Masafumi Hirano

发表

Reaction of an oxaruthenacycle with DMAD. Stoichiometric transformations of 2,6-xylenol to allylic phenols and benzopyrans via sp(3) C-H bond cleavage reaction.

I. Izhab, Masafumi Hirano, Naoki Kurata, 2009, Dalton transactions.

Preferential Bond Activation of sp3 C–H over sp2 C–H in α,β-Unsaturated Carboxylic Acids by Ruthenium Complex

Masafumi Hirano, N. Komine, S. Komiya, 2001 .

Hydrogen Abstraction from Transition Metal Hydrides by Gold Alkoxides Giving Gold-Containing Heterodinuclear Complexes

A. Fukuoka, Y. Usui, Masafumi Hirano, 1997 .

Homogeneous Bimetallic Catalysts for Production of Carboxylic Acids from Carbon Dioxide, Hydrogen, and Organic Iodides

A. Fukuoka, Masafumi Hirano, S. Komiya, 1995 .

Synthesis of heterodinuclear ruthenium–manganese complex having μ-benzylidene ligand

Masafumi Hirano, N. Komine, S. Komiya, 2011 .

Multiple C–H Bond Cleavage of the Alkyl Group in (2,6-Dialkylphenoxo)ruthenium(II) Complexes

Masafumi Hirano, N. Komine, S. Komiya, 2014 .

Chapter 3 - Activation of Substrates with Polar Single Bonds

Masafumi Hirano, S. Komiya, M. Hirano, 2003 .

Synthesis, structure and reactions of a carbon dioxide complex of iron(0) containing 1,2-bis(diethylphosphino)ethane ligands

A. Fukuoka, Masafumi Hirano, S. Komiya, 1994 .

Ru(0)-Catalyzed Regioselective Synthesis of Borylated-1,4- and -1,5-Diene Building Blocks

Masafumi Hirano, N. Komine, Shione Okazaki, 2022, Organometallics.

Dibenzo[d,d′]benzo[2,1-b:3,4-b′]difurans with extended π-conjugated chains: synthetic approaches and properties

Masafumi Hirano, N. Komine, K. Nakano, 2022, New Journal of Chemistry.

New strategy for synthesising conjugated hexatrienylferrocenes via cross-dimerisation

S. Kawauchi, Masafumi Hirano, N. Komine, 2021 .

Polymerization of Alkyl Methacrylate Catalyzed by Hydridorhenium Complexes

Toru Suzuki, Masafumi Hirano, S. Komiya, 1999 .

Carbon–Hydrogen Bond Cleavage Reaction in Four-Coordinate (2,6-Dimethylbenzenethiolato)platinum(II) Complexes. Dramatic Acceleration by Thiolato Hydrogen Acceptor

Masafumi Hirano, N. Komine, S. Komiya, 2011 .

Preparation of highly dispersed nano-scale platinum composite polymer using reactive organoplatinum complexes

Masafumi Hirano, S. Komiya, N. Awazu, 2001 .

Synthesis of organo(siloxo)platinum and -palladium complexes and preparation of supported nanoclusters by facile ligand reduction

A. Fukuoka, Masafumi Hirano, S. Komiya, 1999 .

Synthesis and Structure of Novel Organo(siloxo)platinum Complexes. Facile Reduction by Dihydrogen

A. Fukuoka, Masafumi Hirano, S. Komiya, 1994 .

Synthesis and β-Hydrogen Elimination of Water-Soluble Dialkylplatinum(II) Complexes in Water

Masafumi Hirano, N. Komine, S. Komiya, 2003 .

Enhancement of β-Hydrogen Elimination Reaction on Platinum-containing Heterodinuclear Complexes

A. Fukuoka, Masafumi Hirano, S. Komiya, 1997 .

Synthesis and reactivity of organoplatinui-rhenium heterobimetallic complexes having sulfur ligands

A. Fukuoka, Masafumi Hirano, S. Komiya, 1996 .

Synthesis of hydridoplatinum–molybdenum (or tungsten) heterodinuclear complexes by β-hydrogen elimination of (dppe)EtPt–MCp(CO)3. Selective hydride transfer from Pt to Mo (or W)

A. Fukuoka, Masafumi Hirano, S. Komiya, 2000 .

C–O and C–S bond activation of allyl esters, ethers, and sulfides by low valent ruthenium complexes

Masafumi Hirano, S. Komiya, J. G. Planas, 1999 .

Synthesis, structure and reactions of a dinitrogen complex of iron(0), [Fe(N2)(depe)2] (depe = Et2PCH2CH2PEt2)

A. Fukuoka, Masafumi Hirano, S. Komiya, 1997 .

Synthesis of heterodinuclear hydride complexes by oxidative addition of a transition-metal hydride to Pt(0) and Pd(0) complexes ☆

Masafumi Hirano, N. Komine, S. Komiya, 2015 .

Alkene and Alkyne Insertion into Hydrogen-Transition Metal Bonds Catalyzed by Palladium(0) Complex

Masafumi Hirano, N. Komine, S. Komiya, 2014, Topics in Catalysis.

Ru(0)-Catalyzed C3-Selective Cross-Dimerization of 2,5-Dihydrofuran with Conjugated Dienes

Masafumi Hirano, N. Komine, S. Komiya, 2016 .

CSi bond cleavage of trihalomethyltrimethylsilane by alkoxo- and aryloxogold or -copper complexes

Y. Usui, Masafumi Hirano, S. Komiya, 2000 .

Selective Allylation of Arenethiols Using Water-soluble Palladium Complex Catalyst in Recyclable Water/Hexane Biphasic Media

Masafumi Hirano, N. Komine, S. Komiya, 2005 .

Ring opening reactions of thiiranes by alkoxo- and aryloxo-gold( I ) complexes

Y. Usui, Masafumi Hirano, S. Komiya, 1999 .

Condensation reactions of benzaldehyde catalysed by gold alkoxides

A. Fukuoka, Y. Usui, Masafumi Hirano, 1996 .

Pd/Cu-Catalyzed Dehydrogenative Coupling of Dimethyl Phthalate: Synchrotron Radiation Sheds Light on the Cu Cycle Mechanism

H. Takaya, Masafumi Hirano, T. Mitsudome, 2020 .

C-S Bond Cleavage of Allyl Thioethers by Zerovalent Ru Complexes.

Masafumi Hirano, S. Komiya, J. G. Planas, 1998 .

Stereoselective thiirane desulfurization controlled by a bridging or terminal acyl ligand: Concerted vs. SN2 pathways

Masafumi Hirano, N. Komine, S. Komiya, 2013 .

Insertion of CO into a CH3-Pd Bond in a Heterodinuclear Complex (dpe)MePd-Co(CO)4. Preferential Insertion of Coordinated CO on a Cobalt Moiety

A. Fukuoka, Masafumi Hirano, S. Komiya, 1997 .

Stoichiometric CH Bond Cleavage Reaction in a Bis(carboxylato)ruthenium(II) Complex and Its Application to the Catalytic H–D Exchange Reaction of Carboxylic Acids

Masafumi Hirano, N. Komine, S. Komiya, 2013 .

Acid-Promoted sp3 C–H Bond Cleavage in a Series of (2-Allylphenoxo)ruthenium(II) Complexes. Mechanistic Insight into the Aryloxo–Acid Interaction and Bond Cleavage Reaction

M. Murakami, Masafumi Hirano, N. Komine, 2012 .

Crystal and solution structures of photochromic spirobenzothiopyran. First full characterization of the meta-stable colored species.

K. Osakada, Masafumi Hirano, A. Miyashita, 2002, The Journal of organic chemistry.

An insight into regioselectivity in the transformation through a ruthenacycle

Masafumi Hirano, Sayori Kiyota, 2020 .

C–S, C–H, and N–H bond cleavage of heterocycles by a zero-valent iron complex, Fe(N2)(depe)2 [depe=1,2-bis(diethylphosphino)ethane]

Masafumi Hirano, S. Komiya, Akito Sasaki, 1999 .

Michael addition of N-bonded enolato ligands to acrylonitrile in iron and ruthenium complexes

Masafumi Hirano, S. Komiya, Sayori Kiyota, 2000 .

Synthesis of N-bonded enolatoruthenium(II) by oxidative addition of alkyl cyanocarboxylate to a ruthenium(0) complex

Masafumi Hirano, S. Komiya, M. Hiraoka, 1999 .

N -bonded enolatorhenium(I) complexes having dimethylphenylphosphine ligands as active key intermediates in catalytic Knoevenagel and Michael reactions

A. Fukuoka, Masafumi Hirano, S. Komiya, 1998 .

Michael reactions promoted by η1-O-enolatoruthenium(II) complexes derived from Ru(cod)(cot), diphosphine, and dimethyl malonate

Masafumi Hirano, S. Komiya, S. G. Alvarez, 1998 .

Synthesis of novel rhenium(I) enolate complexes as active key intermediates in the catalytic aldol type reaction

A. Fukuoka, Masafumi Hirano, S. Komiya, 1993 .

Regioselective CH or NH bond cleavage reactions of heterocyclic compounds by [Ru(1,5-COD)(1,3,5-COT)]/monodentate phosphine

Masafumi Hirano, S. Komiya, Y. Kimura, 2003 .

Stoichiometric and Catalytic Cross Dimerization between Conjugated Dienes and Conjugated Carbonyls by a Ruthenium(0) Complex: Straightforward Access to Unsaturated Carbonyl Compounds by an Oxidative Coupling Mechanism

Masafumi Hirano, N. Komine, S. Komiya, 2012 .

Catalytic cross-dimerisation giving reactive borylated polyenes toward cross-coupling.

Masafumi Hirano, N. Komine, S. Westcott, 2019, Chemical communications.

Recent Advances in the Catalytic Linear Cross-Dimerizations

Masafumi Hirano, M. Hirano, 2019, ACS Catalysis.

Cobalt-Catalyzed Divergent Cycloadditions of Alkynes with Conjugated Dienes Yielding 3-Vinylcyclobutenes, Bicyclo[3.1.0]hexenes, and Cyclohexa-1,4-dienes.

Masafumi Hirano, N. Komine, Sayori Kiyota, 2022, Organic letters.

Activation of Coordinated Carbon Dioxide in Fe(CO2)(depe)2 by Group 14 Electrophiles

Masafumi Hirano, S. Komiya, N. C. Kasuga, 1997 .

Asymmetric cross-dimerization between methyl methacrylate and substituted alkene by Ru(0)-bicyclononadiene complex.

Masafumi Hirano, N. Komine, S. Komiya, 2013, Organic letters.

Oxidative coupling reactions at ruthenium(0) and their applications to catalytic homo- and cross-dimerizations¶

Masafumi Hirano, S. Komiya, M. Hirano, 2016 .

Stoichiometric Carbon–Carbon Bond Forming Reaction of 1,3-Diene with 1,2-Diene in a Ruthenium(0) Complex

Masafumi Hirano, N. Komine, S. Komiya, 2012 .

Stoichiometric formation of conjugated dienyl ketones from 1,3-dienes and ketenes at a ruthenium(0) centre

Masafumi Hirano, N. Komine, S. Komiya, 2014 .

Synthesis and reactions of heterodinuclear organopalladium–cobalt complexes acting as copolymerization catalyst for aziridine and carbon monoxide

Masafumi Hirano, N. Komine, S. Komiya, 2007 .

Synthesis and structures of heterodinuclear organoplatinum(or -palladium)–molybdenum(or -tungsten) complexes: Unexpected structural deformation of heterodinuclear propionylplatinum–tungsten complex having 1,2-bis(diphenylphosphino)ethane ligand

Masafumi Hirano, N. Komine, S. Komiya, 2006 .

Selective Isomerization of 2-Allylphenol to (Z)-2-Propenylphenol Catalyzed by Ru(cod)(cot)/PEt3

Masafumi Hirano, N. Komine, S. Komiya, 1999 .

E-Selective dimerization of phenylacetylene catalyzed by cationic tris(μ-hydroxo)diruthenium(II) complex and the mechanistic insight: The role of two ruthenium centers in catalysis

Masafumi Hirano, N. Komine, S. Komiya, 2017 .

Enhancement of CO Insertion into a Pd−C Bond in a Pd−Co Heterodinuclear Complex

A. Fukuoka, Masafumi Hirano, S. Komiya, 2001 .

Isolation of trans-2,5-Bis(methoxycarbonyl)ruthenacyclopentane by Oxidative Coupling of Methyl Acrylate on Ruthenium(0) as an Active Intermediate for Tail-to-Tail Selective Catalytic Dimerization

Masafumi Hirano, N. Komine, S. Komiya, 2009 .

Synthesis of conjugated diene complexes of ruthenium(0) derived from Ru(η6-naphthalene)(η4-1,5-COD): Z to E isomerisation of coordinated 1,3-pentadiene

Masafumi Hirano, N. Komine, S. Komiya, 2012 .

Enhanced Reductive Elimination of Dialkylgold(III) Complexes in Water

Masafumi Hirano, N. Komine, S. Komiya, 2005 .

Synthesis and Reactions of Water-soluble Diorganoplatinum(II) Complexes

Masafumi Hirano, N. Komine, S. Komiya, 2002 .

Water-soluble iridium and rhodium complexes with tris(hydroxymethyl)phosphine and their catalysis in biphasic hydrogenation and hydroformylation

A. Fukuoka, Masafumi Hirano, S. Komiya, 1999 .

CO bond cleavage and oxidative addition of allyl carboxylate to ruthenium(0) complex. Isolation of (π-allyl)(trifluoroacetato)tris(triethylphosphine)ruthenium(II)

A. Fukuoka, Masafumi Hirano, S. Komiya, 1994 .

Catalytic Tail-to-Tail Selective Dimerization of Methyl Methacrylate Promoted by a Ruthenium(0) Complex

Masafumi Hirano, N. Komine, S. Komiya, 2010 .

Synthesis of and catalytic nitrile hydration by a cationic tris(μ-hydroxo)diruthenium(II) complex having PMe 3 ligands

Masafumi Hirano, N. Komine, S. Komiya, 2016 .

Direct Access to Fluorene by Successive C–O/C–H Bond Activations of 2-Phenylbenzyl Ester

Masafumi Hirano, N. Komine, Sosuke Kawazu, 2014 .

Branch selective allylation of acetylacetone catalyzed by Water-soluble rhodium complex catalyst

Masafumi Hirano, N. Komine, S. Komiya, 2011 .

Recent advances of achiral and chiral diene ligands in transition-metal catalyses

Masafumi Hirano, N. Komine, Harumi Okada, 2019, Tetrahedron Letters.

Synthesis, structure and reactivity of an (η6-naphthalene)iron(0) complex having a 1,2-bis(dicyclohexylphosphino)ethane ligand

Masafumi Hirano, S. Komiya, Hiroaki Kubo, 1998 .

Markovnikov-Selective Hydrosilylation of Electron-Deficient Alkenes with Arylsilanes Catalyzed by Mono(phosphine)palladium(0)

Masafumi Hirano, N. Komine, M. Abe, 2015 .

Cross-Dimerization of 2,5-Dihydrofuran with Conjugated Dienes Catalyzed by (Chiral Diene)ruthenium(0) Complexes and Origins of the Enantioselectivity

Masafumi Hirano, N. Komine, Hsyueh-Liang Wu, 2021, Organometallics.

Ru(0)-Catalyzed Synthesis of Borylated-Conjugated Triene Building Blocks by Cross-Dimerization and Their Use in Cross-Coupling Reactions

Masafumi Hirano, N. Komine, Sayori Kiyota, 2021, Bulletin of the Chemical Society of Japan.

Carbon−Oxygen and Carbon−Hydrogen Bond Cleavage Reactions of ortho-Substituted Phenols by Ruthenium(II) Complexes

Masafumi Hirano, Naoki Kurata, N. Komine, 2007 .

Hydrogen Transfer in Pt-Mo Heterodinuclear Hydride Complexes Promoted by Alkynes

A. Fukuoka, Masafumi Hirano, S. Komiya, 1998 .

Regio- and Enantioselective Linear Cross-Dimerizations between Conjugated Dienes and Acrylates Catalyzed by New Ru(0) Complexes

Masafumi Hirano, N. Komine, S. Komiya, 2014 .

Synthesis of and Catalytic Linear Cross-Dimerizations by an Electron-Deficient Cyclic Diene Complex of Ruthenium(0)

Masafumi Hirano, N. Komine, Yuki Tanaka, 2018, Organometallics.

Ru(0)-catalyzed C3-selective Coupling Reactions of Unsaturated 5-Membered Heterocycles with Methyl Methacrylate and Methacryl Amide

Masafumi Hirano, N. Komine, T. Murakami, 2017 .

Regioselectivity Control by Added MeCN in Ru(0)-catalyzed Cross-dimerization of Internal Alkynes with Methyl Methacrylate

Masafumi Hirano, N. Komine, Sayori Kiyota, 2017 .

Prostereogenic Face and Orientation Selective Oxidative Coupling Reaction between Methyl Methacrylate and 2,5-Dihydrofuran Catalyzed by a Ruthenium(0) Compound

Masafumi Hirano, N. Komine, S. Komiya, 2011 .

Stoichiometric Regio- and Stereoselective Oxidative Coupling Reactions of Conjugated Dienes with Ruthenium(0). A Mechanistic Insight into the Origin of Selectivity

Masafumi Hirano, N. Komine, S. Komiya, 2011 .

Stoichiometric and Catalytic Cross Dimerization between Butadiene and Methyl Acrylate Promoted by a Ruthenium(0) Complex

Masafumi Hirano, N. Komine, S. Komiya, 2010 .

Regio- and Stereoselective Insertion Reactions of Thiiranes into Pt−Mn (or Re) Bond in Organoplatinum−Manganese or −Rhenium Heterodinuclear Complexes as Intermediates toward Desulfurization Reaction

Masafumi Hirano, S. Komiya, Shinsuke Muroi, 2000 .

Enhanced C-C Bond Formation of Heterodinuclear Methylplatinum-Molybdenum Complexes Having a Hemilabile Ligand with Dialkyl Acetylenedicarboxylate

Masafumi Hirano, N. Komine, S. Komiya, 2004 .

E-Selective Allyl Transfer Reaction in a μ-η1:η2-Crotylplatinum−Cobalt Complex

Masafumi Hirano, N. Komine, S. Komiya, 2008 .

Synthesis and reactions of heterodinuclear organopalladium complex having an unsymmetrical PN ligand

Masafumi Hirano, N. Komine, S. Komiya, 2003 .

Catalytic synthesis of thiobutyrolactones via CO insertion into the C-S bond of thietanes in the presence of a heterodinuclear organoplatinum-cobalt complex.

M. Furuya, Masafumi Hirano, N. Komine, 2003, Chemical communications.

An Organometallic approarch to synergistic effect in catalysis; synthesis and reactions of heterodinuclear organotransition metal complexes

A. Fukuoka, Masafumi Hirano, S. Komiya, 1999 .

Bond activation by low valent ruthenium complexes

Masafumi Hirano, S. Komiya, M. Hirano, 2003 .

Synthesis and Ligand Exchange Control of Ru(η2-C2H3YPh)(cod)(depe) (Y = O, S)

Masafumi Hirano, S. Komiya, J. G. Planas, 1999 .

Copolymerization of Aziridines and Carbon Monoxide Catalyzed by a Heterodinuclear Organopalladinum-Cobalt Complex

Masafumi Hirano, N. Komine, S. Komiya, 2004 .

In Situ Routes to Catalytically Active Ru(0) Species by Reduction of Readily Available, Air-Stable Precursors

Masafumi Hirano, N. Komine, M. A. Bennett, 2018 .

Mechanistic insights into catalytic linear cross-dimerization between conjugated dienes and styrenes by a ruthenium(0) complex

S. Kawauchi, Masafumi Hirano, N. Komine, 2015 .

Ru(0)-Catalyzed Direct Coupling of Internal Alkynes with Conjugated Dienes: An Efficient Access to Conjugated Trienes

Masafumi Hirano, N. Komine, R. Saito, 2016 .

Cross-dimerisation between different cisoid- and transoid-1,3-dienes at a ruthenium(0) centre

Masafumi Hirano, N. Komine, S. Komiya, 2013 .

Synthesis of di-, tri-, tetra- and pentacyclic arene complexes of ruthenium(II):[Ru(η6-polycyclic arene)-(1-5-η5-cyclooctadienyl)]PF6 and their reactions with NaBH4

Masafumi Hirano, N. Komine, S. Komiya, 2007 .

Tail-to-Tail Dimerization of Acrylonitrile Catalyzed by Low-Valent Ruthenium Complexes.

A. Fukuoka, M. Yoshizawa, Masafumi Hirano, 1998 .