M. Doyle

发表

The influence of ligands on dirhodium(II) on reactivity and selectivity in metal carbene reactions

M. Doyle, T. Ren, 2007 .

Catalytic Divergent [3+3]- and [3+2]-Cycloaddition by Discrimination Between Diazo Compounds.

H. Arman, M. Doyle, Yongming Deng, 2017, Angewandte Chemie.

Efficient synthesis of oxazoles by dirhodium(II)-catalyzed reactions of styryl diazoacetate with oximes.

P. Zavalij, M. Doyle, Wenhao Hu, 2012, Chemical communications.

Tetracarbonyl(di‐μ‐chloro)dirhodium

I. Ojima, M. Doyle, M. Huffman, 2007 .

Divergent stereocontrol of acid catalyzed intramolecular aldol reactions of 2,3,7-triketoesters: synthesis of highly functionalized cyclopentanones.

M. Doyle, P. Truong, C. S. Shanahan, 2012, Organic letters.

Enantioselective cis-β-lactam synthesis by intramolecular C–H functionalization from enoldiazoacetamides and derivative donor–acceptor cyclopropenes

P. Zavalij, M. Doyle, Yongming Deng, 2015, Chemical Science.

Catalytic methods for metal carbene transformations

M. Doyle, 1987 .

Modern Catalytic Methods for Organic Synthesis with Diazo Compounds: From Cyclopropanes to Ylides

T. Ye, M. Doyle, M. Mckervey, 1998 .

Mechanistic investigation of oxidative Mannich reaction with tert-butyl hydroperoxide. The role of transition metal salt.

M. Doyle, M. Ratnikov, 2013, Journal of the American Chemical Society.

Correlation between catalytic cyclopropanation and ylide generation

M. Doyle, W. Tamblyn, S. Hoffmann, 1981 .

Catalytic Allylic Oxidation of Cyclic Enamides and 3,4-Dihydro-2H-Pyrans by TBHP.

M. Doyle, Yang Yu, James R. Alleyn, 2017, The Journal of organic chemistry.

tert‐Butyl Hydroperoxide

T. E. Wilson, Chao‐Jun Li, M. Doyle, 2012 .

Conformational isomers of extraordinary stability: carboxamidate-bridged dimetalloorganic compounds.

Yang Liu, Huai Sun, P. Zavalij, 2009, Chemical communications.

Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds

P. Zavalij, R. Poli, M. Doyle, 2008 .

Synthesis of bis(sigma-aryl)dirhodium(III) caprolactamates by oxidative arylation with arylboronic acids.

M. Doyle, Jianhua Xie, J. Nichols, 2008, Chemical communications.

Bis(phenyl)dirhodium(III) caprolactamate: a dinuclear paddlewheel complex with no metal-metal bond.

B. Varughese, P. Zavalij, M. Doyle, 2007, Journal of the American Chemical Society.

(4,0)-Dirhodium(II) tetrakis[methyl 1-acetyl-2-oxoimidazolidine-4(S)-carboxylate]. Implications for the mechanism of ligand exchange reactions

V. Lynch, C. Raab, M. Doyle, 1997 .

Copper(i)-catalyzed highly enantioselective [3 + 3]-cycloaddition of γ-alkyl enoldiazoacetates with nitrones

M. Doyle, Xinfang Xu, Kuiyong Dong, 2020 .

Catalytic asymmetric cycloaddition reactions of enoldiazo compounds.

M. Doyle, Kostiantyn O. Marichev, 2019, Organic & biomolecular chemistry.

Effective methods for the syntheses of 2‐pyrazolines and pyrazoles from diazocarbonyl compounds

M. Doyle, Mark R. Colsman, R. L. Dorow, 1983 .

Kinetics and mechanism of the oxidation of human deoxyhemoglobin by nitrites.

M. Doyle, R. A. Pickering, T. M. DeWeert, 1981, The Journal of biological chemistry.

Hydrolysis, nitrosyl exchange, and synthesis of alkyl nitrites

M. Doyle, J. Terpstra, R. A. Pickering, 1983 .

Medium effects in nucleophilic substitution reactions

M. Doyle, 1968 .

Dirhodium(II)-catalyzed carbonyl ylide generation. Stereoelectronic control in dioxolane formation

David C. Forbes, D. C. Forbes, M. Doyle, 1998 .

Ag I ‐Catalyzed Reaction of Enol Diazoacetates and Imino Ethers: Synthesis of Highly Functionalized Pyrroles

M. Doyle, W. Griffith, Xinfang Xu, 2021, Angewandte Chemie.

Ag(I)-Catalyzed Reactions of Enol Diazoacetates and Imino Ethers: Synthesis of Highly Functionalized Pyrroles.

H. Arman, M. Doyle, W. Griffith, 2021, Angewandte Chemie.

Catalyst-Directed Divergent Catalytic Approaches to Expand Structural and Functional Scaffold Diversity via Metallo-Enolcarbene Intermediates

H. Arman, M. Doyle, Xinfang Xu, 2021 .

Rhodium acetate-catalyzed aerobic Mukaiyama epoxidation of alkenes

M. Doyle, D. Shabashov, 2013 .

Allylic Oxidation Catalyzed by Dirhodium(II) Tetrakis[ε‐caprolactamate] of tert‐Butyldimethylsilyl‐protected trans‐Dehydroandrosterone

M. Doyle, M. Ratnikov, E. McLaughlin, 2014 .

Oxidative deamination of primary amines by copper halide nitrosyls. The formation of geminal dihalides

M. Doyle, B. Siegfried, James J. Hammond, 1976 .

Oxidation of oxymyoglobin by nitric oxide through dissociation from cobalt nitrosyls

M. Doyle, B. Cook, R. A. Pickering, 1983 .

Involvement of peroxide and superoxide in the oxidation of hemoglobin by nitrite.

M. Doyle, R. Boyer, R. A. Pickering, 1982, Biochemical and biophysical research communications.

Copper-Catalyzed Formal [4+2] Cycloaddition of Enoldiazoimides with Sulfur Ylides.

H. Arman, M. Doyle, Yongming Deng, 2018, Angewandte Chemie.

Nitric Oxide Dissociation from Trioxodinitrate(II) in Aqueous Solution

M. Doyle, S. N. Mahapatro, 1984 .

5.2 – Transition Metal Carbene Complexes: Diazodecomposition, Ylide, and Insertion

M. Doyle, 1995 .

Dirhodium(II) tetrakis[N,N-dimethyl-2-pyrrolidone-5(S)-carboxamide]. Structural effects on enantioselection in metal carbene transformations

M. Doyle, R. Ghosh, S. H. Simonsen, 1994 .

Degradation of uric acid during autocatalytic oxidation of oxyhemoglobin induced by sodium nitrite.

M. Doyle, R. C. Smith, J. Gore, 1991, Free radical biology & medicine.

Exceptionally effective catalysis of cyclopropanation reactions by the hexarhodium carbonyl cluster

M. Doyle, R. L. Dorow, W. E. Buhro, 1981 .

Selectivity in reactions of allyl diazoacetates as a function of catalyst and ring size from gamma-lactones to macrocyclic lactones.

M. Doyle, W. Hu, W. Hu, 2000, The Journal of organic chemistry.

Enantiocontrol in the Generation and Diastereoselective Reactions of Catalytically Generated Oxonium and Iodonium Ylides. Metal-Stabilized Ylides as Reaction Intermediates

David C. Forbes, D. C. Forbes, M. Doyle, 1998 .

Macrocyclic oxonium ylide formation and internal [2,3]-sigmatropic rearrangement catalyst influence on selectivity

M. Doyle, C. S. Peterson, 1997 .

Facile catalytic methods for intermolecular generation of allylic oxonium ylides and their stereoselective[2,3]-sigmatropic rearrangement

V. Bagheri, M. Doyle, N. K. Harn, 1988 .

Rearrangements of Ylides Generated from Reactions of Diazo Compounds with Allyl Acetals and Thioketals by Catalytic Methods. Heteroatom Acceleration of the [2,3]-Sigmatropic Rearrangement

J. Griffin, M. Doyle, M. S. Chinn, 1984 .

Identification of a Mr = 17,000 protein as the plastoquinone-binding protein in the cytochrome b6-f complex from spinach chloroplasts.

M. Doyle, L. Yu, L. B. Li, 1989, Journal of Biological Chemistry.

Catalysts with mixed ligands on immobilized supports. Electronic and steric advantages.

M. Doyle, M. Yan, H. Gau, 2003, Organic letters.

The new chemical biology of nitrite reactions with hemoglobin: R-state catalysis, oxidative denitrosylation, and nitrite reductase/anhydrase.

Mark T Gladwin, M. Gladwin, Rozalina Grubina, 2009, Accounts of chemical research.

The New Chemical Biology of Nitrite Reactions with Hemoglobin: R-State Catalysis, Oxidative Denitrosylation, and Nitrite Reductase/Anhydrase

M. Gladwin, Rozalina Grubina, M. Doyle, 2009 .

Asymmetric catalysis, part 108 copper catalysts with optically active ligands in the enantioselective Meerwein arylation of activated olefins

H. Brunner, M. Doyle, Christian Blüchel, 1997 .

Oxidation of hemoglobin by arenediazonium salts. The influence of dioxygen

M. Doyle, S. Tran, S. N. Mahapatro, 1984 .

Catalytic, Asymmetric, Intramolecular Carbon–Hydrogen Insertion

Yu Liu, M. Doyle, M. Ratnikov, 2013 .

Catalytic Desymmetric Cycloaddition of Diaziridines with Metalloenolcarbenes: the Special Role of Donor-Acceptor Cyclopropenes.

M. Doyle, Haifeng Zheng, 2019, Angewandte Chemie.

Catalytic Desymmetric Cycloaddition of Diaziridines with Metalloenolcarbenes: The Role of Donor–Acceptor Cyclopropenes

M. Doyle, Haifeng Zheng, 2019, Angewandte Chemie.

Rhodium(ii)-catalysed generation of cycloprop-1-en-1-yl ketones and their rearrangement to 5-aryl-2-siloxyfurans.

Zhi‐Xiang Yu, M. Doyle, Yi Wang, 2018, Chemical communications.

Efficient aziridination of olefins catalyzed by mixed-valent dirhodium(II,III) caprolactamate.

M. Doyle, R. Forslund, J. Nichols, 2005, Organic letters.

Rh(II)‐Catalyzed Isomerizations of Cyclopropenes Evidence for Rh(II)‐Complexed Vinylcarbene Intermediates

P. Müller, V. Bagheri, M. Doyle, 1990 .

The oxidative mannich reaction catalyzed by dirhodium caprolactamate.

M. Doyle, J. Nichols, Brian J. Nettles, 2006, Journal of the American Chemical Society.

Reactions of the nitrosonium ion. VII. Syntheses of dihydroisoquinolines and oxazoles from azides in nitrile solvents

G. D. Spoelhof, M. Doyle, Mary A. Zaleta, 1975 .

Alkyl nitrite-metal halide deamination reactions. 6. Direct synthesis of arenediazonium tetrafluoroborate salts from aromatic amines, tert-butyl nitrite, and boron trifluoride etherate in anhydrous media

M. Doyle, William J. Bryker, 1979 .

Highly enantioselective dearomatizing formal [3+3] cycloaddition reactions of N-acyliminopyridinium ylides with electrophilic enol carbene intermediates.

P. Zavalij, M. Doyle, Xinfang Xu, 2013, Angewandte Chemie.

Alkyl nitrite-metal halide deamination reactions. 7. Synthetic coupling of electrophilic bromination with substitutive deamination for selective synthesis of multiply brominated aromatic compounds from arylamines

M. Doyle, W. Fobare, Michael A. Van Lente, 1980 .

Alkyl Nitrite-Metal Halide Deamination Reactions. 3. Arylation of Olefinic Compounds in the Deamination of Arylamines by Alkyl Nitrites and Copper(II) Halides. A Convenient and Effective Variation of the Meerwein Arylation Reaction

M. Doyle, B. Siegfried, J. Dellaria, 1977 .

Catalytic carbene insertion into C-H bonds.

Lei Zhou, M. Doyle, M. Ratnikov, 2010, Chemical reviews.

Rhodium(II) acetate and nafion-H catalyzed decomposition of N-aryldiazoamides. An efficient synthesis of 2(3H)-indolinones

M. Doyle, M. Shanklin, S. N. Mahapatro, 1988 .

Recent Advances in Asymmetric Catalytic Metal Carbene Transformations.

David C. Forbes, D. C. Forbes, M. Doyle, 1998, Chemical reviews.

Catalytic Oxidative Cleavage Reactions of Arylalkenes by tert-Butyl Hydroperoxide - A Mechanistic Assessment.

M. Doyle, Yong-liang Su, Yang Yu, 2020, The Journal of organic chemistry.

Rhodium(II) acetate catalyzed hydrocarbon oxidations by molecular oxygen

J. Griffin, C. Winter, M. Doyle, 1984 .

Dirhodium caprolactamate and tert-butyl hydro- peroxide – a universal system for selective oxidations

M. Doyle, M. Ratnikov, 2014 .

Alkyl Nitrite-Metal Halide Deamination Reactions. 2. Substitutive Deamination of Arylamines by Alkyl Nitrites and Copper(II) Halides. A Direct and Remarkably Efficient Conversion of Arylamines to Aryl Halides

M. Doyle, B. Siegfried, J. Dellaria, 1977 .

Generation of Diazomethyl Radicals by Hydrogen Atom Abstraction and Their Cycloaddition with Alkenes

M. Doyle, Yong-liang Su, Haifeng Zheng, 2021, Angewandte Chemie.

Generation of Diazomethyl Radicals by Hydrogen Atom Abstraction and Their Cycloaddition with Alkenes.

M. Doyle, Yong-liang Su, Haifeng Zheng, 2021, Angewandte Chemie.

Reactivity and Selectivity in Catalytic Reactions of Enoldiazoacetamides. Assessment of Metal Carbenes as Intermediates

H. Arman, M. Doyle, Yongming Deng, 2016 .

Enantioselective cis-β-lactam synthesis by intramolecular C-H functionalization from enoldiazoacetamides and derivative donor-acceptor cyclopropenes.

P. Zavalij, M. Doyle, Yongming Deng, 2015, Chemical science.

Synthesis of 1,2,3-Triazine Derivatives by Deoxygenation of 1,2,3-Triazine 1-Oxides.

M. Doyle, G. Rivera, Soumen Biswas, 2022, Organic letters.

The [3 + 3]-Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts

M. Doyle, Xinfang Xu, 2014, Accounts of chemical research.

Vinylogous reactivity of enol diazoacetates with donor-acceptor substituted hydrazones. Synthesis of substituted pyrazole derivatives.

P. Zavalij, M. Doyle, Wenhao Hu, 2013, The Journal of organic chemistry.

A survey of enoldiazo nucleophilicity in selective C-C bond forming reactions for the synthesis of natural product-like frameworks.

Yu Liu, M. Doyle, Xichen Xu, 2014, Organic & biomolecular chemistry.

Chiral catalyst controlled diastereoselection and regioselection in intramolecular carbon-hydrogen insertion reactions of diazoacetates

M. Doyle, A. V. Kalinin, D. Ene, 1996 .

Chiral Dirhodium(II) Carboxamidate-Catalyzed [2+2]-Cycloaddition of TMS-Ketene and Ethyl Glyoxylate

M. Doyle, James W. Cain, J. Colyer, 2005 .

Highly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates.

P. Zavalij, M. Doyle, Y. Qian, 2013, Journal of the American Chemical Society.

Precise Introduction of the -CHnX3-n (X = F, Cl, Br, I) Moiety to Target Molecules by a Radical Strategy: A Theoretical and Experimental Study.

Yundong Wu, Tian-Yu Sun, Xinhao Zhang, 2021, Journal of the American Chemical Society.

Silane reductions in acidic media. III. Reductions of aldehydes and ketones to alcohols and alcohol derivatives. General syntheses of alcohols, symmetrical ethers, carboxylate esters and acetamides

M. Doyle, D. Kooistra, D. DeBruyn, 1974 .

Electrophilic metal carbenes as reaction intermediates in catalytic reactions

M. Doyle, 1986 .

Silane reductions in acidic media : VIII. Boron trifluoride catalyzed organosilane reductions. selectivity and mechanism

M. Doyle, C. C. McOsker, S. Donnelly, 1976 .

Basic Organic Stereochemistry

M. Doyle, E. Eliel, S. Wilen, 2001 .

Synthesis and Structures of (2,2-cis)-Dirhodium(II) Tetrakis[methyl l-acyl-2-oxoimidazolidine-4(S)-carboxylates]. Chiral Catalysts for Highly Stereoselective Metal Carbene Transformations

V. Lynch, C. Raab, M. Doyle, 1996 .

A new approach to macrocyclization via alkene formation in catalytic diazo decomposition. Synthesis of patulolides A and B.

M. Doyle, A. Wee, W. Hu, 2000, Organic letters.

Dinuclear compounds without a metal-metal bond. Dirhodium(III,III)carboxamidates

W. Browne, M. Doyle, A. Draksharapu, 2015 .

A readily prepared neutral heterobimetallic titanium(IV)-rhodium(I) catalyst for intramolecular hydroacylation.

M. Doyle, J. P. Morgan, K. Kundu, 2005, Chemical communications.

Rhodium(II)- and copper(II)-catalyzed reactions of enol diazoacetates with nitrones: metal carbene versus Lewis acid directed pathways.

M. Doyle, Wenhao Hu, Y. Qian, 2012, Angewandte Chemie.

Highly enantioselective trapping of zwitterionic intermediates by imines

C. Zhai, Li-qin Jiang, M. Doyle, 2012, Nature Chemistry.

Addition/elimination in the rhodium(II) perfluorobutyrate catalyzed hydrosilylation of 1-alkenes. Rhodium hydride promoted isomerization and hydrogenation

M. Doyle, G. Devora, A. O. Nefedov, 1992 .

Silane reductions in acidic media. II. Reductions of aryl aldehydes and ketones by trialkylsilanes in trifluoroacetic acid. Selective method for converting the carbonyl group to methylene

M. Doyle, D. Kooistra, S. Donnelly, 1973 .

Catalytic Intramolecular Addition of Metal Carbenes to Remote Furans

M. Doyle, Wenhao Hu, M. Mckervey, 1999 .

Bicyclic pyrazolidinone derivatives from diastereoselective catalytic [3 + 3]-cycloaddition reactions of enoldiazoacetates with azomethine imines.

M. Doyle, Wenhao Hu, Y. Qian, 2013, Organic letters.

Dirhodium(II)-catalyzed formal [3+2+1]-annulation of azomethine imines with two molecules of a diazo ketone.

P. Zavalij, M. Doyle, Xinfang Xu, 2013, Chemical communications.

Oxidation of secondary amines catalyzed by dirhodium caprolactamate.

M. Doyle, Hojae Choi, 2007, Chemical communications.

Exceptionally high trans (anti) stereoselectivity in catalytic cyclopropanation reactions

T. Wandless, V. Bagheri, M. Doyle, 1990 .

Highly effective catalytic methods for ylide generation from diazo compounds. Mechanism of the rhodium- and copper-catalyzed reactions with allylic compounds

V. Bagheri, M. Doyle, W. H. Tamblyn, 1982 .

A novel three-component reaction catalyzed by dirhodium(II) acetate: decomposition of phenyldiazoacetate with arylamine and imine for highly diastereoselective synthesis of 1,2-diamines.

M. Doyle, Wenhao Hu, Yanxin Zhu, 2003, Organic letters.

Epoxides and aziridines from diazoacetates via ylide intermediates.

D. J. Timmons, M. Doyle, W. Hu, 2001, Organic letters.

Benzylic oxidation catalyzed by dirhodium(II,III) caprolactamate.

M. Doyle, J. Nichols, A. Catino, 2005, Organic letters.

Synthesis of 1 H-Pyrrol-3(2 H)-ones via Three-Component Reactions of 2,3-Diketo Esters, Amines, and Ketones.

M. Doyle, Junke Wang, Q. Sha, 2018, The Journal of organic chemistry.

A facile three-component one-pot synthesis of structurally constrained tetrahydrofurans that are t-RNA synthetase inhibitor analogues.

Zhi-yong Chen, M. Doyle, Wenhao Hu, 2004, The Journal of organic chemistry.

Dirhodium(II) Tetraacetate

M. Doyle, H. Davies, J. R. Manning, 2006 .

Intramolecular catalytic asymmetric carbon-hydrogen insertion reactions. Synthetic advantages in total synthesis in comparison with alternative approaches.

Yu Liu, M. Doyle, M. Ratnikov, 2011, Organic & biomolecular chemistry.

Unexpected catalytic reactions of silyl-protected enol diazoacetates with nitrile oxides that form 5-arylaminofuran-2(3H)-one-4-carboxylates.

P. Zavalij, M. Doyle, Xinfang Xu, 2012, Organic letters.

A new rhodium(II) phosphate catalyst for diazocarbonyl reactions including asymmetric synthesis

M. Doyle, M. Mccann, T. Ye, 1992 .

Stereoretentive Catalytic [3+2]-Cycloaddition/Rearrangement/Decarboxylation Reactions of Indoles with Non-Racemic Donor–Acceptor Cyclopropanes

M. Bao, M. Doyle, Hadi Arman, 2023, ACS Catalysis.

Metal Carbene Cycloaddition Reactions

M. Doyle, Kostiantyn O. Marichev, Haifeng Zheng, 2021, Transition Metal‐Catalyzed Carbene Transformations.

Copper(I)‐Catalyzed Highly Enantioselective [3+3]‐Cycloaddition of β‐Aryl/Alkyl Vinyl Diazoacetates with Nitrones

M. Doyle, Haifeng Zheng, Isa Faghihi, 2021, Helvetica Chimica Acta.

Enantioselective Catalytic Cyclopropanation-Rearrangement Approach to Chiral Spiroketals.

M. Doyle, Xinfang Xu, R. Gurung, 2021, Organic letters.

Formal [4 + 4]-, [4 + 3]-, and [4 + 2]-cycloaddition reactions of donor–acceptor cyclobutenes, cyclopropenes and siloxyalkynes induced by Brønsted acid catalysis†

Kan Wang, H. Arman, M. Doyle, 2021, Chemical science.

Enoldiazosulfones for Highly Enantioselective [3 + 3]-Cycloaddition with Nitrones Catalyzed by Copper(I) with Chiral BOX Ligands.

H. Arman, M. Doyle, Kostiantyn O. Marichev, 2018, Organic letters.

Catalyst Choice for Highly Enantioselective [3 + 3]-Cycloaddition of Enoldiazocarbonyl Compounds

H. Arman, M. Doyle, Kostiantyn O. Marichev, 2018, ACS Catalysis.

Selective C(sp3)–H Bond Insertion in Carbene/Alkyne Metathesis Reactions. Enantioselective Construction of Dihydroindoles

Han-Xun Wei, M. Doyle, Xinfang Xu, 2018, ACS Catalysis.

Vinyldiazo Reagents and Metal Catalysts: A Versatile Toolkit for Heterocycle and Carbocycle Construction

M. Doyle, Yang Yu, Q. Cheng, 2018 .

Cycloaddition reactions of enoldiazo compounds.

M. Doyle, Yongming Deng, Marianne Lankelma, 2017, Chemical Society reviews.

Divergent Rhodium-Catalyzed Cyclization Reactions of Enoldiazoacetamides with Nitrosoarenes.

H. Arman, M. Doyle, Daniel J. Wherritt, 2017, Journal of the American Chemical Society.

Catalytic Asymmetric [3+1]-Cycloaddition Reaction of Ylides with Electrophilic Metallo-enolcarbene Intermediates.

P. Zavalij, M. Doyle, Yongming Deng, 2017, Angewandte Chemie.

Syntheses of Tetrahydropyridazine and Tetrahydro-1,2-diazepine Scaffolds through Cycloaddition Reactions of Azoalkenes with Enol Diazoacetates.

H. Arman, M. Doyle, Yongming Deng, 2016, Organic letters.

Unusually large scalar coupling between geminal protons in a saturated pyrimidine

M. Doyle, E. Mazzola, O. Gutierrez, 2016 .

Highly Regio- and Enantioselective Formal [3 + 2]-Annulation of Indoles with Electrophilic Enol Carbene Intermediates.

H. Arman, M. Doyle, Yongming Deng, 2016, Organic letters.

Catalytic Asymmetric Synthesis of Cyclopentyl β-Amino Esters by [3+2] Cycloaddition of Enecarbamates with Electrophilic Metalloenolcarbene Intermediates.

H. Arman, M. Doyle, Yongming Deng, 2016, Angewandte Chemie.

Dirhodium(II)-Catalyzed Annulation of Enoldiazoacetamides with α-Diazoketones: An Efficient and Highly Selective Approach to Fused and Bridged Ring Systems.

H. Arman, M. Doyle, Q. Cheng, 2016, Angewandte Chemie.

Copper-Catalyzed Divergent Addition Reactions of Enoldiazoacetamides with Nitrones.

H. Arman, M. Doyle, Q. Cheng, 2016, Journal of the American Chemical Society.

The Selection of Catalysts for Metal Carbene Transformations

M. Doyle, Q. Cheng, 2016 .

Hg(OTf)2 Catalyzed Intramolecular 1,4-Addition of Donor-Acceptor Cyclopropenes to Arenes.

P. Zavalij, M. Doyle, Yongming Deng, 2015, Organic letters.

Lewis Acid/Rhodium-Catalyzed Formal [3 + 3]-Cycloaddition of Enoldiazoacetates with Donor-Acceptor Cyclopropanes.

P. Zavalij, M. Doyle, Y. Qian, 2015, Organic letters.

Straightforward access to the [3.2.2]nonatriene structural framework via intramolecular cyclopropenation/Buchner reaction/Cope rearrangement cascade.

P. Zavalij, M. Doyle, Xinfang Xu, 2015, Organic letters.

Divergent pathways of β,γ-unsaturated α-diazocarbonyl compounds catalyzed by dirhodium and Lewis acids catalysts separately or in combination

M. Doyle, Xinfang Xu, 2015 .

The [3 + 3]‐Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts

M. Doyle, Xinfang Xu, 2014 .

Recent Developments in the Synthetic Uses of Silyl-protected Enoldiazoacetates for Heterocyclic Syntheses

M. Doyle, Xinfang Xu, 2014 .

A Donor—Acceptor Cyclopropene as a Dipole Source for a Silver(I) Catalyzed Asymmetric Catalytic [3 + 3]‐Cycloaddition with Nitrones.

M. Doyle, Xinfang Xu, P. J. Zavalij, 2014 .

Tetrahydroquinolines and Benzazepines Through Catalytic Diastereoselective Formal [4 + 2]-Cycloaddition Reactions Between Donor—Acceptor Cyclopropenes and Imines.

P. Zavalij, M. Doyle, P. Truong, 2013 .

A donor-acceptor cyclopropene as a dipole source for a silver(I) catalyzed asymmetric catalytic [3+3]-cycloaddition with nitrones.

M. Doyle, Xinfang Xu, P. J. Zavalij, 2013, Chemical communications.

Catalytic asymmetric syntheses of quinolizidines by dirhodium-catalyzed dearomatization of isoquinolinium/pyridinium methylides--the role of catalyst and carbene source.

P. Zavalij, M. Doyle, Xichen Xu, 2013, Journal of the American Chemical Society.

Highly Selective Catalyst‐Dependent Competitive 1,2‐C→C, ‐O→C, and ‐N→C Migrations from β‐Methylene‐β‐silyloxy‐β‐amido‐α‐diazoacetates.

P. Zavalij, M. Doyle, Y. Qian, 2013 .

Tetrahydroquinolines and benzazepines through catalytic diastereoselective formal [4 + 2]-cycloaddition reactions between donor-acceptor cyclopropenes and imines.

P. Zavalij, M. Doyle, P. Truong, 2013, Organic letters.

Synthesis of tetrahydropyridazines by a metal-carbene-directed enantioselective vinylogous N-H insertion/Lewis acid-catalyzed diastereoselective Mannich addition.

P. Zavalij, M. Doyle, Xinfang Xu, 2012, Angewandte Chemie.

Highly regio- and stereoselective dirhodium vinylcarbene induced nitrone cycloaddition with subsequent cascade carbenoid aromatic cycloaddition/N-O cleavage and rearrangement.

P. Zavalij, M. Doyle, Xiao‐Chen Wang, 2012, Angewandte Chemie.

Substrate-dependent divergent outcomes from catalytic reactions of silyl-protected enol diazoacetates with nitrile oxides: azabicyclo[3.1.0]hexanes or 5-arylaminofuran-2(3H)-ones.

P. Zavalij, M. Doyle, Xinfang Xu, 2012, The Journal of organic chemistry.

Asymmetric Formal [3 + 3]-Cycloaddition Reactions of Nitrones with Electrophilic Vinylcarbene Intermediates.

P. Zavalij, M. Doyle, Xinfang Xu, 2012 .

Divergent outcomes of carbene transfer reactions from dirhodium- and copper-based catalysts separately or in combination.

P. Zavalij, M. Doyle, Wenhao Hu, 2011, Angewandte Chemie.

Multifunctionalized 3-hydroxypyrroles in a three-step, one-pot cascade process from methyl 3-TBSO-2-diazo-3-butenoate and nitrones.

P. Zavalij, M. Doyle, Xinfang Xu, 2011, Organic letters.

Asymmeric formal [3 + 3]-cycloaddition reactions of nitrones with electrophilic vinylcarbene intermediates.

P. Zavalij, M. Doyle, Xinfang Xu, 2011, Journal of the American Chemical Society.

Enantiomer recognition of amides by dirhodium(II) tetrakis[methyl 2-oxopyrrolidine-5(S)-carboxylate].

M. Doyle, Xichen Xu, 2011, Inorganic chemistry.

Solvent enhancement of reaction selectivity: a unique property of cationic chiral dirhodium carboxamidates.

M. Doyle, Xiao‐Chen Wang, C. Weigl, 2011, Journal of the American Chemical Society.

Tandem sequence of phenol oxidation and intramolecular addition as a method in building heterocycles.

M. Doyle, M. Ratnikov, Linda E Farkas, 2012, The Journal of organic chemistry.

Asymmetric Synthesis of 1H‐Pyrrol‐3(2H)‐ones from 2,3‐Diketoesters by Combination of Aldol Condensation with Benzilic Acid Rearrangement.

H. Arman, M. Doyle, Q. Sha, 2016 .

Three-Component Cascade Reactions with 2,3-Diketoesters: A Novel Metal-Free Synthesis of 5-Vinyl-pyrrole and 4-Hydroxy-indole Derivatives.

H. Arman, M. Doyle, Q. Sha, 2015, Organic letters.

Highly selective catalyst-directed pathways to dihydropyrroles from vinyldiazoacetates and imines.

Luisa S. Gronenberg, M. Doyle, M. Yan, 2003, Journal of the American Chemical Society.

Catalytic conversion of diazocarbonyl compounds to imines: applications to the synthesis of tetrahydropyrimidines and β-lactams.

P. Zavalij, M. Doyle, P. Truong, 2014, Organic letters.

Reactivities and selectivities in macrocyclic addition reactions with diazoacetates using copper(I) and rhodium(II) catalysts

M. Doyle, Wenhao Hu, 2000 .

Propargylic oxidations catalyzed by dirhodium caprolactamate in water: efficient access to alpha,beta-acetylenic ketones.

M. Doyle, E. McLaughlin, 2008, The Journal of organic chemistry.

Construction of highly functionalized diazoacetoacetates via catalytic Mukaiyama-Michael reactions.

Yu Zhang, Yu Liu, M. Doyle, 2008, Organic letters.

Chiral Dirhodium(II) Catalysts and Their Applications

D. J. Timmons, M. Doyle, 2005 .

New aspects of catalytic asymmetric cyclopropanation

M. Doyle, M. Protopopova, 1998 .

Chiral catalysts for enantioselective intermolecular cyclopropanation reactions with methyl phenyldiazoacetate. Origin of the solvent effect in reactions catalyzed by homochiral dirhodium(II) prolinates

M. Doyle, Qi‐Lin Zhou, M. Mckervey, 1996 .

Oxidation of nitrogen oxides by bound dioxygen in hemoproteins.

M. Doyle, J. W. Hoekstra, James W. Hoekstra, 1981, Journal of inorganic biochemistry.

Nitrosyl transfer to metalloproteins. Selective intermolecular transfer of the nitrosyl group from cobalt nitrosyls to hemoglobin and myoglobin

M. Doyle, C. Funckes, F. J. V. Doornik, 1980 .

Diazoacetoacetate enones for the synthesis of diverse natural product-like scaffolds.

M. Doyle, P. Truong, Charles S. Shanahan, 2013, Organic letters.

The Future of Catalysis by Chiral Lewis Acids

M. Doyle, Yongming Deng, Q. Sha, 2015 .

Dirhodium(II) tetrakis[methyl 2-oxaazetidine-4-carboxylate]: a chiral dirhodium(II) carboxamidate of exceptional reactivity and selectivity.

M. Doyle, Wenhao Hu, S. Davies, 2000, Organic letters.

Highly enantioselective oxonium ylide formation and stevens rearrangement catalyzed by chiral Dirhodium(II) carboxamidates

David C. Forbes, D. C. Forbes, J. Tedrow, 1997 .

Role of Donor–Acceptor Cyclopropenes in Metal Carbene Reactions. Conversion of E-Substituted Enoldiazoacetates to Z-Substituted Metallo-Enolcarbenes

M. Doyle, Kostiantyn O. Marichev, Kuiyong Dong, 2019, Organometallics.

Stereoselective synthesis of highly functionalized alpha-diazo-beta-ketoalkanoates via catalytic one-pot Mukaiyama-Aldol reactions.

Lei Zhou, M. Doyle, 2010, Organic letters.

Perspective on dirhodium carboxamidates as catalysts.

M. Doyle, 2006, The Journal of organic chemistry.

Michael addition/pericyclization/rearrangement--a multicomponent strategy for the synthesis of substituted resorcinols.

Yu Liu, M. Doyle, Michael P Doyle, 2012, Organic & biomolecular chemistry.

Macrocyclic Cyclopropenes by Highly Enantioselective Intramolecular Addition of Metal Carbenes to Alkynes.

V. Lynch, M. Doyle, D. Ene, 1999, Angewandte Chemie.

Macrocycle Formation by Catalytic Intramolecular Cyclopropanation. A New General Methodology for the Synthesis of Macrolides

V. Lynch, M. Doyle, D. Parker, 1997 .

FORMATION OF MACROCYCLES BY CATALYTIC INTRAMOLECULAR AROMATIC CYCLOADDITION OF METAL CARBENES TO REMOTE ARENES

M. Doyle, M. Mckervey, J. Vitale, 1996 .

Formation of Macrocyclic Lactones by Enantioselective Intramolecular Cyclopropanation of Diazoacetates Catalyzed by Chiral CuI and RhII Compounds

M. Doyle, D. Parker, C. S. Peterson, 1996 .

Dirhodium(II) tetrakis(carboxamidates) with chiral ligands. Structure and selectivity in catalytic metal-carbene transformations

V. Lynch, M. Doyle, J. Hoorn, 1993 .

Cyclopropanation versus carbon–hydrogen insertion. The influences of substrate and catalyst on selectivity

M. Doyle, I. Phillips, I. M. Phillips, 2001 .

Exceptional selectivity in cyclopropanation reactions catalyzed by chiral cobalt(II)-porphyrin catalysts.

M. Doyle, 2009, Angewandte Chemie.

Stereoselectivity in Metal Carbene Addition to a Carbon‐Carbon Triple Bond Tied to the Reactant Diazoacetate Through a Chiral Linker

M. Doyle, Yuanhua Wang, T. Weathers, 2006 .

ASYMMETRIC RHODIUM CARBENOID INSERTION INTO THE SI-H BOND

David C. Forbes, D. C. Forbes, M. Drysdale, 1996 .

A New and General Synthesis of α-Silyl Carbonyl Compounds by SI-H Insertion from Transition Metal Catalyzed Reactions of Diazo Esters and Diazo Ketones

J. Taunton, V. Bagheri, M. Doyle, 1988 .

Highly stereoselective syntheses of five- and seven-membered ring heterocycles from ylides generated by catalytic reactions of styryldiazoacetates with aldehydes and imines.

D. J. Timmons, M. Doyle, W. Hu, 2001, Organic letters.

Highly enantioselective catalytic synthesis of functionalized chiral diazoacetoacetates.

M. Doyle, Wenhao Hu, Xinfang Xu, 2011, Angewandte Chemie.

Cyclopropanation of .alpha.,.beta.-unsaturated carbonyl compounds and nitriles with diazo compounds. The nature of the involvement of transition-metal promoters

M. Doyle, R. L. Dorow, W. H. Tamblyn, 1982 .

Unprecedented Intramolecular [4 + 2]-Cycloaddition between a 1,3-Diene and a Diazo Ester.

P. Zavalij, M. Doyle, Harathi D. Srinivas, 2016, Journal of the American Chemical Society.

Highly Selective Enantiomer Differentiation in Intramolecular Cyclopropanation Reactions of Racemic Secondary Allylic Diazoacetates.

S. Liras, M. Spaller, M. Doyle, 1996 .

Tetrakis[(4S)‐4‐phenyloxazolidin‐2‐one]dirhodium(II) and Its Catalytic Applications for Metal Carbene Transformations

G. Bernardinelli, P. Müller, M. Doyle, 1993 .

Lewis acid catalyzed indole synthesis via intramolecular nucleophilic attack of phenyldiazoacetates to iminium ions.

Lei Zhou, M. Doyle, 2009, The Journal of organic chemistry.

Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels-Alder reactions.

M. Doyle, Xiao‐Chen Wang, Zhuoyan Li, 2009, Chemical communications.

Asymmetric hetero-Diels-Alder reaction catalyzed by dirhodium(II) carboxamidates.

M. Doyle, Penglin Huang, Marcela Valenzuela, 2004, Proceedings of the National Academy of Sciences of the United States of America.

Enantiomer differentiation in intramolecular carbon—hydrogen insertion reactions of racemic secondary alkyl diazoacetates catalyzed by chiral dirhodium(ii) carboxamidates

M. Doyle, A. Kalinin, 1995 .

Synthesis and catalytic reactions of chiral N-(diazoacetyl)oxazolidones

M. Doyle, J. Terpstra, R. L. Dorow, 1985 .

An efficient route to highly enantioenriched tetrahydroazulenes and β-tetralones by desymmetrization reactions of δ,δ-diaryldiazoaceto-acetates.

Renhua Liu, P. Zavalij, M. Doyle, 2015, Chemical communications.

Templated Carbene Metathesis Reactions from the Modular Assembly of Enol‐diazo Compounds and Propargyl Acetates

M. Doyle, Y. Qian, Charles S. Shanahan, 2013 .

Competitive [2,3]- and [1,2]-oxonium ylide rearrangements. Concerted or stepwise?

P. Zavalij, Deana Jaber, M. Doyle, 2012, Organic letters.

Catalytic addition methods for the synthesis of functionalized diazoacetoacetates and application to the construction of highly substituted cyclobutanones.

A. E. Russell, M. Doyle, K. Kundu, 2005, Organic letters.

Ligand effects on dirhodium(II) carbene reactivities. Highly effective switching between competitive carbenoid transformations

D. Austin, A. Padwa, M. Doyle, 1993 .

Silane reductions in acidic media. I. Reduction of aldehydes and ketones in alcoholic acidic media. General synthesis of ethers

M. Doyle, D. Kooistra, D. DeBruyn, 1972 .

"Matched/mismatched" diastereomeric dirhodium(II) carboxamidate catalyst pairs. Structure-selectivity correlations in diazo decomposition and hetero-Diels-Alder reactions.

J. Fettinger, M. Carducci, P. Zavalij, 2005, The Journal of organic chemistry.

Enantioselective carbonyl-ene reactions catalyzed by chiral cationic dirhodium(II,III) carboxamidates.

M. Doyle, Xiao‐Chen Wang, Xichen Xu, 2014, The Journal of organic chemistry.

Control of selectivity in the generation and reactions of oxonium ylides.

P. Zavalij, Deana Jaber, M. Doyle, 2011, Chemical communications.

Cationic chiral dirhodium carboxamidates are activated for Lewis acid catalysis.

P. Zavalij, M. Doyle, Yuanhua Wang, 2008, Angewandte Chemie.

A new class of chiral lewis acid catalysts for highly enantioselective hetero-Diels-Alder reactions: exceptionally high turnover numbers from dirhodium(II) carboxamidates.

M. Doyle, Wenhao Hu, W. Hu, 2001, Journal of the American Chemical Society.

Constructing chiral diazoacetoacetates by enantioselective catalytic Mukaiyama aldol reactions

M. Doyle, K. Kundu, 2006 .

α-Amino Radical-Mediated Diverse Difunctionalization of Alkenes: Construction of C–C, C–N, and C–S Bonds

H. Arman, M. Doyle, Daniel J. Wherritt, 2020 .

Stereocontrol in Intermolecular Dirhodium(II)-Catalyzed Carbonyl Ylide Formation and Reactions. Dioxolanes and Dihydrofurans.

David C. Forbes, D. C. Forbes, M. Doyle, 1997, The Journal of organic chemistry.

Asymmetric Addition and Insertion Reactions of Catalytically‐Generated Metal Carbenes

M. Doyle, 2005 .

Diazo Esters as Dienophiles in Intramolecular (4 + 2) Cycloadditions: Computational Explorations of Mechanism.

Feng Long Gu, Peiyuan Yu, K N Houk, 2017, Journal of the American Chemical Society.

Synthesis of nitrogen-containing polycycles via rhodium(II)-induced cyclization-cycloaddition and insertion reactions of N-(diazoacetoacetyl)amides. Conformational control of reaction selectivity

J. Taunton, R. Pieters, A. Padwa, 1991 .

Stereoselective synthesis of bicyclic pyrrolidines by a rhodium-catalyzed cascade process.

N. Jacobsen, Luisa S. Gronenberg, M. Doyle, 2004, Angewandte Chemie.

Expedient access to substituted 3-amino-2-cyclopentenones by dirhodium-catalyzed [3+2]-annulation of silylated ketene imines and enoldiazoacetates.

P. Zavalij, M. Doyle, Xichen Xu, 2014, Chemical communications.

Simple and sustainable iron-catalyzed aerobic C-H functionalization of N,N-dialkylanilines.

M. Doyle, Xinfang Xu, M. Ratnikov, 2013, Journal of the American Chemical Society.

Stereoselectivity in metal carbene and Lewis acid-catalyzed reactions from diastereomeric dirhodium(II) carboxamidates: Menthyl N-acetyl-2-oxoimidazolidine-4(S)-carboxylates

M. Doyle, J. Colyer, J. P. Morgan, 2005 .

Dirhodium(II) Tetrakis[methyl 2‐oxapyrrolidine‐carboxylate]

A. E. Russell, M. Doyle, 2005 .

Dirhodium(II) Tetrakis[methyl 1‐(3‐phenylpropanoyl)‐2‐oxaimidazolidine‐carboxylate]

M. Doyle, Marcela Valenzuela, 2005 .

Amplification of asymmetric induction in sequential reactions of bis-diazoacetates catalyzed by chiral dirhodium(II) carboxamidates.

M. Doyle, Yuanhua Wang, Erhard Bappert, 2005, Organic letters.

Steric balance within chiral dirhodium(II) carboxamidate catalysts enhances stereoselectivity

M. Doyle, J. Colyer, 2003 .

The Influence of Ligands on Dirhodium(II) on Reactivity and Selectivity in Metal Carbene Reactions

M. Doyle, T. Ren, 2002 .

Catalyst Selection for Metal Carbene Transformations

D. J. Timmons, M. Doyle, 2001 .

Enantiocontrol in catalytic metal carbene reactions

M. Doyle, 1999 .

Chiral Catalyst Controlled Diastereoselection and Regioselection in Intramolecular Carbon-Hydrogen Insertion Reactions of Diazoacetates.

M. Doyle, A. V. Kalinin, D. Ene, 1997 .

Dirhodium(II) Tetraacetate Catalysed Hydroboration of Alkenes

M. Doyle, M. Jarstfer, M. Protopopova, 1993 .

High selectivity from configurational match/mismatch in carbon-hydrogen insertion reactions of steroidal diazoacetates catalyzed by chiral dirhodium(II) carboxamidates.

M. Doyle, S. Davies, E. May, 2001, The Journal of organic chemistry.

Highly Enantioselective Route to β-Lactams via Intramolecular C-H Insertion Reactions of Diazoacetylazacycloalkanes Catalyzed by Chiral Dirhodium(II) Carboxamidates

M. Doyle, A. Kalinin, A. Kalinin, 1995 .

Enantiocontrol and regiocontrol in lactam syntheses by intramolecular carbon-hydrogen insertion reactions of diazoacetamides catalyzed by chiral rhodium(II) carboxamides

M. Doyle, M. Protopopova, W. Winchester, 1992 .

Construction of β-lactams by highly selective intramolecular C-H insertion from rhodium(II) carboxylate catalyzed reactions of diazoacetamides

M. Doyle, W. Veal, M. Shanklin, 1988 .

Conformational and electronic preferences in rhodium(II) carboxylate and rhodium(II) carboxamide catalyzed carbon-hydrogen insertion reactions of N,N-disubstituted diazoacetoacetamides

J. Taunton, M. Doyle, Hoan Q. Pho, 1989 .

Challenges in the Highly Selective [3 + 1]-Cycloaddition of an Enoldiazoacetamide to Form a Donor–Acceptor Cis-Cyclobutenecarboxamide †

M. Doyle, Sipak Joyasawal, D. Ma, 2021, Molecules.

Chiral 3-Acylglutaric Acid Derivatives from Strain-Induced Nucleophilic retro-Claisen Ring-Opening Reactions.

M. Doyle, Rui Wang, Kostiantyn O. Marichev, 2020, The Journal of organic chemistry.

Synthesis of Chiral Tetrasubstituted Azetidines from Donor-Acceptor Azetines via Asymmetric Copper(I)-Catalyzed Imido-Ylide [3+1]-Cycloaddition with Metallo-Enolcarbenes.

Kan Wang, H. Arman, M. Doyle, 2019, Angewandte Chemie.

Enantioselective β-Lactone Formation from Phenyldiazoacetates via Catalytic Intramolecular Carbon-Hydrogen Insertion

M. Doyle, E. May, 2001 .

Highly enantioselective carbonyl-ene reactions of 2,3-diketoesters: efficient and atom-economical process to functionalized chiral α-hydroxy-β-ketoesters.

P. Zavalij, M. Doyle, P. Truong, 2014, Angewandte Chemie.

Reactivity Enhancement for Chiral Dirhodium(II) Tetrakis(Carboxamidates)

A. Slawin, M. Doyle, C. Moody, 2001 .

Allylic oxidations catalyzed by dirhodium caprolactamate via aqueous tert-butyl hydroperoxide: the role of the tert-butylperoxy radical.

Kan Wang, M. Doyle, E. McLaughlin, 2009, The Journal of organic chemistry.

Chiral Dirhodium Carboxamidates: Catalysts for Highly Enantioselective Syntheses of Lactones and Lactams

M. Doyle, 1996 .

Substrate versus Catalyst Control of Stereoselectivity in the Cyclopropanation of a Carbon-Carbon Double Bond Linked to the Reactant Diazoacetate through a Chiral Linker

M. Carducci, M. Doyle, T. Weathers, 2006 .

501 – Transition Metal Carbene Complexes: Cyclopropanation

M. Doyle, 1995 .

A new catalytic transformation of diazo esters: hydride abstraction in dirhodium(II)-catalysed reactions

M. Doyle, A. B. Dyatkin, C. Autry, 1995 .

Asymmetric syntheses with catalytic enantioselective metal carbene transformations

M. Doyle, 1994 .

Stereoselective synthesis of disubstituted 3(2H)-furanones via catalytic intramolecular C-H insertion reactions of α-diazo-β-keto esters including asymmetric induction

M. Doyle, T. Ye, M. Mckervey, 1994 .

β-Lactam formation via rhodium(II) catalyzed carbon-hydrogen insertion reactions of α-diazo amides

M. Doyle, S. Oon, F. R. V. D. Heide, 1993 .

Diazirines in carbenoid reactions catalyzed by rhodium(II) carboxylates

M. Doyle, K. High, S. Oon, 1989 .

Procatalysts for carbenoid transformations

J. Griffin, M. Doyle, Jose Da Conceicão, 1985 .

Olefin coordination with rhodium(II) trifluoroacetate

M. Doyle, Mark R. Colsman, M. S. Chinn, 1984 .

Catalytic role of copper triflate in Lewis acid promoted reactions of diazo compounds

M. Doyle, M. Trudell, 1984 .

Stereoselectivity of catalytic cyclopropanation reactions. Catalyst dependence in reactions of ethyl diazoacetate with alkenes

J. Griffin, M. Doyle, M. Trudell, 1984 .

Influence of olefin coordination on cyclopropanation selectivity

M. Doyle, K. Loh, Linda Wang, 1984 .

Correlations between catalytic reactions of diazo compounds and stoichiometric reactions of transition-metal carbenes with alkenes. Mechanism of the cyclopropanation reaction

J. Griffin, V. Bagheri, M. Doyle, 1984 .

Rearrangements of oxocyclopropanecarboxylate esters to vinyl ethers. Disparate behavior of transition-metal catalysts

M. Doyle, D. V. Leusen, 1983 .

Regioselectivity in catalytic cyclopropanation reactions

M. Doyle, R. L. Dorow, W. E. Buhro, 1982 .

Transition-metal-catalyzed rearrangements of oxocyclopropanes to vinyl ethers. Activation by vicinal carboalkoxy substituents

M. Doyle, D. V. Leusen, 1981 .

Efficient Alternative Catalysts and Methods for the Synthesis of Cyclopropanes from Olefins and Diazo Compounds

M. Doyle, D. V. Leusen, W. H. Tamblyn, 1981 .

Molybdenum hexacarbonyl catalyzed cyclopropanation of .alpha.,.beta.-unsaturated esters and nitriles and diazocarbonyl compounds

M. Doyle, J. G. Davidson, 1980 .

Medium effects. I. Solvolysis of 5-hexenyl p-nitrobenzenesulfonate in acetic acid-nonhydroxylic solvent (20:80) mixtures

M. Doyle, W. S. Trahanovsky, 1967 .

Dirhodium(II) caprolactamate: an exceptional catalyst for allylic oxidation.

M. Doyle, R. Forslund, A. Catino, 2004, Journal of the American Chemical Society.

Displacement of Dinitrogen by Oxygen: A Methodology for the Catalytic Conversion of Diazocarbonyl Compounds to Ketocarbonyl Compounds by 2,6-Dichloropyridine-N-oxide.

M. Doyle, Hui Cui, Yang Yu, 2018, Organic letters.

Olefin coordination with rhodium(II) perfluoroalkanoates in solution

M. Doyle, Mark R. Colsman, S. N. Mahapatro, 1987 .

Lewis acid promoted reactions of diazocarbonyl compounds. 3. Synthesis of oxazoles from nitriles through intermediate .beta.-imidatoalkenediazonium salts

M. Doyle, J. G. Davidson, M. Oppenhuizen, 1980 .

Lewis acid - promoted cyclopropanation of α,β-unsaturated carbonyl compounds by diazocarbonyl compounds. A facile synthesis of 1,2-disubstituted cyclopropylcarbonyl compounds of high isomeric purity

M. Doyle, J. Dellaria, W. E. Buhro, 1979 .

Discussion Addendum For: Allylic Oxidation Catalyzed by Dirhodium(II) Tetrakis[ε‐Caprolactamate] of tert ‐Butyldimethylsilyl‐Protected trans ‐Dehydroandrosterone

M. Doyle, Yong-liang Su, L. Angelis, 2019 .

Effective and highly stereoselective coupling with vinyldiazomethanes to form symmetrical trienes.

M. Doyle, M. Yan, 2002, The Journal of organic chemistry.

Brønsted Acid Catalyzed Oxocarbenium-Olefin Metathesis/Rearrangements of 1H-Isochromene Acetals with Vinyl Diazo Compounds.

Kan Wang, H. Arman, M. Doyle, 2021, Journal of the American Chemical Society.

Chiral catalyst enhancement of diastereocontrol for OH insertion reactions of styryl- and phenyldiazoacetate esters of pantolactone

M. Doyle, M. Yan, 2002 .

Regioselectivity in catalytic cyclopropanation reactions

M. Doyle, R. L. Dorow, W. E. Buhro, 1982 .

Enantioselectivity and cis/trans‐Selectivity in Dirhodium(II)‐Catalyzed addition of diazoacetates to olefins

P. Müller, M. Doyle, A. B. Dyatkin, 1995 .

A short stereoselective synthesis of (+)- and (−)-2-oxabicyclo[3.3.0]oct-6-en-3-one by intramolecular carbon–hydrogen insertion catalyzed by chiral dirhodium(II) carboxamidates

M. Doyle, A. Catino, 2003 .

The chemistry of vicinal tricarbonyls: an expedient route to fully-substituted 3-aminopyrroles

M. Doyle, P. Truong, Michael D Mandler, 2015 .

Highly regioselective and stereoselective silylformylation of alkynes under mild conditions promoted by dirhodium(II) perfluorobutyrate

M. Doyle, M. Shanklin, 1994 .

Chiral Dirhodium(II) Catalysts for Selective Metal Carbene Reactions

M. Doyle, Yongming Deng, Harathi D. Srinivas, 2015 .

(1R, 5S)-(-)-6,6-DIMETHYL-3-OXABICYCLO3.1.0HEXAN-2-ONE. HIGHLY ENANTIOSELECTIVE INTRAMOLECULAR CYCLOPROPANATION CATALYZED BY DIRHODIUM(II) TETRAKISMET HYL 2-PYRROLIDONE-5(R)-CARBOXYLATE : ((3-OXABICYCLO3.1.0HEXAN-2-ONE, 6,6-DI METHYL-, (1R-CIS)-)

M. Doyle, M. Protopopova, W. Winchester, 1996 .

Enantioselective Intramolecular Cyclopropanations of Allylic and Homoallylic Diazoacetates and Diazoacetamides Using Chiral Dirhodium(II) Carboxamide Catalysts

S. Liras, M. Dwyer, M. Doyle, 1995 .

Catalyst-Free Rearrangement of Allenyl Aryldiazoacetates into 1,5-Dihydro-4H-pyrazol-4-ones.

H. Arman, M. Doyle, Kostiantyn O. Marichev, 2016, The Journal of organic chemistry.

Preparation and Catalytic Properties of Immobilized Chiral Dirhodium(II) Carboxamidates

D. J. Timmons, M. Doyle, H. Gau, 2002 .

Reduction of arenediazonium salts by hydroquinone. Kinetics and mechanism for the electron-transfer step

K. Brown, M. Doyle, 1988 .

Silane reductions in acidic media. IV. Reductions of alkyl-substituted cyclohexanones by mono-, di-, and trialkylsilanes. Stereochemistry of alcohol and ether formation

M. Doyle, C. T. West, 1975 .

Silane reductions in acidic media. VII. Aluminum chloride catalyzed hydrogen-halogen exchange between organosilanes and alkyl halides. An efficient hydrocarbon synthesis

M. Doyle, C. C. McOsker, C. T. West, 1976 .

Cyclic ether formation in oxidations of primary alcohols by cerium(IV). Reactions of 5-phenyl-1-pentanol, 4-phenyl-1-butanol, and 3-phenyl-1-propanol with ceric ammonium nitrate

M. Doyle, L. Zuidema, T. R. Bade, 1975 .

Intramolecular regioselective insertion into unactivated prochiral carbon-hydrogen bonds with diazoacetates of primary alcohols catalyzed by chiral dirhodium(II) carboxamidates. Highly enantioselective total synthesis of natural lignan lactones

M. Doyle, Qi‐Lin Zhou, J. Bode, 1996 .

Reductive deamination of arylamines by alkyl nitrites in N,N-dimethylformamide. A direct conversion of arylamines to aromatic hydrocarbons

M. Doyle, B. Siegfried, J. Dellaria, 1977 .

Recent advances in stereoselective synthesis involving diazocarbonyl intermediates

M. Doyle, M. Mckervey, 1997 .

Reactions of the nitrosonium ion. IV. Nitrosative cleavage of the carbon-nitrogen double bond. Reaction of N-arylimines and ketimines with nitrosonium salts

M. Doyle, W. Wierenga, Mary A. Zaleta, 1972 .

Rhodium(II) Perfluorobutyrate Catalyzed Silane Alcoholysis. A Highly Selective Route to Silyl Ethers

R. Pieters, V. Bagheri, M. Doyle, 1990 .

Transition-metal-catalyzed rearrangements of oxocyclopropanes to vinyl ethers. Activation by vicinal carboalkoxy substituents

M. Doyle, D. V. Leusen, 1981 .

Cycloheptanone via a Lewis acid-catalyzed cyclization of 6-heptenoyl chloride to .beta.-chlorocycloheptanone

M. Doyle, W. S. Trahanovsky, P. Mullen, 1969 .

SILANE REDUCTIONS IN ACIDIC MEDIA PART 3, REDUCTIONS OF ALDEHYDES AND KETONES TO ALCOHOLS AND ALCOHOL DERIVATIVES, GENERAL SYNTHESES OF ALCOHOLS, SYMMETRICAL ETHERS, CARBOXYLATE ESTERS, AND ACETAMIDES

M. Doyle, D. Kooistra, S. Donnelly, 1974 .

New catalysts and methods for highly enantioselective metal carbene reactions

M. Doyle, 1998 .

Electronic and steric control in carbon-hydrogen insertion reactions of diazoacetoacetates catalyzed by dirhodium(II) carboxylates and carboxamides

W. P. Boone, W. N. E. Wolthuis, V. Bagheri, 1993 .

Asymmetric synthesis of lactones with high enantioselectivity by intramolecular carbon-hydrogen insertion reactions of alkyl diazoacetates catalyzed by chiral rhodium(II) carboxamides

M. Doyle, A. V. Oeveren, T. W. Clayton, 1991 .

Chiral rhodium(II) carboxamides. A new class of catalysts for enantioselective cyclopropanation reactions

L. Watkins, R. Pieters, M. Doyle, 1990 .

Control of chemoselectivity in catalytic carbenoid reactions. Dirhodium(II) ligand effects on relative reactivities

D. Austin, A. Padwa, S. F. Hornbuckle, 1992 .

Highly selective γ-lactone syntheses by intramolecular carbenoid carbon-hydrogen insertion in rhodium(II) carboxylate and rhodium(II) carboxamide catalyzed reactions of diazo esters

V. Bagheri, M. Doyle, Matthew M. Pearson, 1989 .

Homologation of acetals of α,β-unsaturated carbonyl compounds with diazo esters. Synthesis of acetals of β,γ-unsaturated carbonyl compounds

M. Doyle, J. Terpstra, M. Trudell, 1983 .

Chiral donor–acceptor azetines as powerful reactants for synthesis of amino acid derivatives

Kan Wang, H. Arman, M. Doyle, 2019, Nature Communications.

Improved enantioselection for chiral dirhodium(II) carboxamide-catalysed carbon-hydrogen insertion reactions of tertiary alkyl diazoacetates

C. Raab, M. Doyle, Qi‐Lin Zhou, 1995 .

Cycloheptatriene syntheses through rhodium(II) acetate-catalyzed intramolecular addition reactions of N-benzyldiazoacetamides

M. Doyle, M. Shanklin, Hoan Q. Pho, 1988 .

Enhancement of stereoselectivity in catalytic cyclopropanation reactions

M. Doyle, K. Loh, M. S. Chinn, 1987 .

Dirhodium(II) Tetrakis(perfluorobutyrate)

M. Doyle, 2001 .

Lewis acid-promoted 1,3-dipolar addition reactions of diazocarbonyl compounds. A general synthesis of oxazoles

M. Doyle, M. Oppenhuizen, R. C. Elliott, 1978 .

Silane reductions in acidic media. V. Reductions of alkyl-substituted cyclohexanones by di- and tri-tert-butylsilanes. Steric hindrance to nucleophilic attack at silicon in the trifluoroacetolysis of silyl alkyl ethers

M. Doyle, C. T. West, 1975 .

Hindered organosilicon compounds. Synthesis and properties of di-tert-butyl-, di-tert-butylmethyl-, and tri-tert-butylsilanes

M. Doyle, C. T. West, 1975 .

Dirhodium(II) Tetrakis(trifluoroacetate)

M. Doyle, H. Davies, J. R. Manning, 2006 .

Silane reductions in acidic media. VI. Mechanism of organosilane reductions of carbonyl compounds. Transition state geometries of hydride transfer reactions

M. Doyle, C. T. West, 1975 .

Radical-Mediated Strategies for the Functionalization of Alkenes with Diazo Compounds.

M. Doyle, Yong-liang Su, Junwen Liu, 2020, Journal of the American Chemical Society.

Diphenylglycoluril as a novel ligand architecture for dirhodium(II) carboxamidates

P. Zavalij, Yu Liu, L. Isaacs, 2008 .

Observations of Rhodium‐Containing Reaction Intermediates using HPLC with ICP‐MS and ESI‐MS Detection

C. Welch, Q. Tu, C. Raab, 2006 .

Synthesis of dirhodium(II) tetrakis[methyl 1-(3-phenylpropanoyl)-2-oxaimidazolidine-4(S)-carboxylate], Rh2(4S-MPPIM)4

M. Doyle, J. Colyer, 2003 .

Influences of catalyst configuration and catalyst loading on selectivities in reactions of diazoacetamides. Barrier to equilibrium between diastereomeric conformations.

M. Doyle, Wenhao Hu, A. Wee, 2003, Organic letters.

Enantiocontrol in intramolecular cyclopropanation of diazoketones. Conformational control of metal carbene alignment

M. Doyle, Qi‐Lin Zhou, Q. L. Zhou, 1997 .

Does an axial propeller shape on a dirhodium(III,III) core affect equatorial ligand chirality?

C. Welch, P. Zavalij, Lei Zhou, 2011 .

Oxidative deamination of primary amines: selective synthesis of geminal dihalides

M. Doyle, B. Siegfried, 1976 .

Enhancement of enantiocontrol/diastereocontrol in catalytic intramolecular cyclopropanation and carbon-hydrogen insertion reactions of diazoacetates with Rh2(4S-MPPIM)4

M. Doyle, Qi‐Lin Zhou, A. B. Dyatkin, 1995 .

Macrocyclic lactones from dirhodium(II)-catalyzed intramolecular cyclopropanation and carbon-hydrogen insertion

C. Poulter, M. Doyle, D. Rogers, 1995 .

Effective Uses of Dirhodium(II) Tetrakis[methyl 2-oxopyrrolidine-5(R or S)-carboxylate] for Highly Enantioselective Intermolecular Cyclopropenation Reactions

P. Müller, M. Doyle, E. Shapiro, 1994 .

Diastereocontrol for Highly Enantioselective Carbon-Hydrogen Insertion Reactions of Cycloalkyl Diazoacetates

P. Mueller, M. Doyle, G. Roos, 1994 .

Enantioselective metal carbene transformations with polyethylene-bound soluble recoverable dirhodium(II) 2-pyrrolidone-5(S)-carboxylates

D. Bergbreiter, M. Doyle, H. Gray, 1992 .

Divergence of carbonyl ylide reactions as a function of diazocarbonyl compound and aldehyde substituent: dioxolanes, dioxolenes, and epoxides.

A. E. Russell, Luisa S. Gronenberg, M. Doyle, 2004, The Journal of organic chemistry.

Epoxides and aziridines from diazoacetates via ylide intermediates.

D. J. Timmons, M. Doyle, W. Hu, 2001, Organic letters.

Disproportionation of trityl alkyl ethers. Synthesis of aldehydes and ketones in a cationic chain reaction involving hydride transfer

D. Scholten, M. Doyle, D. DeBruyn, 1973 .

Dirhodium-catalyzed phenol and aniline oxidations with T-HYDRO. Substrate scope and mechanism of oxidation.

M. Doyle, M. Ratnikov, S. El-khalafy, 2011, The Journal of organic chemistry.

Stereoselectivity of catalytic cyclopropanation reactions. Catalyst dependence in reactions of ethyl diazoacetate with alkenes

J. Griffin, M. Doyle, M. Trudell, 1984 .

Correlations between catalytic reactions of diazo compounds and stoichiometric reactions of transition-metal carbenes with alkenes. Mechanism of the cyclopropanation reaction

J. Griffin, V. Bagheri, M. Doyle, 1984 .

In search of high stereocontrol for the construction of cis-disubstituted cyclopropane compounds. Total synthesis of a cyclopropane-configured urea-PETT analogue that is a HIV-1 reverse transcriptase inhibitor.

D. J. Timmons, M. Doyle, Wenhao Hu, 2002, Organic letters.

Dirhodium(II) Tetraoctanoate

M. Doyle, H. Davies, J. R. Manning, 2006 .

Perspective on dirhodium carboxamidates as catalysts.

M. Doyle, 2006, The Journal of organic chemistry.

RHODIUM(II) PERFLUOROBUTYRATE CATALYZED HYDROSILYLATION OF 1-ALKYNES. TRANS ADDITION AND REARRANGEMENT TO ALLYLSILANES

M. Doyle, T. W. Clayton, K. High, 1991 .

Macrocycle Formation from Catalytic Metal Carbene Transformations

M. Doyle, Wenhao Hu, 2001 .

Enantiocontrolled macrocycle formation by catalytic intramolecular cyclopropanation

M. Doyle, Wenhao Hu, Alan B. Marnett, 2000 .

Enantiocontrol in Macrocycle Formation from Catalytic Metal Carbene Transformations

M. Doyle, Wenhao Hu, 2001 .

Highly Regio-, Diastereo-, and Enantioselective Rhodium-Catalyzed Intramolecular Cyclopropanation of (Z)-1,3-Dienyl Aryldiazoacetates.

H. Arman, M. Doyle, Kostiantyn O. Marichev, 2017, Organic letters.

Enantiocontrolled Macrocycle Formation by Catalytic Intramolecular Cyclopropanation.

M. Doyle, Wenhao Hu, J. Vitale, 2000 .

Enantioselective carbon-hydrogen insertion is an effective and efficient methodology for the synthesis of (R)-(-)-baclofen.

M. Doyle, Wenhao Hu, 2002, Chirality.

Chiral Catalysts for Enantioselective Carbenoid Cyclopropanation Reactions

M. Doyle, 1991 .

Generation of Halomethyl Radicals by Halogen Atom Abstraction and Their Addition Reactions with Alkenes.

Xinhao Zhang, M. Doyle, Yong-liang Su, 2019, Journal of the American Chemical Society.

Highly efficient regioselective silylcarbonylation of alkynes catalyzed by dirhodium(II) perfluorobutyrate

M. Doyle, M. Shanklin, 1993 .

High enantioselectivity in the intramolecular cyclopropanation of allyl diazoacetates using a novel rhodium(II) catalyst

P. Mueller, R. Pieters, M. Doyle, 1991 .

Enantioselective intramolecular cyclopropanation of N-allylic- and N-homoallylic diazoacetamides catalyzed by chiral dirhodium(II) catalysts

M. Doyle, M. Protopopova, M. Eismont, 1994 .

High Enantioselectivity in the Intramolecular Cyclopropanation of Allyl Diazoacetates Using a Novel Rhodium(II) Catalyst.

R. Pieters, M. Doyle, S. Martin, 1991 .

Comparative evaluation of enantiocontrol for intramolecular cyclopropanation of diazoacetates with chiral CuI, RhII and RuII catalysts

M. Doyle, H. Nishiyama, Qilin Zhou, 1997 .

Alkyl nitrite-metal halide deamination reactions. 5. In situ generation of nitrosyl halides. Effective product control from nitrosyl chloride diazotization of primary aliphatic amines in N,N-dimethylformamide

Paul G. Seites, M. Doyle, R. J. Bosch, 1978 .

Chemical and electrochemical oxidation of O,O,O-trisubstituted phosphorothioates and triphenylphosphine sulfide

M. Doyle, Daniel J. Smith, R. Blankespoor, 1983 .

M. Doyle, William J. Bryker, 1979 .

Reactions of the nitrosonium ion. V. Nitrosative cleavage of the carbon-nitrogen double bond. Attempted exchange of oxygen for nitrogen

M. Doyle, W. Wierenga, Mary A. Zaleta, 1973 .

Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate.

M. Doyle, Hojae Choi, 2007, Organic letters.

Reactions of the nitrosonium ion. 11. Fluoride transfer from complex fluoride anions to carbenium ions in the nitrosative decomposition of aliphatic azides

M. Doyle, R. J. Bosch, J. L. Whitefleet, 1979 .

High enantioselectivity for intermolecular cyclopropenation of alkynes by diazo esters catalyzed by chiral dirhodium(II) carboxamides

P. Mueller, M. Doyle, M. Protopopova, 1992 .

Addition of arylchlorocarbenes to α,β-unsaturated esters. Absolute rates, substituent effects, and variable reactivities

J. E. Jackson, M. Doyle, M. Platz, 1988 .

Diazo Chemistry II: Aliphatic, Inorganic and Organometallic Compounds By Heinrich Zollinger (Swiss Federal Institute of Technology). VCH: New York. 1995. xiii + 522 pp. $125.00. ISBN 3-527-29222-5.

M. Doyle, 1996 .

Formation and Reactions of Dithiodicarbenium Salts

M. Doyle, R. Blankespoor, D. Hedstrand, 1982 .

A Spectrometric Study of the Oxidation of Alcohols by Cerium(IV).

M. Doyle, 1974 .

Activation parameters for the reaction of phenylchloro carbene with pyridine, tri-n-butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins

J. E. Jackson, M. Doyle, M. Platz, 1989 .

Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbene

J. E. Jackson, J. Taunton, M. Doyle, 1988 .

Spirolactones from Dirhodium(II)-Catalyzed Diazo Decomposition with Regioselective Carbon-Hydrogen Insertion.

M. Doyle, A. B. Dyatkin, 1995 .

Dirhodium(II) Tetraacetamidate

M. Doyle, R. Forslund, 2007 .

Stereoselective Synthesis of Substituted 5-Hydroxy-1,3-dioxanes

D. C. Forbes, M. Doyle, D. Ene, 1998 .

Versatile Donor‐Acceptor Cyclopropenes in Metal Carbene Transformations

M. Doyle, Yongming Deng, 2016 .

SPIROLACTONES FROM DIRHODIUM(II)-CATALYZED DIAZO DECOMPOSITION WITH REGIOSELECTIVE CARBON-HYDROGEN INSERTION

M. Doyle, A. B. Dyatkin, 1995 .

Free-radical rearrangements in the thermal decomposition of tert-butylperoxy 3-(1-phenylcyclopropyl)propanoate, 4-(1-phenylcyclopropyl)butanoate, and 5-(1-phenylcyclopropyl)pentanoate

M. Doyle, W. C. Danen, C. T. West, 1973 .

Determination of a geometry and dead time correction factor for neutron activation analysis

Michael P. Doyle, M. Doyle, Gerald L. Hoffman, 1974 .

Oxidation and reduction of hemoproteins by trioxodinitrate(II). The role of nitrosyl hydride and nitrite

R. Broene, M. Doyle, S. N. Mahapatro, 1988 .

Chemoselectivity and enantiocontrol in catalytic intramolecular metal carbene reactions of diazo acetates linked to reactive functional groups by naphthalene-1,8-dimethanol

D. C. Forbes, M. Doyle, Thomas H. Pillow, 1999 .

Intramolecular cycloaddition/rearrangement cascade from gold(iii)-catalysed reactions of propargyl aryldiazoesters with cinnamyl imines.

H. Arman, M. Doyle, Wenhao Hu, 2018, Chemical communications.

Synthesis of allenes by [2,3]-sigmatropic rearrangement of prop-2-yn-1-yl oxonium ylides formed in rhodium(II) carboxylate catalysed reactions of diazo compounds

V. Bagheri, M. Doyle, E. Claxton, 1990 .

ALKYL NITRITE‐METAL HALIDE DEAMINATION REACTIONS. 2. SUBSTITUTIVE DEAMINATION N OF ARYLAMINES BY ALKYL NITRITES AND COPPER(II) HALIDES. A DIRECT AND REMARKABLY EFFICIENT CONVERSION OF ARYLAMINES TO ARYL HALIDES

M. Doyle, B. Siegfried, J. Dellaria, 1977 .

An efficient methodology to substituted furans via oxidation of functionalized α-diazo-β-ketoacetates.

M. Doyle, Xinfang Xu, P. Truong, 2011, Tetrahedron letters.

Nitrosative oxidation of arylhydrazines by alkyl nitrites and copper(II) halides

M. Doyle, W. Fobare, B. Siegfried, 1977 .

ALKYL NITRITE-METAL HALIDE DEAMINATION REACTIONS. PART IV. NITROSATIVE OXIDATION OF ARYLHYDRAZINES BY ALKYL NITRITES AND COPPER(II) HALIDES

M. Doyle, W. Fobare, B. Siegfried, 1977 .

Contemporary Carbene Chemistry: Moss/Contemporary Carbene Chemistry

R. Moss, M. Doyle, 2013 .

Intermolecular [5 + 1]-Cycloaddition between Vinyl Diazo Compounds and tert-Butyl Nitrite to 1,2,3-Triazine 1-Oxides and Their Further Transformation to Isoxazoles.

M. Doyle, Haifeng Zheng, Hadi Arman, 2021, Organic letters.

Strain-Induced Nucleophilic Ring Opening of Donor-Acceptor Cyclopropenes for Synthesis of Monosubstituted Succinic Acid Derivatives.

Kan Wang, M. Doyle, Jinping Lei, 2020, Chemistry.

Diverse Reactions of Vinyl Diazo Compounds with Quinone Oxonium Ions, Quinone Imine Ketals, and Eschenmoser’s Salt

Kan Wang, M. Doyle, W. Griffith, 2021, ACS Catalysis.

Vinyldiazolactone as a vinylcarbene precursor: Highly selective C-H insertion and cyclopropanation reactions.

M. Doyle, D. Bykowski, Kou-Hui Wu, 2006, Journal of the American Chemical Society.

Contemporary Carbene Chemistry

R. Moss, M. Doyle, 2013 .

A facile route to some useful homochiral alkyl Imidazolidin-2-one-4(S)-carboxylates

C. Raab, M. Doyle, G. Roos, 1996 .

Inverse Electron Demand Diels-Alder-Type Heterocycle Syntheses with 1,2,3-Triazine 1-Oxides: Expanded Versatility.

M. Doyle, G. Rivera, Soumen Biswas, 2023, Organic letters.

Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleate

M. Doyle, Michael T. H. Liu, K. Loh, 1986 .

Nucleophilic character of an electrophilic carbene. Synthesis of cyclopropanes by thermal decomposition of 3-chloro-3-phenyldiazirine

C. Winter, M. Doyle, J. Terpstra, 1984 .

Nucleophilic Reactivity of the Carbon-Carbon Double Bond. VI. The Use of Urea as a Base in Acetolysis Reactions

M. Doyle, W. S. Trahanovsky, P. Bartlett, 1967 .

Formation of a Dipolar Adduct in the Reaction of Arylchlorocarbenes with Diethyl Maleate.

M. Doyle, Michael T. H. Liu, K. Loh, 1987 .

Application of α-Aminoalkyl Radicals as Reaction Activators

M. Doyle, Yong‐Liang Su, 2021, Synthesis.

Identification and characterization of isomeric intermediates in a catalyst formation reaction by means of speciation analysis using HPLC-ICPMS and HPLC-ESI-MS.

C. Welch, Q. Tu, C. Raab, 2006, Analytical chemistry.

C-H functionalization.

K. I. Goldberg, M. Doyle, 2012, Accounts of Chemical Research.

Brønsted Acid Catalyzed Friedel-Crafts-type Coupling and Dedinitrogenation Reactions of Vinyldiazo Compounds.

H. Arman, M. Doyle, Daniel J. Wherritt, 2020, Angewandte Chemie.

Brønsted Acid Catalyzed Friedel-Crafts-type Coupling and Dedinitrogenation Reactions of Vinyldiazo Compounds.

H. Arman, M. Doyle, Daniel J. Wherritt, 2020, Angewandte Chemie.

Total synthesis of (S)-(+)-imperanene. Effective use of regio- and enantioselective intramolecular carbon-hydrogen insertion reactions catalyzed by chiral dirhodium(II) carboxamidates.

M. Doyle, Wenhao Hu, Marcela Valenzuela, 2002, The Journal of organic chemistry.

Total Synthesis of (S)‐(+)‐Imperanene. Effective Use of Regio‐ and Enantioselective Intramolecular Carbon—Hydrogen Insertion Reactions Catalyzed by Chiral Dirhodium(II) Carboxamidates.

M. Doyle, Wenhao Hu, Marcela Valenzuela, 2002 .

Dinitrogen extrusion from enoldiazo compounds under thermal conditions: synthesis of donor-acceptor cyclopropenes.

M. Doyle, Yongming Deng, Changcheng Jing, 2015, Chemical communications.

Nitrosative cleavage of benzalazine and related aldehyde azines. Production, decomposition and trapping of iminodiazonium ions

M. Doyle, W. Wierenga, James E. DeBoer, 1974 .

Reactions of the nitrosonium ion. II. Reactions of triphenylmethyl, benzhydryl, and benzyl azides with nitrosonium compounds

M. Doyle, W. Wierenga, 1972 .

Polyfunctionalization of vicinal carbon centers and synthesis of unsymmetric 1,2,3,4-tetracarbonyl compounds

M. Doyle, Daniel J. Wherritt, R. Koenigs, 2023, Nature Communications.

Cu(OTf)2-Catalyzed Three-Component Imino Diels-Alder Reaction Using Propenylbenzenes: Synthesis of 2,4-Diaryl Tetrahydroquinoline Derivatives

M. Doyle, V. Kouznetsov, A. R. Bohórquez, 2011 .

Intramolecular Catalytic Asymmetric Carbon—Hydrogen Insertion Reactions. Synthetic Advantages in Total Synthesis in Comparison with Alternative Approaches.

Yu Liu, M. Doyle, M. Ratnikov, 2011 .

Construction of Highly Functionalized Diazoacetoacetates via Catalytic Mukaiyama—Michael Reactions.

Yu Zhang, Yu Liu, M. Doyle, 2008 .

Polyether macrocycles from intramolecular cyclopropanation and ylide formation. Effect of catalyst and coordination.

M. Doyle, Yuanhua Wang, T. Weathers, 2006, The Journal of organic chemistry.

Optimization of enantiocontrol in cis-selective cyclopropanation reactions catalyzed by dirhodium(II) tetrakis[alkyl 2-oxaazetidine-4(S)-carboxylates]

M. Doyle, Wenhao Hu, S. Davies, 2000 .

REARRANGEMENTS OF YLIDES GENERATED FROM REACTIONS OF DIAZO COMPOUNDS WITH ALLYL ACETALS AND THIOKETALS BY CATALYTIC METHODS. HETEROATOM ACCELERATION OF THE (2,3)-SIGMATROPIC REARRANGEMENT

J. Griffin, M. Doyle, M. S. Chinn, 1984 .

Synthesis of 2-deoxyxylolactone from glycerol derivatives via highly enantioselective carbon-hydrogen insertion reactions

J. Tedrow, M. Doyle, A. B. Dyatkin, 1994 .

Steric selectivity in oxidations of diols

V. Bagheri, R. L. Dow, M. Doyle, 1980 .

Nickel(II) bromide-catalyzed oxidations of primary and secondary alcohols to carbonyl compounds by benzoyl peroxide

M. Doyle, W. Patrie, S. Williams, 1979 .

The disproportionation of trityl benzyl ethers. Kinetic analysis of the trityl salt catalyzed reaction. Evidence for the involvement of ion pairs in the hydrogen transfer step

M. Doyle, B. Siegfried, 1976 .

Selective Oxidations of Alcohols by Bromine in Combination with Nickel(II) Benzoate

R. L. Dow, M. Doyle, 1981 .

THE DISPROPORTIONATION OF TRITYL BENZYL ETHERS. KINETIC ANALYSIS OF THE TRITYL SALT CATALYZED REACTION. EVIDENCE FOR THE INVOLVEMENT OF ION PAIRS IN TH HYDROGEN TRANSFER STEP

M. Doyle, B. Siegfried, 1976 .

Autocatalytic oxidation of hemoglobin induced by nitrite: activation and chemical inhibition.

J. Herman, M. Doyle, R. Dykstra, 1985, Journal of free radicals in biology & medicine.

Enhanced enantiocontrol in catalytic metal carbene transformations with dirhodium (II) tetrakis[methyl 2‐oxooxazolidin‐4(S)‐carboxylate], Rh2(4S‐MEOX)4

V. Lynch, M. Doyle, R. Ghosh, 2010 .

Synthesis of pyrrolizidine bases by highly diastereoselective and regioselective catalytic carbon-hydrogen insertion reactions of chiral pyrrolidinediazoacetamides

M. Doyle, A. V. Kalinin, Alexey V. Kalinin, 1996 .

Synthesis of 2-Deoxyxylolactone from Glycerol Derivatives via Highly Enantioselective Carbon-Hydrogen Insertion Reactions.

J. Tedrow, M. Doyle, A. B. Dyatkin, 1994 .

Oxidation of hemoglobin and myoglobin by alkyl nitrites inhibition by oxygen.

M. Doyle, R. A. Pickering, D. M. Lepoire, 1981, The Journal of biological chemistry.

Silane reductions in acidic media. 9. The effect of Lewis acids on stereoselectivities in ketone reductions. The principle of complexation-induced conformational perturbation. Energy minimization in the transition states for hydride transfer

M. Doyle, N. Ball, C. C. McOsker, 1977 .

Medium effects. II. Cyclization of 6-heptenyl p-nitrobenzenesulfonate during solvolysis in 2,2,2-trifluoroethanol☆

M. Doyle, W. S. Trahanovsky, 1968 .

A New Enantioselective Synthesis of Milnacipran and an Analogue by Catalytic Asymmetric Cyclopropanation

M. Doyle, Wenhao Hu, 2001 .

Asymmetric Catalysis. Part 108. Copper Catalysts with Optically Active Ligands in the Enantioselective Meerwein Arylation of Activated Olefins.

H. Brunner, M. Doyle, C. Bluechel, 1998 .

Catalyst-Free Formation of Nitrile Oxides and Their Further Transformations to Diverse Heterocycles.

H. Arman, M. Doyle, Daniel J. Wherritt, 2021, Organic letters.

LEWIS ACID PROMOTED REACTIONS OF DIAZOCARBONYL COMPOUNDS. 3. SYNTHESIS OF OXAZOLES FROM NITRILES THROUGH INTERMEDIATE β-IMIDATOALKENEDIAZONIUM SALTS

M. Doyle, J. G. Davidson, M. Oppenhuizen, 1981 .

Lewis Acid Catalyzed Diastereoselective 1,3-Dipolar Cycloaddition Between Diazoacetoacetate Enones and Azomethine Ylides.

M. Doyle, P. Truong, Michael D Mandler, 2014 .

Silver‐Catalyzed Carbene Functionalization of Methane in Supercritical Carbon Dioxide

M. Doyle, 2011 .

Chemoselectivity in dirhodium(II) catalyzed reactions of diazoacetoacetates prepared from α,β-unsaturated ketones

M. Doyle, Yu Zhang, 2010 .

Metal Carbene Reactions from Dirhodium(II) Catalysts

M. Doyle, 2005 .

Enantioselectivity for catalytic cyclopropanation with diazomalonates

M. Doyle, Wenhao Hu, 2003 .

Attempted synthesis of casbene by intramolecular cyclopropanation

M. Doyle, M. Yan, 2002 .

First attempts at differential diastereoselection in catalytic reactions of N-chirally substituted dirhodium(ii) tetrakis[methyl 2-oxoimidazolidine-4(S)-carboxylates] with diazoacetates

D. J. Timmons, M. Doyle, J. Colyer, 2001 .

Exceptional Selectivity in Cyclopropanation Reactions Catalyzed by Chiral Cobalt(II) Porphyrins **

M. Doyle, 2012 .

Comparative enantiocontrol with allyl phenyldiazoacetates in asymmetric catalytic intramolecular cyclopropanation.

M. Doyle, Wenhao Hu, T. Weathers, 2003, Chirality.

Untitled Document

M. Doyle, E. Eliel, S. Wilen, 2001 .

Dirhodium(II) Tetrakis[methyl 2‐oxooxazolidine‐4(S)‐carboxylate]

A. E. Russell, M. Doyle, K. Kundu, 2005 .

Diverse Pathways in Catalytic Reactions of Propargyl Aryldiazoacetates: Selectivity between Three Reaction Sites.

M. Doyle, Kostiantyn O. Marichev, H. Qiu, 2017, The Journal of organic chemistry.

Structural effects in alkyl nitrite oxidation of human hemoglobin.

M. Doyle, R. A. Pickering, J. D. da Conceição, 1984, The Journal of biological chemistry.

Simple and sustainable iron-catalyzed aerobic C-H functionalization of N,N-dialkylanilines.

M. Doyle, Xinfang Xu, M. Ratnikov, 2013, Journal of the American Chemical Society.

C-H functionalization.

K. I. Goldberg, M. Doyle, 2012, Accounts of chemical research.

Silane reductions in acidic media : VIII. Boron trifluoride catalyzed organosilane reductions. selectivity and mechanism

M. Doyle, C. C. McOsker, S. Donnelly, 1976 .

Oxidation of deoxyhemerythrin to semi-methemerythrin by nitrite.

J. Nocek, M. Doyle, D. Kurtz, 1984, The Journal of biological chemistry.

MECHANISM OF NITROSYL TRANSFER. DISSOCIATION OF NITRIC OXIDE FROM COBALT NITROSYLS

M. Doyle, R. A. Pickering, R. Dykstra, 1982 .

Enantioselective Syntheses of 2-Deoxyxylono-1,4-lactone and 2-Deoxyribono-1,4-lactone from 1,3-Dioxan-5-yl Diazoacetates.

J. Tedrow, M. Doyle, A. B. Dyatkin, 1999, The Journal of organic chemistry.

Highly Enantioselective Intramolecular Cyclopropanation Reactions of N-Allylic-N-methyldiazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxamidates

M. Doyle, A. V. Kalinin, 1996 .

Optimization of Enantiocontrol for Carbon-Hydrogen Insertion with Chiral Dirhodium(II) Carboxamidates. Synthesis of Natural Dibenzylbutyrolactone Lignans from 3-Aryl-l-propyl Diazoacetates in High Optical Purity

V. Lynch, M. Doyle, Qi‐Lin Zhou, 1995 .

Unsymmetrical alkenes by carbene coupling from diazirine decomposition in the presence of diazo compounds

M. Doyle, J. Terpstra, S. N. Mahapatro, 1987 .

Highly Selective Synthesis of a 2-Deoxyxylonolactam via Enantioselective Carbon-Hydrogen Insertion Reactions Using Chiral Dirhodium(II) Carboxamidates

D. J. Timmons, M. Doyle, M. Yan, 2002 .

Synthesis, Structure and Reactivity of a Novel Series of Diastereomeric Dirhodium(II) Tetracarboxamidates. Catalysts for Asymmetric Diazoacetate Transformations

V. Lynch, C. Raab, M. Doyle, 1998 .

Dirhodium(II)-catalyzed formal [3+2+1]-annulation of azomethine imines with two molecules of a diazo ketone.

P. Zavalij, M. Doyle, Xinfang Xu, 2013, Chemical Communications.

Cycloaddition reactions of enoldiazo compounds.

M. Doyle, Yongming Deng, Marianne Lankelma, 2017, Chemical Society reviews.

Dirhodium(II)-Catalyzed Annulation of Enoldiazoacetamides with α-Diazoketones: An Efficient and Highly Selective Approach to Fused and Bridged Ring Systems.

H. Arman, M. Doyle, Q. Cheng, 2016, Angewandte Chemie.

Stereoselective synthesis of bicyclic pyrrolidines by a rhodium-catalyzed cascade process.

N. Jacobsen, Luisa S. Gronenberg, M. Doyle, 2004, Angewandte Chemie.

Stereoretentive Catalytic [3 + 2]/[3 + 3]-Cycloaddition of Nonracemic Donor-Acceptor Cyclopropanes: Synthesis of Substituted Pyrrolidines and 1,2-Oxazinanes.

M. Bao, M. Doyle, 2023, Organic letters.

Asymmetric [3+3] Cycloaddition for Heterocycle Synthesis

M. Doyle, Yongming Deng, Q. Cheng, 2017, Synlett.