R. Knowles

发表

Total synthesis of diazonamide A.

I. Mangion, D. MacMillan, R. Knowles, 2011, Chemical science.

Enantioselective thiourea-catalyzed cationic polycyclizations.

E. Jacobsen, R. Knowles, Song Lin, 2010, Journal of the American Chemical Society.

Catalytic olefin hydroamination with aminium radical cations: a photoredox method for direct C-N bond formation.

R. Knowles, Andrew J. Musacchio, Lucas Q. Nguyen, 2014, Journal of the American Chemical Society.

Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis

Philip R. D. Murray, R. Knowles, Elizabeth A. McLoughlin, 2021, Chemical reviews.

Ion-pair reorganization regulates reactivity in photoredox catalysts

J. McCusker, G. Scholes, A. Zieleniewska, 2022, Nature Chemistry.

Bond-weakening catalysis: conjugate aminations enabled by the soft homolysis of strong N-H bonds.

David C. Miller, R. Knowles, Kyle T. Tarantino, 2015, Journal of the American Chemical Society.

Evaluation of excited state bond weakening for ammonia synthesis from a manganese nitride: stepwise proton coupled electron transfer is preferred over hydrogen atom transfer.

Lei Tian, G. Scholes, P. Chirik, 2019, Chemical communications.

Decarboxylative Intramolecular Arene Alkylation Using N-(Acyloxy)phthalimides, an Organic Photocatalyst, and Visible Light.

Hai-yun Xiao, E. Simmons, R. Knowles, 2019, The Journal of organic chemistry.

Synthetic Applications of Proton-Coupled Electron Transfer

Emily C. Gentry, R. Knowles, 2016 .

Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines

Xin Zhang, R. Knowles, Andrew J. Musacchio, 2017, Science.

Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer.

R. Knowles, Gilbert J. Choi, 2015, Journal of the American Chemical Society.

Catalytic ketyl-olefin cyclizations enabled by proton-coupled electron transfer.

P. Liu, R. Knowles, Kyle T. Tarantino, 2013, Journal of the American Chemical Society.

Enantioselective Hydroamination of Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer.

David E. Graff, R. Knowles, J. Demaerel, 2020, Journal of the American Chemical Society.

PCET-Enabled Olefin Hydroamidation Reactions with N-Alkyl Amides.

R. Knowles, Suong T T Nguyen, Qilei Zhu, 2019, ACS catalysis.

Catalytic C–N Bond-Forming Reactions Enabled by Proton-Coupled Electron Transfer Activation of Amide N–H Bonds

R. Knowles, Lucas Q. Nguyen, 2016 .

Photocatalytic Generation of Aminium Radical Cations for C─N Bond Formation.

Philip R. D. Murray, R. Knowles, Jacob M. Ganley, 2020, ACS catalysis.

PCET-Based Ligand Limits Charge Recombination with an Ir(III) Photoredox Catalyst.

T. Moore, A. Moore, G. Scholes, 2021, Journal of the American Chemical Society.

Rate-Driving Force Relationships in the Multisite Proton-Coupled Electron Transfer Activation of Ketones.

R. Knowles, Guanqi Qiu, 2019, Journal of the American Chemical Society.

Proton-Coupled Electron Transfer in Organic Synthesis: Novel Homolytic Bond Activations and Catalytic Asymmetric Reactions with Free Radicals

Hatice G. Yayla, R. Knowles, 2014, Synlett.

Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

David C. Miller, R. Knowles, Gilbert J. Choi, 2016, Nature.

Noncovalent Stabilization of Radical Intermediates in the Enantioselective Hydroamination of Alkenes with Sulfonamides.

M. Sigman, R. Knowles, Jacob Werth, 2022, Journal of the American Chemical Society.

Catalytic generation of alkoxy radicals from unfunctionalized alcohols

R. Knowles, Elaine Tsui, Huaiju Wang, 2020, Chemical science.

A Redox Strategy for Light-Driven, Out-of-Equilibrium Isomerizations and Application to Catalytic C-C Bond Cleavage Reactions.

R. Knowles, Eisuke Ota, Huaiju Wang, 2019, Journal of the American Chemical Society.

Catalytic Carbocation Generation Enabled by the Mesolytic Cleavage of Alkoxyamine Radical Cations.

Emily C. Gentry, R. Knowles, Qilei Zhu, 2016, Angewandte Chemie.

Ion-pair reorganization regulates reactivity in photoredox catalysts

J. McCusker, G. Scholes, A. Zieleniewska, 2022, Nature Chemistry.

Interference of nuclear wavepackets in a pair of proton transfer reactions

G. Scholes, R. Knowles, Kyra N Schwarz, 2022, Proceedings of the National Academy of Sciences of the United States of America.

Ir(III)-Naphthoquinone Complex as a Platform for Photocatalytic Activity

T. Moore, A. Moore, G. Scholes, 2021, Journal of Photochemistry and Photobiology.

Light-driven deracemization enabled by excited-state electron transfer

Scott J. Miller, Xin Zhang, R. Knowles, 2019, Science.

Catalytic Olefin Hydroamidation Enabled by Proton-Coupled Electron Transfer

David C. Miller, R. Knowles, Gilbert J. Choi, 2015, Journal of the American Chemical Society.

Attractive noncovalent interactions in asymmetric catalysis: Links between enzymes and small molecule catalysts

Eric N. Jacobsen, E. Jacobsen, Robert R. Knowles, 2010, Proceedings of the National Academy of Sciences.

Contra-Thermodynamic Positional Isomerization of Olefins.

R. Knowles, Kuo Zhao, 2021, Journal of the American Chemical Society.

Anti-Markovnikov Hydroamination of Unactivated Alkenes with Primary Alkyl Amines.

David C. Miller, W. R. Ewing, R. Knowles, 2019, Journal of the American Chemical Society.

Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities

David C. Miller, R. Knowles, Kyle T. Tarantino, 2016, Topics in Current Chemistry.

Catalytic Carbocation Generation Enabled by the Mesolytic Cleavage of Alkoxyamine Radical Cations.

Emily C. Gentry, R. Knowles, Qilei Zhu, 2016, Angewandte Chemie.

Synthetic Applications of Proton-Coupled Electron Transfer.

Emily C. Gentry, Robert R. Knowles, R. Knowles, 2016, Accounts of chemical research.

Enantioselective Photoredox Catalysis Enabled by Proton-Coupled Electron Transfer

David Y. Wang, Hatice G. Yayla, R. Knowles, 2016 .

C-H Alkylation via Multisite-Proton-Coupled Electron Transfer of an Aliphatic C-H Bond.

Z. S. Toa, L. Troian‐Gautier, R. Knowles, 2019, Journal of the American Chemical Society.

Intermolecular Anti-Markovnikov Hydroamination of Unactivated Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer.

David E. Graff, R. Knowles, Qilei Zhu, 2018, Journal of the American Chemical Society.

Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway.

Jeffrey F. Van Humbeck, D. MacMillan, R. Knowles, 2010, Journal of the American Chemical Society.

Catalytic Hydroetherification of Unactivated Alkenes Enabled by Proton-Coupled Electron Transfer.

A. J. Metrano, R. Knowles, Yuto Tsuchiya, 2020, Angewandte Chemie.

Catalytic Ring-Opening of Cyclic Alcohols Enabled by PCET Activation of Strong O-H Bonds.

Hatice G. Yayla, R. Knowles, Kyle T. Tarantino, 2016, Journal of the American Chemical Society.

Depolymerization of Hydroxylated Polymers via Light-Driven C-C Bond Cleavage.

B. Fors, R. Knowles, Elizabeth A. McLoughlin, 2021, Journal of the American Chemical Society.

Mechanistic Investigation and Optimization of Photoredox Anti-Markovnikov Hydroamination.

D. Nocera, R. Knowles, Rui Sun, 2021, Journal of the American Chemical Society.

Expeditious synthesis of aromatic-free piperidinium-functionalized polyethylene as alkaline anion exchange membranes†

Hsin-Yu Ko, W. You, Brian G Ernst, 2021, Chemical science.

Radical Redox Annulations: A General Light-Driven Method for the Synthesis of Saturated Heterocycles

Philip R. D. Murray, A. Doyle, R. Knowles, 2022, ACS catalysis.

Enantioselective Photoredox Catalysis Enabled by Proton‐Coupled Electron Transfer: Development of an Asymmetric Aza‐Pinacol Cyclization.

David Y. Wang, Hatice G. Yayla, R. Knowles, 2014 .

Intermolecular Crossed [2 + 2] Cycloaddition Promoted by Visible-Light Triplet Photosensitization: Expedient Access to Polysubstituted 2-Oxaspiro[3.3]heptanes.

L. Hamann, Philip R. D. Murray, Jacob T. Edwards, 2021, Journal of the American Chemical Society.

Discovery and mechanistic study of a photocatalytic indoline dehydrogenation for the synthesis of elbasvir† †Electronic supplementary information (ESI) available: Detailed experimental procedures and characterization data for all new compounds. See DOI: 10.1039/c5sc03350k

Ian W. Davies, Louis-Charles Campeau, Feng Peng, 2015, Chemical science.

N-H Bond Formation in a Manganese(V) Nitride Yields Ammonia by Light-Driven Proton-Coupled Electron Transfer.

P. Chirik, R. Knowles, Dian Wang, 2019, Journal of the American Chemical Society.

Enantioselective Synthesis of Pyrroloindolines via Noncovalent Stabilization of Indole Radical Cations and Applications to the Synthesis of Alkaloid Natural Products.

Emily C. Gentry, R. Knowles, R. Matsuura, 2018, Journal of the American Chemical Society.

Understanding Chemoselectivity in Proton-Coupled Electron Transfer: A Kinetic Study of Amide and Thiol Activation.

R. Knowles, Guanqi Qiu, 2019, Journal of the American Chemical Society.

Rate-Driving Force Relationships in the Multisite-PCET Activation of Ketones

R. Knowles, Guanqi Qiu, 2019 .

Radicals as Exceptional Electron-Withdrawing Groups: Nucleophilic Aromatic Substitution of Halophenols Via Homolysis-Enabled Electronic Activation.

G. Scholes, M. Bird, R. Knowles, 2022, Journal of the American Chemical Society.

Modelling the effects of confinement on the glass transition temperature and segmental mobility

D. Kranbuehl, R. Knowles, M. Hurt, 2003 .

Monte Carlo simulations of the effect of confinement geometry on the lowering of the glass transition temperature

D. Kranbuehl, R. Knowles, A. Hossain, 2002 .

Light-Driven Depolymerization of Native Lignin Enabled by Proton-Coupled Electron Transfer

Philip R. D. Murray, R. Knowles, Suong T. T. Nguyen, 2019, ACS Catalysis.

Dipole Moment and Charge Reorganization in Photoredox Catalysts

J. McCusker, G. Scholes, A. Zieleniewska, 2021 .

1,3‐Alkyl Transposition in Allylic Alcohols Enabled by Proton‐Coupled Electron Transfer

R. Knowles, Gesa Seidler, Kuo Zhao, 2021, Angewandte Chemie.

1,3-Alkyl Transposition in Allylic Alcohols Enabled by Proton-Coupled Electron Transfer.

R. Knowles, Gesa Seidler, Kuo Zhao, 2021, Angewandte Chemie.

Catalytic Ring Expansions of Cyclic Alcohols Enabled by Proton-Coupled Electron Transfer.

W. R. Ewing, P. Cheng, R. Knowles, 2019, Journal of the American Chemical Society.

Enantioselective Thiourea‐Catalyzed Cationic Polycyclizations.

E. Jacobsen, R. Knowles, Song Lin, 2010 .

Singly Reduced Iridium Chromophores: Synthesis, Characterization, and Photochemistry.

P. Jeffrey, G. Scholes, R. Knowles, 2023, Journal of the American Chemical Society.

Reversible Homolysis of a Carbon-Carbon σ-Bond Enabled by Complexation-Induced Bond-Weakening.

K. Houk, R. Knowles, Suhong Kim, 2022, Journal of the American Chemical Society.

Isotopic Fractionation as a Mechanistic Probe in Light-Driven C-H Bond Exchange Reactions.

R. Knowles, Guanqi Qiu, Chi-Li Ni, 2023, Journal of the American Chemical Society.

Chemical Recycling of Thiol Epoxy Thermosets via Light-Driven C-C Bond Cleavage.

Yuting Ma, B. Fors, R. Knowles, 2023, Journal of the American Chemical Society.

I. Davies, I. Mangion, M. McLaughlin, 2015, Chemical science.

Catalytic ketyl-olefin cyclizations enabled by proton-coupled electron transfer.

R. Knowles, Kyle T. Tarantino, Peng Liu, 2013, Journal of the American Chemical Society.

Catalytic Ring-Opening of Cyclic Alcohols Enabled by PCET Activation of Strong O-H Bonds.

Hatice G. Yayla, R. Knowles, Kyle T. Tarantino, 2016, Journal of the American Chemical Society.

Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway.

Jeffrey F. Van Humbeck, D. MacMillan, R. Knowles, 2010, Journal of the American Chemical Society.

Enantioselective photoredox catalysis enabled by proton-coupled electron transfer: development of an asymmetric aza-pinacol cyclization.

Hatice G. Yayla, R. Knowles, Lydia J Rono, 2013, Journal of the American Chemical Society.