C. Kouklovsky

发表

S. Ley, C. Kouklovsky, 1995 .

Connecting Tyrosine and Tryptophan Units of Diazonamide A and Azonazine by a Diastereodivergent Arylative Dearomatization.

Natacha Denizot, R. Guillot, C. Kouklovsky, 2015, Chemistry.

Regioselective hydroarylation reactions of C3 electrophilic N-acetylindoles activated by FeCl3: an entry to 3-(hetero)arylindolines.

R. Guillot, C. Kouklovsky, G. Vincent, 2014, Chemistry.

FeCl3-mediated Friedel-Crafts hydroarylation with electrophilic N-acetyl indoles for the synthesis of benzofuroindolines.

R. Guillot, C. Kouklovsky, G. Vincent, 2012, Angewandte Chemie.

Stereodivergent synthesis of substituted N,O-containing bicyclic compounds by sequential addition of nucleophiles to N-alkoxybicyclolactams.

R. Guillot, C. Kouklovsky, G. Vincent, 2011, Angewandte Chemie.

(1S,2S)-1,2-Diaminocyclohexane†

C. Kouklovsky, Y. Langlois, E. Aguilar, 2003 .

8.14 Reduction of NN, N–N, N–O, and O–O Bonds

C. Kouklovsky, G. Vincent, 2014 .

Ring-rearrangement metathesis of nitroso Diels-Alder cycloadducts.

C. Kouklovsky, G. Vincent, 2011, Chemistry.

Tertiary aromatic amide for memory of chirality: access to enantioenriched alpha-substituted valine.

R. Guillot, C. Kouklovsky, M. Branca, 2008, Journal of the American Chemical Society.

Intermolecular nitroso Diels-Alder cycloaddition of alpha-acetoxynitroso derivatives in aqueous medium.

R. Guillot, C. Kouklovsky, N. Blanchard, 2005, Organic & biomolecular chemistry.

Camphor-derived sulfonylhydrazines: catalysts for Diels–Alder cycloadditions

A. Petit, P. Rémy, C. Kouklovsky, 2008 .

Frozen Chirality of Tertiary Aromatic Amides: Access to Enantioenriched Tertiary α-Amino Acid or Amino Alcohol without Chiral Reagent.

R. Guillot, C. Kouklovsky, Jean‐Valère Naubron, 2017, Chemistry.

Absolute asymmetric synthesis of tertiary α-amino acids.

R. Guillot, C. Kouklovsky, M. Branca, 2012, Angewandte Chemie.

Radical-Mediated Dearomatization of Indoles with Sulfinate Reagents for the Synthesis of Fluorinated Spirocyclic Indolines.

R. Guillot, C. Kouklovsky, G. Vincent, 2017, Organic letters.

One or More CC Bond(s) Formed by Substitution: Substitution of Carbon–Nitrogen, –Phosphorus, –Arsenic, –Antimony, –Boron, –Silicon, –Germanium, and –Metal Functions

C. Kouklovsky, 2005 .

Gram-Scale Enantioselective Synthesis of (+)-Lucidumone.

Guanghao Huang, C. Kouklovsky, Aurélien de la Torre, 2022, Journal of the American Chemical Society.

Studies towards the total synthesis of rapamycin: Preparation of the cyclohexyl C33C42 fragment and further coupling to afford the C22C42 carbon unit

S. Marsden, S. Ley, C. Kouklovsky, 1994 .

Towards the synthesis of the C37-C42 fragment of rapamycin: intramolecular reactions of allyl silanes with oxonium ions generated from α-alkoxy sulfones.

S. Ley, C. Kouklovsky, 1994 .

Synthesis of 3-arylated indolines from dearomatization of indoles

Natacha Denizot, C. Kouklovsky, G. Vincent, 2015 .

Direct oxidative coupling of N-acetyl indoles and phenols for the synthesis of benzofuroindolines related to phalarine.

R. Guillot, C. Kouklovsky, G. Vincent, 2014, Angewandte Chemie.

Regioselective hydroarylation reactions of C3 electrophilic N-acetylindoles activated by FeCl3: an entry to 3-(hetero)arylindolines.

R. Guillot, C. Kouklovsky, G. Vincent, 2014, Chemistry.

α-Acyloxynitroso dienophiles in [4+2] hetero Diels–Alder cycloadditions: mechanistic insights

C. Kouklovsky, N. Blanchard, S. Coote, 2010 .

Efficient cleavage of the N-O bond of 3,6-dihydro-1,2-oxazines mediated by some alpha-hetero substituted carbonyl compounds in mild conditions.

C. Kouklovsky, N. Blanchard, G. Galvani, 2008, Organic & biomolecular chemistry.

β,γ-diamino acids as building blocks for new analogues of Gramicidin S: Synthesis and biological activity.

S. Zirah, Yang Wan, C. Kouklovsky, 2018, European journal of medicinal chemistry.

Synthesis of Ferrocenyl Schiff Bases Under Solvent-Free Conditions Using Microwave Irradiation

A. Petit, C. Kouklovsky, Gülşen Öztürk, 2008 .

Foldamers containing γ-amino acid residues or their analogues: structural features and applications

C. Kouklovsky, V. Alezra, Francelin Bouillère, 2011, Amino Acids.

Unexpected dimerization of a tripeptide comprising a β,γ‐diamino acid

E. Miclet, J. Baltaze, Yang Wan, 2019, Journal of peptide science : an official publication of the European Peptide Society.

Oxazoline N-oxide mediated [2 + 3] cycloadditions. Application to a formal synthesis of (+)-carpetimycin A.

M. Mauduit, C. Kouklovsky, Y. Langlois, 2000, Organic Letters.

Memory of chirality of tertiary aromatic amide: application to the asymmetric synthesis of (S)-α-methylDOPA.

C. Kouklovsky, V. Alezra, D. Gori, 2012, The Journal of organic chemistry.

Oxidative coupling of enolates using memory of chirality: an original enantioselective synthesis of quaternary α-amino acid derivatives.

R. Guillot, C. Kouklovsky, V. Alezra, 2018, Chemical communications.

Oxazoline N-Oxide Mediated [3+2] Cycloadditions: Application to a Formal Synthesis of a (+)-β-Methylcarbapenem

M. Mauduit, C. Kouklovsky, Y. Langlois, 2000 .

Enantioselective Intramolecular Hydroamination of Secondary Amines Catalyzed by Easily Accessible Ate and Neutral Rare‐Earth Complexes

J. Collin, A. Meddour, C. Kouklovsky, 2011 .

Synthesis and biological evaluation of bengacarboline derivatives.

J. Annereau, C. Bailly, J. Barret, 2008, Bioorganic & Medicinal Chemistry Letters.

Access to β,γ-diamino acids. Application to the synthesis of 3-deoxyaminostatine.

R. Guillot, C. Kouklovsky, V. Alezra, 2011, Organic & biomolecular chemistry.

3-Aminopyrrolidines from alpha-aminoacids: total synthesis of (+)-nemonapride from D-alanine.

C. Kouklovsky, V. Alezra, V. Nguyen, 2008, The Journal of organic chemistry.

A stereoselective entry into functionalized 1,2-diamines by zinc-mediated homologation of alpha-aminoacids.

R. Guillot, C. Kouklovsky, V. Alezra, 2007, Organic Letters.

Enantioselective total synthesis of pyrinodemin A.

C. Kouklovsky, Y. Langlois, A. Vidal, 2008, Organic & biomolecular chemistry.

Synthesis of 3,3-Spiroindolines via FeCl3-Mediated Cyclization of Aryl- or Alkene-Containing 3-Substituted N-Ac Indoles.

R. Nandi, R. Guillot, C. Kouklovsky, 2016, Organic letters.

Inverse-Electron-Demand Diels-Alder Reactions of 2-Pyrones: Bridged Lactones and Beyond.

Guanghao Huang, C. Kouklovsky, A. Torre, 2020, Chemistry.

3.16 Synthetically Derived Auxiliaries: Amines (including Diamines), Hydrazines and Hydroxylamines, and Amino Alcohols

C. Kouklovsky, 2012 .

Highly Stereoselective Aldol Reactions by Memory of Chirality: Synthesis of Quaternary β‐Hydroxy α‐Amino Acids

R. Guillot, C. Kouklovsky, V. Alezra, 2021, Helvetica Chimica Acta.

Memory of Chirality in a Flow‐Based System: Enantioselective Synthesis of Quaternary α‐Amino Acids Using Flow Microreactors

J. Yoshida, Heejin Kim, C. Kouklovsky, 2018 .

Memory of chirality of tertiary aromatic amides: a simple and efficient method for the enantioselective synthesis of quaternary alpha-amino acids.

R. Guillot, C. Kouklovsky, M. Branca, 2009, Journal of the American Chemical Society.

Substrate control in enantioselective and diastereoselective aldol reaction by memory of chirality: a rapid access to enantiopure β-hydroxy quaternary α-amino acids.

R. Guillot, C. Kouklovsky, V. Alezra, 2014, Organic letters.

Stereodivergent synthesis of piperidine alkaloids by ring-rearrangement metathesis/reductive lactam alkylation of nitroso Diels-Alder cycloadducts.

C. Kouklovsky, G. Vincent, D. Gori, 2013, Chemistry.

Domino metathesis of 3,6-dihydro-1,2-oxazine: access to isoxazolo[2,3-a]pyridin-7-ones.

C. Kouklovsky, N. Blanchard, G. Calvet, 2007, Organic letters.

Amino acid homologation by the Blaise reaction: a new entry into nitrogen heterocycles.

C. Kouklovsky, V. Alezra, D. Gori, 2009, The Journal of organic chemistry.

Synthesis of benzofuro[3,2-b]indoline amines via deamination-interrupted Fischer indolization and their unexpected reactivity towards nucleophiles.

R. Guillot, C. Kouklovsky, G. Vincent, 2016, Chemical communications.

The Pivotal Role of N-O bonds in the Synthesis of Natural Products: A mini-review

C. Kouklovsky, 2020 .

Bioinspired direct access to benzofuroindolines by oxidative [3 + 2] annulation of phenols and indoles.

Natacha Denizot, R. Guillot, C. Kouklovsky, 2014, Organic letters.

Electrochemical Dearomative 2,3-Difunctionalization of Indoles.

R. Guillot, C. Kouklovsky, G. Vincent, 2018, Journal of the American Chemical Society.

New chiral amino acid-derived α-acyloxynitroso reagents for asymmetric nitroso Diels–Alder reactions

C. Kouklovsky, G. Vincent, D. Gori, 2010 .

Total synthesis of rapamycin.

Matthew L. Maddess, S. Marsden, S. Ley, 2009, Chemistry.

Unified biomimetic assembly of voacalgine A and bipleiophylline via divergent oxidative couplings.

J. Gallard, V. Dumontet, M. Beniddir, 2017, Nature chemistry.

Electrochemical synthesis of 3a-bromofuranoindolines and 3a-bromopyrroloindolines mediated by MgBr2.

R. Guillot, C. Kouklovsky, G. Vincent, 2019, Chemical communications.

Synthesis of oxaspirannic building blocks by regioselective nitroso-Diels-Alder reactions.

C. Kouklovsky, G. Vincent, D. Gori, 2013, Chemistry.

Bioinspired Divergent Oxidative Cyclizations of Geissoschizine: Total Synthesis of (–)‐17‐nor‐Excelsinidine, (+)‐16‐ epi ‐Pleiocarpamine, (+)‐16‐Hydroxymethyl‐Pleiocarpamine and (+)‐Taberdivarine H

Natacha Denizot, L. Evanno, C. Kouklovsky, 2020 .

Bioinspired Oxidative Cyclization of the Geissoschizine Skeleton for Enantioselective Total Synthesis of Mavacuran Alkaloids.

J. Gallard, L. Evanno, C. Kouklovsky, 2019, Angewandte Chemie.

Bioinspired Oxidative Cyclization of the Geissoschizine Skeleton for the Total Synthesis of (-)-17-nor-Excelsinidine.

L. Evanno, C. Kouklovsky, G. Vincent, 2018, Angewandte Chemie.

Double diastereoselection in asymmetric [2+3] cycloaddition of chiral oxazoline N-oxides: application to the kinetic resolution of a racemic α,β-unsaturated δ-lactone

J. Courtieu, C. Kouklovsky, Y. Langlois, 1999 .

Expedient Approach to α,β‐Unsaturated δ‐Lactones through a Catalytic Asymmetric [2+2] Cycloaddition

R. Guillot, C. Kouklovsky, G. Vincent, 2017 .

Oxazoline N-Oxide-Mediated [2 + 3] Cycloadditions: Application to a Total Synthesis of the Hypocholesterolemic Agent 1233A

C. Kouklovsky, Y. Langlois, O. Dirat, 1998 .

Lewis Acid-Promoted Hetero Diels−Alder Cycloaddition of α-Acetoxynitroso Dienophiles

C. Kouklovsky, N. Blanchard, G. Calvet, 2004 .

Chiral α,β-unsaturated oxazolines in the asymmetric diels-alder reaction ☆

E. Uriarte, A. Chiaroni, C. Kouklovsky, 1989 .

Regio- and stereochemical studies on the nitroso-Diels-Alder reaction with 1,2-disubstituted dienes.

C. Kouklovsky, G. Galvani, R. Lett., 2013, Chemistry.

An Approach to the Synthesis of Tetrahydroisoquinoline Alkaloids by Alkene Hydroamination: Synthesis of Coralydine

J. Baltaze, C. Kouklovsky, A. Pouilhès, 2013 .

Enantioselective Total Synthesis of Cymoside through a Bioinspired Oxidative Cyclization of a Strictosidine Derivative

V. Gandon, C. Kouklovsky, G. Vincent, 2019, Angewandte Chemie.

Oxazoline N-oxide-mediated [2+3] cycloadditions. Application to a synthesis of (-)-tetrahydrolipstatin.

C. Kouklovsky, Y. Langlois, O. Dirat, 1999, Organic letters.

Synthesis of 3,3-Spirocyclic 2-Phosphonoindolines via a Dearomative Addition of Phosphonyl Radicals to Indoles.

J. Baltaze, R. Guillot, C. Kouklovsky, 2019, Organic letters.

[3 + 2] Cycloadditions between α,β-Unsaturated Esters or Nitroalkenes and Camphor-Derived Oxazoline N-Oxides: Experimental and Theoretical Study

C. Kouklovsky, Y. Langlois, O. Dirat, 1998 .

Cyanomethylene cyclopropane, a useful dipolarophile and dienophile in [2+3] and [2+4] cycloadditions

M. Mauduit, C. Kouklovsky, Y. Langlois, 1998 .

.alpha.,.beta.-Unsaturated oxazolines, a powerful tool in asymmetric Diels-Alder cycloadditions

C. Kouklovsky, Y. Langlois, A. Pouilhès, 1990 .

α,β-Unsaturated oxazolines and oxazine, useful dienophiles in the Diels-Alder reaction

C. Kouklovsky, N. Langlois, Y. Langlois, 1987 .

β,γ-Diamino acid: an original building block for hybrid α/γ-peptide synthesis with extra hydrogen bond donating group

E. Miclet, R. Guillot, C. Kouklovsky, 2014, Amino Acids.

Constrained Cyclic β,γ‐Diamino Acids from Glutamic Acid: Synthesis of Both Diastereomers and Unexpected Kinetic Resolution

Yang Wan, R. Guillot, C. Kouklovsky, 2018 .

Efficient synthesis of both diastereomers of β,γ-diamino acids from phenylalanine and tryptophan

R. Guillot, C. Kouklovsky, V. Alezra, 2016, Amino Acids.

Original β,γ-diamino acid as an inducer of a γ-turn mimic in short peptides.

E. Miclet, J. Baltaze, F. Brisset, 2012, Organic & biomolecular chemistry.

Constrained α/γ-peptides: a new stable extended structure in solution without any hydrogen bond and characterized by a four-fold symmetry.

E. Miclet, R. Guillot, C. Kouklovsky, 2012, Chemical communications.

A Stereoselective Entry into Functionalized 1,2-Diamines by Zinc-Mediated Homologation of α-Amino Acids.

R. Guillot, C. Kouklovsky, V. Alezra, 2007 .

Accurate conformation analysis in solution: NMR and DFT/PCM study of the S-3-(1-naphthoyl)-4-isopropyl-2,2-dimethyloxazolidin-5-one in CDCl3

P. Archirel, C. Kouklovsky, M. Branca, 2008 .

Dearomatization Reactions of Indoles to Access 3D Indoline Structures

C. Kouklovsky, G. Vincent, Hussein Abou-Hamdan, 2020, Synlett.

Electrochemical Dearomative Dihydroxylation and Hydroxycyclization of Indoles

R. Guillot, C. Kouklovsky, G. Vincent, 2020, Advanced Synthesis & Catalysis.

Dearomative Diallylation of N-Acylindoles Mediated by FeCl3.

R. Nandi, R. Guillot, C. Kouklovsky, 2018, Organic letters.

1,3-Dioxanes, 1,3-Dioxepanes, and Larger-Ring O/O Acetals

C. Kouklovsky, 2009 .

Total synthesis of grayanane natural products

C. Kouklovsky, R. Blieck, Aurélien de la Torre, 2022, Beilstein journal of organic chemistry.

The chemistry of mavacurane alkaloids: a rich source of bis-indole alkaloids.

L. Evanno, C. Kouklovsky, G. Vincent, 2021, Natural product reports.

Bioinspired Divergent Oxidative Cyclization from Strictosidine and Vincoside Derivatives: Second Generation Total Synthesis of Cymoside and Access to an Original Hexacyclic-Fused Furo[3,2-b]indoline.

C. Kouklovsky, G. Vincent, Y.-L. Dou, 2020, Chemistry.

Synthetic approaches to racemic porantheridine and 8-epihalosaline via a nitroso Diels-Alder cycloaddition/ring-rearrangement metathesis sequence.

C. Kouklovsky, G. Vincent, D. Karila, 2010, The Journal of organic chemistry.

Triflic Acid as an Efficient Brønsted Acid Promoter for the Umpolung of N‐Ac Indoles in Hydroarylation Reactions

R. Nandi, V. Gandon, R. Guillot, 2018 .

Revealing the electrophilicity of N-Ac indoles with FeCl3: a mechanistic study.

N. Ghermani, R. Nandi, V. Gandon, 2017, Chemical communications.

Enantioselective Total Synthesis of Cymoside through a Bioinspired Oxidative Cyclization of a Strictosidine Derivative.

V. Gandon, C. Kouklovsky, G. Vincent, 2019, Angewandte Chemie.

Intermolecular dearomative C2-arylation of N-Ac indoles activated by FeCl3.

R. Nandi, R. Guillot, C. Kouklovsky, 2016, Chemical communications.

Divergent Oxidative Couplings between Indoles and 2,3-Dihydroxybenzoic Acid Derivatives for the Biomimetic Synthesis of Voacalgine A and Bipleiophylline

Natacha Denizot, L. Evanno, C. Kouklovsky, 2018, Synthesis.

Mild Cleavage of N–O Bond of 3,6-Dihydro-1,2-oxazines by Condensation of Aldehydes in Aqueous Media

C. Kouklovsky, G. Galvani, R. Lett., 2015, Synlett.

Investigation of the Synthesis of Benzofuroindolines from N-Hydroxyindoles: An O-Arylation/[3,3]-Sigmatropic Rearrangement Sequence

C. Kouklovsky, G. Vincent, Terry Tomakinian, 2015, Synlett.

Evaluation of a NIS‐mediated Oxidative Cyclisation from Phenol‐Containing N‐Acyl Tryptamine Precursors Towards Phalarine: Synthesis of Spiro‐Dihydro‐[1,3]‐Oxazino‐Indolenines.

J. Baltaze, Natacha Denizot, R. Guillot, 2017 .

The Quest for an Oxidative Coupling of Phenols and Indoles towards Benzofuroindolines: A Two-Stage Approach

Natacha Denizot, C. Kouklovsky, G. Vincent, 2014, Synlett.

Using the Noncanonical Metallo-Amino Acid [Cu(II)(2,2'-Bipyridin-5-yl)]-alanine to Study the Structures of Proteins.

C. Kouklovsky, S. Un, V. Alezra, 2023, The journal of physical chemistry letters.

As Chiral Auxiliaries

C. Kouklovsky, 2007 .

2,2-Dimethyl-5-nitroso-1,3-dioxan-5-yl benzoate, 2,2-dimethyl-5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate and 5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate.

R. Guillot, C. Kouklovsky, N. Blanchard, 2007, Acta Crystallographica Section C: Crystal Structure Communications.

Oxazoline N‐Oxide‐Mediated [2 + 3] Cycloadditions. Application to a Synthesis of (‐)‐Tetrahydrolipstatin.

C. Kouklovsky, O. Dirat, Y. Langlois*, 1999 .

Synthesis of 3,3-Spirocyclic 2-Phosphonoindolines via a Dearomative Addition of Phosphonyl Radicals to Indoles.

J. Baltaze, R. Guillot, C. Kouklovsky, 2019, Organic letters.

Synthesis of 3,3-Spiroindolines via FeCl3-Mediated Cyclization of Aryl- or Alkene-Containing 3-Substituted N-Ac Indoles.

R. Nandi, R. Guillot, C. Kouklovsky, 2016, Organic letters.

Collective Total Synthesis of Mavacuran Alkaloids through Intermolecular 1,4-Addition of an Organolithium Reagent.

V. Gandon, R. Guillot, C. Kouklovsky, 2023, Angewandte Chemie.

Total Synthesis of Lucidumone: Attempted Shortcuts, Dead Ends and Lessons Learnt

C. Kouklovsky, Aurélien de la Torre, Guangho Huang, 2023, Synthesis.