D. MacMillan

发表

Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II)

J. McCusker, E. Welin, C. Le, 2017, Science.

The advent and development of organocatalysis

D. MacMillan, David W. C. MacMillan, 2008, Nature.

Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides

D. MacMillan, David W. C. MacMillan, C. P. Johnston, 2016, Nature.

Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.

D. MacMillan, David W. C. MacMillan, Christopher K. Prier, 2013, Chemical reviews.

An Expedited Phenotypic Approach Towards Organic Reaction Generality

D. MacMillan, Cesar N. Prieto Kullmer, Jacob A Kautzky, 2021 .

Total synthesis of diazonamide A.

I. Mangion, D. MacMillan, R. Knowles, 2011, Chemical science.

Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity

Christopher K Prier, D. MacMillan, Andrew McNally, 2011, Science.

Mechanistic complexity in organo-SOMO activation.

J. Conrad, D. MacMillan, R. Flowers, 2010, Angewandte Chemie.

New Strategies for Organic Catalysis: The First Highly Enantioselective Organocatalytic Diels−Alder Reaction

D. MacMillan, K. Ahrendt, and Christopher J. Borths, 2000 .

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

D. MacMillan, Christopher K. Prier, Danica A Rankic, 2013 .

Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.

D. MacMillan, P. Pham, David A. Nagib, 2011, Angewandte Chemie.

Enantioselective α-benzylation of aldehydes via photoredox organocatalysis.

D. MacMillan, Hui‐Wen Shih, Mark N Vander Wal, 2010, Journal of the American Chemical Society.

Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis.

Mark E. Scott, D. MacMillan, David A. Nagib, 2009, Journal of the American Chemical Society.

Transient Absorption Spectroscopy Offers Mechanistic Insights for an Iridium/Nickel Catalyzed C-O Coupling.

Lei Tian, G. Scholes, Bryan Kudisch, 2020, Journal of the American Chemical Society.

Enantioselective Organocatalysis Using SOMO Activation

D. MacMillan, A. Mastracchio, K. Ashton, 2007, Science.

Enantioselective direct α-amination of aldehydes via a photoredox mechanism: a strategy for asymmetric amine fragment coupling.

D. MacMillan, G. Cecere, Christian König, 2013, Journal of the American Chemical Society.

A general strategy for organocatalytic activation of C-H bonds via photoredox catalysis: direct arylation of benzylic ethers.

D. MacMillan, Danica A Rankic, Katrine Qvortrup, 2014, Journal of the American Chemical Society.

A biohybrid strategy for enabling photoredox catalysis with low-energy light

Stephanie M. Hart, F. Castellano, G. Schlau-Cohen, 2021, Chem.

Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin

Z. Zuo, D. MacMillan, L. Chu, 2014, Journal of the American Chemical Society.

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids.

D. MacMillan, L. Chu, Jeffrey M Lipshultz, 2015, Angewandte Chemie.

Fragment Couplings via CO2 Extrusion-Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox.

C. Le, D. MacMillan, 2015, Journal of the American Chemical Society.

Simple catalytic mechanism for the direct coupling of α-carbonyls with functionalized amines: a one-step synthesis of Plavix.

D. MacMillan, J. Zbieg, Wei Li, 2013, Journal of the American Chemical Society.

Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3-sp2 Cross-Coupling of Oxalates with Aryl Halides.

D. MacMillan, Xiaheng Zhang, 2016, Journal of the American Chemical Society.

Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation.

Sean P. Brown, D. MacMillan, T. Beeson, 2009, Angewandte Chemie.

Enantioselective organocatalytic α-fluorination of cyclic ketones.

J. Conrad, D. MacMillan, P. Kwiatkowski, 2011, Journal of the American Chemical Society.

Enantioselective alpha-arylation of aldehydes via organo-SOMO catalysis. An ortho-selective arylation reaction based on an open-shell pathway.

J. Conrad, D. MacMillan, J. Kong, 2009, Journal of the American Chemical Society.

Enantioselective organocatalytic direct aldol reactions of alpha-oxyaldehydes: step one in a two-step synthesis of carbohydrates.

I. Mangion, D. MacMillan, Alan B. Northrup, 2004, Angewandte Chemie.

The importance of iminium geometry control in enamine catalysis: identification of a new catalyst architecture for aldehyde-aldehyde couplings.

I. Mangion, D. MacMillan, Alan B. Northrup, 2004, Angewandte Chemie.

A General N-alkylation Platform via Copper Metallaphotoredox and Silyl Radical Activation of Alkyl Halides.

D. MacMillan, Albert Cabré, Nathan W. Dow, 2021, Chem.

Strategies to Bypass the Taxol Problem. Enantioselective Cascade Catalysis, a New Approach for the Efficient Construction of Molecular Complexity

D. MacMillan, A. Walji, 2007 .

Open-Shell Fluorination of Alkyl Bromides: Unexpected Selectivity in a Silyl Radical-Mediated Chain Process.

K. Houk, D. MacMillan, Xiao‐Song Xue, 2019, Journal of the American Chemical Society.

Accelerating reaction generality and mechanistic insight through additive mapping

D. MacMillan, Cesar N. Prieto Kullmer, Jacob A Kautzky, 2022, Science.

Microenvironment mapping via Dexter energy transfer on immune cells

R. Oslund, C. White, E. Hett, 2020, Science.

The organocatalytic three-step total synthesis of (+)-frondosin B.

D. MacMillan, M. Reiter, Staffan Torssell, 2010, Chemical science.

Direct, enantioselective α-alkylation of aldehydes using simple olefins.

D. MacMillan, J. Malinowski, J. Kuhne, 2017, Nature chemistry.

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling.

C. Le, D. MacMillan, Patricia Zhang, 2016, Journal of the American Chemical Society.

Photoredox α-Vinylation of α-Amino Acids and N-Aryl Amines

D. MacMillan, Adam Noble, 2014, Journal of the American Chemical Society.

Enantioselective α-Alkylation of Aldehydes by Photoredox Organocatalysis: Rapid Access to Pharmacophore Fragments from β-Cyanoaldehydes.

J. Conrad, E. Welin, D. MacMillan, 2015, Angewandte Chemie.

Native functionality in triple catalytic cross-coupling: sp3 C–H bonds as latent nucleophiles

D. MacMillan, J. Cuthbertson, M. H. Shaw, 2016, Science.

Enantioselective Organocatalysis Using SOMO Activation

D. MacMillan, A. Mastracchio, K. Ashton, 2007, Science.

Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides

D. MacMillan, Adam Noble, Stefan J. McCarver, 2014, Journal of the American Chemical Society.

Alcohols as alkylating agents in heteroarene C–H functionalization

D. MacMillan, Jian Jin, 2015, Nature.

Dual Photoredox Catalysis: The Merger of Photoredox Catalysis with Other Catalytic Activation Modes

D. MacMillan, Christopher K. Prier, 2018 .

Sulfonamidation of Aryl and Heteroaryl Halides through Photosensitized Nickel Catalysis.

D. MacMillan, Chulbom Lee, Taehoon Kim, 2018, Angewandte Chemie.

Amine α-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway.

D. MacMillan, Christopher K. Prier, 2014, Chemical science.

Photoredox Catalysis in Organic Chemistry

D. MacMillan, M. H. Shaw, Jack Twilton, 2016, The Journal of organic chemistry.

Bioinspired Supercharging of Photoredox Catalysis for Applications in Energy and Chemical Manufacturing.

G. Scholes, G. Schlau-Cohen, D. MacMillan, 2022, Accounts of chemical research.

Decatungstate-Catalyzed C(sp3)-H Sulfinylation: Rapid Access to Diverse Organosulfur Functionality.

D. MacMillan, P. Sarver, Noah B Bissonnette, 2021, Journal of the American Chemical Society.

Rapid Optimization of Photoredox Reactions for Continuous-Flow Systems Using Microscale Batch Technology

D. MacMillan, J. A. Rincón, O. de Frutos, 2021, ACS central science.

Site-Selective Functionalization of Methionine Residues via Photoredox Catalysis.

W. R. Ewing, Richard Y.-C. Huang, D. MacMillan, 2020, Journal of the American Chemical Society.

Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor®.

D. MacMillan, Javier Miró, J. Jeffrey, 2019, Tetrahedron.

Spin-Center Shift-Enabled Direct Enantioselective α-Benzylation of Aldehydes with Alcohols.

D. MacMillan, Eric D. Nacsa, Eric D Nacsa, 2018, Journal of the American Chemical Society.

Decarboxylative sp3 C–N Coupling via Dual Copper/Photoredox Catalysis

D. MacMillan, Yufan Liang, Xiaheng Zhang, 2018, Nature.

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

C. Le, D. MacMillan, Yufan Liang, 2017, Nature.

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds

I. Davies, D. MacMillan, S. Colletti, 2017, Science.

Direct β-functionalization of cyclic ketones with aryl ketones via the merger of photoredox and organocatalysis.

D. MacMillan, M. Nappi, Filip R Petronijević, 2013, Journal of the American Chemical Society.

The Direct and Enantioselective Organocatalytic α-Oxidation of Aldehydes

Sean P. Brown, D. MacMillan, C. Sinz, 2003 .

The productive merger of iodonium salts and organocatalysis: a non-photolytic approach to the enantioselective alpha-trifluoromethylation of aldehydes.

D. MacMillan, A. Allen, 2010, Journal of the American Chemical Society.

Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis.

Mark E. Scott, D. MacMillan, David A. Nagib, 2010 .

Enantioselective Organo-SOMO Catalysis: The α-Vinylation of Aldehydes.

D. MacMillan, Hahn Kim, 2008 .

Merging photoredox with nickel catalysis: Coupling of α-carboxyl sp3-carbons with aryl halides

Derek T. Ahneman, Derek T Ahneman, Z. Zuo, 2014, Science.

Decarboxylative Borylation and Cross-Coupling of (Hetero)aryl Acids Enabled by Copper Charge Transfer Catalysis.

D. Blakemore, D. MacMillan, Thomas Knauber, 2022, Journal of the American Chemical Society.

HARC as an open-shell strategy to bypass oxidative addition in Ullmann–Goldberg couplings

T. Liang, D. MacMillan, Marissa N Lavagnino, 2020, Proceedings of the National Academy of Sciences.

Decarboxylative Oxygenation via Photoredox Catalysis

D. MacMillan, Wei Li, Tomer M. Faraggi, 2019, Israel Journal of Chemistry.

Metallaphotoredox-Catalyzed Cross-Electrophile Csp3-Csp3 Coupling of Aliphatic Bromides.

D. MacMillan, Russell T. Smith, J. A. Rincón, 2018, Journal of the American Chemical Society.

Merging Photoredox with Nickel Catalysis: Coupling of α‐Carboxyl sp3‐Carbons with Aryl Halides.

Derek T Ahneman, Z. Zuo, D. MacMillan, 2015 .

Photoredox Activation for the Direct β‐Arylation of Ketones and Aldehydes.

D. MacMillan, Danica A Rankic, Michael T Pirnot, 2013 .

Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis.

D. MacMillan, M. Clift, J. Terrett, 2014 .

Direct α-arylation of ethers through the combination of photoredox-mediated C-H functionalization and the Minisci reaction.

D. MacMillan, Jian Jin, 2015, Angewandte Chemie.

Nature of intermediates in organo-SOMO catalysis of alpha-arylation of aldehydes.

K. Houk, D. MacMillan, O. Gutierrez, 2010, Journal of the American Chemical Society.

Enantioselective aldehyde alpha-nitroalkylation via oxidative organocatalysis.

D. MacMillan, Anthony D. Casarez, Jonathan E. Wilson, 2009, Journal of the American Chemical Society.

Direct Aldehyde C-H Arylation and Alkylation via the Combination of Nickel, Hydrogen Atom Transfer, and Photoredox Catalysis.

D. MacMillan, Xiaheng Zhang, 2017, Journal of the American Chemical Society.

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids

D. MacMillan, L. Chu, Jeffrey M Lipshultz, 2015 .

The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation

Danielle M. Schultz, E. Sherer, D. MacMillan, 2020, Nature Chemistry.

Direct Arylation of Strong Aliphatic C–H Bonds

Danielle M. Schultz, T. Brewer, D. MacMillan, 2018, Nature.

Metallaphotoredox Perfluoroalkylation of Organobromides.

D. MacMillan, Xiangbo Zhao, 2020, Journal of the American Chemical Society.

A Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity.

Lei Tian, G. Scholes, D. MacMillan, 2020, Journal of the American Chemical Society.

Direct and enantioselective α-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis

D. MacMillan, A. Mastracchio, A. Walji, 2010, Proceedings of the National Academy of Sciences.

Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes.

Hye‐Young Jang, D. MacMillan, J. Hong, 2007, Journal of the American Chemical Society.

Radius measurement via super-resolution microscopy enables the development of a variable radii proximity labeling platform

G. Scholes, Daniel G. Oblinsky, D. MacMillan, 2022, Proceedings of the National Academy of Sciences of the United States of America.

Photochemical Identification of Auxiliary Severe Acute Respiratory Syndrome Coronavirus 2 Host Entry Factors Using μMap

Tomokazu Tamura, A. Ploss, D. MacMillan, 2022, Journal of the American Chemical Society.

Cross-Electrophile Coupling of Unactivated Alkyl Chlorides.

Wei Liu, C. Le, D. MacMillan, 2020, Journal of the American Chemical Society.

Total synthesis and structural revision of callipeltoside C.

John J. M. Wiener, D. MacMillan, Joseph E Carpenter, 2008, Angewandte Chemie.

The first Suzuki cross-couplings of aryltrimethylammonium salts.

D. MacMillan, S. Blakey, 2003, Journal of the American Chemical Society.

Enantioselective organo-SOMO cascade cycloadditions: a rapid approach to molecular complexity from simple aldehydes and olefins.

D. MacMillan, N. Jui, E. Lee, 2010, Journal of the American Chemical Society.

Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene

L. Overman, D. MacMillan, 1995 .

From the Cover: Organocatalysis Special Feature: Organocatalysis

E. Jacobsen, D. MacMillan, 2010 .

The Evolution of High-Throughput Experimentation in Pharmaceutical Development and Perspectives on the Future

Ling Li, Emma McInturff, Ke Wang, 2019, Organic Process Research & Development.

Native Functionality in Triple Catalytic Cross‐Coupling: Sp3 C—H Bonds as Latent Nucleophiles.

D. MacMillan, J. Cuthbertson, M. H. Shaw, 2016 .

Enantioselective Organocatalytic α-Fluorination of Aldehydes

D. MacMillan, T. Beeson, 2005 .

Enantioselective organo-cascade catalysis.

Yong Huang, D. MacMillan, A. Walji, 2005, Journal of the American Chemical Society.

The First General Enantioselective Catalytic Diels−Alder Reaction with Simple α,β-Unsaturated Ketones

D. MacMillan, Alan B. Northrup, 2002 .

New strategies in organic catalysis: the first enantioselective organocatalytic Friedel-Crafts alkylation.

Nick A. Paras, N. Paras, D. MacMillan, 2001, Journal of the American Chemical Society.

New Strategies for Organic Catalysis: The First Enantioselective Organocatalytic 1,3-Dipolar Cycloaddition

John J. M. Wiener, D. MacMillan, W. Jen, 2000 .

Enantioselective organocatalytic transfer hydrogenation reactions using Hantzsch esters.

D. MacMillan, S. Ouellet, A. Walji, 2007, Accounts of chemical research.

A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes

T. Liang, C. Le, D. MacMillan, 2018, Science.

Strategies to Bypass the Taxol Problem. Enantioselective Cascade Catalysis, a New Approach for the Efficient Construction of Molecular Complexity

D. MacMillan, A. Walji, 2007 .

Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development.

D. MacMillan, Anna E Allen, David W C Macmillan, 2012, Chemical science.

Enantioselective organocatalytic hydride reduction.

D. MacMillan, S. Ouellet, J. Tuttle, 2005, Journal of the American Chemical Society.

A General and Enantioselective Approach to Pentoses: A Rapid Synthesis of PSI-6130, the Nucleoside Core of Sofosbuvir

J. Conrad, D. MacMillan, M. Peifer, 2014, Journal of the American Chemical Society.

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

D. MacMillan, David A. Nagib, 2011, Nature.

Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis.

D. MacMillan, Filip R Petronijević, Sandrine Ventre, 2015, Journal of the American Chemical Society.

Metallaphotoredox Difluoromethylation of Aryl Bromides.

D. MacMillan, S. Cardinal, M. Yamauchi, 2018, Angewandte Chemie.

Metallaphotoredox Difluoromethylation of Aryl Bromides

D. MacMillan, S. Cardinal, M. Yamauchi, 2018, Angewandte Chemie.

Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development

D. MacMillan, A. Allen, 2012 .

Decarboxylative Trifluoromethylation of Aliphatic Carboxylic Acids.

Tao Wang, D. MacMillan, Jacob A Kautzky, 2018, Journal of the American Chemical Society.

Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis.

G. C. Fu, Z. Zuo, D. MacMillan, 2016, Journal of the American Chemical Society.

Enantioselective copper-catalyzed construction of aryl pyrroloindolines via an arylation-cyclization cascade.

D. MacMillan, Shaolin Zhu, 2012, Journal of the American Chemical Society.

Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis.

D. MacMillan, E. Skucas, 2012, Journal of the American Chemical Society.

Enantioselective α-arylation of carbonyls via Cu(I)-bisoxazoline catalysis.

D. MacMillan, S. Simonovich, C. Jamison, 2011, Journal of the American Chemical Society.

Enantioselective α-arylation of aldehydes via the productive merger of iodonium salts and organocatalysis.

D. MacMillan, A. Allen, 2011, Journal of the American Chemical Society.

The direct arylation of allylic sp3 C–H bonds via organocatalysis and photoredox catalysis

D. MacMillan, J. Cuthbertson, 2015, Nature.

Enantioselective organocatalytic epoxidation using hypervalent iodine reagents

D. MacMillan, Sandra Lee, 2006 .

Nontraditional Fragment Couplings of Alcohols and Carboxylic Acids: C(sp3)-C(sp3) Cross-Coupling via Radical Sorting.

D. MacMillan, H. A. Sakai, 2022, Journal of the American Chemical Society.

Enantioselective intramolecular aldehyde α-alkylation with simple olefins: direct access to homo-ene products.

Fernanda G. Finelli, D. MacMillan, Robert J. Comito, 2013, Journal of the American Chemical Society.

The Intramolecular Asymmetric Allylation of Aldehydes via Organo-SOMO Catalysis: A Novel Approach to Ring Construction.

D. MacMillan, K. Ashton, P. Pham, 2011, Chemical science.

Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.

D. MacMillan, Yufan Liang, Ciaran P. Seath, 2021, Chemical reviews.

The merger of transition metal and photocatalysis

Jack Twilton, C. Le, D. MacMillan, 2017 .

The first direct and enantioselective cross-aldol reaction of aldehydes.

D. MacMillan, Alan B Northrup, David W C MacMillan, 2002, Journal of the American Chemical Society.

Two-Step Synthesis of Carbohydrates by Selective Aldol Reactions

D. MacMillan, Alan B. Northrup, 2004, Science.

Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α‐Trifluoromethyl Carbonyl Compounds.

D. MacMillan, P. Pham, David A. Nagib, 2011 .

Switching on Elusive Organometallic Mechanisms with Photoredox Catalysis

D. MacMillan, J. Cuthbertson, V. Shurtleff, 2015, Nature.

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

David A. Nicewicz, D. Nicewicz, D. MacMillan, 2008, Science.

Development of a general, enantioselective organocatalytic Mukaiyama-Michael reaction with α,β-unsaturated aldehydes.

Christopher J. Borths, D. MacMillan, Diane E. Carrera, 2009, Tetrahedron.

Development of a New Lewis Acid-Catalyzed Claisen Rearrangement

D. MacMillan, T. Yoon, V. M. Dong, 1999 .

Enantioselective organocatalytic amine conjugate addition.

D. MacMillan, Masanori Yoshida, Young K Chen, 2006, Journal of the American Chemical Society.

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis.

Rebecca T. Ruck, I. Davies, D. MacMillan, 2018, Angewandte Chemie.

The Application of Pulse Radiolysis to the Study of Ni(I) Intermediates in Ni-Catalyzed Cross-Coupling Reactions.

Seokjoon Oh, D. MacMillan, M. Bird, 2021, Journal of the American Chemical Society.

Enantioselective organocatalytic aldehyde-aldehyde cross-aldol couplings. The broad utility of α-thioacetal aldehydes

R. I. Storer, D. MacMillan, 2004 .

Photoredox α‐Vinylation of α‐Amino Acids and N‐Aryl Amines.

D. MacMillan, Adam Noble, 2015 .

Visible light photocatalysis in organic chemistry

D. MacMillan, T. Yoon, C. Stephenson, 2018 .

Modern strategies in organic catalysis: The advent and development of iminium activation

D. MacMillan, David W. C. MacMillan, Gérald Lelais, 2006 .

O—H Hydrogen Bonding Promotes H‐Atom Transfer from α C—H Bonds for C‐Alkylation of Alcohols.

D. MacMillan, J. Jeffrey, J. Terrett, 2016 .

O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols

D. MacMillan, J. Jeffrey, J. Terrett, 2015, Science.

Activation of C–H Bonds via the Merger of Photoredox and Organocatalysis: A Coupling of Benzylic Ethers with Schiff Bases

D. MacMillan, D. Hager, 2014, Journal of the American Chemical Society.

Organocatalytic transfer hydrogenation of cyclic enones.

D. MacMillan, S. Ouellet, J. Tuttle, 2006, Journal of the American Chemical Society.

Enantioselective organocatalytic construction of pyrroloindolines by a cascade addition-cyclization strategy: synthesis of (-)-flustramine B.

W. Xiao, D. MacMillan, C. Sinz, 2004, Proceedings of the National Academy of Sciences of the United States of America.

Enantioselective organocatalytic reductive amination.

Y. Ni, R. I. Storer, D. MacMillan, 2006, Journal of the American Chemical Society.

C2-Symmetric Tin(II) Complexes as Chiral Lewis Acids. Catalytic Enantioselective Anti Aldol Additions of Enolsilanes to Glyoxylate and Pyruvate Esters

Davidr . Evans, D. MacMillan, K. Campos, 1997 .

Collective synthesis of natural products by means of organocascade catalysis

D. MacMillan, Spencer B. Jones, Bryon Simmons, 2011, Nature.

Decarboxylative Hydroalkylation of Alkynes.

D. MacMillan, Russell T. Smith, Nicholas A. Till, 2018, Journal of the American Chemical Society.

Decarboxylative alkylation for site-selective bioconjugation of native proteins via oxidation potentials

Chun Liu, William R Ewing, M. Poss, 2017, Nature Chemistry.

Nine-step enantioselective total synthesis of (+)-minfiensine.

D. MacMillan, Spencer B. Jones, Bryon Simmons, 2009, Journal of the American Chemical Society.

Cycle-specific organocascade catalysis: application to olefin hydroamination, hydro-oxidation, and amino-oxidation, and to natural product synthesis.

D. MacMillan, Bryon Simmons, A. Walji, 2009, Angewandte Chemie.

Catalyst-controlled oligomerization for the collective synthesis of polypyrroloindoline natural products

D. MacMillan, Robert J. Comito, Jeffrey M Lipshultz, 2017, Nature Chemistry.

Development of a generic activation mode: nucleophilic α-substitution of ketones via oxy-allyl cations

D. MacMillan, M. V. Wal, Andreew K. Dilger, 2013 .

Development of a new Lewis acid-catalyzed [3,3]-sigmatropic rearrangement: the allenoate-Claisen rearrangement.

T. Lambert, D. MacMillan, 2002, Journal of the American Chemical Society.

Enantioselective Claisen rearrangements: development of a first generation asymmetric acyl-Claisen reaction.

D. MacMillan, T. Yoon, 2001, Journal of the American Chemical Society.

Design of a new cascade reaction for the construction of complex acyclic architecture: the tandem acyl-claisen rearrangement.

D. MacMillan, V. M. Dong, 2001, Journal of the American Chemical Society.

Total synthesis of brasoside and littoralisone.

I. Mangion, D. MacMillan, 2005, Journal of the American Chemical Society.

Photoredox Activation for the Direct &bgr;-Arylation of Ketones and Aldehydes

D. MacMillan, David W. C. MacMillan, Danica A Rankic, 2013, Science.

Nine-step enantioselective total synthesis of (-)-vincorine.

Benjamin D. Horning, D. MacMillan, 2013, Journal of the American Chemical Society.

Enantioselective organocatalytic indole alkylations. Design of a new and highly effective chiral amine for iminium catalysis.

D. MacMillan, David W C MacMillan, Joel F Austin, 2002, Journal of the American Chemical Society.

Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway.

Jeffrey F. Van Humbeck, D. MacMillan, R. Knowles, 2010, Journal of the American Chemical Society.

The Enantioselective Organocatalytic 1,4-Addition of Electron-Rich Benzenes to α,β-Unsaturated Aldehydes

Nick A. Paras, N. Paras, D. MacMillan, 2002 .

The first enantioselective organocatalytic Mukaiyama-Michael reaction: a direct method for the synthesis of enantioenriched gamma-butenolide architecture.

Sean P. Brown, N. C. Goodwin, D. MacMillan, 2003, Journal of the American Chemical Society.

Enantioselective organocatalytic cyclopropanations. The identification of a new class of iminium catalyst based upon directed electrostatic activation.

R. Kunz, D. MacMillan, 2005, Journal of the American Chemical Society.

Enantioselective organocatalytic intramolecular Diels-Alder reactions. The asymmetric synthesis of solanapyrone D.

D. MacMillan, Rebecca M. Wilson, W. Jen, 2005, Journal of the American Chemical Society.

Direct and Enantioselective Organocatalytic α-Chlorination of Aldehydes

Sean P. Brown, D. MacMillan, M. Brochu, 2004 .

Selective Radical-Radical Cross-Couplings: Design of a Formal β-Mannich Reaction.

D. MacMillan, J. Jeffrey, Filip R Petronijević, 2015, Journal of the American Chemical Society.

Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis

D. MacMillan, M. Clift, J. Terrett, 2014, Journal of the American Chemical Society.

Enantioselective organo-singly occupied molecular orbital catalysis: the carbo-oxidation of styrenes.

Casey M. Jones, D. MacMillan, T. Graham, 2008, Journal of the American Chemical Society.

C2-SYMMETRIC COPPER(II) COMPLEXES AS CHIRAL LEWIS ACIDS. CATALYTIC ENANTIOSELECTIVE ALDOL ADDITIONS OF ENOLSILANES TO PYRUVATE ESTERS

Davidr . Evans, M. Kozlowski, D. MacMillan, 1997 .

Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore

Z. Zuo, D. MacMillan, David W. C. MacMillan, 2014, Journal of the American Chemical Society.

Stereoselection in the Prins-pinacol synthesis of acyltetrahydrofurans.

L. Overman, D. MacMillan, F. Cohen, 2001, Organic letters.

Stereoselection in the prins-pinacol synthesis of 2,2-disubstituted 4-acyltetrahydrofurans. Enantioselective synthesis of (-)-citreoviral.

L. Overman, D. MacMillan, J. T. Link, 2000, Organic letters.

A general method for the enantioselective synthesis of pantolactone derivatives.

Davidr . Evans, C. Masse, D. MacMillan, 2002, Organic letters.

Synthesis of Enantiopure Unnatural Amino Acids by Metallaphotoredox Catalysis.

D. MacMillan, J. A. Rincón, O. de Frutos, 2021, Organic process research & development.

Enantioselective organo-SOMO cycloadditions: a catalytic approach to complex pyrrolidines from olefins and aldehydes.

Fernanda G. Finelli, D. MacMillan, N. Jui, 2012, Journal of the American Chemical Society.

A general strategy for the synthesis of cladiellin diterpenes: enantioselective total syntheses of 6-acetoxycladiell-7(16),11-dien-3-ol (deacetoxyalcyonin acetate), cladiell-11-ene-3,6,7-triol, sclerophytin A, and the initially purported structure of sclerophytin A.

L. Overman, D. MacMillan, L. Pennington, 2001, Journal of the American Chemical Society.

Copper-Mediated Synthesis of Drug-like Bicyclopentanes

N. Carruthers, C. Le, D. MacMillan, 2020, Nature.

Nickel Catalysis via SH2 Homolytic Substitution: The Double Decarboxylative Cross-Coupling of Aliphatic Acids.

D. MacMillan, Artem V. Tsymbal, L. Bizzini, 2022, Journal of the American Chemical Society.

Metallaphotoredox Aryl and Alkyl Radiomethylation for PET Ligand Discovery

Talakad G. Lohith, L. Gantert, E. Hostetler, 2020, Nature.

Enantioselective α-alkenylation of aldehydes with boronic acids via the synergistic combination of copper(II) and amine catalysis.

Jason M. Stevens, D. MacMillan, 2013, Journal of the American Chemical Society.

Enantioselective Organo-SOMO Catalysis : The α-Vinylation of Aldehydes

D. MacMillan, Hahn Kim, 2007 .

Development of a General Enantioselective Organocatalytic Mukaiyama—Michael Reaction with α,β-Unsaturated Aldehydes.

Christopher J. Borths, D. MacMillan, Diane E. Carrera, 2009 .

Organocatalytic vinyl and Friedel-Crafts alkylations with trifluoroborate salts.

D. MacMillan, Sandra Lee, 2007, Journal of the American Chemical Society.

A Unified Approach to Decarboxylative Halogenation of (Hetero)aryl Carboxylic Acids.

Cory E. Hauke, F. Castellano, E. Danilov, 2022, Journal of the American Chemical Society.

Carboxylic Acids as Adaptive Functional Groups in Metallaphotoredox Catalysis.

D. MacMillan, Sebastian B. Beil, Tiffany Q. Chen, 2022, Accounts of chemical research.

Enantioselective organocatalysis involving iminium, enamine, SOMO, and photoredox activation

D. MacMillan, A. Watson, 2010 .

Development of a New Lewis Acid‐Catalyzed Claisen Rearrangement.

D. MacMillan, T. Yoon, V. M. Dong, 2000 .

Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the Asymmetric α‐Chlorination of Aldehydes and Terminal Epoxide Formation.

Sean P. Brown, D. MacMillan, T. Beeson, 2009 .

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling.

Christopher C. Nawrat, L. Overman, D. MacMillan, 2015, Journal of the American Chemical Society.

A Metallaphotoredox Strategy for the Cross-Electrophile Coupling of Alpha-Chloro Carbonyls with Aryl Halides.

D. MacMillan, Tiffany Q. Chen, 2019, Angewandte Chemie.

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides.

D. MacMillan, David J. P. Kornfilt, D. J. P. Kornfilt, 2019, Journal of the American Chemical Society.

Enantioselective polyene cyclization via organo-SOMO catalysis.

D. MacMillan, S. Rendler, 2010, Journal of the American Chemical Society.

Enantioselective Organocatalytic Aldehyde—Aldehyde Cross‐Aldol Couplings. The Broad Utility of α‐Thioacetal Aldehydes.

R. I. Storer, D. MacMillan, 2004 .

Static to inducibly dynamic stereocontrol: The convergent use of racemic β-substituted ketones

D. MacMillan, Jacob A Kautzky, M. Yamauchi, 2020, Science.

A biomimetic SH2 cross-coupling mechanism for quaternary sp3-carbon formation

J. Alcázar, Wei Liu, D. MacMillan, 2021, Science.

Aryl amination using ligand-free Ni(II) salts and photoredox catalysis

Ian W. Davies, Spencer D. Dreher, Stephen L. Buchwald, 2016, Science.

The Preparation of (2R,5S)‐2‐t‐Butyl‐3,5‐Dimethylimidazolidin‐4‐One

Benjamin D. Horning, D. MacMillan, T. Graham, 2012 .

Enantioselective syntheses of authentic sclerophytin A, sclerophytin B, and cladiell-11-ene-3,6,7-triol.

L. Overman, L. Paquette, F. Gallou, 2001, Organic letters.

Carbon–Carbon Bond Formation by Metallaphotoredox Catalysis

D. MacMillan, Eric D. Nacsa, Eric D Nacsa, 2019, Organic Reactions.

Selective Isomerization via Transient Thermodynamic Control: Dynamic Epimerization of trans to cis Diols.

D. MacMillan, Christian J. Oswood, 2021, Journal of the American Chemical Society.

Metallaphotoredox-enabled deoxygenative arylation of alcohols

D. MacMillan, Zhe Dong, 2021, Nature.

Late-Stage C(sp3)-H Methylation of Drug Molecules.

D. MacMillan, Edna Mao, 2023, Journal of the American Chemical Society.

A process for the rapid removal of dialkylamino-substituents from aromatic rings. Application to the expedient synthesis of (R)-tolterodine

N. Paras, D. MacMillan, Bryon Simmons, 2009 .

A general approach to the enantioselective α-oxidation of aldehydes via synergistic catalysis.

Jeffrey F. Van Humbeck, D. MacMillan, S. Simonovich, 2012, Chemical science.

μMap-Red: Proximity Labeling by Red Light Photocatalysis.

G. Scholes, Daniel G. Oblinsky, A. Ploss, 2022, Journal of the American Chemical Society.

History and Perspective of Chiral Organic Catalysts

D. MacMillan, Gérald Lelais, 2006 .

Decarboxylative Peptide Macrocyclization through Photoredox Catalysis.

Martin D. Eastgate, M. Poss, R. Borzilleri, 2017, Angewandte Chemie.

Small molecule photocatalysis enables drug target identification via energy transfer

R. Oslund, C. White, P. Tawa, 2021, bioRxiv.

Reactive intermediates for interactome mapping.

T. Muir, D. MacMillan, Ciaran P. Seath, 2021, Chemical Society reviews.

Tracking chromatin state changes using μMap photo-proximity labeling

T. Muir, D. MacMillan, A. Burton, 2021, bioRxiv.

Synthesis of Callipeltoside C

D. MacMillan, Joseph E Carpenter, Alan B. Northrup, 2008 .

Oxy-Allyl Cation Catalysis: An Enantioselective Electrophilic Activation Mode.

Chun Liu, D. MacMillan, E. Z. Oblak, 2016, Journal of the American Chemical Society.

Tracking chromatin state changes using nanoscale photo-proximity labelling

Ralph E. Kleiner, T. Muir, D. MacMillan, 2023, Nature.

Enantioselective total synthesis of (-)-minovincine in nine chemical steps: an approach to ketone activation in cascade catalysis.

D. MacMillan, B. N. Laforteza, M. Pickworth, 2013, Angewandte Chemie.

Site-selective tyrosine bioconjugation via photoredox catalysis for native-to-bioorthogonal protein transformation

G. Scholes, Daniel G. Oblinsky, W. R. Ewing, 2021, Nature Chemistry.

Deoxytrifluoromethylation of Alcohols.

D. MacMillan, Agustin Millet, Nicholas E. Intermaggio, 2022, Journal of the American Chemical Society.

Correction to "Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling".

Christopher C. Nawrat, L. Overman, D. MacMillan, 2016, Journal of the American Chemical Society.

α-Oxidation Reactions

D. MacMillan, A. Watson, 2011 .

Rapid Access to 2-Substituted Bicyclo[1.1.1]pentanes.

D. MacMillan, C. Yeung, Yufan Liang, 2023, Journal of the American Chemical Society.

General access to cubanes as benzene bioisosteres

D. MacMillan, C. Yeung, D. J. Bennett, 2023, Nature.

A General Strategy for Organocatalytic Activation of C—H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers.

D. MacMillan, Danica A Rankic, Katrine M Qvortrup, 2014 .

New Strategies for Organic Catalysis: The First Highly Enantioselective Organocatalytic Diels—Alder Reaction.

Christopher J. Borths, D. MacMillan, K. Ahrendt, 2000 .

A General Small-Scale Reactor To Enable Standardization and Acceleration of Photocatalytic Reactions

Ian W. Davies, Michael K. Wismer, I. Davies, 2017, ACS central science.

New Strategies for Organic Catalysis: The First Enantioselective Organocatalytic 1,3‐Dipolar Cycloaddition.

John J. M. Wiener, D. MacMillan, W. Jen, 2001 .

μMap Photoproximity Labeling Enables Small Molecule Binding Site Mapping.

R. Oslund, C. White, Keun Ah Ryu, 2023, Journal of the American Chemical Society.

Decarboxylative sp3 C–N Coupling via Dual Copper/Photoredox Catalysis

D. MacMillan, Yufan Liang, Xiaheng Zhang, 2018, Nature.

Photoproximity Labeling of Sialylated Glycoproteins (GlycoMap) Reveals Sialylation-Dependent Regulation of Ion Transport.

J. Rabinowitz, W. Lu, D. MacMillan, 2022, Journal of the American Chemical Society.

Alcohols as Alkylating Agents: Photoredox-Catalyzed Conjugate Alkylation via In Situ Deoxygenation.

D. MacMillan, H. A. Sakai, John Wang, 2022, Angewandte Chemie.

Rapid and Modular Access to Quaternary Carbons from Tertiary Alcohols via Bimolecular Homolytic Substitution.

D. MacMillan, C. Gould, Andria L Pace, 2023, Journal of the American Chemical Society.

Expedient Access to Underexplored Chemical Space: Deoxygenative C(sp3)-C(sp3) Cross-Coupling.

D. MacMillan, W. L. Lyon, 2023, Journal of the American Chemical Society.

Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II)

J. McCusker, E. Welin, C. Le, 2017, Science.

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes.

David A. Nicewicz, D. MacMillan, 2009 .

Aryl amination using ligand-free Ni(II) salts and photoredox catalysis

I. Davies, D. MacMillan, S. Dreher, 2016, Science.

Metallaphotoredox Difluoromethylation of Aryl Bromides.

D. MacMillan, S. Cardinal, M. Yamauchi, 2018, Angewandte Chemie.

The advent and development of organocatalysis

D. MacMillan, 2008, Nature.

O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols

D. MacMillan, J. Jeffrey, Jack A. Terrett, 2015, Science.

Selective Radical-Radical Cross-Couplings: Design of a Formal β-Mannich Reaction.

D. MacMillan, J. Jeffrey, Filip R Petronijević, 2015, Journal of the American Chemical Society.

Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway.

Jeffrey F. Van Humbeck, D. MacMillan, R. Knowles, 2010, Journal of the American Chemical Society.

One-Pot Synthesis of Sulfonamides from Unactivated Acids and Amines via Aromatic Decarboxylative Halosulfonylation.

D. Blakemore, D. MacMillan, G. Chinigo, 2023, Journal of the American Chemical Society.

Site-Selective Functionalization of Methionine Residues via Photoredox Catalysis.

W. R. Ewing, Richard Y.-C. Huang, D. MacMillan, 2020, Journal of the American Chemical Society.

Nine-step enantioselective total synthesis of (-)-vincorine.

Benjamin D. Horning, D. MacMillan, 2013, Journal of the American Chemical Society.

Enantioselective total synthesis of (-)-minovincine in nine chemical steps: an approach to ketone activation in cascade catalysis.

D. MacMillan, B. N. Laforteza, M. Pickworth, 2013, Angewandte Chemie.

Fragment Couplings via CO2 Extrusion-Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox.

C. Le, D. MacMillan, 2015, Journal of the American Chemical Society.

Two-Step Synthesis of Carbohydrates by Selective Aldol Reactions

D. MacMillan, Alan B. Northrup, 2004, Science.

Organocatalysis

E. Jacobsen, D. MacMillan, 2010, Proceedings of the National Academy of Sciences.