amino‐borane H2B=NH2 Trapped on a Rhodium Dimer: Pre‐Catalysts for Amine–Borane Dehydropolymerization

Amit Kumar, S. Macgregor, A. Weller, 2016, Angewandte Chemie.

Variable coordination modes and catalytic dehydrogenation of B-phenyl amine-boranes.

Amit Kumar, A. Weller, T. Hooper, 2016, Dalton transactions.

Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies

S. Macgregor, A. Weller, T. Hooper, 2015, Chemical science.

Dehydrocoupling of dimethylamine borane catalyzed by Rh(PCy3)2H2Cl.

A. Weller, G. Lloyd‐Jones, M. A. Huertos, 2013, Inorganic chemistry.

A tert-butyl-substituted amino-borane bound to an iridium fragment: A latent source of free H2BNtBuH

A. Weller, H. Johnson, 2012 .

Development of a generic mechanism for the dehydrocoupling of amine-boranes: a stoichiometric, catalytic, and kinetic study of H3B·NMe2H using the [Rh(PCy3)2]+ fragment.

A. Weller, G. Lloyd‐Jones, Laura J. Sewell, 2012, Journal of the American Chemical Society.

Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation.

A. Weller, Adrian B. Chaplin, Laura J. Sewell, 2011, Dalton transactions.

B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes.

A. Weller, Adrian B. Chaplin, 2010, Angewandte Chemie.

Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes.

A. Weller, Adrian B. Chaplin, 2010, Inorganic chemistry.

Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center.

A. Weller, Adrian B. Chaplin, Romaeo Dallanegra, 2009, Angewandte Chemie.

Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes.

A. Weller, Adrian B. Chaplin, Thomas M Douglas, 2008, Journal of the American Chemical Society.

Dihydrogen Loss from a 14-Electron Rhodium(III) Bis-Phosphine Dihydride To Give a Rhodium(I) Complex That Undergoes Oxidative Addition with Aryl Chlorides

A. Weller, Adrian B. Chaplin, Thomas M Douglas, 2008 .

[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex.

A. Weller, S. Brayshaw, Gemma L. Moxham, 2007, Dalton transactions.

Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes.

C. Frost, Jérôme Le Nôtre, A. Weller, 2006, Chemical communications.

Dihydrogen complexes of rhodium: [RhH2(H2)x (PR3)2]+ (R = Cy, iPr; x = 1, 2).

G. Ruggiero, A. Weller, M. Ingleson, 2005, Inorganic chemistry.

MOLECULAR ORBITAL ANALYSIS OF THE TREND IN 11B NMR CHEMICAL SHIFTS FOR (CP*M)2B5H9 (M = CR, MO, W; CP* = ETA 5-C5ME5)

T. Fehlner, A. Weller, 1999 .

Phosphoramidate-Supported Cp*Ir(III) Aminoborane H2 B=NR2 Complexes: Synthesis, Structure, and Solution Dynamics.

A. Weller, J. Love, E. Bowes, 2016, Chemistry.

Investigation of the synthesis of {Mo(η5-C5H5)(CO)3}+ fragments partnered with the monoanionic carboranes [closo-CB11H11Br]−, [closo-CB11H6Br6]− and [closo-HCB11Me11]− by silver salt metathesis and hydride abstraction

A. Weller, M. Ingleson, M. Mahon, 2003 .

Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2.

J. S. McIndoe, G. Kociok‐Köhn, Jennifer C. Green, 2005, Angewandte Chemie.

A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand.

M. Willis, R. Woodward, A. Weller, 2006, Angewandte Chemie.

Iron Precatalysts with Bulky Tri(tert-butyl)cyclopentadienyl Ligands for the Dehydrocoupling of Dimethylamine-Borane.

I. Manners, Amit Kumar, A. Weller, 2018, Chemistry.

Rhodium-catalysed aryl transfer to aldehydes: counterion effects with nitrogen containing ligands

C. Frost, A. Weller, Christelle Moreau, 2001 .

Bi- and tri-metallic {Cp*RhCl} fragments partnered with carborane monoanions [CB11H6Y6]? (Y = H, Br): control of nuclearity by choice of anion

A. Weller, M. Mahon, N. Patmore, 2003 .

[Rh(C7H8)(PPh3)Cl]: an experimental charge-density study.

A. Weller, J. Howard, H. Sparkes, 2008, Acta crystallographica. Section B, Structural science.

Cluster expansion and vertex substitution pathways in nickel germanide Zintl clusters.

A. Weller, J. Goicoechea, Oliver P. E. Townrow, 2021, Chemical communications.

A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes

S. Macgregor, A. Weller, J. Goicoechea, 2020, Journal of the American Chemical Society.

Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P.BH3.

C. Frost, M. Willis, A. Weller, 2004, Dalton transactions.

Polyethyl substituted weakly coordinating carborane anions: a sequential dehydrogenative borylation-hydrogenation route.

G. Kociok‐Köhn, A. Weller, E. Molinos, 2005, Chemical communications.

Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation.

S. Macgregor, A. Weller, N. Rees, 2010, Chemistry.

Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling.

M. Willis, A. Weller, Adrian B. Chaplin, 2012, Journal of the American Chemical Society.

Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment.

T. Donohoe, A. Weller, Adrian B. Chaplin, 2011, Dalton transactions.

Rhodium cyclooctadiene complexes of the weakly co-ordinating carborane anion [closo-CB11H12]−. Isolation and crystal structures of [(COD)Rh(η2-CB11H12)] and [(COD)Rh(THF)2][CB11H12]

J. Steed, A. Weller, M. Mahon, 2000 .

Dihalogeno(diphosphane)metal(II) complexes (metal = Co, Ni, Pd) as pre-catalysts for the vinyl/addition polymerization of norbornene – elucidation of the activation process with B(C6F5)3/AlEt3 or Ag[closo-1-CB11H12] and evidence for the in situ formation of “naked” Pd2+ as a highly active species

Biao Wu, C. Janiak, A. Weller, 2003 .

Rhodium Phosphine Olefin Complexes of the Weakly Coordinating Anions [BArF4]- and [1-closo-CB11H6Br6]-. Kinetic versus Thermodynamic Factors in Anion Coordination and Complex Reactivity

A. Weller, S. Brayshaw, Thomas M Douglas, 2007 .

Exploring the mechanism of the hydroboration of alkenes by amine–boranes catalysed by [Rh(xantphos)]

J. S. McIndoe, A. Weller, Robin Theron, 2014 .

Dehydropolymerization of H3B·NMeH2 Using a [Rh(DPEphos)]+ Catalyst: The Promoting Effect of NMeH2

A. Weller, Alasdair I. McKay, G. Lloyd‐Jones, 2019, ACS catalysis.

Edinburgh Research Explorer Dehydropolymerization of H3B·NMeH2 Using a [Rh(DPEphos)] + Catalyst: The Promoting Effect of NMeH 2

A. Weller, Alasdair I. McKay, G. Lloyd‐Jones, 2019 .

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.

M. Willis, A. Weller, Adrian B. Chaplin, 2012, Journal of the American Chemical Society.

POP-type ligands: Variable coordination and hemilabile behaviour

A. Weller, Gemma M. Adams, 2018 .

Coupling an electrospray ionization mass spectrometer with a glovebox: A straightforward, powerful, and convenient combination for analysis of air-sensitive organometallics

A. Lubben, J. S. McIndoe, A. Weller, 2008 .

The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.

G. Kociok‐Köhn, A. Weller, J. Lowe, 2006, Dalton transactions.

B–C activation in highly alkylated carborane monoanions partnered with cationic transition metal fragments: observations and comments

G. Kociok‐Köhn, A. Weller, M. Ingleson, 2005 .

[PtMe(iPr3P)2]+: a Pt(II) complex with an agostic interaction that undergoes C-H activation.

A. Weller, M. Ingleson, M. Mahon, 2004, Chemical communications.

Synthesis of Highly Fluorinated Arene Complexes of [Rh(Chelating Phosphine)]+ Cations, and their use in Synthesis and Catalysis

M. Willis, A. Weller, Alasdair I. McKay, 2019, Chemistry.

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.

M. Willis, A. Weller, Adrian B. Chaplin, 2011, Angewandte Chemie.

Silver-phosphine complexes of the highly methylated carborane monoanion [closo-1-H-CB11Me11]-.

G. Kociok‐Köhn, G. Ruggiero, A. Weller, 2004, Journal of the American Chemical Society.

Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes

M. Willis, A. Weller, S. Pike, 2015, Angewandte Chemie.

Well-defined indium(III)N-heterocyclic carbene complexes with triflate ligands: structural models for the In(OTf)3 catalyst.

C. Frost, G. Kociok‐Köhn, G. Ruggiero, 2004, Dalton transactions.

Facile, metal promoted, oxidation of η4-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(η4-1,3-P2C2But2)(η5-L)] (L = C5H5, C5Me5) and [MoCl(CO){η3,λ3,λ5-PC2But2PH(OR)}(η5-L)] (L= C5H5,R = H, Me)

Christopher D. Andrews, Jason M. Lynam, A. Weller, 1999 .

Intramolecular C-C agostic complexes: C-C sigma interactions by another name.

A. Weller, M. Etienne, 2014, Chemical Society reviews.

Experimental charge density study into C-C σ-interactions in a Binor-S rhodium complex.

Jennifer C. Green, T. Krämer, A. Weller, 2011, Dalton transactions.

Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes

Arron L. Burnage, S. Macgregor, B. Tegner, 2019, Journal of the American Chemical Society.

Carbon–carbon bond construction using boronic acids and aryl methyl sulfides: orthogonal reactivity in Suzuki-type couplings

M. Willis, A. Weller, Rowan D. Young, 2013 .

Mixed Sandwich Carborane/Thiamacrocycle Compounds. Synthesis and Characterization of 1-Ph-3,3,3-[9]aneS3-κ3-S,S‘,S‘‘-3,1,2-closo-RuC2B9H10 and 1,2-Ph2-3,3,3-[9]aneS3-κ3-S,S‘,S‘‘-3,1,2-pseudocloso-RuC2B9H9†,‡

A. Weller, A. J. Welch, 1996 .

Synthesis and Characterization of a Rhodium(I) σ-Alkane Complex in the Solid State

Andrés G. Algarra, D. Apperley, S. Macgregor, 2012, Science.

Controlling Selectivity in Intermolecular Alkene or Aldehyde Hydroacylation Reactions Catalyzed by {Rh(L2)}+ Fragments

M. Willis, A. Weller, Adrian B. Chaplin, 2010 .

Exploiting Carbonyl Groups to Control Intermolecular Rhodium-Catalyzed Alkene and Alkyne Hydroacylation.

M. Willis, A. Weller, Alasdair I. McKay, 2017, Journal of the American Chemical Society.

Effect of the Phosphine Steric and Electronic Profile on the Rh-Promoted Dehydrocoupling of Phosphine–Boranes

I. Manners, A. Weller, T. Jurca, 2014, Inorganic chemistry.

Revealing the P–B coupling event in the rhodium catalysed dehydrocoupling of phosphine–boranes H3B·PR2H (R = tBu, Ph)

A. Weller, M. A. Huertos, 2013 .

Intermediates in the Rh-catalysed dehydrocoupling of phosphine-borane.

A. Weller, M. A. Huertos, 2012, Chemical communications.

Rh(DPEPhos)-Catalyzed Alkyne Hydroacylation Using β-Carbonyl-Substituted Aldehydes: Mechanistic Insight Leads to Low Catalyst Loadings that Enables Selective Catalysis on Gram-Scale.

M. Willis, A. Weller, Simon Hardy, 2018, Journal of the American Chemical Society.

Controlled Synthesis of Well-Defined Polyaminoboranes on Scale Using a Robust and Efficient Catalyst.

J. Town, D. Haddleton, S. Huband, 2021, Journal of the American Chemical Society.

Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer.

Thomas T D Chen, A. Weller, A. Martı́nez-Martı́nez, 2020, Chemical communications.

FERROCENYL SUBSTITUTED CARBORANES : SYNTHESIS AND CHARACTERISATION

G. Rosair, A. Weller, C. L. Beckering, 1998 .

Si-C(sp3) bond activation through oxidative addition at a Rh(i) centre.

A. Weller, A. Martı́nez-Martı́nez, M. A. Huertos, 2020, Dalton transactions.

A d10 Ag(i) amine-borane σ-complex and comparison with a d8 Rh(i) analogue: structures on the η1 to η2:η2 continuum.

S. Macgregor, A. Weller, A. Martı́nez-Martı́nez, 2019, Dalton transactions.

[Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2.

S. Macgregor, A. Weller, S. Sabo-Etienne, 2011, Chemistry.

Intermolecular alkene and alkyne hydroacylation with beta-S-substituted aldehydes: mechanistic insight into the role of a hemilabile P-O-P ligand.

M. Willis, A. Weller, S. Brayshaw, 2008, Chemistry.

Cationic rhodium mono-phosphine fragments partnered with carborane monoanions [closo-CB11H6X6]- (X = H, Br). Synthesis, structures and reactivity with alkenes.

A. Weller, S. Brayshaw, G. Kociok-Köhn, 2007, Dalton transactions.

Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates

T. Krämer, S. Macgregor, A. Weller, 2017, Chemical science.

Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts.

S. Macgregor, A. Weller, Alasdair I. McKay, 2017, Journal of the American Chemical Society.

P–C-Activated Bimetallic Rhodium Xantphos Complexes: Formation and Catalytic Dehydrocoupling of Amine–Boranes**

A. Weller, H. Johnson, 2015, Angewandte Chemie.

A CH2Cl2 complex of a [Rh(pincer)](+) cation.

A. Weller, F. M. Chadwick, S. Pike, 2015, Dalton transactions.

Dehydrogenative boron homocoupling of an amine-borane.

S. Macgregor, A. Weller, Claire L. McMullin, 2013, Angewandte Chemie.

A Second‐Generation Catalyst for Intermolecular Hydroacylation of Alkenes and Alkynes Using β‐S‐Substituted Aldehydes: The Role of a Hemilabile P—O—P Ligand.

M. Willis, R. Woodward, A. Weller, 2007 .

Single-Crystal to Single-Crystal Addition of H2 to [Ir(iPr-PONOP)(propene)][BArF4] and Comparison Between Solid-State and Solution Reactivity

Arron L. Burnage, S. Macgregor, A. Weller, 2022, Organometallics.

η2-Alkene Complexes of [Rh(PONOP-iPr)(L)]+ Cations (L = COD, NBD, Ethene). Intramolecular Alkene-Assisted Hydrogenation and Dihydrogen Complex [Rh(PONOP-iPr)(η-H2)]+

S. Duckett, A. Weller, A. Martı́nez-Martı́nez, 2021, Inorganic chemistry.

Transition Metal Alkane-Sigma Complexes: Synthesis, Characterization, and Reactivity

A. Weller, Alasdair I. McKay, F. M. Chadwick, 2016 .

Amine–Borane Dehydropolymerization: Challenges and Opportunities

A. Weller, Annie L. Colebatch, 2018, Chemistry.

A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid–state

A. Weller, F. M. Chadwick, Nicholas Olliff, 2016 .

Solid-state synthesis and characterization of σ-alkane complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine).

T. Krämer, S. Macgregor, A. Weller, 2015, Journal of the American Chemical Society.

[Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound

A. Weller, Adrian B. Chaplin, 2011 .

Exploring Small Bite-Angle Ligands for the Rhodium-Catalyzed Intermolecular Hydroacylation of β-S-Substituted Aldehydes with 1-Octene and 1-Octyne

M. Willis, A. Weller, Adrian B. Chaplin, 2012 .

Isolation of a low-coordinate rhodium phosphine complex formed by C−C bond activation of biphenylene

R. Tonner, A. Weller, Adrian B. Chaplin, 2010 .

Cationic Iridium Phosphines Partnered with [closo-CB11H6Br6]-: (PPh3)2Ir(H)2(closo-CB11H6Br6) and [(PPh3)2Ir(η2-C2H4)3][closo-CB11H6Br6]. Relevance to Counterion Effects in Olefin Hydrogenation

J. Steed, G. Kociok‐Köhn, A. Weller, 2004 .

Solvent-free anhydrous Li+, Na+ and K+ salts of [B(3,5-(CF3)2C6H3)4]-, [BArF4]-. Improved synthesis and solid-state structures.

A. Weller, A. Martı́nez-Martı́nez, A. Martínez‐Martínez, 2019, Dalton transactions.

C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state.

A. Weller, S. Pike, 2013, Dalton transactions.

Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine).

G. Kociok‐Köhn, Prabha Vadivelu, S. Macgregor, 2008, Chemistry.

Sequential Dehydrogenative Borylation/Hydrogenation Route to Polyethyl-Substituted, Weakly Coordinating Carborane Anions

A. Weller, S. Brayshaw, E. Molinos, 2007 .

Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)2Rh]+. The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(η4-C6H8)Rh(PPh3)2][closo-CB11H6Br6]

A. Weller, M. Mahon, Adem Rifat, 2003 .

Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.

M. Willis, A. Weller, Rowan D. Young, 2013, Chemistry.

A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale.

A. Weller, Timothy M. Boyd, Kori A Andrea, 2019, Chemical communications.

The role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalyst.

S. Macgregor, A. Weller, A. Martı́nez-Martı́nez, 2019, Dalton transactions.

[(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.

C. Frost, A. Weller, M. Mahon, 2001, Chemical communications.

Transition metal complexes of the weakly coordinating carborane anion [CB11H12]−: the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction

J. Steed, A. Weller, N. Patmore, 2000 .

[(PPh(3))Ag(HCB(11)Me(11))]: a complex with intermolecular Ag.H3C interactions.

G. Ruggiero, A. Weller, M. Ingleson, 2002, Angewandte Chemie.

Solution and Solid-State Structure of the Anion [Ag2{closo-CB11H12}4]2-

M. A. Fox, A. Weller, M. Mahon, 2002 .

Synthesis and characterisation of {Mo(η-L)(CO)3}+ (η-L = C5H5 or C5Me5) fragments ligated with [CB11H12]− and derivatives. Isolation and structural characterisation of an intermediate in a silver salt metathesis reaction

J. Steed, A. Weller, M. Mahon, 2001 .

Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).

Jennifer C. Green, A. Weller, Adrian B. Chaplin, 2010, Dalton transactions.

Rhodium phosphines partnered with the carborane monoanions [CB11H6Y6]- (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts

A. Weller, M. Mahon, N. Patmore, 2002 .

D-and f-block metallaboranes

A. Weller, 2007 .

[1‐Me‐1‐closo‐SnB11H11]− as a potential weakly coordinating anion: Synthesis of Rh(PPh3)2(1‐Me‐closo‐SnB11H11) and comparisons with Rh(PR3)2 (1‐H‐closo‐CB11 H11)

G. Kociok‐Köhn, A. Weller, Giuseppe D. Ruggerio, 2006 .

exo-closo-Rhodacarboranes: synthesis and characterisation of [{exo-(R3P)2Rh}(closo-CB11H12)] [R3P=P(OMe)3, PCy3, 1/2dppe]

G. Ruggiero, A. Weller, M. Mahon, 2003 .

Synthesis, characterisation and reactivity of group six alkylidynes bearing the tridentate phosphine PPh(C2H4PPh2)2-‘triphos’. Crystal structure of mer-[W(NCMe)(≡CC6H4Me-4)PPh(C2H4PPh2)2(CO)][BF4]

A. Weller, J. Jeffery, 1997 .

Reversible Binding of Dihydrogen in Multimetallic Complexes

J. S. McIndoe, A. Weller, J. McIndoe, 2007 .

Chelating Monoborane Phosphines: Rational and High-Yield Synthesis of [(COD)Rh{(η2-BH3)Ph2PCH2PPh2}][PF6] (COD = 1,5-cyclooctadiene)

C. Frost, M. Willis, G. Ruggiero, 2001 .

Synthesis of Mono- and Ditungstaboranes from Reaction of Cp*WCl4 and [Cp*WCl2]2 with BH3·thf or LiBH4 (Cp* = η5-C5Me5). Control of Reaction Pathway by Choice of Monoboron Reagent and Oxidation State of Metal Center

T. Fehlner, A. Weller, M. Shang, 1999 .

Synthesis and Structure of the Metallaborane Cp*3(μ-H)W3B8H8 from the Thermolysis of Cp*H3WB4H8 (Cp* = η5-C5Me5). A Close-Packed 11-Atom Boron-Rich Cluster

T. Fehlner, A. Weller, M. Shang, 1998 .

Sequential reduction of high hydride count octahedral rhodium clusters [Rh6(PR3)6H12][BArF4]2: redox-switchable hydrogen storage.

F. Marken, J. Warren, J. S. McIndoe, 2007, Journal of the American Chemical Society.

High hydride count rhodium octahedra, [Rh6(PR3)6H12][BArF4]2: synthesis, structures, and reversible hydrogen uptake under mild conditions.

J. S. McIndoe, G. Kociok‐Köhn, Jennifer C. Green, 2006, Journal of the American Chemical Society.

[(iPr3P)6Rh6H12]2+: a high-hydride content octahedron that bridges the gap between late and early transition metal clusters.

A. Weller, M. Ingleson, M. Mahon, 2004, Journal of the American Chemical Society.

Relative binding af fi nities of fl uorobenzene ligands in cationic rhodium bisphosphine h 6 e fl uorobenzene complexes probed using collision-induced dissociation

J. S. McIndoe, A. Weller, Indrek Pernik, 2022 .

A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane

S. Coles, G. Tizzard, Arron L. Burnage, 2021, Journal of the American Chemical Society.

A Structurally Characterized Cobalt(I) σ‐Alkane Complex

M. Hayward, Samuel E. Neale, S. Coles, 2020, Angewandte Chemie.

A Rhodium–Pentane Sigma‐Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques

M. Iannuzzi, T. Krämer, S. Macgregor, 2016, Angewandte Chemie.

Early versus late transition metals. Electronic structure of nido-2-CpMLnB4H8, CpMLn=CpTaCl2, CpWH3 and CpCo

T. Fehlner, S. Aldridge, A. Weller, 1999 .

New Structural Motifs in Metallaborane Chemistry. Synthesis, Characterization, and Solid-State Structures of (Cp*W)3(μ-H)B8H8, (Cp*W)2B7H9, and (Cp*Re)2B7H7(Cp* = η-C5Me5)

T. Fehlner, A. Weller, M. Shang, 1999 .

Synthesis and characterization of the nine-atom, rhena- and tungsta-boranes (Cp*Re)2B7H7 and (Cp*W)2B7H9, Cp* = η5-C5Me5. Molecular mimics of hypoelectronic main-group clusters in Zintl phases

T. Fehlner, A. Weller, M. Shang, 1998 .

C−C Bond Activation of a Cyclopropyl Phosphine: Isolation and Reactivity of a Tetrameric Rhodacyclobutane

A. Weller, Adrian B. Chaplin, 2010 .

Storing and releasing hydrogen with a redox switch.

F. Marken, J. S. McIndoe, N. Hazari, 2006, Angewandte Chemie.

Reversible on/off switching of interactions in rhodathiaboranes with “anomalous” electron counts. Synthesis and molecular structure of [(Ph3P2N][1-dppe-1,2-closo-RhSB9H9]

A. Weller, Rhodri Ll. Thomas, Kerry J. Adams, 1997 .

8-[1,2-bis(diphenylphosphino)ethane]9,10-μ-hydrido-8-rhoda-7-thia-nido-undecaborane(10)dichloromethane (2/1)

G. Rosair, A. Weller, A. J. Welch, 1996 .

Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H2 binding materials on a surface

F. Marken, A. Weller, P. Raithby, 2009 .

ISOLATION OF A NONICOSAHEDRAL INTERMEDIATE IN THE ISOMERIZATION OF AN ICOSAHEDRAL METALLACARBORANE

G. Rosair, A. Weller, Rhodri Ll. Thomas, 1997 .

Acceptorless, intramolecular, alkyl dehydrogenation in the solid-state in a rhodium phosphine complex; reversible uptake of three equivalents of H2 per molecule

A. Weller, Thomas M Douglas, 2008 .

Steric effects in heteroboranes. Part 21. Metallation of a bis(thiophenyl)carborane giving both exo and endo products. Synthesis and structural characterisation of RuCl{7,8-(SPh)2-7,8-nido-C2B9H10}(p-cymene) and 1,2-(SPh)2-3-(p-cymene)-3,1,2--RuC2B9H9

F. Teixidor, C. Viňas, G. Rosair, 1998 .

Chelating Phosphane–Boranes as Hemilabile Ligands – Synthesis of[Mn(CO)3(η2‐H3B·dppm)][BArF4] and [Mn(CO)4(η1‐H3B·dppm)][BArF4]

C. Frost, G. Kociok‐Köhn, M. Willis, 2006 .

A Structurally Characterized Cobalt(I) σ‐Alkane Complex

M. Hayward, Samuel E. Neale, S. Coles, 2020, Angewandte Chemie.

Encapsulation of an organometallic cationic catalyst by direct exchange into an anionic MOF† †Electronic supplementary information (ESI) available: Detailed experimental procedures and methods, additional figures and tables describing materials characterisation and catalytic activity, crystallograph

Jianliang Xiao, L. Brammer, M. Rosseinsky, 2015, Chemical science.

Synthesis and reactivity of 7,9-diphenyl-nido-carbaundecaboranes: rearrangement processes in carbaplatinaboranes revisited

A. Weller, A. J. Welch, 1997 .

C–C σ complexes of rhodium

A. Weller, E. Sceats, S. Brayshaw, 2007, Proceedings of the National Academy of Sciences.

A rhodium complex with one Rh...C-C and one Rh...H-C agostic bond.

G. Kociok‐Köhn, A. Weller, E. Sceats, 2006, Angewandte Chemie.

Amine–Borane Dehydropolymerization Using Rh-Based Precatalysts: Resting State, Chain Control, and Efficient Polymer Synthesis

A. Weller, G. Lloyd‐Jones, James J. Race, 2020, ACS Catalysis.

SYNTHESIS, CHARACTERISATION AND MOLECULAR STRUCTURES OF THE CLOSO AND PSEUDOCLOSO HEPTAMETHYLINDENYL CARBARHODABORANES 1-PH-3-(ETA -C9ME7)-3,1,2-CLOSO -RHC2B9H10 AND 1,2-PH2-3-(ETA -C9ME7)3,1,2-PSEUDOCLOSO-RHC2B9H9. EXPERIMENT AL ASSIGNMENT OF THE 11B NMR SPECTRUM OF A PSEUDOCLOSO CARBAMETALLABORANE

U. Grädler, A. Weller, D. Reed, 1996 .

Mechanistic Insights into Molecular Crystalline Organometallic Heterogeneous Catalysis through Parahydrogen-Based Nuclear Magnetic Resonance Studies

S. Duckett, A. Weller, Cameron G Royle, 2023, Journal of the American Chemical Society.

STERICALLY ENCUMBERED CHARGE-COMPENSATED CARBABORANES: SYNTHESIS AND REACTIVITY MOLECULAR STRUCTURES OF 7-PH-11-SME2-7,8-NIDO-C2B9H10 AND 1-PH-3,3-(CO )2-7-SME2-3,1,2-CLOSO-RHC2B9H8

G. Rosair, A. Weller, S. Zahn, 1997 .

Expected and unexpected outcomes of a heteroborane isomerisation

A. Weller, Shirley Dunn, 1998 .

Reactivity of an Unsaturated Iridium(III) Phosphoramidate Complex, [Cp*Ir{κ2-N,O}][BArF4]

A. Weller, J. Love, Marcus W. Drover, 2015 .

Conversion of butanol to propene in flow: A triple dehydration, isomerisation and metathesis cascade

P. Dyer, A. Weller, Philip W. Dyer, 2022, Catalysis Communications.

Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation.

A. Weller, Adrian B. Chaplin, Joseph A. B. Abdalla, 2010, Dalton transactions.

Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate.

J. Howard, S. Macgregor, A. Weller, 2009, Chemical communications.

Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

S. Macgregor, A. Weller, Timothy M. Boyd, 2022, ACS catalysis.

Ruthenium, Rhodium, and Iridium Bis(σ-B−H) Diisopropylaminoborane Complexes†

L. Vendier, A. Weller, E. Clot, 2010 .

Stoichiometric and Catalytic Solid–Gas Reactivity of Rhodium Bis-phosphine Complexes

T. Krämer, S. Macgregor, A. Weller, 2015 .

catena -Poly[[(tetrafluoroborato-κ F )silver(I)]-μ-triphenylphosphine-κ 2 P : C 3 ]

Simon K. Brayshaw, Eduardo Molinos, Andrew S. Weller, 2007 .

The Synthesis, Characterization and Dehydrogenation of Sigma‐Complexes of BN‐Cyclohexanes

Shih‐Yuan Liu, D. Dixon, Amit Kumar, 2015, Chemistry.

Rhodathiaboranes with `anomalous' electron counts: synthesis, structure and reactivity

G. Rosair, A. Weller, Kerry J. Adams, 1998 .

A DFT based investigation into the electronic structure and properties of hydride rich rhodium clusters.

N. Hazari, A. Weller, S. Brayshaw, 2007, Dalton transactions.

Bond catastrophes in rhodium complexes: experimental charge-density studies of [Rh(C7H8)(P(t)Bu3)Cl] and [Rh(C7H8)(PCy3)Cl].

A. Weller, Adrian B. Chaplin, J. Howard, 2010, Acta crystallographica. Section B, Structural science.

Towards experimental mapping of the mechanism of heteroborane isomerisation

F. Teixidor, C. Viňas, M. A. Fox, 2000 .

Ligand design: the two faces of carboranes.

A. Weller, 2011, Nature chemistry.

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.

M. Willis, A. Weller, Adrian B. Chaplin, 2012, Journal of the American Chemical Society.

Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates

T. Krämer, S. Macgregor, A. Weller, 2017, Chemical science.

S. Coles, G. Tizzard, S. Macgregor, 2018, Journal of the American Chemical Society.

A combined experimental and computational study of fluxional processes in sigma amine-borane complexes of rhodium and iridium.

Andrés G. Algarra, S. Macgregor, A. Weller, 2014, Dalton transactions.

Mechanistic studies of the dehydrocoupling and dehydropolymerization of amine-boranes using a [Rh(Xantphos)]⁺ catalyst.

I. Manners, A. Weller, G. Lloyd‐Jones, 2014, Journal of the American Chemical Society.

The Promoting

A. Weller, Alasdair I. McKay, G. Lloyd‐Jones, 2020 .

The Promoting

A. Weller, Alasdair I. McKay, G. Lloyd‐Jones, 2020 .

Tuning the [L2Rh···H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes.

I. Manners, A. Weller, Adrian B. Chaplin, 2011, Chemical communications.

Amino-borane oligomers bound to a Rh(I) metal fragment.

A. Weller, Adrian B. Chaplin, Romaeo Dallanegra, 2010, Chemical communications.

Variable coordination modes and catalytic dehydrogenation of B-phenyl amine-boranes.

Amit Kumar, A. Weller, T. Hooper, 2016, Dalton transactions.

Correction to Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H3B·NMeHBH2·NMeH2 Bound to Iridium

I. Manners, A. Weller, M. Haddow, 2012 .

Dehydrogenative boron homocoupling of an amine-borane.

S. Macgregor, A. Weller, Claire L. McMullin, 2013, Angewandte Chemie.

Bis(phosphine)boronium salts. Synthesis, structures and coordination chemistry.

A. Weller, Rowan D. Young, Indrek Pernik, 2013, Dalton transactions.

Amine–Borane Dehydropolymerization The Simplest Amino-borane H 2 B = NH 2 Trapped on a Rhodium Dimer: Pre-Catalysts for Amine–Borane Dehydropolymerization

S. Macgregor, A. Weller, Nicholas A. Beattie, 2020 .

The role of neutral Rh(PONOP)H, free NMe 2 H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)( η 2 -H 2 )] + catalyst †‡

A. Weller, Andrew Docker, Annie L. Colebatch, 2020 .

Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.

M. Willis, A. Weller, Rowan D. Young, 2013, Chemistry.

Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation.

A. Weller, Adrian B. Chaplin, Laura J. Sewell, 2011, Dalton transactions.

Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism

R. Perutz, A. Weller, S. Sabo-Etienne, 2021, Angewandte Chemie.