Robert A. Gossage

发表

The Effect of the Trimethylsilyl Group on Electrophilic Cyclopalladation; A study of Caryl -Si versus Caryl-H Selective Bond Activation with 2,6-(Me2NCH2)2C6H3R (R=H or SiMe3)

D. M. Grove, G. Koten, P. Steenwinkel, 1998 .

A General Survey and Recent Advances in the Activation of Unreactive Chemical Bonds by Metal Complexes

G. Koten, Robert A. Gossage, 2000 .

Activation of Unreactive Bonds and Organic Synthesis

William Jones, Shunji Murai, V. V. Grushin, 1999 .

Synthesis, Characterization, and Theoretical Analysis of Soluble Poly(oxothiazenes): The Ambient Temperature Lewis Acid Catalyzed in Situ Polymerization of N-Silylsulfonimidoyl Chlorides

Robert A. Gossage, D. Foucher, Jon-Paul S. Ward, 2013 .

Biomass Utilisation Strategies for Applications in Novel Polymer and Polymer Resin Production

A. Lough, Robert A. Gossage, D. Foucher, 2017 .

Transfer hydrogenation with abnormal dicarbene rhodium(iii) complexes containing ancillary and modular poly-pyridine ligands.

M. Albrecht, H. Müller‐Bunz, Robert A. Gossage, 2016, Dalton transactions.

Recent advances in the homogeneous polymerisation of olefins mediated by nickel complexes

Robert A. Gossage, D. Foucher, Yee-Yue Grace Luk, 2013 .

Tautomerism and metal complexation of 2-acylmethyl-2-oxazolines: a combined synthetic, spectroscopic, crystallographic and theoretical treatment.

J. Quail, B. Koivisto, A. Lough, 2013, Organic & biomolecular chemistry.

Alkene and Alkyne Reactivity Towards a Bisruthenium (II) µ2-Dinitrogen Complex Containing the 'Pincer' ligand 2,6-Bis[(dimethylamino)methyl]pyridine(NN'N). The X-ray Crystal Structures of [Ru(=C=CHPh)Cl2(NN'N)] and [Ru(=C=CHPh)(OTf)(NN'N)(PPh3)][OTf] (OTf =Trifluoromethane Sulfonate)

G. Koten, A. Spek, M. Lutz, 1999 .

Oxazoles revisited: On the nature of binding of benzoxazole and 2-methylbenzoxazole with the zinc and palladium halides.

J. Quail, B. Yates, Robert A. Gossage, 2011, Dalton transactions.

Pre-catalyst resting states: a kinetic, thermodynamic and quantum mechanical analyses of [PdCl2(2-oxazoline)2] complexes.

N. D. Jones, B. Yates, Robert A. Gossage, 2008, Dalton transactions.

Synthesis and catalytic applications of 1,2,3-triazolylidene gold(i) complexes in silver-free oxazoline syntheses and C-H bond activation.

M. Albrecht, P. Pérez, R. Pretorius, 2016, Dalton transactions.

Proof of Concept Studies Directed Towards Designed Molecular Wires: Property-Driven Synthesis of Air and Moisture-Stable Polystannanes.

A. Lough, Robert A. Gossage, D. Foucher, 2017, Chemistry.

Oxazoline Chemistry. Part 11: Syntheses of natural and synthetic isoflavones, stilbenes and related species via C–C bond formation promoted by a Pd–oxazoline complex

Robert A. Gossage, P. N. Yadav, Charles R. Eisnor, 2006 .

Synthesis and characterization of ruthenium ‘pincer’ complexes containing sulfur atom donor ligands. The X-ray crystal structure of [RuCl2(η3-NN′N)(SMe2)] (NN′N={2,6-(Me2NCH2)2C5H3N})

G. Koten, A. Spek, M. Lutz, 1999 .

Reactivity of a binuclear Ru(II) N2-bridged complex towards phosphines: facile access to novel mono and binuclear phosphorous derivatives. X-ray structural characterization of two unusual binuclear complexes containing ‘pincer’ ligands: [{RuCl2(η3-NN′N)}2(μ-η2-P2)] (NN′N=2,6-bis[(dimethylamino)methy

G. Koten, A. Spek, M. Lutz, 1999 .

Diaminoarylnickel(II) “Pincer” Complexes: Mechanistic Considerations in the Kharasch Addition Reaction, Controlled Polymerization, and Dendrimeric Transition Metal Catalysts

G. Koten, Robert A. Gossage, van de L.A. Kuil, 1998 .

Recent Findings in Cyclometallation of meta‐Substituted Aryl Ligands by Platinum Group Metal Complexes by Caryl–R Bond Activation (R=H, CR3, SiR3)

G. Koten, P. Steenwinkel, Robert A. Gossage, 1998 .

Synthesis, Characterization, and Catalytic Exploration of Mononuclear Mo(VI) Dioxido Complexes of (Z)-1-R-2-(4′,4′-Dimethyl-2′-oxazolin-2′-yl)-eth-1-en-1-ates

A. Lough, Robert A. Gossage, A. Petrov, 2022, Molecules.

Piperonylic anhydride: Isolation and conformational analysis by X-ray crystallography and density functional theory calculations

A. Lough, Robert A. Gossage, R. S. Wylie, 2011 .

Ortho-bis(amino)arylnickel(II) halide complexes containing perfluoroalkyl chains as model catalyst precursors for use in fluorous biphase systems

G. Koten, A. Spek, Robert A. Gossage, 1998 .

Lanthanide complexes of an oxazoline-phenoxide hybrid chelate

B. Twamley, Shengyu Feng, Chuanjian Zhou, 2005 .

Titanium σ-acetylides as building blocks for heterobimetallic transition metal complexes: synthesis and redox behaviour of π-conjugated organometallic systems

G. Koten, H. Lang, Robert A. Gossage, 1999 .

RuIII Complexes of Edta and Dtpa Polyaminocarboxylate Analogues and Their Use as Nitric Oxide Scavengers

J. Zubieta, Michael T. Wilson, T. Storr, 2005 .

Pd-catalysed reactions of alkynes with model distannanes and poly[di-(n-butyl)]stannane.

A. Lough, Robert A. Gossage, D. Foucher, 2013, Dalton transactions.

Oxazoles XXI. Three Ester Ammonium Salts Resulting from the Rupture of an Oxazoline Ring

J. Quail, Robert A. Gossage, H. Jenkins, 2010 .

ortho‐Bis(amino)arylnickel(II) Halide Complexes Containing Perfluoroalkyl Chains as Model Catalyst Precursors for Use in Fluorous Biphase Systems.

G. Koten, A. Spek, Robert A. Gossage, 1998 .

New ' Bucky- ligands'. Potentially Monoanionic Terdentate Diamino Aryl Pincer Ligands Anchored to C60

G. Koten, M. Rump, Robert A. Gossage, 1998 .

Sulfur dioxide gas detection by reversible η1-SO2–Pt bond formation as a novel application for periphery functionalised metallo-dendrimers‡

G. Koten, A. Spek, M. Albrecht, 1998 .

Transition metal complexes of monodentate 2-oxazolines containing long chain alkyl groups. The crystal structure of trans-PdCl2(κ1-N-rac-2-heptadecyl-4,5-dihydro-5-methyl-2-oxazole)2

A. Lough, Robert A. Gossage, G. Sacripante, 2020 .

Application of an air stable Pd oxazoline complex for Heck, Suzuki, Sonogashira and related C–C bond-forming reactions

Robert A. Gossage, H. Jenkins, P. N. Yadav, 2004 .

Enhanced product selectivity promoted by remote metal coordination in acceptor-free alcohol dehydrogenation catalysis.

M. Albrecht, H. Müller‐Bunz, Robert A. Gossage, 2016, Chemical communications.

Synthesis and characterization of two new "pincer" complexes of zinc(II). The X-ray crystal structures of the five coordinate complexes [ZnCl2{η3-NN'N-2,6-(R2NCH2)2C5H3N}] (R = n-Bu or Me)

G. Koten, A. Spek, M. Lutz, 2000 .

SYNTHESIS AND CATALYTIC APPLICATION OF AMINO ACID BASED DENDRITIC MACROMOLECULES

G. Koten, R. Liskamp, A. J. Brouwer, 1999 .

Synthesis of a key reactive unit for use in the divergent or convergent synthesis of carbosilane dendrimers

G. Koten, Robert A. Gossage, E. Muñoz-Martínez, 1998 .

Oxazoline chemistry — Part IV: Synthesis and characterization of oxazoline complexes of the zinc halides

Robert A. Gossage, I. D. Rı́o, T. Barclay, 2003 .

Oxazoline chemistry part III. Synthesis and characterisation of [2‐(2′‐anilinyl)‐2‐oxazolines] and some related compounds

Robert A. Gossage, Karen M. Button, 2003 .

Hetero-aggregate compounds of aryl and alkyl lithium reagents: a structurally intriguing aspect of organolithium chemistry.

G. van Koten, Robert A. Gossage, J. Jastrzebski, 2005, Angewandte Chemie.

Unusual cationic trinuclear nickel clusters incorporating oxazolines or N,N,N',N'-tetramethylethylene-1,2-diamine: applications in olefin polymerization.

J. Quail, Robert A. Gossage, D. Foucher, 2011, Inorganic chemistry.

Structurally characterised silyls

Robert A. Gossage, 2000 .

Synthesis and characterisation of κ2-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation

A. Lough, Robert A. Gossage, Jeanette A. Adjei, 2019, RSC advances.

Divalent cobalt and copper coordination complexes of κ2-N, O-derivatives of (Z)-1-R-2-(2′-oxazolin-2′-yl)-eth-1-en-1-ates: Structure and reactivity patterns

A. Lough, Robert A. Gossage, S. Resanović, 2019, Inorganica Chimica Acta.

A report on the “new frontiers in group 13 chemistry” symposium from the 88th Canadian Society for Chemistry Conference and Exhibition

Robert A. Gossage, S. Westcott, 2007 .

Oxazoles XXII. The Cobalt(II) Coordination Chemistry of 2-(ortho-Anilinyl)-4,4-dimethyl-2-oxazoline: Syntheses, Properties, and Solid-State Structural Characterization

Robert A. Gossage, A. Decken, Susan L. Wheaton, 2010 .

Synthesis, Structure, and Reactivity of an Unusual Platinum Olefin Carbene Complex, [(η4-cod)Pt{C(Ph2PNSiMe3)2-κC,κN}]

N. D. Jones, R. McDonald, Robert A. Gossage, 2003 .

Organomolybdenum(VI) and Lithium Organomolybdate(VI) and -(V) Complexes with C,N-Chelating Aminoaryl Ligands

G. Koten, A. Spek, Robert A. Gossage, 1999 .

Oxazoline chemistry. Part 12: A metal-mediated synthesis of DMU-212; X-ray diffraction studies of an important anti-cancer agent

Robert A. Gossage, H. Jenkins, Charles R. Eisnor, 2006 .

Platinum-oxazoline complexes as anti-cancer agents: syntheses, characterisation and initial biological studies

T. Hambley, J. Blay, Robert A. Gossage, 2011 .

Amido-pincer complexes of Cu(II): Synthesis, coordination chemistry and applications in catalysis ☆

A. Lough, Robert A. Gossage, Joaquín García‐Álvarez, 2017 .

On the purity of 2‐[ortho‐anilinyl]‐1,3‐benzoxazole derived from 2H‐3,1‐benzoxazine‐2,4(1H)dione (isatoic anhydride) [1,2]

Tayseer Mahdi, Robert A. Gossage, H. Jenkins, 2010 .

Coordination chemistry and applications of metal phenolates containing an oxazoline group

Robert A. Gossage, M. Taghvaee, 2013 .

Zinc halide oxazoline complexes — The quest for structural diversity

J. Quail, Robert A. Gossage, A. Decken, 2009 .

The Crystal Structure of bis-(μ-N-ethyl-Nphenyldithiocarbamato- S,S’)-bis[(N-ethyl-Nphenyldithiocarbamato- κ2S,S’)zinc(II)]

Robert A. Gossage, H. Jenkins, 2009 .

Crystallographic report: Bis(N,N‐dibenzyldithiocarbamato)mercury(II)

E. Tiekink, Robert A. Gossage, A. Decken, 2004 .

Synthesis and biological activities of 4-N-(anilinyl-n-[oxazolyl])-7-chloroquinolines (n=3' or 4') against Plasmodium falciparum in in vitro models.

Todd G. Smith, S. Ward, Robert A. Gossage, 2011, Bioorganic & medicinal chemistry letters.

Novel tridentate diamino organomanganese(II) complexes as homogeneous catalysts in manganese(II)/copper(I) catalyzed carbon-carbon bond forming reactions

G. Koten, G. Cahiez, J. Vicario, 1998 .

Pincer Complexes of Lithium, Sodium, Magnesium and Related Metals: A Discussion of Solution and Solid-State Aggregated Structure and Reactivity

Robert A. Gossage, 2015 .

Synthesis and characterisation of the first transition metal complex of zoxazolamine (2-amino-5-chlorobenzoxazole): the X-ray crystal structure determination of [ZnCl2(eta 1-Nbenzoxazole-2-amino-5-chlorobenzoxazole)2].

Robert A. Gossage, A. Decken, 2005, Journal of inorganic biochemistry.

Mechanistic aspects of the reversible binding of SO2 on arylplatinum complexes: Experimental and ab initio studies

G. Koten, M. Albrecht, E. Baerends, 2001 .

Models for the Initial Stages of Oxidative Addition : Synthesis, Characterization and Mechanistic Investigation of N1-I2 Organometallic 'Pincer' Complexes of Platinum : X-ray Crystal Structures of [Ptl(C6H3{CH2NMe2}2-2,6)(N1-I2)] and exo-meso-[Pt(N1-I3)(N1-I2)(C6H3{CH2N-(t-Bu)Me}2-2,6)

G. Koten, A. Spek, A. Ryabov, 1999 .

Oxazoline chemistry. Part VIII. Synthesis and characterization of a new class of pincer ligands derived from the 2-(o-anilinyl)-2-oxazoline skeleton Applications to the synthesis of group X transition metal catalysts

Robert A. Gossage, A. Decken, P. Yadav, 2005 .

Coordination Behaviour of the New Multidentate Ligand 3,5‐Bis(dimethylaminomethyl)pyridine with Palladium(II) and Platinum(II) Metal Centres

G. Koten, A. Spek, Robert A. Gossage, 1998 .

Pincer oxazolines: emerging tools in coordination chemistry and catalysis--where to next?

Robert A. Gossage, 2011, Dalton transactions.

Solid-state and solution structures of hetero-aggregates formed between nBuLi and NCN pincer aryl lithium.

Preston A. Chase, A. Spek, G. van Koten, 2008, Dalton transactions.

Formation of organolithium hetero-aggregates [Li4Ar2(nBu)2] (Ar=C6H4CH(Me)NMe2-2) during the directed ortho-lithiation of [1-(dimethylamino)ethyl]benzene.

Gerard van Koten, Martin Lutz, Claudia M P Kronenburg, 2004, Chemistry.

Mononuclear ruthenium complexes containing chiral aminooxazolines: Syntheses, X-ray studies and catalytic activity

Robert A. Gossage, I. D. Rı́o, D. Miguel, 2007 .

Replacement of a cyclometalated terdentate diamino ligand by a phosphorus analogue. Isolation and crystallographic characterization of an intermediate in aryl C-H bond activation in models of dendrimer-bound organometallic catalysts

G. Koten, A. Spek, Robert A. Gossage, 1997 .

Mechanistic Aspects of the Kharasch Addition Reaction Catalyzed by Organonickel(II) Complexes Containing the Monoanionic Terdentate Aryldiamine Ligand System [C6H2(CH2NMe2)2-2,6-R-4]-†

D. M. Grove, G. Koten, L. W. Jenneskens, 1997 .

Models for the Initial Stages of Oxidative Addition. Synthesis, Characterization, and Mechanistic Investigation of η-I2 Organometallic “Pincer” Complexes of Platinum. X-ray Crystal Structures

G. Koten, A. Spek, A. Ryabov, 1999 .

Modern Organometallic Multidentate Ligand Design Strategies: The Birth of the Privileged “Pincer” Ligand Platform

Preston A. Chase, G. Koten, Robert A. Gossage, 2015 .

Triruthenium carbonyl clusters derived from chiral aminooxazolines: synthesis and catalytic activity.

I. da Silva, Robert A. Gossage, D. Miguel, 2006, Dalton transactions.

Organometallic Iridium Complexes of (Z)-1-Phenyl-2-(4′,4′-dimethyl-2′-oxazolin-2′-yl)-eth-1-en-1-ate: Structural Aspects, Reactivity and Applications in the Catalytic Dehydrogenation of Alkanes

A. Lough, Robert A. Gossage, Roxanne Clément, 2021, Bulletin of the Chemical Society of Japan.

A convenient route to distannanes, oligostannanes, and polystannanes

Robert A. Gossage, D. Foucher, Aman Khan, 2010 .

Synthesis of a New Multidentate Phosphane Ligand C6H2(CH2PPh2)4‐1,2,4,5 − X‐ray Structure of a Dinuclear Ruthenium(II)‐Bridged Complex: [{RuCl2(PPh3)}2{C6H2(CH2PPh2)4‐1,2,4,5‐P,P′,P′′,P′′′}]

G. Koten, N. Veldman, A. Spek, 1998 .

Resveratrol analog trans 3,4,5,4′-tetramethoxystilbene (DMU-212) mediates anti-tumor effects via mechanism different from that of resveratrol

R. Lai, A. Lavasanifar, Robert A. Gossage, 2008, Cancer Chemotherapy and Pharmacology.

The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications

G. Koten, M. Albrecht, Robert A. Gossage, 2016 .

(Phosphinoalkyl)silanes. 3.(1) Poly(o-(diphenylphosphino)benzyl)silanes: Synthesis, Spectroscopic Properties, and Complexation at Platinum or Iridium.

Robert A. Gossage, S. R. Stobart, G. McLennan, 1996, Inorganic chemistry.

Metal-Mediated C-C Bond Making and Breaking : First Direct Evidence for a Reversible Migration of a Benzyl Group Along a Metal-Carbon Bond

G. Koten, A. Spek, Robert A. Gossage, 1999 .

Mixed Metal Acetylides: The PtII Aryl Acetylide “[PtC6H2(CH2NMe2)22,6‐(C≡C)‐4]” as a Connective Fragment

G. Koten, H. Lang, Robert A. Gossage, 2000 .

On the kinetics and mechanism of the conversion of Cr(CO)5(κ1-P-dppm) to Cr(CO)4(κ2-P,P′-dppm) (dppm = 1,2-diphenylphosphinomethane): an alternative hypothesis

Robert A. Gossage, 2018, Transition Metal Chemistry.

A tris(carbene) pincer complex: monomeric platinum carbonyl with three bound carbene centers.

N. D. Jones, R. McDonald, Robert A. Gossage, 2003, Angewandte Chemie.

Synthesis and Characterization of the Bis-Cyclometalating Ligand 3,3‘,5,5‘-Tetrakis[(dimethylamino)methyl]biphenyl and Its Use in the Preparation of Bimetallic M(II), M(IV) (M = Pt, Pd), and Mixed-Valence Pt(II)−Pt(IV) Complexes via a Dilithio-Derivative. Crystal Structure of the Pd Dimer [ClPd{2,6-

G. Koten, A. Spek, Robert A. Gossage, 1998 .

Correlations of carbonyl stretching frequencies and 31P and 95Mo NMR parameters for FAC-[Mo(CO)3(bipy)(PR3)] complexes

Robert A. Gossage, E. C. Alyea, Z. A. Munir, 1990 .

A 95Mo NMR study of bis[pentacarbonylmolybdenum(O)] bridging ditertiary phosphine complexes. The crystal structure of [Mo(CO)5]2(μ-Ph2PCH2CH2CH 2PPh2)

M. Jennings, Robert A. Gossage, K. Fisher, 1990 .

Ligand effects in the substitution chemistry of cis-bis(piperidine)tetracarbonylmolybdenum(O). A molybdenum-95 NMR study

Robert A. Gossage, E. C. Alyea, J. Malito, 1992 .

Preparation and DFT Studies of κ2C,N-Hypercoordinated Oxazoline Organotins: Monomer Constructs for Stable Polystannanes

A. Lough, Robert A. Gossage, D. Foucher, 2020, Inorganics.

A SIMPLE LARGE SCALE SYNTHESIS OF 1,3-BIS-(4,4-DIMETHYL-2-OXAZOLINYL)BENZENE1*

Robert A. Gossage, Karen M. Button, R. Phillips, 2002 .

Replacing the Z-phenyl Ring in Tamoxifen® with a para-Connected NCN Pincer-Pt-Cl Grouping by Post-Modification †

G. P. V. van Klink, G. van Koten, M. Lutz, 2021, Molecules.

Hydrogen-Transfer Catalysis with Pincer-Aryl Ruthenium(II) Complexes.

Dani, Gossage, G. van Koten, 2000, Angewandte Chemie.

The Crystal and Molecular Structure of (2Z)-2-[3-(4-Methoxybenzoyl)-4,4-dimethyl-1,2-oxazolidin-2-ylidene]-1-(4-methoxyphenyl)ethanone

A. Lough, Robert A. Gossage, A. Petrov, 2011 .

THE CRYSTAL STRUCTURE AND QUANTUM MECHANICAL TREATMENT OF THE ANTI-CANCER AGENT FLAVOPIRIDOL (HYDROCHLORIDE) AND THE CHROMONE ALKALOID ROHITUKINE

J. Quail, Robert A. Gossage, 2011 .

Enhanced product selectivity promoted by remote metal coordination in acceptor-free alcohol dehydrogenation catalysis.

M. Albrecht, H. Müller‐Bunz, Robert A. Gossage, 2016, Chemical communications.

Diaminoarylnickel(II) “Pincer” Complexes: Mechanistic Considerations in the Kharasch Addition Reaction, Controlled Polymerization, and Dendrimeric Transition Metal Catalysts

G. Koten, Robert A. Gossage, L. A. V. D. Kuil, 1998 .

The "Dendritic Effect" in Homogeneous Catalysis with Carbosilane-Supported Arylnickel(II) Catalysts: Observation of Active-Site Proximity Effects in Atom-Transfer Radical Addition.

Arjan W. Kleij, Gossage, G. Koten, 2000, Angewandte Chemie.

Synthesis and catalytic applications of 1,2,3-triazolylidene gold(i) complexes in silver-free oxazoline syntheses and C-H bond activation.

M. Albrecht, P. Pérez, R. Pretorius, 2016, Dalton transactions.

The development of Au-titania photoanode composites toward semiflexible dye-sensitized solar cells

E. Schott, X. Zarate, Robert A. Gossage, 2023, Solar Energy.

Hypercoordinating Stannanes with C,N-Donor Ligands: A Structural, Computational, and Polymerization Study

A. Lough, Robert A. Gossage, D. Foucher, 2024, Inorganics.

Zinc (II) Bromide: An Overview of its Solution Chemistry and Recent Applications in Synthesis†

Robert A. Gossage, 2006 .