D. Milstein

发表

Formal oxidative addition of a C-H bond by a 16e iridium(i) complex involves metal-ligand cooperation.

Y. Diskin‐Posner, Amit Kumar, Moran Feller, 2018, Chemical communications.

PNN Ruthenium Pincer Complexes Based on Phosphinated 2,2′-Dipyridinemethane and 2,2′-Oxobispyridine. Metal–Ligand Cooperation in Cyclometalation and Catalysis

Y. Diskin‐Posner, L. Shimon, E. Balaraman, 2013 .

Nickel promoted C–H, C–C and C–O bond activation in solution

L. Shimon, M. Boom, Yehoshoa Ben‐David, 2004 .

Metallinsertion in C-C-Bindungen in Lösung

D. Milstein, B. Rybtchinski, 1999 .

Activation of a non-strained C–C bond with plantinum(II)

M. Boom, H. Kraatz, Yehoshoa Ben‐David, 1996 .

Carbon–carbon activation by rhodium in solution; sp2–sp3 is preferred over sp3–sp3 bond cleavage

M. Gozin, D. Milstein, Shyh-Yeon Liou, 1995 .

Transfer of methylene groups promoted by metal complexation

M. Gozin, M. Aizenberg, D. Milstein, 1994, Nature.

N–Hvis. C–H activation; a major ligand size effect

M. Schulz, D. Milstein, 1993 .

Activation of a carbon–carbon bond in solution by transition-metal insertion

M. Gozin, D. Milstein, Alexander Weisman, 1993, Nature.

Noninnocent behavior of PCP and PCN pincer ligands of late metal complexes

E. Poverenov, D. Milstein, 2013 .

A Dearomatized Anionic PNP Pincer Rhodium Complex: C–H and H–H Bond Activation by Metal–Ligand Cooperation and Inhibition by Dinitrogen

M. Iron, D. Milstein, Leonid Schwartsburd, 2011 .

Pi-accepting-pincer rhodium complexes: an unusual coordination mode of PCP-type systems.

L. Shimon, Jan M. L. Martin, M. Iron, 2005, Chemistry.

Rh(I) and Rh(III) silyl PMe3 complexes. Syntheses, reactions and 103Rh NMR spectroscopy

C. J. Elsevier, M. Aizenberg, D. Milstein, 1998 .

The unexpected role of CO in C--H oxidative addition by a cationic rhodium(I) complex.

Jan M. L. Martin, Yehoshoa Ben‐David, D. Milstein, 2007, Angewandte Chemie.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

David Milstein, Yehoshoa Ben‐David, D. Milstein, 2007, Science.

Reusable Homogeneous Catalytic System for Hydrogen Production from Methanol and Water

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2014 .

Mechanism of Coupling of Alcohols and Amines To Generate Aldimines and H2 by a Pincer Manganese Catalyst

A. Poater, D. Milstein, J. A. Luque‐Urrutia, 2019, ACS Catalysis.

Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity

A. Frenkel, L. Shimon, Jan M. L. Martin, 2008, Nature.

A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol-Ethylenediamine and Ethylene Urea.

Yehoshoa Ben‐David, D. Milstein, P. Hu, 2019, Angewandte Chemie.

Direct Synthesis of Secondary Amines From Alcohols and Ammonia Catalyzed by a Ruthenium Pincer Complex

Y. Diskin‐Posner, E. Balaraman, D. Milstein, 2014, Catalysis Letters.

Recent Topics in Cooperative Catalysis: Asymmetric Catalysis, Polymerization, Hydrogen Activation, and Water Splitting

M. Kanai, T. Ikariya, K. Ding, 2012 .

Formamides as Isocyanate Surrogates: A Mechanistically-Driven Approach to the Development of Atom-Efficient, Selective Catalytic Syntheses of Ureas, Carbamates and Heterocycles.

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2019, Journal of the American Chemical Society.

Concept of the H(δ+)⋯ H(δ–) interaction. A low-temperature neutron diffraction study of cis-[IrH(OH)(PMe3)4]PF6

R. Stevens, T. Koetzle, D. Milstein, 1990 .

Combining Low-Pressure CO2 Capture and Hydrogenation To Form Methanol

D. Milstein, Julia R. Khusnutdinova, J. Garg, 2015 .

Pyridine-based SNS-iridium and -rhodium sulfide complexes, including d8-d8 metal-metal interactions in the solid state.

Y. Diskin‐Posner, L. Shimon, Yehoshoa Ben‐David, 2008, Dalton transactions.

CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation.

L. Shimon, Amit Kumar, Yehoshoa Ben‐David, 2019, Dalton transactions.

Bond activation and catalysis by ruthenium pincer complexes.

D. Milstein, C. Gunanathan, 2014, Chemical reviews.

Complexation of N2, H2, CO2, and Ethylene to a T-Shaped Rhodium(I) Core

Yehoshoa Ben‐David, D. Milstein, A. Vigalok, 1996 .

Bottom-Up Construction of a CO2-Based Cycle for the Photocarbonylation of Benzene, Promoted by a Rhodium(I) Pincer Complex.

Y. Diskin‐Posner, L. Shimon, Moran Feller, 2016, Journal of the American Chemical Society.

Synthesis and reactivity of iron complexes with a new pyrazine-based pincer ligand, and application in catalytic low-pressure hydrogenation of carbon dioxide.

Y. Diskin‐Posner, D. Milstein, G. Leitus, 2015, Inorganic chemistry.

Low-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex exhibiting noble metal activity.

Y. Diskin‐Posner, L. Shimon, R. Langer, 2011, Angewandte Chemie.

Bond Activation by Metal-Ligand Cooperation: Design of “Green” Catalytic Reactions Based on Aromatization-Dearomatization of Pincer Complexes

D. Milstein, C. Gunanathan, 2011 .

How Innocent are Potentially Redox Non-Innocent Ligands? Electronic Structure and Metal Oxidation States in Iron-PNN Complexes as a Representative Case Study.

T. Bendikov, Y. Diskin‐Posner, L. Shimon, 2015, Inorganic chemistry.

Synthesis of peptides and pyrazines from β-amino alcohols through extrusion of H2 catalyzed by ruthenium pincer complexes: ligand-controlled selectivity.

E. Balaraman, Yehoshoa Ben‐David, D. Milstein, 2011, Angewandte Chemie.

Synthesis and Reactivity of Cationic Boron Complexes Distorted by Pyridine-based Pincer Ligands: Isolation of a Photochemical Hofmann-Martius-type Intermediate.

Y. Diskin‐Posner, D. Milstein, Trevor Janes, 2020, Angewandte Chemie.

Synthesis and Reactivity of Cationic Boron Complexes Distorted by Pyridine‐based Pincer Ligands: Isolation of a Photochemical Hofmann–Martius‐type Intermediate

Y. Diskin‐Posner, D. Milstein, Trevor Janes, 2020, Angewandte Chemie.

A general, selective, and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium

D. Milstein, J. Stille, 1978 .

Mechanistic Investigations of Ruthenium Catalyzed Dehydrogenative Thioester Synthesis and Thioester Hydrogenation

L. Avram, Yehoshoa Ben‐David, D. Milstein, 2021, ACS catalysis.

Catalytic Oxidative Deamination by Water with H2 Liberation

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2020, Journal of the American Chemical Society.

Reductive Cleavage of CO2 by Metal-Ligand-Cooperation Mediated by an Iridium Pincer Complex.

Y. Diskin‐Posner, Moran Feller, D. Milstein, 2016, Journal of the American Chemical Society.

Mononuclear Rh(II) PNP-type complexes. Structure and reactivity.

Y. Diskin‐Posner, L. Shimon, L. Weiner, 2007, Inorganic chemistry.

Cationic, Neutral, and Anionic Platinum(II) Complexes Based on an Electron-Rich PNN Ligand. New Modes of Reactivity Based on Pincer Hemilability and Dearomatization

Y. Diskin‐Posner, L. Shimon, D. Vuzman, 2008 .

Synthesis, Structure, and Reactivity of New Rhodium and Iridium Complexes, Bearing a Highly Electron-Donating PNP System. Iridium-Mediated Vinylic C−H Bond Activation

H. Rozenberg, L. Shimon, D. Milstein, 2002 .

Efficient hydrogenation of ketones catalyzed by an iron pincer complex.

R. Langer, Yehoshoa Ben‐David, D. Milstein, 2011, Angewandte Chemie.

H/D exchange at aromatic and heteroaromatic hydrocarbons using D2O as the deuterium source and ruthenium dihydrogen complexes as the catalyst.

W. Leitner, Yehoshoa Ben‐David, D. Milstein, 2007, Angewandte Chemie.

Direct Synthesis of Benzimidazoles by Dehydrogenative Coupling of Aromatic Diamines and Alcohols Catalyzed by Cobalt

Yehoshoa Ben‐David, D. Milstein, P. Daw, 2017 .

Synthesis, structure, and reactivity of rhodium and iridium complexes of the chelating bis-sulfoxide tBuSOC2H4SOtBu. Selective O-H activation of 2-hydroxy-isopropyl-pyridine.

Y. Diskin‐Posner, D. Milstein, T. Schaub, 2008, Inorganic Chemistry.

Formation, structures, and reactivity of cis-hydroxy-, cis-methoxy-, and cis-mercaptoiridium hydrides. Oxidative addition of water to Ir(I)

Ian D. Williams, D. Milstein, J. Calabrese, 1986 .

Manganese-Catalyzed Environmentally Benign Dehydrogenative Coupling of Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic Study.

L. Shimon, D. Milstein, G. Leitus, 2016, Journal of the American Chemical Society.

Direct deamination of primary amines by water to produce alcohols.

Yehoshoa Ben‐David, D. Milstein, Julia R. Khusnutdinova, 2013, Angewandte Chemie.

Metal-ligand cooperation in C-H and H2 activation by an electron-rich PNP Ir(I) system: facile ligand dearomatization-aromatization as key steps.

L. Shimon, D. Milstein, G. Leitus, 2006, Journal of the American Chemical Society.

Oxidation of Alkenes by Water with H2 Liberation

Yehoshoa Ben‐David, D. Milstein, Shan Tang, 2020, Journal of the American Chemical Society.

Metal–Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes

L. Shimon, L. Avram, Sayan Kar, 2020, Journal of the American Chemical Society.

C-C Bond Formation of Benzyl Alcohols and Alkynes Using a Catalytic Amount of KOt Bu: Unusual Regioselectivity through a Radical Mechanism.

Y. Diskin‐Posner, Amit Kumar, D. Milstein, 2019, Angewandte Chemie.

C−C Bond Formation of Benzyl Alcohols and Alkynes Using a Catalytic Amount of KOt Bu: Unusual Regioselectivity through a Radical Mechanism

Y. Diskin‐Posner, Amit Kumar, D. Milstein, 2019, Angewandte Chemie.

Recent Advances in the Applications of Metal-Ligand Cooperation via Dearomatization and Aromatization of Pincer Complexes

Amit Kumar, D. Milstein, 2020 .

CO Oxidation by N2O Homogeneously Catalyzed by Ruthenium Hydride Pincer Complexes Indicating a New Mechanism

Y. Diskin‐Posner, L. Shimon, Rong Zeng, 2018, Journal of the American Chemical Society.

Hydrogenation and Hydrosilylation of Nitrous Oxide Homogeneously Catalyzed by a Metal Complex

Rong Zeng, Moran Feller, Yehoshoa Ben‐David, 2017, Journal of the American Chemical Society.

Hydrogenation of Polar Bonds Catalysed by Ruthenium-Pincer Complexes

E. Balaraman, D. Milstein, 2014 .

Bond Activation and Catalysis by Ruthenium Pincer Complexes

D. Milstein, C. Gunanathan, 2015 .

Processes Involved in the Reduction of a Cyclometalated Palladium(II) Complex

D. Milstein, G. Leitus, C. Frech, 2008 .

Redox-induced collapse and regeneration of a pincer-type complex framework: a nonplanar coordination mode of palladium(II).

L. Shimon, D. Milstein, C. Frech, 2005, Angewandte Chemie.

Highly Active Pd(II) PCP-Type Catalysts for the Heck Reaction

D. Milstein, M. Ohff, A. Ohff, 1997 .

Palladium-catalyzed coupling of tetraorganotin compounds with aryl and benzyl halides. Synthetic utility and mechanism

D. Milstein, J. Stille, 1979 .

A new mode of activation of CO2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature.

Y. Diskin‐Posner, M. Iron, Yehoshoa Ben‐David, 2012, Chemistry.

Facile Oxidative Addition of C−Cl Bonds to New Neutral and Cationic Rhodium(I)‐Bipyridine Complexes

H. Rozenberg, L. Shimon, D. Milstein, 2002 .

Polarizable stilbazole-based organometallic complexes and polymers

D. Milstein, Juan Burdeniuk, 1993 .

Metal-ligand cooperation.

D. Milstein, Julia R. Khusnutdinova, J. Khusnutdinova, 2015, Angewandte Chemie.

Formation of η2 C−H Agostic Rhodium Arene Complexes and Their Relevance to Electrophilic Bond Activation

L. Shimon, Jan M. L. Martin, Yehoshoa Ben‐David, 1998 .

Structure and Reactivity of Rhodium(I) Complexes Based on Electron-Withdrawing Pyrrolyl-PCP-Pincer Ligands

Y. Diskin‐Posner, L. Shimon, D. Milstein, 2009 .

Interplay between solvent and counteranion stabilization of highly unsaturated rhodium(III) complexes: facile unsaturation-induced dearomatization.

H. Rozenberg, D. Milstein, L. Konstantinovski, 2003, Chemistry.

Evidence for Direct trans Insertion in a Hydrido-Olefin Rhodium Complex-Free Nitrogen as a Trap in a Migratory Insertion Process.

H. Kraatz, D. Milstein, A. Vigalok, 1997, Chemistry.

Iron pincer complex catalyzed, environmentally benign, E-selective semi-hydrogenation of alkynes.

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2013, Angewandte Chemie.

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes.

Yehoshoa Ben‐David, D. Milstein, S. Chakraborty, 2016, Angewandte Chemie.

Reversible CO2 binding triggered by metal–ligand cooperation in a rhenium(I) PNP pincer-type complex and the reaction with dihydrogen

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2014 .

Unprecedented catalytic hydrogenation of urea derivatives to amines and methanol.

E. Balaraman, Yehoshoa Ben‐David, D. Milstein, 2011, Angewandte Chemie.

N–H Activation by Rh(I) via Metal–Ligand Cooperation

Y. Diskin‐Posner, L. Shimon, Moran Feller, 2012 .

Controlled Selectivity through Reversible Inhibition of the Catalyst: Stereodivergent Semihydrogenation of Alkynes

Y. Diskin‐Posner, L. Avram, D. Milstein, 2022, Journal of the American Chemical Society.

Efficient Base-Free Aqueous Reforming of Methanol Homogeneously Catalyzed by Ruthenium Exhibiting a Remarkable Acceleration by Added Catalytic Thiol

Sayan Kar, Yehoshoa Ben‐David, D. Milstein, 2021, Journal of the American Chemical Society.

Manganese-Catalyzed Direct Deoxygenation of Primary Alcohols

D. Milstein, J. O. Bauer, S. Chakraborty, 2017 .

Pincer “Hemilabile” Effect. PCN Platinum(II) Complexes with Different Amine “Arm Length”

H. Rozenberg, L. Shimon, E. Poverenov, 2005 .

Metal-ligand Cooperation as Key in Formation of Dearomatized Ni ( II )-H Pincer Complexes and in their Reactivity Towards CO and CO 2

Y. Diskin‐Posner, L. Avram, Moran Feller, 2018 .

Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols.

Arunandan Kumar, Amit Kumar, D. Milstein, 2018, Angewandte Chemie.

Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols.

Amit Kumar, D. Milstein, N. Espinosa‐Jalapa, 2018, Angewandte Chemie.

Chelate effect on the structure and reactivity of electron-rich palladium complexes and its relevance to catalysis

D. Milstein, M. Portnoy, 1993 .

Iron-catalysed ring-opening metathesis polymerization of olefins and mechanistic studies

Y. Diskin‐Posner, L. Shimon, S. Wolf, 2022, Nature Catalysis.

Near-Ambient-Temperature Dehydrogenative Synthesis of the Amide Bond: Mechanistic Insight and Applications

Y. Diskin‐Posner, Sayan Kar, Yehoshoa Ben‐David, 2021, ACS catalysis.

Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands.

W. Leitner, W. Wisniewski, Yehoshoa Ben‐David, 2007, Chemistry.

Formation of thioesters by dehydrogenative coupling of thiols and alcohols with H2 evolution

Y. Diskin‐Posner, L. Avram, Yehoshoa Ben‐David, 2020, Nature Catalysis.

Highly active PdII cyclometallated imine catalysts for the Heck reaction

D. Milstein, M. Ohff, A. Ohff, 1999 .

Iron dicarbonyl complexes featuring bipyridine-based PNN pincer ligands with short interpyridine C-C bond lengths: innocent or non-innocent ligand?

T. Bendikov, Y. Diskin‐Posner, T. Zell, 2014, Chemistry.

Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes.

Yehoshoa Ben‐David, D. Milstein, Dipankar Srimani, 2013, Chemical communications.

Reversible Aromaticity Transfer in a Bora-Cycle: Boron-Ligand Cooperation.

Y. Diskin‐Posner, L. Shimon, D. Milstein, 2016, Journal of the American Chemical Society.

NO˙ disproportionation by a {RhNO}9 pincer-type complex.

D. Milstein, F. Doctorovich, C. Gaviglio, 2017, Dalton transactions.

Metall‐Ligand‐Kooperation

D. Milstein, Julia R. Khusnutdinova, J. Khusnutdinova, 2015 .

Cobalt-catalyzed hydrogenation of esters to alcohols: unexpected reactivity trend indicates ester enolate intermediacy.

Y. Diskin‐Posner, L. Shimon, D. Milstein, 2015, Angewandte Chemie.

Direct observation of reductive elimination of MeX (X = Cl, Br, I) from Rh(III) complexes: mechanistic insight and the importance of sterics.

Y. Diskin‐Posner, L. Shimon, Moran Feller, 2013, Journal of the American Chemical Society.

Palladium-catalyzed vinylation of aryl chlorides. Chelate effect in catalysis

M. Gozin, Yehoshoa Ben‐David, D. Milstein, 1992 .

Rhodium complexes with chiral counterions: achiral catalysts in chiral matrices

L. Shimon, D. Milstein, Romano Dorta, 2004 .

Methylene transfer from SnMe groups mediated by a rhodium(I) pincer complex: Sn-C, C-C, and C-H bond activation.

L. Shimon, D. Milstein, C. Frech, 2007, Chemistry.

Pd Catalyzed, Acid Accelerated, Rechargeable, Liquid Organic Hydrogen Carrier System Based on Methylpyridines/Methylpiperidines

D. Milstein, Yinjun Xie, 2019, ACS Applied Energy Materials.

A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol‐Ethylenediamine and Ethylene Urea

Yehoshoa Ben‐David, D. Milstein, Yinjun Xie, 2019, Angewandte Chemie.

Mild, selective, general method of ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium

D. Milstein, J. Stille, 1979 .

Chelate-assisted, Pd-catalyzed efficient carbonylation of aryl chlorides

Yehoshoa Ben‐David, D. Milstein, M. Portnoy, 1989 .

Formylation of aryl chlorides catalysed by a palladium complex

D. Milstein, Y. Ben-David, M. Portnoy, 1989 .

The product-forming step in palladium-catalysed methoxycarbonylation of organic halides

D. Milstein, 1986 .

Aspects of intermediacy of carbalkoxymetal complexes in carbon monoxide reactions

D. Milstein, 1988 .

Synthesis of amides from esters and amines with liberation of H2 under neutral conditions.

D. Milstein, B. Gnanaprakasam, 2011, Journal of the American Chemical Society.

Catalytic System for the Heck Reaction of Fluorinated Haloaryls

D. Milstein, P. Espinet, A. C. Albéniz, 2005 .

Catalytic system for Heck reactions involving insertion into Pd-(perfluoro-organyl) bonds.

D. Milstein, P. Espinet, A. C. Albéniz, 2001, Journal of the American Chemical Society.

B–H Bond Cleavage via Metal–Ligand Cooperation by Dearomatized Ruthenium Pincer Complexes

L. Shimon, Moran Feller, Yehoshoa Ben‐David, 2014 .

Catalytic Activation of Carbon-Fluorine Bonds by a Soluble Transition Metal Complex

M. Aizenberg, D. Milstein, 1994, Science.

Catalytic System for the Heck Reaction of Fluorinated Haloaryls.

D. Milstein, P. Espinet, A. C. Albéniz, 2005 .

O2 activation by metal-ligand cooperation with Ir(I) PNP pincer complexes.

Y. Diskin‐Posner, L. Weiner, Moran Feller, 2015, Journal of the American Chemical Society.

Ligand-Controlled Formation of a Low-Valent Pincer Rhodium(I)-Dioxygen Adduct Bearing a Very Short O O Bond

L. Shimon, D. Milstein, C. Frech, 2006 .

Formation of difluoromethylene-arenium complexes by consecutive Aryl- CF3 C-C bond activation and C-F bond cleavage

M. Boom, Yehoshoa Ben‐David, D. Milstein, 1999 .

N-Substituted Hydrazones by Manganese-Catalyzed Coupling of Alcohols with Hydrazine: Borrowing Hydrogen and Acceptorless Dehydrogenation in One System.

Y. Diskin‐Posner, U. Das, Yehoshoa Ben‐David, 2018, Angewandte Chemie.

Metal-Stabilized Quinone and Thioquinone Methides

D. Milstein, A. Vigalok, 1997 .

Catalysis by Pincer Complexes: Synthesis of Esters, Amides, and Peptides

D. Milstein, C. Gunanathan, 2014 .

The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2017, Journal of the American Chemical Society.

Osmium-mediated C--H and C--C bond cleavage of a phenolic substrate: p-quinone methide and methylene arenium pincer complexes.

H. Rozenberg, L. Shimon, Yehoshoa Ben‐David, 2007, Chemistry.

Self-oxidation of a phenolate complex to a bimetallic stilbene quinone.

H. Rozenberg, L. Shimon, M. E. van der Boom, 2004, Angewandte Chemie.

Substituent effects on the McLafferty rearrangement of ionized 2‐(aryl)ethyl arylacetates

H. Schwarz, D. Milstein, J. Blum, 1981 .

Imidazole synthesis by transition metal free, base-mediated deaminative coupling of benzylamines and nitriles.

L. Shimon, U. Das, D. Milstein, 2017, Chemical communications.

Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes

D. Milstein, A. Mukherjee, 2018, ACS Catalysis.

Manganese-Catalyzed N-Formylation of Amines by Methanol Liberating H2 : A Catalytic and Mechanistic Study.

Y. Diskin‐Posner, L. Avram, D. Milstein, 2017, Angewandte Chemie.

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

D. Milstein, C. Gunanathan, 2013, Science.

Stepwise metal-ligand cooperation by a reversible aromatization/deconjugation sequence in ruthenium complexes with a tetradentate phenanthroline-based ligand.

Y. Diskin‐Posner, L. Shimon, R. Langer, 2013, Chemistry.

Metal-ligand cooperation by aromatization-dearomatization: a new paradigm in bond activation and "green" catalysis.

D. Milstein, C. Gunanathan, 2011, Accounts of chemical research.

Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes.

Yehoshoa Ben‐David, D. Milstein, G. Leitus, 2005, Journal of the American Chemical Society.

Electron-Rich, Bulky Ruthenium PNP-Type Complexes. Acceptorless Catalytic Alcohol Dehydrogenation

H. Rozenberg, L. Shimon, D. Milstein, 2004 .

Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal–Ligand Cooperation

D. Milstein, 2010 .

Cyclometalated phosphine-based pincer complexes: mechanistic insight in catalysis, coordination, and bond activation.

David Milstein, Milko E van der Boom, M. E. van der Boom, 2003, Chemical reviews.

HOMOGENEOUS METAL-CATALYZED HYDROGENOLYSIS OF C-F BONDS

M. Aizenberg, D. Milstein, 1995 .

Manganese Catalyzed Hydrogenation of Azo (N=N) Bonds to Amines

Y. Diskin‐Posner, U. Das, Sayan Kar, 2021, Advanced Synthesis & Catalysis.

Hydrogenation and dehydrogenation iron pincer catalysts capable of metal-ligand cooperation by aromatization/dearomatization.

T. Zell, D. Milstein, 2015, Accounts of chemical research.

Unprecedented iron-catalyzed ester hydrogenation. Mild, selective, and efficient hydrogenation of trifluoroacetic esters to alcohols catalyzed by an iron pincer complex.

T. Zell, Yehoshoa Ben‐David, D. Milstein, 2014, Angewandte Chemie.

Electron-Rich PNP- and PNN-Type Ruthenium(II) Hydrido Borohydride Pincer Complexes. Synthesis, Structure, and Catalytic Dehydrogenation of Alcohols and Hydrogenation of Esters

E. Balaraman, D. Milstein, G. Leitus, 2011 .

New CNN-Type Ruthenium Pincer NHC Complexes. Mild, Efficient Catalytic Hydrogenation of Esters

E. Balaraman, D. Milstein, G. Leitus, 2011 .

Efficient homogeneous catalytic hydrogenation of esters to alcohols.

Yehoshoa Ben‐David, D. Milstein, G. Leitus, 2006, Angewandte Chemie.

Facile Conversion of Alcohols into Esters and Dihydrogen Catalyzed by New Ruthenium Complexes

Yehoshoa Ben‐David, D. Milstein, G. Leitus, 2005 .

Reactions of electron-rich arylpalladium complexes with olefins. Origin of the chelate effect in vinylation catalysis

I. Rousso, D. Milstein, Y. Ben-David, 1994 .

Direct Synthesis of Symmetrical Azines from Alcohols and Hydrazine Catalyzed by a Ruthenium Pincer Complex: Effect of Hydrogen Bonding

Yehoshoa Ben‐David, D. Milstein, G. Leitus, 2016, ACS catalysis.

Direct synthesis of imines from alcohols and amines with liberation of H2.

D. Milstein, B. Gnanaprakasam, Jing Zhang, 2010, Angewandte Chemie.

Selective synthesis of primary amines directly from alcohols and ammonia.

D. Milstein, C. Gunanathan, 2008, Angewandte Chemie.

A PCN Ligand System. Exclusive C−C Activation with Rhodium(I) and C−H Activation with Platinum(II)

L. Shimon, D. Milstein, A. Vigalok, 1997 .

Synthesis, structures, and dearomatization by deprotonation of iron complexes featuring bipyridine-based PNN pincer ligands.

Y. Diskin‐Posner, L. Shimon, T. Zell, 2013, Inorganic chemistry.

Sustainable amidation through acceptorless dehydrogenative coupling by pincer-type catalysts: recent advances

D. Milstein, M. Montag, 2023, Pure and Applied Chemistry.

Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal–Ligand Cooperation

Y. Diskin‐Posner, L. Avram, U. Das, 2022, Journal of the American Chemical Society.

A Reversible Liquid-to-Liquid Organic Hydrogen Carrier System Based on Ethylene Glycol and Ethanol.

Yehoshoa Ben‐David, D. Milstein, You‐Quan Zou, 2020, Chemistry.

Synthesis of oxalamides by acceptorless dehydrogenative coupling of ethylene glycol and amines and the reverse hydrogenation catalyzed by ruthenium†

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2020, Chemical science.

Ethylene Glycol as an Efficient and Reversible Liquid Organic Hydrogen Carrier

D. Milstein, Yinjun Xie, Niklas von Wolff, 2019, Nature Catalysis.

Pyridine-Based PCP-Ruthenium Complexes: Unusual Structures and Metal-Ligand Cooperation.

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2019, Journal of the American Chemical Society.

Dehydrogenative Cross-Coupling of Primary Alcohols To Form Cross-Esters Catalyzed by a Manganese Pincer Complex

Y. Diskin‐Posner, U. Das, Yehoshoa Ben‐David, 2018, ACS Catalysis.

CO2 activation by metal−ligand-cooperation mediated by iridium pincer complexes

Y. Diskin‐Posner, Moran Feller, D. Milstein, 2018 .

Manganese-Catalyzed Hydrogenation of Esters to Alcohols.

L. Shimon, L. Avram, Yehoshoa Ben‐David, 2017, Chemistry.

Low‐Pressure Hydrogenation of Nitriles to Primary Amines Catalyzed by Ruthenium Pincer Complexes. Scope and mechanism

Yehoshoa Ben‐David, D. Milstein, Dipankar Srimani, 2017 .

Highly Efficient Process for Production of Biofuel from Ethanol Catalyzed by Ruthenium Pincer Complexes.

L. Shimon, Yehoshoa Ben‐David, D. Milstein, 2016, Journal of the American Chemical Society.

General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2.

Yehoshoa Ben‐David, D. Milstein, P. Hu, 2016, Journal of the American Chemical Society.

Rechargeable Hydrogen Storage System Based on the Dehydrogenative Coupling of Ethylenediamine with Ethanol.

Yehoshoa Ben‐David, D. Milstein, P. Hu, 2016, Angewandte Chemie.

Catalytic, oxidant-free, direct olefination of alcohols using Wittig reagents.

D. Milstein, E. Khaskin, 2015, Chemical communications.

Metal–ligand cooperation by aromatization–dearomatization as a tool in single bond activation

D. Milstein, 2015, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

New ruthenium nitrosyl pincer complexes bearing an O2 ligand. Mono-oxygen transfer.

Y. Diskin‐Posner, Jan M. L. Martin, Yehoshoa Ben‐David, 2015, Inorganic chemistry.

Transformations in Chemical Synthesis Applications of Acceptorless Dehydrogenation and Related

D. Milstein, C. Gunanathan, 2014 .

Activation of nitriles by metal ligand cooperation. Reversible formation of ketimido- and enamido-rhenium PNP pincer complexes and relevance to catalytic design.

Y. Diskin‐Posner, L. Shimon, M. Iron, 2013, Journal of the American Chemical Society.

Ru(0) and Ru(II) nitrosyl pincer complexes: structure, reactivity, and catalytic activity.

Y. Diskin‐Posner, L. Shimon, M. Iron, 2013, Inorganic chemistry.

Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes.

Yehoshoa Ben‐David, D. Milstein, Dipankar Srimani, 2013, Angewandte Chemie.

Anionic nickel(II) complexes with doubly deprotonated PNP pincer-type ligands and their reactivity toward CO2

Y. Diskin‐Posner, L. Shimon, M. Iron, 2013 .

Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source

E. Balaraman, D. Milstein, G. Leitus, 2013, Nature Chemistry.

Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure.

Moran Feller, Yehoshoa Ben‐David, D. Milstein, 2012, Chemical communications.

Ruthenium Pincer‐Catalyzed Cross‐Dehydrogenative Coupling of Primary Alcohols with Secondary Alcohols under Neutral Conditions

E. Balaraman, Yehoshoa Ben‐David, D. Milstein, 2012 .

PNS-Type Ruthenium Pincer Complexes

Y. Diskin‐Posner, L. Shimon, D. Milstein, 2012 .

Aldehyde binding through reversible C-C coupling with the pincer ligand upon alcohol dehydrogenation by a PNP-ruthenium catalyst.

D. Milstein, M. Montag, Jing Zhang, 2012, Journal of the American Chemical Society.

Iron borohydride pincer complexes for the efficient hydrogenation of ketones under mild, base-free conditions: synthesis and mechanistic insight.

Y. Diskin‐Posner, R. Langer, M. Iron, 2012, Chemistry.

Synthesis of polyamides from diols and diamines with liberation of H2

E. Balaraman, D. Milstein, C. Gunanathan, 2012 .

Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols.

E. Balaraman, D. Milstein, E. Fogler, 2012, Chemical communications.

Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO

David Milstein, Linda J. W. Shimon, L. Shimon, 2011, Nature Chemistry.

Direct hydrogenation of amides to alcohols and amines under mild conditions.

L. Shimon, E. Balaraman, D. Milstein, 2010, Journal of the American Chemical Society.

"Long-range" metal-ligand cooperation in H2 activation and ammonia-promoted hydride transfer with a ruthenium-acridine pincer complex.

L. Shimon, M. Iron, D. Milstein, 2010, Journal of the American Chemical Society.

Anionic d8 Alkyl Hydrides – Selective Formation and Reactivity of Anionic cis‐PtII Methyl Hydride

M. Iron, E. Poverenov, Yehoshoa Ben‐David, 2010 .

Stable Carbene and Diazoalkane Complexes of the Same Complex System. Synthesis, Structure, and Reactivity of PNP−Ru(II) Fluorenylidene and Diazofluorene Complexes

L. Shimon, D. Milstein, Jing Zhang, 2008 .

Advances in metal chemistry of quinonoid compounds: new types of interactions between metals and aromatics.

D. Milstein, A. Vigalok, 2001, Accounts of chemical research.

N-H activation of amines and ammonia by Ru via metal-ligand cooperation.

L. Shimon, M. Iron, D. Milstein, 2010, Journal of the American Chemical Society.

Mechanism of aryl chloride oxidative addition to chelated palladium(0) complexes

D. Milstein, M. Portnoy, 1993 .

Formal loss of an H radical by a cobalt complex via metal-ligand cooperation.

Y. Diskin‐Posner, L. Weiner, D. Milstein, 2013, Chemical communications.

Highly active PdII cyclometallated imine catalyst for the Suzuki reaction

D. Milstein, H. Weissman, 1999 .

Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex.

Yehoshoa Ben‐David, D. Milstein, S. Chakraborty, 2015, Journal of the American Chemical Society.

Manganese-Pincer-Catalyzed Nitrile Hydration, α-Deuteration, and α-Deuterated Amide Formation via Metal Ligand Cooperation

Y. Diskin‐Posner, Sayan Kar, Yehoshoa Ben‐David, 2021, ACS catalysis.

Directly Observed Oxidative Addition of a Strong Carbon-Carbon Bond to a Soluble Metal Complex

M. Gozin, D. Milstein, Shyh-Yeon Liou, 1995 .

Iron(II) complexes based on electron-rich, bulky PNN- and PNP-type ligands

L. Shimon, J. Zhang, Yehoshoa Ben‐David, 2006 .

Transition-metal-catalyzed cyclization of alkynoic acids to alkylidene lactones

N. Taylor, D. Milstein, T. Marder, 1987 .

Mechanistic studies of the rhodium-catalysed cyclization of α,ω-alkynoci acids to alkylidene lactones. Crystals structures of two iridium model catalytic intermediates

D. Milstein, J. Calabrese, W. C. Fultz, 1987 .

Metal Insertion into C-C Bonds in Solution.

D. Milstein, B. Rybtchinski, 1999, Angewandte Chemie.

A binuclear palladium(I) hydride. Formation, reactions, and catalysis

D. Milstein, M. Portnoy, 1994 .

Nitrogen-hydrogen activation. 1. Oxidative addition of ammonia to iridium(I). Isolation, structural characterization and reactivity of amidoiridium hydrides

D. Milstein, J. Calabrese, A. Casalnuovo, 1987 .

Mild, low-pressure carbonylation of (.pi.-allyl)palladium complexes

D. Milstein, 1982 .

Z-Selective (Cross-)Dimerization of Terminal Alkynes Catalyzed by an Iron Complex.

L. Shimon, Yehoshoa Ben‐David, D. Milstein, 2016, Angewandte Chemie.

Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols

D. Milstein, S. Chakraborty, P. Daw, 2018, ACS catalysis.

Unsaturated Pd(0), Pd(I), and Pd(II) complexes of a new methoxy-substituted benzyl phosphine. Aryl-X (X = Cl, I) oxidative addition, C-O cleavage, and Suzuki-Miyaura coupling of aryl chlorides

L. Shimon, D. Milstein, H. Weissman, 2004 .

Novel azine reactivity: facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI.

L. Shimon, Jan M. L. Martin, D. Milstein, 2003, Angewandte Chemie.

Selective sp3 C-H activation of ketones at the beta position by Ir(I). Origin of regioselectivity and water effect.

Jan M. L. Martin, A. Karton, Moran Feller, 2006, Journal of the American Chemical Society.

The cis-alkyl and cis-acylrhodium and iridium hydrides. Model intermediates in homogeneous catalysis

D. Milstein, 1984 .

Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes

Y. Diskin‐Posner, Amit Kumar, Yehoshoa Ben‐David, 2018, ACS catalysis.

Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex.

Y. Diskin‐Posner, Amit Kumar, D. Milstein, 2017, Journal of the American Chemical Society.

Cobalt-catalyzed hydrogenation of esters to alcohols: unexpected reactivity trend indicates ester enolate intermediacy.

Y. Diskin‐Posner, L. Shimon, D. Milstein, 2015, Angewandte Chemie.

Catalytic transformation of benzoic anhydrides into fluorenones and biphenyls

Y. Sasson, D. Milstein, J. Blum, 1970 .

Catalytic Furfural/5-Hydroxymethyl Furfural Oxidation to Furoic Acid/Furan-2,5-dicarboxylic Acid with H2 Production Using Alkaline Water as the Formal Oxidant

Sayan Kar, Yehoshoa Ben‐David, D. Milstein, 2022, Journal of the American Chemical Society.

Iron-Catalyzed Mild and Selective Hydrogenative Cross-Coupling of Nitriles and Amines To Form Secondary Aldimines.

D. Milstein, G. Leitus, S. Chakraborty, 2017, Angewandte Chemie.

Ruthenium Pincer-Catalyzed Acylation of Alcohols Using Esters with Liberation of Hydrogen under Neutral Conditions

Yehoshoa Ben‐David, D. Milstein, B. Gnanaprakasam, 2010 .

Metal-ligand cooperation in the trans addition of dihydrogen to a pincer Ir(I) complex: a DFT study.

M. Iron, D. Milstein, Eyal Ben-Ari, 2009, Dalton transactions.

Consecutive Thermal H2 and Light-Induced O2 Evolution from Water Promoted by a Metal Complex

David Milstein, L. Shimon, M. Iron, 2009, Science.

Direct conversion of alcohols to acetals and H(2) catalyzed by an acridine-based ruthenium pincer complex.

L. Shimon, D. Milstein, C. Gunanathan, 2009, Journal of the American Chemical Society.

Electron-rich, bulky PNN-type ruthenium complexes: synthesis, characterization and catalysis of alcohol dehydrogenation.

L. Shimon, D. Milstein, Jing Zhang, 2007, Dalton transactions.

Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C–C Bond Formation

Y. Diskin‐Posner, L. Shimon, Amit Kumar, 2020 .

Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium

Yehoshoa Ben‐David, D. Milstein, P. Daw, 2018, Journal of the American Chemical Society.

Selective hydrogenation of nitriles to primary amines catalyzed by a novel iron complex.

D. Milstein, G. Leitus, S. Chakraborty, 2016, Chemical communications.

Mechanistic investigations of the catalytic formation of lactams from amines and water with liberation of H2.

D. Milstein, G. Leitus, Julia R. Khusnutdinova, 2015, Journal of the American Chemical Society.

Oxidant-free conversion of cyclic amines to lactams and H2 using water as the oxygen atom source.

Yehoshoa Ben‐David, D. Milstein, Julia R. Khusnutdinova, 2014, Journal of the American Chemical Society.

Formation of Tertiary Amides and Dihydrogen by Dehydrogenative Coupling of Primary Alcohols with Secondary Amines Catalyzed by Ruthenium Bipyridine‐Based Pincer Complexes

E. Balaraman, Yehoshoa Ben‐David, D. Milstein, 2013 .

Simple and efficient catalytic reaction for the selective deuteration of alcohols

D. Milstein, E. Khaskin, 2013 .

Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes.

Yehoshoa Ben‐David, D. Milstein, Dipankar Srimani, 2013, Angewandte Chemie.

Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with either Alcohols or Esters: Manganese Pincer Complex as Catalyst.

Y. Diskin‐Posner, L. Avram, Amit Kumar, 2017, Angewandte Chemie.

Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols.

U. Das, Yehoshoa Ben‐David, D. Milstein, 2017, Journal of the American Chemical Society.

Template catalysis by manganese pincer complexes: oxa- and aza-Michael additions to unsaturated nitriles

D. Milstein, Shan Tang, 2019, Chemical science.

Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese

Y. Diskin‐Posner, U. Das, D. Milstein, 2018, Angewandte Chemie.

Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese.

Y. Diskin‐Posner, U. Das, D. Milstein, 2018, Angewandte Chemie.

Template Catalysis by Metal-Ligand Cooperation. C-C Bond Formation via Conjugate Addition of Non-activated Nitriles under Mild, Base-free Conditions Catalyzed by a Manganese Pincer Complex.

Yehoshoa Ben‐David, D. Milstein, G. Leitus, 2016, Journal of the American Chemical Society.

Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2018, ACS catalysis.

Hydride elimination from an iridium(III) alkoxide complex: a case in which a vacant cis coordination site is not required

D. Milstein, O. Blum, 2000 .

The first isolated, stable cis-hydridoalkylrhodium complexes and their reductive elimination reaction

D. Milstein, 1982 .

Oxidative addition of unactivated epoxides to iridium(I) complexes. Formation of stable cis-hydridoformylmethyl and -acylmethyl complexes

D. Milstein, J. Calabrese, 1982 .

Selective synthesis of primary amines directly from alcohols and ammonia.

D. Milstein, C. Gunanathan, 2008, Angewandte Chemie.

Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C–N bond

D. Milstein, M. Gandelman, 2000 .

Reaction of Aryl Iodides with (PCP)Pd(II)—Alkyl and Aryl Complexes: Mechanistic Aspects of Carbon—Carbon Bond Formation

M. Boom, H. Kraatz, Yehoshoa Ben‐David, 2001 .

Hydrogenative Depolymerization of Nylons

L. Avram, Amit Kumar, Yehoshoa Ben‐David, 2020, Journal of the American Chemical Society.

Heterogeneously catalyzed selective hydrogenation of amides to alcohols and amines

T. Bendikov, D. Milstein, P. Hu, 2018 .

Selective Hydrogenation of Nitriles to Secondary Imines Catalyzed by an Iron Pincer Complex

D. Milstein, S. Chakraborty, 2017 .

Unprecedented iron-catalyzed selective hydrogenation of activated amides to amines and alcohols.

Yehoshoa Ben‐David, D. Milstein, S. Chakraborty, 2016, Chemical communications.

Highly efficient, general hydrogenation of aldehydes catalyzed by PNP iron pincer complexes

T. Zell, Yehoshoa Ben‐David, D. Milstein, 2015 .

Efficient hydrogenation of ketones catalyzed by an iron pincer complex.

R. Langer, Yehoshoa Ben‐David, D. Milstein, 2011, Angewandte Chemie.

Mild, selective, general method of ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium

D. Milstein, J. Stille, 1979 .

Selective N-Formylation of Amines with H2 and CO2 Catalyzed by Cobalt Pincer Complexes

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2017 .

Catalytic selective cleavage of a strong C–C single bond by rhodium in solution

M. Boom, D. Milstein, Shyh-Yeon Liou, 1998 .

Methylene Arenium Cations via Quinone Methides and Xylylenes Stabilized by Metal Complexation

L. Shimon, D. Milstein, A. Vigalok, 1998 .

Formation and X-ray Structures of PCP Ligand Based Platinum(II) and Palladium(II) Macrocycles.

L. Shimon, F. Frolow, M. E. van der Boom, 1996, Inorganic chemistry.

Rational design in homogeneous catalysis. Iridium(I)-catalyzed addition of aniline to norbornylene via nitrogen-hydrogen activation

D. Milstein, J. Calabrese, A. Casalnuovo, 1988 .

Organometallic Pincer Chemistry

G. Koten, D. Milstein, A. Castonguay, 2013 .

Cationic, neutral, and anionic PNP Pd(II) and Pt(II) complexes: dearomatization by deprotonation and double-deprotonation of pincer systems.

Y. Diskin‐Posner, L. Shimon, M. Iron, 2010, Inorganic chemistry.

SELECTIVE TRANSFORMATION OF VICINAL-DISUBSTITUTED EPOXIDES INTO KETONES BY HOMOGENEOUS RHODIUM CATALYSTS

D. Milstein, J. Blum, O. Buchman, 1977 .

Manganese Catalyzed Hydrogenation of Carbamates and Urea Derivatives.

U. Das, M. Iron, Amit Kumar, 2019, Journal of the American Chemical Society.

Direct Synthesis of Amides by Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and Ammonia Catalyzed by a Manganese Pincer Complex: Unexpected Crucial Role of Base.

Amit Kumar, Yehoshoa Ben‐David, D. Milstein, 2019, Journal of the American Chemical Society.

Direct coupling of alcohols to form esters and amides with evolution of H2 using in situ formed ruthenium catalysts

W. Leitner, Yehoshoa Ben‐David, D. Milstein, 2012 .

Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics

D. Milstein, P. Daw, Amit Kumar, 2021, Chemical reviews.

Mechanism of the Manganese-Pincer-Catalyzed Acceptorless Dehydrogenative Coupling of Nitriles and Alcohols.

A. Poater, M. Solà, D. Milstein, 2019, Journal of the American Chemical Society.

Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia

Yehoshoa Ben‐David, D. Milstein, M. Montag, 2022, Chemical science.

Conversion of alcohols to carboxylates using water and base with H 2 liberation

D. Milstein, P. Hu, 2018 .

Ketone hydrogenation catalyzed by a new iron(II)–PNN complex

Y. Diskin‐Posner, Moran Feller, D. Milstein, 2016 .

A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation

Y. Diskin‐Posner, M. Iron, D. Milstein, 2015, Nature Communications.

System with potential dual modes of metal-ligand cooperation: highly catalytically active pyridine-based PNNH-Ru pincer complexes.

L. Shimon, D. Milstein, G. Leitus, 2014, Chemistry.

Direct catalytic olefination of alcohols with sulfones.

Yehoshoa Ben‐David, D. Milstein, G. Leitus, 2014, Angewandte Chemie.

Electron Transfer Behavior of Pincer-Type {RhNO}8 Complexes: Spectroscopic Characterization and Reactivity of Paramagnetic {RhNO}9 Complexes

D. Milstein, F. Doctorovich, C. Gaviglio, 2013 .

Selective Acceptorless Conversion of Primary Alcohols to Acetals and Dihydrogen Catalyzed by the Ruthenium(II) Complex Ru(PPh3)2(NCCH3)2(SO4)

Y. Diskin‐Posner, D. Milstein, G. Leitus, 2012 .

Ruthenium Pincer‐Catalyzed Acylation of Alcohols Using Esters with Liberation of Hydrogen under Neutral Conditions.

Yehoshoa Ben‐David, D. Milstein, B. Gnanaprakasam, 2011 .

Synthesis and reactivity of an iridium(I) acetonyl PNP complex. Experimental and computational study of metal-ligand cooperation in H-H and C-H bond activation via reversible ligand dearomatization

Y. Diskin‐Posner, L. Shimon, M. Iron, 2010 .

ortho C-H Activation of Haloarenes and Anisole by an Electron-Rich Iridium(I) Complex: Mechanism and Origin of Regio- and Chemoselectivity. An Experimental and Theoretical Study

L. Shimon, Jan M. L. Martin, D. Milstein, 2006 .

Selective ortho C-h activation of haloarenes by an Ir(I) system.

H. Rozenberg, L. Shimon, D. Milstein, 2003, Journal of the American Chemical Society.

Ligand‐Controlled Chemoselectivity in the Classical Oxidative Addition Reactions of MeI and Aldehydes to Rhodium(I) Complexes

D. Milstein, Roman Goikhman, 2001 .

Chelation versus Cyclometalation in a Cationic Dppn−RhI Complex − A Unique Rearrangement of Norbornadiene via C−H Activation of the Pyridazine Ring

L. Shimon, Yehoshoa Ben‐David, D. Milstein, 2003 .

Comparison of steric and electronic requirements for C-C and C-H bond activation. Chelating vs nonchelating case.

H. Rozenberg, D. Milstein, B. Rybtchinski, 2001, Journal of the American Chemical Society.

Methanol reduces an organopalladium(II) complex to a palladium(I) hydride. Crystallographic characterization of a hydrido-bridged palladium complex

F. Frolow, D. Milstein, M. Portnoy, 1991 .

Alkyl− and Aryl−Oxygen Bond Activation in Solution by Rhodium(I), Palladium(II), and Nickel(II). Transition-Metal-Based Selectivity

M. Boom, Yehoshoa Ben‐David, D. Milstein, 1998 .

Silanol-based pincer Pt(II) complexes: synthesis, structure, and unusual reactivity.

L. Shimon, D. Milstein, G. Leitus, 2008, Inorganic chemistry.

C-C versus C-H activation and versus agostic C-C interaction controlled by electron density at the metal center.

L. Shimon, D. Milstein, M. Gandelman, 2003, Chemistry.

CO-Induced Methyl Migration in a Rhodium Thiophosphoryl Pincer Complex and Its Comparison with Phosphine-Based Complexes: The Divergent Effects of S and P Donor Ligands

Jan M. L. Martin, Yehoshoa Ben‐David, D. Milstein, 2013 .

Metal—Ligand Cooperation

D. Milstein, Julia R. Khusnutdinova, 2015 .

Nucleophilic de-coordination and electrophilic regeneration of "hemilabile" pincer-type complexes: formation of anionic dialkyl, diaryl, and dihydride Pt(II) complexes bearing no stabilizing pi-acceptors.

H. Rozenberg, L. Shimon, E. Poverenov, 2004, Chemistry.

Formation of transition metal carbenes using haloalkylzinc reagents.

E. Poverenov, D. Milstein, 2007, Chemical communications.

Mechanism of a Directly Observed Beta-Hydride Elimination Process of Iridium Alkoxo Complexes

D. Milstein, O. Blum, 1995 .

DIMERIZATION OF TERMINAL EPOXIDES BY HOMOGENEOUS TRANSITION METAL COMPLEXES. A NOVEL SYNTHESIS OF CARBOXYLIC ESTERS

D. Milstein, J. Blum, B. Zinger, 1978 .

Reductive dechlorination of aryl chlorides catalyzed by palladium complexes containing basic, chelating phosphines

M. Gozin, D. Milstein, Y. Ben-David, 1992 .

Hexamethylenetetramine formation by Ru-catalyzed methanol hydrogen transfer

D. Milstein, 1986 .

Oxidation of Organic Compounds Using Water as the Oxidant with H2 Liberation Catalyzed by Molecular Metal Complexes

Sayan Kar, D. Milstein, 2022, Accounts of chemical research.

Efficient hydrogen liberation from formic acid catalyzed by a well-defined iron pincer complex under mild conditions.

T. Zell, Yehoshoa Ben‐David, D. Milstein, 2013, Chemistry.

Pyridine-Based Sulfoxide Pincer Complexes of Rhodium and Iridium

Y. Diskin‐Posner, L. Shimon, D. Milstein, 2008 .

Oxidative addition of water to novel Ir(I) complexes stabilized by dimethyl sulfoxide ligands.

H. Rozenberg, L. Shimon, D. Milstein, 2002, Journal of the American Chemical Society.

Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal‐Ligand Cooperation by Aromatization/Dearomatization

T. Zell, D. Milstein, 2015 .

Homogeneous catalytic transformation of aryl-substituted epoxides by some complexes of the platinum metals

D. Milstein, J. Blum, O. Buchman, 1974 .

Naphthyl-Based PCP Platinum Complexes. Nucleophilic Activation of Coordinated CO and Synthesis of a Pt(II) Formyl Complex

L. Shimon, E. Poverenov, D. Milstein, 2007 .

RHODIUM AND PALLADIUM COMPLEXES OF A 3,5-LUTIDINE-BASED PHOSPHINE LIGAND

H. Kraatz, M. Gozin, D. Milstein, 1996 .

Exclusive C-C activation and an apparent α-H elimination with a rhodium phosphinite pincer complex

L. Shimon, Yehoshoa Ben‐David, D. Milstein, 2006 .

B-C bond cleavage of BArF anion upon oxidation of rhodium(I) with AgBArF. Phosphinite rhodium(I), rhodium(II), and rhodium(III) pincer complexes

L. Shimon, L. Weiner, D. Milstein, 2008 .

Formation of Stable trans-Dihydride Ruthenium(II) and 16-Electron Ruthenium(0) Complexes Based on Phosphinite PONOP Pincer Ligands. Reactivity toward Water and Electrophiles

Y. Diskin‐Posner, L. Shimon, Yehoshoa Ben‐David, 2009 .

Reactivity and stability of platinum(II) formyl complexes based on PCP-type ligands. The significance of sterics.

Y. Diskin‐Posner, L. Shimon, D. Vuzman, 2007, Dalton Transactions.

C-Metalated Diazoalkane Complexes of Platinum Based on PCP- and PCN-Type Ligands

L. Shimon, E. Poverenov, D. Milstein, 2005 .

Effect of CO on the oxidative addition of arene C-H bonds by cationic rhodium complexes.

Y. Diskin‐Posner, L. Shimon, Jan M. L. Martin, 2010, Chemistry.

Synthesis and Structure of New Osmium−PCP Complexes. Osmium-Mediated C−C Bond Activation

H. Rozenberg, L. Shimon, D. Milstein, 2001 .

The First Observation and Kinetic Evaluation of a Single Step Metal Insertion into a C−C Bond

D. Milstein, L. Konstantinovski, A. Vigalok, 2000 .

The Methylene-Transfer Reaction: Synthetic and Mechanistic Aspects of a Unique C−C Coupling and C−C Bond Activation Sequence

H. Rozenberg, L. Shimon, M. Boom, 2000 .

Selective C - C vs C - H bond activation by rhodium(I) PCP pincer complexes. A computational study

Jan M. L. Martin, D. Milstein, A. Sundermann, 2000 .

CARBON-CARBON VS CARBON-HYDROGEN BOND ACTIVATION BY RUTHENIUM(II) AND PLATINUM(II) IN SOLUTION

M. Boom, H. Kraatz, Yehoshoa Ben‐David, 1999 .

Solvent-controlled selectivity toward exclusive C-C or C-H bond activation by a cationic metal center

D. Milstein, B. Rybtchinski, 1999 .

A Room Temperature Direct Metal Insertion into a Nonstrained Carbon−Carbon Bond in Solution. C−C vs C−H Bond Activation

Yehoshoa Ben‐David, D. Milstein, B. Rybtchinski, 1996 .

Synthesis, structure and reactivity of NO+, NO˙ and NO- pincer PCN-Rh complexes.

Yehoshoa Ben‐David, D. Milstein, F. Doctorovich, 2020, Dalton transactions.

Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal-Ligand Cooperation

D. Milstein, 2011 .

Competitive C-I versus C-CN reductive elimination from a Rh(III) complex. Selectivity is controlled by the solvent.

Y. Diskin‐Posner, L. Shimon, M. Iron, 2008, Journal of the American Chemical Society.

Pincer Systems as Models for the Activation of Strong Bonds: Scope and Mechanism

D. Milstein, B. Rybtchinski, 2007 .

C—C versus C—H Bond Oxidative Addition in PCX (X = P,N,O) Ligand Systems: Facility, Mechanism, and Control

D. Milstein, B. Rybtchinski, 2005 .

Challenging metal-based transformations. From single-bond activation to catalysis and metallaquinonoids

D. Milstein, 2003 .

Ru-catalyzed oxidative coupling of arenes with olefins using O(2).

D. Milstein, H. Weissman, X. Song, 2001, Journal of the American Chemical Society.

Exclusive C–C Oxidative Addition in a Rhodium Thiophosphoryl Pincer Complex and Computational Evidence for an η3-C–C–H Agostic Intermediate

Y. Diskin‐Posner, Jan M. L. Martin, Yehoshoa Ben‐David, 2012 .

Mechanism of reductive elimination. Reaction of alkylpalladium(II) complexes with tetraorganotin, organolithium, and Grignard reagents. Evidence for palladium(IV) intermediacy

D. Milstein, J. Stille, 1979 .

SELECTIVE ACTIVATION OF ALKYL- AND ARYL-OXYGEN SINGLE BONDS IN SOLUTION WITH TRANSITION METAL COMPLEXES

M. Boom, Yehoshoa Ben‐David, D. Milstein, 1997 .

Formation of iridalactones by CH2-O oxidative addition of propiolactone to iridium(I)

F. Frolow, D. Milstein, A. Zlota, 1990 .

A pincer-type anionic platinum(0) complex.

D. Milstein, Leonid Schwartsburd, L. Konstantinovski, 2008, Angewandte Chemie.

Facile NH Cleavage of Ammonia

D. Milstein, R. Koelliker, 1991 .

Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

U. Das, Amit Kumar, D. Milstein, 2020, Green Chemistry.

Electron-rich siloxane-platinum complexes - Synthesis, structures, and reactivity

L. Shimon, D. Milstein, G. Leitus, 2005 .

C–F bond activation by iridium(I). A unique process involving P–C bond cleavage, P–F bond formation and net retention of oxidation state

F. Frolow, D. Milstein, O. Blum, 1991 .

Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier

Amit Kumar, D. Milstein, N. Espinosa‐Jalapa, 2018, Journal of the American Chemical Society.

Direct Observation of OH Reductive Elimination from IrIII Complexes

D. Milstein, O. Blum, 1995 .

C-H vs. O-H reductive elimination of methanol from a metal complex. Which is a more likely process?

D. Milstein, 1986 .

Reactivity of rhodium-triflate complexes with diphenylsilane: evidence for silylene intermediacy in stoichiometric and catalytic reactions.

D. Milstein, Roman Goikhman, 2005, Chemistry.

A general method for preparation of metal carbenes via solution- and polymer-based approaches.

E. Poverenov, Yehoshoa Ben‐David, D. Milstein, 2005, Journal of the American Chemical Society.

Ruthenium, [6‐[[Bis(1,1‐dimethylethyl)phosphino‐κP] methylene]‐N,N‐diethyl‐1,6‐dihydro‐2‐pyridinemethanaminato‐κN1,κN2]carbonylhydride

D. Milstein, C. Gunanathan, 2009 .

Metal-stabilized phenoxonium cation.

H. Rozenberg, Yehoshoa Ben‐David, D. Milstein, 2003, Journal of the American Chemical Society.

METAL-MEDIATED GENERATION, STABILIZATION, AND CONTROLLED RELEASE OF A BIOLOGICALLY RELEVANT, SIMPLE PARA QUINONE METHIDE : BHT-QM

O. Rabin, D. Milstein, and Arkadi Vigalok, 1998 .

Oxidative addition of unactivated epoxides to iridium(I) complexes. Formation of stable cis-hydridoformylmethyl and -acylmethyl complexes

D. Milstein, J. Calabrese, 1982 .

Cobalt-catalyzed carbalkoxylation of olefins: a new mechanism

D. Milstein, John L. Huckaby, 1982 .

A new ligand system based on a bipyridine-functionalized calix[4]arene backbone leading to mono- and bimetallic complexes.

H. Rozenberg, L. Shimon, Yehoshoa Ben‐David, 2003, Inorganic Chemistry.

Discovery of the First Metallaquinone

L. Shimon, Jan M. L. Martin, Yehoshoa Ben‐David, 2000 .

The impact of weak C-H...Rh interactions on the structure and reactivity of trans-[Rh(CO)2(phosphine)2]+: an experimental and theoretical examination.

Y. Diskin‐Posner, L. Shimon, Jan M. L. Martin, 2008, Chemistry.

Is Rh(PMe3)3+ formed upon anion exchange of Rh(PMe3)4+CI−? Crystal and molecular structure of Rh(PMe3)4+BPh4− and Ir(PMe3)4+PF6−

F. Frolow, D. Milstein, J. Calabrese, 1990 .

DFT study of the structure and reactivity of the terminal Pt(IV)-oxo complex bearing no electron-withdrawing ligands.

Jan M. L. Martin, E. Poverenov, D. Milstein, 2010, Journal of the American Chemical Society.

Transition metal-catalyzed silanone generation

L. Shimon, M. Aizenberg, D. Milstein, 1996 .

Iridium- and rhodium-silanol complexes: Synthesis and reactivity

L. Shimon, M. Aizenberg, D. Milstein, 2003 .

New Tridentate Phosphine Rhodium and Iridium Complexes, Including a Stable Rhodium(I) Silyl. Si−S Activation and a Strong Effect of X in (PP2)M−X (X = H, Cl, Me) on Si−H Activation

L. Shimon, M. Aizenberg, Yehoshoa Ben‐David, 2002 .

Reversible Cyclometalation of Silyl Ligands. First X-ray Structure of an Iridium(I) Silyl That Is Not Stabilized by Chelation

M. Aizenberg, D. Milstein, 1996 .

C-H rather than O–H activation: synthesis and molecular structure of a cationic cis-hydrido-σ-acetylide complex of rhodium

D. Milstein, J. Calabrese, T. Herskovitz, 1987 .

Direct observation of reductive elimination of methyl iodide from a rhodium(III) pincer complex: the importance of sterics.

D. Milstein, C. Frech, 2006, Journal of the American Chemical Society.

Solvent-dependent interconversions between Rh(I), Rh(II), and Rh(III) complexes of an aryl-monophosphine ligand.

L. Shimon, Yehoshoa Ben‐David, D. Milstein, 2007, Chemistry.

Metallacarbenes from diazoalkanes: an experimental and computational study of the reaction mechanism.

H. Rozenberg, Jan M. L. Martin, D. Milstein, 2003, Journal of the American Chemical Society.

Gd3+ complexes as potential spin labels for high field pulsed EPR distance measurements.

D. Goldfarb, Jan M. L. Martin, D. Milstein, 2007, Journal of the American Chemical Society.

Dimethylsulfoxide as a ligand for RhI and IrI complexes--isolation, structure, and reactivity towards X-H bonds (X=H, OH, OCH3).

H. Rozenberg, L. Shimon, D. Milstein, 2003, Chemistry.

Oxidative addition of water and aliphatic alcohols by IrCl(trialkylphosphine)(3).

D. Milstein, O. Blum, 2002, Journal of the American Chemical Society.

Water-soluble contrast agents targeted at the estrogen receptor for molecular magnetic resonance imaging.

David Milstein, Ayelet Vilan, Erez Eyal, 2007, Bioconjugate chemistry.

Benzyl Cation Stabilized by Metal Complexation. Relative Stability of Coordinated Methylene Arenium, π-Benzylic, and σ-Benzylic Structures

Jan M. L. Martin, E. Poverenov, D. Milstein, 2013 .

Synthesis and reactivity of the methylene arenium form of a benzyl cation, stabilized by complexation.

E. Poverenov, D. Milstein, G. Leitus, 2006, Journal of the American Chemical Society.

Isolation and chemical properties of ruthenium and iron hydroxymethyl complexes (η5-C5H5)M(CO)2CH2OH

D. Milstein, S. S. Wreford, Y. Lin, 1983 .

Formylation of Aryl Chlorides Catalyzed by a Palladium Complex.

D. Milstein, Y. Ben-David, M. Portnoy, 1990 .

Formation of P,C-chelated palladium complexes by phosphine-assisted oxidative addition of an aliphatic CCl bond

D. Milstein, Y. Ben-David, P. Moshe, 1995 .

Chelate-Assisted, Pd-Catalyzed Efficient Carbonylation of Aryl Chlorides.

Yehoshoa Ben‐David, D. Milstein, M. Portnoy, 1990 .

Clarification of a remarkable chelate effect leads to palladium-catalyzed base-free olefin arylation

Yehoshoa Ben‐David, D. Milstein, M. Portnoy, 1993 .

Aspects of Intermediacy of Carbalkoxymetal Complexes in CO Reactions

D. Milstein, 1989 .

(Hydroxyacetyl)iridium and -rhodium complexes: model compounds for CO hydrogenation

D. Milstein, J. Calabrese, W. C. Fultz, 1986 .

Isolation of cis-hydridoacylrhodium(III) complexes not stabilized by chelation. Reductive elimination and decarbonylation

D. Milstein, 1982 .

Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex

D. Milstein, 1982 .

Transition-metal-catalyzed carbon-carbon bond formation via carbon-hydrogen activation. Intermolecular hydroacylation: the addition of aldehydes to alkenes

D. Roe, D. Milstein, T. Marder, 1988 .

Rhodaoxetane: synthesis, structure, and theoretical evaluation

C. Unaleroglu, F. Frolow, D. Milstein, 1993 .

Highly Efficient Additive-Free Dehydrogenation of Neat Formic Acid

Sayan Kar, Yehoshoa Ben‐David, D. Milstein, 2021, Nature Catalysis.

Palladium‐Catalyzed Cross‐Methylation of Aryl Chlorides by Stabilized Dimethylaluminum and ‐Gallium Reagents.

D. Milstein, Y. Ben-David, J. Blum, 2000 .

UNEXPECTED ISOMERIZATION OF A CIS- INTO A TRANS-DIHYDRIDE COMPLEX. A NEUTRAL LATE TRANSITION METAL COMPLEX AS A HYDRIDE DONOR

Yehoshoa Ben‐David, D. Milstein, B. Rybtchinski, 1997 .

Aliphatic and aromatic C–H activation of benzo[h]quinolines by Rh(I). Unique precursor dependent formation of mono-, di- and trinuclear complexes

Y. Diskin‐Posner, L. Shimon, D. Milstein, 2011 .

Evidence for an unprecedented Ir(H)(NH3) ⇄ Ir(H2)(NH2) equilibrium and hydrogen exchange between NH and CH bonds

D. Milstein, R. Koelliker, 1991 .

The first fully characterized neutral and cationic rhodium(I)-complexes containing DMSO as the only dative ligand; S-, O- and bridging S,O-bidentate binding modes.

H. Rozenberg, D. Milstein, Reto Dorta, 2002, Chemical communications.

Ruthenium dihydrogen complex for C-H activation: Catalytic H/D exchange under mild conditions

W. Leitner, Yehoshoa Ben‐David, D. Milstein, 2008 .

A unique dioxo alkene hydride metal complex: [RhH(O2){CH2C(CH2CH2PBut2)2}]

L. Shimon, D. Milstein, A. Vigalok, 1996 .

Dimerization of terminal epoxides by homogeneous transition-metal complexes. A novel synthesis of carboxylic esters

D. Milstein, J. Blum, B. Zinger, 1978 .

Synthesis and x-ray structure of a simple metallaoxetane. Metal-based selectivity in oxidative addition

F. Frolow, D. Milstein, A. Zlota, 1990 .

Metal-Stabilized Methylene Arenium and σ-Arenium Compounds: Synthesis, Structure, Reactivity, Charge Distribution, and Interconversion

L. Shimon, Yehoshoa Ben‐David, D. Milstein, 1999 .

Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and N-Heteroarenes: H2 and N–H Activation by Metal–Ligand Cooperation as Key Steps

Y. Diskin‐Posner, D. Milstein, Yaoyu Liang, 2023, Journal of the American Chemical Society.

Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack

M. Aizenberg, D. Milstein, 1994 .

CARBON-CARBON BOND ACTIVATION BY RHODIUM(I) IN SOLUTION. COMPARISON OF SP2-SP3 VS SP3-SP3 C-C, C-H VS C-C, AND AR-CH3 VS AR-CH2CH3 ACTIVATION

M. Boom, M. Gozin, Yehoshoa Ben‐David, 1998 .

ISOLATION, CHARACTERIZATION, AND INTERCONVERSIONS OF (ET3P)2IR(C2H4)NCL (N 1,2)

M. Aizenberg, D. Milstein, Thomas H. Tulip, 1996 .

Exclusive C-Si bond formation upon reaction of a platinum(II) alkyl with silanes

M. Boom, D. Milstein, J. Ott, 1998 .

Consecutive cyclometalation by platinum(II)

L. Shimon, M. Boom, Yehoshoa Ben‐David, 1996 .

Sustainable catalysis with fluxional acridine-based PNP pincer complexes

Sayan Kar, D. Milstein, 2022, Chemical communications.

Facial (methyl)(hydrido)(silyl) Complexes of Iridium: Synthesis, X-ray Structures, and Reductive Elimination Reactions. Facile Formation of Silametalacycles by Metalation of Silyl Ligands

M. Aizenberg, D. Milstein, 1995 .

Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight

Sayan Kar, Amit Kumar, Yehoshoa Ben‐David, 2020, ACS catalysis.

Aromatic vs aliphatic C-H bond activation by rhodium(I) as a function of agostic interactions: catalytic H/D exchange between olefins and methanol or water.

Jan M. L. Martin, Yehoshoa Ben‐David, D. Milstein, 2003, Journal of the American Chemical Society.

Unprecedented Iron‐Catalyzed Selective Hydrogenation of Activated Amides to Amines and Alcohols.

Yehoshoa Ben‐David, D. Milstein, S. Chakraborty, 2016 .

Reactivity of [Ir(COE)2(solvent)2]PF6 Complexes toward Alkylphosphines: Room-Temperature C−H Activation (Cyclometalation) and Isolation of a 14-Electron Alkyl−Iridium(III) Complex

D. Milstein, Reto Dorta, Roman Goikhman, 2003 .

POLYMERIC SUPPORTS FOR CATALYSTS.

J. Lieto, B. Gates, D. Milstein, 1983 .

Efficient Hydrogenation of Biomass‐Derived Cyclic Di‐Esters to 1,2‐Diols.

E. Balaraman, D. Milstein, E. Fogler, 2012 .

Metal–Ligand Cooperation as Key in Formation of Dearomatized NiII–H Pincer Complexes and in Their Reactivity toward CO and CO2

Y. Diskin‐Posner, L. Avram, Moran Feller, 2018, Organometallics.

Why Does the Tetrakis(trimethylphosphine)iridium(III) Hydridochloride Cation Adopt the Sterically and Electronically Unfavorable Cis Geometry

Jan M. L. Martin, D. Milstein, O. Blum, 2000 .

Bond activation and catalysis by ruthenium pincer complexes.

D. Milstein, C. Gunanathan, 2014, Chemical reviews.

Efficient homogeneous catalytic hydrogenation of esters to alcohols.

Yehoshoa Ben‐David, D. Milstein, G. Leitus, 2006, Angewandte Chemie.

Imidazole synthesis by transition metal free, base-mediated deaminative coupling of benzylamines and nitriles.

L. Shimon, U. Das, D. Milstein, 2017, Chemical communications.

Iron-Catalyzed Mild and Selective Hydrogenative Cross-Coupling of Nitriles and Amines To Form Secondary Aldimines.

D. Milstein, G. Leitus, S. Chakraborty, 2017, Angewandte Chemie.

[2,6‐Bis[(bis(1‐methylethyl)phosphino‐P]methyl]‐3,5 dimethylphenyl]methyl‐C]tri‐fluoroacetato‐O)palladium

D. Milstein, 2002 .

Pyridine-Based PCP-Ruthenium Complexes: Unusual Structures and Metal-Ligand Cooperation.

Y. Diskin‐Posner, Yehoshoa Ben‐David, D. Milstein, 2019, Journal of the American Chemical Society.

Hydrogenative alkene perdeuteration aided by a transient cooperative ligand

D. Milstein, M. Montag, Yaoyu Liang, 2023, Nature Chemistry.

Bottom-Up Construction of a CO2-Based Cycle for the Photocarbonylation of Benzene, Promoted by a Rhodium(I) Pincer Complex.

Y. Diskin‐Posner, L. Shimon, Moran Feller, 2016, Journal of the American Chemical Society.

N-Substituted Hydrazones by Manganese-Catalyzed Coupling of Alcohols with Hydrazine: Borrowing Hydrogen and Acceptorless Dehydrogenation in One System.

Y. Diskin‐Posner, U. Das, Yehoshoa Ben‐David, 2018, Angewandte Chemie.

Polyoxymethylene Upcycling into Methanol and Methyl Groups Catalyzed by a Manganese Pincer Complex.

Y. Diskin‐Posner, D. Milstein, M. Montag, 2024, Journal of the American Chemical Society.

Metal–Ligand Cooperation with Thiols as Transient Cooperative Ligands: Acceleration and Inhibition Effects in (De)Hydrogenation Reactions

D. Milstein, M. Montag, Jie Luo, 2024, Accounts of chemical research.

Synthesis of peptides and pyrazines from β-amino alcohols through extrusion of H2 catalyzed by ruthenium pincer complexes: ligand-controlled selectivity.

E. Balaraman, Yehoshoa Ben‐David, D. Milstein, 2011, Angewandte Chemie.

Iridium complexes of acridine-based PNP-type pincer ligands: Synthesis, structure and reactivity

Y. Diskin‐Posner, L. Shimon, L. Avram, 2023, Inorganica Chimica Acta.

Efficient hydrogen liberation from formic acid catalyzed by a well-defined iron pincer complex under mild conditions.

T. Zell, Yehoshoa Ben‐David, D. Milstein, 2013, Chemistry.

Catalytic Main‐group Metal Complexes of Phosphine‐based Pincer Ligands

D. Milstein, M. Montag, 2023, Israel Journal of Chemistry.

sp3 C–H and sp2 C–H agostic ruthenium complexes: a combined experimental and theoretical study ☆

H. Rozenberg, L. Shimon, M. Boom, 2004 .

Advances in metal chemistry of quinonoid compounds: new types of interactions between metals and aromatics.

D. Milstein, A. Vigalok, 2001, Accounts of chemical research.