X. Qi

发表

Mechanism of Synergistic Cu(II)/Cu(I)-Mediated Alkyne Coupling: Dinuclear 1,2-Reductive Elimination after Minimum Energy Crossing Point.

Lei Zhu, R. Jin, Y. Lan, 2016, The Journal of organic chemistry.

β-Mannosylation via O-Alkylation of Anomeric Cesium Alkoxides: Mechanistic Studies and Synthesis of the Hexasaccharide Core of Complex Fucosylated N-Linked Glycans.

P. Liu, Peng Liu, X. Qi, 2020, European journal of organic chemistry.

Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydrobo-ration of Disubstituted Alkenes.

P. Liu, J. Hartwig, Peng Liu, 2020, Journal of the American Chemical Society.

Homolytic cleavage of the O-Cu(ii) bond: XAFS and EPR spectroscopy evidence for one electron reduction of Cu(ii) to Cu(i).

Jyhfu Lee, Jeffrey T. Miller, A. J. Kropf, 2016, Chemical communications.

Dual-Resolving of Lipid Positional and Geometric Isomers of C=C Bonds via Bifunctional Photocycloaddition-Photoisomerization Reaction System and Mass Spectrometry

Qiongqiong Wan, X. Qi, Jiayi Chen, 2022, bioRxiv.

Visible Light-Driven Aza-ortho-Quinone Methide Generation Enables a Multicomponent Reaction

Xiao‐Ye Yu, W. Xiao, Jia‐Rong Chen, 2017 .

Visible-Light-Driven Aza-ortho-quinone Methide Generation for the Synthesis of Indoles in a Multicomponent Reaction.

Xiao‐Ye Yu, W. Xiao, Jia‐Rong Chen, 2017, Angewandte Chemie.

Ir(III)/Ir(V) or Ir(I)/Ir(III) Catalytic Cycle? Steric-Effect-Controlled Mechanism for the para-C–H Borylation of Arenes

Lei Zhu, Lufeng Zou, Y. Lan, 2017 .

Effective Chirality Transfer in [3+2] Reaction between Allenyl-Rhodium and Enal: Mechanistic Study Based on DFT Calculations.

Tao Zhang, Jianxian Gong, Zhen Yang, 2016, The Journal of organic chemistry.

From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3 + 2] Cycloaddition

Lei Zhu, Y. Lan, X. Qi, 2017, Scientific Reports.

Construction of axial chirality via asymmetric radical trapping by cobalt under visible light

W. Xiao, X. Qi, Liang‐Qiu Lu, 2022, Nature Catalysis.

Visible‐Light‐Mediated Decarboxylation/Oxidative Amidation of α‐Keto Acids with Amines under Mild Reaction Conditions Using O2.

Y. Lan, Qiang Liu, Jie Liu, 2014 .

Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation

W. Xiao, Jia‐Rong Chen, Q. Wei, 2016, Nature Communications.

The mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO2: a computational study

Lei Zhu, Da‐Gang Yu, Y. Lan, 2018 .

Oxidation-induced C-H amination leads to a new avenue to build C-N bonds.

Jyhfu Lee, Hong Chen, Y. Lan, 2017, Chemical communications.

Transition-metal-assisted radical/radical cross-coupling: a new strategy to the oxidative C(sp3)-H/N-H cross-coupling.

Y. Lan, A. Lei, X. Qi, 2014, Organic letters.

An enzymatic platform for the asymmetric amination of primary, secondary and tertiary C(sp3)–H bonds

F. Arnold, Peng Liu, Peng Liu, 2019, Nature Chemistry.

Photoredox-Enabled Chromium-Catalyzed Alkene Diacylations

Wei Zhao, W. Xiao, X. Qi, 2022, ACS Catalysis.

Nickel-catalyzed selective oxidative radical cross-coupling: an effective strategy for inert Csp3-H functionalization.

Dong Liu, Y. Lan, A. Lei, 2015, Organic letters.

Precise electro-reduction of alkyl halides for radical defluorinative alkylation

Zhiliang Huang, A. Lei, X. Qi, 2022, Science China Chemistry.

Stereodivergent Alkyne Hydrofluorination Using Protic Tetrafluoroborates as Tunable Reagents.

Peng Liu, X. Qi, Ruihan Wang, 2020, Angewandte Chemie.

Stereodivergent Alkyne Hydrofluorination Using a Simple Practical Reagent

X. Qi, Ruihan Wang, Yi‐Ming Wang, 2020 .

Ligand Conformational Flexibility Enables Enantioselective Tertiary C-B Bond Formation in the Phosphonate-Directed Catalytic Asymmetric Alkene Hydroboration.

Suman Chakrabarty, Peng Liu, X. Qi, 2021, Journal of the American Chemical Society.

P-stereogenic N-vinylphosphonamides enabled by asymmetric allylic substitution-isomerization

Ying He, Peng Liu, X. Qi, 2021, Cell Reports Physical Science.

Theoretical Study of Ni-Catalyzed C-N Radical-Radical Cross-Coupling.

Y. Lan, X. Qi, Ruopeng Bai, 2019, The Journal of organic chemistry.

Theoretical study of the ligand effect on NHC–cobalt-catalyzed hydrogenation of ketones

Juan Wang, Kangbing Wu, X. Qi, 2019, Catalysis Science & Technology.

Mechanistic insight into cobalt-catalyzed stereodivergent semihydrogenation of alkynes: The story of selectivity control

Y. Lan, Qiang Liu, X. Qi, 2018, Journal of Catalysis.

Insights into disilylation and distannation: sequence influence and ligand/steric effects on Pd-catalyzed difunctionalization of carbenes.

Lei Zhu, Y. Lan, X. Qi, 2018, Dalton transactions.

Mechanism, Regio-, and Diastereoselectivity of Rh(III)-Catalyzed Cyclization Reactions of N-Arylnitrones with Alkynes: A Density Functional Theory Study.

K. Houk, Y. Lan, X. Qi, 2017, The journal of physical chemistry. A.

Mononuclear or Dinuclear? Mechanistic Study of the Zinc-Catalyzed Oxidative Coupling of Aldehydes and Acetylenes.

Y. Lan, A. Lei, X. Qi, 2017, Chemistry.

Stabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical–Radical Cross-Coupling

Lei Zhu, Y. Lan, X. Qi, 2017, Scientific Reports.

Rhodium-Catalyzed Hetero-(5 + 2) Cycloaddition of Vinylaziridines and Alkynes: A Theoretical View of the Mechanism and Chirality Transfer

Lei Zhu, Y. Lan, X. Qi, 2016 .

Mechanism of Ruthenium-Catalyzed Direct Arylation of C–H Bonds in Aromatic Amides: A Computational Study

Y. Lan, X. Qi, Chunhui Shan, 2016 .

The Mechanism of N-O Bond Cleavage in Rhodium-Catalyzed C-H Bond Functionalization of Quinoline N-oxides with Alkynes: A Computational Study.

Y. Lan, Xingwei Li, X. Qi, 2015, Chemistry.

2-Sulfonyl pyridines as tunable, cysteine-reactive electrophiles.

P. Schultz, B. Cravatt, C. Zambaldo, 2020, Journal of the American Chemical Society.

Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids.

C. Tung, Li‐Zhu Wu, Yi Luo, 2016, Chemical communications.

Site-selective amination towards tertiary aliphatic allylamines

A. Lei, X. Qi, He Sun, 2022, Nature Catalysis.

Site-Selective Allylic C-H Amination with Aliphatic Amines

Dali Yang, A. Lei, X. Qi, 2021 .

Coordination strategy-induced selective C-H amination of 8-aminoquinolines.

A. Singh, Jyhfu Lee, Hong Chen, 2017, Chemical communications.

Mechanism of Rhodium-Catalyzed C-H Functionalization: Advances in Theoretical Investigation.

Y. Lan, X. Qi, Ruopeng Bai, 2017, Accounts of chemical research.

Stereoselective Palladium-Catalyzed Base-Free Suzuki–Miyaura Cross-Coupling of Tetrasubstituted gem-Difluoroalkenes: An Experimental and Computational Study

Peng Liu, X. Qi, Q. Ma, 2021 .

Iron-Catalyzed Decarboxylative (4+1) Cycloadditions: Exploiting the Reactivity of Ambident Iron-Stabilized Intermediates.

W. Xiao, Y. Lan, X. Qi, 2016, Angewandte Chemie.

Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine

Jyhfu Lee, Jeffrey T. Miller, C. Pao, 2015, Science Advances.

Revealing the halide effect on the kinetics of the aerobic oxidation of Cu(i) to Cu(ii).

Jeffrey T. Miller, A. J. Kropf, Guanghui Zhang, 2015, Chemical communications.

Computational Investigation of the Role Played by Rhodium(V) in the Rhodium(III)-Catalyzed ortho-Bromination of Arenes.

Y. Lan, X. Qi, Ruopeng Bai, 2017, Chemistry.

C–H bond cleavage occurring on a Rh(V) intermediate: a theoretical study of Rh-catalyzed arene azidation

Y. Lan, X. Qi, Ruopeng Bai, 2018 .

Transition-metal-assisted radical/radical cross-coupling: a new strategy to the oxidative C(sp3)-H/N-H cross-coupling.

Y. Lan, A. Lei, X. Qi, 2014, Organic letters.

From N–H Nitration to Controllable Aromatic Mononitration and Dinitration—The Discovery of a Versatile and Powerful N-Nitropyrazole Nitrating Reagent

H. Cong, X. Qi, Qianghui Zhou, 2022, JACS Au.

Computational Studies on an Aminomethylation Precursor: (Xantphos)Pd(CH2NBn2)+

Y. Lan, X. Qi, Song Liu, 2016 .

Energy Decomposition Analyses Reveal the Origins of Catalyst and Nucleophile Effects on Regioselectivity in Nucleopalladation of Alkenes.

Peng Liu, X. Qi, Kami L. Hull, 2019, Journal of the American Chemical Society.

Mechanism, chemoselectivity and enantioselectivity for the rhodium-catalyzed desymmetric synthesis of hydrobenzofurans: a theoretical study

Y. Lan, X. Qi, Song Liu, 2016 .

Iridium-Catalyzed Intramolecular β-C-H Alkenylation of Ketones with Alkynes via a Hydride-Transfer Approach.

Guangbin Dong, X. Qi, Yin Xu, 2022, Journal of the American Chemical Society.

Dinuclear versus mononuclear pathways in zinc mediated nucleophilic addition: a combined experimental and DFT study.

Guanghui Zhang, Y. Lan, A. Lei, 2015, Dalton transactions.

Bimetallic zinc complex--active species in coupling of terminal alkynes with aldehydes via nucleophilic addition/Oppenauer oxidation.

Jeffrey T. Miller, A. J. Kropf, Guanghui Zhang, 2015, Chemical communications.

Cascade cyclization of alkene-tethered acylsilanes and allylic sulfones enabled by unproductive energy transfer photocatalysis

Li‐Zhu Wu, X. Qi, Chen Ye, 2022, Nature Communications.

Switchable Radical Carbonylation by Philicity Regulation.

W. Xiao, Jia‐Rong Chen, X. Qi, 2022, Journal of the American Chemical Society.

Switchable radical carbonylation by polarity-regulation

W. Xiao, Jia‐Rong Chen, X. Qi, 2021 .

C8-H bond activation vs. C2-H bond activation: from naphthyl amines to lactams.

Y. Lan, A. Lei, X. Qi, 2016, Chemical communications.

Revealing the solution structure of Pd( OAc ) 2 with halide additives

Dali Yang, H. Alhumade, A. Lei, 2021, Chinese Journal of Chemistry.

Deacylative Transformations of Ketones via Aromatization-Promoted C−C Bond Activation

Guangbin Dong, P. Liu, Peng Liu, 2019, Nature.

Reactivity for the Diels-Alder reaction of cumulenes: a distortion-interaction analysis along the reaction pathway.

Y. Lan, X. Qi, Song Liu, 2014, The journal of physical chemistry. A.

Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study

Dongdong Xu, Y. Lan, X. Qi, 2017 .

Room-Temperature Coupling/Decarboxylation Reaction of α-Oxocarboxylates with α-Bromoketones: Solvent-Controlled Regioselectivity for 1,2- and 1,3-Diketones.

Y. Lan, X. Qi, J. You, 2017, The Journal of organic chemistry.

Transition-metal-free formal decarboxylative coupling of α-oxocarboxylates with α-bromoketones under neutral conditions: a simple access to 1,3-diketones.

Y. Lan, X. Qi, Jingbo Lan, 2015, Angewandte Chemie.

Mechanism and selectivity for zinc-mediated cycloaddition of azides with alkynes: a computational study

Y. Lan, X. Qi, Y. Lei, 2015 .

Tuning radical reactivity using iodine in oxidative C(sp(3))-H/C(sp)-H cross-coupling: an easy way toward the synthesis of furans and indolizines.

Y. Lan, A. Lei, X. Qi, 2015, Chemical communications.

Catalytic Asymmetric Vinylogous and Bisvinylogous Propargylic Substitution.

X. Qi, Chaochao Yao, Chunrong Liu, 2022, Journal of the American Chemical Society.

Time-Resolved EPR Revealed the Formation, Structure, and Reactivity of N-Centered Radicals in an Electrochemical C(sp3)-H Arylation Reaction.

H. Alhumade, A. Lei, X. Qi, 2021, Journal of the American Chemical Society.

Transition-metal-free formal decarboxylative coupling of α-oxocarboxylates with α-bromoketones under neutral conditions: a simple access to 1,3-diketones.

Y. Lan, X. Qi, Jingbo Lan, 2015, Angewandte Chemie.

Readily Accessible and Highly Efficient Ferrocene-Based Amino-Phosphine-Alcohol (f-Amphol) Ligands for Iridium-Catalyzed Asymmetric Hydrogenation of Simple Ketones.

Xumu Zhang, Jianfei Yu, Y. Lan, 2017, Chemistry.

Long distance unconjugated agostic-assisted 1,5-H shift in a Ru-mediated Alder-ene type reaction: mechanism and stereoselectivity

Dongdong Xu, Y. Lan, X. Qi, 2018 .

Silver Migration Facilitates Isocyanide-Alkyne [3 + 2] Cycloaddition Reactions: Combined Experimental and Theoretical Study

Heng Zhang, Yu Lan, Lei Zhu, 2015 .

Aromatic C–H bond cleavage by using a Cu(I) ate-complex

Jeffrey T. Miller, A. J. Kropf, Guanghui Zhang, 2016 .

Electrochemical Borylation of Alkyl Halides: Fast, Scalable Access to Alkyl Boronic Esters.

X. Qi, P. Hu, Pan Peng, 2021, Journal of the American Chemical Society.

From Esters to Ketones via a Photoredox-Assisted Reductive Acyl Cross-Coupling (PARAC) Strategy.

Weirong Li, X. Qi, Hongping Zhao, 2021, Angewandte Chemie.

Palladium-catalyzed aerobic (1+2) annulation of Csp3-H bonds with olefin for the synthesis of 3-azabicyclo[3.1.0]hex-2-ene.

Zhiliang Huang, A. Lei, X. Qi, 2017, Chemical communications.

Carbon-centered radical addition to O=C of amides or esters as a route to C-O bond formations.

Dong Liu, Y. Lan, A. Lei, 2014, Chemistry.

Branched-Selective Direct α-Alkylation of Cyclic Ketones with Simple Alkenes.

Guangbin Dong, P. Liu, Peng Liu, 2019, Angewandte Chemie.

Epoxide Electroreduction.

X. Qi, Minghao Xu, Xueliang Zheng, 2021, Journal of the American Chemical Society.

Development and Mechanistic Studies of the Iridium‐Catalyzed C−H Alkenylation of Enamides with Vinyl Acetates: A Versatile Approach for Ketone Functionalization

P. Liu, Guangbin Dong, X. Qi, 2021, Angewandte Chemie.

Development and Mechanistic Studies of the Iridium-catalyzed C-H Alkenylation of Enamides with Vinyl Acetates: A Versatile Approach for Ketone Functionalization.

P. Liu, Guangbin Dong, X. Qi, 2021, Angewandte Chemie.

Tandem Iridium Catalysis as a General Strategy for Atroposelective Construction of Axially Chiral Styrenes.

Ying He, Peng Liu, X. Qi, 2021, Journal of the American Chemical Society.

Asymmetric allylic substitution–isomerization to axially chiral enamides via hydrogen-bonding assisted central-to-axial chirality transfer†

P. Liu, Ying He, Peng Liu, 2020, Chemical science.

Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates

Jyhfu Lee, Dali Yang, C. Pao, 2017, Nature Communications.

Compatibility Score for Rational Electrophile Selection in Pd/NBE Cooperative Catalysis.

Guangbin Dong, P. Liu, Peng Liu, 2020, Chem.

Visible-light-mediated decarboxylation/oxidative amidation of α-keto acids with amines under mild reaction conditions using O(2).

Y. Lan, Qiang Liu, Jie Liu, 2014, Angewandte Chemie.

Chemical Recycling of Polystyrene to Valuable Chemicals via Selective Acid-Catalyzed Aerobic Oxidation under Visible Light

E. L. Bennett, Jianliang Xiao, Adam Brookfield, 2022, Journal of the American Chemical Society.

Remote Enantioselective [4 + 1] Annulation with Copper-Vinylvinylidene Intermediates.

Hao Xu, X. Qi, Chaochao Yao, 2022, Journal of the American Chemical Society.

Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations.

Y. Lan, X. Qi, 2021, Accounts of chemical research.

Construction of Axially Chiral Biaryls via Atroposelective ortho-C–H Arylation of Aryl Iodides

Yuanda Hua, X. Qi, Qianghui Zhou, 2023, ACS Catalysis.

Stereoselective C–O silylation and stannylation of alkenyl acetates

X. Qi, Ying Hu, Xingchen Liu, 2023, Nature Communications.

Unraveling the Structure and Reactivity Patterns of the Indole Radical Cation in Regioselective Electrochemical Oxidative Annulations.

H. Cong, A. Lei, X. Qi, 2023, Journal of the American Chemical Society.

Dual-resolving of positional and geometric isomers of C=C bonds via bifunctional photocycloaddition-photoisomerization reaction system

Qiongqiong Wan, X. Qi, Jiayi Chen, 2022, Nature Communications.

Tuning the Reactivity of Radical through a Triplet Diradical Cu(II) Intermediate in Radical Oxidative Cross-Coupling

Lei Zhu, Y. Lan, A. Lei, 2015, Scientific Reports.

Site- and Stereoselective O-Alkylation of Glycosides by Rh(II)-Catalyzed Carbenoid Insertion.

Weiping Tang, I. Guzei, Peng Liu, 2019, Journal of the American Chemical Society.

Thiolate–palladium(IV) or sulfonium–palladate(0)? A theoretical study on the mechanism of palladium-catalyzed C–S bond formation reactions

Lei Zhu, Dongdong Xu, Y. Lan, 2017 .

From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3 + 2] Cycloaddition

Lei Zhu, Y. Lan, X. Qi, 2017, Scientific Reports.

Diastereoselective Transfer of Tri(di)fluoroacetylsilanes-Derived Carbenes to Alkenes.

X. Qi, Zhuanzhuan Guo, Xingxing Gong, 2022, Angewandte Chemie.

Cu(II)-Cu(I) synergistic cooperation to lead the alkyne C-H activation.

Jeffrey T. Miller, A. J. Kropf, Guanghui Zhang, 2014, Journal of the American Chemical Society.

Radical-Radical Cross-Coupling for C-S Bond Formation.

Zhiliang Huang, A. Lei, X. Qi, 2016, Organic Letters.

Reactivity of Single-Walled Carbon Nanotubes in the Diels-Alder Cycloaddition Reaction: Distortion-Interaction Analysis along the Reaction Pathway.

K. Houk, Sílvia Osuna, M. Garcia‐Borràs, 2016, Chemistry.

Revealing the reduction process of Cu(ii) by sodium bis(trimethylsilyl)amide.

Jyhfu Lee, Dali Yang, C. Pao, 2019, Faraday discussions.

Energy Decomposition Analysis Reveals the Nature of Lone Pair-π Interactions with Cationic π Systems in Catalytic Acyl Transfer Reactions.

Weiping Tang, Peng Liu, X. Qi, 2021, Organic letters.

Enantioselective Synthesis of α-All-Carbon Quaternary Center-Containing Carbazolones via Amino-palladation/Desymmetrizing Nitrile Addition Cascade.

J. Zhao, X. Qi, Hui Zhang, 2021, Journal of the American Chemical Society.

Electroreduction Enables Regioselective 1,2-Diarylation of Alkenes with Two Electrophiles.

Tao Wang, A. Lei, X. Qi, 2023, Angewandte Chemie.

Electrooxidative Activation of B-B Bond in B2cat2: Access to gem-Diborylalkanes via Paired Electrolysis.

X. Qi, Long Zou, Qingquan Lu, 2023, Angewandte Chemie.

Photoinduced Copper-Catalyzed Asymmetric C(sp3)-H Alkynylation of Cyclic Amines by Intramolecular 1,5-Hydrogen Atom Transfer.

Sijia Li, X. Qi, Yinlong Guo, 2022, Angewandte Chemie.

The mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO2: a computational study

Y. Lan, X. Qi, Ruopeng Bai, 2018 .

Cobalt-catalysed allylic fluoroalkylation of terpenes

A. Lei, X. Qi, Demin Ren, 2023, Nature Synthesis.

Radical thioesterification via nickel-catalysed sensitized electron transfer

F. Glorius, Ankita Das, X. Qi, 2023, Nature Synthesis.

Tuning radical reactivity using iodine in oxidative C(sp(3))-H/C(sp)-H cross-coupling: an easy way toward the synthesis of furans and indolizines.

Y. Lan, A. Lei, X. Qi, 2015, Chemical communications.

Visible-light-mediated decarboxylation/oxidative amidation of α-keto acids with amines under mild reaction conditions using O(2).

Y. Lan, Qiang Liu, Jie Liu, 2014, Angewandte Chemie.

Coordination strategy-induced selective C-H amination of 8-aminoquinolines.

A. Singh, Jyhfu Lee, Hong Chen, 2017, Chemical communications.

Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids.

C. Tung, Yi Luo, A. Lei, 2016, Chemical communications.

Dinuclear versus mononuclear pathways in zinc mediated nucleophilic addition: a combined experimental and DFT study.

Guanghui Zhang, Y. Lan, A. Lei, 2015, Dalton transactions.

Iron-Catalyzed Decarboxylative (4+1) Cycloadditions: Exploiting the Reactivity of Ambident Iron-Stabilized Intermediates.

W. Xiao, Y. Lan, X. Qi, 2016, Angewandte Chemie.

Computational Investigation of the Role Played by Rhodium(V) in the Rhodium(III)-Catalyzed ortho-Bromination of Arenes.

Y. Lan, X. Qi, Ruopeng Bai, 2017, Chemistry.