S. A. Pullarkat

发表

Synthesis of Stereoprojecting, Chiral N-C(sp3)-E Type Pincer Complexes

Yongxin Li, L. Balázs, Wee Shan Tay, 2018, Organometallics.

Palladacycle promoted base controlled regio- and enantioselective hydrophosphination of 2-pyridylacrylate/amide and the cytotoxicity of their gold complexes.

Pengcheng Zhu, Yongxin Li, S. A. Pullarkat, 2015, Dalton transactions.

Chiral cyclopalladated complex promoted asymmetric synthesis of diester-substituted P,N-ligands via stepwise hydrophosphination and hydroamination reactions.

Yongxin Li, S. A. Pullarkat, P. Leung, 2012, Dalton transactions.

Stability and Reactivity of Cyclometallated Naphthylamine Complexes in Pd–C Bond Insertion Reactions with Coordinated Alkynylphosphanes

Yongxin Li, S. A. Pullarkat, P. Leung, 2013 .

Intermolecular Insertion of Dialkynylphosphanes into the M–C Bond of Cyclopalladated Rings through Activation by Cyclometallated Amines

Yongxin Li, S. A. Pullarkat, P. Leung, 2012 .

Asymmetric hydroarsination reactions toward synthesis of alcohol functionalised C-chiral As–P ligands promoted by chiral cyclometallated complexes

Yongxin Li, S. A. Pullarkat, P. Leung, 2012 .

Chiral palladacycle promoted asymmetric synthesis of functionalized bis-phosphine monoxide ligand

Yongxin Li, Yi Ding, S. A. Pullarkat, 2011 .

Synthesis of Homo‐ and Hetero‐Bimetallic Arsenic Complexes by Means of Regioselective Monoinsertion of Alkynylarsane into the Pd–C Bond of a Palladacycle

Yongxin Li, S. A. Pullarkat, P. Leung, 2011 .

Synthesis of a Chiral Palladacycle and Its Application in Asymmetric Hydrophosphanation Reactions

Yongxin Li, Yi Ding, S. A. Pullarkat, 2010 .

Novel Enantioselective Synthesis of Functionalized Pyridylarsanes by a Chiral Palladium Template Promoted Asymmetric Hydroarsanation Reaction

Yongxin Li, S. A. Pullarkat, P. Leung, 2009 .

Rational Design of a Novel Chiral Palladacycle: Synthesis, Optical Resolution, and Stereochemical Evaluation

Yongxin Li, Yi Ding, S. A. Pullarkat, 2009 .

Asymmetric synthesis of 1,2-bis(diphenylphosphino)-1-phenylethane via a chiral palladium template promoted hydrophosphination reaction

Yongxin Li, S. A. Pullarkat, P. Leung, 2009 .

Enantioselective, High‐Yielding Synthesis of Alcohol‐Functionalized Diphosphanes Utilizing Asymmetric Control with a Chiral Auxiliary

Yongxin Li, S. A. Pullarkat, P. Leung, 2009 .

Design, Synthesis, and Stereochemical Evaluation of a Novel Chiral Amine–Palladacycle

Yongxin Li, Yi Ding, S. A. Pullarkat, 2008 .

Asymmetric synthesis of a P-chiral heteroditopic ligand via chiral metal template promoted cycloaddition between 3,4-dimethyl-1-phenylphosphole and its sulfonated analog

J. Vittal, S. A. Pullarkat, P. Leung, 2006 .

Alkali Additives Enable Efficient Large Area (>55 cm2) Slot‐Die Coated Perovskite Solar Modules

Wei Lin Leong, A. Kanwat, S. Mhaisalkar, 2022, Advanced Functional Materials.

Palladacycle-Catalyzed Tandem Allylic Amination/Allylation Protocol for One-Pot Synthesis of 2-Allylanilines from Allylic Alcohols

Yongxin Li, S. A. Pullarkat, P. Leung, 2012 .

C-As Bond Formation Reactions for the Preparation of Organoarsenic(III) Compounds.

Wee Shan Tay, S. A. Pullarkat, S. Pullarkat, 2020, Chemistry, an Asian journal.

New thioether–dithiolate complexes of Cp∗Ir and some reactivity features

Yongxin Li, S. A. Pullarkat, Chang Xu, 2012 .

Air-stable phosphine organocatalysts for the hydroarsination reaction

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2020 .

Palladacycle catalyzed asymmetric P-H addition of diarylphosphines to N-enoyl phthalimides.

Yongxin Li, Yunpeng Lu, S. A. Pullarkat, 2014, Chemistry.

Palladium(II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines.

Yongxin Li, S. A. Pullarkat, P. Leung, 2010, Chemical communications.

Catalytic and mechanistic developments of the Nickel(II) pincer complex-catalyzed hydroarsination reaction.

Yongxin Li, Yunpeng Lu, Wee Shan Tay, 2019, Chemistry.

The synthesis and efficient one-pot catalytic "self-breeding" of asymmetrical NC(sp(3))E-hybridised pincer complexes.

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2016, Chemical communications.

Grignard reagents-catalyzed hydroboration of aldehydes and ketones

Li Xu, S. A. Pullarkat, Mengtao Ma, 2020 .

Copper(II) Triflate Catalyzed Allylic Arylation of Allylic Alcohols: Direct and Selective Access to C‐Allylanilines

Jinglei Yang, S. A. Pullarkat, K. Chen, 2013 .

Access to a Chiral Phosphine–NHC Palladium(II) Complex via the Asymmetric Hydrophosphination of Achiral Vinyl Azoles

Yongxin Li, S. A. Pullarkat, P. Leung, 2021, Organometallics.

Asymmetric synthesis of enaminophosphines via palladacycle-catalyzed addition of Ph2PH to α,β-unsaturated imines.

Yongxin Li, S. A. Pullarkat, P. Leung, 2012, The Journal of organic chemistry.

Catalytic Approach toward Chiral P,N-Chelate Complexes Utilizing the Asymmetric Hydrophosphination Protocol.

Yongxin Li, Yunpeng Lu, S. A. Pullarkat, 2020, Inorganic chemistry.

A one-pot diastereoselective self assembly of C-stereogenic copper(I) diphosphine clusters.

Yongxin Li, S. A. Pullarkat, Xianghua Yang, 2014, Inorganic chemistry.

Nickel catalyzed enantioselective hydroarsination of nitrostyrene.

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2017, Chemical communications.

Ytterbium-Catalyzed Hydroboration of Aldehydes and Ketones.

Li Xu, S. A. Pullarkat, Mengtao Ma, 2018, The Journal of organic chemistry.

Synthesis, structural characterisation and stereochemical investigation of chiral sulfur-functionalised N-heterocyclic carbene complexes of palladium and platinum.

Yongxin Li, S. A. Pullarkat, P. Leung, 2013, Chemistry.

N-Heterocyclic Carbene C,S Palladium(II) π-Allyl Complexes: Synthesis, Characterization, and Catalytic Application In Allylic Amination Reactions

Yongxin Li, S. A. Pullarkat, P. Leung, 2013 .

Synthesis and characterization of conformationally rigid chiral pyridine-N-heterocyclic carbene-based palladacycles with an unexpected Pd-N bond cleavage.

Yongxin Li, S. A. Pullarkat, M. Chiang, 2013, Chirality.

Chiral Metal Complex-Promoted Asymmetric Hydrophosphinations

S. A. Pullarkat, P. Leung, 2011 .

Chemoselective Synthesis and Evaluation of β-Oxovinylarsines as an Arsenic Synthetic Precursor

Yongxin Li, Yunpeng Lu, Wee Shan Tay, 2020 .

Chelating Phosphine-N-Heterocyclic Carbene Platinum Complexes via Catalytic Asymmetric Hydrophosphination and Their Cytotoxicity Toward MKN74 and MCF7 Cancer Cell Lines.

N. Tan, Yongxin Li, S. A. Pullarkat, 2021, Inorganic chemistry.

Desymmetrization of Achiral Heterobicyclic Alkenes through Catalytic Asymmetric Hydrophosphination.

Yongxin Li, S. A. Pullarkat, P. Leung, 2018, Chemistry, an Asian journal.

Domino cyclization-alkylation protocol for the synthesis of 2,3-functionalized indoles from o-alkynylanilines and allylic alcohols.

S. A. Pullarkat, Chang Xu, V. Murugan, 2012, Organic & biomolecular chemistry.

A tandem Heck-aza-Michael addition protocol for the one-pot synthesis of isoindolines from unprotected amines.

S. A. Pullarkat, K. Chen, 2012, Organic & biomolecular chemistry.

Access to C-Stereogenic PN(sp2)P Pincer Ligands via Phosphapalladacycle Catalyzed Asymmetric Hydrophosphination

Yongxin Li, S. A. Pullarkat, P. Leung, 2021 .

Enantioselective addition of diphenylphosphine to 3-methyl-4-nitro-5-alkenylisoxazoles

Yongxin Li, S. A. Pullarkat, P. Leung, 2013 .

Synthesis, optical resolution, and stereochemical properties of a rationally designed chiral C–N palladacycle

Yongxin Li, S. A. Pullarkat, P. Leung, 2014 .

Investigating palladium pincer complexes in catalytic asymmetric hydrophosphination and hydroarsination.

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2019, Dalton transactions.

Catalyst-free and Solvent-free Cyanosilylation and Knoevenagel Condensation of Aldehydes

Li Xu, S. A. Pullarkat, P. Leung, 2018, ACS Sustainable Chemistry & Engineering.

Low-valent magnesium(i)-catalyzed cyanosilylation of ketones.

S. A. Pullarkat, Mengtao Ma, Jia Li, 2018, Chemical communications.

Evaluation of palladacycles as a non-rhodium based alternative for the asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated enones

S. A. Pullarkat, J. Wong, Kennard Gan, 2014 .

Efficient Iridium-Thioether-Dithiolate Catalyst for β-Alkylation of Alcohols and Selective Imine Formation via N-Alkylation Reactions

S. A. Pullarkat, Chang Xu, L. Goh, 2011 .

Challenges in cyclometalation: steric effects leading to competing pathways and η1,η2-cyclometalated iridium(iii) complexes.

Yongxin Li, S. A. Pullarkat, P. Leung, 2018, Dalton transactions.

Efficient access to a designed phosphapalladacycle catalyst via enantioselective catalytic asymmetric hydrophosphination.

Yongxin Li, S. A. Pullarkat, P. Leung, 2017, Dalton transactions.

Enantioselective phospha-Michael addition of diarylphosphines to β,γ-unsaturated α-ketoesters and amides.

Yongxin Li, S. A. Pullarkat, P. Leung, 2014, Chemical communications.

Palladacycle-catalyzed asymmetric hydrophosphination of enones for synthesis of C*- and P*-chiral tertiary phosphines.

Yongxin Li, S. A. Pullarkat, P. Leung, 2012, Inorganic chemistry.

Direct synthesis of chiral tertiary diphosphines via Pd(II)-catalyzed asymmetric hydrophosphination of dienones.

Yongxin Li, S. A. Pullarkat, P. Leung, 2011, Organic letters.

Triflic-Acid-Catalyzed Tandem Allylic Substitution–Cyclization Reaction of Alcohols with Thiophenols—Facile Access to Polysubstituted Thiochromans

Yongxin Li, S. A. Pullarkat, M. D. Vu, 2018, ACS omega.

Palladacycle mediated synthesis of cyano-functionalized chiral 1,2-diphosphine and subsequent functional group transformations

Yongxin Li, S. A. Pullarkat, P. Leung, 2011 .

Chiral Phosphapalladacycles as Efficient Catalysts for the Asymmetric Hydrophosphination of Substituted Methylidenemalonate Esters: Direct Access to Functionalized Tertiary Chiral Phosphines

Yongxin Li, S. A. Pullarkat, P. Leung, 2012 .

Novel Synthesis of Chiral 1,3-Diphosphines via Palladium Template Promoted Hydrophosphination and Functional Group Transformation Reactions

Yongxin Li, S. A. Pullarkat, P. Leung, 2010 .

Asymmetric Catalytic 1,2‐Dihydrophosphination of Secondary 1,2‐Diphosphines – Direct Access to Free P *‐ and P *, C *‐Diphosphines

Yongxin Li, S. A. Pullarkat, P. Leung, 2020 .

Recent Progress in Palladium-Catalyzed Asymmetric Hydrophosphination

S. A. Pullarkat, 2015 .

Asymmetric synthesis of diphosphine ligands containing phosphorus and carbon stereogenic centers by means of a chiral palladium complex promoted hydrophosphination reaction.

Yongxin Li, S. A. Pullarkat, P. Leung, 2009, Inorganic chemistry.

Catalytic asymmetric diarylphosphine addition to α-diazoesters for the synthesis of P-stereogenic phosphinates via P*-N bond formation.

Yongxin Li, L. Balázs, S. A. Pullarkat, 2020, The Journal of organic chemistry.

Evaluation of ferrocenyl phosphines as potent antimalarials targeting the digestive vacuole function of Plasmodium falciparum.

G. Subramanian, Rajesh Chandramohanadas, S. A. Pullarkat, 2019, Dalton transactions.

Screening of ferrocenyl–phosphines identifies a gold-coordinated derivative as a novel anticancer agent for hematological malignancies

A. Kizhakeyil, N. Verma, S. A. Pullarkat, 2018, RSC advances.

Highly Enantioselective Synthesis of (2-Pyridyl)phosphine Based C-Chiral Unsymmetrical P,N-Ligands Using a Chiral Palladium Complex

Yongxin Li, S. A. Pullarkat, P. Leung, 2009 .

Mechanistic Insights into the PdII‐Catalyzed Chemoselective N‐Demethylation vs. Cyclometalation Reactivity Pathways in 1‐Aryl‐N,N‐dimethylethanamines

Yongxin Li, Yi Ding, S. A. Pullarkat, 2014 .

One-pot β-alkylation of secondary alcohols with primary alcohols catalyzed by ruthenacycles

Li Yongxin, S. A. Pullarkat, X. Chang, 2012 .

Catalytic access to ferrocenyl phosphines bearing both planar and central chirality – A kinetic resolution approach via catalytic asymmetric P(III)–C bond formation

Yongxin Li, S. A. Pullarkat, J. Ng, 2020 .

Pd-catalyzed enantiodivergent and regiospecific phospha-Michael addition of diphenylphosphine to 4-oxo-enamides: efficient access to chiral phosphinocarboxamides and their analogues.

Yongxin Li, S. A. Pullarkat, P. Leung, 2015, Chemistry.

Palladacycle promoted asymmetric hydrophosphination of α,β-unsaturated sulfonyl fluorides

Yongxin Li, S. A. Pullarkat, P. Leung, 2019, Journal of Organometallic Chemistry.

Versatile Syntheses of Optically Pure PCE Pincer Ligands: Facile Modifications of the Pendant Arms and Ligand Backbones

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2015 .

Asymmetric 1,4-Conjugate Addition of Diarylphosphines to α,β,γ,δ-Unsaturated Ketones Catalyzed by Transition-Metal Pincer Complexes

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2015 .

Sterically bulky amido magnesium methyl complexes: syntheses, structures and catalysis

S. A. Pullarkat, Mengtao Ma, Jia Li, 2017 .

Unsymmetrical β-diketiminate magnesium(I) complexes: syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds

Li Xu, S. A. Pullarkat, Mengtao Ma, 2018 .

Efficient and stereoselective synthesis of monomeric and bimetallic pincer complexes containing Pd-bonded stereogenic carbons

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2016 .

Asymmetric synthesis of a chiral diarsine ligand via a cycloaddition reaction between 3,4-dimethyl-1-phenylarsole and diphenylvinylarsine

Li Xu, S. A. Pullarkat, P. Leung, 2014 .

Palladium-promoted asymmetric cycloaddition reaction of arsole via an unusual exo–endo stereochemically controlled method

S. A. Pullarkat, P. Leung, Mengtao Ma, 2014 .

Steric effects on the control of endo/exo-selectivity in the asymmetric cycloaddition reaction of 3,4-dimethyl-1-phenylarsole.

S. A. Pullarkat, P. Leung, Mengtao Ma, 2010, Dalton transactions.

Metal Effects on the Asymmetric Synthesis of a New Heterobidentate As/P=S Ligand

Yongxin Li, S. A. Pullarkat, P. Leung, 2010 .

Metal Effects on the Asymmetric Cycloaddition Reaction between 3,4-Dimethyl-1-phenylarsole and Diphenylvinylphosphine Oxide

Yongxin Li, S. A. Pullarkat, P. Leung, 2009 .

Template effects on the asymmetric cycloaddition reaction between 3,4-dimethyl-1-phenylarsole and diphenylvinylphosphine and their arsenic elimination reaction

Yongxin Li, S. A. Pullarkat, P. Leung, 2009 .

Asymmetric synthesis of a chiral hetero-bidentate As–P ligand containing both As and P-stereogenic centres

Yongxin Li, S. A. Pullarkat, P. Leung, 2008 .

Novel stereochemistry, reactivity, and stability of an arsenic heterocycle in a metal-promoted asymmetric cycloaddition reaction.

Yongxin Li, S. A. Pullarkat, P. Leung, 2007, Inorganic chemistry.

Mechanistic insights into the role of PC- and PCP-type palladium catalysts in asymmetric hydrophosphination of activated alkenes incorporating potential coordinating heteroatoms.

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2016, Dalton transactions.

Palladium catalyzed asymmetric hydrophosphination of α,β- and α,β,γ,δ-unsaturated malonate esters - efficient control of reactivity, stereo- and regio-selectivity.

Yongxin Li, S. A. Pullarkat, P. Leung, 2015, Dalton transactions.

Catalytic asymmetric synthesis of Pt- and Pd-PCP pincer complexes bearing a para-N pyridinyl backbone

Yongxin Li, S. A. Pullarkat, P. Leung, 2018 .

Metal effects on the asymmetric syntheses of chiral P−N bidentate ligands

S. A. Pullarkat, P. Leung, N. Zhang, 2016 .

Efficient Synthesis of Malonate Functionalized Chiral Phosphapalladacycles and their Catalytic Evaluation in Asymmetric Hydrophosphination of Chalcone

Yongxin Li, S. A. Pullarkat, P. Leung, 2018, European Journal of Inorganic Chemistry.

Stereogenic Lock in 1-Naphthylethanamine Complexes for Catalyst and Auxiliary Design: Structural and Reactivity Analysis for Cycloiridated Pseudotetrahedral Complexes

Yongxin Li, S. A. Pullarkat, P. Leung, 2018 .

Asymmetric Synthesis of Functionalized 1,2-Diphosphine via the Chemoselective Hydrophosphination of Coordinated Allylic Phosphines

Ashok K. Goel, Yongxin Li, S. A. Pullarkat, 2009 .

A novel approach toward asymmetric synthesis of alcohol functionalized C-chiral diphosphines via two-stage hydrophosphination of terminal alkynols.

Yongxin Li, S. A. Pullarkat, P. Leung, 2006, Inorganic chemistry.

Reactivity of cycloplatinated amine complexes : intramolecular C–C bond formation, C–H activation, and PPh2 migration in coordinated alkynylphosphines

Yongxin Li, S. A. Pullarkat, P. Leung, 2012 .

Divergent Reactivity of Phosphapalladacycles toward E–H (E = N, P, As) Bonds

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2020 .

Stereoelectronic and Catalytic Properties of Chiral Cyclometalated Phospha-palladium and -platinum Complexes

Yongxin Li, S. A. Pullarkat, P. Leung, 2014 .

Catalyst-free and solvent-free hydroboration of ketones

Li Xu, S. A. Pullarkat, P. Leung, 2019, New Journal of Chemistry.

Bis(allyl)ruthenium(IV)-initiated S-S and C-S Bond Cleavages in Tetraalkylthiuram Sulfides. Formation and X-ray Crystal Structures of Dithiocarbamato Complexes ∗

S. A. Pullarkat, Chang Xu, L. Goh, 2009 .

Kinetic resolution of racemic 5-alkylcyclohexenones via Pd(II)-catalyzed 1,4-additions of arylboronic acids – access to trans 3-alkyl-5-arylcyclohexanones

Yunpeng Lu, S. A. Pullarkat, J. Ng, 2015 .

Kinetic Resolution of Racemic 5‐Alkylcyclohexenones via Pd(II)‐Catalyzed 1,4‐Additions of Arylboronic Acids — Access to trans 3‐Alkyl‐5‐arylcyclohexanones.

Yunpeng Lu, S. A. Pullarkat, J. Ng, 2015 .

Asymmetric Construction of a Ferrocenyl Phosphapalladacycle from Achiral Enones and a Demonstration of Its Catalytic Potential

Yongxin Li, S. A. Pullarkat, Chang Xu, 2014 .

Palladacycle-catalyzed asymmetric intermolecular construction of chiral tertiary p-heterocycles by stepwise addition of H–P–H bonds to bis(enones)

Yongxin Li, S. A. Pullarkat, P. Leung, 2012 .

Palladacyclo-promoted asymmetric hydrophosphination reaction between diphenylphosphine and 2-ethynylpyridine

Yongxin Li, N. Zhang, S. A. Pullarkat, 2016 .

Palladium Template Promoted Asymmetric Synthesis of 1,2-Diphosphines by Hydrophosphination of Functionalized Allenes

Yongxin Li, Yi Ding, S. A. Pullarkat, 2010 .

Asymmetric synthesis of functionalized 1,3-diphosphines via chiral palladium complex promoted hydrophosphination of activated olefins.

Yongxin Li, N. Zhang, S. A. Pullarkat, 2010, Inorganic chemistry.

Catalytic Asymmetric Hydrophosphination as a Valuable Tool to Access Dihydrophosphinated Curcumin and Its Derivatives

N. Tan, Yongxin Li, S. A. Pullarkat, 2021, Organometallics.

Controllable synthesis of P-chiral 1,2- and 1,3-diphosphines via asymmetric Diels-Alder reactions involving functionalized allylic phosphines as dienophiles.

Yongxin Li, S. A. Pullarkat, P. Leung, 2009, Dalton transactions.

Inducing thermoreversible optical transitions in urethane-acrylate systems via ionic liquid incorporation for stretchable smart devices

Ankit, D. Accoto, Terence Yan King Ho, 2021 .

Computational and carbon-13 NMR studies of Pt-C bonds in P-C-P pincer complexes.

Yongxin Li, Wee Shan Tay, S. A. Pullarkat, 2016, Dalton transactions.