F. Toste

发表

Exceptionally Fast Carbon-Carbon Bond Reductive Elimination from Gold(III)

W. J. Wolf, Matthew S. Winston, F. Toste, 2013, Nature chemistry.

Relativistic effects in homogeneous gold catalysis

F. Dean Toste, F. Toste, David J Gorin, 2007, Nature.

Ligand effects in homogeneous Au catalysis.

F Dean Toste, F. Toste, David J Gorin, 2008, Chemical reviews.

Ligand-Controlled Access to [4 + 2] and [4 + 3] Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes.

F. Toste, P. Mauleón, R. M. Zeldin, 2009 .

Generation of Axially Chiral Fluoroallenes through a Copper-Catalyzed Enantioselective β-Fluoride Elimination.

Binh Khanh Mai, Peng Liu, Peng Liu, 2021, Journal of the American Chemical Society.

Highly selective condensation of biomass-derived methyl ketones as a source of aviation fuel.

Eric R. Sacia, A. Bell, Matthew Deaner, 2015, ChemSusChem.

A Comparison of Photocatalytic Activities of Gold Nanoparticles Following Plasmonic and Interband Excitation and a Strategy for Harnessing Interband Hot Carriers for Solution Phase Photocatalysis

Son C. Nguyen, A. P. Alivisatos, G. Somorjai, 2017, ACS central science.

Enantioselective Allenoate-Claisen Rearrangement using Chiral Phosphate Catalysts.

Mario Ellwart, F. Toste, M. Sigman, 2020, Journal of the American Chemical Society.

Gold-catalyzed cycloisomerization of 1,5-allenynes via dual activation of an ene reaction.

K. Houk, F. Toste, P. Cheong, 2008, Journal of the American Chemical Society.

Hydrogen Gas-Mediated Deoxydehydration/Hydrogenation of Sugar Acids: Catalytic Conversion of Glucarates to Adipates.

F. Toste, Jianbin Chen, S. Zuend, 2017, Journal of the American Chemical Society.

Data Science Meets Physical Organic Chemistry.

Cian Kingston, F. Toste, M. Sigman, 2021, Accounts of chemical research.

Strategies for remote enantiocontrol in chiral gold(iii) complexes applied to catalytic enantioselective γ,δ-Diels–Alder reactions†

Jolene P. Reid, F. Toste, M. Sigman, 2020, Chemical science.

Site-selective acylation of natural products with BINOL-derived phosphoric acids.

Scott J. Miller, Junqi Li, F. Toste, 2019, ACS catalysis.

Disparate Catalytic Sca ff olds for Atroposelective Cyclodehydration

Scott J. Miller, Jolene P. Reid, Junqi Li, 2019 .

Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer-Type Transformation using Phase-Transfer Catalysis.

F. Toste, M. Sigman, M. Orlandi, 2018, Angewandte Chemie.

Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc02223b

F. Toste, Margaret J. Hilton, M. Sigman, 2018, Chemical science.

Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer.

F. Toste, Margaret J. Hilton, M. Sigman, 2016, Journal of the American Chemical Society.

An In Situ Directing Group Strategy for Chiral Anion Phase-Transfer Fluorination of Allylic Alcohols

F. Toste, Yi‐Ming Wang, W. Zi, 2014, Journal of the American Chemical Society.

Direct asymmetric amination of α-branched cyclic ketones catalyzed by a chiral phosphoric acid.

F. Toste, Xiaoyu Yang, 2015, Journal of the American Chemical Society.

Chemoselective and Site-Selective Reductions Catalyzed by a Supramolecular Host and a Pyridine-Borane Cofactor.

K. Raymond, R. Bergman, F. Toste, 2021, Journal of the American Chemical Society.

Catalytic upgrading of biomass-derived methyl ketones to liquid transportation fuel precursors by an organocatalytic approach.

M. Head‐Gordon, A. Bell, S. Sreekumar, 2015, Angewandte Chemie.

Title Production of Fuels and Chemicals from Biomass : Condensation Reactions and Beyond Permalink

Takahiko Moteki, David W. Flaherty, F. Toste, 2017 .

Single-operation deracemization of 3H-indolines and tetrahydroquinolines enabled by phase separation.

F. Toste, Andrew V. Samant, A. D. Lackner, 2013, Journal of the American Chemical Society.

Gold(I)-Catalyzed Enantioselective Desymmetrization of 1,3-Diols through Intramolecular Hydroalkoxylation of Allenes.

F. Toste, W. Zi, 2015, Angewandte Chemie.

Protein-like proton exchange in a synthetic host cavity

C. Perrin, K. Raymond, C. Sgarlata, 2015, Proceedings of the National Academy of Sciences.

Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion

Ying He, F. Toste, H. Frei, 2014, Journal of the American Chemical Society.

Enantioselective synthesis of cyclic ethers through a vanadium-catalyzed resolution/oxidative cyclization.

F. Toste, A. Blanc, 2006, Angewandte Chemie.

Gold-catalyzed intramolecular aminoarylation of alkenes: C-C bond formation through bimolecular reductive elimination.

W. Goddard, F. Toste, Diego Benítez, 2010, Angewandte Chemie.

Enantioselective synthesis of highly substituted furans by a copper(II)-catalyzed cycloisomerization-indole addition reaction.

F. Toste, Z. J. Wang, V. Rauniyar, 2011, Journal of the American Chemical Society.

Chiral (acyclic diaminocarbene)gold(I)-catalyzed dynamic kinetic asymmetric transformation of propargyl esters.

F. Toste, Yi‐Ming Wang, C. Kuzniewski, 2011, Journal of the American Chemical Society.

Synthesis of Biomass-Derived Ethers for Use as Fuels and Lubricants.

A. Bell, F. Toste, Julie E. Rorrer, 2019, ChemSusChem.

Deoxygenation of biomass-derived feedstocks: oxorhenium-catalyzed deoxydehydration of sugars and sugar alcohols.

F. Toste, M. Shiramizu, F. Toste, 2012, Angewandte Chemie.

Catalytic, Enantioselective Fluorination Reactions

F. Toste, R. Thornbury, F. Toste, 2019, Organic Reactions.

High-spatial-resolution mapping of catalytic reactions on single particles

H. Bechtel, Yehonatan Levartovsky, Michael C. Martin, 2017, Nature.

A step beyond the Feltham-Enemark notation: spectroscopic and correlated ab initio computational support for an antiferromagnetically coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni).

K. Wieghardt, S. DeBeer, T. Petrenko, 2011, Journal of the American Chemical Society.

Development of ruthenium catalysts for the enantioselective synthesis of P-stereogenic phosphines via nucleophilic phosphido intermediates.

R. Bergman, F. Toste, V. Chan, 2009, Journal of the American Chemical Society.

The progression of chiral anions from concepts to applications in asymmetric catalysis.

G. L. Hamilton, Robert J. Phipps, F. Toste, 2012, Nature chemistry.

Control of Selectivity in Heterogeneous Catalysis by Tuning Nanoparticle Properties and Reactor Residence Time Results and Discussion

G. Somorjai, F. Toste, E. Gross, 2022 .

Ligand-controlled access to [4 + 2] and [4 + 3] cycloadditions in gold-catalyzed reactions of allene-dienes.

F. Toste, P. Mauleón, R. M. Zeldin, 2009, Journal of the American Chemical Society.

Mechanistic studies on Au(I)-catalyzed [3,3]-sigmatropic rearrangements using cyclopropane probes.

F. Toste, P. Mauleón, J. Krinsky, 2009, Journal of the American Chemical Society.

Advances in supramolecular host-mediated reactivity

K. Raymond, Kay T. Xia, R. Bergman, 2020, Nature Catalysis.

Highly active heterogeneous palladium nanoparticle catalysts for homogeneous electrophilic reactions in solution and the utilization of a continuous flow reactor.

G. Somorjai, Chia‐Kuang Tsung, Wenyu Huang, 2010, Journal of the American Chemical Society.

Enantioselective cyclization of enamide-ynes and application to the synthesis of the kopsifoline core.

F. Toste, Yi‐Ming Wang, B. Corkey, 2013, Tetrahedron.

Syntheses of seven-membered rings: ruthenium-catalyzed intramolecular [5+2] cycloadditions.

B. Trost, Hong C Shen, F. Toste, 2005, Chemistry.

On the impact of steric and electronic properties of ligands on gold(I)-catalyzed cycloaddition reactions.

W. Goddard, F. Toste, A. Z. González, 2009, Organic letters.

Elucidating the Influence of Anchoring Geometry on the Reactivity of NO2-Functionalized N-Heterocyclic Carbene Monolayers.

D. Feferman, A. Verdini, A. Cossaro, 2019, The journal of physical chemistry letters.

A Nucleophilic Strategy for Enantioselective Intermolecular α-Amination: Access to Enantioenriched α-Arylamino Ketones.

Joan Guasch, F. Toste, D. Miles, 2015, Journal of the American Chemical Society.

Synthesis of (-)-Octalactin A

F. Toste, A. T. Radosevich, Hui‐Wen Shih, 2008 .

Effect of Alcohol Structure on the Kinetics of Etherification and Dehydration over Tungstated Zirconia.

A. Bell, F. Toste, Julie E. Rorrer, 2018, ChemSusChem.

Title Effect of Alcohol Structure on the Kinetics of Etherification and Dehydration over Tungstated Zirconia Permalink

A. Bell, F. Toste, Julie E. Rorrer, 2018 .

Mechanism and kinetics of 1-dodecanol etherification over tungstated zirconia

A. Bell, Ying He, F. Toste, 2017 .

Title Mechanism and kinetics of 1-dodecanol etherification over tungstated zirconia Permalink

A. Bell, F. Toste, Julie E. Rorrer, 2017 .

A dual catalytic strategy for carbon–phosphorus cross-coupling via gold and photoredox catalysis

Ying He, F. Toste, Hongmiao Wu, 2014, Chemical science.

Asymmetric catalysis at the mesoscale: gold nanoclusters embedded in chiral self-assembled monolayer as heterogeneous catalyst for asymmetric reactions.

G. Somorjai, M. Marcus, S. Fakra, 2013, Journal of the American Chemical Society.

Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks.

O. Yaghi, Xiaokun Pei, F. Toste, 2020, Chem.

Mechanism of Photoredox-Initiated C-C and C-N Bond Formation by Arylation of IPrAu(I)-CF3 and IPrAu(I)-Succinimide.

F. Toste, Suhong Kim, 2019, Journal of the American Chemical Society.

Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-Coupling

F. Toste, M. D. Levin, Suhong Kim, 2016, ACS central science.

Visible light-mediated gold-catalysed carbon(sp2)–carbon(sp) cross-coupling† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc03025k

F. Toste, Suhong Kim, Jaime Rojas-Martín, 2015, Chemical science.

Alkylgold complexes by the intramolecular aminoauration of unactivated alkenes.

W. Goddard, F. Toste, Diego Benítez, 2010, Chemical science.

Gold-catalyzed oxidative coupling reactions with aryltrimethylsilanes.

W. Goddard, S. Denmark, F. Dean Toste, 2010, Organic letters.

Two metals are better than one in the gold catalyzed oxidative heteroarylation of alkenes.

W. Goddard, F. Toste, N. Mankad, 2011, Journal of the American Chemical Society.

Photoinitiated Oxidative Addition of CF3I to Gold(I) and Facile Aryl-CF3 Reductive Elimination

W. J. Wolf, Matthew S. Winston, F. Toste, 2014, Journal of the American Chemical Society.

Gold-catalyzed three-component coupling: oxidative oxyarylation of alkenes.

F. Toste, William E. Brenzovich, A. D. Lackner, 2010, Journal of the American Chemical Society.

A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation.

Christopher J. Chang, Shang Jia, F. Toste, 2019, Journal of the American Chemical Society.

Enantioselective α-amination enabled by a BINAM-derived phase-transfer catalyst

F. Toste, H. Nelson, H. Shunatona, 2014, Chemical Science.

Source of Rate Acceleration for Carbocation Cyclization in Biomimetic Supramolecular Cages.

Jinghua Guo, Lee‐Ping Wang, Wanli Yang, 2022, Journal of the American Chemical Society.

Electrochemical Deposition of Addressable N-Heterocyclic Carbene Monolayers

Q. Hu, A. Roy, F. Toste, 2020 .

Thiocyanate as a versatile synthetic unit: Efficient conversion of ArSCN to aryl alkyl sulfides and aryl thioesters

F. Toste, F. Laronde, I. V. Still, 1995 .

Synthesis of N-trifluoromethyl amides from carboxylic acids.

David M. Wilson, R. Flavell, Sinan Wang, 2021, Chem.

Enantioselective construction of remote tertiary carbon–fluorine bonds

Jianbo Liu, F. Toste, M. Sigman, 2019, Nature chemistry.

Gold-Catalyzed Hydrofluorination of Electron-Deficient Alkynes: Stereoselective Synthesis of β-Fluoro Michael Acceptors.

F. Toste, T. O’Connor, F. Toste, 2018, ACS catalysis.

Asymmetric Palladium-Catalyzed Directed Intermolecular Fluoroarylation of Styrenes

E. Talbot, F. Toste, J. McKenna, 2014, Journal of the American Chemical Society.

The Chemistry of Gold Fluoride Complexes

W. J. Wolf, F. Toste, W. Wolf, 2014 .

Asymmetric Fluorination of α-Branched Cyclohexanones Enabled by a Combination of Chiral Anion Phase-Transfer Catalysis and Enamine Catalysis using Protected Amino Acids

Robert J. Phipps, F. Toste, Xiaoyu Yang, 2014, Journal of the American Chemical Society.

Chiral anion phase-transfer catalysis applied to the direct enantioselective fluorinative dearomatization of phenols.

Robert J. Phipps, F. Toste, 2013, Journal of the American Chemical Society.

Asymmetric fluorination of enamides: access to α-fluoroimines using an anionic chiral phase-transfer catalyst.

Robert J. Phipps, F. Toste, K. Hiramatsu, 2012, Journal of the American Chemical Society.

A doubly axially chiral phosphoric acid catalyst for the asymmetric tandem oxyfluorination of enamides.

Robert J. Phipps, F. Toste, V. Rauniyar, 2012, Angewandte Chemie.

Enantioselective fluoroamination: 1,4-addition to conjugated dienes using anionic phase-transfer catalysis.

F. Toste, Yi‐Ming Wang, N. Frueh, 2013, Angewandte Chemie.

Development of catalysts and ligands for enantioselective gold catalysis.

F. Toste, Yi‐Ming Wang, A. D. Lackner, 2014, Accounts of chemical research.

4.20 Other C–C Bond Formations including Au

F. Toste, M. Campbell, 2012 .

Mechanistic study of gold(I)-catalyzed intermolecular hydroamination of allenes.

W. Goddard, F. Toste, Diego Benítez, 2010, Journal of the American Chemical Society.

Heterogeneous Supramolecular Catalysis through Immobilization of Anionic M4L6 Assemblies on Cationic Polymers.

K. Raymond, R. Bergman, H. Miyamura, 2020, Journal of the American Chemical Society.

Flexible NO2-Functionalized N-Heterocyclic Carbene Monolayers on Au (111) Surface.

A. Verdini, A. Cossaro, F. Toste, 2019, Chemistry.

Seven Post-synthetic Covalent Reactions in Tandem Leading to Enzyme-like Complexity within Metal-Organic Framework Crystals.

H. Furukawa, O. Yaghi, Mitsuharu Suzuki, 2016, Journal of the American Chemical Society.

A catalytic fluoride-rebound mechanism for C(sp3)-CF3 bond formation

J. O’Neil, M. Janabi, Ilia J. Kobylianskii, 2017, Science.

Measuring ion-pairing and hydration in variable charge supramolecular cages with microwave microfluidics

Kathleen A. Schwarz, Charles A. E. Little, J. Booth, 2019, Communications Chemistry.

Dendrimer-Stabilized Metal Nanoparticles as Efficient Catalysts for Reversible Dehydrogenation/Hydrogenation of N-Heterocycles.

G. Somorjai, C. Deraedt, F. Toste, 2017, Journal of the American Chemical Society.

Supported Au Nanoparticles with N-Heterocyclic Carbene Ligands as Active and Stable Heterogeneous Catalysts for Lactonization.

Brent B. Wickemeyer, G. Somorjai, S. Fakra, 2018, Journal of the American Chemical Society.

Au(I)-Catalyzed cycloisomerizations terminated by sp(3) C-H bond insertion.

Shigeyasu Kuroda, F. Toste, Y. Horino, 2009, Journal of the American Chemical Society.

Stereoselective synthesis of vinylsilanes by a gold(I)-catalyzed acetylenic sila-cope rearrangement.

F. Toste, Y. Horino, M. Luzung, 2006, Journal of the American Chemical Society.

Supramolecular catalysis in metal-ligand cluster hosts.

K. Raymond, R. Bergman, F. Toste, 2015, Chemical reviews.

Discovery of Potent Pyrazoline-Based Covalent SARS-CoV-2 Main Protease Inhibitors

M. Schirle, J. Tallarico, D. Nomura, 2022, bioRxiv.

Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics.

K. Raymond, R. Bergman, F. Toste, 2019, Journal of the American Chemical Society.

Title Hydrogen Gas-Mediated Deoxydehydration / Hydrogenation of Sugar Acids : Catalytic Conversion of Glucarates to Adipates Permalink

F. Toste, Jianbin Chen, S. Zuend, 2017 .

Expanding the scope of biomass-derived chemicals through tandem reactions based on oxorhenium-catalyzed deoxydehydration.

F. Toste, M. Shiramizu, F. Toste, 2013, Angewandte Chemie.

Enantioselective, Stereodivergent Hydroazidation and Hydroamination of Allenes Catalyzed by Acyclic Diaminocarbene (ADC) Gold(I) Complexes.

F. Toste, Chuanzhou Tao, Sophia L Shevick, 2016, Angewandte Chemie.

Inorganic micelles as efficient and recyclable micellar catalysts.

A. P. Alivisatos, G. Somorjai, J. M. Lucas, 2014, Nano letters.

New Insights into Aldol Reactions of Methyl Isocyanoacetate Catalyzed by Heterogenized Homogeneous Catalysts.

G. Somorjai, M. Chang, Bing Yuan, 2017, Nano letters.

A Pt-cluster-based Heterogeneous Catalyst for Homogeneous Catalytic Reactions: X-ray Absorption Spectroscopy and Reaction Kinetic Studies of Their Activity and Stability against Leaching ' Introduction

G. Somorjai, M. Marcus, Wenyu Huang, 2022 .

Site-dependent selectivity in oxidation reactions on single Pt nanoparticles.

D. Feferman, F. Toste, S. Dery, 2020, Physical chemistry chemical physics : PCCP.

Identifying site-dependent reactivity in oxidation reactions on single Pt particles

A. Verdini, A. Cossaro, F. Toste, 2018, Chemical science.

Supported Dendrimer-Encapsulated Metal Clusters: Toward Heterogenizing Homogeneous Catalysts.

G. Somorjai, C. Deraedt, F. Toste, 2017, Accounts of chemical research.

Gold(I)-catalyzed oxidative rearrangements.

N. Shapiro, F. Toste, B. Sherry, 2007, Journal of the American Chemical Society.

Catalytic Dynamic Kinetic Resolutions in Tandem to Construct Two-Axis Terphenyl Atropisomers.

Scott J. Miller, E. Miller, F. Toste, 2020, Journal of the American Chemical Society.

Enantioselective cyclizations of silyloxyenynes catalyzed by cationic metal phosphine complexes.

Ignacio Colomer, F. Toste, B. Corkey, 2012, Journal of the American Chemical Society.

Palladium-Catalyzed Defluorinative Coupling of 1-Aryl-2,2-Difluoroalkenes and Boronic Acids: Stereoselective Synthesis of Monofluorostilbenes.

F. Toste, R. Thornbury, F. Toste, 2016, Angewandte Chemie.

Modern Approaches for Asymmetric Construction of Carbon-Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs.

M. Sodeoka, F. Toste, Jianlin Han, 2018, Chemical reviews.

Methionine oxidation activates pyruvate kinase M2 to promote pancreatic cancer metastasis.

M. Hollingsworth, R. Friedman, J. Wilkinson, 2022, Molecular cell.

Approaching 100% Selectivity at Low Potential on Ag for Electrochemical CO2 Reduction to CO Using a Surface Additive

F. Toma, W. Goddard, Chenhui Zhu, 2021, ACS Catalysis.

Asymmetric catalytic synthesis of P-stereogenic phosphines via a nucleophilic ruthenium phosphido complex.

R. Bergman, F. Toste, I. Stewart, 2006, Journal of the American Chemical Society.

Staphylococcus aureus Peptide Methionine Sulfoxide Reductases Protect from Human Whole-Blood Killing

Eric P. Skaar, William N. Beavers, E. Skaar, 2021, Infection and immunity.

Non-oxidative vanadium-catalyzed C-O bond cleavage: application to degradation of lignin model compounds.

Su-Young Son, F. Toste, F. Toste, 2010, Angewandte Chemie.

An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage

G. Schwaab, M. Havenith, K. Raymond, 2020, Proceedings of the National Academy of Sciences.

Encapsulated water in a supramolecular $Ga_4$$L_6$$^{-12}$ cage is neither ice- nor bulk water-like

G. Schwaab, M. Havenith, K. Raymond, 2020 .

A Re(V)-catalyzed C-N bond-forming route to human lipoxygenase inhibitors.

T. Holman, F. Toste, A. T. Radosevich, 2005, Organic letters.

Deconvoluting the Role of Charge in a Supramolecular Catalyst.

K. Raymond, R. Bergman, F. Toste, 2018, Journal of the American Chemical Society.

Chiral anion-mediated asymmetric ring opening of meso-aziridinium and episulfonium ions.

G. L. Hamilton, F. Toste, Toshio Kanai, 2008, Journal of the American Chemical Society.

Z-selective semihydrogenation of alkynes catalyzed by a cationic vanadium bisimido complex.

F. Toste, H. L. La Pierre, J. Arnold, 2011, Angewandte Chemie.

Investigation of the Early Steps in Electrophilic Bromination through the Study of the Reaction with Sterically

F. Toste, David J Gorin, 2016 .

Gold(I)-catalyzed enantioselective [3+2] and [3+3] cycloaddition reactions of propargyl acetals/ketals.

N. Shapiro, F. Toste, C. Navarro, 2015, Tetrahedron.

Gold(I)-catalyzed enantioselective polycyclization reactions.

F. Toste, T. Mayer, Steven G. Sethofer, 2010, Journal of the American Chemical Society.

Gold-catalyzed [3+3]-annulation of azomethine imines with propargyl esters.

N. Shapiro, F. Toste, Yun Shi, 2009, Journal of the American Chemical Society.

Gold(I)-catalyzed enantioselective ring expansion of allenylcyclopropanols.

F. Toste, F. Kleinbeck, F. Dean Toste, 2009, Journal of the American Chemical Society.

Gold(I)-catalyzed enantioselective synthesis of benzopyrans via rearrangement of allylic oxonium intermediates.

F. Toste, I. D. Watson, M. Uemura, 2009, Journal of the American Chemical Society.

Asymmetric synthesis of medium-sized rings by intramolecular Au(I)-catalyzed cyclopropanation.

F. Toste, I. D. Watson, S. Ritter, 2009, Journal of the American Chemical Society.

Synthesis and structural characterization of isolable phosphine coinage metal π-complexes

N. Shapiro, F. Toste, 2008, Proceedings of the National Academy of Sciences.

Total synthesis of (+)-fawcettimine.

F. Toste, Xin Linghu, J. Kennedy‐Smith, 2007, Angewandte Chemie.

Gold(I)-catalyzed cyclizations of silyl enol ethers: application to the synthesis of (+)-lycopladine A.

F. Toste, S. Staben, B. Corkey, 2006, Angewandte Chemie.

Synthesis of indenyl ethers by gold(I)-catalyzed intramolecular carboalkoxylation of alkynes.

F. Toste, P. Dubé, 2006, Journal of the American Chemical Society.

Gold(I)-catalyzed synthesis of dihydropyrans.

F. Toste, B. Sherry, B. N. Laforteza, 2006, Journal of the American Chemical Society.

Synthesis of aromatic ketones by a transition metal-catalyzed tandem sequence.

Jing Zhao, F. Toste, Colin O. Hughes, 2006, Journal of the American Chemical Society.

Gold(I)-catalyzed stereoselective olefin cyclopropanation.

Magnus J. Johansson, F. Toste, David J Gorin, 2005, Journal of the American Chemical Society.

Catalytic enantioselective Conia-ene reaction.

F. Toste, B. Corkey, 2005, Journal of the American Chemical Society.

Gold(I)-catalyzed intramolecular acetylenic Schmidt reaction.

F. Toste, David J Gorin, N. Davis, 2005, Journal of the American Chemical Society.

Gold(I)-catalyzed ring expansion of cyclopropanols and cyclobutanols.

F. Toste, S. Staben, Jordan P. Markham, 2005, Journal of the American Chemical Society.

Synthesis of 2-cyclopentenones by gold(I)-catalyzed Rautenstrauch rearrangement.

Xiaodong Shi, F. Toste, David J Gorin, 2005, Journal of the American Chemical Society.

Gold(I)-catalyzed 5-endo-dig carbocyclization of acetylenic dicarbonyl compounds.

F. Toste, S. Staben, J. Kennedy‐Smith, 2004, Angewandte Chemie.

Gold(I)-Catalyzed Conia-Ene Reaction of β-Ketoesters with Alkynes

F. Toste, S. Staben, J. Kennedy‐Smith, 2004 .

Regio- and Enantioselective Bromocyclization of Difluoroalkenes as a Strategy to Access Tetrasubstituted Difluoromethylene-Containing Stereocenters.

Jeffrey S Derrick, E. Miller, F. Toste, 2020, Journal of the American Chemical Society.

C-C coupling reactivity of an alkylgold(III) fluoride complex with arylboronic acids.

F. Toste, N. Mankad, Neal P. Mankad, 2010, Journal of the American Chemical Society.

On the Diels-Alder approach to solely biomass-derived polyethylene terephthalate (PET): conversion of 2,5-dimethylfuran and acrolein into p-xylene.

F. Toste, M. Shiramizu, F. Toste, 2011, Chemistry.

Enantioselective α-amination enabled by a BINAM-derived phase-transfer catalyst

Jigar S. Patel, F. Toste, H. Nelson, 2014, Chemical science.

Isolation and Reactivity of Trifluoromethyl Iodonium Salts

Johnathan N. Brantley, F. Toste, Andrew V. Samant, 2016, ACS central science.

Enantioselective halocyclization using reagents tailored for chiral anion phase-transfer catalysis.

J. Wu, F. Toste, Yi‐Ming Wang, 2012, Journal of the American Chemical Society.

Mechanism and Kinetics of Isobutene Formation from Ethanol and Acetone over ZnxZryOz

A. Bell, F. Toste, Julie E. Rorrer, 2019, ACS Catalysis.

Mechanism and Kinetics of Isobutene Formation from Ethanol and Acetone over Zn xZr yO z

A. Bell, F. Toste, Julie E. Rorrer, 2019 .

Ligand-based carbon-nitrogen bond forming reactions of metal dinitrosyl complexes with alkenes and their application to C-H bond functionalization.

Chen Zhao, R. Bergman, Mark R. Crimmin, 2014, Accounts of chemical research.

Enabling New Modes of Reactivity via Constrictive Binding in a Supramolecular-Assembly-Catalyzed Aza-Prins Cyclization.

David M. Kaphan, K. Raymond, R. Bergman, 2015, Journal of the American Chemical Society.

Pd-catalyzed dynamic kinetic enantioselective arylation of silylphosphines.

R. Bergman, F. Toste, V. Chan, 2007, Journal of the American Chemical Society.

ABE Condensation over Monometallic Catalysts: Catalyst Characterization and Kinetics

G. Gunbas, K. Goulas, F. Toste, 2017 .

A Combined DFT, Energy Decomposition, and Data Analysis Approach to Investigate the Relationship Between Noncovalent Interactions and Selectivity in a Flexible DABCOnium/Chiral Anion Catalyst System.

Binh Khanh Mai, Jeffrey S Derrick, P. Liu, 2022, ACS catalysis.

Rearrangement of alkynyl sulfoxides catalyzed by gold(I) complexes.

N. Shapiro, F. Toste, 2007, Journal of the American Chemical Society.

A heterogeneous iridium single-atom-site catalyst for highly regioselective carbenoid O–H bond insertion

Yadong Li, Dingsheng Wang, Juncai Dong, 2021, Nature Catalysis.

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

Robert J. Phipps, Tao Wu, F. Toste, 2014, Chemical reviews.

Enantioselective Oxidative Homocoupling and Cross-Coupling of 2-Naphthols Catalyzed by Chiral Iron Phosphate Complexes.

F. Toste, S. Narute, R. Parnes, 2016, Journal of the American Chemical Society.

Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes

Ying He, F. Toste, R. Thornbury, 2015, Journal of the American Chemical Society.

Asymmetric Fluorination Reactions

E. Miller, F. Toste, 2021 .

Catalytic Enantioselective Fluorination

F. Toste, G. Schäfer, R. Thornbury, 2017 .

Catalytic isomerization of 1,5-enynes to bicyclo[3.1.0]hexenes.

F. Toste, M. Luzung, Jordan P. Markham, 2004, Journal of the American Chemical Society.

SONICATION AND ALUMINUM AMALGAM IN THE LEIMGRUBER-BATCHO REACTION : AN IMPROVED PREPARATION OF 6-AMINOINDOLE

F. Toste, I. V. Still, 1995 .

A New Route to the Synthesis of the Naturally Occurring Benzopentathiepin Varacin

F. Toste, I. V. Still, 1995 .

A Versatile Procedure for the Preparation of Aryl Thiocyanates Using N-Thiocyanatosuccinimide (NTS)

F. Toste, I. V. Still, V. D. Stefano, 1995 .

Cooperative Stereoinduction in Asymmetric Photocatalysis.

I. Guzei, F. Toste, T. Yoon, 2022, Journal of the American Chemical Society.

Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration.

Scott J. Miller, Jolene P. Reid, Junqi Li, 2019, Journal of the American Chemical Society.

Enantiodivergent Fluorination of Allylic Alcohols: Data Set Design Reveals Structural Interplay between Achiral Directing Group and Chiral Anion.

Andrew J. Neel, Anat Milo, Matthew S Sigman, 2016, Journal of the American Chemical Society.

Enantioselective Synthesis of γ-Hydroxyenones by Chiral Base-Catalyzed Kornblum DeLaMare Rearrangement

F. Toste, S. Staben, Xin Linghu, 2006 .

Enantioselective Synthesis of Fluoro-Dihydroquinazolones and -Benzooxazinones by Fluorination-Initiated Asymmetric Cyclization Reactions.

F. Toste, K. Hiramatsu, V. Rauniyar, 2016, ACS catalysis.

Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters Using Molecular Oxygen as Stoichiometric Oxidant.

F. Toste, A. T. Radosevich, Christine Musich, 2005 .

Vanadium-catalyzed asymmetric oxidation of alpha-hydroxy esters using molecular oxygen as stoichiometric oxidant.

F. Toste, A. T. Radosevich, Christine Musich, 2005, Journal of the American Chemical Society.

A NEW PALLADIUM-CATALYZED ADDITION : A MILD METHOD FOR THE SYNTHESIS OF COUMARINS

B. Trost, F. Toste, B. M. T. and, 1996 .

Tandem Cycloisomerization/Suzuki Coupling of Arylethynyl MIDA Boronates.

F. Toste, G. Amarante, Julian M. W. Chan, 2011, Tetrahedron.

Rhenium(V)-Catalyzed Synthesis of 2-Deoxy-α-glycosides

F. Toste, B. Sherry, Rebecca N. Loy, 2004 .

Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and Enantioselective Lactonization Reactions.

Son C. Nguyen, A. P. Alivisatos, G. Somorjai, 2015, Journal of the American Chemical Society.

Gold catalysis for organic synthesis

F Dean Toste, F. Toste, 2011, Beilstein journal of organic chemistry.

Phosphine-catalyzed hydration and hydroalkoxylation of activated olefins: use of a strong nucleophile to generate a strong base.

Ian C. Stewart, R. Bergman, F. Toste, 2003, Journal of the American Chemical Society.

Enantioselective synthesis of cyclic carbamimidates via a three-component reaction of imines, terminal alkynes, and p-toluenesulfonylisocyanate using a monophosphine gold(I) catalyst().

F. Toste, M. Campbell, 2011, Chemical science.

Sodium Tetrachloroaurate(III)

F. Toste, B. Sherry, S. Westcott, 2006 .

Gold(I)-catalyzed enantioselective carboalkoxylation of alkynes.

F. Toste, W. Zi, 2013, Journal of the American Chemical Society.

A Catalytic Enantioselective Approach to Chromans and Chromanols. A Total Synthesis of (−)-Calanolides A and B and the Vitamin E Nucleus

B. Trost, F. Toste, B. M. T. and, 1998 .

A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization.

William R. Dichtel, S. Denmark, W. Dichtel, 2019, Journal of the American Chemical Society.

Atom economy. Palladium-catalyzed formation of coumarins by addition of phenols and alkynoates via a net C-H insertion.

B. Trost, F. Toste, Kevin Greenman, 2003, Journal of the American Chemical Society.

Rhenium(V)-catalyzed synthesis of 2-deoxy-alpha-glycosides.

F. Toste, B. Sherry, Rebecca N. Loy, 2004, Journal of the American Chemical Society.

Au(I)-catalyzed ring expanding cycloisomerizations: total synthesis of ventricosene.

N. Shapiro, F. Toste, S. Staben, 2008, Organic letters.

Foundations and strategies of the construction of hybrid catalysts for optimized performances

Rong Ye, Jie Zhao, Gabor A. Somorjai, 2018, Nature Catalysis.

Enantioselective reduction of ketones and imines catalyzed by (CN-box)Re(V)-oxo complexes.

Yusuke Kobayashi, Richard W. Ahn, F. Toste, 2010, Chemistry.

Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex.

Richard W. Ahn, F. Toste, K. Nolin, 2005, Journal of the American Chemical Society.

Rhenium-catalyzed coupling of propargyl alcohols and allyl silanes.

F. Toste, M. Luzung, 2003, Journal of the American Chemical Society.

Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles.

G. Somorjai, J. Kuhn, Chia‐Kuang Tsung, 2011, Nature chemistry.

Non-metathesis ruthenium-catalyzed C-C bond formation.

B. Trost, A. Pinkerton, F. Toste, 2001, Chemical reviews.

Divergent enantioselective synthesis of (-)-galanthamine and (-)-morphine.

B. Trost, Weiping Tang, F. Toste, 2005, Journal of the American Chemical Society.

Gold(I)-catalyzed propargyl Claisen rearrangement.

F. Toste, B. Sherry, 2004, Journal of the American Chemical Society.

A Powerful Chiral Counterion Strategy for Asymmetric Transition Metal Catalysis

G. L. Hamilton, F. Toste, M. Mba, 2007, Science.

Stable Gold(III) Catalysts by Oxidative Addition of a Carbon-Carbon Bond

C. Jacobsen, F. Toste, Chung-Yeh Wu, 2014, Nature.

Gold(I)-catalyzed [2 + 2]-cycloaddition of allenenes.

F. Toste, P. Mauleón, M. Luzung, 2007, Journal of the American Chemical Society.

Gold‐Catalyzed Reactions of Propargyl Esters, Propargyl Alcohols, and Related Compounds

F. Toste, P. Mauleón, 2012 .

Catalytic enantioselective carbon-carbon bond formation using cycloisomerization reactions

F. Toste, I. D. Watson, 2012 .

Gold(I)-catalyzed enantioselective synthesis of pyrazolidines, isoxazolidines, and tetrahydrooxazines.

F. Toste, M. Mba, Z. J. Wang, 2010, Angewandte Chemie.

Gold Catalysed Redox Synthesis of Imidazo[1,2-a]pyridine using Pyridine N-Oxide and Alkynes.

E. Talbot, F. Toste, M. Richardson, 2014, Advanced synthesis & catalysis.

Regio- and enantioselective hydroamination of dienes by gold(I)/menthol cooperative catalysis.

F. Toste, Z. J. Wang, O. Kanno, 2011, Angewandte Chemie.

Palladium-catalyzed enantioselective cyclization of silyloxy-1,6-enynes.

F. Toste, B. Corkey, 2007, Journal of the American Chemical Society.

A bonding model for gold(I) carbene complexes

W. Goddard, N. Shapiro, F. Toste, 2009, Nature chemistry.

Enantioselective Total Synthesis of (−)-Galanthamine

B. Trost, F. Toste, B. M. T. and, 2000 .

Gold(I)-catalyzed diastereo- and enantioselective 1,3-dipolar cycloaddition and Mannich reactions of azlactones.

F. Toste, G. Amarante, Z. J. Wang, 2011, Journal of the American Chemical Society.

Au(I)-catalyzed enantioselective 1,3-dipolar cycloadditions of münchnones with electron-deficient alkenes.

F. Toste, Asa D. Melhado, M. Luparia, 2007, Journal of the American Chemical Society.

Synthesis of flinderoles B and C by a gold-catalyzed allene hydroarylation().

F. Toste, R. M. Zeldin, Rachel M. Zeldin, 2011, Chemical science.

Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors

R. Bergman, F. Toste, A. DiPasquale, 2014, Organometallics.

Gold-catalyzed allylation of aryl boronic acids: accessing cross-coupling reactivity with gold.

F. Toste, M. Levin, F. Toste, 2014, Angewandte Chemie.

A Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic Reactions.

N. Shapiro, F. Toste, 2010, Synlett : accounts and rapid communications in synthetic organic chemistry.

Gold(I)-catalyzed enantioselective intramolecular hydroamination of allenes.

F. Toste, B. Sherry, E. Kang, 2007, Journal of the American Chemical Society.

Revisiting the Bonding Model for Gold(I) Species: The Importance of Pauli Repulsion Revealed in a Gold(I)-Cyclobutadiene Complex.

M. Head‐Gordon, F. Toste, Z. R. Wong, 2022, Angewandte Chemie.

Preparation and reactivity of terminal gold(I) amides and phosphides

R. Bergman, F. Toste, Sophia L Shevick, 2013 .

Modern gold catalyzed synthesis

A. Hashmi, F. Toste, D. Toste, 2012 .

Uncovering Subtle Ligand Effects of Phosphines Using Gold(I) Catalysis.

Matthew S Sigman, F Dean Toste, F. Toste, 2017, ACS catalysis.

Asymmetric cross-dehydrogenative coupling enabled by the design and application of chiral triazole-containing phosphoric acids.

Andrew J. Neel, F. Toste, Andrew J Neel, 2013, Journal of the American Chemical Society.

Palladium catalyzed kinetic and dynamic kinetic asymmetric transformations of gamma-acyloxybutenolides. Enantioselective total synthesis of (+)-Aflatoxin B1 and B2a.

B. Trost, F. Toste, 2003, Journal of the American Chemical Society.

A New Palladium-Catalyzed Addition: A Mild Method for the Synthesis of Coumarins.

B. Trost, F. Toste, 1996 .

Living ring-opening polymerization of N-sulfonylaziridines: synthesis of high molecular weight linear polyamines.

R. Bergman, Cameron C. Lee, F. Toste, 2005, Journal of the American Chemical Society.

Synthesis of azepines by a gold-catalyzed intermolecular [4 + 3]-annulation.

N. Shapiro, F. Toste, 2008, Journal of the American Chemical Society.

Deracemization of Baylis−Hillman Adducts

B. Trost, F. Toste, and Hon-Chung Tsui, 2000 .

Analysis of an unprecedented mechanism for the catalytic hydrosilylation of carbonyl compounds.

Michael D. Pluth, R. Bergman, F. Toste, 2007, Journal of the American Chemical Society.

Reversing the Role of the Metal−Oxygen π-Bond. Chemoselective Catalytic Reductions with a Rhenium(V)-Dioxo Complex

F. Toste, J. Kennedy‐Smith, H. P. Gunterman, 2003 .

Asymmetric Catalytic Synthesis of P‐Stereogenic Phosphines via a Nucleophilic Ruthenium Phosphido Complex.

R. Bergman, F. Toste, I. Stewart, 2006 .

Production of Fuels and Chemicals from Biomass: Condensation Reactions and Beyond

F. Dean Toste, Lipeng Wu, Takahiko Moteki, 2016 .

Asymmetric O- and C-Alkylation of Phenols

B. Trost, F. Toste, B. M. T. and, 1998 .

Gold(I)-catalyzed regioselective cyclizations of silyl ketene amides and carbamates with alkynes.

Hong C Shen, F. Toste, S. Colletti, 2007, The Journal of organic chemistry.

Regio- and Enantioselective Allylic Alkylation of an Unsymmetrical Substrate: A Working Model

F. Toste, B. M. T. and, 1999 .

Gold(I)-catalyzed enantioselective [4 + 2]-cycloaddition of allene-dienes.

F. Toste, A. Z. González, Ana Z. González, 2010, Organic letters.

Rhenium-catalyzed aromatic propargylation.

F. Toste, J. Kennedy‐Smith, L. Young, 2004, Organic letters.

Gold(I)-catalyzed enantioselective bromocyclization reactions of allenes

F. Toste, D. Miles, Marcos Veguillas, 2013 .

Chiral Brønsted acid from a cationic gold(I) complex: catalytic enantioselective protonation of silyl enol ethers of ketones.

F. Toste, C. Cheon, O. Kanno, 2011, Journal of the American Chemical Society.

Hydroalkoxylation catalyzed by a gold(I) complex encapsulated in a supramolecular host.

Z Jane Wang, F Dean Toste, K. Raymond, 2011, Journal of the American Chemical Society.

Phosphoramidite gold(I)-catalyzed diastereo- and enantioselective synthesis of 3,4-substituted pyrrolidines.

W. Goddard, F. Toste, A. Z. González, 2011, Journal of the American Chemical Society.

Modern Gold Catalyzed Synthesis: TOSTE:GOLD_SYNTHESIS O-BK

A. Hashmi, F. Toste, 2012 .

Enantioselective Gold-Catalyzed Synthesis of Heterocyclic Compounds

F. Toste, D. Miles, 2015 .

Enantioselective Synthesis of Cyclic Carbamimidates via a Three-Component Reaction of Imines, Terminal Alkynes, and p-Toluenesulfonylisocyanate Using a Monophosphine Gold(I) Catalyst.

F. Toste, M. Campbell, 2011 .

Palladium-Catalyzed Kinetic and Dynamic Kinetic Asymmetric Transformation of 5-Acyloxy-2-(5H)-furanone. Enantioselective Synthesis of (−)-Aflatoxin B Lactone

B. Trost, F. Toste, B. M. T. and, 1999 .

A Two-Component Catalyst System for Asymmetric Allylic Alkylations with Alcohol Pronucleophiles

B. Trost, F. Toste, Andrew McEachern, 1998 .

A supramolecular approach to combining enzymatic and transition metal catalysis

Z Jane Wang, F Dean Toste, K. Raymond, 2013, Nature Chemistry.

Synthesis of [RuCl2(NO)2(THF)] and its double C-N bond-forming reactions with alkenes.

R. Bergman, Mark R. Crimmin, F. Toste, 2011, Angewandte Chemie.

Synthesis of 1,1-disubstituted alkenes via a Ru-catalyzed addition.

B. Trost, A. Pinkerton, F. Toste, 2001, Journal of the American Chemical Society.

A new Ru catalyst for alkenealkyne coupling

B. Trost, F. Toste, 1999 .

Synthesis of coumarins by ring-closing metathesis

R. Grubbs, S. Goldberg, F. Toste, 2003 .

Beyond Allylic Alkylation: Applications of Trost Chemistry in Complex Molecule Synthesis

F. Toste, Christopher A. Kalnmals, J. Tracy, 2021, Israel Journal of Chemistry.

Gold catalysis : an homogeneous approach

F. Toste, V. Michelet, 2014 .

Synthesis of benzonorcaradienes by gold(I)-catalyzed [4+3] annulation.

F. Toste, David J Gorin, P. Dubé, 2006, Journal of the American Chemical Society.

Asymmetric addition of α-branched cyclic ketones to allenamides catalyzed by a chiral phosphoric acid

F. Toste, Xiaoyu Yang, 2016, Chemical science.

Gold(I)-catalyzed dearomative Rautenstrauch rearrangement: enantioselective access to cyclopenta[b]indoles.

F. Toste, W. Zi, Hongmiao Wu, 2015, Journal of the American Chemical Society.

Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis.

F. Dean Toste, Matthew S. Sigman, Scott J. Miller, 2017, Accounts of chemical research.

Redox-based reagents for chemoselective methionine bioconjugation

F Dean Toste, Christopher J Chang, Shixian Lin, 2017, Science.

Exploiting non-covalent π interactions for catalyst design

F. Dean Toste, Andrew J. Neel, Matthew S. Sigman, 2017, Nature.

Enantioselective Palladium-Catalyzed Oxidative β,β-Fluoroarylation of α,β-Unsaturated Carbonyl Derivatives.

C. del Pozo, F. Toste, S. Fustero, 2016, Angewandte Chemie.

Functional group diversity by ruthenium-catalyzed olefin cross-metathesis

R. Grubbs, A. Chatterjee, F. Toste, 2002 .

A data-intensive approach to mechanistic elucidation applied to chiral anion catalysis

F. Dean Toste, Andrew J. Neel, Anat Milo, 2015, Science.

Chiral amide directed assembly of a diastereo- and enantiopure supramolecular host and its application to enantioselective catalysis of neutral substrates.

Chen Zhao, F Dean Toste, Chen Zhao, 2013, Journal of the American Chemical Society.

Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives.

R. Bergman, F. Toste, N. Mankad, 2014, Angewandte Chemie.

Integration of chemical catalysis with extractive fermentation to produce fuels

F. Dean Toste, Elad Gross, Harvey W. Blanch, 2012, Nature.

Organometallic chemistry: Charting the course of catalysis

G. L. Hamilton, F. Toste, 2009, Nature.

Enantioselective Intramolecular Allylic Substitution via Synergistic Palladium/Chiral Phosphoric Acid Catalysis: Insight into Stereoinduction through Statistical Modeling.

Tao Wu, F. Toste, Buyun Chen, 2020, Angewandte Chemie.

Chiral Diaryliodonium Phosphate Enables Light Driven Diastereoselective α-C(sp3)-H Acetalization.

K. Zhao, F. Toste, Jie Zhao, 2018, Journal of the American Chemical Society.

Ruthenium-Catalyzed Cycloisomerization of 1,6-Enynes Initiated by C−H Activation

B. Trost, F. Toste, B. M. T. and, 1999 .

Biomimetic Approach to the Catalytic Enantioselective Synthesis of Flavonoids.

Ying He, F. Toste, Zhenyu Yang, 2016, Journal of the American Chemical Society.

Asymmetric Additions to Dienes Catalyzed by a Dithiophosphoric Acid

G. L. Hamilton, J. Wu, N. Shapiro, 2011, Nature.

Harnessing Noncovalent Interactions in Dual-Catalytic Enantioselective Heck-Matsuda Arylation.

R. B. Sunoj, F. Toste, Yernaidu Reddi, 2019, Journal of the American Chemical Society.

Enantioselective Heck-Matsuda Arylations through Chiral Anion Phase-Transfer of Aryl Diazonium Salts.

R. B. Sunoj, Jigar S. Patel, M. Saito, 2017, Angewandte Chemie.

Synthesis of (-)-octalactin a by a strategic vanadium-catalyzed oxidative kinetic resolution.

F. Toste, A. T. Radosevich, Hui‐Wen Shih, 2008, Angewandte Chemie.

Enantioselective 1,1-arylborylation of alkenes: merging chiral anion phase transfer with Pd catalysis.

Brett D. Williams, F. Toste, B. D. Williams, 2015, Journal of the American Chemical Society.

Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement.

Guigen Li, Hongjian Lu, F. Toste, 2015, Angewandte Chemie.

Gold(I)-catalyzed synthesis of functionalized cyclopentadienes.

Jun Hee Lee, F. Toste, Jun Hee Lee, 2007, Angewandte Chemie.

Supramolecular Ga4L6(12-) Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer.

R. Mathies, K. Raymond, R. Bergman, 2015, Journal of the American Chemical Society.

The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations† †Electronic supplementary information (ESI) available: Kinetics plots are available free of charge. See DOI: 10.1039/c4sc02735c Click here for additional data file.

Chen Zhao, K. Raymond, R. Bergman, 2014, Chemical science.

Carbon monoxide, isocyanide, and nitrile complexes of cationic, d(0) vanadium bisimides: π-back bonding derived from the π symmetry, bonding metal bisimido ligand orbitals.

R. Bergman, F. Toste, H. L. La Pierre, 2012, Inorganic chemistry.

A mild C-O bond formation catalyzed by a rhenium-oxo complex.

F. Toste, B. Sherry, A. T. Radosevich, 2003, Journal of the American Chemical Society.

Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis.

David M. Kaphan, K. Raymond, R. Bergman, 2016, Journal of the American Chemical Society.

Cobalt-mediated [3 + 2]-annulation reaction of alkenes with alpha,beta-unsaturated ketones and imines.

J. Schomaker, R. Bergman, F. Toste, 2009, Organic letters.

Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins.

Ian C. Stewart, J. Schomaker, R. Bergman, 2008, Journal of the American Chemical Society.

Synthesis of the First (1‐3:6,7‐η‐Cyclodecadienyl)ruthenium Complex by the Intramolecular Reaction of an Alkene and a Vinylcyclopropane

B. Trost, F. Toste, 2001 .

Backbone-Photodegradable Polymers by Incorporating Acylsilane Monomers via Ring-Opening Metathesis Polymerization.

F. Toste, Mufeng Wei, Banruo Huang, 2021, Journal of the American Chemical Society.

Synergistic Effects in Bimetallic Palladium-Copper Catalysts Improve Selectivity in Oxygenate Coupling Reactions.

L. Grabow, G. Gunbas, K. Goulas, 2016, Journal of the American Chemical Society.

Zirconium-Redox-Shuttled Cross-Electrophile Coupling of Aromatic and Heteroaromatic Halides.

P. Liu, Yue Fu, F. Toste, 2021, Chem.

A combination of directing groups and chiral anion phase-transfer catalysis for enantioselective fluorination of alkenes

Robert J. Phipps, J. Wu, F. Dean Toste, 2013, Proceedings of the National Academy of Sciences.

A Catalytic Enantioselective Approach to Chromans and Chromanols. A Total Synthesis of (‐)‐Calanolides A (IX) and B (VIII) and the Vitamin E Nucleus (XIII).

B. Trost, F. Toste, 1999 .

Nucleophilic substitution catalyzed by a supramolecular cavity proceeds with retention of absolute stereochemistry.

Chen Zhao, F Dean Toste, Chen Zhao, 2014, Journal of the American Chemical Society.

Ruthenium-catalyzed enyne cycloisomerizations. Effect of allylic silyl ether on regioselectivity.

B. Trost, F. Toste, J. Surivet, 2004, Journal of the American Chemical Society.

Controlled Single-Electron Transfer via Metal-Ligand Cooperativity Drives Divergent Nickel-Electrocatalyzed Radical Pathways.

Jeffrey S Derrick, M. Head‐Gordon, F. Toste, 2021, Journal of the American Chemical Society.

Photo-Brook rearrangement of acyl silanes as a strategy for photoaffinity probe design

John A. Tallarico, M. Schirle, J. Tallarico, 2022, Chemical science.

Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates.

Eiji Yamamoto, F. Dean Toste, Matthew S. Sigman, 2017, Journal of the American Chemical Society.

directing groups anion phase-transfer catalysis for enantioselective fluorination of alkenes.

Robert J. Phipps, F. Toste, Yi‐Ming Wang, 2013 .

Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.

Leo A. Joyce, F. Toste, M. Sigman, 2017, Journal of the American Chemical Society.

Ruthenium-Catalyzed Cycloisomerizations of 1,6- and 1,7-Enynes

F. Toste, B. M. T. and, 2000 .

A SIMPLE METHOD FOR THE SELECTIVE MOM PROTECTION OF THIOLS

F. Toste, I. V. Still, 1995 .

A Nanovessel-Catalyzed Three-Component Aza-Darzens Reaction.

K. Raymond, R. Bergman, F. Toste, 2020, Journal of the American Chemical Society.

Production of renewable lubricants via self-condensation of methyl ketones

A. Bell, F. Toste, A. Gokhale, 2016 .

Vanadium bisimide bonding investigated by X-ray crystallography, 51V and 13C nuclear magnetic resonance spectroscopy, and V L(3,2)-edge X-ray absorption near-edge structure spectroscopy.

T. Tyliszczak, D. Shuh, R. Bergman, 2013, Inorganic chemistry.

Phosphonium Formation by Facile Carbon-Phosphorus Reductive Elimination from Gold(III).

W. J. Wolf, Matthew S. Winston, F. Toste, 2016, Journal of the American Chemical Society.

Cluster Preface: Gold Catalysisfor Organic Synthesis: Opportunities Abound

F. Toste, 2012 .

Gold Catalysis – Steadily Increasing in Importance

A. Hashmi, A. Echavarren, F. Toste, 2016 .

A supramolecular microenvironment strategy for transition metal catalysis

David M. Kaphan, Robert G. Bergman, F. Dean Toste, 2015, Science.

Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts.

K. Raymond, R. Bergman, F. Toste, 2018, Accounts of chemical research.

Homogeneous Gold Redox Chemistry: Organometallics, Catalysis, and Beyond.

F. Toste, Mingyou Hu, Banruo Huang, 2020, Trends in chemistry.

A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length.

K. Raymond, R. Bergman, F. Toste, 2019, Journal of the American Chemical Society.

Conformational Selection as the Mechanism of Guest Binding in a Flexible Supramolecular Host.

David M. Kaphan, K. Raymond, R. Bergman, 2017, Journal of the American Chemical Society.

Selective monoterpene-like cyclization reactions achieved by water exclusion from reactive intermediates in a supramolecular catalyst.

F Dean Toste, K. Raymond, R. Bergman, 2012, Journal of the American Chemical Society.

Halide-Dependent Mechanisms of Reductive Elimination from Gold(III)

W. J. Wolf, Matthew S. Winston, F. Toste, 2015, Journal of the American Chemical Society.

C(sp(3))-F reductive elimination from alkylgold(iii) fluoride complexes.

F. Toste, N. Mankad, Neal P. Mankad, 2012, Chemical science.

A Ruthenium-Catalyzed Hydrative Cyclization and [4 + 2] Cycloaddition of Yne-enones

B. Trost, F. Toste, A. R. Brown, 2000 .

Impact of Host Flexibility on Selectivity in a Supramolecular Host-Catalyzed Enantioselective aza-Darzens Reaction.

K. Raymond, Nicholas S. Settineri, R. Bergman, 2022, Journal of the American Chemical Society.

[(TMEDA)Co(NO)2][BPh4]: A versatile synthetic entry point to four and five coordinate {Co(NO)2}10 complexes

K. Wieghardt, R. Bergman, Mark R. Crimmin, 2011 .

Fluorenes and styrenes by Au(I)-catalyzed annulation of enynes and alkynes.

F. Toste, David J Gorin, I. D. Watson, 2008, Journal of the American Chemical Society.

Title Correction : Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment

Corinne D. Scown, Alexis T. Bell, F. Dean Toste, 2015 .

Combining microbial production with chemical upgrading.

Jamie H. D. Cate, F Dean Toste, A. Ball, 2016, Current opinion in biotechnology.

Strong Metal-Adsorbate Interactions Increase the Reactivity and Decrease the Orientational Order of OH-functionalized N-Heterocyclic Carbene Monolayers.

A. Verdini, A. Cossaro, F. Toste, 2019, Langmuir : the ACS journal of surfaces and colloids.

A New Route to the Synthesis of the Naturally Occurring Benzopentathiepin Varacin.

F. Toste, I. V. Still, 1995 .

Site-Independent Hydrogenation Reactions on Oxide-Supported Au Nanoparticles Facilitated by Intraparticle Hydrogen Atom Diffusion

Lillian V. A. Hale, M. Noked, Reut Yemini, 2021, ACS catalysis.

Direct Michael addition of alkenes via a cobalt-dinitrosyl mediated vinylic C-H functionalization reaction.

Chen Zhao, R. Bergman, F. Toste, 2011, Journal of the American Chemical Society.

Cobalt-mediated, enantioselective synthesis of C(2) and C(1) dienes.

J. Schomaker, R. Bergman, Mark R. Crimmin, 2010, Journal of the American Chemical Society.

Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin

Š. Bauer, Kun Wang, F. Toste, 2013 .

CO2 reduction on pure Cu produces only H2 after subsurface O is depleted: Theory and experiment

F. Toma, W. Goddard, F. Toste, 2021, Proceedings of the National Academy of Sciences.

Preparation of t-butyl sulfides by a novel ligand-transfer reaction of aryl thiocyanates

F. Toste, I. V. Still, 1995 .

Ruthenium-catalyzed enyne cycloisomerizations. Effect of allylic silyl ether on regioselectivity.

B. Trost, F. Toste, J. Surivet, 2004, Journal of the American Chemical Society.

The development and mechanistic investigation of a palladium-catalyzed 1,3-aryl ﬂ uorination of chromenes †

E. Talbot, F. Toste, M. Sigman, 2017 .

Enantioselective Kinetic Resolution/Desymmetrization of Para-Quinols: A Case Study in Boronic-Acid-Directed Phosphoric Acid Catalysis.

Ying He, R. Bergman, F. Toste, 2019, Advanced synthesis & catalysis.

Chiral Diaryliodonium Phosphate Enables Light Driven Diastereoselective α-C(sp3)-H Acetalization.

K. Zhao, F. Toste, Jie Zhao, 2018, Journal of the American Chemical Society.

Ruthenium‐Catalyzed Olefin Cross Metathesis of Styrenes as an Alternative to the Heck and Cross‐Coupling Reactions

R. Grubbs, A. Chatterjee, F. Toste, 2002 .

Ruthenium-Catalyzed Olefin Cross Metathesis of Styrenes as an Alternative to the Heck and Cross-Coupling Reactions.

R. Grubbs, A. Chatterjee, F. Toste, 2010 .

An Activity-Based Oxaziridine Platform for Identifying and Developing Covalent Ligands for Functional Allosteric Methionine Sites: Redox-Dependent Inhibition of Cyclin-Dependent Kinase 4.

Richard A. Lewis, John A. Tallarico, M. Schirle, 2022, Journal of the American Chemical Society.

Profiling the Proteome-Wide Selectivity of Diverse Electrophiles

A. Nesvizhskii, Kathrin Lang, Fengchao Yu, 2021 .

An Activity-Based Methionine Bioconjugation Approach To Developing Proximity-Activated Imaging Reporters

Evan W. Miller, Lakshmi Krishnamoorthy, F. Toste, 2019, ACS central science.

Systematic identification of engineered methionines and oxaziridines for efficient, stable, and site-specific antibody bioconjugation

B. Hann, F. Toste, V. Steri, 2019, Proceedings of the National Academy of Sciences.

Reduction of Aryl Thiocyanates with SmI(2) and Pd-Catalyzed Coupling with Aryl Halides as a Route to Mixed Aryl Sulfides.

F. Toste, I. V. Still, 1996, Journal of Organic Chemistry.

Reduction of Aryl Thiocyanates with SmI2 and Pd-Catalyzed Coupling with Aryl Halides as a Route to Mixed Aryl Sulfides.

F. Toste, I. V. Still, 1997 .

Chiral anion phase transfer of aryldiazonium cations: an enantioselective synthesis of C3-diazenated pyrroloindolines.

Jigar S. Patel, F. Toste, H. Nelson, 2014, Angewandte Chemie.

Development of high-voltage bipolar redox-active organic molecules through the electronic coupling of catholyte and anolyte structures

F. Toste, V. A. Roytman, Jacob S. Tracy, 2022, Chemical science.

Production of an acetone-butanol-ethanol mixture from Clostridium acetobutylicum and its conversion to high-value biofuels

H. Blanch, D. Clark, G. Gunbas, 2015, Nature Protocols.

Asymmetric Electrophilic Fluorination Using an Anionic Chiral Phase-Transfer Catalyst

G. L. Hamilton, F. Toste, A. D. Lackner, 2011, Science.

In situ IR and X-ray high spatial-resolution microspectroscopy measurements of multistep organic transformation in flow microreactor catalyzed by Au nanoclusters.

H. Bechtel, G. Somorjai, Michael C. Martin, 2014, Journal of the American Chemical Society.

Chemocatalytic upgrading of tailored fermentation products toward biodiesel.

Harvey W Blanch, Elad Gross, Gorkem Gunbas, 2014, ChemSusChem.

Preparation of 6,12-Imino-6H,12H-dibenzo[b,f]-1,5-dithiocins.

A. Lough, F. Toste, I. V. Still, 1995 .

A versatile synthetic route to 1,5-dithiocins from o-mercapto aromatic aldehydes

F. Toste, I. V. Still, Rosanne Natividad-Preyra, 1999 .

Enantioselective Synthesis of γ‐Hydroxyenones by Chiral Base‐Catalyzed Kornblum DeLaMare Rearrangement.

F. Toste, S. Staben, Xin Linghu, 2007 .

Electrocatalysis at Organic-Metal Interfaces: Identification of Structure-Reactivity Relationships for CO2 Reduction at Modified Cu Surfaces.

F. Toma, W. Goddard, F. Toste, 2019, Journal of the American Chemical Society.

Chiral Broensted Acid from a Cationic Gold(I) Complex: Catalytic Enantioselective Protonation of Silyl Enol Ethers of Ketones.

F. Toste, C. Cheon, O. Kanno, 2012 .

Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis.

Matthew S Sigman, F Dean Toste, F. Toste, 2017, Journal of the American Chemical Society.

Selectivity tuning over monometallic and bimetallic dehydrogenation catalysts: effects of support and particle size

L. Grabow, K. Goulas, Yuying Song, 2018 .

Migratory Insertion of Carbenes into Au(III)–C Bonds

Ilia J. Kobylianskii, F. Toste, A. Zhukhovitskiy, 2017, Journal of the American Chemical Society.

Ligand Effects in Homogeneous Au Catalysis

F. Toste, David J Gorin, B. Sherry, 2008 .

Metal Nanoparticles Catalyzed Selective Carbon-Carbon Bond Activation in the Liquid Phase.

G. Somorjai, Bing Yuan, F. Toste, 2016, Journal of the American Chemical Society.

Back Cover: Highly Selective Condensation of Biomass‐Derived Methyl Ketones as a Source of Aviation Fuel (ChemSusChem 10/2015)

Eric R. Sacia, A. Bell, Matthew Deaner, 2015 .

Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes.

F. Toste, P. T. Bohan, Patrick T. Bohan, 2017, Journal of the American Chemical Society.

Triphenylphosphinegold(I) chloride

F. Toste, David J Gorin, B. Sherry, 2008 .

Modification of Cysteine-Substituted Antibodies Using Enzymatic Oxidative Coupling Reactions.

M. Francis, J. Flygare, F. Toste, 2023, Bioconjugate chemistry.

Rauniyar Phase-Transfer Catalyst Asymmetric Electrophilic Fluorination Using an Anionic Chiral

G. L. Hamilton, F. Toste, A. D. Lackner, 2011 .

Upgrading Lignocellulosic Products to Drop-In Biofuels via Dehydrogenative Cross-Coupling and Hydrodeoxygenation Sequence.

A. Bell, C. Scown, G. Gunbas, 2015, ChemSusChem.

Co‐production of acetone and ethanol with molar ratio control enables production of improved gasoline or jet fuel blends

H. Blanch, D. Clark, S. Bormann, 2016, Biotechnology and bioengineering.

Using silyl protecting group to enable post-deposition C-C coupling reactions of alkyne-functionalized N-heterocyclic carbene monolayers on Au surfaces.

F. Toste, E. Gross, I. Berg, 2021, Chemical communications.

A Mild C—O Bond Formation Catalyzed by a Rhenium-Oxo Complex.

F. Toste, B. Sherry, A. T. Radosevich, 2003 .

Synthesis of 1,1-disubstituted alkenes via a Ru-catalyzed addition.

B. Trost, A. Pinkerton, F. Toste, 2001, Journal of the American Chemical Society.

Palladium‐Catalyzed Defluorinative Coupling of 1‐Aryl‐2,2‐difluoroalkenes and Boronic Acids: Stereoselective Synthesis of Monofluorostilbenes.

F. Toste, R. Thornbury, 2016 .

N‐Heterocyclic Carbene Based Nanolayer for Copper Film Oxidation Mitigation

F. Toste, E. Gross, Einav Amit, 2022, Angewandte Chemie.

Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc02223b

F. Toste, Margaret J. Hilton, M. Sigman, 2018, Chemical science.

Erich Hückel Prize: H.-J. Werner / Hermann Staudinger Prize: B. Voit / Alfred Stock Memorial Prize: C. Limberg / Janssen Prize for Creativity in Organic Synthesis: F. D. Toste / 20th Volumes and Anniversaries of EurJIC and EurJOC.

H. Werner, F. Toste, C. Limberg, 2018, Angewandte Chemie.

Indolo[2,3-b]quinoxaline as a Low Reduction Potential and High Stability Anolyte Scaffold for Nonaqueous Redox Flow Batteries

M. Head‐Gordon, B. Helms, M. Sanford, 2023, Journal of the American Chemical Society.

Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis.

F. Toste, Margaret J. Hilton, M. Sigman, 2017, Journal of the American Chemical Society.

Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.

F. Toste, M. Sigman, Zachary L. Niemeyer, 2017, Journal of the American Chemical Society.

Data Science-Enabled Palladium-Catalyzed Enantioselective Aryl-Carbonylation of Sulfonimidamides.

F. Gosselin, F. Toste, M. Sigman, 2023, Journal of the American Chemical Society.

Data Science Enables the Development of a New Class of Chiral Phosphoric Acid Catalysts.

F. Toste, M. Sigman, René Rahimoff, 2023, Chem.

Supramolecular catalysis in metal-ligand cluster hosts.

K. Raymond, R. Bergman, F. Toste, 2015, Chemical reviews.

Modern Approaches for Asymmetric Construction of Carbon-Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs.

M. Sodeoka, F. Toste, Jianlin Han, 2018, Chemical reviews.

Gold-catalyzed intramolecular aminoarylation of alkenes: C-C bond formation through bimolecular reductive elimination.

W. Goddard, F. Toste, H. P. Shunatona, 2010, Angewandte Chemie.

A supramolecular microenvironment strategy for transition metal catalysis

David M. Kaphan, K. Raymond, R. Bergman, 2015, Science.

Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts.

K. Raymond, R. Bergman, F. Toste, 2018, Accounts of chemical research.

The Interface is a Tunable Dimension in Electricity-Driven Organic Synthesis

Anna Wuttig, Dean Toste, F. Toste, 2021, Natural Sciences.

Two metals are better than one in the gold catalyzed oxidative heteroarylation of alkenes.

F. Toste, Neal P. Mankad, D. Benítez, 2011, Journal of the American Chemical Society.

Multidimensional Correlations in Asymmetric Catalysis through Parameterization of Uncatalyzed Transition States.

F. Toste, M. Sigman, M. Orlandi, 2017, Angewandte Chemie.

Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics.

F. Toste, T. Bender, Mariko Morimoto, 2019, Journal of the American Chemical Society.

Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles.

G. Somorjai, Chia‐Kuang Tsung, Wenyu Huang, 2010, Nature chemistry.

Enantioselective Oxidative Homocoupling and Cross-Coupling of 2-Naphthols Catalyzed by Chiral Iron Phosphate Complexes.

F. Toste, S. Narute, R. Parnes, 2016, Journal of the American Chemical Society.

Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and Enantioselective Lactonization Reactions.

G. Somorjai, Ying He, F. Toste, 2015, Journal of the American Chemical Society.

Control of selectivity in heterogeneous catalysis by tuning nanoparticle properties and reactor residence time

G. Somorjai, F. Toste, E. Gross, 2012, Nature Chemistry.