H. Schmalz

发表

Transition-metal-mediated synthesis of novel carbocyclic nucleoside analogues with antitumoral activity.

J. Lex, T. Wieder, A. Prokop, 2004, Chemistry.

Azides Derived from Colchicine and their Use in Library Synthesis: a Practical Entry to New Bioactive Derivatives of an Old Natural Drug

H. Oschkinat, A. Prokop, J. Neudörfl, 2010, ChemMedChem.

Prevention of colitis by controlled oral drug delivery of carbon monoxide.

L. Meinel, Y. Naito, T. Takagi, 2016, Journal of controlled release : official journal of the Controlled Release Society.

Molecular oxygen as a redox catalyst in intramolecular photocycloadditions of coumarins.

K. Meerholz, R. Pérez-Ruíz, J. Neudörfl, 2012, Angewandte Chemie.

Molekularer Sauerstoff als Redox‐Katalysator in intramolekularen Cumarin‐Photocycloadditionen

K. Meerholz, R. Pérez-Ruíz, J. Neudörfl, 2012 .

New Colchicine-Derived Triazoles and Their Influence on Cytotoxicity and Microtubule Morphology.

Aruljothi Mariappan, N. Teusch, H. Schmalz, 2016, ACS medicinal chemistry letters.

Enantioselective synthesis of new C2-symmetric ferrocenylalkylamines via sonochemical amination of 1-ferrocenylalkyl acetates

H. Schmalz, M. Woltersdorf, R. Kranich, 1997 .

Design, synthesis, and functional evaluation of CO-releasing molecules triggered by Penicillin G amidase as a model protease.

B. Yard, H. Schmalz, N. Sitnikov, 2015, Angewandte Chemie.

Nucleoside analogues with a 1,3-diene-Fe(CO)3 substructure: stereoselective synthesis, configurational assignment, and apoptosis-inducing activity.

T. Wieder, C. Hirschhäuser, A. Prokop, 2013, Chemistry.

Microwave-Assisted Amination of a Chloropurine Derivative in the Synthesis of Acyclic Nucleoside Analogues

Andreas Lanver, H. Schmalz, 2005, Molecules.

Synthesis of Oxa‐B‐Ring Analogs of Colchicine through Rh‐Catalyzed Intramolecular [5+2] Cycloaddition

A. Prokop, J. Neudörfl, H. Schmalz, 2012 .

TADDOL‐Based Phosphane–Phosphite Ligands in Enantioselective Cu‐Catalyzed Grignard 1,4‐Additions Followed by Mannich‐Type Alkylations

R. Šebesta, H. Schmalz, A. Škvorcová, 2012 .

Cobalt-catalyzed 1,4-hydrobutadienylation of 1-aryl-1,3-dienes with 2,3-dimethyl-1,3-butadiene.

G. Hilt, H. Schmalz, M. A. Bohn, 2011, Angewandte Chemie.

A General Stereocontrolled Synthesis of Opines through Asymmetric Pd‐Catalyzed N‐Allylation of Amino Acid Esters

J. Neudörfl, H. Schmalz, Dominik Albat, 2021 .

Pd‐Catalyzed Asymmetric N‐Allylation of Amino Acid Esters with Exceptional Levels of Catalyst Control: Stereo‐Divergent Synthesis of ProM‐15 and Related Bicyclic Dipeptide Mimetics

R. Kühne, J. Neudörfl, H. Schmalz, 2020, Chemistry.

Piceatannol, a hydroxylated analog of the chemopreventive agent resveratrol, is a potent inducer of apoptosis in the lymphoma cell line BJAB and in primary, leukemic lymphoblasts

B. Dörken, G. Henze, P. Daniel, 2001, Leukemia.

Heck coupling in the gas phase: Examination of the reaction mechanism by ion/molecule reactions and mass spectrometry

M. Schäfer, Lukas Fiebig, H. Schmalz, 2011 .

A fast and simple LC-MS-based characterization of the flavonoid biosynthesis pathway for few seed(ling)s

M. Hülskamp, U. Hoecker, M. Bucher, 2016, BMC Plant Biology.

Organometallic nucleosides induce non-classical leukemic cell death that is mitochondrial-ROS dependent and facilitated by TCL1-oncogene burden

C. Prinz, D. Mougiakakos, M. Hallek, 2015, Molecular Cancer.

Colchicine Alkaloids, and Synthetic Analogues: Current Progress and Perspectives.

I. A. Gracheva, I. Beletskaya, H. Schmalz, 2020, Journal of medicinal chemistry.

Synthesis of Indole-Derived Allocolchicine Congeners through Pd-Catalyzed Intramolecular C-H Arylation Reaction

V. Fokin, G. Fukin, A. Fedorov, 2014 .

Total synthesis of indole-derived allocolchicine analogues exhibiting strong apoptosis-inducing activity.

A. Prokop, A. Y. Fedorov, J. Neudörfl, 2012, Chemistry.

Ergothioneine stands out from hercynine in the reaction with singlet oxygen: Resistance to glutathione and TRIS in the generation of specific products indicates high reactivity

M. Schäfer, Vera Wewer, D. Gründemann, 2017, Free radical biology & medicine.

Reply to: "Paraoxonase-1 and clopidogrel efficacy"

C. Hirschhäuser, E. Schömig, H. Bouman, 2011, Nature Medicine.

A Stereoselective Synthesis of the ACE Inhibitor Trandolapril

J. Neudörfl, H. Schmalz, Slim Chiha, 2019, Synlett.

Radical cyclization of η6-arene-Cr(CO)3 complexes: A regio- and stereoselective entry to functionalized pseudopterosin precursors

H. Schmalz, A. Schwarz, S. Siegel, 1996 .

Radical Additions to (η6‐Arene)(tricarbonyl)‐chromium Complexes: Diastereoselective Synthesis of Hydrophenalene and Hydrobenzindene Derivatives by Samarium(II) Iodide Induced Cyclization

J. Bats, H. Schmalz, S. Siegel, 1995 .

Electron Transfer Driven Transformations of Transition Metal π-Complexes: Samarium(II) Iodide Mediated Coupling of Fluoroarene-Cr(CO)3 Complexes with Ketones

H. Schmalz, B. Gotov, O. Kiehl, 2002 .

Phenol-derived chiral phosphine–phosphite ligands in the rhodium-catalyzed enantioselective hydrogenation of functionalized olefins

T. Robert, J. Reek, H. Schmalz, 2010 .

Modular Synthesis of Chiral Phosphine‐Phosphite‐Ligands from Phenolic Precursors: A New Approach to Bidentate Chelate Ligands Exploiting a PO to PC Migration Rearrangement

T. Robert, J. Lex, J. Neudörfl, 2008 .

ET-CORM Mediated Vasorelaxation of Small Mesenteric Arteries: Involvement of Kv7 Potassium Channels

B. Yard, P. Wohlfart, H. Schmalz, 2021, Frontiers in Pharmacology.

New modular manganese(I) tricarbonyl complexes as PhotoCORMs: in vitro detection of photoinduced carbon monoxide release using COP-1 as a fluorogenic switch-on probe.

B. Yard, H. Schmalz, U. Schatzschneider, 2014, Dalton transactions.

Synthesis and Performance of Acyloxy-diene-Fe(CO)3 Complexes with Variable Chain Lengths as Enzyme-Triggered Carbon Monoxide-Releasing Molecules

B. Yard, Miguel Guttentag, R. Alberto, 2013 .

Acyloxybutadiene tricarbonyl iron complexes as enzyme-triggered CO-releasing molecules (ET-CORMs): a structure-activity relationship study.

Miguel Guttentag, R. Alberto, S. Amslinger, 2012, Dalton transactions.

Acyloxybutadiene iron tricarbonyl complexes as enzyme-triggered CO-releasing molecules (ET-CORMs).

S. Amslinger, J. Neudörfl, H. Schmalz, 2011, Angewandte Chemie.

Organocatalyzed Synthesis of Oleochemical Carbonates from CO2 and Renewables.

C. Wulf, H. Schmalz, T. Werner, 2017, ChemSusChem.

Corrigendum: Acyloxybutadiene Iron Tricarbonyl Complexes as Enzyme‐Triggered CO‐Releasing Molecules (ET‐CORMs)

S. Amslinger, J. Neudörfl, H. Schmalz, 2011 .

Iron containing anti-tumoral agents: unexpected apoptosis-inducing activity of a ferrocene amino acid derivative

A. Prokop, H. Schmalz, P. Jesse, 2011, Journal of Cancer Research and Clinical Oncology.

Synthesis and biological evaluation of furanoallocolchicinoids.

V. Fokin, I. Beletskaya, P. Barbier, 2015, Journal of medicinal chemistry.

Enantioselective Nickel‐Catalyzed Hydrocyanation using Chiral Phosphine‐Phosphite Ligands: Recent Improvements and Insights

G. Nichol, H. Schmalz, D. Vogt, 2015 .

Enantioselective nickel-catalyzed hydrocyanation of vinylarenes using chiral phosphine-phosphite ligands and TMS-CN as a source of HCN.

H. Schmalz, Anna Falk, Anna‐Lena Göderz, 2013, Angewandte Chemie.

ItaCORMs: conjugation with a CO-releasing unit greatly enhances the anti-inflammatory activity of itaconates

T. Wieder, J. Neudörfl, H. Schmalz, 2021, RSC Medicinal Chemistry.

Synthesis and biological evaluation of novel non-racemic indole-containing allocolchicinoids.

I. A. Gracheva, A. Fedorov, E. Svirshchevskaya, 2017, European journal of medicinal chemistry.

Hydrophenalene–Cr(CO)3 complexes as anti-inflammatory agents based on specific inhibition of NOD2 signalling: a SAR study

J. Neudörfl, H. Schmalz, T. Kufer, 2012 .

Synthesis and First Biological Evaluation of an Iron-Containing HETE Analogue

A. Prokop, J. Neudörfl, H. Schmalz, 2011 .

Gold(I)-catalyzed reaction of 1-(1-alkynyl)-cyclopropyl ketones with nucleophiles: a modular entry to highly substituted furans.

Junliang Zhang, H. Schmalz, 2006, Angewandte Chemie.

Chiral phosphine–phosphite ligands in the enantioselective 1,4-addition of Grignard reagents to α,β-unsaturated carbonyl compounds

T. Robert, H. Schmalz, D. Kranz, 2011 .

Stereospecific Side Chain Activation in Cyclobutadiene–Fe(CO)3 Chemistry: A Theoretical and Experimental Study on the Structure and Configurational Stability of Cationic, Radical and Anionic Intermediates

J. Lex, H. Schmalz, A. Pfletschinger, 2007 .

An efficient organometallic approach to new carbocyclic nucleoside analogues.

J. Lex, J. Velcicky, H. Schmalz, 2002, Organic letters.

Palladium-catalyzed cyanomethylation of aryl halides through domino Suzuki coupling-isoxazole fragmentation.

R. Steiner, J. Velcicky, H. Schmalz, 2011, Journal of the American Chemical Society.

A Facile Synthetic Approach to Nonracemic Substituted Pyrrolo-allocolchicinoids Starting from Natural Colchicine

A. Fedorov, E. Svirshchevskaya, H. Schmalz, 2018, Synthesis.

Synthesis of Diverse 6‐Oxa‐allocolchicinoids by a Suzuki–Miyaura Coupling, Acid‐Catalyzed Intramolecular Transacetalization Strategy

W. V. Otterlo, C. B. Koning, A. Prokop, 2015 .

Enantioselective synthesis of ferrocenyl nucleoside analogues with apoptosis-inducing activity.

A. Prokop, M. Eissmann, J. Neudörfl, 2006, Organic letters.

Synthesis of an analog of the cytotoxic marine diterpene helioporin C exploiting arene-Cr(CO)3 chemistry

G. Kociok‐Köhn, H. Schmalz, D. Hörstermann, 1999 .

Controlling the Course of Nucleophilic Additions to ortho‐Substituted (η6‐Anisole)tricarbonyl‐chromium Complexes: Dienol Ether Formation versus tele‐Substitution

H. Schmalz, K. Schellhaas, 1996 .

tele-Substitution as the major pathway in intermolecular nucleophilic addition/protonation reactions of ortho-alkylated η6-anisole-Cr(CO)3 derivatives

H. Schmalz, K. Schellhaas, 1995 .

Palladium‐Catalyzed Synthesis of Vitamin D‐Active Compounds

H. Schmalz, S. Krause, 2003 .

CATALYTIC RING-CLOSING METATHESIS : A NEW, POWERFUL TECHNIQUE FOR CARBON-CARBON COUPLING IN ORGANIC SYNTHESIS

H. Schmalz, 1995 .

Chapter 13. Intramolecular Alkoxypalladation

H. Schmalz, Oliver Geis and, 2008 .

Total synthesis of cyclo-mumbaistatin analogues through anionic homo-Fries rearrangement.

N. Schlörer, J. Neudörfl, H. Schmalz, 2011, Chemistry.

A catalytic-enantioselective entry to planar chiral pi-complexes: enantioselective methoxycarbonylation of 1,2-dichlorobenzene-Cr(CO)(3).

H. Schmalz, B. Gotov, 2001, Organic letters.

Synthesis of the 8,19‐Epoxysteroid Eurysterol A

J. Neudörfl, H. Schmalz, M. Breugst, 2020, Chemistry.

Synthesis and biological evaluation of new antimalarial isonitriles related to marine diterpenoids

O. Schwarz, J. Bats, R. Brun, 2002 .

Kinetics of the borane reduction of pinacolone in THF catalyzed by two different oxazaboroles

R. Schmidt, H. Schmalz, Holger Jockel, 1997 .

Electrophilic activation of benzaldehydes through ortho palladation: one-pot synthesis of 3-methylene-indan-1-ols through a domino allylstannylation/Heck reaction under neutral conditions.

J. Cvengroš, H. Schmalz, Nils E Schloerer, 2009, Angewandte Chemie.

A convenient entry to new C-7-modified colchicinoids through azide alkyne 〔3+2〕 cycloaddition: application of ring-contractive rearrangements

A. Fedorov, H. Schmalz, Norman Nicolaus, 2010 .

Synthesis of C2-Symmetric Bisphosphine Ligands from Tartaric Acid, and Their Performance in the Pd-Catalyzed Asymmetric O-Allylation of a Phenol

H. Schmalz, M. Dindaroglu, S. Dincer, 2014 .

Total Syntheses of Colchicine in Comparison: A Journey Through 50 Years of Synthetic Organic Chemistry

H. Schmalz, T. Graening, 2004 .

Nucleophile- or light-induced synthesis of 3-substituted phthalides from 2-formylarylketones.

H. Schmalz, D. Gerbino, N. Slavov, 2012, Organic letters.

N-Capping of primary amines with 2-acyl-benzaldehydes to give isoindolinones.

J. Neudörfl, H. Schmalz, D. Gerbino, 2011, Organic letters.

Introduction of Allyl and Prenyl Side-Chains into Aromatic Systems by Suzuki Cross-Coupling Reactions

H. Schmalz, Sandra D. Mandolesi, D. Gerbino, 2009 .

Insertion of Carbenoids into CpH Bonds of Ferrocenes: An Enantioselective‐Catalytic Entry to Planar‐Chiral Ferrocenes

H. Schmalz, S. Siegel, 1997 .

1.5 – Asymmetric Nucleophilic Addition to Electron Deficient Alkenes

H. Schmalz, 1991 .

Total synthesis of (-)-colchicine via a Rh-triggered cycloaddition cascade.

J. Lex, J. Neudörfl, H. Schmalz, 2005, Organic letters.

Facile construction of the colchicine skeleton by a rhodium-catalyzed cyclization/cycloaddition cascade.

J. Lex, H. Schmalz, T. Graening, 2002, Angewandte Chemie.

New Developments in the Pauson-Khand Reaction.

H. Schmalz, Oliver Geis, 1998, Angewandte Chemie.

A Pauson-Khand approach to new carbocyclic nucleoside analogs

Andreas Lanver, H. Schmalz, 2005 .

Chiral Phosphine-Phosphite Ligands in Asymmetric Gold Catalysis: Highly Enantioselective Synthesis of Furo[3,4-d]-Tetrahydropyridazine Derivatives through [3+3]-Cycloaddition.

J. Neudörfl, H. Schmalz, Qingwei Du, 2018, Chemistry.

Memory of Chirality in Electron Transfer Mediated Benzylic Umpolung Reactions of Arene-Cr(CO)3 Complexes.

C. D. de Koning, H. Schmalz, S. Siegel, 1999, Angewandte Chemie.

Total synthesis of (R,R,R)-α-tocopherol through asymmetric Cu-catalyzed 1,4-addition.

T. Netscher, W. Bonrath, H. Schmalz, 2014, Chemistry.

Total Synthesis of (2RS)‐α‐Tocopherol through Ni‐Catalyzed 1,4‐Addition to a Chromenone Intermediate

T. Netscher, W. Bonrath, H. Schmalz, 2014 .

TARTROL-derived chiral phosphine–phosphite ligands and their performance in enantioselective Cu-catalyzed 1,4-addition reactions

J. Neudörfl, H. Schmalz, A. Burke, 2013 .

An enantioselective total synthesis of helioporins C and E.

J. Neudörfl, H. Schmalz, Wibke Loelsberg, 2012, Organic letters.

Cu‐Catalyzed Enantioselective 1,4‐Additions of Aryl‐Grignard Reagents to Cyclohexenone in the Presence of TADDOL‐Derived Phosphane‐Phosphite Ligands

H. Schmalz, D. Kranz, M. Dindaroglu, 2012 .

Enantioselective Copper‐Catalysed Allylic Alkylation of Cinnamyl Chlorides by Grignard Reagents using Chiral Phosphine‐Phosphite Ligands

H. Schmalz, Wibke Loelsberg, Shute Ye, 2010 .

Synthesis of a Mumbaistatin Analogue through Cross-Coupling

J. Lex, H. Schmalz, David Sucunza, 2007 .

Asymmetric catalytic arylation of ethyl glyoxylate using organoboron reagents and Rh(I)–phosphane and phosphane–phosphite catalysts

H. Schmalz, A. Burke, M. Dindaroglu, 2014 .

Michael Additions of Aldehydes and Ketones to β‐Nitrostyrenes in an Ionic Liquid

H. Schmalz, Š. Toma, Peter Kotrusz, 2004 .

Enantioselective Organocatalysis in Ionic Liquids: Addition of Aliphatic Aldehydes and Ketones to Diethyl Azodicarboxylate

H. Schmalz, Š. Toma, Peter Kotrusz, 2005 .

Hydrogen peroxide sensors based on fluorescence quenching of the 2-aminobenzimidazole fluorophore.

A. Griesbeck, H. Schmalz, B. Goldfuss, 2019, The Journal of organic chemistry.

Chiral [η6‐Arene–Cr(CO)3] Complexes as Synthetic Building Blocks: A Short Enantioselective Total Synthesis of (+)‐Ptilocaulin

J. Bats, H. Schmalz, K. Schellhaas, 1998 .

Gaining absolute control of the regiochemistry in the cobalt-catalyzed 1,4-hydrovinylation reaction.

G. Hilt, H. Schmalz, M. Dindaroglu, 2011, Organic letters.

Stereoselective syntheses of the 2-Isopropenyl-2,3-dihydrobenzofuran nucleus: potential chiral building blocks for the syntheses of tremetone, hydroxytremetone, and rotenone.

S. Pelly, C. D. de Koning, M. Fernandes, 2007, The Journal of organic chemistry.

Gram-scale synthesis of pinusolide and evaluation of its antileukemic potential.

G. Henze, S. Chernov, G. Tolstikov, 2006, Bioorganic & medicinal chemistry letters.

An Atom-Economic and Stereospecific Access to Trisubstituted Olefins through Enyne Cross Metathesis Followed by 1,4-Hydrogenation

H. Schmalz, Friederike Ratsch, 2018 .

Low-Pressure Cobalt-Catalyzed Enantioselective Hydrovinylation of Vinylarenes.

H. Schmalz, J. Westphal, M. Dindaroglu, 2016, Chemistry.

Cobalt-catalyzed 1,4-hydrobutadienylation of 1-aryl-1,3-dienes with 2,3-dimethyl-1,3-butadiene.

G. Hilt, H. Schmalz, M. A. Bohn, 2011, Angewandte Chemie.

Ligand Control of the Cobalt-Catalysed 1,4-Hydrovinylation Reaction

G. Hilt, H. Schmalz, M. Dindaroglu, 2012 .

Total Synthesis of α-Tocopherol through Enantioselective Iridium-Catalyzed Fragmentation of a Spiro-Cyclobutanol Intermediate.

T. Netscher, J. Neudörfl, H. Schmalz, 2019, Chemistry.

Electron Transfer Driven Addition of Ketimine Derived Radicals to Arene-Cr(CO)3 Complexes

H. Schmalz, O. Hoffmann, 1998 .

Electron transfer driven reactions of transition metal π-complexes: Hydrogenation of styrene-Cr(CO)3 derivatives by samarium(II)iodide in the presence of water

H. Schmalz, S. Siegel, D. Bernicke, 1998 .

On the oxazaborolidine-catalyzed borane reduction of 1-tetralone-Cr(CO)3 complexes: The control of the reagent over a strong substrate

H. Schmalz, H. Jope, 1998 .

Chiral arene-Cr(CO) 3 complexes in organic synthesis: A short enantioselective total synthesis of putative helioporin D

J. Bats, H. Schmalz, Thomas Geller, 1998 .

ENANTIOSELECTIVE SYNTHESIS OF THE AGLYCONES OF PSEUDOPTEROSIN AND SECO-PSEUDOPTEROSIN VIA A COMMON SYNTHETIC INTERMEDIATE

H. Schmalz, A. Majdalani, 1997 .

Chiral η6-Arene-Cr(CO)3 complexes in organic synthesis: A short and highly selective synthesis of the 18-nor-seco-pseudopterosin aglycone

H. Schmalz, A. Majdalani, 1997 .

Chiral η6-arene-Cr(CO)3 complexes as synthetic building blocks: An enantio- and diastereoselective approach to substituted hydrophenalenes related to helioporin E and pseudopterosin G

H. Schmalz, A. Schwarz, G. Duerner, 1994 .

The Total Synthesis of cis‐7,8‐Dihydroxy‐11,12‐dehydrocalamenene by Regio‐ and Diastereo‐selective Alkylation of Chiral η6‐Arenetricarbonylchromium Complexes: An Unexpected Case of Nucleophilic Aromatic tele‐Substitution with Methoxide as a Leaving Group

J. Bats, H. Schmalz, M. Arnold, 1994 .

Total synthesis of (1S,4S)-7,8-dihydroxycalamenene via benzylic alkylation of η6-arene-Cr(CO)3 complexes

H. Schmalz, M. Arnold, G. Duerner, 1993 .

Diastereoselective Complexation of Temporarily Chirally Modified Ligands: Enantioselective Preparation and Configurational Assignment of Synthetically Valuable η6-Tricarbonylchromium-1-tetralone Derivatives†‡

J. Bats, H. Schmalz, G. Duerner, 1992 .

Unexpected endo selectivity of conjugate nucleophilic addition to an arene-Cr(CO)3 complex: enantioselective synthesis of the diterpene 11-epi-helioporin B.

H. Schmalz, F Dehmel, H G Schmalz, 2001, Organic letters.

On the enantioselective deprotonation/silylation of prochiral mono- and 1,2-dimethoxybenzene-Cr(CO)3 derivatives

H. Schmalz, K. Schellhaas, 1995 .

On the regioselectivity of nucleophilic additions to anisole-Cr(CO)3 and related complexes: a density functional study

W. Koch, H. Schmalz, A. Pfletschinger, 2001 .

An approach to serrulatane diterpenes via endo-selective conjugate nucleophilic addition to arene-Cr(CO)3 complexes.

J. Lex, H. Schmalz, F. Dehmel, 2002, Organic letters.

Application of Chromium-Arene Complexes in the Organic Synthesis. Efficient Synthesis of Stilbene Phytoalexins

H. Schmalz, K. E. Polunin, K. E. Polunin, 2004 .

On the deprotonation of η6-1,3-dimethoxybenzene-Cr(CO)3 derivatives: Influence of the reaction conditions on the regioselectivity

H. Schmalz, S. Huneck, D. Bernicke, 1997 .

Kontrolle des Reaktionsverlaufes bei nucleophilen Additionen an ortho-substituierte (η6-Anisol)tricarbonylchrom-Komplexe: Dienolether-Bildung versus tele-Substitution†

H. Schmalz, K. Schellhaas, 1996 .

Natural Products Synthesis

H. Schmalz, B. Gotov, A. Böttcher, 2004 .

Highly Regioselective Benzylic Deprotonation of Some (η6-Tetralin)- and (η6-trans-Octahydroanthracene)Cr(CO)3 Derivatives: Is the Regioselectivity Stereoelectronically Controlled?

J. Bats, H. Schmalz, D. Bernicke, 1998 .

Iron-containing nucleoside analogues with pronounced apoptosis-inducing activity.

T. Wieder, A. Prokop, J. Velcicky, 2004, Angewandte Chemie.

Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched Vinylcyclopropane Derivatives.

I. Marek, H. Schmalz, Sema Akyol, 2017, Organic letters.

Kinetic investigation of the reduction of pinacolone by borane catalyzed by oxazaborolidines in THF. Hydride shift as rate determining step

R. Schmidt, H. Schmalz, Holger Jockel, 2000 .

Encyclopedia of Reagents for Organic Synthesis. Vol. 1–8. Gesamtherausgeber L. A. Paquette. Wiley, Chichester, 1995. 6223 S., geb. 1750 £. – ISBN 0‐471‐93623‐5

Hans-Günther Schmalz, H. Schmalz, 1996 .

Enantioselective Heck Reactions

H. Schmalz, M. Jachmann, 2003 .

Zr‐Catalyzed Carbomagnesation of Alkenes

H. Schmalz, Florian Blume, 2003 .

Identification of Suitable Ligands for a Transition Metal‐Catalyzed Reaction: Screening of a Modular Ligand Library in the Enantioselective Hydroboration of Styrene

H. Schmalz, R. Kranich, Florian Blume, 2002 .

Total Synthesis of Ikarugamycin

O. Schwarz, H. Schmalz, 2002 .

Synthesis of 4-benzyliden-2-oxazolidinone derivatives via gold-catalyzed intramolecular hydroamination

H. Schmalz, S. Ritter, Kristina Hackelöer, 2007 .

Biomimetic Synthesis of Isoindolinones Related to the Marilines

H. Schmalz, Daniel Augner, 2015, Synlett.

Pd-catalyzed cross-coupling of chloroarene-Cr(CO)3 complexes with stabilized organoindium (III) reagents under remarkably mild conditions

H. Schmalz, H. Schumann, B. Gotov, 2002 .

Rhodium‐Catalyzed Enantioselective Intramolecular [4+2] Cycloaddition using a Chiral Phosphine‐Phosphite Ligand: Importance of Microwave‐Assisted Catalyst Conditioning

J. Neudörfl, Lukas Fiebig, H. Schmalz, 2011 .

Total synthesis of the marine antibiotic pestalone and its surprisingly facile conversion into pestalalactone and pestalachloride A.

J. Cvengroš, J. Neudörfl, H. Schmalz, 2010, Angewandte Chemie.

Enantioselective synthesis of a trans-7,8-dimethoxycalamenene.

J. Neudörfl, H. Schmalz, T. Fey, 2007, Organic letters.

Synthetic analogues of the antibiotic pestalone

Florian Kaiser, H. Schmalz, 2003 .

Exercises in pyrrolidine chemistry: gram scale synthesis of a Pro-Pro dipeptide mimetic with a polyproline type II helix conformation.

R. Kühne, J. Neudörfl, H. Schmalz, 2011, Chemistry.

Synthetic Indolactam V Analogues as Inhibitors of PAR2‐Induced Calcium Mobilization in Triple‐Negative Breast Cancer Cells

N. Teusch, J. Neudörfl, H. Schmalz, 2018, ChemMedChem.

Chiral η4-butadiene-Fe(CO)3 complexes for organic synthesis: Reactions of (η4-2-alkoxy-4-vinyl-2,5-dihydrofuran)-Fe(CO)3 derivatives

H. Schmalz, E. Hessler, G. Duerner, 1994 .

Diallylaluminium-N,N-dimethylaminoethanolate, the first stable allyl-alane suitable for additions to aldehydes, ketones and imines

H. Schmalz, S. Dechert, H. Schumann, 2002 .

Stereoselective Synthesis and Biological Evaluation of Ferrocene‐Containing 5‐Hydroxyeicosatetraenoic Acid Analogues

A. Prokop, J. Neudörfl, H. Schmalz, 2011 .

Total syntheses of colchicine in comparison: a journey through 50 years of synthetic organic chemistry.

H. Schmalz, T. Graening, 2004, Angewandte Chemie.

Enantioselective Total Synthesis and Structural Revision of Dysiherbol A

J. Neudörfl, H. Schmalz, D. Blunk, 2021, Angewandte Chemie.

Structural and Energetical Characterization of the Methylbutadiene–Fe(CO)3 Isomers and Related Reactive Intermediates with Quantum Chemical Methods

W. Koch, H. Schmalz, A. Pfletschinger, 1999 .

Enantioselective Cu-catalyzed 1,4-addition of Grignard reagents to cyclohexenone using taddol-derived phosphine-phosphite ligands and 2-methyl-THF as a solvent.

T. Robert, H. Schmalz, J. Velder, 2008, Angewandte Chemie.

A [2 + 2 + 2]-cycloaddition approach toward 6-oxa-allocolchicinoids with apoptosis-inducing activity.

A. Prokop, H. Schmalz, Norman Nicolaus, 2009, Organic letters.

Synthesis of indole-derived allocolchicine congeners exhibiting pronounced anti-proliferative and apoptosis-inducing properties

P. Barbier, Diane Allegro, A. Fedorov, 2015 .

Synthesis and cytostatic properties of polyfunctionalized furanoallocolchicinoids.

I. A. Gracheva, I. V. Voitovich, A. Fedorov, 2017, European journal of medicinal chemistry.

Synthesis of new sulfur-containing derivatives of furanoallocolchicinoids

A. Fedorov, E. Svirshchevskaya, H. Schmalz, 2016, Russian Journal of Organic Chemistry.

Lipophilic prodrugs of a triazole-containing colchicine analogue in liposomes: Biological effects on human tumor cells

H. Oschkinat, A. Fedorov, A. Prokop, 2013, Russian Journal of Bioorganic Chemistry.

A Convenient Entry to New C-7-Modified Colchicinoids Through Azide Alkyne [3 + 2] Cycloaddition: Application of Ring-Contractive Rearrangements.

A. Fedorov, H. Schmalz, Norman Nicolaus, 2011 .

Pd-catalyzed enantioselective allylic substitution: new strategic options for the total synthesis of natural products.

H. Schmalz, T. Graening, 2003, Angewandte Chemie.

Iron Dienylphosphate Tricarbonyl Complexes as Water-Soluble Enzyme-Triggered CO-Releasing Molecules (ET-CORMs)

B. Yard, Miguel Guttentag, R. Alberto, 2012 .

Regeneration of ergothioneine after reaction with singlet oxygen.

D. Gründemann, H. Schmalz, B. Goldfuss, 2019, Free radical biology & medicine.

Asymmetric hydroformylation using Taddol-based chiral phosphine-phosphite ligands

T. Robert, J. Reek, J. Neudörfl, 2010 .

Chromium Carbene Complexes in Organic Synthesis: Recent Developments and Perspectives

H. Schmalz, 1994 .

η6-Arene–tricarbonylchromium complexes in the syntheses of trans-resveratrol and pinostilbene

H. Schmalz, K. E. Polunin, I. Polunina, 2002 .

A practical synthesis of trans-3-substituted proline derivatives through 1,4-addition.

J. Neudörfl, H. Schmalz, P. Huy, 2011, Organic letters.

Total Synthesis of (+)‐Erogorgiaene and the Pseudopterosin A−F Aglycone via Enantioselective Cobalt‐Catalyzed Hydrovinylation

M. Hochgürtel, N. Teusch, J. Neudörfl, 2021, Chemistry.

Preparation of helioporin D from the seco-pseudopterosin aglycone: Revision of the stereostructure of helioporin D

H. Schmalz, J. Jakupovic, Thomas Geller, 1998 .

3β-Acetoxy-19-hydroxy-Δ5-pregnen-20-one

J. Neudörfl, H. Schmalz, D. Kranz, 2013, Acta crystallographica. Section E, Structure reports online.

Synthesis of B-ring-modified steroids through BF3-promoted rearrangement/substitution of 6β-hydroxy-5,19-cyclosteroids.

J. Neudörfl, H. Schmalz, D. Kranz, 2012, Organic letters.

Triple‐Helix‐Stabilizing Effects in Collagen Model Peptides Containing PPII‐Helix‐Preorganized Diproline Modules

U. Baumann, R. Kühne, J. Neudörfl, 2020, Angewandte Chemie.

Design and Synthesis of Building Blocks for PPII‐Helix Secondary‐Structure Mimetics: A Stereoselective Entry to 4‐Substituted 5‐Vinylprolines

R. Kühne, R. Opitz, Matthias M. Müller, 2018 .

Design and Stereoselective Synthesis of ProM-2: A Spirocyclic Diproline Mimetic with Polyproline Type II (PPII) Helix Conformation.

R. Kühne, R. Opitz, J. Neudörfl, 2015, Chemistry.

Addressing protein-protein interactions with small molecules: a Pro-Pro dipeptide mimic with a PPII helix conformation as a module for the synthesis of PRD-binding ligands.

R. Kühne, H. Oschkinat, R. Opitz, 2010, Angewandte Chemie.

A synthetic derivative of houttuynoid B prevents cell entry of Zika virus.

E. Hildt, H. Schmalz, Fabian Elgner, 2019, Antiviral research.

A Short Enantioselective Synthesis of (S)-Levetiracetam through Direct Palladium-Catalyzed Asymmetric N-Allylation of Methyl 4-Aminobutyrate

J. Neudörfl, H. Schmalz, Dominik Albat, 2021, Synlett.

An approach to chiral η4-butadiene-Fe(CO)3 complexes via diastereoselective complexation of nonracemic 2-alkoxy-4-vinyl-2,5-dihydrofuran derivatives

J. Bats, H. Schmalz, E. Hessler, 1994 .

Total Synthesis of the Pseudoguaianolide (+)‐Confertin

J. Bats, H. Schmalz, G. Quinkert, 1987 .

Studies toward the total synthesis of mumbaistatin, a highly potent glucose-6-phosphate translocase inhibitor. Synthesis of a mumbaistatin analogue.

Florian Kaiser, H. Schmalz, Lothar Schwink, 2002, The Journal of organic chemistry.

Low-Pressure Cobalt-Catalyzed Enantioselective Hydrovinylation of Vinylarenes.

H. Schmalz, J. Westphal, M. Dindaroglu, 2016, Chemistry.

Proline-rich sequence recognition domains (PRD): ligands, function and inhibition.

R. Kühne, J. Sticht, C. Freund, 2008, Handbook of experimental pharmacology.

Paraoxonase-1 is a major determinant of clopidogrel efficacy

C. Hirschhäuser, E. Schömig, H. Bouman, 2011, Nature Medicine.

A modular toolkit to inhibit proline-rich motif–mediated protein–protein interactions

P. Schmieder, R. Kühne, B. Wiesner, 2015, Proceedings of the National Academy of Sciences.

Synthesis of Nonracemic Pyrrolo‐allocolchicinoids Exhibiting Potent Cytotoxic Activity

I. Beletskaya, A. Fedorov, E. Svirshchevskaya, 2016 .

Methyl Fumarate‐Derived Iron Carbonyl Complexes (FumET‐CORMs) as Powerful Anti‐inflammatory Agents

T. Wieder, H. Braumüller, M. Röcken, 2017, ChemMedChem.

Enzyme-triggered CO-releasing molecules (ET-CORMs): evaluation of biological activity in relation to their structure.

B. Krämer, B. Yard, M. Hafner, 2013, Free radical biology & medicine.

New caspase-independent but ROS-dependent apoptosis pathways are targeted in melanoma cells by an iron-containing cytosine analogue.

J. Eberle, A. Prokop, H. Schmalz, 2010, Biochemical pharmacology.

Sn(OTf)2 as an Effective Lewis Acid in Reactions of Cyclopropyl Ketones with Acetic Anhydride: Application in the Synthesis of a 19‐Nor‐B‐homo Steroid

J. Neudörfl, H. Schmalz, D. Kranz, 2011 .

Proposed “Biosynthesis” of Primarolides A and B from a Common 2-Formylbenzophenone Precursor

H. Schmalz, 2019 .

On the antibiotic and antifungal activity of pestalone, pestalachloride A, and structurally related compounds.

H. Sahl, M. Krönke, O. Krut, 2013, Journal of natural products.

N-Capping of Primary Amines with 2-Acylbenzaldehydes to Give Isoindolinones.

H. Schmalz, D. Gerbino, Joerg‐Martin Neudoerfl, 2012 .

Stereoselective Synthesis of Tricyclic Diproline Analogues that Mimic a PPII Helix: Structural Consequences of Ring-Size Variation

R. Kühne, N. Schlörer, J. Neudörfl, 2014 .

Stereoselective Synthesis of Proline‐Derived Dipeptide Scaffolds (ProM‐3 and ProM‐7) Rigidified in a PPII Helix Conformation

R. Kühne, J. Neudörfl, H. Schmalz, 2014 .

Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate

Cédric Reuter, Jörg M. Neudörfl, Hans-Günther Schmalz, 2010, Acta crystallographica. Section E, Structure reports online.

Inhibition of CPAP–tubulin interaction prevents proliferation of centrosome‐amplified cancer cells

A. Hyman, M. Odenthal, H. Urlaub, 2018, The EMBO journal.

Design and Synthesis of New Protease‐Triggered CO‐Releasing Peptide–Metal‐Complex Conjugates

A. Fedorov, H. Schmalz, Yulia B. Malysheva, 2019, European Journal of Organic Chemistry.

Structural and Energetical Characterization of Reactive Intermediates Derived from Toluene–Cr(CO)3

J. Bats, W. Koch, H. Schmalz, 1999 .

Benzylic endo-alkylation of phthalan-Cr(CO)3 complexes via temporary silylation: an entry to trans-1,3-disubstituted dihydroisobenzofurans.

J. Lex, H. Schmalz, Saskia Zemolka, 2002, Angewandte Chemie.

Density functional investigation of reactive intermediates derived from alkyne-Co2(CO)6 complexes.

W. Koch, H. Schmalz, L. Koch, 2001, Chemistry.

A Scalable Synthesis of (±)-2-Oxoclopidogrel

C. Hirschhäuser, H. Bouman, H. Schmalz, 2010 .

Efficient α-helix induction in a linear peptide chain by N-capping with a bridged-tricyclic diproline analogue.

P. Schmieder, R. Kühne, R. Opitz, 2013, Angewandte Chemie.

Total Synthesis of (-)-Colchicine via a Rh-Triggered Cycloaddition Cascade

J. Lex, J. Neudörfl, H. Schmalz, 2005 .

Designed nanomolar small-molecule inhibitors of Ena/VASP EVH1 interaction impair invasion and extravasation of breast cancer cells

P. Schmieder, P. Lindemann, R. Kühne, 2020, Proceedings of the National Academy of Sciences.

Anti‐inflammatory AreneChromium Complexes Acting as Specific Inhibitors of NOD2 Signalling

M. Krönke, S. Meemboor, H. Schmalz, 2010, ChemMedChem.

Stereospecificity of the Au(I)-catalyzed reaction of 1-alkynyl-bicyclo[4.1.0]-heptan-2-ones with nucleophiles

J. Neudörfl, H. Schmalz, Andreas Adler, 2010 .

The Use of (+)-8-Phenylneomenthol in the Synthesis of Enantiomerically Pure (−)-Jasmonate Methyl Ester†‡

J. Bats, H. Schmalz, G. Quinkert, 1986 .

Gram-scale synthesis of suspension-polymerized styrene-divinylbenzene-based resins using an oscillatory baffled reactor.

D. Sherrington, X. Ni, Andreas Lanver, 2002, Angewandte Chemie.

Different design of enzyme-triggered CO-releasing molecules (ET-CORMs) reveals quantitative differences in biological activities in terms of toxicity and inflammation

B. Krämer, B. Yard, M. Hafner, 2014, Redox biology.

(RS)-Tricarbonyl(η4-1,3-diacetoxy-5,5-dimethylcyclohexa-1,3-diene)iron(0)

J. Neudörfl, H. Schmalz, S. Romanski, 2011, Acta crystallographica. Section E, Structure reports online.

Lipophilic prodrugs of a triazole-containing colchicine analogue in liposomes: Biological effects on human tumor cells

A. Fedorov, A. Prokop, H. Schmalz, 2013, Russian Journal of Bioorganic Chemistry.

Acyloxybutadiene iron tricarbonyl complexes as enzyme-triggered CO-releasing molecules (ET-CORMs).

S. Amslinger, J. Neudörfl, H. Schmalz, 2011, Angewandte Chemie.

A novel conjugate of a cell-penetrating peptide and a ferrocenyl amino acid: a potential electrochemical sensor for living cells?

H. Schmalz, I. Neundorf, Jan Hoyer, 2012, Dalton transactions.

Total synthesis of the marine antibiotic pestalone and its surprisingly facile conversion into pestalalactone and pestalachloride A.

J. Cvengroš, J. Neudörfl, H. Schmalz, 2010, Angewandte Chemie.

Exercises in pyrrolidine chemistry: gram scale synthesis of a Pro-Pro dipeptide mimetic with a polyproline type II helix conformation.

R. Kühne, J. Neudörfl, H. Schmalz, 2011, Chemistry.

Synthesis and antitumor activity of 7-(triazol-1-yl)pyrroloallocolchicine derivatives

V. Fokin, A. Fedorov, A. Prokop, 2015, Russian Chemical Bulletin.

Synthesis and biological evaluation of furanoallocolchicinoids.

Diane Allegro, S. Combes, H. Schmalz, 2015, Journal of medicinal chemistry.

Synthesis of Novel AllocolchicineAnalogues with a Pyridine C-Ring through Intermolecular VollhardtDiyne-Nitrile Cyclotrimerization

H. Schmalz, Norman Nicolaus, 2010 .

Pd-Catalyzed Cross-Coupling of Haloarenes and Chloroarene-Cr(CO)3 Complexes with Stabilized Vinyl- and Allylaluminium Reagents

H. Schmalz, H. Schumann, B. Gotov, 2003 .

Chiral phosphine–phosphite ligands in the enantioselective 1,4-addition of Grignard reagents to α,β-unsaturated carbonyl compounds

T. Robert, H. Schmalz, D. Kranz, 2011 .