Z. Xi

发表

Carbon-Carbon Bond Cleavage and Selective Transformation of Zirconacycles

Tamotsu Takahashi, M. Kotora, R. Hara, 1999 .

Synthesis and applications of 1-iodo-4-MgCl-1,3-dienes and 1-iodovinyl phenylmagnesium chlorides

Z. Xi, Junnian Wei, Yonglian Zhang, 2014 .

ChemInform Abstract: Preparation and Reactions of Monocyclic Bis(cyclopentadienyl)titanacyclopentenes and -pentadienes.

Y. Nishihara, Tamotsu Takahashi, Z. Xi, 2001 .

Metalla-aromatics: Planar, Nonplanar, and Spiro.

Shengfa Ye, Chao Yu, Z. Xi, 2021, Accounts of chemical research.

Synthesis of chrysenosiloles via Mallory photocyclization

Z. Xi, Qi Yang, K. Ouyang, 2018, Tetrahedron.

Mechanistic study on the cleavage and reorganization of C(sp3)-H and C=N bonds in carbodiimides: synthesis of 1,2-dihydrothiopyrimidines and 2,3-dihydropyrimidinthiones through four-component coupling.

Z. Xi, Wen‐Xiong Zhang, Yang Wang, 2013, Chemistry.

Zirconocene-mediated intermolecular coupling of Si-tethered diynes with alkynes, ketones, aldehydes, and isocyanates by means of novel skeletal rearrangement of zirconacyclobutene-silacyclobutene and zirconacyclohexadiene-silacyclobutene fused-ring intermediates.

Tao Yu, Z. Xi, L. Deng, 2005, Chemistry.

β-Hydride Elimination from α-Positioned Methyl Group of Bicyclic Zirconacyclopentanes Assisted by Aldehyde

Hegen Zheng, Tamotsu Takahashi, Z. Xi, 2004 .

Alkyne and ketone induced novel cleavage of a CC bond and a CSi bond in zirconacyclobutene–silacyclobutene fused ring compounds

Z. Xi, L. Deng, Zhiping Li, 2003 .

Reaction of aluminacyclopentadienes with aldehydes affording cyclopentadiene derivatives

Z. Xi, Hongyun Fang, Changjia Zhao, 2003 .

Deoxygenative Cycloaddition of Aldehydes with Alkynes Mediated by AlCl3 and Zirconium: Formation of Cyclopentadiene Derivatives

Pixu Li, Z. Xi, 2000 .

Substituent-Selective Mixed-Dihalogenation of Unsymmetrical Zirconacyclopentadienes

Tamotsu Takahashi, Z. Xi, H. Ubayama, 1998 .

Palladium-catalyzed cleavage of the Me–Si bond in ortho-trimethylsilyl aryltriflates: synthesis of benzosilole derivatives from ortho-trimethylsilyl aryltriflates and alkynes

Z. Xi, K. Ouyang, Meng Tianhao, 2013 .

Formation of alpha-lithio siloles from silylated 1,4-dilithio-1,3-butadienes: mechanism and applications.

Z. Xi, Wen‐Xiong Zhang, Qian Luo, 2010, Chemistry, an Asian journal.

Synthesis of functionalized siloles from Si-tethered diynes

Z. Xi, Wen‐Xiong Zhang, Qian Luo, 2009 .

Palladium-catalyzed intermolecular coupling of 2-silylaryl bromides with alkynes: synthesis of benzosiloles and heteroarene-fused siloles by catalytic cleavage of the C(sp3)-Si bond.

Z. Xi, Yun Liang, Junnian Wei, 2012, Angewandte Chemie.

Lithio siloles: facile synthesis and applications.

Z. Xi, Qian Luo, Chao Wang, 2007, Journal of the American Chemical Society.

Opening the silole ring: Efficient and specific cleavage of the endo-C(sp2)-Si bond with AcOH/ROH system

Z. Xi, M. Uchiyama, K. Ouyang, 2011 .

Cleavage of C–Si bond by intramolecular nucleophilic attack: lithiation-promoted formation of siloles from 1-bromo-4-trisubstituted silyl-1,3-butadiene derivatives

Z. Xi, Zhihui Wang, Hongyun Fang, 2005 .

Novel reaction patterns of carbon disulfide with organolithium compounds via cleavage of CS bonds or via cycloaddition reactions

Q. Song, Z. Xi, Jinglong Chen, 2002 .

Dialkenylation of Carbonyl Groups by Alkenyllithium Compounds: Formation of Cyclopentadiene Derivatives by the Reaction of 1,4-Dilithio-1,3-dienes with Ketones and Aldehydes This work was partially supported by the National Science Fund for Distinguished Young Scholars (29825105), the Major State Ba

Pixu Li, Q. Song, Z. Xi, 2001, Angewandte Chemie.

Indacyclopentadienes and Aromatic Indacyclopentadienyl Dianions: Synthesis and Characterization.

Zhenqiang Yang, Z. Xi, Yonglian Zhang, 2019, Chemistry.

Synthesis of benzothieno[2,3-b]thiophenes, [2,3-b:3′,2′-d]-dithienothiophenes and their selenium derivatives via electrophilic cyclization and McMurry cyclization

Z. Xi, Wen‐Xiong Zhang, Zitao Wang, 2012 .

Oxidant-switchable selective synthesis of 2-aminobenzimidazoles via C-H amination/acetoxylation of guanidines.

Z. Xi, Wen‐Xiong Zhang, Yue Chi, 2014, Organic letters.

Synthesis of Quinoline Derivatives via Cu-Catalyzed Cascade Annulation of Heterocumulenes, Alkynes, and Diaryliodonium Salts.

Z. Xi, Wen‐Xiong Zhang, Yue Chi, 2017, Organic letters.

Formation of Cyclopenta[c]pyridine Derivatives from 2,5-Disubstituted Pyrroles and 1,4-Dibromo-1,3-butadienes via Pyrrole-Ring One-Carbon Expansion.

Yucheng Gu, Z. Xi, Wei Hao, 2017, Organic letters.

2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins.

Tianyang Chen, Jun Li, Chao Yu, 2020, Journal of the American Chemical Society.

Direct transformation of dinitrogen: synthesis of N-containing organic compounds via N−C bond formation

Dehui Deng, Zhangjie Shi, Z. Xi, 2020, National science review.

Iterative dianion relay along the ring: formation of gem-bis(trimethylsilyl) cyclopentenones from 2,5-bis(trimethylsilyl) oxy-cyclopentadienyl dianions and acid chlorides.

Lantao Liu, Z. Xi, Wen‐Xiong Zhang, 2011, Chemistry.

Formation of stable enols from 1,4-dilithio-1,3-dienes and acid chlorides by a de-aromatization/Michael addition/re-aromatization domino process.

Z. Xi, Chao Wang, Qiaoshu Hu, 2007, Organic & biomolecular chemistry.

Efficient one-pot synthesis of 2,3-dihydropyrimidinthiones via multicomponent coupling of terminal alkynes, elemental sulfur, and carbodiimides.

Z. Hou, Z. Xi, Wen‐Xiong Zhang, 2009, Journal of the American Chemical Society.

Organo-di-Metallic Compounds (or Reagents): Synergistic Effects and Synthetic Applications

Z. Xi, G. Barozzino-Consiglio, 2014 .

Dinickelaferrocene: A Ferrocene Analogue with Two Aromatic Nickeloles Realized by Electron Back‐Donation from Iron

Shengfa Ye, Z. Xi, L. Deng, 2020, Angewandte Chemie.

Dinickelaferrocene: Ferrocene Analogue with Two Aromatic Nickeloles Realized by Electron Back Donation from Fe.

Shengfa Ye, Z. Xi, L. Deng, 2020, Angewandte Chemie.

1,3-Butadienyl Dianions as Non-Innocent Ligands: Synthesis and Characterization of Aromatic Dilithio Rhodacycles.

Z. Xi, Junnian Wei, Yonglian Zhang, 2015, Angewandte Chemie.

Lewis Acid mediated reactions of zirconacyclopentadienes with aldehydes: one-pot synthetic route to indene and cyclopentadiene derivatives from aldehydes and benzyne or alkynes.

Pixu Li, Z. Xi, Changjia Zhao, 2002, Chemistry.

Barium dibenzopentalenide as a main-group metal η⁸ complex: facile synthesis from 1,4-dilithio-1,3-butadienes and Ba[N(SiMe₃)₂]₂, structural characterization, and reaction chemistry.

Z. Xi, Wen‐Xiong Zhang, Baosheng Wei, 2013, Angewandte Chemie.

CuOTf-Catalyzed Selective Generation of 2-Aminopyrimidines from Carbodiimides and Diaryliodonium Salts by a Triple C(sp3 )-H Functionalization.

Z. Xi, Wen‐Xiong Zhang, Yue Chi, 2017, Chemistry.

Intramolecular C–F and C–H bond cleavage promoted by butadienyl heavy Grignard reagents

J. Pei, Xiao-Ye Wang, Z. Xi, 2014, Nature Communications.

Dinitrogen Functionalization Affording Chromium Hydrazido Complex.

Z. Xi, Jiapeng Li, Wen‐Xiong Zhang, 2019, Journal of the American Chemical Society.

Mechanistic insights into N-N bond cleavage in catalytic guanylation reactions between 1,2-diarylhydrazines and carbodiimides.

Yu-Chen Wang, Z. Xi, Wen‐Xiong Zhang, 2014, The Journal of organic chemistry.

Preparation and Characterization of a 19-Electron Ni(I) Complex Bearing a Cyclopentadienyl-Phosphine Ligand

Shengfa Ye, Z. Xi, Junnian Wei, 2022, Organometallics.

Dianions as Formal Oxidants: Synthesis and Characterization of Aromatic Dilithionickeloles from 1,4-Dilithio-1,3-butadienes and [Ni(cod)2].

Z. Xi, Junnian Wei, Wen‐Xiong Zhang, 2015, Angewandte Chemie.

Aromatic Dicupra[10]annulenes.

Z. Xi, Junnian Wei, Yonglian Zhang, 2016, Journal of the American Chemical Society.

Outlook of nitrogen fixation by carbene

Chun-Hai Wang, Z. Xi, Junnian Wei, 2020 .

Cyclopentadiene-phosphine/palladium-catalyzed cleavage of C-N bonds in secondary amines: synthesis of pyrrole and indole derivatives from secondary amines and alkenyl or aryl dibromides.

Z. Xi, Wei Hao, Wen‐Xiong Zhang, 2012, Journal of the American Chemical Society.

Synthesis and reactivity of asymmetric Cr(i) dinitrogen complexes supported by cyclopentadienyl-phosphine ligands.

Z. Xi, Jiapeng Li, Wen‐Xiong Zhang, 2019, Chemical communications.

Ruthenium Complexes Bearing Bulky Pentasubstituted Cyclopentadienyl Ligands and Evaluation of [Ru(η5‐C5Me4R)(MeCN)3][PF6] Precatalysts in Nucleophilic Allylic Substitution Reactions

Z. Xi, C. Bruneau, B. Demerseman, 2008 .

Selective synthesis of dibenzo[a,c]cyclooctatetraenes via palladium-catalyzed [4+4] cyclic homocoupling of borylvinyl iodobenzene derivatives.

Z. Xi, Yun Liang, Junnian Wei, 2010, Chemical communications.

Zirconocene-mediated ligand-switched selective cleavage of active and inert carbon-carbon bonds in allylcyclopropanes.

Z. Xi, L. Deng, Wen‐Xiong Zhang, 2009, Chemical communications.

Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation.

Z. Xi, Wen‐Xiong Zhang, Zhe Huang, 2019, Journal of the American Chemical Society.

Efficient synthesis of aza-triquinacene derivatives via cycloaddition of 2,6-diazasemibullvalenes with nitroso compounds.

Z. Xi, Ming Zhan, Zhe Huang, 2015, Chemistry, an Asian journal.

Cyclopentadiene-Phosphine/Palladium-Catalyzed Synthesis of Indolizines from Pyrrole and 1,4-Dibromo-1,3-butadienes.

Z. Xi, Wei Hao, Wen‐Xiong Zhang, 2015, Organic letters.

Synthesis, structural characterization, and skeletal rearrangement of dibenzo tricyclo[3.3.0.02,6]-1,2,5,6-tetrasubstituted octanes

Z. Xi, Hongyun Fang, Shiwei Zhang, 2004 .

Selective preparation of 1,3-butadienyl phosphines, 1-iodo- and 1,4-diiodo-butadienyl phosphine oxides via zirconocene-mediated cross-coupling of alkynylphosphines

Tamotsu Takahashi, Z. Xi, Wen‐Xiong Zhang, 2004 .

Acyl-lithiation of olefins: formation of cyclopentenones from 1-lithio-butadienes and CO.

Q. Song, Z. Xi, Cong-Hui Wang, 2002, Organic letters.

Ln4(CH2)4 cubane-type rare-earth methylidene complexes consisting of "(C5Me4SiMe3)LnCH2" units (Ln = Tm, Lu).

Z. Hou, Z. Xi, M. Nishiura, 2011, Journal of the American Chemical Society.

Transition-Metal-Catalyzed Cleavage of C-N Single Bonds.

Z. Xi, Wei Hao, Wen‐Xiong Zhang, 2015, Chemical reviews.

Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(ii) complex.

Z. Xi, Gengwen Tan, Wen‐Xiong Zhang, 2019, Chemical communications.

(n-Bu)4NBr-Promoted N2 Splitting to Molybdenum Nitride.

Zhangjie Shi, Z. Xi, Shuo-qing Zhang, 2022, Journal of the American Chemical Society.

Metal mediated synthesis of substituted cyclooctatetraenes.

Z. Xi, Chao Wang, 2007, Chemical communications.

One-pot selective syntheses of 5-azaindoles through zirconocene-mediated multicomponent reactions with three different nitrile components and one alkyne component.

Jing Zhao, Z. Xi, Wen‐Xiong Zhang, 2011, Chemistry.

Efficient one-pot synthesis of N-containing heterocycles by multicomponent coupling of silicon-tethered diynes, nitriles, and isocyanides through intramolecular cyclization of iminoacyl-Zr intermediates.

Z. Xi, Wen‐Xiong Zhang, Shaoguang Zhang, 2010, Chemistry.

One-pot multicomponent synthesis of azaindoles and pyrroles from one molecule of a silicon-tethered diyne and three or two molecules of organonitriles mediated by zirconocene.

Z. Xi, Wen‐Xiong Zhang, Xiaohua Sun, 2009, Chemistry.

Diazo compounds as electrophiles to react with 1,4-dilithio-1,3-dienes: efficient synthesis of 1-imino-pyrrole derivatives.

Z. Xi, Ming Zhan, Wen‐Xiong Zhang, 2013, Organic letters.

Cleavage of the C=N bond in carbodiimides via release of high ring strain: a new strategy for the selective synthesis of 2-aminoaryl alkynyl imines.

Z. Xi, Wen‐Xiong Zhang, Yi Zhou, 2014, Chemistry.

Zirconocene and Si-tethered diynes: a happy match directed toward organometallic chemistry and organic synthesis.

Z. Xi, Wen‐Xiong Zhang, Shaoguang Zhang, 2011, Accounts of chemical research.

Zirconium- and silicon-containing intermediates with three fused rings in a zirconocene-mediated intermolecular coupling reaction.

Z. Hou, Z. Xi, M. Nishiura, 2009, Angewandte Chemie.

Zirconocene-mediated intermolecular coupling of one molecule of Si-tethered diyne with three molecules of organonitriles: one-pot formation of pyrrolo[3,2-c]pyridine derivatives via cleavage of CN triple bonds of organonitriles.

Z. Xi, Cong-Hui Wang, Zhiping Li, 2004, Journal of the American Chemical Society.

Coordination-induced skeletal rearrangements of zirconacyclobutene–silacyclobutene fused complexes

Z. Xi, Wen‐Xiong Zhang, J. Zhao, 2014 .

Reaction of Titanacyclobutene–Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C–N Triple Bond of Nitrile into the Silacyclobutene Ring

J. Zhao, Z. Xi, Wen‐Xiong Zhang, 2014 .

Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile

J. Zhao, Z. Xi, Wen‐Xiong Zhang, 2012 .

Formation of Zirconocenes Containing Vinyl-imine and Keteniminate Species from Zirconacycles and Diphenylacetonitrile

J. Zhao, Z. Xi, Wen‐Xiong Zhang, 2011 .

Efficient One‐Pot Synthesis of N‐Containing Heterocycles by Multicomponent Coupling of Silicon‐Tethered Diynes, Nitriles, and Isocyanides Through Intramolecular Cyclization of Iminoacyl—Zr Intermediates.

Z. Xi, Wen‐Xiong Zhang, Shaoguang Zhang, 2010 .

Cleavage and reorganization of Zr-C/Si-C bonds leading to Zr/Si-N organometallic and heterocyclic compounds.

Jing Zhao, Z. Xi, Wen‐Xiong Zhang, 2010, Journal of the American Chemical Society.

Star-Shaped Silacyclobutene-Containing π-Systems: Synthesis and Optical Properties

Z. Xi, Wen‐Xiong Zhang, Junhui Liu, 2009 .

Isolation and Synthetic Applications of 2,5-Bis(alkynylsilyl) Zirconacyclopentadienes

Z. Hou, Z. Xi, Wen‐Xiong Zhang, 2007 .

Synthesis of multiply substituted alkylidene silacyclohexadiene derivatives via palladium-catalyzed insertion of alkynes into alkylidene silacyclobutenes.

Lantao Liu, Z. Xi, Cong-Hui Wang, 2007, The Journal of organic chemistry.

Selective Intermolecular Coupling of Alkynes with Nitriles and Ketones via β,β‘ Carbon−Carbon Bond Cleavage of Zirconacyclopentenes

C. Xi, E. Negishi, K. Nakajima, 1998 .

ZIRCONOCENE-MEDIATED INTRAMOLECULAR CARBON-CARBON BOND FORMATION OF TWO ALKYNYL GROUPS OF BIS(ALKYNYL)SILANES

K. Nakajima, Tamotsu Takahashi, R. Hara, 1997 .

Intramolecular Coupling of Alkynyl Groups of Bis(alkynyl)silane Mediated by Zirconocene Compounds: Formation of Silacyclobutene Derivatives

Tamotsu Takahashi, Z. Xi, Y. Obora, 1995 .

Copper-Catalyzed or Mediated Carbon-Carbon Bond Formation Reactions of Zirconacycles and Alkenylzirconocenes

Tamotsu Takahashi, M. Kotora, Z. Xi, 1997 .

One‐Pot Selective Syntheses of 5‐Azaindoles Through Zirconocene‐Mediated Multicomponent Reactions with Three Different Nitrile Components and One Alkyne Component.

Z. Xi, Wen‐Xiong Zhang, J. Zhao, 2011 .

Highly efficient synthesis of stereodefined multisubstituted 1,4-dicyano- and 1-cyano-1,3-butadienes and their reactions with organolithium reagents.

Z. Xi, Cong-Hui Wang, Chao Wang, 2007, Chemistry.

Organo-di-Lithio Reagents: Cooperative Effect and Synthetic Applications

Z. Xi, Wen‐Xiong Zhang, Shaoguang Zhang, 2013 .

1,3-Butadienylzinc Trimer Formed via Transmetalation from 1,4-Dilithio-1,3-butadienes: Synthesis, Structural Characterization, and Application in Negishi Cross-Coupling

Z. Xi, Wen‐Xiong Zhang, Yi Zhou, 2012 .

2,6-Diazasemibullvalenes: synthesis, structural characterization, reaction chemistry, and theoretical analysis.

Z. Xi, Ming Zhan, Junnian Wei, 2012, Journal of the American Chemical Society.

1,4-Dilithio-1,3-dienes: reaction and synthetic applications.

Z. Xi, 2010, Accounts of chemical research.

Isolation, structural characterization, and synthetic application of oxycyclopentadienyl dianions.

Lantao Liu, Z. Xi, Cong-Hui Wang, 2009, Angewandte Chemie.

Synthetic Methods for MultiplySubstituted Butadiene-Containing Building Blocks

Z. Xi, Wen‐Xiong Zhang, 2008 .

Highly regio- and stereoselective 1,1-cycloaddition of carbon monoxide with 1,4-dilithio-1,3-dienes. Novel synthetic methods for 3-cyclopenten-1-one derivatives.

Q. Song, Z. Xi, Jinglong Chen, 2001, Journal of the American Chemical Society.

Carbodiimide-based synthesis of N-heterocycles: moving from two classical reactive sites to chemical bond breaking/forming reaction.

Z. Xi, Wen‐Xiong Zhang, Yang Wang, 2020, Chemical Society reviews.

DFT Studies on the Reaction Mechanisms of 1,4-Dilithio 1,3-Dienes with Nitriles

Z. Xi, Ming Zhan, Wen‐Xiong Zhang, 2013 .

Diverse reactions of 1,4-dilithio-1,3-dienes with nitriles: facile access to tricyclic Delta1-bipyrrolines, multiply substituted pyridines, siloles, and (Z,Z)-dienylsilanes by tuning of substituents on the butadienyl skeleton.

Lantao Liu, Z. Xi, Cong-Hui Wang, 2008, Chemistry.

Lewis acid catalyzed site-selective cycloadditions of 2,6-diazasemibullvalenes with isocyanides, azides, and diazo compounds for the synthesis of diaza- and triazabrexadiene derivatives.

Z. Xi, Wen‐Xiong Zhang, Shaoguang Zhang, 2013, Angewandte Chemie.

Alkenyl Magnesium Compounds: Generation and Synthetic Application.

Z. Xi, Hai‐tao Yu, Wen‐Xiong Zhang, 2018, Chemistry.

Organocopper(III) Compounds with Well-defined Structures Undergo Reductive Elimination to Form C-C or C-Heteroatom Bonds

Z. Xi, Liang Liu, 2018, Chinese Journal of Chemistry.

Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation.

Z. Xi, Hai‐tao Yu, Wen‐Xiong Zhang, 2017, Journal of the American Chemical Society.

Well-defined styryl and biphenyl calcium complexes from dilithio compounds and calcium iodide: synthesis, structure and reactivity toward nitrous oxide.

Z. Xi, Wen‐Xiong Zhang, Baosheng Wei, 2018, Dalton transactions.

Novel cycloaddition of nitriles with monolithio- and dilithiobutadienes.

Q. Song, Z. Xi, Cong-Hui Wang, 2002, Journal of the American Chemical Society.

Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity.

Z. Xi, Wen‐Xiong Zhang, Zhe Huang, 2019, Journal of the American Chemical Society.

Partially fluorinated naphthalene derivatives from 1,4-dilithio-1,3-dienes and C6F6

Z. Xi, Zhihui Wang, Chao Wang, 2006 .

Insertion/Rearrangement Reactivity of a Lutetacyclopentadiene towards N,N'-Diphenylcarbodiimide: Cooperative Effect of the Metal Center, Concentration of LiCl, and Solvent.

Z. Xi, Junnian Wei, Wen‐Xiong Zhang, 2015, Chemistry.

Synthesis and Mechanistic Study of Cyclic Oxoguanidines via Zn(OTf)2 -Catalyzed Guanylation/Amidation from Readily Available Amino Acid Esters and Carbodiimides.

Z. Xi, Shanshan Du, Wen‐Xiong Zhang, 2015, Chemistry.

Mechanistic Considerations of the Catalytic Guanylation Reaction of Amines with Carbodiimides for Guanidine Synthesis

Z. Xi, Wen‐Xiong Zhang, Ling Xu, 2015 .

Cleavage of the C=N Bond in Carbodiimides via Release of High Ring Strain: A New Strategy for the Selective Synthesis of 2‐Aminoaryl Alkynyl Imines.

Z. Xi, Wen‐Xiong Zhang, Yi Zhou, 2014 .

Novel reactivities of 2,2-dichloroimidazolidine-4,5-diones: synthesis of copper(I) diamidocarbene complex, 2-thioxo/selenoxoimidazolidine-4,5-dione, and 2,2-difluoroimidazolidine-4,5-dione

Z. Xi, Wen‐Xiong Zhang, Yang Wang, 2014 .

Regioselective ring expansion of 2,4-diiminoazetidines via cleavage of C-N and C(sp3)-H bonds: efficient construction of 2,3-dihydropyrimidinesulfonamides.

Z. Xi, Wen‐Xiong Zhang, Yang Wang, 2012, Journal of the American Chemical Society.

Procedure-controlled selective synthesis of 5-acyl-2-iminothiazolines and their selenium and tellurium derivatives by convergent tandem annulation.

Z. Xi, Wen‐Xiong Zhang, Yang Wang, 2011, Angewandte Chemie.

Rare-earth metal tris(trimethylsilylmethyl) anionic complexes bearing one 1-phenyl-2,3,4,5-tetrapropylcyclopentadienyl ligand: synthesis, structural characterization, and application.

Z. Xi, Wen‐Xiong Zhang, Zitao Wang, 2012, Inorganic chemistry.

Formation and ligand-based reductive chemistry of bridged bis-alkylidene scandium(iii) complexes

Tianyang Chen, Chao Yu, Z. Xi, 2017, Chemical science.

Cyclopentadienyl-Like Ligand as a Reactive Site in Half-Sandwich Bis(amidinato) Rare-Earth-Metal Complexes: An Efficient Application in Catalytic Addition of Amines to Carbodiimides

P. Wei, Z. Xi, Wen‐Xiong Zhang, 2014 .

Half-sandwich bis(propiolamidinate) rare-earth metal complexes: synthesis, structure and dissociation of the cyclopentadienyl ligand via competition with an amidinate.

Yu-Chen Wang, Z. Xi, Wen‐Xiong Zhang, 2013, Dalton transactions.

Palladium-catalyzed one-pot three- or four-component coupling of aryl iodides, alkynes, and amines through C-N bond cleavage: efficient synthesis of indole derivatives.

Z. Xi, Wei Hao, Wen‐Xiong Zhang, 2014, Chemistry.

Cationic scandium allyl complexes bearing mono(cyclopentadienyl) ligands: synthesis, novel structural variety, and olefin-polymerization catalysis.

Z. Hou, Z. Xi, Xiaofang Li, 2008, Chemistry, an Asian journal.

Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization

Z. Xi, Wen‐Xiong Zhang, Qi Yang, 2015 .

Synthesis and characterization of manganese(ii) complexes supported by cyclopentadienyl-phosphine ligands

Z. Xi, Jiapeng Li, Wen‐Xiong Zhang, 2019, Inorganic Chemistry Frontiers.

Calcium-Mediated C–H and C–F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes

Z. Xi, Wen‐Xiong Zhang, Baosheng Wei, 2016 .

Alkaline earth metallocenes coordinated with ester pendants: synthesis, structural characterization, and application in metathesis reactions.

Z. Xi, Wen‐Xiong Zhang, Heng Li, 2013, Chemistry.

1,2,3,4-Tetrasubstituted cyclopentadienes and their applications for metallocenes: efficient synthesis through zirconocene- and CuCl-mediated intermolecular coupling of two alkynes and one diiodomethane.

Z. Xi, Wei Hao, J. Guang, 2013, Chemistry.

New Methods for the Preparation of Multiply Substituted Cyclopentadienes and Related Compounds

Z. Xi, 2005 .

Cycloaddition Reaction of Zirconacyclopentadienes to Alkynes: Highly Selective Formation of Benzene Derivatives from Three Different Alkynes

K. Nakajima, Tamotsu Takahashi, M. Kotora, 1998 .

Co-operative effect of Lewis acids with transition metals for organic synthesis.

Z. Xi, Cong-Hui Wang, 2007, Chemical Society reviews.

Magnesiacyclopentadienes as alkaline-earth metallacyclopentadienes: facile synthesis, structural characterization, and synthetic application.

Z. Xi, Ming Zhan, Junnian Wei, 2014, Angewandte Chemie.

Insertion Reaction of Aldehydes into Zirconacyclopentanes

Pixu Li, Tamotsu Takahashi, Z. Xi, 2010 .

Formation of Zirconacyclohexadienes from Zirconacyclopentadienes and LiCHClSiR3

Tamotsu Takahashi, Z. Xi, Yoshinori Noguchi, 2000 .

Reaction of 3-zircona-1-cyclopentenes and zirconacyclopentanes with aldehydes. A selective and convenient synthesis of 4-penten-1-ols, (Z)-5-iodo-4-penten-1-ols, and related alkanols

C. Copéret, E. Negishi, Tamotsu Takahashi, 1994 .

Pair-Selective Coupling of Alkynes with Alkenes on Zirconocene Complex

Tamotsu Takahashi, Z. Xi, N. Suzuki, 1993 .

Metallacyclopentadienes: synthesis, structure and reactivity.

Tianyang Chen, Chao Yu, Z. Xi, 2017, Chemical Society reviews.

Construction of benzosiloles, six- and eight-membered silacyclic skeletons, via a Pd-catalyzed intramolecular Mizoroki-Heck reaction of vinylsilanes.

Z. Xi, Yun Liang, K. Ouyang, 2012, Organic letters.

Reactions of 1,4-dilithiobutadienes with isothiocyanates: preparation of iminocyclopentadiene derivatives via cleavage of the CS double bond of a RNCS molecule

Q. Song, Z. Xi, Cong-Hui Wang, 2004 .

CO insertion reaction of zirconacyclopentadienes

Tamotsu Takahashi, Z. Xi, Hongtao Fan, 2003 .

Convenient preparative method of α,β-disubstituted cyclopentenone by zirconium promoted intermolecular coupling of an alkyne, EtMgBr (or ethylene) and CO

Y. Nishihara, E. Negishi, Tamotsu Takahashi, 1997 .

Reaction of oxazirconacycloheptenes with aldehydes mediated by CuCl: one-pot synthesis of tetrahydrofuran derivatives from four different components involving two molecules of the same or different aldehydes, an ethylene and an alkyne

Z. Xi, Zhiping Li, Changjia Zhao, 2004 .

Transition Metal‐Catalyzed C ? H Functionalization: Synthetically Enabling Reactions for Building Molecular Complexity

Zhangjie Shi, jin-quan yu, K. Engle, 2012 .

Palladium-catalyzed silyl C(sp3)-H bond activation.

Z. Xi, Yun Liang, Junnian Wei, 2012, Organic & biomolecular chemistry.

Carbonylation of 1-lithiobutadiene with carbon monoxide followed by intramolecular acyllithiation of C═C double bond and intermolecular acylation with acid chloride: scope, applications, and mechanistic aspects.

Lantao Liu, Q. Song, Z. Xi, 2012, The Journal of organic chemistry.

Formation of stereodefined multiply substituted all-cis octatetraenes, tricyclo[4.2.0.02,5]octa-3,7-dienes and pentalenes via CuCl- or FeCl3-mediated dimerization of 1-lithiobutadienes and 1,4-dilithiobutadienes

Z. Xi, Hongyun Fang, Guotao Li, 2003 .

Substituent-controlled selective synthesis of N-acyl 2-aminothiazoles by intramolecular Zwitterion-mediated C-N bond cleavage.

Z. Xi, Wen‐Xiong Zhang, Yang Wang, 2014, The Journal of organic chemistry.

Metal-free synthesis of cyclic di-oxoguanidines via one-pot sequential transformation of amines, carbodiimides and acyl dichlorides.

Z. Xi, Wen‐Xiong Zhang, Yang Wang, 2012, Organic & biomolecular chemistry.

One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)2

Z. Xi, J. Guang, Wen‐Xiong Zhang, 2011 .

Selective synthesis of (Z)-2-enynyl-2-hydroxy-imidazolidine-4,5-diones via Cu(I)-mediated multicomponent coupling of terminal alkynes, carbodiimides and oxalyl chloride.

Z. Xi, Wen‐Xiong Zhang, Yang Wang, 2014, Organic & biomolecular chemistry.

Silyl-substituted 1,3-butadienes for Diels-Alder reaction, ene reaction and allylation reaction.

Z. Xi, F. Zhao, Shaoguang Zhang, 2011, Chemical communications.

Selective synthesis of multiply substituted 7-norbornenone derivatives or Diels-Alder cycloadducts from 1,2,3,4-tetrasubstituted 1,3-butadienes and maleic anhydride with or without Lewis acids

Guang‐Zhen Liu, Z. Xi, Wen‐Xiong Zhang, 2008 .

Programmed selective sp2 C-O bond activation toward multiarylated benzenes.

Da‐Gang Yu, Zhangjie Shi, Z. Xi, 2013, Organic letters.

A DFT Study on the Conversion of Aryl Iodides to Alkyl Iodides: Reductive Elimination of R-I from Alkylpalladium Iodide Complexes with Accessible β-Hydrogens.

P. Walsh, Z. Xi, Junnian Wei, 2016, Chemistry.

One-pot synthesis of pyrrolo[3,2-d]pyridazines and pyrrole-2,3-diones via zirconocene-mediated four-component coupling of Si-tethered diyne, nitriles, and azide.

Z. Xi, Wen‐Xiong Zhang, J. Zhao, 2011, Organic letters.

CuCl-mediated tandem CO insertion and annulation of 1,4-dilithio-1,3-dienes: formation of multiply substituted cyclopentadienones and/or their head-to-head dimers.

Z. Xi, Wen‐Xiong Zhang, Qian Luo, 2008, Chemical communications.

Synthesis of triarylmethanols via tandem arylation/oxidation of diarylmethanes

P. Walsh, Z. Xi, Jianyou Mao, 2015, Tetrahedron letters.

Diastereoselective nucleophilic ring-opening reactions of 2,6-diazasemibullvalenes for the synthesis of diverse functionalized δ(1) -bipyrroline derivatives.

Z. Xi, Ming Zhan, Wen‐Xiong Zhang, 2014, Chemistry.

Synthesis of semibullvalene derivatives via Co2(CO)8-mediated cyclodimerization of 1,4-dilithio-1,3-butadienes

Z. Xi, Ming Zhan, Wen‐Xiong Zhang, 2014 .

Recent development of synthetic preparation methods for guanidines via transition metal catalysis.

Z. Xi, Wen‐Xiong Zhang, Ling Xu, 2015, Chemical communications.

Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species.

Z. Xi, J. Guang, Wen‐Xiong Zhang, 2010, Organic & biomolecular chemistry.

Facile one-pot construction of polycyclic frameworks using a synergistic Diels-Alder reaction, ene reaction, and allylation reaction strategy.

Z. Xi, Yang Cao, Dongzhen Li, 2011, Chemistry, an Asian journal.

Synthesis of dibromo- and tetrabromo-bipyrrolines and their corresponding 2,6-diazasemibullvalene derivatives

Z. Xi, Ming Zhan, Wen‐Xiong Zhang, 2017 .

Semibullvalene and diazasemibullvalene: recent advances in the synthesis, reaction chemistry, and synthetic applications.

Z. Xi, Wen‐Xiong Zhang, Shaoguang Zhang, 2015, Accounts of chemical research.

Synthesis of α,α,α',α'-tetrachloro-Δ1-bipyrrolines and 4,8-dichloro-2,6-diazasemibuvallenes.

Z. Xi, Ming Zhan, Zhe Huang, 2015, Organic letters.

Butadienyl Diiron Complexes: Nonplanar Metalla-Aromatics Involving σ-Type Orbital Overlap.

Shengfa Ye, Chao Yu, Z. Xi, 2020, Angewandte Chemie.

1-Lithio-1,3-dienes: Useful Building Blocks for Cyclic Compounds

Z. Xi, 2007 .

Preparation and electrophilic cyclization of multisubstituted dienamides leading to cyclic iminoethers.

Z. Xi, Cong-Hui Wang, Guoliang Mao, 2005, The Journal of organic chemistry.

Pyranylidene Carbene Complexes from 1-Lithio 1,3-Dienes and M(CO)6 (M = Cr, Mo, W): Novel Synthesis and Demetalation Reaction

Z. Xi, Wen‐Xiong Zhang, Qifeng Wang, 2008 .

1-Lithio-1,3-dienes: Useful Building Blocks for Cyclic Compounds

Z. Xi, 2007 .

Reaction Chemistry of 1,4‐Dilithio‐1,3‐diene and 1‐Lithio‐1,3‐diene Derivatives

Z. Xi, 2004 .

Palladium-catalyzed synthesis of benzosilolo[2,3-b]indoles via cleavage of a C(sp3)-Si bond and consequent intramolecular C(sp2)-Si coupling.

Z. Xi, Yun Liang, Shaoguang Zhang, 2011, Journal of the American Chemical Society.

Lewis Acid promoted tandem intermolecular Diels-Alder/intramolecular allylation reactions of silyl-substituted 1,3-butadienes leading to multisubstituted 7-norbornenones and related polycyclic compounds.

Guang‐Zhen Liu, Z. Xi, Chao Wang, 2007, Organic letters.

Correction: Metallacyclopentadienes: synthesis, structure and reactivity.

Tianyang Chen, Chao Yu, Z. Xi, 2018, Chemical Society reviews.

Lewis Acid-Promoted Ring-Contraction of 2,4,6,8-Tetrasubstituted 1,5-Diazacyclooctatetraenes to 2,4,6-Trisubstituted Pyridines.

Z. Xi, Wen‐Xiong Zhang, Zhe Huang, 2018, Organic letters.

Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca4 [O] Inverse Crown Ether Complex.

Z. Xi, Wen‐Xiong Zhang, Baosheng Wei, 2017, Angewandte Chemie.

Selective Transformation of Well-Defined Alkenyllithiums to Alkenylmagnesiums via Transmetalation.

Z. Xi, Hai‐tao Yu, Yonglian Zhang, 2018, Chemistry.

The first lutetacyclopentadienes: synthesis, structure, and diversified insertion/C-H activation reactivity.

Yu-Chen Wang, Z. Xi, Junnian Wei, 2015, Chemistry.

Intermolecular Coupling Reaction of Alkynes with Vinyl Bromide with Selective Skeletal Rearrangement

K. Nakajima, Tamotsu Takahashi, Z. Xi, 1997 .

A VINYLZIRCONATION REACTION OF ALKYNES

D. Kondakov, Tamotsu Takahashi, Z. Xi, 1995 .

A novel reaction of titanacyclopentenes and aldehydes with or without Lewis acids

Z. Xi, Hui‐Jun Zhang, Qiaoshu Hu, 2007 .

Synthesis of stereo-defined 1,1,4,4-tetrahalo- and 1,1,4,4-mixed-tetrahalo-1,3-butadienes

Zhiyi Song, Z. Xi, C. Bruneau, 2008 .

Aromatic Tetralithiodigalloles with a Ga–Ga Bond: Synthesis and Structural Characterization

Hui Chen, Z. Xi, Yang Zhenqiang, 2017 .

Lithium Aluminate Complexes and Alumoles from 1,4-Dilithio-1,3-Butadienes and AlEt2Cl.

Z. Xi, Junnian Wei, Yonglian Zhang, 2015, Inorganic chemistry.

Reaction of Dilithio Reagents with PhSiH3: Formation of Siloles and 3-Silacyclopentenes.

Z. Xi, Wen‐Xiong Zhang, Baosheng Wei, 2015, The Journal of organic chemistry.

Lewis acid-controlled reactions of zirconacyclopentadienes with isocyanates and isothiocyanates. One-pot three- or four-component synthesis of multiply substituted iminocyclopentadienes and butadiene-tethered 1,6-bisamides and electrophilic cyclization

Z. Xi, Cong-Hui Wang, Chao Wang, 2007 .

Preparation of 1,2,3-trisubstituted cyclopentadienes and tetrahydroindene derivatives from zirconacyclopentenes

C. Xi, K. Nakajima, Tamotsu Takahashi, 1996 .

Highly Selective and Practical Alkyne-Alkyne Cross-Coupling Using Cp2ZrBu2 and Ethylene

Tamotsu Takahashi, R. Hara, Z. Xi, 1995 .

Inverse Sandwich Arene-Bridged Titanium Complexes Supported by a Bulky Tridentate [O, P, O] Ligand

Z. Xi, Junnian Wei, Xueli Wang, 2023, Organometallics.

Copper(I)-catalyzed tandem inter–intramolecular cyclization reactions of zirconacycles: formation of highly substituted styrenes, vinylcyclohexadienes, and related compounds

Pixu Li, Tamotsu Takahashi, M. Kotora, 2002 .

Reaction of Zirconocene Ethylene Complex with Diynes. Formation of Bridged Zirconacyclopentenes

Tamotsu Takahashi, Z. Xi, V. Denisov, 1995 .

Trishomoaromatic (B 3 N 3 Ph 6 ) Dianion: Characterization and Two‐Electron Reduction

Chao Yu, Z. Xi, Wen‐Xiong Zhang, 2020, Angewandte Chemie.

Trishomoaromatic (B3N3Ph6)-Dianion: Characterization and Two-Electron Reduction.

Chao Yu, Z. Xi, Wen‐Xiong Zhang, 2020, Angewandte Chemie.

Cycloaddition of zirconacyclopentadienes to alkynes using copper salts: formation of benzene derivatives

Tamotsu Takahashi, M. Kotora, Z. Xi, 1995 .

Diversified Aggregation States of Phospholyl Lithiums

Z. Xi, Shanshan Du, Wen‐Xiong Zhang, 2018, Organometallics.

Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines

Z. Xi, Wen‐Xiong Zhang, Wangyang Ma, 2015 .

Novel [Ruthenium(substituted-tetramethylcyclopentadiene) (2-quinolinecarboxylato)(allyl)] Hexafluorophosphate Complexes as Efficient Catalysts for Highly Regioselective Nucleophilic Substitution of Aliphatic Allylic Substrates

Z. Xi, L. Toupet, C. Bruneau, 2008 .

Cyclic Bis-alkylidene Complexes of Titanium and Zirconium: Synthesis, Characterization and Reaction.

Z. Xi, Mingdong Zhong, Yonglian Zhang, 2020, Chemistry.

Alkyl Aluminum-Catalyzed Addition of Amines to Carbodiimides: A Highly Efficient Route to Substituted Guanidines

Z. Xi, Wen‐Xiong Zhang, Zitao Wang, 2009 .

Synthesis of benzothiophene derivatives from dilithio reagents, sulfur, and electrophiles via electrophilic cyclization

Z. Xi, Wen‐Xiong Zhang, Zitao Wang, 2011 .

Isolation and X-ray Structure of a Trimeric 1,4-Dilithio-1,3-butadiene and a Dimeric Me3Si-Substituted 1,4-Dilithio-1,3-butadiene

Lantao Liu, Z. Xi, Wen‐Xiong Zhang, 2010 .

Synthetic Methods for Multiply Substituted Butadiene‐Containing Building Blocks

Z. Xi, Wen‐Xiong Zhang, 2009 .

Metal Mediated Synthesis of Substituted Cyclooctatetraenes

Z. Xi, Chao Wang, 2008 .

Facile Synthesis of Multiply Substituted Cyclopentadienes and Conjugated Dienals through Reactions between 1,4‐Dilithio‐1,3‐dienes and Carboxylic Acid Derivatives Including Acyl Chlorides, Anhydrides, and DMF

Z. Xi, Zhihui Wang, Guoliang Mao, 2007 .

Partially Fluorinated Naphthalene Derivatives from 1,4-Dilithio-1,3-dienes and C6F6.

Z. Xi, Zhihui Wang, Chao Wang, 2006 .

Metal-mediated efficient synthesis, structural characterization, and skeletal rearrangement of octasubstituted semibullvalenes.

Z. Xi, J. Yuan, Shiwei Zhang, 2006, Journal of the American Chemical Society.

Concise synthesis of multiply substituted stereodefined cis,cis-2,4-diene-1,6-dials, cis,cis-2,4-diene-1,6-diols and further applications

Z. Xi, Cong-Hui Wang, Ayako Muramatsu, 2005 .

Formation of 2,6‐Dioxabicyclo[3.3.0]‐octa‐3,7‐dienes or Multiply Substituted o‐Benzoquinones from Reactions of 1,4‐Dilithio‐1,3‐dienes with Dimethyl Oxalate.

Z. Xi, Guoliang Mao, Jiang Lu, 2005 .

Reactions of 1,4‐Dilithiobutadienes with Isothiocyanates: Preparation of Iminocyclopentadiene Derivatives via Cleavage of the C=S Double Bond of a RN=C=S Molecule.

Q. Song, Z. Xi, Cong-Hui Wang, 2004 .

Reactions of substituted (1,3-butadiene-1,4-diyl)magnesium, 1,4-bis(bromomagnesio)butadienes and 1,4-dilithiobutadienes with ketones, aldehydes and PhNO to yield cyclopentadiene derivatives and N-Ph pyrroles by cyclodialkenylation.

Z. Xi, Hongyun Fang, Guoliang Mao, 2004, Chemistry.

Formation of Stereodefined Multiply Substituted all-cis Octatetraenes, Tricyclo[4.2.0.02.5]octa-3,7-dienes and Pentalenes via CuCl- or FeCl3-Mediated Dimerization of 1-Lithiobutadienes and 1,4-Dilithiobutadienes.

Z. Xi, Hongyun Fang, Guotao Li, 2004 .

Stereoselective synthesis of polysubstituted 2,5-dihydrofurans from reaction of 1,4-dilithio-1,3-dienes with aldehydes.

Pixu Li, Q. Song, Z. Xi, 2002, Organic letters.

Dialkenylation of Carbonyl Groups by Alkenyllithium Compounds: Formation of Cyclopentadiene Derivatives by the Reaction of 1,4‐Dilithio‐1,3‐dienes with Ketones and Aldehydes.

Pixu Li, Q. Song, Z. Xi, 2001 .

Zirconocene mediated cyclization and isomerization of 1,3,6-heptatriene

Tamotsu Takahashi, M. Kotora, Z. Xi, 2002 .

Reaction of (cycloalkenyl)alkylzirconium compounds with alkynes: novel procedure for the formation of bicyclic compounds

Tamotsu Takahashi, M. Kotora, Z. Xi, 2000 .

Cu(I) catalyzed or promoted metallacycle transfer of zirconacycles to stannacycles

Tamotsu Takahashi, Yanzhong Li, Z. Xi, 1998 .

Efficient ruthenium-catalyzed synthesis of [3]dendralenes from 1,3-dienic allylic carbonates.

Basker Sundararaju, Z. Xi, C. Bruneau, 2009, Chemical communications.

C,C- and C,N-Chelated Organocopper Compounds

Zhenqiang Yang, Z. Xi, Hui Chen, 2021, Molecules.

Pd-catalyzed cyclodimerization of alkenyl and aryl dibromides: Construction of dibenzo[a,e]cyclooctatetraenes

Z. Xi, K. Ouyang, Kunbing Ouyang, 2015 .

One-pot synthetic routes to multiply substituted indene derivatives by hydrolysis of zirconocene-mediated intermolecular coupling reactions of aromatic ketones and alkynes.

Hongliang Yan, K. Nakajima, Tamotsu Takahashi, 2003, The Journal of organic chemistry.

Skeletal rearrangement of all-carbon spiro skeletons mediated by a Lewis acid.

Lantao Liu, Z. Xi, Wen‐Xiong Zhang, 2009, Chemical communications.

Organometallic intermediate-based organic synthesis: organo-di-lithio reagents and beyond

Z. Xi, Wen‐Xiong Zhang, 2014 .

Isolable and well-defined butadienyl organocopper(I) aggregates: facile synthesis, structural characterization, and reaction chemistry.

Z. Xi, Junnian Wei, Wen‐Xiong Zhang, 2014, Journal of the American Chemical Society.

Butadienyl Diiron Complexes: Nonplanar Metalla‐Aromatics Involving σ‐Type Orbital Overlap

Shengfa Ye, Chao Yu, Z. Xi, 2020, Angewandte Chemie.

Selective one carbon-carbon bond formation reaction of zirconacyclopentadienes with aryl iodides or alkynyl iodides

C. Xi, Tamotsu Takahashi, Z. Xi, 1998 .

One-pot synthetic route to homoallylketones via selective combination of alkyne, ethylene and aldehyde mediated by AlCl3 and zirconocene.

Z. Xi, Tao Yu, Changjia Zhao, 2002, Chemical communications.

Isolation and Characterization of Zirconacyclopentane

K. Nakajima, Tamotsu Takahashi, Z. Xi, 1996 .

Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation

Yu-Chen Wang, Z. Xi, Wen‐Xiong Zhang, 2016 .

Lewis acid-promoted reactions of zirconacyclopentadienes with isocyanates. A one-pot three-component synthesis of multiply-substituted iminocyclopentadienes from one isocyanate and two alkynes.

Z. Xi, Wen‐Xiong Zhang, Guoliang Mao, 2005, Chemical communications.

1-Lithio-1,3-dienes as useful building blocks in organic synthesis

Z. Xi, Wen‐Xiong Zhang, 2009 .

Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn‐β‐Hydrogen Atoms.

Z. Xi, Junnian Wei, Wei Hao, 2015 .

Transfer of aryl halide to alkyl halide: reductive elimination of alkylhalide from alkylpalladium halides containing syn-β-hydrogen atoms.

Z. Xi, Junnian Wei, Wei Hao, 2014, Angewandte Chemie.

Half-Sandwich Complexes of Dy(III): A Janus-Motif with Facile Tunability of Magnetism.

Song Gao, Z. Xi, Bingwu Wang, 2015, Inorganic chemistry.

3-D Brick-Wall Polymeric Structure of TMEDA-Supported 1,4-Dilithio-1,3-Butadiene

Z. Xi, Ming Zhan, Wen‐Xiong Zhang, 2013 .

Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P64- Ligand

Z. Xi, Shanshan Du, Wen‐Xiong Zhang, 2019, Chinese Journal of Organic Chemistry.

Direct Synthesis of Phospholyl Lithium from White Phosphorus.

Z. Xi, Shanshan Du, Wen‐Xiong Zhang, 2016, Angewandte Chemie.

Synthesis of gem-dihaloenynes and butatrienes from gem-dihalovinyl derivatives

Z. Xi, Hui‐Jun Zhang, Tianhao Meng, 2012 .

Mono- and Bis-Titanium Complexes Bridged by 2-Butene Tetraanion: Synthesis and Structural Characterization

Chao Yu, Z. Xi, Wen‐Xiong Zhang, 2020 .

Alkaline-earth metallacyclic complexes bearing a diborane-bridged tetraamide ligand: synthesis, structure and fluorescence property.

Z. Bian, Chao Yu, Z. Xi, 2019, Dalton transactions.

Synthesis and Reactivity of Side-Arm Phosphine Functionalized Amidinatosilylene- and Amidinatogermylene-Supported Nickel(0) Complexes

Z. Xi, Mingdong Zhong, Junnian Wei, 2021 .

Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P-C Bonds.

Z. Xi, Jimin Yang, Gen Luo, 2019, Journal of the American Chemical Society.

Isolation and Characterization of Four Phosphorus Cluster Anions P 7 3– , P 14 4– , P 16 2– and P 26 4– from the Nucleophilic Functionalization of White Phosphorus with 1,4‐Dilithio‐1,3‐butadienes

Z. Xi, Shanshan Du, Wen‐Xiong Zhang, 2018, Chinese Journal of Chemistry.

The aromatic dianion metalloles

Z. Xi, Junnian Wei, Wen‐Xiong Zhang, 2017, Chemical science.

Synthesis of gem-Dihaloenynes and Butatrienes from gem-Dihalovinyl Derivatives.

Z. Xi, Hui‐Jun Zhang, Tianhao Meng, 2012 .

Advances in the synthesis and reactivity of 2-pyranylidene carbene complexes

Z. Xi, Wen‐Xiong Zhang, Qifeng Wang, 2010 .

Preparation of partially substituted 1-halo- and 1,4-dihalo-1,3-dienes via reagent-controlled desilylation of halogenated 1,3-dienes.

Guang‐Zhen Liu, Zhiyi Song, Tamotsu Takahashi, 2006, The Journal of organic chemistry.

Synthesis of 1,1,4,4-tetrabromo-2-butenes and related compounds via desilylation-bromination of silylated 1,3-butadiene derivatives.

Tamotsu Takahashi, Z. Xi, Zhiping Li, 2004, The Journal of organic chemistry.

Oxidation of C-H bonds to C=O bonds by O2 only or N-oxides and DMSO: synthesis of Δ(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes.

Z. Xi, Ming Zhan, Wen‐Xiong Zhang, 2013, Chemical communications.

Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts.

Z. Xi, Junnian Wei, Wen‐Xiong Zhang, 2016, Angewandte Chemie.

Dilithio Spiro Zincacyclopentadienes and Dizinca[10]cycles: Synthesis and Structural Characterization

Tianyang Chen, Z. Xi, Yonglian Zhang, 2019, Organometallics.

Organometallic intermediate-based organic synthesis: organo-di-lithio reagents and beyond

Z. Xi, Wen‐Xiong Zhang, 2014 .

A tris-spiro metalla-aromatic system featuring Craig-Möbius aromaticity

Shengfa Ye, Z. Xi, Junnian Wei, 2021, Nature Communications.

Tetralithio Metalla-aromatics with Two Independent Perpendicular Dilithio Aromatic Rings Spiro-fused by One Manganese Atom.

Shengfa Ye, Z. Xi, Junnian Wei, 2019, Angewandte Chemie.

Tetralithio Metalla‐aromatics with Two Independent Perpendicular Dilithio Aromatic Rings Spiro‐fused by One Manganese Atom

Shengfa Ye, Z. Xi, Junnian Wei, 2019, Angewandte Chemie.

Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization.

Xuan Zhang, Z. Xi, Junnian Wei, 2017, Journal of the American Chemical Society.

Synthesis of pyrimidines from dinitrogen and carbon

Teng He, Z. Xi, Jianping Guo, 2022, National Science Review.

Formation of 2,6-dioxabicyclo[3.3.0]-octa-3,7-dienes or multiply substituted o-benzoquinones from reactions of 1,4-dilithio-1,3-dienes with dimethyl oxalate

Z. Xi, Guoliang Mao, Jiang Lu, 2004 .

Reaction of 4-methyl, 4-phenyl, and 4-hydrogen substituted 1-lithio-1,3-butadienes with aldehydes: preparation of multiply substituted cyclopentadienes

Z. Xi, Zhihui Wang, Hongyun Fang, 2006 .

Reaction of 4-Methyl, 4-Phenyl, and 4-Hydrogen Substituted 1-Lithio-1,3-butadienes with Aldehydes: Preparation of Multiply Substituted Cyclopentadienes.

Z. Xi, Zhihui Wang, Hongyun Fang, 2006 .

Preparation of vinyl allenes from 1-lithio-1,3-dienyl phosphine oxides and aldehydes by the Wittig-Horner reaction.

F. Kong, Zhiyi Song, Tamotsu Takahashi, 2005, Journal of Organic Chemistry.

Concise synthesis of stereodefined dienols and cyclopentadienes via direct addition of 1-bromomagnesiobutadienes and 1-lithiobutadienes to carbonyl compounds

Q. Song, Z. Xi, Zhihui Wang, 2004 .

Generation of cyclobutadiene derivatives from 1-metallo-4-halobuta-1,3-diene derivatives

Tamotsu Takahashi, Z. Xi, Wen‐Hua Sun, 1998 .

Preparation of Vinyl Allenes from 1‐Lithio‐1,3‐dienyl Phosphine Oxides and Aldehydes by the Wittig—Horner Reaction.

F. Kong, Zhiyi Song, Tamotsu Takahashi, 2006 .

Concise Synthesis of Stereodefined Dienols and Cyclopentadienes via Direct Addition of 1‐Bromomagnesiobutadienes and 1‐Lithiobutadienes to Carbonyl Compounds.

Q. Song, Z. Xi, Zhihui Wang, 2004 .

Generation of Cyclobutadiene Derivatives from 1-Metallo-4-halobuta-1,3-diene Derivatives.

Z. Xi, Wen‐Hua Sun, H. Ubayama, 1999 .

Reversible Two-Electron Redox Reactions Involving Tetralithio/Dilithio Palladole, Platinacycle, and Dicupra[10]annulene

Z. Xi, Yonglian Zhang, Wen‐Xiong Zhang, 2019, Organometallics.

Cyclobutadiene Sandwich Complexes of Nickel and Iron from Cyclization of 1,3-Butadiene Dianions: Synthesis and Structural Characterization

Chao Yu, Z. Xi, Wen‐Xiong Zhang, 2018, Organometallics.

Inverse-Sandwich Cyclobutadiene Dinickel Complexes: Synthesis and Structural Characterization

Chao Yu, Z. Xi, Wen‐Xiong Zhang, 2020 .

Combining Pd(π-allyl)Cp and PPh3 as a unique catalyst for efficient synthesis of alkyliodo indoles via C(sp3)–I reductive elimination

P. Walsh, Z. Xi, Wei Hao, 2015 .

Rhodium-catalyzed intramolecular carbosilylation of alkynes via C(sp3)–Si bond cleavage

Z. Xi, Wei Hao, Wen‐Xiong Zhang, 2018 .

Roles of Bases in Transition-Metal Catalyzed Organic Reactions

Z. Xi, K. Ouyang, 2013 .

Synthesis and structural analysis of titanium-μ-dinitrogen complex supported by di-anionic guanidinate ligands

Z. Xi, Junnian Wei, Gaoji Wang, 2023, Science China Chemistry.

Synthesis, Structural Characterization, and Reactivity of a Fluorene-Based Calcium Oxycyclopentadienide Complex

Z. Xi, Wen‐Xiong Zhang, Baosheng Wei, 2015 .

Unprecedented double C-C bond cleavage of a cyclopentadienyl ligand.

Tamotsu Takahashi, Z. Xi, Kimihiko Sato, 2003, Journal of the American Chemical Society.

Unprecedented Double C—C Bond Cleavage of a Cyclopentadienyl Ligand.

Tamotsu Takahashi, Z. Xi, Kimihiko Sato, 2003 .

Snapshots of Early-Stage Quantitative N2 Electrophilic Functionalization.

Shengfa Ye, Z. Xi, Junnian Wei, 2023, Journal of the American Chemical Society.

Dinitrogen Functionalization Affording Chromium Diazenido and Side-on η2-Hydrazido Complexes.

Z. Xi, Junnian Wei, Gaoji Wang, 2023, Journal of the American Chemical Society.

Dinitrogen Functionalization Affording Structurally Well-Defined Cobalt Diazenido Complexes

Z. Xi, Lili Zhao, Mingdong Zhong, 2021 .

Reactions of Aluminacyclopentadienes with Aldehydes Affording Cyclopentadiene Derivatives.

Z. Xi, Hongyun Fang, Changjia Zhao, 2003 .

Construction of octaalkyl-substituted and decasubstituted all-cis-octatetraenes via linear dimerization of 1,4-dicopper-1,3-butadienes and subsequent cross-coupling with halides.

Z. Xi, Junnian Wei, Wen‐Xiong Zhang, 2013, Organic letters.

Palladium-catalyzed intermolecular coupling of 2-silylaryl bromides with alkynes: synthesis of benzosiloles and heteroarene-fused siloles by catalytic cleavage of the C(sp3)-Si bond.

Z. Xi, Yun Liang, Junnian Wei, 2012, Angewandte Chemie.

Reaction of Dilithio Reagents with PhSiH3: Formation of Siloles and 3-Silacyclopentenes.

Z. Xi, Wen‐Xiong Zhang, Baosheng Wei, 2015, The Journal of organic chemistry.

Transition-Metal-Catalyzed Cleavage of C-N Single Bonds.

Z. Xi, Wei Hao, Wen‐Xiong Zhang, 2015, Chemical reviews.

Direct conversion of N2 and O2: status, challenge and perspective

Dehui Deng, Zhangjie Shi, Z. Xi, 2022, National science review.

Ruthenium Catalysts for Controlled Mono- and Bis-Allylation of Active Methylene Compounds with Aliphatic Allylic Substrates

Z. Xi, C. Bruneau, B. Demerseman, 2009 .

Ruthenium-Catalyzed Nucleophilic Allylic Substitution Reactions from beta-Silylated Allylic Carbonates

Z. Xi, L. Toupet, C. Bruneau, 2009 .

Hydride-induced novel cyclization of dienedinitriles leading to multifunctionalized cyclopentadienes.

Z. Xi, C. Bruneau, B. Demerseman, 2009, Organic letters.

Preparation of S-containing heterocycles via novel reaction patterns of carbon disulfide with 1-lithiobutadienes and 1,4-dilithiobutadienes

Q. Song, Z. Xi, Cong-Hui Wang, 2003 .

Pixu Li, Q. Song, Z. Xi, 2001, Angewandte Chemie.

Palladium-Catalyzed Intermolecular Domino Reaction of gem-Dibromoenynes with Anilines; A One-Pot Synthesis of Quinolines and Quinolinones

Z. Xi, Yun Liang, Wen‐Xiong Zhang, 2012 .

Substituent-controlled selective synthesis of N-acyl 2-aminothiazoles by intramolecular Zwitterion-mediated C-N bond cleavage.

Z. Xi, Wen‐Xiong Zhang, Yang Wang, 2014, The Journal of organic chemistry.

Alkenylzirconocene-mediated preparation of alkenylphosphines.

K. Nakajima, Tamotsu Takahashi, Z. Xi, 2007, The Journal of organic chemistry.