R. Hughes

发表

Conversion of Carbon–Fluorine Bonds α to Transition Metal Centers to Carbon–Hydrogen, Carbon–Carbon, and Carbon–Heteroatom Bonds

R. Hughes, 2009 .

Bonding Analysis of TM(cAAC)2 (TM = Cu, Ag, and Au) and the Importance of Reference State

F. Weinhold, R. Hughes, C. Landis, 2015 .

Octahedral perfluoroalkyl complexes of Ir(III) formed by oxidative addition of perfluoroalkyl iodides to Ir(acac)(CO)2

A. Rheingold, R. Hughes, Hui Huang, 2009 .

Synthesis and structure of ferrocenylmethylphosphines, their borane adducts, and some related derivatives

A. Rheingold, R. Hughes, J. Golen, 2009 .

Organo-Transition Metal Compounds Containing Perfluorinated Ligands

R. Hughes, 2010 .

Octafluorocyclooctatetraene transition metal compounds: displacement of fluoride by metal carbonyl anions

Deborah E. Samkoff, S. Doig, S. Patt, 1983 .

Synthesis, Structure, and Luminescence of Copper(I) Halide Complexes of Chiral Bis(phosphines).

R. B. Arthur, H. Patterson, A. Nicholas, 2017, Inorganic chemistry.

Competing (4+2) and (2+2) cycloaddition reactions of tetrafluorothiophene-S,S-dioxide with phenylacetylene: A computational study

R. Hughes, D. Lemal, 2019, Journal of Fluorine Chemistry.

Heterocycles Derived from Generating Monovalent Pnictogens within NCN Pincers and Bidentate NC Chelates: Hypervalency versus Bell-Clappers versus Static Aromatics

Libor Dostál, A. Růžička, A. Rheingold, 2018, Organometallics.

Fluorocarbene, fluoroolefin, and fluorocarbyne complexes of Rh

David E. Herbert, R. Hughes, Christopher J. Pell, 2017, Chemical science.

Synthesis of a Tris(phosphaalkene)phosphine Ligand and Fundamental Organometallic Reactions on Its Sterically Shielded Metal Complexes

C. Krause, A. Rheingold, R. Hughes, 2016 .

What controls regiochemistry in 1,3-dipolar cycloadditions of münchnones with nitrostyrenes?

G. Gribble, R. Hughes, J. Lopchuk, 2013, Organic letters.

Synthesis and structural characterization of group 6 transition metal complexes with terminal fluoromethylidyne (CF) ligands; a DFT/NBO/NRT comparison of bonding characteristics of terminal NO, CF and CH ligands.

A. Rheingold, R. Hughes, Hui Huang, 2011, Dalton transactions.

Synthesis of Phosphine-Ligated Zinc Acetylide Dimers: Enhanced Reactivity in Carbonyl Additions

A. Oliver, B. Ashfeld, Erin E. Wilson, 2011 .

E-Selective Synthesis and Coordination Chemistry of Pyridine-Phosphaalkenes: Five Ligands Produce Four Distinct Types of Ru(II) Complexes.

T. J. O'Donnell, A. Rheingold, R. Hughes, 2019, Organometallics.

P-Alkynyl functionalized benzazaphospholes as transmetalating agents.

T. J. O'Donnell, D. Y. Zhou, C. Krause, 2021, Dalton transactions.

Crystallographic Studies of fac- and mer-Isomers of Cu[1,4,7,10,13,16-hexaazacyclooctadecane]2+. Influence of Counterion and Crystallization Solvent on Crystal Structure and Dynamic Jahn-Teller Effects. Computational Studies of Structures, Energetics, and Mechanism of mer-fac Isomerization

A. Rheingold, E. Wong, R. Hughes, 2022, Polyhedron.

A Masked Phosphinidene Trapped in a Fluxional NCN Pincer.

A. Rheingold, R. Hughes, W. Yoshida, 2016, Chemistry.

Organometallic Fluorine Chemistry

M. G. Campbell, R. Hughes, T. Braun, 2015 .

Near-infrared light activated azo-BF2 switches.

Y. Yang, I. Aprahamian, R. Hughes, 2014, Journal of the American Chemical Society.

Cyanide detection using a triazolopyridinium salt.

I. Aprahamian, R. Hughes, Xin Su, 2013, Organic letters.

Gallium(III)-catalyzed three-component (4+3) cycloaddition reactions.

R. Hughes, Hui Li, Jimmy Wu, 2012, Angewandte Chemie.

Selective Solubility of Organometallic Complexes in Saturated Fluorocarbons. Synthesis of Cyclopentadienyl Ligands with Fluorinated Ponytails

R. Hughes, H. Trujillo, 1996 .

A New Stepwise Mechanism for Formation of a Metallacyclobutane via a Singlet Diradical Intermediate

D. Ess, Jack Fuller, R. Hughes, 2015 .

Transition metal-promoted reactions of unsaturated hydrocarbons : IV. Reactions of norbornenyl complexes of palladium(II) with group V donor ligands, olefins, 1,3-dienes and 1,2-dienes

R. Hughes, J. Powell, E. Ban, 1974 .

Transition metal promoted reactions of unsaturated hydrocarbons : II. Insertion of bicyclic olefins into allylic-palladium and -platinum bonds

R. Hughes, J. Powell, 1973 .

Manipulating liquid-crystal properties using a pH activated hydrazone switch.

I. Aprahamian, R. Hughes, Xin Su, 2013, Angewandte Chemie.

Fluoroalkylation of cobalt complexes: selective reactions at the metal or the cyclopentadienyl ring

A. Rheingold, R. Hughes, B. Holliday, 1997 .

Syntheses and crystallographic studies of [Ir(η5-C5Me5)(L)(RF)I] (L = CO, PMe3; RF = CF2CF3, CF2CF2CF3, CF2C6F5, CF(CF3)2) complexes. Cone and solid angle steric parameters for perfluoroalkyl ligands

C. Incarvito, Jeremy M. Smith, A. Rheingold, 2000 .

Synthesis and structure of intermediates in copper-catalyzed alkylation of diphenylphosphine.

A. Rheingold, R. Hughes, J. Golen, 2010, Inorganic chemistry.

Tuning the fluorous partition coefficients of organometallic complexes. The synthesis and characterization of [η5-C5H4CH2CH2(CF2)9CF3]Rh(CO)L (L = CO or P[CH2CH2(CF2)5CF3]3) and Cl2Ni{P[CH2CH2(CF2)5CF3]3}2

I. Horváth, V. Herrera, R. Hughes, 1998 .

Cationic Two-Coordinate Complexes of Pd(I) and Pt(I) Have Longer Metal-Ligand Bonds Than Their Neutral Counterparts

Jia Zhou, K. Meyer, R. Hughes, 2016 .

Coordination contributions to protein stability in metal-substituted carbonic anhydrase

George P. Lisi, R. Hughes, D. Wilcox, 2016, JBIC Journal of Biological Inorganic Chemistry.

Inversion of Configuration at the Phosphorus Nucleophile in the Diastereoselective and Enantioselective Synthesis of P-Stereogenic syn-Phosphiranes from Chiral Epoxides.

A. Rheingold, R. Hughes, C. Moore, 2018, Angewandte Chemie.

Syntheses, solution behavior, and computational bond length analyses of trifluoromethyl and perfluoroethyl cuprate salts

D. Dixon, R. Hughes, D. Vicic, 2020 .

Conversion of Perfluorobenzyl Complexes of Rhodium to Fluorinated Oxarhodacycles

A. Rheingold, R. Hughes, Danielle C. Lindner, 2001 .

Perfluorobenzyl Complexes of Cobalt and Rhodium. Unusual Coupling between Pentafluorophenyl and Pentamethylcyclopentadienyl Rings

A. Rheingold, G. Yap, R. Hughes, 1996 .

Synthesis and molecular structures of titanocene, zirconocene, and uranocene dichlorides containing 1,2-di-tert-butylcyclopentadienyl ligands

A. Rheingold, G. Yap, R. Hughes, 1996 .

Preparation of the 1,2-Di-tert-Butylcyclopentadienyl Anion and a Transition Metal Derivative. Crystal Structure of 1,1',2,2'-Tetra-tert-butylferrocene

A. Rheingold, R. Hughes, Jeffrey R. Lomprey, 1994 .

Synthesis, Structure, Dynamics, and Enantioface-Selective η3-Benzyl Coordination in the Chiral Rhodium Complexes Rh(diphos*)(η3-CH2Ph)

A. Rheingold, M. Gembicky, R. Hughes, 2020 .

Unexpected Synthesis of a Perfluoroacyl Complex, Cp*Ir(CO)(COC6F11)Br, by Direct Fluoroalkylation of a CO Ligand, and Elimination of Perfluorocyclohexene by Activation of a γ-C−F Bond

A. Rheingold, R. Hughes, Jian Yuan, 2011 .

Variable-Temperature NMR Determination of the Barriers to Rotation about the Ir−C σ-Bond in a Series of Primary Perfluoroalkyl Iridium Complexes [IrCp*{(CF2)nCF3}(PMe3)2]+X- [n = 1, 2, 3, 5, 7, 9, 11; X = I, OTf]

L. Zakharov, R. Hughes, Hui Huang, 2007 .

Iridium and Rhodium Complexes Containing Fluorinated Phenyl Ligands and Their Transformation to η2-Benzyne Complexes, Including the Parent Benzyne Complex IrCp*(PMe3)(C6H4)

C. Incarvito, A. Rheingold, R. Hughes, 2002 .

Synthesis, molecular structures, and chemistry of some new palladium(II) and platinum(II) complexes with pentafluorophenyl ligands.

L. Zakharov, C. Incarvito, A. Rheingold, 2004, Dalton transactions.

Synthesis and molecular structures of platinum(II) and platinum(IV) diimine complexes possessing fluoroalkyl ligands

L. Zakharov, A. Rheingold, R. Hughes, 2003 .

Organic synthesis using carbon monoxide. Regiospecific cobalt mediated synthesis of 2H-pyran-2-ones.

R. Hughes, W. Henry, 1986, Journal of the American Chemical Society.

Synthesis and characterization of cationic iron vinylidene compounds: formation of carbon-hydrogen, carbon-nitrogen and carbon-phosphorus bonds and the x-ray crystal structure of [Fe(.eta.-C5H5)(CO)(PPh3) {C(PPh3):CH2}]+BF4-

A. Rheingold, R. Hughes, M. Churchill, 1982 .

Metal-carbon bonding in perfluoroethylene and perfluorobenzene transition metal complexes. Some underappreciated π- and σ-acceptor components

R. Hughes, 2021 .

Selective conversion of an ethylene to an ethylidene ligand in reactions of a hydrido(ethylene) complex of tantalum with iodofluorocarbons. Molecular structure of [Ta(η5−C5H5)2(η1−CHCH3)I]

I. Guzei, A. Rheingold, R. Hughes, 1998 .

A novel synthetic route to cyclobutadiene complexes of molybdenum and tungsten. Crystal and molecular structure of Mo(.eta.-C5H5)(.eta.-C4Ph3Me)(CO)(Cl)

A. Rheingold, R. Hughes, J. Reisch, 1984 .

A (pentafluoroethyl)(trifluoromethyl)carbene complex of iridium and reductive activation of its sp(3)α, β, and γ carbon-fluorine bonds to give perfluoro-2-butyne, perfluoro-1,2,3-butatriene and perfluoro-1-irida-2-methyl-2-cyclobutene) complexes.

A. Rheingold, R. Hughes, Jian Yuan, 2015, Dalton Transactions.

Fluorine as a Ligand Substituent in Organometallic Chemistry: A Second Chance and a Second Research Career

R. Hughes, 2010 .

The First Example of a Bis(trifluoromethyl)carbene Transition‐Metal Complex and Its Reduction to a Perfluoroallene Complex

A. Rheingold, R. Hughes, Jian Yuan, 2007 .

α- and β-Fluorine Elimination Reactions Induced by Reduction of Iridium−Fluoroalkyl Complexes. Selective Formation of Fluoroalkylidene and Hydrofluoroalkene Ligands

A. Rheingold, R. Hughes, Cheryl J. Bourgeois, 2006 .

Reactions of Perfluoroalkyl Iodides with M(C5H5)(CO)(PMe3) [M = Rh, Ir]; Evidence for Direct Fluoroalkylation at a CO Ligand

Jeremy M. Smith, A. Rheingold, R. Hughes, 2005 .

A simple route to difluorocarbene and perfluoroalkylidene complexes of iridium.

A. Rheingold, R. Hughes, J. Golen, 2005, Journal of the American Chemical Society.

Reactions of halofluorocarbons with group 6 complexes M(C(5)H(5))(2)L (M = Mo, W; L = C(2)H(4), CO). Fluoroalkylation at molybdenum and tungsten, and at cyclopentadienyl or ethylene ligands.

I. Guzei, A. Rheingold, R. Hughes, 2001, Journal of the American Chemical Society.

SELECTIVE FLUOROALKYLATION OF CYCLOPENTADIENYL AND ETHYLENE LIGANDS IN REACTIONS OF PERFLUOROALKYL IODIDES WITH LOW-VALENT COMPLEXES OF MOLYBDENUM AND TUNGSTEN : EVIDENCE FOR A FLUOROCARBANION MECHANISM

A. Rheingold, R. Hughes, L. Liable-Sands, 1997 .

Ancillary Ligand-Controlled Selectivity for Metal or Cyclopentadienyl Ring Fluoroalkylation in Reactions of Fluoroalkyl Iodides with Cyclopentadienylrhodium Complexes

G. Yap, R. Hughes, A. Rheingold, 1997 .

Does α-fluorination affect the structural trans-influence and kinetic trans-effect of an alkyl ligand? molecular structures of Pd(TMEDA)(CH3)(RF) and a kinetic study of the trans to cis isomerization of Pt(TMEDA)(CH3)2I(RF) [RF = CF2CF3, CFHCF3, CH2CF3]

L. Zakharov, Mark D. Tawa, R. Hughes, 2004 .

Streamlined Preparation and Coordination Chemistry of Hybrid Phosphine–Phosphaalkene Ligands

A. Rheingold, M. Gembicky, R. Hughes, 2016 .

Synthesis, reactivity, and resolution of a C2-symmetric, P-stereogenic benzodiphosphetane, a building block for chiral bis(phosphines).

A. Rheingold, R. Hughes, David S. Glueck, 2012, Organic letters.

Synthetic nat- or ent-steroids in as few as five chemical steps from epichlorohydrin.

A. Eastman, R. Hughes, G. C. Micalizio, 2018, Nature chemistry.

Mechanism of formation of (.eta.3-oxocyclobutenyl)cobalt compounds from [Co(CO)4]- and cyclopropenium cations

W. A. Donaldson, R. Hughes, 1982 .

Reactions of co-ordinated ligands. Part X. Reactions of trifluoroacetonitrile with π-allylic complexes of iridium(I) and with dicarbonyl(cyclopentadienyl)methyliron: the molecular and crystal structure of carbonyl(η-cyclopentadienyl)-1-[(1-iminotrifluoroethyl)imino]trifluoroethyl-Nω-iron

R. Hughes, R. Goddard, P. Woodward, 1975 .

Transition metal promoted reactions of unsaturated hydrocarbons : III. Insertion of 1,2-dienes into allylic palladium bonds

R. Hughes, J. Powell, 1973 .

Diastereoselective Coordination of P-Stereogenic Secondary Phosphines in Copper(I) Chiral Bis(phosphine) Complexes: Structure, Dynamics, and Generation of Phosphido Complexes.

A. Rheingold, R. Hughes, J. Golen, 2019, Inorganic chemistry.

Unusual Reactivity of “Proton Sponge” as a Hydride Donor to Transition Metals: Synthesis and Structural Characterization of Fluoroalkyl(hydrido) Complexes of Iridium(III) and Rhodium(III)

Donghui Zhang, Jeremy M. Smith, A. Rheingold, 2001 .

Carbon−Fluorine Bond Activation Coupled with Alkynyl Migration to Give Fluorinated Allenyl Complexes of Iridium

L. Zakharov, A. Rheingold, R. Hughes, 2006 .

Synthesis and Structural Characterization of (Perfluoroalkyl)fluoroiridium(III) and (Perfluoroalkyl)methyliridium(III) Compounds

L. Zakharov, Donghui Zhang, Jeremy M. Smith, 2006 .

Carbon-fluorine bond activation coupled with carbon-hydrogen bond formation alpha to iridium: kinetics, mechanism, and diastereoselectivity.

Donghui Zhang, R. Hughes, A. J. Ward, 2005, Journal of the American Chemical Society.

Carbon-fluorine bond activation coupled with carbon-carbon bond formation at iridium. Confirmation of complete kinetic diastereoselectivity at the new carbon stereocenter by intramolecular trapping using vinyl as the migrating group.

L. Zakharov, A. Rheingold, R. Hughes, 2005, Journal of the American Chemical Society.

Conformational analysis and assignments of relative stereocenter configurations in fluoroalkyl-iridium complexes using 19F[1H] HOESY experiments. Comparison with solid-state X-ray structural results.

L. Zakharov, Donghui Zhang, A. Rheingold, 2004, Journal of the American Chemical Society.

Carbon−Fluorine Bond Hydrogenolysis in Perfluoroethyl−Iridium Complexes To Give HFC-134a Involves Heterolytic Activation of H2

Donghui Zhang, R. Hughes, S. Willemsen, 2002 .

The first transition metal complex of tetrafluorobenzyne: Ir(eta(5)-C(5)Me(5))(PMe(3))(eta(2)-C(6)F(4)).

R. Hughes, R. Sommer, A. Rheingold, 2001, Journal of the American Chemical Society.

A study of trihapto-pentahapto equilibria in heptadienylpalladium(ii) complexes and the possible role of such complexes in metal complex catalysed 1,4-polymerizations of 1,3-butadiene

T. Jack, R. Hughes, J. Powell, 1973 .

cis-Addition of a palladium-carbon bond to coordinated olefins

R. Hughes, J. Powell, 1971 .

Chiral Bis(Phospholane) PCP Pincer Complexes: Synthesis, Structure, and Nickel-Catalyzed Asymmetric Phosphine Alkylation

A. Rheingold, R. Hughes, David S. Glueck, 2018, Organometallics.

Generation of Hydrofluoronickelacycles from Trifluoroethylene and Ni(0): Ligand Effects on Regio-/Stereoselectivity and Reactivity.

B. Gabidullin, R. Hughes, R. Baker, 2017, Journal of the American Chemical Society.

Transition Metal Promoted Reactions of Unsaturated Hydrocarbons. I. Mechanism of 1,3-Diene Insertion into Allyl-Palladium Bonds

R. Hughes, J. Powell, 1972 .

A Convenient Synthesis of 2-Alkyl-3-Deutero-2-Cyclopropene-1-Carboxylic Acids

W. A. Donaldson, R. Hughes, 1982 .

The reaction of allene with acetylacetonato-π-allylpalladium(II): formation of 2,2′-bi-π-allyl complexes of palladium(II)

R. Hughes, J. Powell, 1969 .

Synthesis, structure, and reactivity of iridium perfluorocarbene complexes: regio- and stereo-specific addition of HCl across a metal carbon double bond.

A. Rheingold, R. Hughes, Cheryl J. Bourgeois, 2015, Dalton transactions.

Synthesis and crystallographic characterization of dimeric perfluoroalkyl iridium complexes: [Cp∗Ir(X)(RF)]2 (X = I, RF = CF3, CF2CF3, CF2CF2CF3, CF(CF3)2, CF(CF3)(CF2CF3); X = Cl and Br, RF = CF2CF3), and a new perfluoroethylidene complex Cp∗Ir(PPh3)(CFCF3)

A. Rheingold, R. Hughes, Jian Yuan, 2010 .

Reactions of the cationic iron vinylidene compounds [Fe(.eta.-C5H5)(CO)(PPh3)(C:CH2)]+ BF4- with oxygen-hydrogen, nitrogen-hydrogen, sulfur-hydrogen, and chlorine-hydrogen bonds and carbon-carbon triple bonds

R. Hughes, Barbara E. Boland-Lussier, 1982 .

Synthesis and Molecular Structure of [Ru(.eta.5-C5H5)(.eta.5-C5F5)]. Intramolecular Structural Comparison of the Cyclopentadienyl Ligand with its Perfluorinated Analog

R. Ostrander, A. Rheingold, R. Hughes, 1994 .

Diastereoselective Synthesis of P-Stereogenic Secondary Phosphine Oxides (SPOs) Bearing a Chiral Substituent by Ring Opening of (+)-Limonene Oxide with Primary Phosphido Nucleophiles.

A. Rheingold, R. Hughes, G. J. Balaich, 2020, The Journal of organic chemistry.

Oxidative addition of cyclopropenyl cations to zerovalent molybdenum and tungsten centers. Synthesis of .eta.3-cyclopropenyl and .eta.3-oxocyclobutenyl complexes of molybdenum(II) and tungsten(II). Crystal and molecular structures of [Mo(.eta.5-C5H5)(.eta.3-C3Ph2R)(CO)2] (R = Ph, tert-Bu)

A. Rheingold, R. Hughes, J. Reisch, 1985 .

Reactions of cyclopropenyl cations with Group VIB metal carbonyl anions. Synthesis of .eta.3-oxocyclobutenyl complexes of chromium, molybdenum, and tungsten

R. Hughes, W. Klaeui, J. Reisch, 1985 .

2-Cyclopropene-1-carbonyl compounds of rhenium, manganese, and iron. A facile route to nonfluxional 3-.eta.1-cyclopropenyl compounds of rhenium

R. Hughes, D. Desimone, P. Desrosiers, 1982 .

Gas-phase and solution studies of the oxidation of the first perfluorocyclopentadienyl complex, [Ru(.eta.5-C5Me5)(.eta.5-C5F5)]

O. Curnow, M. Ryan, D. Richardson, 1993 .

Topochemical Synthesis of Single-Crystalline Hydrogen-Bonded Cross-Linked Organic Frameworks and Their Guest-Induced Elastic Expansion.

Andrew J E Duncan, Xuanfeng Jiang, Chenfeng Ke, 2019, Journal of the American Chemical Society.

Visible light switching of a BF2-coordinated azo compound.

Y. Yang, I. Aprahamian, R. Hughes, 2012, Journal of the American Chemical Society.

Carbon-13 shielding effects in metal-alkyl, metal-olefin, and metal-allyl bonds

R. Hughes, D. G. Cooper, J. Powell, 1972 .

Reactions of (.eta.3-cyclopropenyl)iron complexes with tertiary phosphorus ligands. Competition between ligand substitution and cyclopropenyl migration to carbon monoxide followed by ring expansion to give oxocyclobutenyl ligands

R. Hughes, J. M. Lambert, J. L. Hubbard, 1986 .

A switching cascade of hydrazone-based rotary switches through coordination-coupled proton relays

Ivan Aprahamian, I. Aprahamian, Debdas Ray, 2012, Nature Chemistry.

Competitive C−H and C−C activation in the reaction of pentamethylcyclopentadiene with decacarbonyldimanganese

Richard C. Hemond, R. Hughes, Harry B. Locker, 1986 .

2,2′-BI-π-allyl complexes of palladium(II)

R. Hughes, J. Powell, 1973 .

The interaction of conjugated and cumulative dienes with allylic palladium systems. The nature of the rate-determining step for “insertion” reactions

R. Hughes, J. Powell, 1971 .

Reductive Activation of Carbon−Fluorine Bonds in Perfluoroalkyl Ligands: An Unexpected Route to the Only Known Tetrafluorobutatriene Transition Metal Complex: Ir(η5-C5Me5)(PMe3)(2,3-η2-CF2CCCF2)

L. Zakharov, A. Rheingold, R. Hughes, 2004 .

Facile propeller rotation in metallacyclopropanes. Synthesis and dynamic behavior of new tetrafluoroethylene-ruthenium complexes. Crystal and molecular structures of [Ru(.eta.5-C5Me5)Cl(.eta.2-C2F4)]2

O. Curnow, A. Rheingold, R. Hughes, 1993 .

Reactions of co-ordinated ligands. Part 16. The oxidative–addition of hexafluorobut-2-yne and 3,3,3-trifluoroprop-1-yne to tricarbonyl(1,3- diene)-iron and -ruthenium and tricarbonyl(diphenyl-o-styrylphosphine)-iron complexes: crystal and molecular structure of [Ru(CO)2{P(OCH2)3CMe}(C6H8)(C4F6)2]

R. Hughes, R. Goddard, P. Woodward, 1977 .

Electronic structure perturbations of substituted ruthenocenes: The first photoelectron spectra of perchloro- and perfluorocyclopentadienyl complexes

D. Lichtenberger, O. Curnow, R. Hughes, 1997 .

X-ray structures and electronic properties of the 1,1′,2,2′- and 1,1′,3,3′-tetra-t-butylferrocenium(1+) cations

A. Gash, S. Strauss, C. Chambliss, 2017 .

A study of trihapto-pentahapto equilibria in heptadienylpalladium(ii) complexes and the possible role of such complexes in metal complex catalysed 1,4-polymerizations of 1,3-butadiene

T. Jack, R. Hughes, J. Powell, 1973 .

A 13C and 1H NMR investigation of the bonding in norbornenyl complexes of palladium(II) and platinum(II)

R. Hughes, J. Powell, 1973 .

Experimental and Computational Evidence for 1,4-Diradical Intermediates in Reactions of Cobalt Fluorocarbene Complexes with Terminal Aryl-alkynes to give Metallacyclobutenes

Alicia Leung, R. Hughes, R. Baker, 2017 .

Syntheses of metal carbonyls

A. Rheingold, W. Herrmann, R. Hughes, 1985 .

Steric congestion in a cyclopentadienyl ligand bearing tert-butyl groups on three contiguous carbon atoms: crystal and molecular structure of (.eta.5-1,2,3-tri-tert-butylcyclopentadienyl)(.eta.5-indenyl)rhodium(III) hexafluorophosphate

A. Rheingold, R. Hughes, H. Trujillo, 1992 .

Reactions of co-ordinated ligands. Part XI. The ring opening of methylenecyclopropanes by palladium(II)–nucleophile systems: formation of substituted η3-but-3-enyl complexes of palladium(II)

R. Hughes, Michael J. Green, 1976 .

Unexpected Formation of an Organoplatinum(IV) Fluoride Complex in the Reaction of Pt(TMEDA)(CH3)2 with Perfluoro-sec-butyl Iodide

L. Zakharov, A. Rheingold, R. Hughes, 2005 .

Synthesis and Molecular Structures of Perfluoro-n-alkyl Complexes of Platinum(II) and Platinum(IV) Containing Tetramethylethylenediamine (TMEDA) or 1,2-Bis(diphenylphosphino)ethane (DPPE) Ligands

C. Incarvito, Mark D. Tawa, R. Hughes, 2001 .

Allylic rearrangements in the thermal decarbonylation of (2-cyclopropene-1-carbonyl)rhenium compounds; nonfluxional .eta.1-cyclopropenylrhenium compounds

R. Hughes, P. Desrosiers, 1981 .

Molybdenum and tungsten complexes containing the 1,2-di-tert-butylcyclopentadienyl ligand

A. Rheingold, G. Yap, R. Hughes, 1996 .

π-Stacking between Pentafluorophenyl and Phenyl Groups as a Controlling Feature of Intra- and Intermolecular Crystal Structure Motifs in Substituted Ferrocenes. Observation of Unexpected Face-to-Face Stacking between Pentafluorophenyl Rings

A. Rheingold, R. Hughes, T. Concolino, 2000 .

Octafluorocyclooctatetraene transition-metal chemistry: 1,2-.eta. and 1,2,3,6-.eta. complexes of iron and platinum

Raymond E. Davis, B. Laird, R. Hughes, 1981 .

General Preparation of (N3N)ZrX (N3N = N(CH2CH2NSiMe3)33−) Complexes from a Hydride Surrogate

R. Waterman, S. MacMillan, R. Hughes, 2009 .

Reactions of perfluoroisopropyl iodide with cyclopentadienyl-rhodium complexes in methanol. an unexpected route to a rhodium-fulvalene complex

A. Rheingold, R. Hughes, L. Liable-Sands, 2002 .

Synthesis and Structure of Metal Complexes of P-Stereogenic Chiral Phosphiranes: An EDA-NOCV Analysis of the Donor–Acceptor Properties of Phosphirane Ligands

A. Rheingold, R. Hughes, Meaghan M. Deegan, 2018 .

Unusual rhodium promoted reaction of a vinylcyclopropene to give a cyclobutadiene ligand. Formation of (η5-pentamethylcyclopentadienyl)- [η4-tri-t-butyl(methyl) cyclobutadiene]rhodium

R. Hughes, B. Donovan, A. Kowalski, 1994 .

Building Strain with Large Macrocycles and Using It To Tune the Thermal Half-Lives of Hydrazone Photochromes.

I. Aprahamian, R. Hughes, H. Qian, 2018, Journal of the American Chemical Society.

Interactions of small organic rings with transition metals; an unusual 1,3-chloropalladation of alkylmethylenecyclopropanes

D. Hunton, R. Hughes, K. Schumann, 1979 .

Titanium(IV) Trifluoromethyl Complexes: New Perspectives on Bonding from Organometallic Fluorocarbon Chemistry

Felicia L. Taw, B. Scott, A. Clark, 2012 .

Serendipitous Discovery of a Simple Compound with an Unsupported Ir−Ir Bond

A. Rheingold, R. Hughes, Hui Huang, 2009 .

Crystal and molecular structure of a five-coordinate rhodium(I)-diene complex and the correlation of structural parameters with carbon-13 nuclear magnetic resonance shifts

R. Hughes, C. Lock, G. Turner, 1977 .

Competition between radiative pumping and nonradiative processes in the multiphoton dissociation of organometallic iron complexes

P. H. Kobsa, J. BelBruno, R. Hughes, 1987 .

Reversible Carbon-Carbon Bond Cleavage of a 3-Vinyl-1-Cyclopropene by Rh(I). Molecular Structures of Two Sterically Crowded 1,2,3,5-η-Pentadienediyl Complexes of Rh(III)

A. Rheingold, R. Hughes, J. W. Egan, 1990 .

Reactions of co-ordinated ligands. Part XIV. Regiospecific thermal rearrangements of tetracarbonyl-η2-[3-methylene-exo-4-vinyldihydrofuran-2(3H)-one]iron(0) and tricarbonyl-η4-[3-methylene-endo-4-vinyl-dihydrofuran-2(3H)-one]iron(0) complexes: the mechanisms of metalpromoted 1,3-hydrogen shifts

R. Hughes, Michael J. Green, 1976 .

REACTIONS OF COORDINATED LIGANDS. XIII.

R. Hughes, Michael J. Green, A. J. Welch, 1977 .

Ring opening of 2,3-bis(hydroxymethyl)methylenecyclopropanes with [Fe2(CO)9]; the molecular structure of a 1,4-diene complex of iron(0), tricarbonyl-η4-(3-methylene-4-vinyldiphydrofuran-2(3H)-one) iron

R. Hughes, Michael J. Green, A. J. Welch, 1975 .

Addition of hexafluorobut-2-yne to co-ordinated 1,3-dienes; crystal structures of the adducts [Ru(CO)2{P(OCH2)3CMe}(C6H8)(C4F6)2] and [Fe(CO)2{P(OCH2)3CMe}(C7H8)(C4F6)2]

R. Hughes, R. Goddard, P. Woodward, 1975 .

Dearomative Indole (3 + 2) Reactions with Azaoxyallyl Cations – New Method for the Synthesis of Pyrroloindolines

R. Hughes, Jimmy Wu, Maria C. DiPoto, 2015, Journal of the American Chemical Society.

Water, water, everywhere. Synthesis and structures of perfluoroalkyl rhodium and iridium(III) compounds containing water ligands

Donghui Zhang, C. Incarvito, Jeremy M. Smith, 2001 .

ADDITION OF HEXAFLUOROBUT-2-YNE TO CO-ORDINATED 1,3-DIENES, CRYSTAL STRUCTURES OF THE ADDUCTS (RU(CO)2(P(OCH2)3CME)(C6H8)(C4F6)2) AND (FE(CO)2(P(OCH2)3CME)(C7H8)(C4F6)2)

R. Hughes, R. Goddard, P. Woodward, 1975 .

Cationic cobalt(I) carbonyl compounds containing complexed cyclobutadienes

W. A. Donaldson, C. Chidsey, R. Hughes, 1979 .

Reactions of co-ordinated ligands. Part XIII. Ring opening of 2,3-bis-(hydroxymethyl)methylenecyclopropane with nonacarbonyldi-iron: molecular and crystal structures of tricarbonyl-η4-[3-methylene-endo-4-vinyldihydrofuran-2(3H)-one]iron(0) and tetracarbonyl-η2-[3-methyl-ene-exo-4-vinyldihydrofuran-2

R. Hughes, Michael J. Green, A. J. Welch, 1976 .

RING OPENING OF 2,3-BIS(HYDROXYMETHYL)METHYLENECYCLOPROPANES WITH (FE2(CO)9), THE MOLECULAR STRUCTURE OF A 1,4-DIENE COMPLEX OF IRON(0), TRICARBONYL-ETA(4)-(3-METHYLENE-4-VINYLDIHYDROFURAN-2(3H)-ONE)IRON

R. Hughes, Michael J. Green, A. J. Welch, 1975 .

Chloropalladation of phenyl-substituted methylenecyclopropanes

R. Hughes, K. Schumann, Bruce K. Dallas, 1982 .

Comment on “Observation of alkaline earth complexes M(CO)8 (M = Ca, Sr, or Ba) that mimic transition metals”

F. Weinhold, R. Hughes, C. Landis, 2019, Science.

A New Synthesis of 1,5-Di-tert-butyl-1,3-cyclopentadiene by Dehydration of an Epoxide and Characterization of its Diels−Alder Dimer

R. Hughes, David R. Neithamer, A. Kowalski, 1996 .

Dearomative indole (3 + 2) cycloaddition reactions.

R. Hughes, Hui Li, Jimmy Wu, 2014, Journal of the American Chemical Society.

Hydrogenolysis of Aliphatic Carbon−Fluorine Bonds in Fluoroalkyl−Iridium Complexes to Give Hydrofluorocarbons

Jeremy M. Smith, R. Hughes, 1999 .

Synthesis and structural characterization of a coordinatively unsaturated ruthenium complex, Cp∗Ru(Ph2nacnac), and its CO adduct

A. Rheingold, R. Hughes, Hui Huang, 2008 .

Comparing Properties of Common Bioinorganic Ligands with Switchable Variants of Cytochrome c.

F. Zhong, S. Alden, E. Pletneva, 2021, Inorganic chemistry.

Cationic iridium-perfluoroalkyl complexes with NH3 and PH3 ligands. Activation of carbon-fluorine bonds by H2S to give bis(trifluoromethyl)dithiametallacyclobutane and bis(trifluoromethyl)trithiametallacyclohexane complexes

C. Incarvito, Jeremy M. Smith, A. Rheingold, 2002 .

Nickel-Catalyzed Homologation of Vinylidene Difluoride (CH2═CF2): Selective β-F vs β-H Elimination.

B. Gabidullin, R. Hughes, R. Baker, 2022, Journal of the American Chemical Society.

[Ru(.eta.5-C5Me5)(.eta.5-C5F5)]: the first transition-metal complex containing a perfluorocyclopentadienyl ligand

O. Curnow, R. Hughes, 1992 .

Stereoselective oxidative additions of a carbon-carbon .sigma.-bond in tetrafluorocyclopropene to iridium(I) complexes

J. M. Spotts, R. Hughes, M. King, 1989 .

Activation of a fluorinated carbon-carbon bond by oxidative addition of tetrafluorocyclopropene to platinum(0). The first example of a perfluorometallacyclobutene

Richard C. Hemond, A. Rheingold, R. Hughes, 1988 .

Stereoselective rhodium-promoted ring closure of an .eta.4-1,3-pentadienediyl ligand to an .eta.4-1,3-cyclopentadiene, with subsequent regiospecific endo-H migration: molecular structure of [Rh(.eta.5-C5H5)(1-4-.eta.)-C5H3-1,2-exo-5-Bu-tert3)]

A. Rheingold, R. Hughes, H. Trujillo, 1993 .

Conversion of Carbon—Fluorine Bonds α to Transition Metal Centers to Carbon—Hydrogen, Carbon—Carbon, and Carbon—Heteroatom Bonds

R. Hughes, 2009 .

Preparation and dynamic behavior of .eta.3-cyclopropenyl complexes of cobalt, rhodium, and iridium. Crystal and molecular structure of [Ir(.eta.3-C3tBu3)(CO)3]

A. Rheingold, R. Hughes, D. S. Tucker, 1993 .

Protonation of P-Stereogenic Phosphiranes: Phospholane Formation via Ring Opening and C–H Activation

R. Hughes, Balázs R. Varga, David S. Glueck, 2023, ACS omega.

Synthesis and X-ray Structure of a Diamagnetic Oxo-Bridged Trifluoromethyl−Chromium(V) Complex: Structural and Computational Comparisons between CF3 and CH3 Ligands in Two Different Oxidation States of Chromium

A. Rheingold, R. Hughes, Hui Huang, 2010 .

Stereoselective ring expansion of 3-vinyl-1-cyclopropenes to give (.eta.5-cyclopentadienyl)ruthenium and (.eta.4-cyclohexadienone)iron complexes. Exclusion of planar metallacyclohexadiene intermediates and relevance to the Doetz reaction

R. Hughes, A. Gauri, H. Trujillo, 1995 .

Transition-metal-promoted activation of carbon-carbon bonds. A new synthetic route to substituted ruthenocene derivatives via ring expansion reactions of 3-vinyl-1-cyclopropenes

R. Hughes, D. Robinson, 1989 .

Reactions of iridium and rhodium complexes containing η2-benzyne, η2-tetrafluorobenzyne, and η2-trifluorobenzyne ligands. Differential rates of arene elimination by protonation of isomeric fluoroaryl complexes and restricted rotation of PMe3 ligands in ortho-iodo and ortho-bromoaryl complexes

L. Zakharov, C. Incarvito, A. Rheingold, 2003 .

Gallium(III)-Catalyzed Three-Component [4 + 3] Cycloaddition Reactions.

R. Hughes, Hui Li, Jimmy Wu, 2013 .

Synthesis, Molecular Structures, and Dynamics of Primary and Secondary Fluoroalkyl Complexes of Palladium(II) with Tetramethylethylenediamine (TMEDA) Ligands. Evaluation of the Structural trans-Influences of Methyl and Fluoroalkyl Groups as Ligands within the Same Coordination Sphere

A. Rheingold, R. Hughes, J. Overby, 2000 .

Rhodium-Catalyzed Asymmetric Dehydrocoupling: Enantioselective Synthesis of a P-Stereogenic Diphospholane with Mistake-Correcting Diastereoselectivity

Joshua S. Figueroa, A. Rheingold, A. Zureick, 2023, Organometallics.

Building Strain with Large Macrocycles and Using It To Tune the Thermal Half-Lives of Hydrazone Photochromes.

I. Aprahamian, R. Hughes, H. Qian, 2018, Journal of the American Chemical Society.