S. Hashimoto

发表

A novel lithium iodide-promoted vinylcyclopropane-cyclopentene rearrangement: Efficient synthesis of bicyclo[3.3.0]oct-6-en-2-one, versatile building block for polycyclopentanoid natural products

S. Ikegami, S. Hashimoto, T. Shinoda, 1986 .

Asymmetric syntheses of diarylheptanoid natural products (-)-centrolobine and (-) -de-O-methylcentrolobine via hetero-Diels-Alder reaction catalyzed by dirhodium(II) tetrakis[(R)-3-(benzene -fused -phthalimido )-2-piperidinonate]

Takumi Abe, S. Hashimoto, Takuya Washio, 2007 .

Synthesis and Application of Thiocarbonyl Compounds

K. Sugimoto, H. Kameoka, S. Hashimoto, 1997 .

A total synthesis of (.+-.)-forskolin

S. Ikegami, S. Hashimoto, S. Sakata, 1988 .

Total synthesis and absolute stereochemistry of polygalolides A and B.

S. Hashimoto, Seiichi Nakamura, Yukihito Sugano, 2006, Angewandte Chemie.

A short, formal, biomimetic synthesis of (+/-)-polygalolides A and B.

B. Snider, S. Hashimoto, Seiichi Nakamura, 2007, Organic letters.

Continuous flow system with a polymer-supported dirhodium(II) catalyst: application to enantioselective carbonyl ylide cycloaddition reactions.

N. Shimada, S. Hashimoto, H. Nambu, 2011, Chemistry.

Synthesis of the Tetrasaccharide Repeating Unit from Acinetobacter baumannii Serogroup O18 Capitalizing on Phosphorus-Containing Leaving Groups.

S. Hashimoto, Kazuhiro Yamada, Seiichi Nakamura, 2015, The Journal of organic chemistry.

N-glycosylation with glycosyl diethyl phosphites: A highly stereoselective synthesis of 2′-deoxy-β-ribonucleosides

S. Hashimoto, M. Nakajima, H. Sakamoto, 1997 .

Synthesis and conformational properties of tetranitroazacalix[4]arenes

S. Hashimoto, Kazuhiro Kobayashi, H. Konishi, 2009 .

Chirally directed synthesis of (-)-methyl 5(S), 6(S)-oxido-7-hydroxyheptanoate, a key intermediate for the total synthesis of leukotrienes A, C, D and E

E. Corey, S. Hashimoto, A. Barton, 1981 .

Catalytic enantioselective C-H functionalization of indoles with α-diazopropionates using chiral dirhodium(II) carboxylates : asymmetric synthesis of the (+)-α-methyl-3-indolylacetic acid fragment of acremoauxin A

S. Hashimoto, Y. Natori, H. Nambu, 2011 .

Chemical and enzymic syntheses of 5-HPETE, a key biological precursor of slow-reacting substance of anaphylaxis (SRS), and 5-HETE

E. Corey, S. Hashimoto, A. Barton, 1980 .

A Facile Access to (R)-Methyl 2-Oxocyclopentane-1-acetate via Lipase-Catalyzed Irreversible Transesterification

S. Ikegami, Yoji Miyazaki, S. Hashimoto, 1992 .

Stereoselective synthesis of a C1–C6 fragment of pinnatoxin A via a 1,4-addition/alkylation sequence

S. Hashimoto, Seiichi Nakamura, Fumiaki Kikuchi, 2008 .

Total syntheses of zaragozic acids A and C by a carbonyl ylide cycloaddition strategy.

M. Shiro, S. Kitagaki, S. Hashimoto, 2006, Chemistry.

An extremely mild and stereocontrolled construction of 1,2-trans-β-glycosidic linkages capitalizing on benzyl-protected glycopyranosyl diethyl phosphites as glycosyl donors

S. Ikegami, S. Hashimoto, M. Nakajima, 1995 .

Enantioselective [2,3]-sigmatropic and [1,2]-Stevens rearrangements via intramolecular formation of allylic oxonium ylides catalyzed by chiral dirhodium(II) carboxylates

S. Kitagaki, S. Hashimoto, M. Anada, 2001 .

グリコシルジフェニルホスファートを用いる1,2-cis-α-グリコシド結合の立体選択的構築とα-ガラクトシルセラミド(KRN7000)の合成

S. Hashimoto, H. Nambu, Seiichi Nakamura, 2010 .

A highly stereoselective construction of 1,2-trans-β-glycosidic linkages capitalizing on 2-azido-2-deoxy-D-glycosyl diphenyl phosphates as glycosyl donors

S. Hashimoto, Seiichi Nakamura, Toshifumi Tsuda, 2004 .

Asymmetric Total Synthesis of (-)-Englerin A through Catalytic Diastereo- and Enantioselective Carbonyl Ylide Cycloaddition.

N. Shimada, S. Hashimoto, H. Nambu, 2015, Chemistry.

Double Asymmetric Induction in Intramolecular C-H Insertion Reactions of α-Diazo β-Keto Esters

S. Ikegami, S. Hashimoto, N. Watanabe, 1994 .

(S)-3,3‘-Dimethyl-2,2‘-biquinoline N,N‘-Dioxide as an Efficient Catalyst for Enantioselective Addition of Allyltrichlorosilanes to Aldehydes

M. Shiro, S. Hashimoto, M. Saito, 1998 .

Enantioselective tandem formation and [2,3]‐sigmatropic rearrangement of cyclic propargylic oxonium ylides catalyzed by dirhodium(II) tetrakis[N‐phthaloyl‐(S)‐tert‐leucinate]

S. Kitagaki, S. Hashimoto, M. Nakajima, 2001 .

Glycosylation using glucopyranosyl fluorides and silicon-based catalysts. Solvent dependency of the stereoselection

M. Hayashi, R. Noyori, S. Hashimoto, 1984 .

Simple synthesis of glycosyl fluorides

M. Hayashi, R. Noyori, S. Hashimoto, 1984 .

Enantiocontrol in tandem allylic sulfonium ylide generation and [2,3] sigmatropic rearrangement catalyzed by chiral dirhodium(II) complexes

S. Kitagaki, S. Hashimoto, M. Nakajima, 2001 .

Stereocontrolled syntheses and biological profiles of (±)-6,7-dideoxyforskolin and Its 13-epimer

S. Ikegami, S. Hashimoto, S. Sakata, 1991 .

Total Synthesis of Brasilicardins A and C.

S. Matsunaga, S. Hashimoto, M. Anada, 2017, Organic letters.

Enantioselective conjugate addition of thiols to enones and enals catalyzed by chiral N-oxide–cadmium complex

S. Hashimoto, M. Saito, M. Nakajima, 2000 .

Asymmetric transamination from amino acids (I) asymmetric synthesis of amino acid by chemical transamination from optically active amino acids to α-keto acid

S. Hashimoto, S. Yamada, 1976 .

Highly enantioselective hetero-Diels-Alder reactions between Rawal's diene and aldehydes catalyzed by chiral dirhodium(II) carboxamidates.

N. Shimada, S. Hashimoto, Takuya Washio, 2009, Chemical communications.

Enantioselective Conjugate Addition of Thiols to Cyclic Enones and Enals Catalyzed by Chiral N,N′-Dioxide–Cadmium Iodide Complex

S. Hashimoto, M. Saito, M. Nakajima, 2000 .

Enantioselective intramolecular CH insertion route to a key intermediate for the synthesis of trinem antibiotics

S. Hashimoto, M. Anada, S. Hashimoto*, 1998 .

Asymmetric synthesis of neolignans (-)-epi-conocarpan and (+)-conocarpan via Rh(II)-catalyzed C-H insertion process and revision of the absolute configuration of (-)-epi-conocarpan.

M. Shiro, S. Hashimoto, Y. Natori, 2009, The Journal of organic chemistry.

Asymmetric Diels–Alder reaction catalysed by chiral alkoxyaluminium dichloride

K. Koga, S. Hashimoto, N. Komeshima, 1979 .

Improvement of the photochemical reactivity of [Cu(dmp)P2]+ (dmp=2,9-dimethyl-1,10-phenanthroline; P=tertiary phosphine) by substituting PPh3 with larger phosphines: application to photoreduction of methylviologen

S. Sakaki, S. Hinokuma, S. Hashimoto, 1987 .

An Attempt at the Direct Construction of 2-Deoxy-β-glycosidic Linkages Capitalizing on 2-Deoxyglycopyranosyl Diethyl Phosphites as Glycosyl Donors

S. Ikegami, S. Hashimoto, M. Nakajima, 1995 .

A Stereocontrolled Construction of 2-Deoxy-β-glycosidic Linkages via 1,2-trans-β-Glycosidation of 2-Deoxy-2-[(p-methoxyphenyl)thio] glycopyranosyl N,N,N′,N′-Tetramethylphosphoroamidates

S. Ikegami, S. Hashimoto, Takeshi Honda, 1992 .

An Attempt at the Direct Construction of 2-Deoxy-β-glycosidic Linkages Capitalizing on 2-Deoxyglycopyranosyl Diethyl Phosphites as Glycosyl Donors.

S. Ikegami, S. Hashimoto, M. Nakajima, 1996 .

Glycoside Synthesis from 1‐Oxygen Substituted Glycosyl Donors: Sections 3.3 and 3.4

S. Hashimoto, K. S. Kim, H. Nambu, 2008 .

Enantioselective amination of silylketene acetals with (N-arylsulfonylimino)phenyliodinanes catalyzed by chiral dirhodium(II) carboxylates: asymmetric synthesis of phenylglycine derivatives

S. Hashimoto, Masahiko Tanaka, Takuya Washio, 2007 .

Asymmetric ring opening of meso-epoxides catalyzed by the chiral phosphine oxide BINAPO

S. Hashimoto, S. Kotani, M. Nakajima, 2005 .

Enantioselective ring opening of meso-epoxides with tetrachlorosilane catalyzed by chiral bipyridine N,N′-dioxide derivatives

S. Hashimoto, M. Saito, M. Nakajima, 2002 .

Enantio- and diastereoselective synthesis of cis-2-aryl-3-methoxycarbonyl-2,3-dihydrobenzofurans via the Rh(II)-catalyzed C-H insertion process.

S. Kitagaki, S. Hashimoto, M. Anada, 2002, Organic letters.

Practical synthesis of Dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate].

Takumi Abe, S. Hashimoto, M. Anada, 2005, Chemical & pharmaceutical bulletin.

Enhancement of enantioselectivity in intramolecular C-H insertion reactions of α-diazo β-keto esters catalyzed by chiral dirhodium(II) carboxylates

Tomohiro Sato, S. Ikegami, M. Shiro, 1993 .

Enantioselective Synthesis of 3-Arylindan-1-ones via Intramolecular C-H Insertion Reactions of α-Diazo-β-Ketoesters Catalyzed by Chiral Dirhodium(II) Carboxylates

S. Hashimoto, Y. Natori, H. Nambu, 2006 .

Catalytic asymmetric synthesis of 1,1'-spirobi[indan-3,3'-dione] via a double intramolecular C-H insertion process.

S. Kitagaki, S. Hashimoto, M. Nakajima, 2001, Chemical communications.

Enantio- and diastereoselective hetero-Diels-Alder reactions between 2-aza-3-silyloxy-1,3-butadienes and aldehydes catalyzed by chiral dirhodium(II) carboxamidates.

S. Hashimoto, Takuya Washio, M. Anada, 2012, Chemical communications.

Enantio- and diastereoselective hetero-Diels–Alder reactions between 4-methyl-substituted Rawal’s diene and aldehydes catalyzed by chiral dirhodium(II) carboxamidates: catalytic asymmetric synthesis of (−)-cis-aerangis lactone

N. Shimada, S. Hashimoto, M. Anada, 2014 .

Asymmetric michael reaction via chiral α,β-unsaturated aldimines

K. Koga, S. Hashimoto, N. Komeshima, 1977 .

Total synthesis of zaragozic acid C by an aldol-based strategy

S. Hashimoto, Seiichi Nakamura, Y. Hirata, 2005 .

Glycosylation with 2-Acetamido-2-deoxyglycosyl Donors at a Low Temperature: Scope of the Non-Oxazoline Method.

S. Hashimoto, Seiichi Nakamura, Ryoichi Arihara, 2015, The Journal of organic chemistry.

Enantioselective Michael additions of β-keto esters to α,β-unsaturated carbonyl compounds catalyzed by a chiral biquinoline N,N′-dioxide–scandium trifluoromethanesulfonate complex

S. Hashimoto, M. Nakajima, Seiichi Nakamura, 2003 .

A stereocontrolled construction of 2-azido-2-deoxy-1,2-cis-α-galactosidic linkages utilizing 2-azido-4,6-O-benzylidene-2-deoxygalactopyranosyl diphenyl phosphates: stereoselective synthesis of mucin core 5 and core 7 structures

N. Suzuki, S. Hashimoto, H. Nambu, 2012 .

Catalytic Asymmetric Wide Generation and Subsequent Transformation via Chiral Metal Carbene Intermediates

S. Kitagaki, S. Hashimoto, S. Hashimoto*, 2001 .

Asymmetric formal synthesis of (-)-pancracine via catalytic enantioselective C-H amination process

N. Shimada, S. Hashimoto, Masahiko Tanaka, 2009 .

Enantiocontrol in Tandem Carbonyl Ylide Formation and Intermolecular 1,3-Dipolar Cycloaddition of α-Diazo Ketones Mediated by Chiral Dirhodium(II) Carboxylate Catalyst

S. Kitagaki, S. Hashimoto, M. Anada, 1999 .

Enantioselective Synthesis of 4-Substituted 2-Pyrrolidinones by Site-selective C-H Insertion of α-Methoxycarbonyl-α-diazoacetanilides Catalyzed by Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]

S. Hashimoto, M. Anada, S. Hashimoto*, 1998 .

Enantioselective synthesis of binaphthol derivatives by oxidative coupling of naphthol derivatives catalyzed by chiral diamine-copper complexes

K. Koga, S. Hashimoto, Masahiro Noji, 1999 .

Catalytic enantioselective intermolecular cycloaddition of diazodiketoester-derived carbonyl ylides with indoles using chiral dirhodium(II) carboxylates.

N. Shimada, S. Hashimoto, H. Nambu, 2011, Organic letters.

Catalytic asymmetric synthesis of descurainin via 1,3-dipolar cycloaddition of a carbonyl ylide using Rh2(R-TCPTTL)4

N. Shimada, S. Hashimoto, H. Nambu, 2010 .

Catalytic asymmetric synthesis of the endo-6-aryl-8-oxabicyclo[3.2.1]oct-3-en-2-one natural product from Ligusticum chuanxing via 1,3-dipolar cycloaddition of a formyl-derived carbonyl ylide using Rh2(S-TCPTTL)4.

N. Shimada, M. Shiro, S. Hashimoto, 2010, The Journal of organic chemistry.

Catalytic enantioselective intermolecular cycloaddition of 2-diazo-3,6-diketoester-derived carbonyl ylides with alkynes and styrenes using chiral dirhodium(II) carboxylates.

N. Shimada, S. Hashimoto, H. Nambu, 2008, Organic letters.

Enantioselective intermolecular 1,3-dipolar cycloaddition via ester-derived carbonyl ylide formation catalyzed by chiral dirhodium(II) carboxylates

S. Kitagaki, S. Hashimoto, M. Anada, 2000 .

A Short, Catalytic, Asymmetric Synthesis of Diospongins A and B by a One-Pot, Sequential Hetero-Diels–Alder/Mukaiyama–Michael Reaction Process

S. Hashimoto, Takuya Washio, M. Anada, 2010 .

Highly Enantioselective Hetero-Diels—Alder Reactions Between Rawal′s Diene and Aldehydes Catalyzed by Chiral Dirhodium(II) Carboxamidates.

N. Shimada, S. Hashimoto, Takuya Washio, 2010 .

Catalytic asymmetric hetero-Diels–Alder route to a key intermediate for the synthesis of calyxin L

S. Hashimoto, Takuya Washio, H. Nambu, 2007 .

Highly Enantio- and Diastereoselective Construction of 1,2-Disubstituted Cyclopentane Compounds by Dirhodium(II) Tetrakis(N-phthaloyl-(S)-tert-leucinate)-Catalyzed C - H Insertion Reactions of α-Diazo Esters

Kazushi Minami, S. Hashimoto, H. Nambu, 2005 .

A new dirhodium(II) carboxamidate complex as a chiral Lewis acid catalyst for enantioselective hetero-Diels-Alder reactions.

N. Shimada, M. Shiro, S. Kitagaki, 2004, Angewandte Chemie.

Highly Enantioselective Intermolecular Cyclopropanation Catalyzed by Dirhodium(II) Tetrakis[3(S)-phthalimido-2-piperidinonate]: Solvent Dependency of the Enantioselection

S. Kitagaki, S. Hashimoto, N. Watanabe, 1997 .

Enantioselective SiH insertion of methyl phenyldiazoacetate catalyzed by dirhodium(II) carboxylates incorporating N-phthaloyl-(S)-amino acids as chiral bridging ligands

M. Kinoshita, S. Kitagaki, S. Hashimoto, 2000 .

Chiral phosphine oxide BINAPO as a lewis base catalyst for asymmetric allylation and aldol reaction of trichlorosilyl compounds

S. Hashimoto, S. Kotani, M. Nakajima, 2007 .

Chiral phosphine oxide BINAPO as a catalyst for enantioselective allylation of aldehydes with allyltrichlorosilanes

S. Hashimoto, S. Kotani, M. Nakajima, 2005 .

Selective synthesis of optically active allenic and homopropargylic alcohols from propargyl chloride

S. Hashimoto, M. Saito, M. Nakajima, 2002 .

Enantio-and diastereoselective desymmetrization of α-alkyl-α-diazoesters by dirhodium(II)-catalyzed intramolecular C–H insertion

S. Matsunaga, Kazushi Minami, S. Hashimoto, 2016 .

Diastereo- and enantioselective intramolecular 1,6-C–H insertion reactions of α-diazo esters catalyzed by chiral dirhodium(II) carboxylates

S. Hashimoto, H. Nambu, M. Anada, 2015 .

One-pot enantioselective synthesis of optically active homoallylic alcohols from allyl halides.

S. Hashimoto, M. Saito, M. Nakajima, 2000, Chemical & pharmaceutical bulletin.

Stereochemical aspects of asymmetric diels-alder reaction catalyzed by chiral alkoxyaluminum dichlorides

K. Tomioka, K. Koga, S. Hashimoto, 1987 .

Stereoselective Reactions. III. A highly Efficient Method for the Asymmetric Synthesis of 2-Alkylcycloalkanones via Chiral Chelated Lithioenamines

K. Koga, S. Hashimoto, 1979 .

Stereoselective Reactions. I. A highly Efficient Asymmetric Synthesis of β-Substituted Aldehydes via 1, 4-Addition of Grignard Reagents to optically Active α, β-Unsaturated Aldimines

K. Koga, S. Hashimoto, S. Yamada, 1979 .

Asymmetric synthesis of 2-substituted cycloalkanecarboxaldehydes

K. Tomioka, K. Koga, H. Kogen, 1979 .

Asymmetric synthesis of α-alkylated cyclic ketones via chiral chelated lithioenamines

K. Koga, S. Hashimoto, 1978 .

Enantioselective Conjugate Addition of Thiols to Cyclic Enones and Enals Catalyzed by Chiral N,N′‐Dioxide—Cadmium Iodide Complex.

S. Hashimoto, M. Saito, M. Nakajima, 2001 .

Enantioselective Michael addition of beta-keto esters to methyl vinyl ketone employing a chiral N,N'-dioxide-scandium trifluoromethanesulfonate complex as a catalyst.

S. Hashimoto, M. Nakajima, Y. Yamaguchi, 2001, Chemical communications.

A novel axially dissymmetric chiral ligand based on amine N-oxide: (R)- and (S)-3,3'-dimethyl-2,2'-biquinoline N,N'-dioxide

M. Shiro, S. Hashimoto, M. Nakajima, 1997 .

Enantioselective Intramolecular C-H Insertion Reactions of N-Alkyl-N-tert-Butyl-α-Methoxycarbonyl-α-Diazoacetamides Catalyzed by Dirhodium(II) Carboxylates: Catalytic, Asymmetric Construction of 2-Azetidinones

S. Ikegami, S. Hashimoto, M. Anada, 1994 .

Synthesis and evaluation of novel dirhodium(II) carboxylate catalysts with atropisomeric biaryl backbone

M. Shiro, S. Kitagaki, S. Hashimoto, 2003 .

Double Stereodifferentiation in Intramolecular C-H Insertion Reaction toward the Synthesis of 1b-Methylcarbapenem Antibiotics

S. Kitagaki, S. Hashimoto, M. Anada, 2000 .

Catalytic Enantioselective Synthesis of the Phosphodiesterase Type IV Inhibitor (R)-(-)-Rolipram via Intramolecular C-H Insertion Process

S. Kitagaki, S. Hashimoto, M. Anada, 1999 .

A polymer-supported chiral dirhodium(II) complex: highly durable and recyclable catalyst for asymmetric intramolecular C-H insertion reactions.

S. Hashimoto, H. Nambu, M. Anada, 2010, Angewandte Chemie.

Catalytic Enantioselective Aziridination of Alkenes Using Chiral Dirhodium(II) Carboxylates.

Takumi Abe, S. Hashimoto, Masahiko Tanaka, 2007 .

Enantioselective Intramolecular C—H Insertion Route to a Key Intermediate for the Synthesis of Trinem Antibiotics.

S. Hashimoto, M. Anada, 1999 .

Site-and Enantiocontrol in Intramolecular C-H Insertion Reactions of α-Diazo Carbonyl Compounds Catalyzed by Dirhodium (II) Carboxylates

S. Ikegami, S. Hashimoto, M. Anada, 1996 .

Highly Enantioselective Construction of the Key Azetidin‐2‐ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C—H Insertion Reactions of α‐Methoxycarbonyl‐α‐diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates.

S. Hashimoto, M. Anada, N. Watanabe, 1998 .

Asymmetric creation of quaternary carbon centers by enantiotopically selective aromatic C-H insertion catalyzed by chiral dirhodium(II) car☐ylates

S. Ikegami, M. Shiro, S. Hashimoto, 1995 .

Highly selective insertion into aromatic C-H bonds in rhodium(II) triphenylacetate-catalysed decomposition of α-diazocarbonyl compounds

S. Ikegami, S. Hashimoto, N. Watanabe, 1992 .

Bipyridine N,N′-Dioxide: A Felicitous Ligand for Methyltrioxorhenium-Catalyzed Epoxidation of Olefins with Hydrogen Peroxide

H. Iwamoto, S. Hashimoto, M. Nakajima, 1998 .

Chiral base-catalyzed aldol reaction of trimethoxysilyl enol ethers: effect of water as an additive on stereoselectivities

S. Hashimoto, M. Nakajima, T. Ishizuka, 2006 .

Toward the second-generation synthesis of zaragozic acids: Construction of the 2,8-dioxabicyclo[3.2.1]octane core system via tandem carbonyl ylide Formation and 1,3-dipolar cycloaddition sequence

J. Kobayashi, M. Shiro, S. Kitagaki, 1998 .

A controlled synthesis of α-(E)-1-alkenyl ketones from β-keto benzyl esters

S. Ikegami, Yoji Miyazaki, S. Hashimoto, 1989 .

Diastereoselective and enantioselective synthesis of 1,2-disubstituted cycloalkanecarboxaldehydes

K. Tomioka, K. Koga, H. Kogen, 1981 .

Asymmetric syntheses using tert-leucine. 1. An asymmetric synthesis of beta-substituted aldehydes via 1,4-addition of Grignard reagents to chiral alpha, beta-unsaturated aldimines.

K. Koga, S. Hashimoto, S. Yamada, 1976, Journal of the American Chemical Society.

Catalytic asymmetric synthesis of (−)-E-δ-viniferin via an intramolecular C–H insertion of diaryldiazomethane using Rh2(S-TFPTTL)4

Shunichi Hashimoto, S. Hashimoto, Y. Natori, 2015 .

Enantioselective cycloaddition of carbonyl ylides with arylallenes using Rh2(S-TCPTTL)4.

A. Yamano, S. Hashimoto, H. Nambu, 2013, Organic & biomolecular chemistry.

A regio- and stereocontrolled synthesis of (+)-isocarbacyclin via (1S,2R,5R)-bicyclo(3.3.0)oct-6-en-endo-2-ol.

S. Ikegami, S. Hashimoto, T. Shinoda, 1989 .

Synthesis of chiral building blocks for oxygenated terpenoids through a simultaneous and stereocontrolled construction of contiguous quaternary stereocenters by an Ireland-Claisen rearrangement.

S. Hashimoto, Hiroyuki Yamakoshi, Seiichi Nakamura, 2014, The Journal of organic chemistry.

Enantioselective aldol reaction of trimethoxysilyl enol ether catalyzed by lithium binaphtholate.

S. Hashimoto, M. Nakajima, T. Ishizuka, 2004, Organic letters.

Aerobic Oxidative Coupling of 2-Naphthol Derivatives Catalyzed by a Copper-Amine Complex without Solvent

K. Koga, S. Hashimoto, Masahiro Noji, 1998 .

Catalytic asymmetric synthesis of binaphthol derivatives by aerobic oxidative coupling of 3-hydroxy-2-naphthoates with chiral diamine-copper complex

Shunichi Hashimoto, S. Hashimoto, Makoto Nakajima, 1995 .

Enantioselective Aldol Reactions of Trichlorosilyl Enol Ethers Catalyzed by the Chiral Phosphine Oxide BINAPO

S. Hashimoto, S. Kotani, M. Nakajima, 2006 .

Asymmetric approach to the pentacyclic skeleton of Aspidosperma alkaloids via enantioselective intramolecular 1,3-dipolar cycloaddition of carbonyl ylides catalyzed by chiral dirhodium(II) carboxylates.

N. Shimada, S. Hashimoto, H. Nambu, 2009 .

Total synthesis of pinnatoxin A.

S. Hashimoto, Seiichi Nakamura, Fumiaki Kikuchi, 2008, Angewandte Chemie.

Direct and Stereoselective Synthesis of β-D-Mannosides Using 4,6-O-Benzylidene-Protected Mannosyl Diethyl Phosphite as a Donor.

Shinya Sato, S. Hashimoto, Seiichi Nakamura, 2005 .

A Stereocontrolled Construction of 2-Azido-2-deoxyβ-glycosidic Linkages Capitalizing on 2-Azido-2-deoxyglycopyranosyl Diphenyl Phosphates

S. Hashimoto, Seiichi Nakamura, Toshifumi Tsuda, 2003 .

Total syntheses of (+)-polygalolide a and (+)-polygalolide b: elucidation of the absolute stereochemistry and biogenetic implications.

S. Hashimoto, Seiichi Nakamura, Yukihito Sugano, 2012, Chemistry.

A new and general glycosidation method for podophyllum lignan glycosides

S. Ikegami, S. Hashimoto, Takeshi Honda, 1991 .

Direct and Stereoselective Synthesis of 2-Azido-2-deoxy-β-D-mannosides Using the Phosphate Method

N. Suzuki, S. Hashimoto, Seiichi Nakamura, 2009 .

A Practical Access to Optically Pure (S)-1-Octyn-3-ol

S. Ikegami, S. Hashimoto, Satoshi Kase, 1991 .

Catalytic stereoselective glycosidation with glycosyl diphenyl phosphates: rapid construction of 1,2-cis-alpha-glycosidic linkages.

S. Hashimoto, H. Nambu, Seiichi Nakamura, 2008, Chemistry, an Asian journal.

A rapid and efficient synthesis of 1,2-trans-β-linked glycosides via benzyl- or benzoyl-protected glycopyranosyl phosphates

S. Ikegami, S. Hashimoto, Takeshi Honda, 1989 .

Direct and stereoselective synthesis of 2-acetamido-2-deoxy-beta-D-glycopyranosides by using the phosphite method.

S. Hashimoto, Seiichi Nakamura, Ryoichi Arihara, 2005, Angewandte Chemie.

An extremely mild and stereocontrolled construction of 1,2-cis-α-glycosidic linkages via benzyl-protected glycopyranosyl diethyl phosphites

Hiroko Tanaka, S. Hashimoto, M. Nakajima, 1999 .

A total synthesis of (.+-.)-forskolin

S. Ikegami, S. Hashimoto, S. Sakata, 1988 .

Total synthesis and absolute stereochemistry of polygalolides A and B.

S. Hashimoto, Seiichi Nakamura, Yukihito Sugano, 2006, Angewandte Chemie.

Enantioselective Construction of a 2,8-Dioxabicyclo[3.2.1]octane Ring System via [2,3]-Sigmatropic Rearrangement of Oxonium Ylide Using Chiral Dirhodium(II) Carboxylates

N. Shimada, M. Shiro, S. Hashimoto, 2009 .

An easy preparation of triphenylmethyl carboxylates

M. Hayashi, R. Noyori, S. Hashimoto, 1984 .

Highly enantioselective cyclopropenation reaction of 1-alkynes with α-alkyl-α-diazoesters catalyzed by dirhodium(II) carboxylates.

N. Shimada, K. Ando, M. Shiro, 2011, Angewandte Chemie.

Catalytic Asymmetric Construction of the exo-7-Aryl-6,8-dioxabicyclo[3.2.1]octane Framework of Psoracorylifols B and C Using a Carbonyl Ylide Cycloaddition Strategy

N. Shimada, S. Hashimoto, H. Nambu, 2010 .

Catalytic Enantioselective Tandem Carbonyl Ylide Formation/1,3-Dipolar Cycloaddition Reactions of α-Diazo Ketones with Aromatic Aldehydes using Dirhodium(II) Tetrakis[N-benzene-fused-phthaloyl-(S)-valinate]

N. Shimada, Takumi Abe, S. Hashimoto, 2007 .

Stereoselective synthesis of the CDE ring system of antitumor saponin scillascilloside E-1.

S. Hashimoto, Hiroyuki Yamakoshi, Seiichi Nakamura, 2014, Organic letters.

Dirhodium(II) tetra(triphenylacetate): A highly efficient catalyst for the site-selective intramolecular C-H insertion reactions of α-Diazo β-Keto Esters

S. Ikegami, S. Hashimoto, N. Watanabe, 1992 .

Enantioselecitve intramolecular CH insertion of α-diazo [β-keto esters catalyzed by homochiral rhodium(II) carboxylates

S. Ikegami, S. Hashimoto, N. Watanabe, 1990 .

Total synthesis of the squalene synthase inhibitor zaragozic acid C by a carbonyl ylide cycloaddition strategy.

S. Kitagaki, S. Hashimoto, M. Anada, 2003, Angewandte Chemie.

Dirhodium(II) tetrakis[N-tetrafluorophthaloyl-(S)-tert-leucinate]: an exceptionally effective Rh(II) catalyst for enantiotopically selective aromatic C–H insertions of diazo ketoesters

S. Kitagaki, S. Hashimoto, M. Anada, 2003 .

“Armed-disarmed” glycosidation strategy based on glycosyl donors and acceptors carrying phosphoroamidate as a leaving group: A convergent synthesis of globotriaosylceramide

H. Abe, S. Ikegami, S. Hashimoto, 1997 .

Enantio- and diastereoselective cyclopropanation with tert-butyl α-diazopropionate catalyzed by dirhodium(II) tetrakis[N-tetrabromophthaloyl-(S)-tert-leucinate]

K. Ando, S. Hashimoto, M. Anada, 2011 .

Dirhodium(II) Tetrakis(perfluorobutyrate)-Catalyzed 1,4-Hydrosilylation of α,β-Unsaturated Carbonyl Compounds

S. Hashimoto, Masahiko Tanaka, H. Nambu, 2006 .

Catalytic Enantioselective Aziridination of Alkenes Using Chiral Dirhodium(II) Carboxylates.

Takumi Abe, S. Hashimoto, Masahiko Tanaka, 2007 .

Dirhodium(II) Tetrakis[N‐tetrachlorophthaloyl‐(S)‐tert‐leucinate]: A New Chiral Rh(II) Catalyst for Enantioselective Amidation of C—H Bonds.

S. Kitagaki, S. Hashimoto, M. Anada, 2003 .

Dirhodium(II) tetrakis[N-tetrachlorophthaloyl-(S)-tert-leucinate]: a new chiral Rh(II) catalyst for enantioselective amidation of CH bonds

S. Kitagaki, S. Hashimoto, M. Anada, 2002 .

Enantioselective Intramolecular C‐H Insertion of α‐Diazo β‐ Keto Esters Catalyzed by Homochiral Rhodium(II) Carboxylates.

S. Ikegami, S. Hashimoto, N. Watanabe, 1991 .

Highly enantioselective cyclopropenation reaction of 1-alkynes with α-alkyl-α-diazoesters catalyzed by dirhodium(II) carboxylates.

N. Shimada, K. Ando, M. Shiro, 2011, Angewandte Chemie.

Enantiocontrol in Tandem Carbonyl Ylide Formation and Intermolecular 1,3-Dipolar Cycloaddition of α-Diazo Ketones Mediated by Chiral Dirhodium(II) Carboxylate Catalyst.

S. Kitagaki, S. Hashimoto, M. Anada, 1999 .

Asymmetric Creation of Quaternary Carbon Centers by Enantiotopically Selective Aromatic C-H Insertion Catalyzed by Chiral Dirhodium(II) Carboxylates.

S. Ikegami, M. Shiro, S. Hashimoto, 1995 .

Total synthesis of 16-membered tetraene macrolide hygrolidin

N. Nakajima, S. Hashimoto, O. Yonemitsu, 1996 .

TOWARD THE TOTAL SYNTHESIS OF HYGROLIDIN : STEREOCONTROLLED CONSTRUCTION OF THE C1-C17 SECO-ACID FRAGMENT AND THE C18-C25 MASKED HEMIACETAL SUBUNIT

N. Nakajima, K. Kimura, S. Hashimoto, 1996 .

Oligosaccharide synthesis based on glycosyl donors and acceptors carrying phosphorus-containing leaving groups

S. Ikegami, S. Hashimoto, Takeshi Honda, 1997 .

An efficient construction of 1,2-trans-β-glycosidic linkages capitalizing on glycopyranosyl N,N,N′,N′-tetramethylphosphroamidates as shelf-stable glycosyl donors

S. Ikegami, S. Hashimoto, Takeshi Honda, 1992 .

AN EFFICIENT CONSTRUCTION OF 1, 2-TRANS-β-GLYCOSIDIC LINKAGES VIA BENZYL-PROTECTED GLYCOPYRANOSYL P, P-DIPHENYL-N-(p-TOLUENESULFONYL)-PHOSPHINIMIDATES

S. Ikegami, S. Hashimoto, Takeshi Honda, 1990 .

A stereocontrolled construction of 2-azido-2-deoxy-1,2-trans-β-glycosidic linkages utilizing 2-azido-2-deoxyglycopyranosyl diphenyl phosphates

S. Hashimoto, Seiichi Nakamura, Toshifumi Tsuda, 2003 .

Chemoselective glycosidation strategy based on glycosyl donors and acceptors carrying phosphorus-containing leaving groups: a convergent synthesis of ganglioside GM3

S. Hashimoto, Seiichi Nakamura, H. Sakamoto, 2000 .

Oligosaccharide Synthesis Based on Glycosyl Donors and Acceptors Carrying Phosphorus-Containing Leaving Groups.

S. Ikegami, S. Hashimoto, Takeshi Honda, 1997 .

Highly Selective Glycosidation Reactions Capitalizing on Phosphorus-containing Leaving Groups

S. Ikegami, S. Hashimoto, M. Nakajima, 1995 .

A Mild and Rapid 1,2-trans-Glycosidation Method via Benzoyl-protected Glycopyranosyl. P,P-Diphenyl-N-(p-toluenesulfonyl)phosphinimidates

S. Ikegami, S. Hashimoto, Takeshi Honda, 1990 .

An Efficient Construction of 1,2-trans-β-Glycosidic Linkages via Benzyl-Protected Glycopyranosyl P,P-Diphenyl-N-(p-toluenesulfonyl) phosphinimidates.

S. Ikegami, S. Hashimoto, Takeshi Honda, 1991 .

AN EXTREMELY MILD AND GENERAL METHOD FOR THE CONSTRUCTION OF 1, 2-TRANS-β-GLYCOSIDIC LINKAGES VIA GLYCOPYRANOSYL DIETHYL PHOSPHITES WITH PARTICIPATING GROUPS AT C-2

S. Ikegami, S. Hashimoto, M. Nakajima, 1995 .

A versatile and convenient method for the preparation of α-(Z)-1-alkenyl ketones from β-keto benzyl esters

S. Ikegami, Yoji Miyazaki, S. Hashimoto, 1990 .

Catalytic enantioselective amination of silyl enol ethers using chiral dirhodium(II) carboxylates: asymmetric formal synthesis of (-)-metazocine.

Takumi Abe, S. Hashimoto, Masahiko Tanaka, 2007, Organic letters.

Studies directed toward the total synthesis of pinnatoxin A: synthesis of the 6,5,6-dispiroketal (BCD ring) system by double hemiketal formation/hetero-Michael addition strategy

S. Hashimoto, M. Nakajima, Seiichi Nakamura, 2002 .

A practical process for large-scale synthesis of (S)-5-hydroxy-6-trans-8,11,14-cis-eicosatetraenoic acid (5-HETE)

E. Corey, S. Hashimoto, S. Hashimoto*, 1981 .

Total Synthesis of 6-Trans, 10-cis and (plus or minus) -6-Trans,8-cis Isomers of Leukotriene B

E. Corey, A. Marfat, S. Hashimoto, 1980 .

A New Access to Mori's Intermediate for the Practical Synthesis of (-)-Periplanone-B.

S. Ikegami, M. Shiro, Yoji Miyazaki, 1995 .

A Polymer‐Supported Chiral Fluorinated Dirhodium(II) Complex for Asymmetric Amination of Silyl Enol Ethers

S. Hashimoto, H. Nambu, M. Anada, 2012 .

CATALYTIC ASYMMETRIC INTERMOLECULAR C–H INSERTION OF 1,4-CYCLOHEXADIENE WITH α-ALKYL-α-DIAZOESTERS USING CHIRAL DIRHODIUM(II) CARBOXYLATES

S. Hashimoto, M. Anada, K. Takeda, 2012 .

A stereoselective synthesis of the C10-C31 (BCDEF ring) portion of pinnatoxin A.

S. Hashimoto, M. Nakajima, T. Sugimoto, 2001, Organic letters.

5-Substituted amino-3,6-dichloro-1,2,4-triazines as new potential herbicides

Y. Tanabe, Yoshinori Nakayama, H. Matsumoto, 1990 .

Products by the sphingosine kinase/sphingosine 1‐phosphate (S1P) lyase pathway but not S1P stimulate mitogenesis

A. Kihara, Y. Igarashi, Yong-Moon Lee, 2005, Genes to cells : devoted to molecular & cellular mechanisms.

Enantiocontrol in Tandem Allylic Sulfonium Ylide Generation and [2,3] Sigmatropic Rearrangement Catalyzed by Chiral Dirhodium(II) Complexes.

S. Kitagaki, S. Hashimoto, M. Nakajima, 2001 .

A highly stereoselective synthesis of the C10–C31 (BCDEF ring) portion of pinnatoxin A

S. Hashimoto, Seiichi Nakamura, T. Sugimoto, 2002 .

Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]: A Notable Catalyst for Enantiotopically Selective Aromatic Substitution Reactions of α-Diazocarbonyl Compounds

S. Ikegami, S. Hashimoto, N. Watanabe, 1996 .

Enantioselective intramolecular C-H insertion reactions of α-diazo β-keto esters catalyzed by dirhodium(II) tetrakis[N-phthaloyl-(S)-phenylalaninate] : the effect of the substituent at the insertion site on enantioselectivity

S. Ikegami, S. Hashimoto, N. Watanabe, 1994 .

Structural and thermodynamic analyses reveal critical features of glycopeptide recognition by the human PILRα immune cell receptor

N. Maeda, S. Matsunaga, T. Saitoh, 2017, The Journal of Biological Chemistry.

Chiral Phosphine Oxide BINAPO as a Lewis Base Catalyst for Asymmetric Allylation and Aldol Reaction of Trichlorosilyl Compounds.

S. Hashimoto, S. Kotani, M. Nakajima, 2007 .

Stereoselective Reactions. II. Asymmetric Synthesis of β-Substituted Aldehydes by Michael Reaction using Chiral α, β-Unsaturated Aldimines

K. Koga, S. Hashimoto, N. Komeshima, 1979 .