R. H. Holm

发表

Magnetic circular dichroism studies. 43. Oxidized cytochrome P-450. Magnetic circular dichroism evidence for thiolate ligation in the substrate-bound form. Implications for the catalytic mechanism

Carl Djerassi, James R. Trudell, Robert E. Linder, 1976 .

Stabilities of cubane type [Fe₄S₄(SR)₄](2-) clusters in partially aqueous media.

Chang-Chun Ling, R. H. Holm, Ping Zhang, 2011, Journal of inorganic biochemistry.

Low-potential nickel(III,II) complexes: new systems based on tetradentate amidate-thiolate ligands and the influence of ligand structure on potentials in relation to the nickel site in [NiFe]-hydrogenases

Gang. Peng, R. H. Holm, Hans-Jörg Krüger, 1991 .

Theoretical Inorganic Chemistry.

R. H. Holm, 1962 .

Metal Complexes Derived from cis‐1,2‐dicyano‐1,2‐ethylenedithiolate and Bis(Trifluoromethyl)‐1,2‐dithiete

W. Mahler, A. Davison, R. H. Holm, 2007 .

Magnetic Investigations of Spin-free Cobaltous Complexes. VI.1 Complexes Containing Phosphines and the Position of Phosphines in the Spectrochemical Series

F. Cotton, R. H. Holm, D. Goodgame, 1961 .

Electronic control of the "Bailar twist" in formally d0-d2 molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory study.

Adam L. Tenderholt, K. Hodgson, B. Hedman, 2008, Inorganic chemistry.

Comparative Isotropic Shifts, Redox Potentials, and Ligand Binding Propensities of [1:3] Site-Differentiated Cubane-Type [Fe4Q4]2+ Clusters (Q = S, Se)

R. H. Holm, Chaoyin Zhou, 1997 .

Multiple-edge XAS studies of cyanide-bridged iron-copper molecular assemblies relevant to cyanide-inhibited heme-copper oxidases using four-body multiple-scattering analysis

K. Hodgson, A. Cicco, B. Hedman, 1997 .

Electron distribution in the nonclassical bis(dithiolene) electron transfer series [M(CO)2(S2C2Me2)2]0/1-/2- (M = Mo, W): assessment by structural, spectroscopic, and density functional theory results.

B. Lim, R. H. Holm, D. Fomitchev, 2001, Inorganic chemistry.

Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters.

R. H. Holm, Wayne Lo, Sonny C. Lee, 2014, Chemical reviews.

Biomimetic chemistry of iron, nickel, molybdenum, and tungsten in sulfur-ligated protein sites.

R. H. Holm, S. Groysman, Stanislav Groysman, 2009, Biochemistry.

Subsite-specific functionalization of the [4Fe-4S]2+ analog of iron-sulfur protein clusters

T. D. Stack, R. H. Holm, T. Stack, 1987 .

Subsite-Specific Functionalization of the (4 Fe-4 S)2+ Analogue of Iron-Sulfur Protein Clusters.

T. D. Stack, R. H. Holm, 1987 .

Synthetic analogs of the active sites of iron-sulfur proteins. II. Synthesis and structure of the tetra(mercapto-m 3 -sulfido-iron) clusters, (Fe 4 S 4 (SR) 4 ) 2- .

J. Ibers, B. Averill, R. H. Holm, 1973, Journal of the American Chemical Society.

Effects of secondary bonding interactions on the iron-sulfur cubane-type [Fe4S4]2+ core of ferredoxin site analogs: [Fe4S4(SC6H4-o-OH)4]2-, a distorted cubane-type cluster with one five-coordinate iron atom

R. Frankel, G. Papaefthymiou, R. E. Johnson, 1983 .

The clusters of nitrogenase: synthetic methodology in the construction of weak-field clusters.

R. H. Holm, Sonny C. Lee, 2004, Chemical reviews.

Functional analogue reaction systems of the DMSO reductase isoenzyme family: probable mechanism of S-oxide reduction in oxo transfer reactions mediated by bis(dithiolene)-tungsten(IV,VI) complexes.

R. H. Holm, K. Sung, 2002, Journal of the American Chemical Society.

Complete Electron-Transfer Series of the [M-N4] Type

A. Balch, R. H. Holm, 1966 .

Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins. XI. Synthesis and Properties of Complexes Containing the Fe2S2 Core and the Structures of Bis[o-xylyl-α,α′-dithiolato-μ-sulfido-ferrate(III)] and Bis[p-tolylthiolato-μ-sulfido-ferrate(III)] Dianions

S. Denmark, J. Ibers, R. H. Holm, 1975 .

Synthetic analogues of the active sites of iron-sulfur proteins.

R. Frankel, P. Venkateswara Rao, R. H. Holm, 1976, Chemical reviews.

The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions

N. Edelstein, A. Davison, R. H. Holm, 1963 .

Studies on Ni(II) Complexes. I. Spectra of Tricyclic Schiff Base Complexes of Ni(II) and Cu(II)

R. H. Holm, 1960 .

Fast carbon dioxide fixation by 2,6-pyridinedicarboxamidato-nickel(II)-hydroxide complexes: influence of changes in reactive site environment on reaction rates.

O. Makhlynets, R. H. Holm, Deguang Huang, 2011, Inorganic chemistry.

Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction

O. Makhlynets, R. H. Holm, Deguang Huang, 2011, Proceedings of the National Academy of Sciences.

Spectroscopic and photophysical properties of hexanuclear rhenium(III) chalcogenide clusters.

D. Nocera, Christina M. Rudzinski, R. H. Holm, 2003, Journal of the American Chemical Society.

Electronic Control of the ‘Bailar Twist’ in Formally d0-d2 Molybdenum tris(dithiolene) Complexes: A Sulfur K-edge XAS and DFT Study

Britt, Adam L. Tenderholt, K. Hodgson, 2009 .

[Fe2S2(CO)6]2− as a cluster precursor: synthesis and structure of [MoFe3S6(CO)6]2− and oxidative decarbonylation to a persulfide-bridged MoFe3S4 double cubane

J. Bashkin, R. H. Holm, J. Kovacs, 1987 .

Theoretical study of the influence of strain and polarization on performance of AlGaN/4H-SiC HBT

C. Eddy, M. Twigg, R. Henry, 2005 .

Substrate and metal control of barrier heights for oxo transfer to Mo and W bis-dithiolene sites.

Adam L. Tenderholt, K. Hodgson, B. Hedman, 2012, Inorganic chemistry.

Sulfur K-edge X-ray absorption spectroscopy and density functional calculations on Mo(IV) and Mo(VI)=O bis-dithiolenes: insights into the mechanism of oxo transfer in DMSO reductase and related functional analogues.

Adam L. Tenderholt, K. Hodgson, B. Hedman, 2010, Journal of the American Chemical Society.

A Study of Transition Metal Compounds Containing the Tricyanomethanide Ion

R. H. Holm, J. Enemark, 1964 .

Subsite-differentiated analogs of native iron sulfide [4Fe-4S]2+ clusters: preparation of clusters with five- and six-coordinate subsites and modulation of redox potentials and charge distributions

S. Ciurli, G. Papaefthymiou, T. D. Stack, 1990 .

Dimensional Reduction of Re6Se8Cl2: Sheets, Chains, and Discrete Clusters Composed of Chloride‐Terminated [Re6Q8]2+ (Q S, Se) Cores

J. Long, R. H. Holm, A. S. Williamson, 1995 .

Speculative synthetic chemistry and the nitrogenase problem

R. H. Holm, Sonny C. Lee, 2003, Proceedings of the National Academy of Sciences of the United States of America.

Structural Insights from the Mo K-Edge X-Ray Absorption Near Edge Structure of the Iron-Molybdenum Protein of Nitrogenase and Its Iron-Molybdenum Cofactor by Comparison with Synthetic Fe

K. Hodgson, M. Adams, P. Mascharak, 1986 .

Structural Conversions of Synthetic and Protein-Bound Iron-Sulfur Clusters.

R. H. Holm, Wayne Lo, 2016, Chemical reviews.

The modular nature of all-ferrous edge-bridged double cubanes.

L. Deng, R. H. Holm, E. L. Bominaar, 2010, Inorganic chemistry.

Synthesis of binucleating macrocycles and their nickel(II) hydroxo- and cyano-bridged complexes with divalent ions: anatomical variation of ligand features.

Xiaofeng Zhang, Yu‐Sheng Chen, R. H. Holm, 2012, Inorganic chemistry.

Reactions of monodithiolene tungsten(VI) sulfido complexes with copper(I) in relation to the structure of the active site of carbon monoxide dehydrogenase.

A. Majumdar, R. H. Holm, Shao-Liang Zheng, 2010, Inorganic chemistry.

Self-assembly of a tetradecanuclear iron nitride cluster.

R. H. Holm, M. Bennett, 2006, Angewandte Chemie.

Isonitrile binding to a site-differentiated synthetic analog of biological [4Fe-4S] clusters: equilibria, magnetic interactions, and the spin-isolated [3Fe-4S] cluster fragment, and the structure of a low-spin iron(II) subsite

R. H. Holm, E. Münck, J. A. Weigel, 1990 .

Chemical Bonding in Solids

J. Dunitz, P. Hemmerich, R. H. Holm, 1974 .

Ground spin state variability in [Fe4S4(SR)4]3-. Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of electronic state and structure to extrinsic factors.

R. Frankel, G. Papaefthymiou, M. Carney, 1988, Journal of the American Chemical Society.

The biologically relevant oxygen atom transfer chemistry of molybdenum: from synthetic analogue systems to enzymes

R. H. Holm, 1990 .

A Thermodynamic Scale for Oxygen Atom Transfer Reactions

R. H. Holm, J. P. Donahue, 1993 .

Comparative molecular chemistry of molybdenum and tungsten and its relation to hydroxylase and oxotransferase enzymes

Adam L. Tenderholt, E. Solomon, A. Majumdar, 2011 .

Proton magnetic resonance investigation of antiferromagnetic oxo-bridged ferric dimers and related high-spin monomeric ferric complexes

F. Walker, G. Eaton, R. H. Holm, 1973 .

Sulfur K-edge XAS of WVO vs. MoVO bis(dithiolene) complexes: contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes.

Adam L. Tenderholt, K. Hodgson, B. Hedman, 2007, Journal of inorganic biochemistry.

Synthesis and structures of the cuboidal iron-sulfur-nitrosyl-phosphine clusters [Fe4S3(NO)4(PR3)3]0,1+ (R = Et, Pri, C6H11)

R. H. Holm, C. Goh, 1998 .

Protein-bound iron-sulfur clusters: application of a structural database☆

J. Long, R. H. Holm, 1995 .

[.beta.-Na2Fe18S30]8- and [Na9Fe20Se38]9-: high-nuclearity clusters by mono- or bicyclization of unidimensional polymeric fragments and the existence of isomeric monocyclic clusters

G. Papaefthymiou, R. H. Holm, J. You, 1992 .

Formation, spectroscopic characterization, and solution stability of an [Fe4S4]2+ cluster derived from β-cyclodextrin dithiolate.

Chang-Chun Ling, R. H. Holm, Shaw. Huang, 2012, Inorganic chemistry.

The influence of net charge on the redox potentials of Fe4S4 cubane-type clusters in aprotic solvents

J. W. Raebiger, R. H. Holm, Chaoyin Zhou, 2000 .

Thermodynamic fitness of molybdenum(IV,VI) complexes for oxygen-atom transfer reactions, including those with enzymic substrates

J. Berg, R. H. Holm, E. W. Harlan, 1986 .

Ligand metathesis as rational strategy for the synthesis of cubane-type heteroleptic iron–sulfur clusters relevant to the FeMo cofactor

Jie Zhou, Zheng Wang, R. H. Holm, 2018, Proceedings of the National Academy of Sciences.

Selenium as a structural surrogate of sulfur: template-assisted assembly of five types of tungsten-iron-sulfur/selenium clusters and the structural fate of chalcogenide reactants.

R. H. Holm, Shao-Liang Zheng, Xu‐Dong Chen, 2012, Journal of the American Chemical Society.

Specific incorporation of chalcogenide bridge atoms in molybdenum/tungsten-iron-sulfur single cubane clusters.

A. Majumdar, R. H. Holm, 2011, Inorganic chemistry.

VFe3S4 single and double cubane clusters: synthesis, structures, and dependence of redox potentials and electron distribution on ligation and heterometal.

R. H. Holm, T. Scott, 2008, Inorganic chemistry.

8.3 – Electron Transfer: Iron–Sulfur Clusters

R. H. Holm, 2003 .

Assembly of vanadium-iron-sulfur cubane clusters from mononuclear and linear trinuclear reactants

R. H. Holm, J. Kovacs, 1986 .

R. Mcmillan, J. Reynolds, J. Renaud, 1979, Journal of inorganic biochemistry.

Controlled Incorporation of Nitrides into W-Fe-S Clusters.

Z. Wang, R. H. Holm, Gan Xu, 2019, Angewandte Chemie.

Heterometal cubane-type MFe(3)S(4) clusters (M = Mo, V) trigonally symmetrized with hydrotris(pyrazolyl)borate(1-) and tris(pyrazolyl)methanesulfonate(1-) capping ligands.

R. H. Holm, D. Fomitchev, C. C. McLauchlan, 2002, Inorganic chemistry.

Comparative electronic properties of vanadium-iron-sulfur and molybdenum-iron-sulfur clusters containing isoelectronic cubane-type [VFe3S4]2+ and [MoFe3S4]3+ cores

R. Frankel, G. Papaefthymiou, M. Carney, 1987 .

Electronic properties of single- and double-MoFe3S4 cubane-type clusters

R. Frankel, G. Papaefthymiou, P. Mascharak, 1983 .

Subsite-specific structures and reactions in native and synthetic [4Fe-4S) cubane-type clusters

S. Ciurli, R. H. Holm, J. A. Weigel, 2007 .

Alternative spin states in synthetic analogs of biological clusters: spin-quartet ground states and structures of tetrakis(benzenethiolato)tetrasulfidotetraferrate(3-) and tetrakis(benzenethiolato)tetraselenidotetraferrate(3-) as their tetramethylammonium salts

R. Frankel, G. Papaefthymiou, M. Carney, 1988 .

Demonstration of alternative spin states in clusters containing the biologically relevant [Fe4S4]1+ core

R. Frankel, G. Papaefthymiou, M. Carney, 1986 .

Demonstration of the generality of the [Fe4S4(SR)4]2- (compressed D2d)/[Fe4S4(SR)4]3- (elongated D2d) structural change in electron-transfer reactions of ferredoxin 4-Fe site analogs. A model for unconstrained structural changes in ferredoxin proteins

R. Frankel, E. Laskowski, G. Papaefthymiou, 1979 .

Synthesis and electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3-, analogues of the 4-Fe active sites of reduced ferredoxins.

R. Frankel, E. Laskowski, G. Papaefthymiou, 1977, Journal of the American Chemical Society.

Insertion of vanadium-iron-sulfur, [VFe3S4]2+, and molybdenum-iron-sulfur, [MoFe3S4]3+, cores into a semirigid trithiolate cavitand ligand: regiospecific reactions at a vanadium site similar to that in nitrogenase

S. Ciurli, R. H. Holm, 1989 .

Vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4] core unit: synthesis of a cluster with the topology of the PN cluster of nitrogenase.

J. Zuo, Hong‐Cai Zhou, R. H. Holm, 2003, Inorganic chemistry.

Rearrangement of symmetrical dicubane clusters into topological analogues of the P cluster of nitrogenase: nature's choice?

J. Zuo, Hong‐Cai Zhou, Yugen Zhang, 2002, Journal of the American Chemical Society.

Polycubane Clusters: Synthesis of [Fe4S4(PR3)4]1+,0 (R = But, Cy, Pri) and [Fe4S4]0 Core Aggregation upon Loss of Phosphine

J. Long, Jie‐Sheng Huang, R. H. Holm, 1996 .

Stabilization of fully reduced iron-sulfur clusters by carbene ligation: the [FenSn]0 oxidation levels (n = 4, 8).

L. Deng, R. H. Holm, 2008, Journal of the American Chemical Society.

Fluorine-19 chemical shifts as probes of the structure and reactivity of the iron-molybdenum cofactor of nitrogenase.

B. Burgess, R. H. Holm, S. Conradson, 1988, The Journal of biological chemistry.

Initial synthesis and structure of an all-ferrous analogue of the fully reduced [Fe4S4]0 cluster of the nitrogenase iron protein.

Hong‐Cai Zhou, C. Berlinguette, R. H. Holm, 2005, Proceedings of the National Academy of Sciences of the United States of America.

The [MoFe3S4]2+ oxidation state: synthesis, substitution reactions, and structures of phosphine-ligated cubane-type clusters with the S=2 ground state.

R. H. Holm, Bin Xi, 2011, Inorganic chemistry.

Identification of iron-sulfur centers in the iron-molybdenum proteins of nitrogenase.

R. Mcmillan, B. Burgess, R. H. Holm, 1979, Proceedings of the National Academy of Sciences of the United States of America.

Controlled Incorporation of Nitrides into W‐Fe‐S Clusters

R. H. Holm, Gan Xu, Xu‐Dong Chen, 2019, Angewandte Chemie.

Heterometal cubane-type WFe3S4 and related clusters trigonally symmetrized with hydrotris(3,5-dimethylpyrazolyl)borate

Yugen Zhang, D. Hong, R. H. Holm, 2005 .

The Clusters of Nitrogenase: Synthetic Methodology in the Construction of Weak-Field Clusters

R. H. Holm, Sonny C. Lee, 2004 .

Hydroxide-promoted core conversions of molybdenum-iron-sulfur edge-bridged double cubanes: oxygen-ligated topological PN clusters.

R. Staples, R. H. Holm, M. Hlavinka, 2007, Inorganic chemistry.

Precursors to clusters with the topology of the P(N) cluster of nitrogenase: edge-bridged double cubane clusters [(Tp)2Mo2Fe6S8L4]z: synthesis, structures, and electron transfer series.

C. Berlinguette, Yugen Zhang, R. H. Holm, 2006, Inorganic chemistry.

Structural conversions of molybdenum-iron-sulfur edge-bridged double cubanes and P(n)-type clusters topologically related to the nitrogenase P-cluster.

Yugen Zhang, R. H. Holm, 2004, Inorganic chemistry.

Synthesis of a molecular Mo2Fe6S9 cluster with the topology of the PN cluster of nitrogenase by rearrangement of an edge-bridged Mo2Fe6S8 double cubane.

Yugen Zhang, R. H. Holm, Richard H. Holm, 2003, Journal of the American Chemical Society.

Quantitative extrusions of the iron sulfide(Fe4S4*) cores of the active sites of ferredoxins and the hydrogenase of Clostridium pasteurianum

J. S. Chen, R. H. Holm, L. Mortenson, 1977 .

Hydrogen evolution from homogeneous reaction systems containing reduced molybdenum-iron-sulfur clusters

G. Christou, R. H. Holm, R. V. Hageman, 1980 .

Ligand K-edge X-ray absorption spectroscopy of [Fe4S4]1+,2+,3+ clusters: changes in bonding and electronic relaxation upon redox.

K. Hodgson, A. Dey, B. Hedman, 2004, Journal of the American Chemical Society.

FERRIC PORPHYRIN THIOLATES, POSSIBLE RELATIONSHIP TO CYTOCHROME P-450 ENZYMES AND THE STRUCTURE OF (P-NITROBENZENETHIOLATO)IRON(III) PROTOPORPHYRIN IX DIMETHYL ESTER

R. Frankel, J. Ibers, R. H. Holm, 1975 .

THE (FE(III)N4SR) COORDINATION UNIT, SYNTHESIS AND GROUND STATE ELECTRONIC PROPERTIES OF MACROCYCLIC FERRIC THIOLATES

R. Frankel, R. H. Holm, S. Koch, 1975 .

Inter- and intramolecular ligand exchange reactions of ruthenium(II) carbonyl porphine complexes with nitrogen bases

S. Eaton, G. Eaton, R. H. Holm, 1972 .

Fluorine-19 chemical shifts as structural probes of metal-sulfur clusters and the cofactor of nitrogenase.

P. Mascharak, B. Burgess, R. H. Holm, 1982, Proceedings of the National Academy of Sciences of the United States of America.

Angle dependence of the properties of the [Fe2X]4+ bridge unit (X = O, S): structures, antiferromagnetic coupling, and properties in solution

T. D. Stack, R. Mukherjee, R. H. Holm, 1988 .

Systematic stereochemistry of metal(II) thiolates: synthesis and structures of [M2(SC2H5)6]2- (M = Mn(II), Ni(II), Zn(II), Cd(II))

C. P. Rao, C. Rao, A. D. Watson, 1985 .

7 – Stereochemistry and Structural and Electronic Equilibria

R. H. Holm, 1973 .

Metal ion exchange reactions in cage molecules: the systems [M4-nM'n(SC6H5)10]2- (M, M' = Fe(II), Co(II), Zn(II), Cd(II)) with adamantane-like stereochemistry and the structure of [Fe4(SC6H5)10]2-

D. Stephan, K. Hagen, R. H. Holm, 1982 .

Oxo transfer reactions mediated by bis(dithiolene)tungsten analogues of the active sites of molybdoenzymes in the DMSO reductase family: comparative reactivity of tungsten and molybdenum.

R. H. Holm, K. Sung, 2001, Journal of the American Chemical Society.

Structure and properties of a synthetic analogue of bacterial iron--sulfur proteins.

W. D. Phillips, J. Ibers, B. Averill, 1972, Proceedings of the National Academy of Sciences of the United States of America.

Mössbauer, electron paramagnetic resonance, and theoretical studies of a carbene-based all-ferrous Fe4S4 cluster: electronic origin and structural identification of the unique spectroscopic site.

L. Deng, R. H. Holm, E. L. Bominaar, 2009, Inorganic chemistry.

Resonance Raman spectroscopic evidence for structural variation among bacterial ferredoxin, HiPIP, and Fe4S4(SCH2Ph)42.

T. Spiro, R. H. Holm, S. P. Tang, 1975, Biochemical and biophysical research communications.

Inversion and ligand-exchange kinetics of tetrahedral bis-chelate complexes of zinc(II) and cadmium(II)

S. Eaton, R. H. Holm, 1971 .

Synthetic analogs of the active sites of iron-sulfur proteins. VI. Spectral and redox characteristics of the tetranuclear clusters (Fe4S4(SR)4).2-.

L. Que, B. Averill, R. H. Holm, 1974, Journal of the American Chemical Society.

Resonance Raman spectra of spinach ferredoxin and adrenodoxin and of analog complexes

A. Gewirth, R. Czernuszewicz, T. Spiro, 1983 .

Nonmolecular Metal Chalcogenide/Halide Solids and Their Molecular Cluster Analogues

R. H. Holm, Sonny C. Lee, 1990 .

Structural characterization of metallopeptides designed as scaffolds for the stabilization of nickel(II)-Fe(4)S(4) bridged assemblies by X-ray absorption spectroscopy.

K. Hodgson, B. Hedman, R. H. Holm, 2002, Journal of the American Chemical Society.

Hexanuclear iron―sulfur basket clusters: topological isomers of prismanes. Synthesis, structure, and reactions

R. H. Holm, Barry S. Synder, 1988 .

Trichlorotetrakis(triethylphosphine)hexathioheptairon (Fe7S6(PEt3)4Cl3): a topological link between the prismatic and cube-octahedral structures of iron-sulfur clusters

R. H. Holm, I. Noda, B. Snyder, 1986 .

Nickel-Mediated Formation of Thio Esters from Bound Methyl, Thiols, and Carbon Monoxide: A Possible Reaction Pathway of Acetyl-Coenzyme A Synthase Activity in Nickel-Containing Carbon Monoxide Dehydrogenases

R. H. Holm, G. Tucci, 1995 .

Preface: biomimetic inorganic chemistry.

E. Solomon, R. H. Holm, 2004, Chemical reviews.

Modeling coordination sites in metallobiomolecules.

J. Ibers, R. H. Holm, R. H. Holm, 1980, Science.

Structural and Functional Aspects of Metal Sites in Biology.

Edward I. Solomon, Pierre Kennepohl, E. Solomon, 1996, Chemical reviews.

A Solid-State Route to Molecular Clusters: Access to the Solution Chemistry of [Re6Q8]2+ (Q = S, Se) Core-Containing Clusters via Dimensional Reduction

J. Long, R. H. Holm, A. L. McCarty, 1996 .

Model for the active site of oxo-transfer molybdoenzymes: synthesis, structure, and properties

J. Berg, R. H. Holm, 1985 .

Synthesis of metal dithiolene complexes by Si-S bond cleavage of a bis(silanylsulfanyl)alkene

R. H. Holm, David V. Partyka, S. Friedle, 2006 .

Synthesis and structural characterization of two tungsten(VI) dioxo complexes with N,O- and N,S-coordinating ligands

E. Nordlander, R. H. Holm, C. Lorber, 2001 .

Direct oxygen atom transfer in the mechanism of action of Rhodobacter sphaeroides dimethyl sulfoxide reductase

R. Hille, R. H. Holm, B. Schultz, 1995 .

Kinetics of oxygen atom transfer in an analogue reaction system of the molybdenum oxotransferases

R. H. Holm, B. Schultz, 1993 .

Molybdenum-mediated oxygen-atom transfer: an improved analog reaction system of the molybdenum oxotransferases

M. J. Scott, R. H. Holm, B. Schultz, 1993 .

A broad-substrate analog reaction system of the molybdenum oxotransferases

M. J. Scott, R. H. Holm, B. Schultz, 1992 .

Synthetic approach to the mononuclear active sites of molybdoenzymes: catalytic oxygen atom transfer reactions by oxomolybdenum(IV,VI) complexes with saturation kinetics and without molybdenum(V) dimer formation

J. Berg, R. H. Holm, 1984 .

Syntheses employing pyridyllithium reagents: new routes to 2,6-disubstituted pyridines and 6,6′-disubstituted 2,2′-bipyridyls

J. Parks, R. H. Holm, B. E. Wagner, 1973 .

Sterically encumbered iron(II) thiolate complexes: Synthesis and structure of trigonal planar [Fe(SR)3]- (R = 2,4,6-t-Bu3C6H2) and Mössbauer spectra of two- and three-coordinate complexes

P. Power, J. J. Ellison, R. H. Holm, 1995 .

Molecular Assemblies Containing Unsupported [Fe(III)-(&mgr;(2):eta(2)-RCO(2))-Cu(II)] Bridges.

M. J. Scott, R. H. Holm, C. Goddard, 1996, Inorganic chemistry.

The [2:2] Site-Differentiated Clusters [Fe4S4L2(RNC)6] Containing Two Low-Spin Iron(II) Sites

R. H. Holm, J. A. Weigel, C. Goh, 1994 .

Synthetic routes to iron sulfide (Fe2S2, Fe3S4, Fe4S4, and Fe6S9), clusters from the common precursor tetrakis(ethanethiolate)ferrate(2-) ion ([Fe(SC2H5)4]2-): structures and properties of [Fe3S4(SR)4]3- and bis(ethanethiolate)nonathioxohexaferrate(4-) ion ([Fe6S9(SC2H5)2]4-), examples of the newest

K. Hagen, A. D. Watson, R. H. Holm, 1983 .

Ligand K-edge X-ray absorption spectroscopy and DFT calculations on [Fe3S4]0,+ clusters: delocalization, redox, and effect of the protein environment.

K. Hodgson, A. Dey, B. Hedman, 2004, Journal of the American Chemical Society.

Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy.

K. Hodgson, B. Hedman, E. Solomon, 2003, Journal of the American Chemical Society.

Studies on Nickel(II)Complexes. IV. Bis-(N-sec-alkylsalicylaldimine) Complexes: Conformational Equilibria in Solution

R. H. Holm, K. Swaminathan, 1963 .

Studies on Nickel(II) Complexes. III. Bis-(N-arylsalicylaldimine) Complexes

R. H. Holm, K. Swaminathan, 1962 .

MAGNETIC OBSERVATIONS OF SOME SUBSTITUTED NICKEL(II) SALICYLALDIMINE COMPLEXES

R. H. Holm, T. McKinney, 1960 .

Magnetic Investigations of Spin-free Cobaltous Complexes. III. On the Existence of Planar Complexes

F. Cotton, R. H. Holm, 1960 .

Magnetic Investigations of Spin‐Free Cobaltous Complexes. II. Tetrahedral Complexes

F. Cotton, R. H. Holm, 1960 .

Magnetic Investigations of Spin-Free Cobaltous Complexes. I. Tetrahalo Cobalt(II) Ions

F. Cotton, R. H. Holm, 1959 .

Fluoride-bridged dimers : binuclear copper(II) complexes and iron(III)-copper(II) assemblies

R. H. Holm, Sonny C. Lee, 1993 .

A synthetic analog of the iron/copper bridged assembly in cytochrome c oxidase

R. H. Holm, Sonny C. Lee, 1993 .

Cubane-type Fe4S4 clusters with chiral thiolate ligation: formation by ligand substitution, detection of intermediates by 1H NMR, and solid state structures including spontaneous resolution upon crystallization.

R. H. Holm, Shaw. Huang, Wayne Lo, 2011, Inorganic chemistry.

Synthesis and comparative reactivity and electronic structural features of [MFe3S4]z+ cubane-type clusters (M = iron, cobalt, nickel)

Gang. Peng, M. J. Scott, R. H. Holm, 1992 .

Model system studies of axial ligation in the oxidized reaction states of cytochrome P-450 enzymes.

R. Frankel, J. Ibers, G. Papaefthymiou, 1976, Advances in experimental medicine and biology.

Variability of niobiumsulfur bond lengths: The molecular structures of sulfido-tris(N,N-diethyldithiocarbamato)niobium(V)

Y. Do, R. H. Holm, 1985 .

Three-dimensional macrocyclic encapsulation reactions. II. Synthesis and properties of nonoctahedral clathro chelates derived from tris(2-aldoximo-6-pyridyl)phosphine and boron trifluoride or tetrafluoroborate

J. Parks, R. H. Holm, B. E. Wagner, 1971 .

Synthesis, solution stereochemistry, and electron delocalization properties of bis(.beta.-iminoamino)nickel(II) complexes

J. Parks, R. H. Holm, 1968 .

Cubane-type Co4S4 clusters: synthesis, redox series, and magnetic ground states.

K. Wieghardt, E. Bill, L. Deng, 2009, Journal of the American Chemical Society.

Synthetic analogues of the active sites of iron-sulfur proteins. 14. Synthesis, properties, and structures of bis(o-xylyl-alpha,alpha'-dithiolato)ferrate(II, III) anions, analogues of oxidized and reduced rubredoxin sites.

R. Frankel, J. Ibers, G. Papaefthymiou, 1977, Journal of the American Chemical Society.

Synthetic analogs of active sites of iron-sulfur proteins: bis (o-xylyldithiolato) ferrate (III) monoanion, a structurally unconstrained model for the rubredoxin Fe-S4 unit.

R. Frankel, J. Ibers, R. H. Holm, 1975, Proceedings of the National Academy of Sciences of the United States of America.

Electron-transfer complexes of the [M-N2S2] type. The existence of cation-stabilized free-radical complexes

A. Balch, A. Davison, R. H. Holm, 1967 .

Concerning Cation-Stabilized Anion Free Radicals

A. Balch, A. Davison, R. H. Holm, 1966 .

The Stereochemistry of Bis‐Chelate Metal(II) Complexes

R. H. Holm, M. J. O'connor, 2007 .

Stabilization of trivalent nickel in tetragonal NiS4N2 and NiN6 environments : synthesis, structures, redox potentials, and observations related to [NiFe]-hydrogenases

R. H. Holm, H. Kruger, 1990 .

Synthesis and ground state electronic properties of tetraaza macrocyclic iron(II, III) complexes containing [14]-, [15]-, and [16]-membered rings

R. Frankel, R. H. Holm, S. Koch, 1975 .

Synthetic approaches to 14-, 15-, and 16-membered tetraaza macrocycles and their metal complexes

R. H. Holm, S. Koch, R. W. Lane, 1973 .

Binuclear iron system ferromagnetic in three oxidation states: synthesis, structures, and electronic aspects of molecules with a Fe2(OR)2 bridge unit containing Fe(III,III), Fe(III,II), and Fe(II,II)

R. H. Holm, G. S. Patterson, A. Abrahamson, 1989 .

Structural and electronic effects on the polarographic half-wave potentials of copper (II) chelate complexes.

R. H. Holm, G. S. Patterson, Richard H. Holm, 1975, Bioinorganic chemistry.

Stability range of heterometal cubane-type clusters MFe3S4: assembly of double-cubane clusters with the rhenium-iron-sulfur [[ReFe3S4]] core

S. Ciurli, G. Papaefthymiou, M. Carney, 1989 .

Octaethylisobacteriochlorin, a model of the sirohydrochlorin ring system of siroheme enzymes: preparation and spectroscopic and electrochemical properties of the free base and its zinc(II) complex

R. H. Holm, L. O. Spreer, A. M. Stolzenberg, 1980 .

Synthesis and properties of tetraaza[14]tetraene and tetraaza[14]hexane macrocyclic complexes

R. H. Holm, T. Truex, 1972 .

Potential Electron Transfer Complexes of the [M-O4] Type: Synthesis and Properties of Complexes Derived from Pyrocatechol and Tetrachloropyrocatechol

A. Balch, R. H. Holm, Freimund Rohrscheid, 1966 .

Ground-State Electronic Structures of Binuclear Iron(II) Sites: Experimental Protocol and a Consistent Description of Moessbauer, EPR, and Magnetization Measurements of the Bis(phenolate)-Bridged Complex [Fe2(salmp)2]2-

M. Hendrich, R. H. Holm, E. Münck, 1994 .

Preparation, properties, and racemization kinetics of copper(II)-Schiff base-amino acid complexes related to vitamin B6 catalysis

R. H. Holm, M. J. O'connor, G. N. Weinstein, 1970 .

Metal Complexes of Schiff Bases and β‐Ketoamines

R. H. Holm, A. Chakravorty, G. Everett, 2007 .

Studies on Nickel(II) Complexes. II. On the Solution Magnetism of Bis-(N-methylsalicylaldimine)-nickel(II) and Related Complexes

R. H. Holm, 1961 .

Spectral Investigations of Metal Complexes of β-Diketones. I. Nuclear Magnetic Resonance and Ultraviolet Spectra of Acetylacetonates1

F. Cotton, R. H. Holm, 1958 .

Structural and Functional Aspects of Metal Sites in Biology

Edward I. Solomon, Pierre Kennepohl, E. Solomon, 1997 .

A binuclear manganese system with three isolated oxidation states: synthesis, structures, and properties of molecules with a Mn2(OR)2 bridge unit containing MnIIIMnIII, MnIIIMnII, and MnIIMnII

R. H. Holm, S. Yu, E. Day, 1991 .

Trinuclear Cuboidal and Heterometallic Cubane-Type Iron–Sulfur Clusters: New Structural and Reactivity Themes in Chemistry and Biology

R. H. Holm, 1992 .

Synthetic approaches to the active sites of iron-sulfur proteins

R. H. Holm, 1977 .

Synthesis of a new class of polydentate ligands: [bis(2-imidazolyl)methyl] amino-thioether-thiols

R. Palermo, R. H. Holm, Marie-Thérèse Youinou, 1984 .

Oxygen-Bridged Iron-Copper Assemblies Pertinent to Heme-Copper Oxidases: Synthesis and Structure of an [FeIII-(OH)-CuII] Bridge and Exafs Multiple-Scattering Effects of Linear Oxo and Nonlinear Hydroxo Bridges

K. Hodgson, B. Hedman, M. J. Scott, 1995 .

Synthesis and Structural Characterization of Unsupported [FeIII-CN-CuII] Bridges Related to That in Cyanide-Inactivated Cytochrome c Oxidase

M. J. Scott, R. H. Holm, Sonny C. Lee, 1994 .

Cyanide poisoning: an analog to the binuclear site of oxidized cyanide-inhibited cytochrome c oxidase

M. J. Scott, R. H. Holm, Sonny C. Lee, 1994 .

Tetrakis (ethane-1,2-dithiolato) divanadate (III): a binuclear complex with a quadruple bridge, a metal-metal bond, and nonoctahedral stereochemistry

R. H. Holm, J. Dorfman, 1983 .

Dihydrogen Evolution by Protonation Reactions of Nickel(I).

T. James, Lisheng Cai, R. H. Holm, 1996, Inorganic chemistry.

Metal-centered oxygen atom transfer reactions

Richard H. Holm, R. H. Holm, 1987 .

New Systems of Complexes Related by Electron-Transfer Reactions

A. Balch, R. H. Holm, Freimund Rohrscheid, 1965 .

Reaction Sequence Related to That of Carbon Monoxide Dehydrogenase (acetyl Coenzyme a Synthase): Thioester Formation Mediated at Structurally Defined Nickel Centers

P. Stavropoulos, R. H. Holm, M. Muetterties, 1990 .

Oxomolybdenum(IV,V,VI) complexes: structures, reactivities, and criteria of detection of binuclear (.mu.-oxo)molybdenum(V) products in oxygen atom transfer systems

R. H. Holm, E. W. Harlan, M. Whitener, 1989 .

Synthesis, structure, and electronic features of (.mu.-sulfido)bis[(N,N'-ethylenebis(salicylaldiminato))iron(III)], [Fe(salen)]2S, containing the only authenticated example of the iron(III)-sulfur-iron(III) single bridge

T. D. Stack, R. H. Holm, J. Girerd, 1984 .

Chemical and electrochemical reactivity of nickel(II,I) thiolate complexes: examples of ligand-based oxidation and metal-centered oxidative addition

R. H. Holm, H. Krueger, 1989 .

Structure proofs of ligated and polymeric dioxomolybdenum(VI)-tridentate complexes: MoO2(C5H3N-2,6-(CH2S)2)(C4H8SO) and [MoO2(C5H3N-2,6-(CH2O)2)]n

J. Berg, R. H. Holm, 1983 .

Effects of chelate ring substituents on the polarographic redox potentials of tris(.beta.-diketonato)ruthenium(II,III) complexes

R. H. Holm, G. S. Patterson, 1972 .

Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo)nickel(II) complex.

O. Troeppner, I. Ivanović‐Burmazović, R. H. Holm, 2014, Dalton transactions.

The Unperturbed Oxo-Sulfido Functional Group cis-Mo(VI)OS, Related to that in the Xanthine Oxidase Family of Molybdoenzymes: Synthesis, Structural Characterization and Reactivity Aspects

K. Hodgson, B. Hedman, E. Nordlander, 1999 .

Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases.

R. H. Holm, J. Enemark, Jun-Jieh Wang, 2004, Chemical reviews.

The biologically relevant oxygen atom transfer chemistry of molybdenum: from synthetic analogue systems to enzymes

R. H. Holm, 1990 .

Model for the active sites of oxo-transfer molybdoenzymes: reactivity, kinetics, and catalysis

J. Berg, R. H. Holm, 1985 .

Toward functional models of metalloenzyme active sites: analog reaction systems of the molybdenum oxo transferases

J. Berg, R. H. Holm, 1986 .

Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and -tungsten Complexes

R. H. Holm, G. Tucci, A. Donahue, 1998 .

Kinetics of oxygen atom transfer reactions involving oxomolybdenum complexes. General treatment for reactions with intermediate oxo-bridged molybdenum(V) dimer formation

J. Berg, R. H. Holm, Martha S. Reynolds, 1984 .

Stabilization of Trivalent Nickel in Tetragonal NiS4N2 and NiN6 Environments: Synthesis, Structures, Redox Potentials, and Observations Related to (NiFe)-Hydrogenases.

R. H. Holm, H. Krueger, 1990 .

Stabilization of nickel(III) in a classical N2S2 coordination environment containing anionic sulfur

R. H. Holm, H. Krueger, 1987 .

Three-dimensional macrocyclic encapsulation reactions. III. Geometrical and electronic features of tris(diimine) complexes of trigonal-prismatic, antiprismatic, and intermediate stereochemistry

J. Parks, R. H. Holm, E. Larsen, 1972 .

Aspects of the oxygen atom transfer chemistry of tungsten

R. H. Holm, S. Yu, 1989 .

Existence of the Planar [UNK] Tetrahedral Equilibrium in Solutions of Cobalt(II) Complexes

R. H. Holm, G. Everett, 1965 .

Electron Paramagnetic Resonance Studies of the Electronic Structures of Bis(maleonitriledithiolato)copper(II), -nickel(III), -cobalt(II), and -rhodium(II) Complexes

N. Edelstein, A. Davison, R. H. Holm, 1964 .

The structure of dihydrooctaaza-[14]-annulenes and their nickel(II) complexes

R. W. Harper, J. Huff, J. Baldwin, 1972 .

Studies of the Planar-Tetrahedral Configurational Equilibrium in Solutions of Bis(β-ketoamino)cobalt(II) Complexes

R. H. Holm, G. Everett, 1966 .

Applications of isotropic shifts to the investigation of structures and structural equilibriums of metal complexes

R. H. Holm, 1969 .

Synthesis and stereochemistry of metal(II) thiolates of the types [M(SR)4]2-, [M2(SR)6]2-, and [M4(SR)10]2- (M = Fe(II), Co(II))

K. Hagen, R. H. Holm, 1984 .

Further Examples of Complexes Related by Electron-Transfer Reactions: Complexes Derived from Bis (trifluoromethyl)-1,2-dithietene

N. Edelstein, A. Davison, R. H. Holm, 1964 .

Equilibria and solute structures in the aqueous systems pyridoxal-alanine-zinc(II) and -aluminum(III) as investigated by proton resonance

O. Gansow, R. H. Holm, 1969 .

Molecular Assemblies Containing Linear and Bent [FeIII-CN-CuII] Bridge Units: Synthesis, Structures, and Relevance to Cyanide-Inhibited Heme-Copper Oxidases

M. J. Scott, R. H. Holm, 1994 .

Synthesis and characterization of an asymmetric bridged assembly containing the unsupported [FeIII-O-CuII] bridge: an analog of the binuclear site in oxidized cytochrome c oxidase

Richard H. Holm, R. H. Holm, Sonny C. Lee, 1993 .

Binuclear Iron System Ferromagnetic in Three Oxidation States: Synthesis, Structures, and Electronic Aspects of Molecules with a Fe2(OR)2 Bridge Unit Containing Fe(III,III), Fe(III,II), and Fe(II,II).

R. H. Holm, G. S. Patterson, A. Abrahamson, 1989 .

A Proton Resonance Study of Bis-(acetylacetone)-ethylenediimine and Related Schiff Bases

R. H. Holm, G. Dudek, 1961 .

Molecular Heme-Cyanide-Copper Bridged Assemblies: Linkage Isomerism, Trends in nu(CN) Values, and Relation to the Heme-a(3)/Cu(B) Site in Cyanide-Inhibited Heme-Copper Oxidases.

B. Lim, R. H. Holm, 1998, Inorganic chemistry.

Nucleophilic reactivity and oxo/sulfido substitution reactions of MVIO3 Groups (M = Mo, W).

R. Staples, R. H. Holm, David V. Partyka, 2003, Inorganic chemistry.

CHAPTER 7 – Synthetic Analogues of the Active Sites of Iron–Sulfur Proteins*

J. Ibers, R. H. Holm, 1977 .

Synthesis and structural systematics of ethane-1,2-dithiolato complexes

C. Rao, R. H. Holm, J. Dorfman, 1986 .

The Synthesis and Proton Resonance Study of the Solution Equilibria of Bis(β-ketoamino) nickel(II) Complexes

R. H. Holm, G. Everett, 1965 .

Preparation and stereochemistry of bis-chelate chromium(II), manganese(II), iron(II), and cobalt(II) complexes of the types M-O4 and M-O2S2

D. Gerlach, R. H. Holm, 1969 .

Comparative stereochemical populations and thermodynamics of structural interconversion of planar and tetrahedral cobalt(II) and nickel(II) complexes

R. H. Holm, G. Everett, 1968 .

Diastereoisomeric four-coordinate complexes. IV. Zinc(II) complexes with three asymmetric centers and ligand racemization in bis[N-(alkoxycarbonylalkyl])salicylaldimino]metal(II) complexes

R. H. Holm, M. J. O'connor, J. Schoenborn, 1968 .

Nuclear Magnetic Resonance Studies of Keto-enol Equilibria. III. α,β-Unsaturated-β-Ketoamines

R. H. Holm, G. Dudek, 1962 .

The stereochemistry of decakis(benzenethiolato)tetracadmate(2-) ion, a cage complex related to the cadmium-cysteinate aggregates in metallothioneins

K. Hagen, R. H. Holm, 1983 .

Stereochemistry of [Cd4(SC6H5)10]2−, a cage complex related to the cadmium―cysteinate aggregates in metallothioneins

K. Hagen, R. H. Holm, 1983 .

Synthetic analogs of the active sites of iron-sulfur proteins. Structure and properties of bis(o-xylyldithiolato-m2-sulfidoferrate (3)), an analog of the 2Fe-2S proteins.

W. D. Phillips, R. Frankel, J. Ibers, 1973, Proceedings of the National Academy of Sciences of the United States of America.

Dithiotropolonates. II. Synthesis and properties of dithiotropolone and its metal(II) complexes

C. E. Forbes, R. H. Holm, 1970 .

Solution stereochemistry of four-coordinate bis(chelate)metal(II) complexes. Further experimental results and a summary of stereochemical trends

D. Gerlach, R. H. Holm, 1970 .

Diastereoisomeric four-coordinate complexes. V. Pseudo-tetrahedral complexes of controlled absolute configuration. Configurational interconversion of nickel(II) complexes withour racemization

R. H. Holm, M. J. O'connor, R. Ernst, 1968 .

The Synthesis, Structures, and Solution Equilibria of Bis(pyrrole-2-aldimino)metal(II) Complexes

R. H. Holm, A. Chakravorty, L. J. Theriot, 1966 .

Synthesis and stereochemistry of mono-, bi-, and tetranuclear manganese thiolates

K. Hagen, R. H. Holm, J. Dorfman, 1983 .

[FeIIIN4SR] coordination unit. Synthesis and ground state electronic properties of macrocyclic ferric thilates

R. Frankel, R. H. Holm, S. Koch, 1975 .

Aqueous solution equilibria of pyridoxamine, pyridoxal, 3-hydroxypyridine-4-aldehyde, and 3-hydroxypyridine-2-aldehyde as studied by proton resonance

O. Gansow, R. H. Holm, 1968 .

Vanadium-mediated oxygen atom transfer reactions

R. H. Holm, Y.-P. Zhang, 1990 .

Single- and double-cubane clusters in the multiple oxidation states [VFe(3)S(4)](3+,2+,1+).

E. Bill, R. H. Holm, C. Hauser, 2002, Inorganic chemistry.

Sulfur ligand substitution at the nickel(II) sites of cubane-type and cubanoid NiFe3S4 clusters relevant to the C-clusters of carbon monoxide dehydrogenase.

Jibin Sun, R. H. Holm, C. Tessier, 2007, Inorganic chemistry.

Synthesis of MFe3S4 clusters containing a planar M(II) site (M = Ni, Pd, Pt), a structural element in the C-cluster of carbon monoxide dehydrogenase.

C. Berlinguette, Yugen Zhang, R. H. Holm, 2005, Journal of the American Chemical Society.

Stability Range of Heterometal Cubane-Type Clusters MFe3S4: Assembly of Double-Cubane Clusters with the ReFe3S4 Core.

S. Ciurli, G. Papaefthymiou, M. Carney, 1989 .

E.s.r. Studies of Four-Coördinate Complexes of Nickel, Palladium and Platinum Related by Electron Transfer Reactions

N. Edelstein, A. Davison, R. H. Holm, 1963 .

Nontemplate synthesis of an unsaturated tetraaza[14]macrocycle and its metal(II) complexes

R. H. Holm, T. Truex, 1971 .

Complexes containing the Fe-S6 core with unusual magnetic, electrochemical, and stereochemical properties

R. H. Holm, L. Pignolet, 1970 .

The Cuboidal Fe3S4 Cluster: Synthesis, Stability, and Geometric and Electronic Structures in a Non-Protein Environment

R. H. Holm, Jian Zhou, E. Münck, 1996 .

Phosphine cleavage of iron(III)-bridged double cubanes: a new route to MoFe3S4 single cubanes

J. Bashkin, R. H. Holm, Y.-P. Zhang, 1987 .

Heterometallic clusters: synthesis and reactions of vanadium-iron-sulfur single- and double-cubane clusters and the structure of [V2Fe6S8Cl4(C2H4S2)2]4-

R. H. Holm, J. Kovacs, 1987 .

Structural chemistry of vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4]2+ core

R. H. Holm, J. Kovacs, 1987 .

Tetrathiovanadate(V) and tetrathiorhenate(VII): structures and reactions, including characterization of the VFe2S4 core unit

Y. Do, R. H. Holm, E. Simhon, 1985 .

The clusters [Co8S6(SPh)8]4-,5-: preparations, properties, and structural relationship of near-cubic Co8(.mu.4-S)6 cores to the clusters in synthetic pentlandite

J. Bashkin, G. Christou, K. Hagen, 1985 .

Persulfide-bridged iron-molybdenum-sulfur clusters of biological relevance: two synthetic routes and the structures of intermediate and product clusters

J. Bashkin, R. H. Holm, J. Kovacs, 1985 .

Analogues of the [Fe4S4]+ sites of reduced ferredoxins: single-step synthesis of the clusters [Fe4S4(SR)4]3− and examples of compressed tetragonal core structures

K. Hagen, A. D. Watson, R. H. Holm, 1984 .

Molybdenum atom ligand substitution reactions of molybdenum-iron-sulfur (MoFe3S4) cubane-type clusters: synthesis and structures of clusters containing molybdenum-bound pseudosubstrates of nitrogenase

J. Bashkin, R. Palermo, R. H. Holm, 1984 .

R. Frankel, G. Papaefthymiou, R. E. Johnson, 1983 .

Derivatives of tetrathiovanadate(V): synthesis of the linear heterometallic Fe(.mu.2-S)2V(.mu.2-S)2Fe core and the structures of tetrathiovanadate(3-) ion ([VS4]3-) and tetrachlorotetrathiodiferratevanadate(3-) ion ([VFe2S4Cl4]3-)

Y. Do, R. H. Holm, E. Simhon, 1983 .

Reactivity properties of single molybdenum iron sulfide (MoFe3S4) cubane-type clusters: synthesis, structure, and ligand substitution reactions of [MoFe3S4Cl3(3,6-(C3H5)2C6H2O2)(THF)]2-

R. Palermo, R. H. Holm, 1983 .

Analogs of the [4Fe-4S]+ sites of reduced ferredoxins: structural and spectroscopic properties of [(C2H5)4N]3[Fe4S4(S-p-C6H4Br)4] in crystalline and solution phases

R. Frankel, G. Papaefthymiou, D. Stephan, 1983 .

Single cubane-type MFe3S4 clusters (M = Mo, W): synthesis and properties of oxidized and reduced forms and the structure of (Et4N)3[MoFe3S4(S-p-C6H4Cl)4(3,6-(C3H5)2C6H2O2)]

P. Mascharak, R. H. Holm, Y. Mizobe, 1983 .

Trinuclear metal(II)-sulfide-thiolate complexes: synthesis, structures, and properties of [M3S(1,2-(SCH2)2C6H4)3]2- (M = Fe(II), Co(II))

G. Christou, K. Hagen, R. H. Holm, 1983 .

Structural distortions of the [Fe4S4]2+ core of [Fe4S4(S-t-C4H9)4]2− in different crystalline environments and detection and instability of oxidized ([Fe4S4]3+) clusters

P. Mascharak, K. Hagen, R. H. Holm, 1983 .

A new structural type in iron-sulfide-thiolate chemistry: preparation, properties, and structure of the hexanuclear cluster [Fe6S9(S-tert-C4H9)2]4-

J. Ibers, G. Christou, M. Sabat, 1982 .

Systematic iron(II)-thiolate chemistry: synthetic entry to trinuclear complexes

K. Hagen, R. H. Holm, 1982 .

Doubly bridged double cubanes containing MFe3S4 clusters (M = Mo, W). Synthesis, structure, and conversion to spin-quartet single clusters in solution

P. Mascharak, R. H. Holm, W. Armstrong, 1982 .

Electron-transfer series of MoFe3S4 double-cubane clusters: electronic properties of components and the structure of [(C2H5)4N]5[Mo2Fe6S8(SC6H5)9]

R. Frankel, G. Papaefthymiou, P. Mascharak, 1982 .

Demonstration of the existence of single cubane-type molybdenum iron sulfide (MoFe3S4) clusters with S = 3/2 ground states: preparation, structure, and properties

P. Mascharak, R. H. Holm, W. Armstrong, 1982 .

Synthesis, structure, and properties of [Co8S6(SC6H5)8]4-, containing an octanuclear Co8S6 rhombic dodecahedron related to that of cobalt pentlandite

G. Christou, K. Hagen, R. H. Holm, 1982 .

Ligand substitution properties of the MFe3S4 double-cubane cluster complexes [Mo2Fe6S8(SR)9]3- and [M2Fe7S8(SR)12]3- (M = molybdenum, tungsten)

R. Palermo, P. Power, R. H. Holm, 1982 .

Centenary Lecture. Metal clusters in biology: quest for a synthetic representation of the catalytic site of nitrogenase

R. H. Holm, 1981 .

A hexanuclear iron-sulfide-thiolate cluster: assembly and properties of [Fe6S9(S-tert-C4H9)2]4- containing three types of bridging sulfur atoms

J. Ibers, G. Christou, M. Sabat, 1981 .

Synthesis and electronic and redox properties of "double-cubane" cluster complexes containing molybdenum iron sulfide (MoFe3S4) and tungsten iron sulfide (WFe3S4) cores

R. Frankel, P. Power, T. Wolff, 1980 .

Structural characterization of the iron-bridged "double-cubane" cluster complexes [Mo2Fe7S8(SC2H5)12]3- and [M2Fe7S8(SCH2C6H5)12]4- (M = molybdenum, tungsten) containing MFe3S4 cores

J. Berg, K. Hodgson, P. Power, 1980 .

THE SYNTHESIS AND STRUCTURE OF DECA(BENZENETHIOLATO)TETRAFERRATE(II) DIANION, AN INTERMEDIATE IN THE ASSEMBLY OF (FE4S4(SC6H5)4)2- FROM SIMPLE REAGENTS

J. Berg, K. Hagen, R. H. Holm, 1980 .

Self-assembly of molybdenum-iron-sulfur clusters as a synthetic approach to the molybdenum site in nitrogenase. Identification of the major products formed by the system FeCl3/MS42-/C2H5SH (M = Molybdenum, tungsten)

J. Berg, K. Hodgson, R. Frankel, 1979 .

Crystal structure of [(C2H5)4N]3[Fe4S4(SCH2Ph)4], a reduced ferredoxin site analog with a nontetragonal Fe4S4 core structure in the solid state

J. Berg, K. Hodgson, R. H. Holm, 1979 .

Synthetic approaches to the molybdenum site in nitrogenase. Preparation and structural properties of the molybdenum-iron-sulfur "double-cubane" cluster complexes [Mo2Fe6S8(SC2H5)9]3- and [Mo2Fe6S9(SC2H5)8]3-

J. Berg, K. Hodgson, R. Frankel, 1979 .

A fluorine-19 NMR method for identification of iron-sulfur cores extruded from active centers of proteins, with applications to milk xanthine oxidase and the iron-molybdenum proteins of nitrogenase

R. H. Holm, D. Kurtz, L. Mortenson, 1979 .

Reaction chemistry of the iron-sulfur protein site analogs [Fe4S4(SR)4]2-. Sequential thiolate ligand substitution reactions with electrophiles

R. H. Holm, Richard W. Johnson, 1978 .

Proton magnetic resonance properties of the tetranuclear clusters [Fe4S4(SR)4]3-, analogs of the 4-Fe sites of reduced ferredoxins

E. Laskowski, J. Reynolds, R. H. Holm, 1978 .

The molybdenum-iron-sulfur cluster complex [Mo2Fe6S9(SC2H5)8]3-. A synthetic approach to the molybdenum site in nitrogenase

J. Berg, K. Hodgson, R. Frankel, 1978 .

Selenium substitution in [Fe4S4(SR)4]2-: synthesis and comparative properties of [Fe4X4(YC6H5)4]2- (X, Y = sulfur, selenium) and the structure of [(CH3)4N]2[Fe4Se4(SC6H5)4]

J. Berg, K. Hodgson, E. Laskowski, 1978 .

Inorganic derivatives of iron sulfide thiolate dimers and tetramers: synthesis and properties of the halide series [Fe2S2X4]2- and [Fe4S4X4]2- (X = chlorine, bromine, iodine)

R. H. Holm, G. Wong, M. A. Bobrik, 1978 .

Chemical and electrochemical interrelationships of the 1-Fe, 2-Fe, and 4-Fe analogs of the active sites of iron-sulfur proteins

A. G. Wedd, R. H. Holm, J. Cambray, 1977 .

Inorganic derivatives of iron-sulfide-thiolate dimers and tetramers. Structures of tetrachloro-.mu.-disulfido-diferrate(III) and tetrakis(chloro-.mu.3-sulfido-iron) dianions

K. Hodgson, R. H. Holm, M. A. Bobrik, 1977 .

Synthetic analogues of the active sites of iron-sulfur proteins. 15. Comparative polarographic potentials of the [Fe4S4(SR)4]2 -- ,3 -- and clostridium pasteurianum ferredoxin redox couples.

J. Renaud, R. H. Holm, C. Hill, 1977, Journal of the American Chemical Society.

Letter: Theoretical model for the 4-Fe active sites in oxidized ferredoxin and reduced "high-potential" proteins. Electronic structure of the analogue [Fe4S4(SCH3)4]2-.

K. H. Johnson, R. H. Holm, J. G. Norman, 1975, Journal of the American Chemical Society.

Synthetic analogs of the active sites of iron-sulfur proteins. IX. Formation and some electronic and reactivity properties of Fe4S4 Glycyl-L-cysteinylglycyl oligopeptide complexes obtained by ligand substitution reactions.

L. Que, J. Anglin, A. Davison, 1974, Journal of the American Chemical Society.

Synthesis and selected properties of a reduced single-cubane cluster containing the [MoFe3,S4]2+ (S = 2) core

R. Palermo, P. Mascharak, R. H. Holm, 1983 .

Synthesis, structure, and properties of the cluster complex [MoFe4S4(SC2H5)3(C6H4O2)3]3-, containing a single cubane-type molybdenum-iron-sulfur (MoFe3S4) core

J. Berg, T. Wolff, R. H. Holm, 1981 .

Chemistry of the Metal Carbonyls. XX. Nature of the Reaction Product from Cyclopentadienylvanadium Tetracarbonyl and Dimethyl Disulfide

R. King, R. H. Holm, F. Stone, 1963 .

Cadmium-113 Fourier Transform Nuclear Magnetic Resonance and Raman Spectroscopic Studies of Cadmium(II)-Sulfur Complexes, Including [Cd10(SCH2CH2OH)16]4+

R. Lord, R. Haberkorn, R. H. Holm, 1976 .

Identification of the Geometrical Isomers of Some Tris-Chelate Cobalt(III) Complexes by Nuclear Resonance

R. H. Holm, A. Chakravorty, 1964 .

J. Berg, R. H. Holm, 1984 .

Magnetic Evidence Indicative of Structures and Structural Changes in Complexes of Cobalt(II)

F. Cotton, R. H. Holm, 1960 .

Synthetic and Electron Spin Resonance Studies of Six-Coordinate Complexes Related by Electron-Transfer Reactions

N. Edelstein, A. Davison, R. H. Holm, 1964 .

Comprehensive iron-selenium-thiolate cluster chemistry

G. Papaefthymiou, R. H. Holm, S. Yu, 1991 .

The cavitand concept in the synthesis of subsite-differentiated analogs of biological [4Fe-4S/Se]2+ clusters: cluster capture reactions, ligand conformational analysis, and the structure of a trigonal [4Fe-4Se]2+ analog

T. D. Stack, R. H. Holm, J. A. Weigel, 1990 .

Hexakis(triethylphosphine)hexathioxohexairon(+): extension of stabilization of the basket core topology to the [Fe6S6]+ oxidation level

R. H. Holm, B. Snyder, 1990 .

Alternative spin states in synthetic analogs of biological iron-sulfur [4Fe-4S]+ clusters: further cases of variable ground states and the structure of (Et4N)3[Fe4S4(S-o-C6H4S-tert-Bu)4], containing a reduced cluster with a compressed tetragonal distortion

R. Frankel, G. Papaefthymiou, M. Carney, 1989 .

Binding of oxysulfur anions to macrocyclic iron(II,III): [(Fe(TPP))2SO4] and Fe(Me6[14]-4,11-dieneN4)(S2O5)]

R. H. Holm, Martha S. Reynolds, 1989 .

Iron-sulfur-thiolate basket clusters

R. H. Holm, Martha S. Reynolds, 1988 .

Core conversion reactions of iron-sulfur clusters: topological isomer of the Fe6S6-prismane core

R. H. Holm, Martha S. Reynolds, I. Noda, 1988 .

New inorganic ring system: planar Fe/sub 3/(. mu. /sub 2/-SR)/sub 3/ in (Fe/sub 3/(SR)/sub 3/X/sub 6/)/sup 3 -/ - synthesis, structures, and solution conformation and equilibrium

J. Bashkin, N. Edelstein, K. Hagen, 1986 .

Synthetic analogs of the active sites of iron-sulfur proteins. VII. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2- and the structure of ((CH3)4N)2(Fe4S4(SC6H5)4).

L. Que, J. Ibers, R. H. Holm, 1974, Journal of the American Chemical Society.

Structural Interconversions of Octahedral, Planar, and Tetrahedral Nickel(II) Complexes

R. H. Holm, A. Chakravorty, J. Fennessey, 1965 .

Sulfur bridging interactions of cis-planar NiII-S2N2 coordination units with nickel(II), copper(I,II), zinc(II), and mercury(II): a library of bridging modes, including NiII(micro2-SR)2MI,II rhombs.

S. Bhaduri, R. H. Holm, P. Rao, 2004, Inorganic chemistry.

Dipole moments and structures of some bis-(trifluoroacetylacetonato) complexes

F. Cotton, R. H. Holm, 1960 .

Iron-sulfur clusters: nature's modular, multipurpose structures.

H. Beinert, R. H. Holm, E Münck, 1997, Science.

Studies on Nickel(II) Complexes. VI. The Conformational Equilibria of Bis(o-hydroxynaphthaldimine) Complexes

R. H. Holm, A. Chakravorty, 1964 .

Studies on Nickel(II) Complexes. V.1 A Nuclear Resonance Study of Conformational Equilibria

R. H. Holm, A. Chakravorty, G. Dudek, 1964 .

Three-dimensional macrocyclic encapsulation reactions. I. Synthesis of six-coordinate complexes with nonoctahedral stereochemistry

J. Parks, R. H. Holm, B. E. Wagner, 1970 .

MOLYBDENUM-IRON SULFIDE-BRIDGED DOUBLE CUBANES

Jie‐Sheng Huang, S. Mukerjee, R. H. Holm, 1997 .

Ligand-based redox reactions. Analysis of the electron paramagnetic resonance spectrum of the [Ni(Me4[14]hexaenatoN4)]+ cation radical, the central member of a three-membered electron transfer series containing a tetraaza[14]annulene ligand system

R. H. Holm, M. Millar, 1975 .

Synthetic transformations of tetraaza macrocyclic metal complexes. Preparation of the corrinoid and other unsaturated ring systems by oxidative dehydrogenation reactions of nickel(II), copper(II), and cobalt(II) macrocycles

R. H. Holm, S. Tang, 1975 .

STEREOELECTRONIC PREFERENCES IN ELECTRON TRANSFER SERIES OF NICKEL WITH TRIDENTATE LIGANDS CONTAINING HARD-SOFT DONOR SETS

T. James, R. H. Holm, Diane M. Smith, 1994 .

Structural and Reaction Chemistry of Nickel Complexes in Relation to Carbon Monoxide Dehydrogenase: A Reaction System Simulating Acetyl-coenzyme a Synthase Activity

P. Stavropoulos, R. H. Holm, M. Muetterties, 1991 .

Cleavage of Ni-(mu(2)-S)-Ni bridges in dinuclear nickel(II) dithiolate pincer complexes and related reactions.

Jibin Sun, L. Deng, R. H. Holm, 2009, Inorganic chemistry.

Studies on nickel(II) complexes. VII. a nuclear resonance investigation of mixed ligand complexes

R. H. Holm, A. Chakravorty, 1964 .

Proton Contact Shifts in Dynamical Nickel(II) Complexes and the Detection of Diastereoisomers by Nuclear Resonance

R. H. Holm, A. Chakravorty, G. Dudek, 1963 .

A NUCLEAR MAGNETIC RESONANCE STUDY OF KETO-ENOL EQUILIBRIA IN SCHIFF BASES. II

R. H. Holm, G. Dudek, 1961 .

Reduction of nitrate to nitrite by molybdenum-mediated atom transfer: a nitrate reductase analog reaction system

R. H. Holm, J. A. Craig, 1989 .

Kinetics, mechanisms, and catalysis of oxygen atom transfer reactions of S-oxide and pyridine N-oxide substrates with molybdenum(IV,VI) complexes: relevance to molybdoenzymes

R. H. Holm, J. Caradonna, P. Reddy, 1988 .

Crystal and molecular structure of bis[(tetramethyl[14]hexaenatotetraaza)nickel] bis(trifluoromethanesulfonate): conversion of a metal-stabilized .pi.-radical to a diamagnetic dimer with a long metal-metal bond and eclipsed macrocyclic ligands upon crystallization

J. Ibers, S. Peng, R. H. Holm, 1976 .

The crystal and molecular structure of the electron transfer complex butane-2, 3-dione-bis(2′-pyridyl-hydrazonato)nickel, [Ni(BDPH)-2H]

R. H. Holm, R. Olcott, 1969 .

Solution chemistry of ethane-1,2-dithiolate complexes: equilibria and electron-transfer reactions

C. Rao, R. Mukherjee, R. H. Holm, 1986 .

Synthesis, Structures and Oxo Transfer Reactivity of bis(Dithiolene) Tungsten(IV,VI) Complexes Related to the Active Sites of Tungstoenzymes

E. Nordlander, R. H. Holm, C. Lorber, 1998 .

Intramolecular rearrangement reactions of tris-chelate complexes. I. General theory and the kinetics and probable mechanism of the isomerization and racemization of tris(5-methylhexane-2,4-dionato)cobalt(III)

R. H. Holm, J. Gordon, 1970 .

Diastereoisomeric four-coordinate complexes. III. Paramagnetic nickel(II) complexes with three asymmetric centers

R. H. Holm, M. J. O'connor, R. Ernst, 1967 .

SOLUBLE METAL SULFIDES - SYNTHESIS AND STRUCTURES OF [M6S17]4- (M = NB, TA) - ICOSAHEDRAL-FRAGMENT CAGES CONTAINING FOUR TYPES OF COORDINATED SULFIDE

J. Berg, Y. Do, J. Solà, 1983 .

[Na9Fe20Se38]9-: a [sodium-iron-selenium] high-nuclearity bicyclic cluster constructed by the fusion of Fe2Se2 rhombs

R. H. Holm, J. You, 1991 .

X-ray absorption spectroscopy of a structural analogue of the oxidized active sites in the sulfite oxidase enzyme family and related molybdenum(V) complexes.

K. Hodgson, B. Hedman, B. Lim, 2003, Inorganic chemistry.

Subsite-Specific Structures and Reactions in Native and Synthetic (4Fe - 4S) Cubane-Type Clusters

S. Ciurli, R. H. Holm, J. A. Weigel, 1991 .

Intrinsic binding properties of a differentiated iron subsite in analogs of native [Fe4S4]2+ clusters

R. H. Holm, J. A. Weigel, 1991 .

Synthetic nickel-iron NiFe3Q4 cubane-type clusters (S = 3/2) by reductive rearrangement of linear [Fe3Q4(SEt)4]3- (Q = sulfur, selenium)

S. Ciurli, R. H. Holm, S. Yu, 1990 .

On the molecular solid-state boundary. A cyclic iron-sulfur cluster of nuclearity eighteen: synthesis, structure, and properties

G. Papaefthymiou, R. H. Holm, J. You, 1990 .

Spin isolation of the [3Fe―4S] fragment of a [4Fe―4S] cluster: electronic properties of the [3Fe―4S]0 cluster

R. H. Holm, E. Münck, J. A. Weigel, 1989 .

Subsite-differentiated analogs of biological [4Fe-4S]2+ clusters: synthesis, solution and solid-state structures, and subsite-specific reactions

T. D. Stack, R. H. Holm, T. Stack, 1988 .

Electronic properties of the linear antiferromagnetically coupled clusters (Fe/sub 3/S/sub 4/(SR)/sub 4/)/sup 3 -/, structural isomers of the (Fe/sub 3/S/sub 4/)/sup +/ unit in iron-sulfur proteins

R. Frankel, G. Papaefthymiou, N. Edelstein, 1984 .

Antiferromagnetic exchange interactions in [Fe4S4(SR)4]2-,3- clusters

R. Frankel, E. Laskowski, G. Papaefthymiou, 1982 .

Definition of reaction sequences resulting in self-assembly of [Fe4S4(SR)4]2- clusters from simple reactants

J. Reynolds, K. Hagen, R. H. Holm, 1981 .

Synthetic analogues of the 4-Fe active sites of reduced ferredoxins. Electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3- and the structure of [(C2H5)3(CH3)N]3[Fe 4S4(SC6H5)4]

R. Frankel, E. Laskowski, J. Ibers, 1978 .

Synthetic analogs of the active sites of iron-sulfur proteins. X. Kinetics and mechanism of the ligand substitution reactions of arylthiols with the tetranuclear clusters [Fe4S4(SR)4]2-

R. H. Holm, G. Dukes, 1975 .

Stereochemistry and rearrangement rates of some tris(β-diketonato)- and tris(β-thioketonato)metal(III) complexes

R. H. Holm, M. J. O'connor, J. Gordon, 1971 .

Nuclear Resonance Studies of Structural Equilibria in Solutions of Nickel(II) Complexes

R. H. Holm, A. Chakravorty, G. Everett, 1964 .

Characterization of dimeric dithiolene complexes

A. Balch, I. Dance, R. H. Holm, 1968 .

Electron transfer behaviour of dimeric complexes of cobalt with dithiolate ligands

A. Balch, R. H. Holm, 1966 .

TETRAKIS(ETHANE-1,2-DITHIOLATO)DIVANADATE(III): A BINUCLEAR COMPLEX WITH A QUADRUPLE BRIDGE, A METAL-METAL BOND, AND NONOCTAHEDRAL STEREOCHEMISTRY

R. H. Holm, J. Dorfman, 1984 .

Diastereoisomeric four-coordinate complexes. VI. Paramagnetic nickel(II) complexes with four asymmetric ligand centers

R. H. Holm, M. J. O'connor, R. Ernst, 1968 .

Isotropic Nuclear Magnetic Resonance Shifts in Tetrahedral Bispyridine and Bispicoline Complexes of Nickel(II)

R. H. Holm, W. Horrocks, G. Everett, 1966 .

Intramolecular rearrangement reactions of tris-chelate complexes. III. Analysis of the rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonato)aluminum(III) and -cobalt(III). Examples of stereochemically nonrigid aluminum(III) and cobalt(III) complexes

S. Eaton, E. Muetterties, R. H. Holm, 1972 .

Stereochemically nonrigid cobalt(III) complexes

S. Eaton, R. H. Holm, 1971 .

Intramolecular rearrangement reactions of tris-chelate complexes. II. Kinetics and probable mechanism of the isomerization and racemization of the "fast" complexes tris(1-phenyl-5-methylhexane-2,4-dionato)aluminum(III) and -gallium(III)

R. H. Holm, J. Gordon, J. R. Hutchison, 1971 .

A binuclear mixed-valence ferromagnetic iron system with an S = 9/2 ground state and valence trapped and detrapped states

R. H. Holm, E. Münck, K. Surerus, 1989 .

Improved syntheses of the dimeric complexes [Fe2X2(SC6H4Y)4]2- and [Fe2X2((SCH2)2C6H4)2]2- (X = sulfur, selenium), analogs of the 2-Fe sites of oxidized ferredoxin proteins

J. Reynolds, R. H. Holm, 1980 .

Synthetic analogs of the active sites of iron-sulfur proteins. V. Proton resonance properties of the tetranuclear clusters [tetra-.mu.-sulfido-tetrakis(alkyl or aryl thiolato)tetraferrate](2-)

W. D. Phillips, B. Averill, R. H. Holm, 1974 .

Tetrahedral and square-pyramidal sulphur-rich complexes of manganese(II)

R. H. Holm, S. Yu, 1993 .

Equivalence of metal centers in the iron-sulfur protein active site analogs (Fe4S4(SR)4)2-.

R. Frankel, H. Gray, F. Grunthaner, 1974, Journal of the American Chemical Society.

Synthetic analogs of the active sites of iron-sulfur proteins. IV. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2-.

L. Que, R. H. Holm, M. A. Bobrik, 1974, Journal of the American Chemical Society.

Synthesis and Structures of Solvated Monoclusters and Bridged Di- and Triclusters Based on the Cubic Building Block [Re(6)(&mgr;(3)-Se)(8)](2+).

Zhiping Zheng, R. H. Holm, Thomas G. Gray, 1999, Inorganic chemistry.

Soluble sulfides of niobium(V) and tantalum(V): synthesis, structures, and properties of the fivefold symmetric cages [M6S17]4−

J. Berg, Y. Do, J. Solà, 1985 .

Synthesis and Metal Ion Incorporation Reactions of the Cuboidal Fe3S4 Cluster

R. H. Holm, Jian Zhou, 1995 .

Heterometal Clusters Containing the Cuboidal Fe4S3 Fragment: Synthesis, Electron Distribution, and Reactions

M. J. Scott, R. H. Holm, W. Cen, 1994 .

A Basis Set of Re6Se8 Cluster Building Blocks and Demonstration of Their Linking Capability: Directed Synthesis of an Re12Se16 Dicluster

Jeffrey R. Long, J. Long, Zhiping Zheng, 1997 .

Rhenium-selenium-chlorine solid phases: cluster excision and core substitution reactions of molecular species

O. Yaghi, M. J. Scott, R. H. Holm, 1992 .

Synthesis and structures of bis(dithiolene)molybdenum complexes related to the active sites of the DMSO reductase enzyme family.

B. Lim, R. H. Holm, J. P. Donahue, 2000, Inorganic chemistry.

Synthesis and Reactivity Aspects of the Bis(dithiolene) Chalcogenide Series [WIVQ(S2C2R2)2]2- (Q = O, S, Se)

R. H. Holm, C. Goddard, 1999 .

Synthesis, Structures, and Reactivity of Bis(dithiolene)molybdenum(IV,VI) Complexes Related to the Active Sites of Molybdoenzymes

R. H. Holm, J. P. Donahue, Christian R. Goldsmith, 1998 .

An expanded set of functional groups in bis(dithiolene)tungsten(IV,VI) complexes related to the active sites of tungstoenzymes, Including WIV-SR and WVI-O(SR).

R. H. Holm, Jian-Bing Jiang, 2004, Inorganic chemistry.

Substitution and oxidation reactions of bis(dithiolene)tungsten complexes of potential relevance to enzyme sites.

R. H. Holm, K. Sung, 2001, Inorganic chemistry.

Molybdenum and Tungsten Structural Analogues of the Active Sites of the Mo(IV) + [O] -> Mo(VI)O Oxygen Atom Transfer Couple of DMSO Reductases

E. Nordlander, R. H. Holm, C. Lorber, 1998 .

An X-ray spectroscopic investigation of bis(dithiolene)molybdenum(IV,V,VI) and -tungsten(IV,V,VI) complexes: Symmetrized structural representations of the active sites of molybdoenzymes in the DMSO reductase family and of tungstoenzymes in the AOR and F(M)DH families

K. Hodgson, B. Hedman, R. H. Holm, 1999 .

Bis(dithiolene)molybdenum analogues relevant to the DMSO reductase enzyme family: synthesis, structures, and oxygen atom transfer reactions and kinetics.

B. Lim, R. H. Holm, Richard H. Holm, 2001, Journal of the American Chemical Society.

X-ray spectroscopy of enzyme active site analogues and related molecules: bis(dithiolene)molybdenum(IV) and -tungsten(IV,VI) complexes with variant terminal ligands.

K. Hodgson, B. Hedman, B. Lim, 2000, Inorganic chemistry.

Synthesis of structural analogues of the oxidized sites in the xanthine oxidoreductase enzyme family.

R. H. Holm, Sonny C. Lee, S. Groysman, 2007, Journal of the American Chemical Society.

Synthesis and structures of bis(dithiolene)tungsten(IV,VI) thiolate and selenolate complexes: approaches to the active sites of molybdenum and tungsten formate dehydrogenases.

R. H. Holm, S. Groysman, 2007, Inorganic chemistry.

Analogue reaction systems of selenate reductase.

R. H. Holm, C. Tessier, Jun-Jieh Wang, 2006, Inorganic chemistry.

Reaction systems related to dissimilatory nitrate reductase: nitrate reduction mediated by bis(dithiolene)tungsten complexes.

R. H. Holm, Jian-Bing Jiang, 2005, Inorganic chemistry.

Monodithiolene molybdenum(V, VI) complexes: a structural analogue of the oxidized active site of the sulfite oxidase enzyme family.

B. Lim, R. H. Holm, M. Willer, 2001, Journal of the American Chemical Society.

Structural and Functional Bis(dithiolene)-Molybdenum/Tungsten Active Site Analogues of the Dimethylsulfoxide Reductase Enzyme Family

B. Lim, R. H. Holm, A. K. Sung, 2000 .

Oxo/sulfidotungstate(VI) as precursors to W(VI)O2, W(VI)OS, and W(VI)S2 complexes and W(IV)-dithiolene chelate rings.

R. H. Holm, M. Willer, M. Miao, 2000, Inorganic chemistry.

Toward an expanded oxygen atom transfer reactivity scale: Computational investigation of the energetics of oxo transfer reaction couples

R. H. Holm, Sonny C. Lee, 2008 .

Bridged multiclusters derived from the face-capped octahedral [Re6 III(μ3-Se)8]2+ cluster core

Zhiping Zheng, R. H. Holm, Thomas G. Gray, 2001 .

Group 5 tetrathiometalates : simplified syntheses and structures

R. H. Holm, Sonny C. Lee, Jiguo Li, 1992 .

Entry to the solution chemistry of niobium and tantalum sulfides: Synthesis of soluble forms of the tetrathiometalates (MS sub 4 ) sup 3 minus

R. H. Holm, Sonny C. Lee, 1990 .

SOLUBLE SULFIDES OF NIOBIUM(V) AND TANTALUM(V): SYNTHESIS, STRUCTURES, AND PROPERTIES OF THE FIVEFOLD SYMMETRIC CAGES (M6S17)4-

J. Berg, Y. Do, J. Solà, 1985 .

Enumeration and Structural Classification of Clusters Derived from Parent Solids: Metal-Chalcogenide Clusters Composed of Edge-Sharing Tetrahedra

J. Long, R. H. Holm, 1994 .

Ligand Substitution Reactions of [Re6S8Br6]4-: A Basis Set of Re6S8 Clusters for Building Multicluster Assemblies

J. Long, R. H. Holm, M. Willer, 1998 .

Cluster Condensation by Thermolysis: Synthesis of a Rhomb-Linked Re12Se16 Dicluster and Factors Relevant to the Formation of the Re24Se32 Tetracluster

Zhiping Zheng, R. H. Holm, 1997 .

Rhenium‐Selenium‐Chlorine Solid Phases: Cluster Excision and Core Substitution Reactions of Molecular Species.

O. Yaghi, M. J. Scott, R. H. Holm, 1993 .

Molybdenum-iron-sulfur clusters of nuclearities eight and sixteen, including a topological analogue of the P-cluster of nitrogenase.

F. Osterloh, C. Achim, R. H. Holm, 2001, Inorganic Chemistry.

Comparative kinetics and mechanism of oxygen and sulfur atom transfer reactions mediated by bis(dithiolene) complexes of molybdenum and tungsten.

R. H. Holm, E. Rybak-Akimova, Jun-Jieh Wang, 2004, Inorganic chemistry.

Sulfur K-Edge X-ray Absorption Spectroscopy and Density Functional Theory Calculations on Monooxo MoIV and Bisoxo MoVI Bis-dithiolenes: Insights into the Mechanism of Oxo Transfer in Sulfite Oxidase and Its Relation to the Mechanism of DMSO Reductase

Adam L. Tenderholt, K. Hodgson, B. Hedman, 2014, Journal of the American Chemical Society.

Synthesis, Structures, and Reactivity of Bis(dithiolene)molybdenum(IV,VI) Complexes Related to the Active Sites of Molybdoenzymes.

R. H. Holm, J. P. Donahue, Christian R. Goldsmith, 1999 .

Nickel dithiolenes revisited: structures and electron distribution from density functional theory for the three-member electron-transfer series [Ni(S2C2Me2)2]0,1-,2-.

B. Lim, R. H. Holm, D. Fomitchev, 2001, Inorganic chemistry.

Molybdenum-mediated imido group transfer: stoichiometric and catalytic reactions and structures

R. H. Holm, E. W. Harlan, 1990 .

Spectroscopic and structural characterization of ruthenium(II) carbonyl-porphine complexes

J. Ibers, S. Eaton, G. Eaton, 1973 .

Trinuclear oxothiomolybdates from the reductive cleavage of [Mo8O26]4- with hexamethyldisilthiane

Y. Do, R. H. Holm, E. Simhon, 1985 .

Oxo sulfido ligand substitution in dimolybdate ([Mo2O7]2-): reaction sequence and characterization of the final product, [MoS3(OSiMe3)]-

Y. Do, R. H. Holm, E. Simhon, 1985 .

Molybdenum-Mediated Oxygen Atom Transfer: An Improved Analogue Reaction System of the Molybdenum Oxotransferases.

M. J. Scott, R. H. Holm, B. Schultz, 1993 .

Thermodynamic Fitness of Molybdenum(IV,VI) Complexes for Oxygen Atom Transfer Reactions, Including Those with Enzymatic Substrates.

J. Berg, R. H. Holm, E. W. Harlan, 1987 .

Synthesis and structures of bis(dithiolene)-tungsten(IV) complexes related to the active sites of tungstoenzymes.

R. H. Holm, K. Sung, 2000, Inorganic chemistry.

Thiol as an electron donor in molybdenum oxo-transferase analog reaction systems: observations by fluorine-19 NMR spectroscopy and biological implications.

R. H. Holm, J. Caradonna, E. W. Harlan, 1986, Journal of the American Chemical Society.

3,4-Bis(1-adamantyl)-1,2-dithiete: the first structurally characterized dithiete unsupported by a ring or benzenoid frame.

R. H. Holm, J. P. Donahue, 1998, Acta crystallographica. Section C, Crystal structure communications.

A biomimetic approach to oxidized sites in the xanthine oxidoreductase family: synthesis and stereochemistry of tungsten(VI) analogue complexes.

R. H. Holm, Sonny C. Lee, S. Groysman, 2008, Journal of the American Chemical Society.

Synthetic and Paramagnetic Resonance Studies of Trigonal Vanadium Complexes

N. Edelstein, A. Davison, R. H. Holm, 1965 .

Bis[bis(1,2-ethanedithiolato)ferrate(III)] dianion, a .mu.2-thiolato dimer. Synthesis and properties

R. H. Holm, T. Herskovitz, B. V. Depamphilis, 1975 .

ASSEMBLY OF BIOLOGICALLY RELEVANT IRON-SULFUR CLUSTERS

K. Hagen, A. D. Watson, R. H. Holm, 1984 .

A Molybdenum-Iron-Sulfur Cluster Containing Structural Elements Relevant to the P-Cluster of Nitrogenase.

F. Osterloh, R. Staples, Y. Sanakis, 1999, Angewandte Chemie.

Reduced mono-, di-, and tetracubane-type clusters containing the [MoFe3S4]2+ core stabilized by tertiary phosphine ligation.

F. Osterloh, C. Achim, R. H. Holm, 2000, Inorganic chemistry.

OCTANUCLEAR IRON-SULFUR CLUSTERS WITH SYMMETRICALLY COUPLED FE4S4 AND FE4S5 CORES

J. Long, M. J. Scott, Lisheng Cai, 1995 .

Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re(6)S(8)](2+) and [Re(6)Se(8)](2+).

D. Nocera, Christina M. Rudzinski, R. H. Holm, 1999, Inorganic chemistry.

Site-differentiated hexanuclear rhenium(III) cyanide clusters [Re(6)Se(8)(PEt(3))(n)()(CN)(6)(-)(n)()](n)()(-)(4) (n = 4, 5) and kinetics of solvate ligand exchange on the cubic [Re(6)Se(8)](2+) Core.

R. H. Holm, Thomas G. Gray, 2002, Inorganic chemistry.

Bridged Binuclear Bis-Dithiolene Complexes of Iron and Cobalt

G. Eaton, R. H. Holm, 1971 .

Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe(6)S(8)(PEt(3))(6)](n)()(+) (n = 0-4) Cluster Electron Transfer Series.

J. Long, R. H. Holm, C. Goddard, 1996, Inorganic chemistry.

Improved syntheses of tetrachlorodi-.mu.-sulfidodiferrate(2-) ([Fe2S2Cl4]2-) and hexachloro-.mu.-oxodiferrate(2-) ([Fe2OCl6]2-) and oxo/sulfido ligand substitution by use of silylsulfide reagents

Y. Do, R. H. Holm, E. Simhon, 1983 .

Oxygen/sulfur substitution reactions of tetraoxometalates effected by electrophilic carbon and silicon reagents.

R. H. Holm, David V. Partyka, 2004, Inorganic chemistry.

Mononuclear active sites of molybdoenzymes: chemical approaches to structure and reactivity

J. Berg, R. H. Holm, 1984 .

Entry to the Solution Chemistry of Niobium and Tantalum Sulfides: Synthesis of Soluble Forms of the Tetrathiometalates (MS4)3-.

R. H. Holm, Sonny C. Lee, 1991 .

Group 5 Tetrathiometalates: Simplified Syntheses and Structures.

R. H. Holm, Sonny C. Lee, Jiguo Li, 1993 .

Comprehensive Tungsten-Iodine Cluster Chemistry: Isolated Intermediates in the Solid-State Nucleation of [W6I14]2-

J. Long, R. H. Holm, J. D. Franolic, 1995 .

[Na2Fe18S30]8-. A high-nuclearity cyclic cluster generated solely by iron-sulfur bridge bonding

R. H. Holm, J. You, B. Snyder, 1988 .

The Mixed-Valence Double-Cubanoid Cluster [Fe8S12(ButNC)12]: Synthesis, Structure, and Exchange Coupling of a New Structural Array of Four Fe(III) Sites

R. H. Holm, Sun Jae Yoo, E. L. Bominaar, 1998 .

Tetranuclear Cuboidal and Hexanuclear Prismatic Iron–Sulfur–Nitrosyl Clusters

M. J. Scott, R. H. Holm, 1993 .

Characterization of the Self-Condensation Equilibrium of [Fe(4)S(4)(SH)(4)](2-): Spectroscopic Identification of a Unique Sulfido-Bridged Acyclic Tricubane Cluster.

H. Hoveyda, R. H. Holm, 1997, Inorganic chemistry.

DETERMINATION OF THE EXCHANGE-COUPLING CONSTANT OF AN FE3+-FE3+ PAIR IN A CUBANE-TYPE IRON-SULFUR CLUSTER

R. H. Holm, Sun Jae Yoo, E. L. Bominaar, 1997 .

High-Nuclearity Sulfide-Rich Molybdenum−Iron−Sulfur Clusters: Reevaluation and Extension

Hong‐Cai Zhou, W. Su, C. Achim, 2002 .

Comparative stereochemical effects of sulfur and oxygen donor atoms in four- and six-coordinate metal complexes

M. McNamee, D. Gerlach, R. H. Holm, 1968 .

Terminal Ligand Assignments Based on Trends in Metal−Ligand Bond Lengths of Cubane-Type [Fe4S4]2+,+ Clusters

H. Hoveyda, R. H. Holm, B. Segal, 1998 .

Structural diversity of homoleptic ethane-1,2-dithiolato complexes of the first transition series

C. Rao, R. H. Holm, J. Dorfman, 1985 .

Synthesis and stereochemistry of bis(N,N-disubstituted-dithiocarbamato)maleonitriledithioleneiron complexes

R. Lewis, R. H. Holm, L. Pignolet, 1972 .

Synthesis and stereochemical rearrangements of complexes containing the Fe-S6 core

R. H. Holm, Louis H. Pinolet, R. Lewis, 1971 .

Dimensional Reduction of Re6S8Cl2: Sheets, Chains and Discrete Clusters Composed of Chloride‐Terminated (Re6Q8)2+ (Q: S, Se) Cores.

J. Long, R. H. Holm, A. S. Williamson, 1995 .

Heterometal dependence of electron distributions and redox potentials in clusters with cubane-type [MFe3S4]z cores

R. H. Holm, W. Cen, F. MacDonnell, 1993 .

Relative stereochemical and electronic effects of oxygen and sulfur donor atoms in planar and tetrahedral complexes of nickel(II)

D. Gerlach, R. H. Holm, 1969 .

Zero-valent nickel complexes of bis(phosphino)-o-carboranes

R. H. Holm, F. Röhrscheid, 1965 .

Systematic iron(II)-thiolate chemistry: synthetic entry to trinuclear complexes

K. Hagen, R. H. Holm, 1982 .

9 – Stereochemically Nonrigid Metal Chelate Complexes

R. H. Holm, 1975 .

Vanadium(III), Cobalt(II), and Nickel(II) β‐Keto Amine Complexes

R. H. Holm, J. Grow, L. J. Todd, 2007 .

The high potential iron-sulfur cluster of aconitase is a binuclear iron-sulfur cluster.

H. Beinert, F. Ruzicka, R. H. Holm, 1979, The Journal of biological chemistry.

A new class of (N,N'-bis(salicylideneamino)ethanato)iron(II) complexes: five-coordinate [FeII(salen)L]-. Preparation, properties, and mechanism of electron-transfer reactions

T. D. Stack, R. Mukherjee, R. H. Holm, 1988 .

Letter: Oxidized cytochrome P-450. Magnetic circular dichroism evidence for thiolate ligation in the substrate-bound form. Implications for the catalytic mechanism.

C. Djerassi, J. Trudell, J. Dawson, 1976, Journal of the American Chemical Society.

Reactions of site-differentiated [Fe4S4]2+, 1+ clusters with sulfonium cations: reactivity analogues of biotin synthase and other members of the S-adenosylmethionine enzyme family.

R. H. Holm, C. J. Daley, 2003, Journal of inorganic biochemistry.

Reactivity of [Fe4S4(SR)4]2-,3- clusters with sulfonium cations: analogue reaction systems for the initial step in biotin synthase catalysis.

R. H. Holm, C. J. Daley, 2001, Inorganic chemistry.

Synthesis of tautomeric Schiff base complexes and ketimine .far. aldimine conversion rates of copper(II) complexes

R. H. Holm, G. N. Weinstein, 1972 .

Letter: Extrusion of Fe2S2 and Fe4S4 cores from the active sites of ferredoxin proteins.

L. Que, R. H. Holm, L. Mortenson, 1975, Journal of the American Chemical Society.

[29] Identification of iron-sulfur clusters in proteins

W. Orme-Johnson, R. H. Holm, 1978 .

Synthetic analogs of the active sites of iron-sulfur proteins. 8. Some electronic properties of (Fe4S4(SR)4)3-, analogs of reduced bacterial ferredoxins.

W. D. Phillips, R. Frankel, P. Krusic, 1974, Biochemical and biophysical research communications.

Iron(II, III)-chlorin and -isobacteriochlorin complexes. Models of the heme prosthetic groups in nitrite and sulfite reductases: means of formation and spectroscopic and redox properties

S. Strauss, R. H. Holm, A. M. Stolzenberg, 1981 .

An initial approach to biologically related bridged assemblies: pyridinethiolate-linked iron Fe4S4-Fe complex systems

R. H. Holm, B. Scharbert, H. Y. Liu, 1991 .

Core chalcogenide atom substitution reactions of [Fe2X2(SR)4]2- and [Fe4X4(SR)4]2-,3- clusters (X = sulfur, selenium)

J. Reynolds, R. H. Holm, 1981 .

Stabilization of 3:1 site-differentiated cubane-type clusters in the [Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2 ground states.

A. Majumdar, L. Deng, R. H. Holm, 2010, Inorganic chemistry.

Helix-loop-helix peptides as scaffolds for the construction of bridged metal assemblies in proteins: the spectroscopic A-cluster structure in carbon monoxide dehydrogenase.

R. H. Holm, C E Laplaza, R H Holm, 2001, Journal of the American Chemical Society.

X-RAY POWDER DATA AND STRUCTURES OF SOME BIS-(ACETYLACETONO)-METAL(II) COMPOUNDS AND THEIR DIHYDRATES

F. Cotton, R. H. Holm, 1961 .

Axial ligation modes in iron(III) Porphyrins. Models for the oxidized reaction states of cytochrome P-450 enzymes and the molecular structure of iron(III) protoporphyrin IX dimethyl ester p-nitrobenzenethiolate.

R. Frankel, J. Ibers, G. Papaefthymiou, 1976, Journal of the American Chemical Society.

Structural identification of iron-sulfur clusters of the respiratory chain-linked NADH dehydrogenase.

J. Reynolds, R. H. Holm, C. Paech, 1981, The Journal of biological chemistry.

Multiple-Edge XAS Studies of Synthetic Iron-Copper Bridged Molecular Assemblies Relevant to Cytochrome c Oxidase. Structure Determination Using Multiple-Scattering Analysis with Statistical Evaluation of Errors.

K. Hodgson, A. Di Cicco, B. Hedman, 1996, Inorganic chemistry.

Identification of the iron-sulfur center in trimethylamine dehydrogenase.

D. J. Steenkamp, R. H. Holm, T. Singer, 1977, Proceedings of the National Academy of Sciences of the United States of America.

Electron Transfer: Iron—Sulfur Clusters

R. H. Holm, 2004 .

Terminal Ligand Assignments Based on Trends in Metal—Ligand Bond Lengths of Cubane-Type [Fe4S4]2+,+ Clusters.

H. Hoveyda, R. H. Holm, B. Segal, 1998 .

Ground Spin State Variability in (Fe4S4(SR)4)3-. Synthetic Analogues of the Reduced Clusters in Ferredoxins and Other Iron-Sulfur Proteins: Cases of Extreme Sensitivity of Electronic State and Structure to Extrinsic Factors.

R. Frankel, G. Papaefthymiou, M. Carney, 1988 .

Lability of ruthenium(II) carbonyl porphine complexes with nitrogen bases

S. Eaton, G. Eaton, R. H. Holm, 1971 .

The magnetic circular dichroism spectra of the linear trinuclear clusters [Fe3S4(SR)4]3− in purple aconitase and in a synthetic model

A. Thomson, K. Hagen, R. H. Holm, 1990 .

Intramolecular rearrangement reactions of tris-chelate complexes. IV. Rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonate)metal(III,IV) complexes

S. Eaton, G. Eaton, E. Muetterties, 1973 .

SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS. 14. SYNTHESIS, , PROPERTIES, AND STRUCTURES OF BIS(O-XYLYL-α,α′-DITHIOLATO)FERRATE(II,III) ANIONS, ANALOGS OF OXIDIZED AND REDUCED RUBREDOXIN SITES

R. Frankel, J. Ibers, G. Papaefthymiou, 1977 .

Heterometal cuboidal clusters MFe[sub 4]S[sub 6](PEt[sub 3])[sub 4]Cl (M = V, Mo): synthesis, structural analysis by crystallography and EXAFS, and relevance to the core structure of the iron-molybdenum cofactor of nitrogenase

K. Hodgson, A. Cicco, B. Hedman, 1993 .

A topological method for the enumeration of bridging modes and connectivity patterns of the clusters MmQnLl with four-coordinate metal sites and Q.mu.2,3,4 bridging atoms

R. H. Holm, J. You, 1992 .

Thermodynamics and kinetics of the planar-tetrahedral interconversion of dihalobis(diarylmethylphosphine)nickel(II) complexes

R. H. Holm, L. Pignolet, W. Horrocks, 1970 .

Structural Analysis of Cubane-Type Iron Clusters.

R. H. Holm, Sonny C. Lee, L. L. Tan, 2013, Polyhedron.

Mössbauer and Magnetization Studies of Heme-Copper-Bridged Assemblies Pertinent to Cytochrome c Oxidase.

R. H. Holm, E. Münck, Y. Zang, 1997, Inorganic chemistry.

Letter: Ferric porphyrin thiolates. Possible relationship to cytochrome P-450 enzymes and the structure of (p-nitrobenzenethiolato)iron(III) protoporphyrin IX dimethyl ester.

J. Ibers, R. H. Holm, S. Koch, 1975, Journal of the American Chemical Society.

Electron exchange kinetics of [Fe4S4(SR)4]2-/[Fe4S4(SR)4]3- and [Fe4Se4(SR)4]2-/[Fe4Se4(SR)4]3- systems. Estimates of the intrinsic self-exchange rate constant of 4-Fe sites in oxidized and reduced ferredoxins

J. Reynolds, R. H. Holm, C. L. Coyle, 1980 .

Subsite-differentiated analogs of biological [4Fe-4S] clusters effected by binding of a macrocyclic polyether trithiol

Gang. Peng, R. H. Holm, M. Whitener, 1991 .

Introduction: bioinorganic enzymology II.

E. Solomon, R. H. Holm, 2014, Chemical reviews.

Metallocyclopeptide complexes with MII(S.Cys)4 chromophores.

K. Hodgson, B. Hedman, R. H. Holm, 2000, Inorganic chemistry.

Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear Fe(III)-CN-Cu(II) Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase.

G. Deinum, G. Babcock, M. T. Gardner, 1996, Inorganic chemistry.

Silylation, sulfidation, and benzene-1,2-dithiolate complexation reactions of oxo- and oxosulfidomolybdates(VI) and -tungstates(VI).

R. H. Holm, Jun-Jieh Wang, 2007, Inorganic chemistry.

STRUCTURE PROOFS OF LIGATED AND POLYMERIC DIOXOMOLYBDENUM(VI)-TRIDENTATE COMPLEXES: MOO2(C5H3N-2,6-(CH2S)2)(C4H8SO) AND (MOO2(C5H3N-2,6-(CH2O)2))N

J. Berg, R. H. Holm, 1983 .

SYNTHETIC ROUTES TO IRON SULFIDE (FE2S2, FE3S4, FE4S4, AND FE6S9), CLUSTERS FROM THE COMMON PRECURSOR TETRAKIS(ETHANETHIOLATE)FERRATE(2-) ION ((FE(SC2H5)4)2-): STRUCTURES AND PROPERTIES OF (FE3S4(SR)4)3- AND BIS(ETHANETHIOLATE)NONATHI

K. Hagen, A. D. Watson, R. H. Holm, 1983 .

MÖSSBAUER PROPERTIES OF SYNTHETIC ANALOGS OF ACTIVE SITES OF THE IRON-SULFUR PROTEINS

R. Frankel, B. Averill, R. H. Holm, 1974 .

Chemical approaches to bridged biological metal assemblies

R. H. Holm, 1995 .

Carbon monoxide affinities of iron(II) octaethylporphyrin, octaethylchlorin, and octaethylisobacteriochlorin

S. Strauss, R. H. Holm, 1982 .

Evidence for the localized iron(III)/iron(II) oxidation state configuration as an intrinsic property of [Fe2S2(SR)4]3- clusters

R. Frankel, G. Papaefthymiou, P. Mascharak, 1981 .

Subsite-Differentiated Analogues of Native (4Fe-4S)2+ Clusters: Preparation of Clusters with Five- and Six-Coordinate Subsites and Modulation of Redox Potentials and Charge Distributions.

S. Ciurli, G. Papaefthymiou, T. D. Stack, 1990 .

On [Fe4S4]2+ -(mu2-SR)-M II bridge formation in the synthesis of an A-cluster analogue of carbon monoxide dehydrogenase/acetylcoenzyme A synthase.

S. Bhaduri, D. Hong, R. H. Holm, 2005, Journal of the American Chemical Society.

Li3[VS4].cntdot.2DMF: a solubilized form of tetrathiovanadate(V)

R. H. Holm, Y.-P. Zhang, 1988 .

Characterization of the iron-sulfur centers in succinate dehydrogenase.

W. Orme-Johnson, R. H. Holm, D. Kurtz, 1979, Proceedings of the National Academy of Sciences of the United States of America.

Edge-bridged Mo2Fe6S8 to pN-type Mo2Fe6S9 cluster conversion: structural fate of the attacking sulfide/selenide nucleophile.

C. Berlinguette, R. H. Holm, 2006, Journal of the American Chemical Society.

Li3(VS4)·2 DMF: A Solubilized Form of Tetrathiovanadate(V).

R. H. Holm, Yan Zhang, 1989 .

The homogeneous hydrogen-evolving systems [Mo2Fe6S8(SPh)9]4-,5-/C6H5SH: reaction characteristics, kinetics, and possible mechanisms

G. Christou, R. H. Holm, T. Yamamura, 1983 .

Stabilization of reduced molybdenum-iron-sulfur single- and double-cubane clusters by cyanide ligation.

C. Berlinguette, R. H. Holm, R. Pesavento, 2007, Inorganic Chemistry.

Formation of bridged [4Fe-4S]2+ double cubanes by site-specific reactions: electron-transfer coupling across sulfur-containing bridges of variable length

M. Carney, R. H. Holm, T. Stack, 1989 .

Formation of Bridged (4Fe-4S)2+ Double Cubanes by Site-Specific Reactions: Electron-Transfer Coupling Across Sulfur-Containing Bridges of Variable Length.

M. Carney, R. H. Holm, T. Stack, 1989 .

SYNTHETIC ANALOGS OF THE 4‐FE ACTIVE SITES OF REDUCED FERREDOXINS. ELECTRONIC PROPERTIES OF THE TETRANUCLEAR TRIANIONS (FE4S4(SR)4)3‐ AND THE STRUCTURE OF ((C2H5)3(CH3)N)3(FE4S4(SC6H5)4)

R. Frankel, E. Laskowski, J. Ibers, 1978 .

Introduction: Bioinorganic enzymology II.

E. Solomon, R. H. Holm, 2014, Chemical reviews.

Synthesis and reactions of cubane-type iron-sulfur-phosphine clusters, including soluble clusters of nuclearities 8 and 16.

R. H. Holm, Hong‐Cai Zhou, 2003, Inorganic chemistry.

Initial structure modification of tetrahedral to planar nickel(II) in a nickel-iron-sulfur cluster related to the C-cluster of carbon monoxide dehydrogenase.

P. Venkateswara Rao, Yugen Zhang, R. H. Holm, 2004, Journal of the American Chemical Society.

Synthetic nickel-containing heterometal cubane-type clusters with NiFe3Q4 cores (Q = sulfur, selenium)

S. Ciurli, M. J. Scott, R. H. Holm, 1992 .

Initial members of the family of molecular mid-valent high-nuclearity iron nitrides: [Fe4N2X10]4- and [Fe10N8X12]5- (X = Cl-, Br-).

R. H. Holm, E. L. Bominaar, E. Münck, 2005, Journal of the American Chemical Society.

Metal Ion Incorporation Reactions of the Cluster [Fe3S4(LS3)]3-, Containing the Cuboidal [Fe3S4]0 Core

J. W. Raebiger, R. H. Holm, Jian Zhou, 1997 .

Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters.

R. H. Holm, Wayne Lo, Sonny C. Lee, 2014, Chemical reviews.

Synthetic analogues of the active sites of iron-sulfur proteins.

R. H. Holm, Pallem Venkateswara Rao, 2004, Chemical reviews.

CHAPTER 7 – Synthetic Analogues of the Active Sites of Iron–Sulfur Proteins*

J. Ibers, R. H. Holm, 1977 .

Nuclear resonance studies of vanadium(III) complexes. III. Synthesis, stereochemistry, and electron delocalization properties of tris(salicylaldehydes) and tris(salicylaldimines)

R. H. Holm, R. Ernst, F. Roehrscheid, 1967 .

Spectroscopic and electronic structure studies of symmetrized models for reduced members of the dimethylsulfoxide reductase enzyme family.

B. Lim, R. H. Holm, M. Kirk, 2008, Journal of the American Chemical Society.