D. Grotjahn

发表

Base-free transfer hydrogenation of aryl-ketones, alkyl-ketones and alkenones catalyzed by an IrIIICp* complex bearing a triazenide ligand functionalized with pyrazole

M. Parra-Hake, A. Rheingold, V. Miranda-Soto, 2020 .

Single bifunctional ruthenium catalyst for one-pot cyclization and hydration giving functionalized indoles and benzofurans.

A. Rheingold, D. Grotjahn, R. Nair, 2010, Chemistry.

A general bifunctional catalyst for the anti-Markovnikov hydration of terminal alkynes to aldehydes gives enzyme-like rate and selectivity enhancements.

D. Grotjahn, Daniel A. Lev, 2004, Journal of the American Chemical Society.

Understanding the performance of a bisphosphonate Ru water oxidation catalyst.

A. Poater, M. Solà, J. A. Luque‐Urrutia, 2020, Dalton transactions.

Effect of betaine in the successful synthesis of CoFe2O4 containing octahedron nanoparticles for electrocatalytic water oxidation

N. Arjona, A. Olivas, R. Valdez, 2017 .

Designing bifunctional alkene isomerization catalysts using predictive modelling

G. Rothenberg, A. Rheingold, D. Grotjahn, 2017 .

Azide Tripodal Dendrons from Behera's Amine and Their Clicked Dendrimers.

E. Wiener, D. Grotjahn, Marie-Caline Z. Abadjian, 2016, The Journal of organic chemistry.

Influence of Carbene and Phosphine Ligands on the Catalytic Activity of Gold Complexes in the Hydroamination and Hydrohydrazination of Alkynes

G. Bertrand, M. Gembicky, R. Jazzar, 2020 .

An Overview of Significant Achievements in Ruthenium-Based Molecular Water Oxidation Catalysis

D. Grotjahn, Jayneil M. Kamdar, 2019, Molecules.

How Do Proximal Hydroxy or Methoxy Groups on the Bidentate Ligand Affect [(2,2′;6′,2"‐Terpyridine)Ru(N,N)X] Water‐Oxidation Catalysts? Synthesis, Characterization, and Reactivity at Acidic and Near‐Neutral pH

Kristine J. Schroeder, A. Cooksy, A. Rheingold, 2014 .

Evolution of iridium-based molecular catalysts during water oxidation with ceric ammonium nitrate.

Derek B. Brown, K. Vecchio, A. Rheingold, 2011, Journal of the American Chemical Society.

Computational Study of the Extensive Role of Heterocyclic Ligands in Acetylene Hydration by a Bifunctional Organometallic Catalyst

A. Cooksy, D. Grotjahn, Amy J. Arita, 2013 .

Structures of Solvent-Free, Monomeric LiCCH, NaCCH, and KCCH.

M. A. Brewster, L. Ziurys, J. Xin, 1998, Angewandte Chemie.

THE PURE ROTATIONAL SPECTRUM OF LICH3(X 1A)

M. D. Allen, J. Robinson, L. Ziurys, 1998 .

First synthesis and structural determination of a monomeric, unsolvated lithium amide, LiNH(2).

P. M. Sheridan, L. Ziurys, P. Sheridan, 2001, Journal of the American Chemical Society.

Gas-phase synthesis, submillimeter spectra, and precise structure of monomeric, solvent-free CuCH3.

L. Ziurys, A. Cooksy, D. Halfen, 2004, Journal of the American Chemical Society.

Stable Singlet Carbenes as Organic Superbases.

G. Bertrand, R. Jazzar, D. Grotjahn, 2021, Angewandte Chemie.

Six-coordinate ruthenium water oxidation catalysts bearing equatorial polypyridinedicarboxylato and axial phosphine ligands

G. Bertrand, A. Rheingold, R. Jazzar, 2022, Polyhedron.

Stereoselective alkene isomerization over one position.

D. Grotjahn, Casey R. Larsen, 2012, Journal of the American Chemical Society.

Dynamic π-Bonding of Imidazolyl Substituent in a Formally 16-Electron Cp*Ru(κ2-P,N)+ Catalyst Allows Dramatic Rate Increases in (E)-Selective Monoisomerization of Alkenes

D. Pullman, A. Cooksy, A. Rheingold, 2019, ACS Catalysis.

Production and characterization of monoclonal anti-sphingosine-1-phosphate antibodies 1

M. Hiraiwa, D. Grotjahn, W. Shestowsky, 2010 .

Extensive isomerization of alkenes using a bifunctional catalyst: an alkene zipper.

D. Grotjahn, R. Nair, J. L. Gustafson, 2007, Journal of the American Chemical Society.

The Value and Application of Transition Metal Catalyzed Alkene Isomerization in Industry

D. Grotjahn, Casey R. Larsen, 2017 .

Bifunctional Organometallic Catalysis and Reactivity Using Heterocyclic Phosphines and Metallated Heterocycles

D. Grotjahn, 2010 .

Bifunctional organometallic catalysts involving proton transfer or hydrogen bonding.

D. Grotjahn, 2005, Chemistry.

A labile and catalytically active imidazol-2-yl fragment system.

A. Cooksy, A. Rheingold, J. Golen, 2011, Angewandte Chemie.

Enabling bifunctionality and hemilability of N-heteroaryl NHC complexes.

A. Rheingold, T. J. Dwyer, J. Golen, 2011, Chemistry.

Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.

M. Zeller, Elizabeth T. Papish, D. Grotjahn, 2017, Inorganica chimica acta.

Carbocyclizations employing 2-sily1-1,3-dithians

N. Andersen, D. Grotjahn, 1981 .

Effects of Hindrance in N-Pyridyl Imidazolylidenes Coordinated to Iridium on Structure and Catalysis

A. Rheingold, C. Moore, D. Grotjahn, 2013 .

Multimodal study of secondary interactions in Cp*Ir complexes of imidazolylphosphines bearing an NH group.

L. Zakharov, A. Cooksy, A. Rheingold, 2010, Journal of the American Chemical Society.

Studies of the synthesis and thermochemistry of coordinatively unsaturated chelate complexes (eta 5-C5Me5)IrL2 (L2 = TsNCH2CH2NTs, TsNCH2CO2, CO2CO2).

S. Nolan, D. Grotjahn, J. Dinoso, 2000, Inorganic chemistry.

Bifunctional Imidazolylphosphine Ligands as Hydrogen Bond Donors Promote N−H and O−H Activation on Platinum

L. Zakharov, A. Rheingold, D. Grotjahn, 2006 .

Structures, Mechanisms, and Results in Bifunctional Catalysis and Related Species Involving Proton Transfer

D. Grotjahn, 2010 .

Heteroatoms moving protons: Synthetic and mechanistic studies of bifunctional organometallic catalysis

D. Grotjahn, 2010 .

New flexible synthesis of pyrazoles with different, functionalized substituents at C3 and C5.

C. Meyer, D. Grotjahn, Lupe H. Mejorado, 2002, The Journal of organic chemistry.

One-Pot Formation of Functionalized Indole and Benzofuran Derivatives Using a Single Bifunctional Ruthenium Catalyst

D. Grotjahn, R. Nair, Paul Lee, 2010 .

Favoring alkene insertion over β-hydride elimination: aqueous media and ligands enable a double Heck reaction on a substrate for which β-hydride elimination is possible

Xiao-wei Zhang, D. Grotjahn, 1997 .

AQUEOUS MEDIA IN THE INTRAMOLECULAR HECK REACTION

Xiao-wei Zhang, D. Grotjahn, 1995 .

First direct structural comparison of complexes of the same metal fragment to ketenes in both C,C- and C,O-bonding modes.

L. Collins, D. Grotjahn, H. Lo, 2001, Journal of the American Chemical Society.

Combined Effects of Metal and Ligand Capable of Accepting a Proton or Hydrogen Bond Catalyze Anti-Markovnikov Hydration of Terminal Alkynes.

C. Incarvito, A. Rheingold, D. Grotjahn, 2001, Angewandte Chemie.

Imidazol-2-yl complexes of Cp*Ir as bifunctional ambident reactants.

A. Rheingold, V. Miranda-Soto, D. Grotjahn, 2008, Journal of the American Chemical Society.

An unprecedented propellane-to-spirofused skeletal rearrangement upon oxidative demetalation of cyclopentadienyl cobalt-complexed polycyclic dienes: synthesis of a pentacyclic, potential precursor to strychnine

K. Vollhardt, D. Grotjahn, 1990 .

Catalysis of Selective Hydrogen/Deuterium Exchange at Allylic Positions Using Deuterium Oxide

D. Grotjahn, Gulin Erdogan, 2010 .

Mild and selective deuteration and isomerization of alkenes by a bifunctional catalyst and deuterium oxide.

D. Grotjahn, Gulin Erdogan, 2009, Journal of the American Chemical Society.

Cationic Protic Imidazolylidene NHC Complexes of Cp*IrCl+ and Cp*RhCl+ with a Pyridyl Tether Formed at Ambient Temperature

A. Rheingold, D. Grotjahn, Jessica K. Martin, 2018 .

Synthesis, Characterization, Reactivity of η3-allylPd(L)(X), Where X = Cl and L = Imidazolylphosphine and Their Application in Aryl Amination Reactions

C. V. Niekerk, D. Grotjahn, R. Nair, 2014, Topics in Catalysis.

Bifunctional catalysts and related complexes: structures and properties.

D. Grotjahn, 2008, Dalton transactions.

Finding the proton in a key intermediate of anti-Markovnikov alkyne hydration by a bifunctional catalyst.

A. Cooksy, V. Miranda-Soto, D. Grotjahn, 2008, Journal of the American Chemical Society.

Hydrogen-bond acceptance of bifunctional ligands in an alkyne-metal pi complex.

A. Cooksy, Xi Zeng, V. Miranda-Soto, 2008, Journal of the American Chemical Society.

Experimental and Computational Study of the Transformation of Terminal Alkynes to Vinylidene Ligands on trans-(Chloro)bis(phosphine)Rh Fragments and Effects of Phosphine Substituents

A. Cooksy, A. Rheingold, Xi Zeng, 2007 .

Effects of the heterocycle and its substituents on structure and fluxionality in rhodium(I) and iridium(I) complexes with the hindered thiolates 6-tert-butylpyridine-2-thiolate and 1-alkyl-4-tert-butylimidazole-2-thiolate (alkyl = methyl and tert-butyl)

F. Lahoz, M. Parra-Hake, L. Oro, 2006 .

Changes in coordination of sterically demanding hybrid imidazolylphosphine ligands on Pd(0) and Pd(II).

L. Zakharov, A. Rheingold, J. Golen, 2006, Journal of the American Chemical Society.

Formation and Structure of Coordinatively Unsaturated CpIr-Amino Acid Complexes. Kinetic and Thermodynamic Control in Highly Diastereoselective Complexation Reactions

T. Groy, D. Grotjahn, 1995 .

Isomerization and Hydrogenation of Alkenes

D. Grotjahn, Erik R. Paulson, 2017 .

The use of metalloids (-SiMe3,-SnR3) as protected carbanions

N. Andersen, T. Sarkar, D. McCrae, 1981 .

Cobalt-mediated [2+2+2] cycloaddition of alkynes to the enamine double bond : a formal total synthesis of γ-lycorane

K. Vollhardt, D. Grotjahn, 1993 .

General catalyst control of the monoisomerization of 1-alkenes to trans-2-alkenes.

D. Grotjahn, Casey R. Larsen, Gulin Erdogan, 2014, Journal of the American Chemical Society.

7.3 – Transition Metal Alkyne Complexes: Transition Metal-catalyzed Cyclotrimerization

D. Grotjahn, 1995 .

Bifunctional Catalyst Control of Alkene Isomerization

D. Grotjahn, Casey R. Larsen, Gulin Erdogan, 2014, Topics in Catalysis.

Arene-selective peptide and protein derivatization

D. Grotjahn, 1999 .

Hydrogen-bonding pincer complexes with two protic N-heterocyclic carbenes from direct metalation of a 1,8-bis(imidazol-1-yl)carbazole by platinum, palladium, and nickel.

A. Rheingold, J. Golen, C. Moore, 2015, Chemistry.

CONTROLLED OXIDATIVE ADDITION OF AMINO ACID ESTERS TO RH(I)

D. Grotjahn, D. Combs, C. Joubran, 1999 .

Activated Aminocarbene Complexes of the Fischer Type: Synthesis, Structure, and Annelation Reactions

K. Harms, D. Grotjahn, K. Dötz, 1989 .

New Insights on Kinetic Versus Thermodynamic Ratios in Catalyzed Alkene Isomerization

D. Grotjahn, Casey R. Larsen, 2010 .

Supported imidazolylphosphine catalysts for highly (E)-selective alkene isomerization.

D. Grotjahn, Gulin Erdogan, 2014, Organic letters.

Highly Stereoselective Formation of Cp*IrCl Complexes of N,N-Dimethylamino Acids

D. Grotjahn, J. L. Hubbard, C. Joubran, 1996 .

Substituent control of hydrogen bonding in palladium(II)-pyrazole complexes.

C. Incarvito, C. Meyer, A. Rheingold, 2003, Inorganic chemistry.

Synthesis and structure of isomeric palladium(II)-pyrazole chelate complexes with and without an N-H group as hydrogen bond donor.

G. Aguirre, D. Grotjahn, F. Ortéga, 2000, Inorganic chemistry.

Rh(III)Cp* and Ir(III)Cp* Complexes of 1-[(4-Methyl)phenyl]-3-[(2-methyl-4′-R)imidazol-1-yl]triazenide (R = t-Bu or H): Synthesis, Structure, and Catalytic Activity

G. Aguirre, M. Parra-Hake, A. Rheingold, 2019, Organometallics.

Synthesis and Reactivity of Bis(protic N-heterocyclic carbene)iridium(III) Complexes

M. Parra-Hake, A. Rheingold, V. Miranda-Soto, 2016 .

A Facile, Convenient, and Green Route to (E)-Propenylbenzene Flavors and Fragrances by Alkene Isomerization

D. Grotjahn, Erik R. Paulson, Casey R. Larsen, 2015, Synlett.

Oxidative addition of the c-o bond of amino acid esters to Rh(I) forming chelating acyl complexes

D. Grotjahn, C. Joubran, 2004 .

Double C-H activation during functionalization of phenyl(methyl)ketene on iridium(I) using alkynes. synthesis of 1,4-dien-3-ones.

D. Grotjahn, J. L. Hubbard, Justin M. Hoerter, 2004, Journal of the American Chemical Society.

Synthesis and characterization of 5H-1,3-dioxolo[4,5-f]indoleethylamines

D. Grotjahn, 1983 .

Facile Oxidative Addition of Rhodium(I) to the Acyl-Oxygen Bond of 2-((Diphenylphosphino)methyl)quinolin-8-ol Acetate

D. Grotjahn, C. Joubran, 1995 .

Hydrogen bonding in the crystal structure of bis[3-([thiomethyl]methyl)pyrazole]copper(II) perchlorate.

A. Rheingold, W. S. Kassel, D. Grotjahn, 2001, Journal of inorganic biochemistry.

Coordination of chiral amines to coordinatively unsaturated Cp∗Ir-amino acid complexes allows determination of enantiomeric purity

D. Grotjahn, C. Joubran, 1995 .

Structure of Solvent-Free, Monomeric CH3Li and CH3Na

Lucy M Ziurys, Douglas B. Grotjahn, L. Ziurys, 1997 .

Formation of Coordinatively Unsaturated Cp*Ir-Amino Acid Complexes and Their Highly Diastereoselective Complexation Reactions

T. Groy, D. Grotjahn, 1994 .

Combined Effects of Metal and Ligand Capable of Accepting a Proton or Hydrogen Bond Catalyze Anti-Markovnikov Hydration of Terminal Alkynes The support of San Diego State University is acknowledged.

C. Incarvito, A. Rheingold, D. Grotjahn, 2001, Angewandte Chemie.

Approaches to the synthesis of (+/-)-strychnine via the cobalt-mediated [2 + 2 + 2] cycloaddition: rapid assembly of a classic framework.

K. Vollhardt, M. J. Eichberg, D. Grotjahn, 2001, Journal of the American Chemical Society.

Cobalt-mediated [2 + 2 + 2] cycloadditions of alkynes to the indole 2,3-double bond: an extremely facile entry into the novel 4a,9a-dihydro-9H-carbazole nucleus

K. Vollhardt, D. Grotjahn, 1986 .

Synthesis and crystal structure of an iridium complex containing the novel electron-poor hybrid monoanionic ligand Ph2PCF2PO2(OiPr)

J. Bailey, D. Grotjahn, D. Sattler, 2022, Polyhedron.

Alkyne-to-vinylidene transformation on trans-(Cl)Rh(phosphine)2: acceleration by a heterocyclic ligand and absence of bimolecular mechanism.

A. Cooksy, Xi Zeng, D. Grotjahn, 2006, Journal of the American Chemical Society.

(CAAC)Copper Catalysis Enables Regioselective Three-Component Carboboration of Terminal Alkynes.

G. Bertrand, Yang Gao, K. Engle, 2022, ACS catalysis.

X-ray crystallography and electrochemistry reveal electronic and steric effects of phosphine and phosphite ligands in complexes RuII(κ4-bda)(PR3)2 and RuII(κ3-bda)(PR3)3 (bda = 2,2′-bipyridine-6,6′-dicarboxylato)

A. Rheingold, D. Grotjahn, S. Yazdani, 2019, Polyhedron.

Carbene Complexes of Chromium Bearing Nitrogen Substituents

D. Grotjahn, K. Doetz, 1992 .

Chiral Recognition and Resolution Mediated by π−π Interactions: Synthesis and X-ray Structure of trans-[(Sp,Sp)-bis(Cp*Ru)-carbazolyl][Δ-Trisphat]†

H. Amouri, K. Boubekeur, D. Grotjahn, 2004 .

Iridium and Ruthenium Complexes of N-Heterocyclic Carbene- and Pyridinol-Derived Chelates as Catalysts for Aqueous Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation: The Role of the Alkali Metal

C. E. Webster, Elizabeth T. Papish, Fengrui Qu, 2017, Organometallics.

Sequential Alkene Isomerization and Ring-Closing Metathesis in Production of Macrocyclic Musks from Biomass.

K. Grela, D. Grotjahn, Gwénaël Forcher, 2018, Chemistry.

A One-Pot Tandem Olefin Isomerization/Metathesis-Coupling (ISOMET) Reaction

R. Schrock, D. Grotjahn, Graham E. Dobereiner, 2014 .

Controlled, Reversible Conversion of a Ketene Ligand to Carbene and CO Ligands on a Single Metal Center

A. Rheingold, L. Collins, D. Grotjahn, 2000 .

Psychotomimetic N-methyl-N-isopropyltryptamines. Effects of variation of aromatic oxygen substituents.

D. Grotjahn, D. B. Repke, A. Shulgin, 1985, Journal of medicinal chemistry.

PLGA nanoparticle-mediated delivery of tumor antigenic peptides elicits effective immune responses

C. Ozkan, M. Bouvet, T. Ichim, 2012, International journal of nanomedicine.

Production and characterization of monoclonal anti-sphingosine-1-phosphate antibodies1

M. Hiraiwa, D. Grotjahn, W. Shestowsky, 2009, Journal of Lipid Research.

Reactions of complex ligands. 45. (Acylamino)carbene complexes: synthesis, structure, and reactivity

K. Harms, D. Grotjahn, T. Schaefer, 1992 .

Synthesis of CH3K in the Gas Phase: Structural and Mechanistic Trends for Monomeric, Unsolvated CH3M and HCCM (M = Li, Na, K)

Lucy M Ziurys, Douglas B. Grotjahn, L. Ziurys, 2000 .

Bifunctional Chelates Optimized for Molecular MRI

L. Vander Elst, E. Wiener, A. Rheingold, 2014, Inorganic chemistry.

Origins of High Kinetic (E)-Selectivity in Alkene Isomerization by a CpRu(PN) Catalyst: a Combined Experimental and Computational Approach

A. Cooksy, D. Grotjahn, T. Cao, 2020 .

High Arenophilicity and Water Tolerance in Direct Derivatization of Peptides and Proteins by Metal π-Coordination

D. Brune, D. Grotjahn, C. Joubran, 1998 .

Ruthenium Complexes of 2,2′‐Bipyridine‐6,6′‐diphosphonate Ligands for Water Oxidation

A. Rheingold, C. Moore, D. Grotjahn, 2016 .

Nanosheets of Co-(Ni and Fe) Layered Double Hydroxides for Electrocatalytic Water Oxidation Reaction

A. Olivas, R. Valdez, J. M. Quintana, 2014 .

Cyclic(Alkyl)(Amino)Carbene Ligands Enable Cu-Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes.

G. Bertrand, Yang Gao, K. Engle, 2021, Angewandte Chemie.

Synthesis of the Electron-Poor Dicationic Arene Complex [Cp*Ir(η6-p-bis(difluoromethyl)benzene)][BF4]2and Ring Attack by Hydroxide in Attempted Deprotonation: Synthesis, Structures, and C−H···F Hydrogen Bonding

M. Rager, H. Amouri, K. Boubekeur, 2008 .

A Binding Pocket for Coordinated Water Formed by the Metal Center and Two Heterocyclic Nitrogens in Chelating Bis-thioethers of the Complexes {Cp*M[Im‘S(CH2)2SIm‘](H2O)}2+ (M = Rh, Ir; Im‘ = 1-alkyl-4-tert-butylimidazol-2-yl)

M. Parra-Hake, V. Miranda-Soto, D. Grotjahn, 2005 .

Unexpected synthesis and structural characterization of Pt(II)Cl2-1,5-hexadiene from reaction of allyl chloride and K2PtCl4

A. Rheingold, J. Golen, D. Grotjahn, 2010 .

An Active‐Site Sulfonate Group Creates a Fast Water Oxidation Electrocatalyst That Exhibits High Activity in Acid

Gregory I. Elliott, D. Musaev, J. Niklas, 2020, Angewandte Chemie.

An Active-Site Sulfonate Group Creates a Fast Water Oxidation Electrocatalyst That Exhibits High Activity in Acid.

Gregory I. Elliott, D. Musaev, J. Niklas, 2020, Angewandte Chemie.

Reactivity of η2-(C,O)-Bound Ir−Ketene Complexes: A 1,3-Hydride Shift Is a Hydride Walk by Way of an Enol Complex

D. Grotjahn, H. Lo, 1996 .

The first precise molecular structure of a monomeric transition metal cyanide, copper(I) cyanide.

Lucy M Ziurys, M. A. Brewster, L. Ziurys, 2002, Journal of the American Chemical Society.

Catalyst versus Substrate Control of Forming (E)-2-Alkenes from 1-Alkenes Using Bifunctional Ruthenium Catalysts

A. Cooksy, D. Grotjahn, Erik R. Paulson, 2018, Organic Process Research & Development.

Stable Singlet Carbenes as Organic Superbases

G. Bertrand, D. Grotjahn, F. Vermersch, 2021, Angewandte Chemie.

Evolution of iridium-based molecular catalysts during water oxidation with ceric ammonium nitrate.

Derek B. Brown, K. Vecchio, A. Rheingold, 2011, Journal of the American Chemical Society.

A Fluorinated Dendrimer-Based Nanotechnology Platform: New Contrast Agents for High Field Imaging

Archana Nigam, E. Wiener, Douglas M Potter, 2010, Investigative radiology.

Bifunctional Chelates Optimized for Molecular MRI

L. Vander Elst, E. Wiener, A. Rheingold, 2014, Inorganic chemistry.