T. Tilley

发表

C–H Bond Activations by Monoanionic, PNP-Supported Scandium Dialkyl Complexes

Daniel S. Levine, R. Andersen, T. Tilley, 2015 .

High oxidation state rhodium and iridium bis(silyl)dihydride complexes supported by a chelating pyridyl-pyrrolide ligand.

T. Tilley, Jennifer L. McBee, J. Escalada, 2009, Journal of the American Chemical Society.

Activated Boron Nitride Derived from Activated Carbon

A. Zettl, W. Han, R. Brutchey, 2004 .

Zirconocene-coupling routes to conjugated polymers: soluble poly(arylenedienylene)s

B. Lucht, T. Tilley, 1998 .

DFT Investigation of the Catalytic Hydromethylation of α-Olefins by Metallocenes. 1. Differences between Scandium and Lutetium in Propene Hydromethylation

O. Eisenstein, L. Maron, T. Tilley, 2006 .

Alkene hydrosilation by a cationic hydrogen-substituted iridium silylene complex.

T. Tilley, E. Calimano, 2008, Journal of the American Chemical Society.

Two-Coordinate Iron(I) Complexes on the Edge of Stability: Influence of Dispersion and Steric Effects

M. Head‐Gordon, D. Hait, T. Tilley, 2021 .

Gauging aromatic conjugation and charge delocalization in the aryl silanes PhnSiH4-n (n = 0-4), with silicon K-edge XAS and TDDFT.

T. Tilley, Nicholas A. Phillips, S. Minasian, 2020, Dalton transactions.

Monomeric, Divalent Vanadium Bis(arylamido) Complexes: Linkage Isomerism and Reactivity

Daniel S. Levine, Micah S. Ziegler, T. Tilley, 2019, Organometallics.

Dicopper Alkyl Complexes: Synthesis, Structure, and Unexpected Persistence

Daniel S. Levine, Nicole A. Torquato, Micah S. Ziegler, 2018, Organometallics.

Synthesis and electronic properties of extended, fused-ring aromatic systems containing multiple pentalene units.

T. Tilley, Z. Levi, 2010, Journal of the American Chemical Society.

Epoxidation catalysts derived from introduction of titanium centers onto the surface of mesoporous aluminophosphate: Comparisons with analogous catalysts based on mesoporous silica

J. Yano, T. Tilley, L. Raboin, 2013 .

A dimeric molecular precursor [(tBuO)2Ti{μ-O2Si[OSi(OtBu)3]2}]2 to Ti(IV)/SiO2 catalysts for selective cyclohexene epoxidation

P. Yang, R. Brutchey, D. Sirbuly, 2005 .

Siloxyaluminate and Siloxygallate Complexes as Models for Framework and Partially-Hydrolyzed Framework Sites in Zeolites and Zeotypes.

Daniel S. Levine, Micah S. Ziegler, M. Head‐Gordon, 2020, Chemistry.

Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide-Alkyne Cycloaddition.

Micah S. Ziegler, T. Tilley, K. Lakshmi, 2017, Journal of the American Chemical Society.

Synthesis and Study of Cyclic π-Systems Containing Silicon and Germanium. The Question of Aromaticity in Cyclopentadienyl Analogues

A. Rheingold, T. Tilley, L. Liable-Sands, 1996 .

Synthesis and Reactivity of η5-Silolyl, η5-Germolyl, and η5-Germole Dianion Complexes of Zirconium and Hafnium

T. Tilley, Jeffrey M. Dysard and, 2000 .

Synthesis and Structure of a Free Germacyclopentadienide Ion: [Li([12]crown‐4)2][C4Me4GeSi(SiMe3)3]

A. Rheingold, T. Tilley, P. Gantzel, 1995 .

ETA 5-SILOLYL AND ETA 5-GERMOLYL COMPLEXES OF D HAFNIUM. STRUCTURAL CHARACTERIZATION OF AN ETA 5-SILOLYL COMPLEX

T. Tilley, J. Dysard, 1998 .

Synthesis and reactivity of η5-germacyclopentadienyl complexes of iron

A. Rheingold, T. Tilley, W. Freeman, 2002 .

Stable Silacyclopentadienyl Complexes of Ruthenium: (.eta.5-C5Me5)Ru[.eta.5-Me4C4SiSi(SiMe3)3] and X-ray Structure of Its Protonated Form

A. Rheingold, T. Tilley, W. Freeman, 1994 .

Silolyl Anions and Silole Dianions: Structure of [K([18]crown‐6)+]2[C4Me4Si2−]

A. Rheingold, T. Tilley, G. Yap, 1996 .

Pt-catalyzed C-C activation induced by C-H activation.

R. Bergman, T. Tilley, Miriam A. Bowring, 2013, Journal of the American Chemical Society.

Transition metal complexes of the novel hexadentate ligand 1,4-bis(di(N-methylimidazol-2-yl)methyl)phthalazine.

T. Tilley, C. Limberg, S. Roggan, 2011, Dalton transactions.

New Fe/SiO2 Materials Prepared using Diiron Molecular Precursors: Synthesis, Characterization and Catalysis

A. Bell, Guangtao Li, G. Long, 2005 .

Assembly of macrocycles by zirconocene-mediated, reversible carbon-carbon bond formation.

V. Gessner, T. Tilley, J. Tannaci, 2011, Accounts of chemical research.

Synthesis and characterization of perfluoroaryl-substituted siloles and thiophenes : A series of electron-deficient blue light emitting materials

T. Tilley, Jennifer L. McBee, Yulong Shen, 2006 .

N-heterocyclic carbene-stabilized gold nanoparticles and their assembly into 3D superlattices.

Joan Vignolle, T. Tilley, 2009, Chemical communications.

Charge-Transfer Interaction of Poly(vinylpyrrolidone) with Platinum and Rhodium Nanoparticles

G. Somorjai, Y. Borodko, T. Tilley, 2007 .

Mechanistic Aspects of Cobalt-Oxo Cubane Clusters in Oxidation Chemistry.

Andy I. Nguyen, T. Tilley, Jaruwan Amtawong, 2022, Journal of the American Chemical Society.

Stabilization of reactive Co4O4 cubane oxygen-evolution catalysts within porous frameworks

Micah S. Ziegler, Andy I. Nguyen, M. Bajdich, 2019, Proceedings of the National Academy of Sciences.

Electrocatalytic water oxidation by single site and small nuclearity clusters of cobalt

J. Swierk, T. Tilley, 2018 .

Mechanistic Investigations of Water Oxidation by a Molecular Cobalt Oxide Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive Terminal Oxo Participation.

Micah S. Ziegler, Andy I. Nguyen, Wooyul Kim, 2015, Journal of the American Chemical Society.

Significant Cooperativity Between Ruthenium and Silicon in Catalytic Transformations of an Isocyanide.

Allegra L. Liberman-Martin, T. Tilley, Mark C. Lipke, 2016, Journal of the American Chemical Society.

Title Electrochemical Study of the Energetics of the Oxygen Evolution Reaction at Nickel Iron ( Oxy ) Hydroxide Catalysts Permalink

A. Bell, J. Swierk, Lena Trotochaud, 2015 .

Electrochemical Study of the Energetics of the Oxygen Evolution Reaction at Nickel Iron (Oxy)Hydroxide Catalysts

A. Bell, J. Swierk, Lena Trotochaud, 2015 .

Influence of a "Dangling" Co(II) Ion Bound to a [MnCo3O4] Oxo Cubane.

Andy I. Nguyen, T. Tilley, David Balcells, 2018, Journal of the American Chemical Society.

Regioselective, Transition Metal-Free C-O Coupling Reactions Involving Aryne Intermediates.

T. Tilley, Yuyang Dong, Michael I. Lipschutz, 2016, Organic letters.

Isolation, observation, and computational modeling of proposed intermediates in catalytic proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4.

R. Wright, Xinzheng Yang, T. Tilley, 2012, Dalton transactions.

Photocatalytic water oxidation by very small cobalt domains on a silica surface

J. Yano, T. Tilley, Hyun S. Ahn, 2013 .

Selective Synthesis of a Series of Isostructural MII CuI Heterobimetallic Complexes Spontaneously Assembled by an Unsymmetrical Naphthyridine-Based Ligand.

T. Tilley, A. Nicolay, 2018, Chemistry.

Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf).

R. Bergman, T. Tilley, J. Curley, 2012, Dalton transactions.

Multifunctional silicon surfaces: reaction of dichlorocarbene generated from Seyferth reagent with hydrogen-terminated silicon (111) surfaces.

I. Sharp, Wenjun Liu, T. Tilley, 2014, Langmuir : the ACS journal of surfaces and colloids.

Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal RuV-Oxo with Significant Oxyl Radical Character.

Andy I. Nguyen, R. D. Britt, Jarett Wilcoxen, 2019, Journal of the American Chemical Society.

Alkyl and Hydrido Complexes of Platinum(IV) Supported by the Bis(8-quinolyl)methylsilyl Ligand

T. Tilley, P. Sangtrirutnugul, 2008 .

9,10-Dichlorooctafluoroanthracene as a building block for n-type organic semiconductors.

T. Tilley, Jennifer L. McBee, Masahiro Noji, 2007, The Journal of organic chemistry.

Manganese-Cobalt Oxido Cubanes Relevant to Manganese-Doped Water Oxidation Catalysts.

Daniel S. Levine, Micah S. Ziegler, Andy I. Nguyen, 2017, Journal of the American Chemical Society.

Water oxidation catalysis via immobilization of the dimanganese complex [Mn2(μ-O)2Cl(μ-O2CCH3)(bpy)2(H2O)](NO3)2 onto silica.

A. Bell, T. Tilley, Hyun S. Ahn, 2013, Dalton transactions.

Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand.

T. Tilley, T. Davenport, 2015, Dalton transactions.

Diiron proton reduction catalysts possessing electron-rich and electron-poor naphthalene-1,8-dithiolate ligands.

R. Wright, T. Tilley, C. Lim, 2009, Chemistry.

Olefin Hydroarylation Catalyzed by (pyridyl-indolate)Pt(II) Complexes: Catalytic Efficiencies and Mechanistic Aspects

Allegra L. Liberman-Martin, T. Tilley, Benjamin A. Suslick, 2017 .

Efficient hydrosilylation of carbonyl compounds with the simple amide catalyst [Fe{N(SiMe3)2}2].

T. Tilley, Jian Yang, 2010, Angewandte Chemie.

Radial anisotropic growth of rhodium nanoparticles.

G. Somorjai, J. Hoefelmeyer, T. Tilley, 2005, Nano letters.

Late 3d-Transition Metal Complexes Bearing a Bis-Phosphine Borane Ligand, PhB(CH2PtBu2)2

Rex C. Handford, T. Tilley, Lingfei Zhong, 2022, Organometallics.

A coordination network based on d0 transition-metal centers: synthesis and structure of the [2,4]-connected layered compound [(TiCl4)2Si(C6H4CN-p)4]·1.5C7H8

T. Tilley, F. Liu, Feng Liu, 1998 .

Versatile synthesis of pentalene derivatives via the Pd-catalyzed homocoupling of haloenynes.

T. Tilley, Z. Levi, 2009, Journal of the American Chemical Society.

Expanded Helicenes as Synthons for Chiral Macrocyclic Nanocarbons.

Janice B. Lin, K. Houk, C. Nuckolls, 2020, Journal of the American Chemical Society.

Novel Templating Effect in the Macrocyclization of Functionalized Diynes by Zirconocene Coupling.

T. Tilley, J. Nitschke, 2001, Angewandte Chemie.

Dendrimers as Building Blocks for Nanostructured Materials: Micro- and Mesoporosity in Dendrimer-Based Xerogels

T. Tilley, J. W. Kriesel, 1999 .

Unusual ruthenium hydride complexes supported by the [N(2-PPh2-4-Me-C6H3)2] pincer ligand

T. Tilley, Meg E. Fasulo, 2010 .

Versatile Fe-Sn Bonding Interactions in a Metallostannylene System: Multiple Bonding and C-H Bond Activation.

R. D. Britt, Rex C. Handford, T. Tilley, 2021, Journal of the American Chemical Society.

ALKOXY(SILOXY) COMPLEXES OF TIN, LEAD AND BISMUTH

K. Su, A. Rheingold, T. Tilley, 1998 .

Selective Catalytic Cyclohexene Oxidation Using Titanium-Functionalized Silicone Nanospheres

T. Tilley, C. Bradley, M. Mcmurdo, 2007 .

A Dicopper Nitrenoid by Oxidation of a CuICuI Core: Synthesis, Electronic Structure, and Reactivity.

Micah S. Ziegler, T. Cundari, T. Tilley, 2021, Journal of the American Chemical Society.

Efficient C–H bond activations via O2 cleavage by a dianionic cobalt(ii) complex

Andy I. Nguyen, E. Solomon, Ryan G. Hadt, 2014, Chemical science.

E ﬃ cient C – H bond activations via O 2 cleavage by a dianionic cobalt( II ) complex † Chemistry 2014

Andy I. Nguyen, Ryan G. Hadt, T. Tilley, 2022 .

Cross-conjugated polymers via condensation of a zirconocene alkynyl(benzyne) derivative generated by thermolysis of Cp2ZrMe(C6H4CCSiMe3)

T. Tilley, S. Mao, 1996 .

C-H Activation by RuCo3O4 Oxo Cubanes: Effects of Oxyl Radical Character and Metal-Metal Cooperativity.

Rex C. Handford, T. Tilley, David Balcells, 2021, Journal of the American Chemical Society.

Rhodium nanoparticles from cluster seeds: control of size and shape by precursor addition rate.

G. Somorjai, T. Tilley, S. M. Humphrey, 2007, Nano letters.

Tantalum–Polyhedral Oligosilsesquioxane Complexes as Structural Models and Functional Catalysts for Epoxidation

T. Tilley, P. Guillo, Meg E. Fasulo, 2017 .

Titanium–Germoxy Precursor Route to Germanium-Modified Epoxidation Catalysts with Enhanced Activity

R. Rioux, T. Tilley, Ji Woong Chang, 2013 .

The Influence of Surface Modification on the Epoxidation Selectivity and Mechanism of TiSBA15 and TaSBA15 Catalysts with Aqueous Hydrogen Peroxide

R. Brutchey, T. Tilley, D. Ruddy, 2008 .

Nonaqueous, Molecular Precursor Route to Hybrid Inorganic/Organic Zirconia−Silica Materials Containing Covalently Linked Organic Bridges

J. Goldberger, R. Brutchey, T. Tilley, 2003 .

Titania−Silica Materials from the Molecular Precursor Ti[OSi(OtBu)3]4: Selective Epoxidation Catalysts

T. Tilley, K. W. Terry, M. P. Coles, 2000 .

Synthesis and Reactivity of Silyl and Silylene Ligands in the Coordination Sphere of the 14-Electron Fragment Cp*(iPr3P)Os+

T. Tilley, P. Glaser, 2004 .

Multiple bonding between silicon and molybdenum: a transition-metal complex with considerable silylyne character.

T. Tilley, B. Mork, 2003, Angewandte Chemie.

Elucidation of Diverse Solid‐State Packing in a Family of Electron‐Deficient Expanded Helicenes via Microcrystal Electron Diffraction (MicroED)**

Christopher G. Jones, Julia Oktawiec, T. Tilley, 2020, Angewandte Chemie.

MicroED Elucidation of Diverse Solid-State Packing in a Family of Electron-Deficient Expanded Helicenes.

Christopher G. Jones, Julia Oktawiec, T. Tilley, 2020, Angewandte Chemie.

Expanded Helicenes: A General Synthetic Strategy and Remarkable Supramolecular and Solid-State Behavior.

Daniel S. Levine, T. Tilley, Patrick W. Smith, 2017, Journal of the American Chemical Society.

Site-Isolated Pt-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pt(II) and Pt(IV)

K. A. Tupper, Jeffrey T. Miller, R. Rioux, 2008 .

Organometallics Roundtable 2013–2014

Patrick L. Holland, C. E. Webster, Connie C. Lu, 2014 .

Highly Dispersed Pd-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pd(II)

Eric G. Moschetta, Jeffrey T. Miller, R. Rioux, 2011 .

2,7-Substituted hexafluoroheterofluorenes as potential building blocks for electron transporting materials.

T. Tilley, Jennifer L. McBee, K. Geramita, 2009, The Journal of organic chemistry.

A sequential cyclization/π-extension strategy for modular construction of nanographenes enabled by stannole cycloadditions

Rex C. Handford, T. Tilley, D. Beattie, 2022, Chemical science.

Spectroscopic characterization of highly dispersed vanadiasupported on SBA-15

C. Hess, J. Hoefelmeyer, T. Tilley, 2003 .

Synthesis and Characterization of MO[OSi(OtBu)3]4 and MO2[OSi(OtBu)3]2 (M = Mo, W): Models for Isolated Oxo-Molybdenum and -Tungsten Sites on Silica and Precursors to Molybdena− and Tungsta−Silica Materials

T. Tilley, M. P. Coles, J. Jarupatrakorn, 2005 .

A hydrogen-substituted osmium stannylene complex: isomerization to a metallostannylene complex via an unusual alpha-hydrogen migration from tin to osmium.

Paul G. Hayes, Christopher W. Gribble, T. Tilley, 2009, Journal of the American Chemical Society.

Aryl Group Transfer from Tetraarylborato Anions to an Electrophilic Dicopper(I) Center and Mixed-Valence μ-Aryl Dicopper(I,II) Complexes.

Daniel S. Levine, Micah S. Ziegler, T. Tilley, 2016, Journal of the American Chemical Society.

A two-coordinate Ni(i) silyl complex: CO2 insertion and oxidatively-induced silyl migrations.

T. Tilley, Ryan J. Witzke, 2019, Chemical communications.

Ga[OSi(O(t)Bu)3]3·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry.

A. Bell, T. Tilley, Gregory R. Johnson, 2016, Dalton transactions.

Dimethyl carbonate production via the oxidative carbonylation of methanol over Cu/SiO2 catalysts prepared via molecular precursor grafting and chemical vapor deposition approaches

A. Bell, T. Tilley, Kyle L. Fujdala, 2005 .

Activations of all Bonds to Silicon (Si-H, Si-C) in a Silane with Extrusion of [CoSiCo] Silicide Cores.

Rex C. Handford, T. Tilley, Patrick W. Smith, 2019, Journal of the American Chemical Society.

Water Oxidation by Cobalt Centers on Various Oxide Surfaces: The Effects of Oxide Surface Acidity and Oxygen Atom Affinity on Catalysis

J. Yano, T. Tilley, Hyun S. Ahn, 2015 .

Molecular and polymer precursor routes to manganese-doped zinc orthosilicate phosphors

K. Su, M. Sailor, T. Tilley, 1996 .

General Route to Homogeneous, Mesoporous, Multicomponent Oxides Based on the Thermolytic Transformation of Molecular Precursors in Non‐polar Media

M. Sander, T. Tilley, J. W. Kriesel, 2001 .

Tris(tert-butoxy)siloxy Complexes as Single-Source Precursors to Homogeneous Zirconia- and Hafnia-Silica Materials. An Alternative to the Sol-Gel Method

T. Tilley, K. W. Terry, Andreas Lugmair, 1997 .

Zirconacyclopentadiene-Annulated Polycyclic Aromatic Hydrocarbons.

Micah S. Ziegler, T. Tilley, G. Kiel, 2017, Angewandte Chemie.

Synthesis and Reactivity of a Dimeric Ni(I) Methyl Complex

T. Tilley, Ryan J. Witzke, 2022, Organometallics.

Multiple Si–H Bond Activations by tBu2PCH2CH2PtBu2 and tBu2PCH2PtBu2 Di(phosphine) Complexes of Rhodium and Iridium

T. Tilley, E. Calimano, J. M. Buchanan, 2013 .

Block Copolymer-Assisted Synthesis of Mesoporous, Multicomponent Oxides by Nonhydrolytic, Thermolytic Decomposition of Molecular Precursors in Nonpolar Media

M. Sander, T. Tilley, J. W. Kriesel, 2001 .

Low-temperature pyrolytic transformations of tri-tert-butoxysiloxy derivatives of aluminum to aluminosilicate materials

T. Tilley, K. W. Terry, Peter Ganzel, 1992 .

Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst.

A. Bell, R. Brutchey, T. Tilley, 2005, Chemical communications.

Bimetallics in a Nutshell: Complexes Supported by Chelating Naphthyridine-Based Ligands.

Micah S. Ziegler, T. Tilley, A. Nicolay, 2020, Accounts of chemical research.

Synthesis, characterization, and catalytic performance of single-site iron(III) centers on the surface of SBA-15 silica.

A. Bell, T. Tilley, C. Nozaki, 2002, Journal of the American Chemical Society.

Robust dicopper(I) µ-boryl complexes supported by a dinucleating naphthyridine-based ligand

S. Teat, Rex C. Handford, T. Tilley, 2022 .

Convenient, zirconocene-coupling routes to germole- and thiophene-containing macrocycles with triangular geometries

T. Tilley, J. Nitschke, 2003 .

New tris(tert-butoxy)siloxy complexes of aluminum and their transformation to homogeneous aluminosilicate materials via low-temperature thermolytic pathways

T. Tilley, C. G. Lugmair, K. Fujdala, 2002 .

Site-selective [2 + 2 + n] cycloadditions for rapid, scalable access to alkynylated polycyclic aromatic hydrocarbons†

T. Tilley, Harrison M. Bergman, G. Kiel, 2019, Chemical science.

Structure and Bonding in a Diamond-Shaped Tin Cluster Possessing a cyclo-Sn4 Core.

Rex C. Handford, T. Tilley, T. Wheeler, 2020, Chemistry.

A structurally rigid bis(amido) ligand framework in low-coordinate Ni(I), Ni(II), and Ni(III) analogues provides access to a Ni(III) methyl complex via oxidative addition.

Xinzheng Yang, T. Tilley, R. Chatterjee, 2013, Journal of the American Chemical Society.

Early-Transition-Metal Complexes of Functionalized Nonagermanide Clusters: Synthesis and Characterization of [Cp2(MeCN)Ti(η1-Ge9{Si(TMS)3}3)] and K3[Cp2Ti(η1-Ge9{Si(TMS)3}2)2].

T. Fässler, T. Tilley, W. Klein, 2019, Inorganic chemistry.

Mechanistic Interrogation of Alkyne Hydroarylations Catalyzed by Highly Reduced, Single-Component Cobalt Complexes.

T. Tilley, Benjamin A. Suslick, T. D. Tilley, 2020, Journal of the American Chemical Society.

Unsymmetrical Naphthyridine-Based Dicopper(I) Complexes: Synthesis, Stability, and Carbon–Hydrogen Bond Activations

Micah S. Ziegler, T. Tilley, David Balcells, 2021 .

A Zirconocene-Coupling Route to Substituted Poly(p-phenylenedienylene)s: Band Gap Tuning via Conformational Control

B. Lucht, T. Tilley, and Shane S. H. Mao, 1998 .

Platinum-based catalysts for the hydroamination of olefins with sulfonamides and weakly basic anilines.

A. Bell, T. Tilley, Dmitry Karshtedt, 2005, Journal of the American Chemical Society.

Oxidative Dehydrogenation of Propane over Vanadia–Magnesia Catalysts Prepared by Thermolysis of OV(OtBu)3 in the Presence of Nanocrystalline MgO

Alexis T. Bell, Chanho Pak, A. Bell, 2002 .

Effects of additives on the activity and selectivity of supported vanadia catalysts for the oxidative dehydrogenation of propane

A. Bell, H. Dai, T. Tilley, 2004 .

A Molecular Precursor Route to Active and Selective Vanadia−Silica−Zirconia Heterogeneous Catalysts for the Oxidative Dehydrogenation of Propane

T. Tilley, R. Rulkens, 1998 .

Efficient and selective catalysis for hydrogenation and hydrosilation of alkenes and alkynes with PNP complexes of scandium and yttrium.

Daniel S. Levine, R. Andersen, T. Tilley, 2017, Chemical communications.

Bimetallic Mechanism for Alkyne Cyclotrimerization with a Two-Coordinate Fe Precatalyst

M. Head‐Gordon, D. Hait, T. Tilley, 2020, ACS Catalysis.

The osmium-silicon triple bond: synthesis, characterization, and reactivity of an osmium silylyne complex.

Paul G. Hayes, J. Keith, M. Hall, 2013, Journal of the American Chemical Society.

Expanded [23]-Helicene with Exceptional Chiroptical Properties via an Iterative Ring-Fusion Strategy.

C. Nuckolls, August J. Rothenberger, Rex C. Handford, 2022, Journal of the American Chemical Society.

Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex

Micah S. Ziegler, David W. Small, M. Scheer, 2019, Chemical science.

Shape-Selective Synthesis of Pentacene Macrocycles and the Effect of Geometry on Singlet Fission.

A. Schwartzberg, T. Tilley, Yi Liu, 2020, Journal of the American Chemical Society.

Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex.

T. Tilley, Michael I. Lipschutz, 2012, Chemical communications.

Atomic level control over surface species via a molecular precursor approach: isolated Cu(I) sites and Cu nanoparticles supported on mesoporous silica.

A. Bell, T. Tilley, Ian Drake, 2004, Journal of the American Chemical Society.

Synthesis and characterization of [(diene)Rh[mu-OSi(OtBu)3]]2, a precursor to silica-bound rhodium.

T. Tilley, J. Jarupatrakorn, 2004, Dalton transactions.

An efficient, single-source molecular precursor to silicoaluminophosphates.

T. Tilley, Kyle L. Fujdala, K. Fujdala, 2001, Journal of the American Chemical Society.

Highly selective olefin epoxidation with aqueous H2O2 over surface-modified TaSBA15 prepared via the TMP method.

Daniel A. Ruddy, T. Tilley, D. Ruddy, 2007, Chemical communications.

Preparation and crystal structure of µ-carbonyl-OC-bis(pentamethylcyclopentadienyl)(tetrahydrofuran)ytterbium(III)tricarbonylcobalt(I); A Yb–OC–Co linkage

R. Andersen, T. Tilley, 1981 .

Zirconium amide, halide, and alkyl complexes supported by tripodal amido ligands derived from cis, cis-1,3,5-triaminocyclohexane

T. Tilley, Laura Turculet, 2002 .

Reactions of Zirconacyclopentadienes with Nitrosobenzene. Characterization of Zirconacycle Intermediates and Formation of N-Phenylpyrroles

M. Nakamoto, T. Tilley, 2001 .

9,10-Disubstituted octafluoroanthracene derivatives via palladium-catalyzed cross-coupling.

T. Tilley, Jennifer L. McBee, Masahiro Noji, 2008, The Journal of organic chemistry.

Synthesis, structures, and reactivity studies of cyclometalated N-heterocyclic carbene complexes of ruthenium.

Micah S. Ziegler, T. Tilley, Hsueh‐Ju Liu, 2018, Dalton transactions.

Ring-opening and double-metallation reactions of the N-Heterocyclic carbene ligand in Cp∗(IXy)Ru (IXy = 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene) complexes. Access to an anionic fischer-type carbene complex of ruthenium

Micah S. Ziegler, T. Tilley, Hsueh‐Ju Liu, 2014 .

Synthesis, characterization, and alkyne trimerization catalysis of a heteroleptic two-coordinate fe(i) complex.

T. Tilley, Teera Chantarojsiri, Yuyang Dong, 2015, Journal of the American Chemical Society.

Functionalization of an iridium–diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources

Allegra L. Liberman-Martin, Micah S. Ziegler, R. Bergman, 2016 .

Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.

Allegra L. Liberman-Martin, T. Tilley, Mark C. Lipke, 2017, Angewandte Chemie.

Cyclometalated N-heterocyclic carbene complexes of ruthenium for access to electron-rich silylene complexes that bind the Lewis acids CuOTf and AgOTf.

O. Eisenstein, C. Raynaud, T. Tilley, 2014, Journal of the American Chemical Society.

Carbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediates.

T. Tilley, Michael I. Lipschutz, T. D. Tilley, 2014, Angewandte Chemie.

Hydroarylation of Olefins with Complexes Bearing d8 Metal Centers

T. Tilley, Benjamin A. Suslick, 2017 .

Thermolytic molecular precursor route to site-isolated vanadia–silica materials and their catalytic performance in methane selective oxidation

Alexis T. Bell, Daniel A. Ruddy, A. Bell, 2006 .

Comparison of cobalt-based nanoparticles as electrocatalysts for water oxidation.

Alexis T Bell, A. Bell, P. Ross, 2011, ChemSusChem.

Divalent lanthanide chemistry. Bis (pentamethylcyclopentadienyl) europium(II) and -ytterbium(II) derivatives: crystal structure of bis (pentamethylcyclopentadienyl) (tetrahydrofuran ytterbium(II) -hemitoluene at 176 K

R. Andersen, T. Tilley, D. H. Templeton, 1980 .

Mechanistic aspects of samarium-mediated sigma-bond activations of arene C-H and arylsilane Si-C bonds.

T. Tilley, I. Castillo, 2001, Journal of the American Chemical Society.

Neutral lanthanide silyl complexes via σ-bond metathesis reactions

A. Rheingold, T. Tilley, N. S. Radu, 1996 .

Samarium-mediated redistribution of silanes and formation of trinuclear samarium–silicon clusters

A. Rheingold, T. Tilley, F. Hollander, 1996 .

Metal-Catalyzed Dehydropolymerization of Secondary Stannanes to High Molecular Weight Polystannanes

T. Tilley, T. Imori, Hui Cai, 1995 .

AUTOCATALYTIC MECHANISM FOR SIGMA -BOND METATHESIS REACTIONS OF (ETA 5-C5ME5)2SMCH(SIME3)2 WITH SILICON-HYDROGEN BONDS

T. Tilley, N. S. Radu, N. Radu, 1995 .

Isolation of the First d0 Metalloxy Ketene Complexes via "Double Insertion" of Carbon Monoxide into Thorium-Silicon Bonds

A. Rheingold, T. Tilley, Christopher P. Gerlach, 1995 .

Synthesis and reactions of silyl and germyl derivatives of scandocene. Structure of Cp2Sc[Si(SiMe3)3](THF)

R. Heyn, T. Tilley, B. Campion, 1993 .

CRYSTAL STRUCTURE OF BIS(PENTAMETHYLCYCLOPENTADIENYL)BIS(PYRIDINE)YTTERBIUM(II)

R. Andersen, T. Tilley, A. Zalkin, 1982 .

Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates†

O. Eisenstein, E. Clot, C. Raynaud, 2020, Chemical science.

Synthesis of chelating, C2-symmetric bis(silylamido) complexes of zirconium, and their activities as olefin polymerization catalysts

T. Tilley, Tomislav I. Gountchev, 2003 .

Useful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe3)(2,6-iPr2-C6H3)]2}

T. Tilley, Michael I. Lipschutz, 2014, Organometallics.

Synthesis and characterization of scandium complexes with reduced ligands: Crystal structures of Cp∗ScI2, [Cp∗ScI(bpy)]2, and [Cp∗ScCl(bpy)]2

K. A. Tupper, T. Tilley, 2005 .

Trityl tetraphenylborate as a reagent in organometallic chemistry

D. Straus, T. Tilley, Cheng Zhang, 1989 .

Dimesitylsilyl derivatives of zirconium

D. Roddick, R. Heyn, T. Tilley, 1989 .

Hafnium imido complexes containing silyl ligands

T. Tilley, I. Castillo, 2002 .

Neutral and anionic silyl hydride derivatives of the tantalum imido fragment Cp*(DippN=)Ta (Cp* = η5-C5Me5; Dipp = 2,6-iPr2C6H3). Reactive σ-bonds and intramolecular C-H bond activations involving the silyl ligands

T. Tilley, Urs. Burckhardt, Gary L. Casty, 2002 .

Perfluoropentaphenylborole: a new approach to Lewis acidic, electron-deficient compounds.

Joan Vignolle, T. Tilley, K. Huynh, 2009, Angewandte Chemie.

Zirconocene “Molecular Zippers”: Implements for Construction of Well-defined Polymers and Macrocycles

T. Tilley, S. Mao, 1999 .

Synthesis, characterization and reactivity of tetramethylphospholyl complexes of scandium

K. A. Tupper, Frédéric-Georges Fontaine, T. Tilley, 2006 .

Synthetic development and chemical reactivity of transition-metal silylene complexes.

Paul G. Hayes, T. Tilley, R. Waterman, 2007, Accounts of chemical research.

Hydrosilylation Catalysis by C2-Symmetric Bis(silylamido) Complexes of Yttrium

T. Tilley, Tomislav I. Gountchev and, 1999 .

Control of Selectivity in the Hydromethylation of Olefins via Ligand Modification in Scandocene Catalysts

Frédéric-Georges Fontaine, T. Tilley, 2005 .

Homogeneous catalysis with methane. A strategy for the hydromethylation of olefins based on the nondegenerate exchange of alkyl groups and sigma-bond metathesis at scandium.

A. Sadow, T. Tilley, 2003, Journal of the American Chemical Society.

Stoichiometric and Catalytic Arene Activations by Platinum Complexes Containing Bidentate Monoanionic Nitrogen-Based Ligands

A. Bell, T. Tilley, Jennifer L. McBee, 2006 .

Element–Hydrogen Bond Activations at Cationic Platinum Centers To Produce Silylene, Germylene, Stannylene, and Stibido Complexes

Rex C. Handford, T. Tilley, R. Waterman, 2019, Organometallics.

Biaryl Reductive Elimination Is Dramatically Accelerated by Remote Lewis Acid Binding to a 2,2′-Bipyrimidyl–Platinum Complex: Evidence for a Bidentate Ligand Dissociation Mechanism

Daniel S. Levine, Allegra L. Liberman-Martin, Wenjun Liu, 2016 .

Bis(triisopropylsilyl)-o-phenylenediamido Complexes of Titanium and Zirconium: Investigation of a New Ancillary Ligand

T. Tilley, P. Gantzel, Koichiro Aoyagi and, 1996 .

Synthesis, Characterization, and Reactivity of Low-Coordinate Titanium(III) Amido Complexes

T. Tilley, Ryan J. Witzke, Irene C. Cai, 2022, Organometallics.

Iridium-catalyzed H/D exchange into organic compounds in water.

R. Bergman, T. Tilley, S. R. Klei, 2002, Journal of the American Chemical Society.

Tricoordinate Organochromium(III) Complexes Supported by a Bulky Silylamido Ligand Produce Ultra-High-Molecular Weight Polyethylene in the Absence of Activators

Micah S. Ziegler, A. Fedorov, C. Copéret, 2016 .

A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states.

T. Tilley, Irene C. Cai, Michael I. Lipschutz, 2014, Chemical communications.

Synthesis and Reactivity of d0 Bis(imido) Silyl and Germyl Complexes of Molybdenum and Tungsten

A. Rheingold, T. Tilley, Gary L. Casty and, 1997 .

Zirconocene-mediated, high-yielding macrocyclizations of silyl-terminated diynes.

T. Tilley, L. Schafer, J. Nitschke, 2002, Chemistry.

Titanocene-Mediated Dinitrile Coupling: A Divergent Route to Nitrogen-Containing Polycyclic Aromatic Hydrocarbons.

T. Tilley, Ryan J. Witzke, A. Nicolay, 2018, Journal of the American Chemical Society.

Evidence for the Existence of Group 3 Terminal Methylidene Complexes

Daniel S. Levine, R. Andersen, T. Tilley, 2017 .

The influence of Michael Lappert on the chemistry landscape.

Christine M. Thomas, W. Piers, T. Tilley, 2014, Dalton transactions.

Synthesis of Highly Charged Organometallic Dendrimers and Their Characterization by Electrospray Mass Spectrometry and Single-Crystal X-ray Diffraction

Michael A. Freitas, A. Marshall, T. Tilley, 1998 .

Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound.

Allegra L. Liberman-Martin, R. Bergman, T. Tilley, 2015, Journal of the American Chemical Society.

Enhancement of epoxidation efficiencies for Ta-SBA15 catalysts. The influence of modification with -EMe3 (E = Si, Ge, Sn) groups.

T. Tilley, P. Cordeiro, T. Don Tilley, 2011, Langmuir : the ACS journal of surfaces and colloids.

Chapter 9. Transition-metal silyl derivatives

James W. White, T. Kendrick, T. Tilley, 2010 .

Transition‐metal silyl derivatives

T. Tilley, 2004 .

Tantalum Alkyl and Silyl Complexes of the Bulky (Terphenyl)imido Ligand [2,6-(2,4,6-Me3C6H2)2C6H3N]2- ([Ar*N]2-). Generation and Reactivity of [(Ar*N)(Ar*NH)Ta(H)(OSO2CF3)], Which Reversibly Transfers Hydride to an Aromatic Ring of the Arylamide Ligand

T. Tilley, John Gavenonis and, 2002 .

Reversible intramolecular hydride transfer between tantalum and an aromatic ring: an eta(5)-cyclohexadienyl complex as a masked hydride.

T. Tilley, John Gavenonis, 2002, Journal of the American Chemical Society.

Tantalum-Mediated Substitution at Germanium: A Germolyl-to-Germole Transformation Leading to η4-C4Me4GeMeCl Complexes

T. Tilley, J. Dysard, 2000 .

Ditantalum Hydride Complexes with Bridging (2,6-iPr2C6H3)NSiHPh Silanimine Ligands Resulting from PhSiH3-Imido Ligand Coupling. A Combined Spectroscopic and Theoretical Investigation

U. Rothlisberger, T. Woo, T. Tilley, 2000 .

Carbonylation Chemistry of the Tantalum Silyl Hydride Cp*(2,6-iPr2C6H3N)Ta[Si(SiMe3)3]H: The Unexpected Formation of a Ta(V) Carbonyl Complex and the Complete Reduction of CO

T. Tilley, Urs. Burckhardt, 1999 .

Structure and Reactivity of Chelating Imido−Amido Complexes of Tantalum. Mechanistic Studies on the Addition of Silanes to Ta−N Multiple Bonds

T. Tilley, Tomislav I. Gountchev and, 1997 .

Bis(triisopropylsilyl)-o-phenylenediamido complexes of tantalum. X-ray structure of (η5-C5Me5)[o-C6H4(NSiPri3)2]TaCl2

T. Tilley, K. Aoyagi, P. Gantzel, 1996 .

Mechanistic studies of the hydroamination of norbornene with electrophilic platinum complexes: the role of proton transfer.

A. Bell, T. Tilley, Jennifer L. McBee, 2008, Journal of the American Chemical Society.

A molecular structural analog of proposed dinuclear active sites in cobalt-based water oxidation catalysts.

Micah S. Ziegler, T. Tilley, Hyun S. Ahn, 2014, Chemical communications.

Low-valent iron and cobalt complexes supported by a rigid xanthene-based disilylamido ligand

Micah S. Ziegler, T. Tilley, A. Nicolay, 2020 .

Dinucleating naphthyridine-based ligand for assembly of bridged dicopper(I) centers: three-center two-electron bonding involving an acetonitrile donor.

T. Tilley, T. Davenport, 2011, Angewandte Chemie.

Identification of Second Shell Coordination in Transition Metal Species Using Theoretical XANES: Example of Ti-O-(C, Si, Ge) Complexes.

M. Janik, R. Rioux, T. Tilley, 2017, The journal of physical chemistry. A.

Pentamethylcyclopentadienyl derivatives of the trivalent lanthanide elements neodymium, samarium, and ytterbium

R. Andersen, T. Tilley, 1981 .

Computational Characterization of Redox Non-Innocence in Cobalt-Bis(Diaryldithiolene)-Catalyzed Proton Reduction.

M. Head‐Gordon, J. Panetier, T. Tilley, 2016, Journal of chemical theory and computation.

Tris(trimethylsilyl)silyl derivatives of tri-tert-butoxyzirconium and tri-tert-butoxyhafnium. X-ray crystal structure of (Me3CO)3ZrSi(SiMe3)3

R. Heyn, T. Tilley, 1989 .

Trimethylsilyl derivatives of bis(cyclopentadienyl)zirconium and -hafnium. Crystal structure of (.eta.5-C5H5)2Zr(SiMe3)(S2CNEt2)

T. Tilley, 1985 .

Activation of Arene C−H Bonds by a Cationic Hafnium Silyl Complex Possessing an α-Agostic Si−H Interaction

A. Sadow, T. Tilley, 2002 .

Synthesis and characterization of scandium silyl complexes of the type Cp*2ScSiHRR'. sigma-Bond metathesis reactions and catalytic dehydrogenative silation of hydrocarbons.

A. Sadow, T. Tilley, 2005, Journal of the American Chemical Society.

Organolutetium Complexes in σ-Bond Metathesis Reactions Involving Silicon. Catalysts for the Hydrogenolysis of Si−C Bonds

T. Tilley, I. Castillo, 2001 .

Coordination of 2,2'-bipyridyl and 1,10-phenanthroline to substituted ytterbocenes: An experimental investigation of spin coupling in lanthanide complexes

J. Boncella, R. Andersen, T. Tilley, 2002 .

Silylene Complexes of Late 3d Transition Metals Supported by tris-Phosphinoborate Ligands

Rex C. Handford, T. Tilley, Patrick W. Smith, 2018, Organometallics.

Bond Activations of PhSiH3 by Cp2SmH: A Mechanistic Investigation by the DFT Method

O. Eisenstein, L. Maron, L. Perrin, 2009 .

Silyl Derivatives of [Bis(8-quinolyl)methylsilyl]iridium(III) Complexes: Catalytic Redistribution of Arylsilanes and Dehydrogenative Arene Silylation

T. Tilley, Preeyanuch Sangtrirutnugul and, 2007 .

Iridium(III) complexes of the new tridentate bis(8-quinolyl)silyl (‘NSiN’) ligand

T. Tilley, M. Stradiotto, K. Fujdala, 2001 .

Preparation and reaction chemistry of trimethylsilyl derivatives of niobium. Redox chemistry of (.eta.5-C5H5)2Nb(SiMe3)Cl and x-ray structures of (.eta.5-C5H5)2Nb(SiMe3)(.eta.2-C2H4) and [(.eta.5-C5H5)2Nb(CH2SiMe3)Cl]PF6

S. Geib, A. Rheingold, T. Tilley, 1987 .

A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex.

Allegra L. Liberman-Martin, R. Bergman, T. Tilley, 2013, Journal of the American Chemical Society.

Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center

T. Tilley, Patrick W. Smith, Yuyang Dong, 2020, Chemical science.

Preparation and characterization of the monomeric copper(II) siloxide complex Cu[OSi(OCMe3)3]2(py)2

S. Geib, A. Rheingold, T. Tilley, 1989 .

POLY(FERROCENYLENEVINYLENE) FROM RING-OPENING METATHESIS POLYMERIZATION OFANSA-(VINYLENE)FERROCENE

T. Tilley, Mihai A. Buretea and, 1997 .

Five-Coordinate Dihydridosilyl Platinum(IV) Complexes Supported by a Chelating Monoanionic Nitrogen-Based Ligand

T. Tilley, Jennifer L. McBee, 2009 .

Enhanced Reactivity of Cationic Hafnocene Complexes toward σ-Bond Metathesis Reactions. Si−H and Si−C Bond Activations in Stoichiometric and Catalytic Organosilane Conversions

A. Sadow, T. Tilley, 2003 .

Cationic hafnium silyl complexes and their enhanced reactivity in sigma-bond metathesis processes with Si-H and C-H bonds.

A. Sadow, T. Tilley, 2003, Journal of the American Chemical Society.

Nickel Complexes with Bis(8-quinolyl)silyl Ligands. An Unusual Ni3Si2 Cluster Containing Six-Coordinate Silicon†

L. Maron, I. Rosal, T. Tilley, 2010 .

Reversible Cycloaddition of Isocyanates to Ruthenium Silylene Complexes

T. Tilley, Gregory P. Mitchell and, 1997 .

TERPHENYL LIGANDS AND COMPLEXES

Joshua S. Figueroa, Brandon R. Barnett, P. Power, 2018, Inorganic Syntheses.

Silane-isocyanide coupling involving 1,1-insertion of XylNC into the Si-H bond of a σ-silane ligand.

T. Tilley, Mark C. Lipke, 2013, Journal of the American Chemical Society.

Selective homo- and heterodehydrocouplings of phosphines catalyzed by rhodium phosphido complexes.

T. Tilley, Li‐Biao Han, 2006, Journal of the American Chemical Society.

Vanadyl tert-Butoxy Orthosilicate, OV[OSi(OtBu)3]3: A Model for Isolated Vanadyl Sites on Silica and a Precursor to Vanadia−Silica Xerogels†

Alexis T. Bell, Jonathan L. Male, Enrique Iglesia, 1999 .

Layered Zincophosphate Materials Prepared from a Molecular Zinc Di(tert-butyl)phosphate Complex in Organic Solvents

T. Tilley, C. G. Lugmair, 1998 .

Molecular Routes to Metal Oxides and Metal Silicates. Synthesis and Thermal Decomposition Studies of Eclipsed Mo2[O2Si(OtBu)2]3 and W2(NHMe2)2[O2Si(OtBu)2]2[OSi(OH)(OtBu)2]2

K. Su, T. Tilley, 1997 .

Zinc di(tert-butyl)phosphate complexes as precursors to zinc phosphates. Manipulation of zincophosphate structures

A. Rheingold, T. Tilley, C. G. Lugmair, 1997 .

Concerted Proton-Electron Transfer Reactivity at a Multimetallic Co4O4 Cubane Cluster.

T. Tilley, David Balcells, Jaruwan Amtawong, 2020, Inorganic chemistry.

Oxygen-atom transfer chemistry and thermolytic properties of a di-tert-butylphosphate-ligated Mn4O4 cubane.

W. Drisdell, J. Yano, T. Tilley, 2015, Chemistry.

Electrocatalytic Water Oxidation at Neutral pH by a Nanostructured Co(PO3)2 Anode

T. Tilley, T. Don Tilley, Hyun S. Ahn, 2013 .

Di-tert-butyl Phosphate Complexes of Titanium

T. Tilley, C. G. Lugmair, 1998 .

Iridium(III) and Rhodium(III) Complexes Bearing Chelating Cyclopentadienyl−Phosphine Ligands as C−H Activation Catalysts for the Deuteration of Hydrocarbons in D2O

R. Bergman, T. Tilley, S. R. Klei, 2002 .

Synthesis and Reactivity of d0 Alkyl, Silyl, and Hydride Complexes of Titanium and Zirconium Featuring an Aryl-Substituted Tripodal Triamido Ligand Derived from cis,cis-1,3,5-Triaminocyclohexane

T. Tilley, Laura Turculet, 2004 .

Coordination chemistry and reactivity of new zwitterionic rhodium and iridium complexes featuring the tripodal phosphine ligand [PhB(CH2PiPr2)3]-. Activation of H-H, Si-H, and ligand B-C bonds

T. Tilley, Laura Turculet, Jay D. Feldman, 2004 .

The mechanism of silicon-hydrogen and carbon-hydrogen bond activation by iridium(III): Production of a silylene complex and the first direct observation of Ir(III)/Ir(V) C-H bond oxidative addition and reductive elimination

R. Bergman, T. Tilley, S. R. Klei, 2000 .

Pt-Ag Catalyst System for Hydroarylations with Unactivated Arenes and Olefins

A. Bell, T. Tilley, Dmitry Karshtedt, 2004 .

Yttrium Complexes of the Chelating, C2-Symmetric, Bis(silylamido)biphenyl Ligand [DADMB]2- (={[6,6‘-Me2-(C6H3)2](2,2‘-NSiMe2tBu)2}2-)

T. Tilley, Tomislav I. Gountchev and, 1999 .

Catalytic hydrosilylation of alkenes by a ruthenium silylene complex. Evidence for a new hydrosilylation mechanism.

T. Tilley, P. Glaser, T. Tilley, 2003, Journal of the American Chemical Society.

Synthesis and Reactivity of Alkyl, Hydride, and Silyl Derivatives of the (Terphenyl)imido Fragments Cp*(ArMesN)Ta (Cp* = η5-C5Me5; ArMes = 2,6-(2,4,6-Me3C6H2)2C6H3) and Cp*(ArTripN)Ta (ArTrip = 2,6-(2,4,6-iPr3C6H2)2C6H3)

T. Tilley, John Gavenonis, 2004 .

Synthesis and study of platinum silylene complexes of the type (R3P)2Pt=SiMes2 (Mes = 2,4,6-trimethylphenyl)

T. Tilley, G. Mitchell, Jay D. Feldman, 2003 .

Isolation and Characterization of Neutral Platinum Silylene Complexes of the Type (R3P)2PtSiMes2 (Mes = 2,4,6-Trimethylphenyl)

T. Tilley, G. Mitchell, Jay D. Feldman, 1998 .

A Fischer-type silylene complex of platinum : [trans-(Cy3P)2(H)Pt=Si(SEt)2]BPh4

A. Rheingold, T. Tilley, F. P. Arnold, 1993 .

Platinum-mediated reactions of hydrosilanes. Isolation of a complex with bridging disilene and silylene ligands

R. Heyn, T. Tilley, 1992 .

Hypercoordinate ketone adducts of electrophilic η3-H2SiRR' ligands on ruthenium as key intermediates for efficient and robust catalytic hydrosilation.

T. Tilley, Mark C. Lipke, T. Tilley, 2014, Journal of the American Chemical Society.

Rhodium(III) and Rhodium(II) Complexes of Novel Bis(oxazoline) Pincer Ligands

T. Tilley, M. Gerisch, J. Krumper, 2003 .

Antimony-antimony bond formation by reductive elimination from a hafnium bis(stibido) complex.

T. Tilley, R. Waterman, 2006, Inorganic chemistry.

Catalytic antimony-antimony bond formation through stibinidene elimination from zirconocene and hafnocene complexes.

T. Tilley, R. Waterman, 2006, Angewandte Chemie.

Mechanism of reversible alkyne coupling at zirconocene: ancillary ligand effects.

T. Tilley, Jennifer L. McBee, Adam D. Miller, 2008, Journal of the American Chemical Society.

Lanthanide–tungsten heterobimetallic complexes viaσ-bond metathesis

T. Tilley, P. Gantzel, N. S. Radu, 1994 .

Insertions of nitriles and pyridine into the ZrSi bond of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]Me

T. Tilley, H. Woo, 1990 .

Octa- and Nonamethylfluorenyl Complexes of Zirconium(IV): Reactive Hydride Derivatives and Reversible Hydrogen Migration between the Metal and the Fluorenyl Ligand

T. Tilley, P. Bazinet, 2009 .

Mesityl alkyne substituents for control of regiochemistry and reversibility in zirconocene couplings: new synthetic strategies for unsymmetrical zirconacyclopentadienes and conjugated polymers.

Samuel A. Johnson, T. Tilley, Jennifer L. McBee, 2009, Journal of the American Chemical Society.

Octa- and Nonamethylfluorenyl Complexes of Zr(II), Zr(IV), and Hf(IV). Investigation of Steric and Electronic Effects

T. Tilley, P. Bazinet, 2008 .

Efficient, Zirconocene-Mediated Cyclotrimerization and Cyclotetramerization of Me3SiC.tplbond.CC6H4C6H4C.tplbond.CSiMe3 to Unsaturated Macrocycles

T. Tilley, S. Mao, 1995 .

Donor-Promoted 1,2-Hydrogen Migration from Silicon to a Saturated Ruthenium Center and Access to Silaoxiranyl and Silaiminyl Complexes.

O. Eisenstein, C. Raynaud, T. Tilley, 2015, Journal of the American Chemical Society.

A Versatile, Transition-Metal Mediated Route to Blue-Light-Emitting Polymers with Chemically Tunable Luminescent Properties

T. Tilley, S. Mao, 1997 .

Reactions of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]X (X Cl, Me) complexes with carbon monoxide and the isocyanide 2,6-Me2C6H3NC. Crystal structure of (η5-C5H5)(η5-C5Me5)Zr[η2-C(N-2,6-Me2C6H3)Si(SiMe3)3]Cl

S. Geib, A. Rheingold, T. Tilley, 1988 .

Strained, ring tilted dicarbon-bridged [2]ferrocenophanes and ferrocene revisited: 57Fe Mössbauer spectroscopic study of bonding, hyperfine interactions, and lattice dynamics

I. Manners, T. Tilley, R. Herber, 1999 .

Divalent lanthanide chemistry. Preparation and crystal structures of sodium tris[bis(trimethylsilyl)amido]europate(II) and sodium tris[bis(trimethylsilyl)amido]ytterbate(II), NaM[N(SiMe3)2]3

R. Andersen, T. Tilley, A. Zalkin, 1984 .

Halide, hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)bis(trimethylphosphine)ruthenium

R. Grubbs, J. Bercaw, T. Tilley, 1984 .

Stabilization of ArSiH4(-) and SiH6(2-) anions in diruthenium Si-H σ-complexes.

T. Tilley, Mark C. Lipke, T. Tilley, 2012, Angewandte Chemie.

Generation and Reactivity of {(Ethane-1,2-diyl)bis[diisopropylphosphine-κP]}-{[2,4,6-tri(tert-butyl)phenyl]phosphino-κP}rhodium ([Rh{PH(tBu3C6H2)}(iPr2PCH2CH2PiPr2)]): Catalytic C−P Bond Formationvia Intramolecular C−H/P−H Dehydrogenative Cross-Coupling

T. Tilley, M. Stradiotto, K. Fujdala, 2001 .

Synthesis, structure and dynamic studies on base-stabilized silylene complexes

A. Rheingold, D. Straus, T. Tilley, 1995 .

The Ruthenostannylene Complex [Cp*(IXy)H2 Ru-Sn-Trip]: Providing Access to Unusual Ru-Sn Bonded Stanna-imine, Stannene, and Ketenylstannyl Complexes.

Micah S. Ziegler, T. Tilley, G. Hillhouse, 2015, Angewandte Chemie.

Reactions of hafnocene stannyl complexes with stannanes: implications for the mechanism of the metal-catalyzed dehydropolymerization of secondary stannanes

N. Neale, T. Tilley, 2004 .

Coordinatively and electronically unsaturated tris(trimethylsilyl)silyl complexes of manganese and iron

R. Heyn, T. Tilley, 2002 .

Preparation and characterization of tris(trimethylsilyl)silyl derivatives of zinc, cadmium, and mercury. X-ray crystal structure of Zn[Si(SiMe3)3]2

S. Geib, A. Rheingold, T. Tilley, 1987 .

Synthesis and reactivity of bis(heptamethylindenyl) yttrium (Ind*2Y) complexes containing alkyl and hydride ligands: crystal structure of Ind*2YCl(THF)

T. Tilley, John Gavenonis, 2004 .

Reactions of carbon monoxide with trimethylsilyl and tris(trimethylsilyl)silyl derivatives of group 4 metals. Synthesis, characterization, and reactivity of silaacyl complexes

T. Tilley, B. Campion, J. Falk, 1987 .

Synthesis of Polysilanylmagnesium Compounds

T. Tilley, Christoph Marschner, Michaela Zirngast, 2006 .

Preparation and characterization of tris(trimethylsilyl)silyl and tris(trimethylsilyl)germyl derivatives of zirconium and hafnium. X-ray crystal structures of (.eta.5-C5Me5)Cl2HfSi(SiMe3)3 and (.eta.5-C5Me5)Cl2HfGe(SiMe3)3

D. Roddick, S. Geib, A. Rheingold, 1988 .

Preparation of the first stable formylsilane, (Me3Si)3SiCHO, from a zirconium .eta.2-silaacyl complex

T. Tilley, H. Woo, F. Elsner, 1988 .

Synthetic, structural and reactivity studies with new group 4 transition-metal silyl complexes

R. Heyn, A. Rheingold, T. Tilley, 1995 .

The Influence of Catalyst Structure on the Dehydropolymerization of Phenylsilane

T. Tilley, T. Imori, 1994 .

Bis[Bis(Trimethylsilyl)Amido]Bis(Diethyl Ether)Ytterbium and (Diethyl Ether)Bis(η5‐Pentamethylcyclopentadienyl)Ytterbium

J. Boncella, R. Andersen, T. Tilley, 2007 .

Synthesis of Sm−SiH3 Complexes via σ-Bond Metathesis of the Si−C Bond of Phenylsilane

T. Tilley, Ivan Castillo and, 2000 .

The coordination polymerization of silanes to polysilanes by a ".sigma.-bond metathesis" mechanism. Implications for linear chain growth

T. Tilley, 1993 .

Synthesis and characterization of the neutral lanthanide silyl complexes (.eta.5-C5Me5)2LnSiH(SiMe3)2 (Ln = Nd, Sm)

A. Rheingold, T. Tilley, N. S. Radu, 1992 .

Mechanistic Aspects of Transition-Metal Catalyzed Dehydrogenative Silane Coupling Reactions

T. Tilley, 1990 .

Preparation and properties of tris(trimethylstannyl)silyl complexes of chromium, molybdenum, and tungsten. X-ray structure of [NEt4][(CO)5WSi(SnMe3)3]

R. Heyn, T. Tilley, 1990 .

Reaction of an early-transition metal .eta.2-silaacyl complex with pyridine. Diastereoselectivity in the formation of a (2-pyridyl)silylmethoxy ligand

S. Geib, A. Rheingold, T. Tilley, 1988 .

Coordinatively unsaturated tris(trimethylsilyl)silyl complexes of chromium, manganese, and iron

D. Roddick, S. Geib, A. Rheingold, 1987 .

Coordinatively and Electronically Unsaturated Zwitterionic Iron Silyl Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]-

T. Tilley, Laura Turculet, Jay D. Feldman, 2003 .

Synthesis and study of the ruthenium-silene complexes (.eta.5-C5Me5)(PR3)RuH(.eta.2-CH2:SiR'2) (R = CHMe2, Cy; R' = Me, Ph)

R. Heyn, A. Rheingold, T. Tilley, 1993 .

Synthesis and Structure of the (tetrahydroxy)oligosiloxane [(tBuO)3SiOSi(OH)2]2O

T. Tilley, M. P. Coles, R. Rulkens, 2000 .

Reactivity of a scandium-silicon bond toward carbon monoxide and CN(2,6-Me2C6H3). Generation and reactivity of an apparent silene intermediate resulting from isocyanide coupling at scandium

R. Heyn, T. Tilley, B. Campion, 1990 .

.sigma.-Bond metathesis reactions for d0 metal-silicon bonds that produce zirconocene and hafnocene hydrosilyl complexes

R. Heyn, T. Tilley, H. Woo, 1992 .

Dehydropolymerization of bis- and tris(silyl)arenes to highly crosslinked disilanylenearylene polymers, catalyzed by [(.eta.5-C5H5)(.eta.5-C5Me5)ZrH2]2

T. Tilley, H. Woo, John F. Walzer, 1991 .

.sigma.-Bond metathesis mechanism for dehydropolymerization of silanes to polysilanes by d0 metal catalysts

T. Tilley, H. Woo, John F. Walzer, 1992 .

Disilanylenearylene oligomers and polymers from dehydropolymerization of 1,4-RH2SiC6H4SiH2R (R = methyl, ethyl, and hexyl)

T. Tilley, H. Woo, T. Imori, 1993 .

Synthesis and characterization of tantalum silsesquioxane complexes.

T. Tilley, P. Guillo, Meg E. Fasulo, 2013, Dalton transactions.

Catalytic functionalization of hydrocarbons by sigma-bond-metathesis chemistry: dehydrosilylation of methane with a scandium catalyst.

A. Sadow, T. Tilley, 2003, Angewandte Chemie.

Catalytic Olefin Hydrosilations Mediated by Ruthenium η3-H2Si σ Complexes of Primary and Secondary Silanes

O. Eisenstein, C. Raynaud, T. Tilley, 2018, ACS Catalysis.

Dehydrogenative polymerization of silanes to polysilanes by zirconocene and hafnocene catalysts. A new polymerization mechanism

T. Tilley, H. Woo, 1989 .

Structural and Chemical Properties of Zwitterionic Iridium Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PPh2)3]-

T. Tilley, J. Peters, Jay D. Feldman, 2002 .

Regioselective coupling of pentafluorophenyl substituted alkynes: mechanistic insight into the zirconocene coupling of alkynes and a facile route to conjugated polymers bearing electron-withdrawing pentafluorophenyl substituents.

Samuel A. Johnson, S. Zürcher, T. Tilley, 2003, Journal of the American Chemical Society.

New Zirconocene-Coupling Route to Large, Functionalized Macrocycles

T. Tilley, J. Nitschke, S. Zurcher, 2000 .

A Simple, Efficient Route to Cage Compounds via Zirconocene Coupling

T. Tilley, F. Liu, G. Harder, 1998 .

SYNTHESIS AND REACTIVITY OF 16-ELECTRON HAFNOCENE SILYL HYDRIDE COMPLEXES

D. Zargarian, T. Tilley, C. G. Lugmair, 1997 .

New Route to Unsaturated Organosilicon Polymers and Macrocycles Based on Zirconocene Coupling of 1,4-MeC.tplbond.C(Me2Si)C6H4(SiMe2)C.tplbond.CMe

T. Tilley, S. Mao, 1995 .

Efficient hydrosilylation of carbonyl compounds with the simple amide catalyst [Fe{N(SiMe3)2}2].

T. Tilley, Jian Yang, 2010, Angewandte Chemie.

Sigma-Bond Metathesis Reactions Involving Lanthanide-Silicon and Lanthanide-Hydrogen Bonds

T. Tilley, N. S. Radu, 1994 .

Base-Free Silylene Complexes without .pi.-Donor Stabilization. Molecular Structure of [Cp*(PMe3)2Ru:SiMe2][B(C6F5)4]

A. Rheingold, T. Tilley, F. P. Arnold, 1994 .

Stoichiometric and Catalytic Reactions Involving Si-H Bond Activations by Rh and Ir Complexes Containing a Pyridylindolide Ligand

A. Bell, T. Tilley, Dmitry Karshtedt, 2006 .

Partial Oxidation of Methanol Over Highly Dispersed Vanadia Supported on Silica SBA-15

Alexis T. Bell, James D. Hoefelmeyer, Christian Hess, 2005 .

Carbonylation chemistry of the tantalum silyl (.eta.5-C5Me5)Cl3TaSiMe3. Synthesis, characterization, and reaction chemistry of (.eta.5-C5Me5)Cl3Ta(.eta.2-COSiMe3) and derivatives

S. Geib, A. Rheingold, A. Arif, 1989 .

Tetrahedral Lewis base adducts of an acyl. Preparation and x-ray structure of the pyridine adduct (.eta.5-C5Me5)Cl3Ta[.eta.2-OC(SiMe3)(NC5H5)]

A. Rheingold, T. Tilley, J. Arnold, 1986 .

Synthesis, characterization, and reactivity of triphenylsilyl, triphenylgermyl, and triphenylstannyl derivatives of zirconium and hafnium

T. Tilley, H. Woo, W. Freeman, 1992 .

Synthesis and structure of [(η5-C5Me5Ru(μ-NHPh)]2,an electron-deficient ruthenium amide complex

R. Heyn, T. Tilley, Robert E. Blake, 1992 .

A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes

Nicole A. Torquato, Micah S. Ziegler, T. Tilley, 2020, Angewandte Chemie.

A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes.

Nicole A. Torquato, Micah S. Ziegler, T. Tilley, 2020, Angewandte Chemie.

Sterically controlled functionalization of carbon surfaces with -C6H4CH2X (X = OSO2Me or N3) groups for surface attachment of redox-active molecules.

Wenjun Liu, T. Tilley, 2015, Langmuir : the ACS journal of surfaces and colloids.

Diphenylanthracene macrocylces from reductive zirconocene coupling: on the edge of steric overload.

V. Gessner, T. Tilley, 2011, Organic letters.

Unsymmetrical Zirconacyclopentadienes from Isolated Zirconacyclopropenes with 1-Alkynylphosphine Ligands

Samuel A. Johnson, K. A. Tupper, T. Tilley, 2009 .

Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications

Benjamin D. Yuhas, T. Tilley, C. Bradley, 2009 .

Reaction of M(C5Me5)2(OEt2), M = Eu or Yb, with phenylacetylene; formation of mixed-valence Yb3(C5Me5)4(µ-CCPh)4 and Eu2(C5Me5)2(µ-CCPh)2(tetrahydrofuran)4

J. Boncella, R. Andersen, T. Tilley, 1984 .

Artificial Metalloproteins Containing Co

Andy I. Nguyen, Ariel L. Furst, A. Borovik, 2018 .

Artificial Metalloproteins Containing Co4O4 Cubane Active Sites.

Andy I. Nguyen, Ariel L. Furst, A. Borovik, 2018, Journal of the American Chemical Society.

Beta-Phosphinoethylboranes as Ambiphilic Ligands in Nickel-Methyl Complexes

T. Tilley, R. Waterman, P. Bazinet, 2008 .

Ruthenium(IV) silyl hydride complexes via reaction of silanes with 16-electron [Ru(η5-C5Me5)(PPri3)X](X = Cl, CH2SiHPh2, SiMePh2) complexes. Hydride migrations to an η2-silene ligand

R. Heyn, T. Tilley, B. Campion, 1992 .

Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand.

Daniel S. Levine, Allegra L. Liberman-Martin, Micah S. Ziegler, 2016, Chemical communications.

Unusual Ar-H/Rh-H J(HH) NMR coupling in complexes of rhodium(III): experimental evidence and theoretical support for an eta1-arene structure.

U. Rothlisberger, A. Magistrato, R. Bergman, 2004, Journal of the American Chemical Society.

Silabenzene and Disilabenzene Complexes of Ruthenium

T. Woo, T. Tilley, Jeffrey M. Dysard and, 2001 .

SILYLENE EXTRUSION FROM A SILANE : DIRECT CONVERSION OF MES2SIH2 TO AN IRIDIUM SILYLENE DIHYDRIDE

T. Tilley, J. Peters, Jay D. Feldman, 1999 .

An Anionic Ruthenium Dihydride [Cp*(iPr2MeP)RuH2]− and Its Conversion to Heterobimetallic Ru(μ-H)2M (M = Ir or Cu) Complexes

Rex C. Handford, T. Tilley, Patrick W. Smith, 2019, Organometallics.

Preparation and crystal structure of bis[bis(pentamethylcyclopentadienyl)ytterbium(III)] undecacarbonyltriferrate, [(C5Me5)2Yb]2 [Fe3(CO)11]; a compound with four isocarbonyl (iron-carbonyl-ytterbium) interactions

R. Andersen, T. Tilley, 1982 .

Synthesis and Reactivity of Iridium and Rhodium Silyl Complexes Supported by a Bipyridine Ligand

T. Tilley, Jennifer L. McBee, 2009 .

Alkoxy and aryloxy derivatives of (pentamethylcyclopentadienyl)ruthenium. X-ray crystal structures of [(.eta.5-C5Me5)Ru(.mu.-OMe)]2, [(.eta.5-C5Me5)(CO)Ru(.mu.-OEt)]2, and (.eta.5-C5Me5)Ru(.eta.5-2,6-tBu2C6H3O) and molecular orbital analysis of [(.eta.5-C5H5)Ru(.mu.-OMe)]2

R. Heyn, T. Tilley, B. Bursten, 1989 .

Stoichiometric Reaction Chemistry of Cationic Ruthenium Silylene Complexes toward Polar and Nonpolar Organic Substrates

T. Tilley, Meg E. Fasulo, 2012 .

Synthesis and structure of PNP-supported iridium silyl and silylene complexes: catalytic hydrosilation of alkenes.

T. Tilley, E. Calimano, 2009, Journal of the American Chemical Society.

Activations of silanes with [PhB(CH2PPh2)3]Ir(H)(η3-C8H13). Formation of iridium silylene complexes via the extrusion of silylenes from secondary silanes R2SiH2

T. Tilley, J. Peters, Jay D. Feldman, 2002 .

Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2(=GeRR')]+.

T. Tilley, Meg E. Fasulo, 2012, Chemical communications.

Synthesis, Structure, and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene and Germylene Complexes

Paul G. Hayes, T. Tilley, R. Waterman, 2009 .

Synthons for coordinatively unsaturated complexes of tungsten, and their use for the synthesis of high oxidation-state silylene complexes.

T. Tilley, B. Mork, 2004, Journal of the American Chemical Society.

Synthesis, Structure, and Reactivity of Osmium Silyl and Silylene Complexes Cp*(Me3P)2OsSiR2X and [Cp*(Me3P)2OsSiR2][B(C6F5)4] (R = Me, iPr; X = Cl, OTf)

T. Tilley, P. Glaser, Paulus W. Wanandi, 2004 .

Reactions of alkynes with coordinatively unsaturated (.eta.5-C5Me5)Ru derivatives. X-ray crystal structures of (.eta.5-C5Me5)Cl2Ru(.eta.2:.eta.4-.mu.2-C4H4)Ru(.eta.5-C5Me5) and (.eta.5-C5Me5)3Ru3(.mu.2-Cl)2(.mu.3-Cl)(.eta.2-.mu.2-HC.tplbond.CSiMe3)

R. Heyn, T. Tilley, B. Campion, 1990 .

Mechanism of the electrocatalytic reduction of protons with diaryldithiolene cobalt complexes.

M. Head‐Gordon, J. Panetier, T. Tilley, 2014, Journal of the American Chemical Society.

High oxidation-state (formally d(0)) tungsten silylene complexes via double Si-H bond activation.

T. Tilley, B. Mork, 2001, Journal of the American Chemical Society.

Silylene Hydride Complexes of Molybdenum with Silicon−Hydrogen Interactions: Neutron Structure of (η5-C5Me5)(Me2PCH2CH2PMe2)Mo(H)(SiEt2)

T. Tilley, A. Schultz, B. Mork, 2004 .

Synthesis and Reactivity of (Pentamethylcyclopentadienyl)ruthenium Complexes of the Stable Neutral Silylene Si(tBuNCHCHNtBu)

T. Tilley, Jeffrey M. Dysard and, 2000 .

Reactivity of an Osmium Silylene Complex toward Chlorocarbons: Promotion of Metal Redox Chemistry by a Silylene Ligand and Relevance to the Mechanism of the Direct Process

T. Tilley, Paulus W. Wanandi, Andreas Glaser, 2000 .

Synthesis and Study of Ruthenium Silylene Complexes of the Type [(η5-C5Me5)(Me3P)2RuSiX2]+(X = Thiolate, Me, and Ph)

A. Rheingold, T. Tilley, G. Mitchell, 1998 .

Base-free silylene complexes [(.eta.5-C5Me5)(PMe3)2Ru:Si(SR)2]BPh4 (R = Et, p-MeC6H4)

D. Straus, T. Tilley, Steven D. Grumbine, 1990 .

Reactions of Cationic PNP-Supported Iridium Silylene Complexes with Polar Organic Substrates

T. Tilley, E. Calimano, 2010 .

Reactions of the ruthenium silylene derivative [(η5-C5Me5)(PMe3)2RuSiPh2(NCMe)]BPh4 with alcohols, ketones and acetic acid

T. Tilley, Cheng Zhang, Steven D. Grumbine, 1991 .

Interconversion of η3-H2SiRR' σ-complexes and 16-electron silylene complexes via reversible H-H or C-H elimination.

T. Tilley, Mark C. Lipke, Felix Neumeyer, 2014, Journal of the American Chemical Society.

A stable .eta.2-silene complex of iridium: (.eta.5-C5Me5)(PMe3)Ir(.eta.2-CH2:SiPh2)

R. Heyn, T. Tilley, B. Campion, 1990 .

Preparation, isolation, and characterization of transition-metal .eta.2-silene complexes. X-ray crystal structure of (.eta.5-C5Me5)[P(iso-Pr)3]Ru(H)(.eta.2-CH2SiPh2)

R. Heyn, T. Tilley, B. Campion, 1988 .

Synthesis and reactivity of tris(imido)rhenium complexes containing rhenium-main group element bonds. silicon-carbon bond activations of PhSiH(3) by silyl complexes.

T. Tilley, John Gavenonis, 2004, Inorganic chemistry.

Reactions of Cp*(PMe3)Ir(Me)OTf with Silanes: Role of Base-Free Silylene Complexes in Rearrangements of the Resulting Silicon-Based Ligands

R. Bergman, T. Tilley, S. R. Klei, 2002 .

Enhanced Reactivity of Cationic vs Neutral Hafnocene Complexes in Stoichiometric and Catalytic σ-Bond Metathesis Reactions Involving Si−H and Si−C Bonds

A. Sadow, T. Tilley, 2001 .

Generation of a Silylene Complex by the 1,2-Migration of Hydrogen from Silicon to Platinum.

T. Tilley, G. Mitchell, Gregory P. Mitchell, 1998, Angewandte Chemie.

POLYSILYL GROUP ISOMERIZATION VIA MIGRATIONS IN RHODIUM AND IRIDIUM DERIVATIVES (ME3P)3MSI(SIME3)3

A. Rheingold, T. Tilley, G. Yap, 1995 .

The Silicon-Heteroatom Bond (1991)

James W. White, T. Kendrick, T. Tilley, 1991 .

Di‐μ‐Chloro‐Bis[(η5‐Pentamethylcyclopentadienyl) Chlororuthenium(III)], [Cp*RuCl2]2 and Di‐μ‐methoxo‐Bis(η5‐Pentamethylcyclopentadienyl)diruthenium(II), [Cp*RuOMe]2

T. Tilley, U. Koelle, J. Kossakowski, 2007 .

Terminal hafnium phosphinidene complexes and phosphinidene ligand exchange

T. Tilley, R. Waterman, 2011 .

Divalent lanthanide chemistry. Preparation of some four- and six-coordinate bis[(trimethylsilyl)amido] complexes of europium(II). Crystal structure of bis[bis(trimethylsilyl)amido]bis(1,2-dimethoxyethane)europium(II)

R. Andersen, T. Tilley, D. H. Templeton, 1981 .

Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(ii) complexes.

Zhenyang Lin, Jing-Xuan Zhang, T. Tilley, 2019, Dalton transactions.

Tertiary phosphine complexes of the f-block metals. Crystal structure of Yb[N(SiMe3)2]2[Me2PCH2CH2PMe2]: evidence for a ytterbium-.gamma.-carbon interaction

R. Andersen, T. Tilley, A. Zalkin, 1982 .

A new mechanism for metal-catalyzed stannane dehydrocoupling based on alpha-H-elimination in a hafnium hydrostannyl complex.

N. Neale, T. Tilley, 2002, Journal of the American Chemical Society.

Synthesis, Structure, and α-Elimination Chemistry of Hafnocene Triarylstannyl Complexes

N. Neale, T. Tilley, 2005 .

Terminal stibinidene ligands. Generation of CpCp*Hf=Sb(dmp) and trapping reactions with PMe3 and 2-butyne.

T. Tilley, R. Waterman, 2006, Chemical communications.

Synthesis and structure of a transition-metal-substituted silylene complex, (CO)4OsSi(STol-p)[Ru(.eta.5-C5Me5)(PMe3)2]

A. Rheingold, T. Tilley, Steven D. Grumbine, 1993 .

Silyl and diphenylsilylene derivatives of (.eta.5-C5Me5)(PMe3)2Ru. Evidence for the base-free silylene complex [(.eta.5-C5Me5)(PMe3)2Ru:SiPh2]+

S. Geib, R. Heyn, A. Rheingold, 1990 .

High molecular mass polystannanes via dehydropolymerization of di(n-butyl)stannane

T. Tilley, T. Imori, 1993 .

Facile interconversion of [Cp2(Cl)Hf(SnH3)] and [Cp2(Cl)Hf(mu-H)SnH2]: DFT investigations of hafnocene stannyl complexes as masked stannylenes.

O. Eisenstein, L. Maron, L. Perrin, 2010, Angewandte Chemie.

Coordination Networks Based on Tetrahedral Silane Building Blocks: Influence of the Anion on Structures Adopted by Ag+−Si(p-C6H4CN)4 Arrays

Fei Liu, T. Tilley, F.-Q. Liu, 1997 .

Group 8 Transition Metal Complexes of the Tripodal Triphosphino Ligands PhSi(CH2PR2)3 (R = Ph, iPr)

T. Tilley, Michael I. Lipschutz, Felix Neumeyer, 2013 .

Bis(pentamethylcyclopentadienyl)carboxylato and -dithiocarbamato derivatives of neodymium(III) and ytterbium(III). Crystal structure of bis(pentamethylcyclopentadienyl)(diethyldithiocarbamato)ytterbium(III)

R. Andersen, T. Tilley, D. H. Templeton, 1982 .

Enhancement of the Catalytic Activity of Titanium-Based Terminal Olefin Epoxidation Catalysts via Surface Modification with Functionalized Protic Molecules

T. Tilley, P. Cordeiro, 2011 .

Stereoselective macrocyclization through zirconocene-mediated coupling of achiral dialkynes.

T. Tilley, Jennifer L. McBee, Ian H. Kratter, 2009, Chemical communications.

Interligand H⋯Si interactions in tungsten silyl trihydride complexes

T. Tilley, Meg E. Fasulo, 2011 .

Tertiary phosphine complexes of the f-block metals. Preparation of pentamethylcyclopentadienyl-tertiary phosphine complexes of ytterbium(II), ytterbium(III), and europium(II). Crystal structure of Yb(Me/sub 5/C/sub 5/)/sub 2/Cl(Me/sub 2/PCH/sub 2/PMe/sub 2/)

R. Andersen, T. Tilley, A. Zalkin, 1983 .

Thermolytic molecular precursor routes to Cr/Si/Al/O and Cr/Si/Zr/O catalysts for the oxidative dehydrogenation and dehydrogenation of propane

T. Tilley, K. Fujdala, 2003 .

Trialkoxysiloxy complexes of nickel. Molecular structures of Na3(.mu.3-I){Ni[.mu.3-OSi(O-tert-Bu)3]3I}.cntdot.0.5THF.cntdot.0.5C5H12 and {(.eta.3-C3H5)Ni[.mu.2-OSi(O-tert-Bu)3]}2

S. Geib, A. Rheingold, T. Tilley, 1990 .

Oxidative dehydrogenation of propane over vanadia-based catalysts supported on high-surface-area mesoporous MgAl2O4

Alexis T. Bell, A. Bell, T. Tilley, 2004 .

Synthesis and chemical functionalization of high surface area dendrimer-based xerogels and their use as new catalyst supports

T. Tilley, J. W. Kriesel, 2000 .

Design and synthesis of heterogeneous catalysts: the thermolytic molecular precursor approach

T. Tilley, Kyle L. Fujdala, K. Fujdala, 2003 .

Thermolytic molecular precursor route to active and selective vanadia-zirconia catalysts for the oxidative dehydrogenation of propane

Alexis T. Bell, Jonathan L. Male, Heiko G. Niessen, 2000 .

Molecular design and synthesis of heterogeneous and single-site, supported catalysts

T. Tilley, 2002 .

Synthesis and Characterization of Et2NM{OB[OSi(OtBu)3]2}3 (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials

T. Tilley, K. Fujdala, 2005 .

Poly(2,5-diphenylgermole): Incorporation of a Germole Ring into a Conjugated Polymer

B. Lucht, T. Tilley, and Mihai A. Buretea, 2000 .

EFFICIENT ZIRCONOCENE-COUPLING OF SILICON-SUBSTITUTED DIYNES TO POLYMERS AND MACROCYCLES

T. Tilley, S. Mao, An Liu, 1998 .

Synthesis and reactivity of rhodium and iridium alkene, alkyl and silyl complexes supported by a phenyl-substituted PNP pincer ligand.

T. Tilley, E. Calimano, 2010, Dalton transactions.

Synthetic Development and Chemical Reactivity of Transition-Metal Silylene

Paul G. Hayes, T. Tilley, Complexes Waterman, 2007 .

Carbon dioxide activation by a transition metal-silicon bond. Formation of silanecarboxylate complexes [Cp2Sc[.mu.-O2CSiR3)]2

R. Heyn, T. Tilley, B. Campion, 1990 .

The nature of transport variations in molecular heterojunction electronics.

A. Majumdar, R. Segalman, J. Malen, 2009, Nano letters.

Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature.

R. Bergman, T. Tilley, J. Suh, 2003, The Journal of organic chemistry.

Disambiguation of Metal and Brønsted Acid Catalyzed Pathways for Hydroarylation with Platinum(II) Catalysts

R. Bergman, T. Tilley, Miriam A. Bowring, 2011 .

Covalent Functionalization of GaP(110) Surfaces via a Staudinger-Type Reaction with Perfluorophenyl Azide

J. Neaton, M. Crommie, Wenjun Liu, 2016 .

Adsorption and Stability of π-Bonded Ethylene on GaP(110)

I. Sharp, J. Neaton, M. Crommie, 2013 .

Mechanism of the Decomposition of Aqueous Hydrogen Peroxide over Heterogeneous TiSBA15 and TS-1 Selective Oxidation Catalysts: Insights from Spectroscopic and Density Functional Theory Studies

Chang Won Yoon, Xinzheng Yang, T. Tilley, 2011 .

Effects of Precursor Composition on the Local Structure of Cu Dispersed on Mesoporous Silica: A Detailed X-ray Absorption Spectroscopy Study

A. Bell, S. Baxamusa, T. Tilley, 2004 .

Kinetics and mechanism of olefin epoxidation with aqueous H2O2 and a highly selective surface-modified TaSBA15 heterogeneous catalyst.

Daniel A. Ruddy, T. Tilley, D. Ruddy, 2008, Journal of the American Chemical Society.

Influence of surface modification of Ti-SBA15 catalysts on the epoxidation mechanism for cyclohexene with aqueous hydrogen peroxide.

L. K. Andersen, Daniel A. Ruddy, R. Brutchey, 2005, Langmuir : the ACS journal of surfaces and colloids.

Size-Dependent Activity of Co 3 O 4 Nanoparticle Anodes for Alkaline Water Electrolysis

A. Bell, A. Esswein, T. Tilley, 2009 .

EFFECTS OF PERCURSOR COMPOSTION ON THE LOCAL STRUCTURE OF CU DISPERSED ON MESOPOROUS SILICA: A DETAILED X-RAY ABSORPTION SPECTROSCOPY STUDY

A. Bell, S. Baxamusa, T. Tilley, 2004 .

Switchable Product Selectivity in Diazoalkane Coupling Catalyzed by a Two-Coordinate Cobalt Complex

J. Panetier, T. Tilley, Ryan J. Witzke, 2021, ACS Catalysis.

Direct Transformation of SiH4 to a Molecular L(H)2Co═Si═Co(H)2L Silicide Complex.

R. D. Britt, S. Teat, Rex C. Handford, 2023, Journal of the American Chemical Society.

Hydrolysis of 3-carboxy-6,8-difluoro-7-hydroxycoumarin (Pacific Blue™) succinimidyl ester under acidic and basic conditions

P. Willis, A. Stockton, M. Cable, 2013 .

Reverse micelle synthesis of rhodium nanoparticles.

G. Somorjai, Hongjiang Liu, J. Hoefelmeyer, 2007, Journal of colloid and interface science.

Identifying the length dependence of orbital alignment and contact coupling in molecular heterojunctions.

A. Majumdar, R. Segalman, J. Malen, 2009, Nano letters.

Probing the chemistry of molecular heterojunctions using thermoelectricity.

A. Majumdar, S. Jang, R. Segalman, 2008, Nano letters.

Efficient, high-yield route to long, functionalized p-phenylene oligomers containing perfluorinated segments, and their cyclodimerizations by zirconocene coupling.

T. Tilley, J. Nitschke, 2001, Journal of the American Chemical Society.

Preparation and reactivity of 16-electron ‘half-sandwich’ ruthenium complexes; X-ray crystal structure of (η5-C5Me5)Ru(PPri3)Cl

R. Heyn, T. Tilley, B. Campion, 1988 .

Transition metal complexes containing donor-stabilized silylyne ligands. Reductive dimerization to a silylene complex

T. Tilley, R. Chadha, Steven D. Grumbine, 1992 .

A new molecular precursor for magnesia-silica materials

T. Tilley, J. W. Kriesel, 2001 .

Trialkoxysiloxy complexes as precursors to MO2.cntdot.4SiO2 (M = Ti, Zr, Hf) materials

T. Tilley, K. W. Terry, 1991 .

Inverse rectification in donor-acceptor molecular heterojunctions.

A. Majumdar, J. Neaton, R. Segalman, 2011, ACS nano.

Hydrogen-substituted osmium silylene complexes: effect of charge localization on catalytic hydrosilation.

Paul G. Hayes, M. Hall, T. Tilley, 2006, Journal of the American Chemical Society.

Cuprous tris(tert-butoxy)siloxy complexes and their thermolytic conversion to copper-silica and copper oxide-silica nanocomposites

T. Tilley, K. W. Terry, C. G. Lugmair, 1996 .

Order−Disorder Phase Transition in Poly(di-n-butylstannane) Observed by UV−Vis and Raman Spectroscopy

T. Tilley, S. Bukalov, L. Leites, 2002 .

Poly(diaryl)stannanes: Influence of Substituents on the σ−σ* Transition Energy

T. Tilley, Victor Y. Lu and, 2000 .

Low-Band-Gap, σ-Conjugated Polymers: Poly(diarylstannanes)

T. Tilley, Victor Y. Lu and, 1996 .

Thermolytic conversion of a bis(alkoxy)tris(siloxy)tantalum(V) single-source molecular precursor to catalytic tantala-silica materials

T. Tilley, C. G. Lugmair, Robert L. Brutchey, 2005 .

Insertion of ethylene into zirconium-silicon and hafnium-silicon bonds

R. Heyn, T. Tilley, J. Arnold, 1989 .

Synthesis and Study of Heterobimetallic Complexes Supported by a Ferrocene-Based Bisphosphine−Diamine Ligand

A. Bell, T. Tilley, Dmitry Karshtedt, 2003 .

Copper(III) Metallacyclopentadienes via Zirconocene Transfer and Reductive Elimination to an Isolable Phenanthrocyclobutadiene.

M. Head‐Gordon, Yi Liu, T. Cundari, 2022, Journal of the American Chemical Society.

BIPYRIDINE-CONTAINING CYCLOPHANES VIA ZIRCONOCENE COUPLING

T. Tilley, J. Nitschke, 1998 .

General, Efficient Route to Thiophene‐1‐oxides and Well‐Defined, Mixed Thiophene‐Thiophene‐1‐oxide Oligomers.

T. Tilley, Biwang Jiang, 2000 .

Mono(η5‐Pentamethylcyclopentadienyl) Complexes of Osmium

Christopher W. Gribble, G. Girolami, J. Jefferis, 2014 .

Pt—Ag Catalyst System for Hydroarylations with Unactivated Arenes and Olefins.

A. Bell, T. Tilley, Dmitry Karshtedt, 2004 .

Rhodium Complexes Containing a Tridentate Bis(8-quinolyl)methylsilyl Ligand: Synthesis and Reactivity

T. Tilley, M. Stradiotto, P. Sangtrirutnugul, 2006 .

Molecular cobalt electrocatalyst for proton reduction at low overpotential.

T. Tilley, T. Davenport, H. S. Ahn, 2014, Chemical communications.

Spatial resolution of a type II heterojunction in a single bipolar molecule.

Yasaman Bahri, Georgy Samsonidze, Yasaman Bahri, 2009, Nano letters.

Efficient diastereoselective syntheses of chiral macrocycles via zirconocene coupling. Synthetic control of size and geometry.

T. Tilley, L. Schafer, 2001, Journal of the American Chemical Society.

DFT Investigation of the Catalytic Hydromethylation of Olefins by Scandocenes. 2. Influence of the Ansa Ligand on Propene and Isobutene Hydromethylation

O. Eisenstein, L. Maron, T. Tilley, 2008 .

Structural and mechanistic investigation of a cationic hydrogen-substituted ruthenium silylene catalyst for alkene hydrosilation

T. Tilley, Meg E. Fasulo, Mark C. Lipke, 2013 .

Heavy Tetrel Complexes of Ru Featuring Ru═E(R)X and Ru–E–R (E = Sn, Pb) Linkages

Rex C. Handford, T. Tilley, Patrick W. Smith, 2019, Organometallics.

Silane–Allyl Coupling Reactions of Cp*(iPr2MeP)Fe(η3-C3H5) and Synthetic Access to the Hydrido–Dinitrogen Complex Cp*(iPr2MeP)FeH(N2)

T. Tilley, Patrick W. Smith, 2015 .

Cp*(PiPr3)RuOTf: A Reagent for Access to Ruthenium Silylene Complexes

T. Tilley, Meg E. Fasulo, P. Glaser, 2011 .

High electrophilicity at silicon in η3-silane σ-complexes: Lewis base adducts of a silane ligand, featuring octahedral silicon and three Ru-H-Si interactions.

T. Tilley, Mark C. Lipke, T. Tilley, 2011, Journal of the American Chemical Society.

Germylene and silylene complexes of molybdenum via E-H (E = Ge, Si) bond activations: steric influences on intramolecular MoH...E interactions.

T. Tilley, Jennifer L. McBee, A. Shinohara, 2009, Inorganic Chemistry.

Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing.

T. Tilley, Patrick W. Smith, 2018, Journal of the American Chemical Society.

1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion.

O. Eisenstein, C. Raynaud, T. Tilley, 2014, Journal of the American Chemical Society.

The [(η5-C5Me5)(2,2‘-bipyridine)Ru]- Anion and Its Use in the Synthesis of Alkyl, Gallyl, and Stannyl Complexes of Ruthenium

T. Tilley, B. Mork, H. F. Yuen, 2004 .

TRANSITION-METAL-MEDIATED REDISTRIBUTION AT SILICON : A BIMOLECULAR MECHANISM INVOLVING SILYLENE COMPLEXES

T. Tilley, S. Grumbine, 1994 .

Reversible 1,2-Migration of Hydrogen between Platinum and Silicon via Intermediate Silylene Complexes

T. Tilley, Gregory P. Mitchell, 1998 .

Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.

Allegra L. Liberman-Martin, T. Tilley, Mark C. Lipke, 2017, Angewandte Chemie.

Activations of all Bonds to Silicon (Si-H, Si-C) in a Silane with Extrusion of [CoSiCo] Silicide Cores.

Rex C. Handford, T. Tilley, Patrick W. Smith, 2019, Journal of the American Chemical Society.

Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound.

Allegra L. Liberman-Martin, R. Bergman, T. Tilley, 2015, Journal of the American Chemical Society.

Preparation, characterization, and x-ray crystal structure of an acetonitrile-complexed ruthenium silylene

S. Geib, A. Rheingold, D. Straus, 1987 .

Silica-supported, single-site titanium catalysts for olefin epoxidation. A molecular precursor strategy for control of catalyst structure.

T. Tilley, J. Jarupatrakorn, T. Don Tilley, 2002, Journal of the American Chemical Society.

Synthesis and chemical functionalization of high surface area dendrimer-based xerogels and their use as new catalyst supports

T. Tilley, J. W. Kriesel, 2000 .

Molecular cobalt electrocatalyst for proton reduction at low overpotential.

T. Tilley, T. Davenport, H. S. Ahn, 2014, Chemical communications.