Marc-André Légaré

发表

Reducing CO2 to Methanol using Frustrated Lewis Pairs: On the Mechanism of Phosphine- Borane Mediated Hydroboration of CO2

Fontaine, Marc-André Courtemanche, L. Maron, 2018 .

Theoretical Calculations for Highly Selective Direct Heteroarylation Polymerization: New Nitrile-Substituted Dithienyl-Diketopyrrolopyrrole-Based Polymers

S. Beaupré, M. Leclerc, O. Ibraikulov, 2018, Molecules.

New Fluorinated Dithienyldiketopyrrolopyrrole Monomers and Polymers for Organic Electronics

S. Beaupré, M. Leclerc, Yuning Li, 2017 .

Fluorinated Thiophene-Based Synthons: Polymerization of 1,4-Dialkoxybenzene and Fluorinated Dithieno-2,1,3-benzothiadiazole by Direct Heteroarylation

S. Beaupré, M. Leclerc, I. Hill, 2017 .

Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes.

Haopeng Gao, H. Braunschweig, Marc-André Légaré, 2017, Chemistry.

Reversible hydrogen activation by a bulky haloborane based FLP system.

Etienne Rochette, Marc-André Courtemanche, Frédéric-Georges Fontaine, 2016, Dalton transactions.

Synthesis of Carboxylate Cp*Zr(IV) Species: Toward the Formation of Novel Metallocavitands.

Jean‐François Morin, Frédéric-Georges Fontaine, Marc-André Légaré, 2015, Inorganic chemistry.

Metal-free catalytic C-H bond activation and borylation of heteroarenes

Etienne Rochette, Marc-André Courtemanche, Frédéric-Georges Fontaine, 2015, Science.

Direct heteroarylation polymerization: guidelines for defect-free conjugated polymers† †Electronic supplementary information (ESI) available. CCDC 1507660 and 1507661. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00589j Click here for additional data file.

S. Beaupré, M. Leclerc, Yuning Li, 2017, Chemical science.

Synthesis of unsymmetrical B2E2 and B2E3 heterocycles by borylene insertion into boradichalcogeniranes

A. Hofmann, H. Braunschweig, Marc-André Légaré, 2019, Chemical science.

The reductive coupling of dinitrogen

M. Holthausen, H. Braunschweig, I. Krummenacher, 2019, Science.

Cooperative Reactivity of Boron-Containing Molecules and Lewis Bases for Metal Free Catalysis

Marc-André Légaré, 2015 .

Intramolecular B/N frustrated Lewis pairs and the hydrogenation of carbon dioxide.

D. Stephan, Etienne Rochette, Marc-André Courtemanche, 2015, Chemical communications.

Hydroboration of Carbon Dioxide Using Ambiphilic Phosphine–Borane Catalysts: On the Role of the Formaldehyde Adduct

D. Bourissou, Marc-André Courtemanche, Frédéric-Georges Fontaine, 2015 .

A tris(triphenylphosphine)aluminum ambiphilic precatalyst for the reduction of carbon dioxide with catecholborane

Marc-André Courtemanche, Frédéric-Georges Fontaine, L. Maron, 2013 .

Design principles in frustrated lewis pair catalysis for the functionalization of carbon dioxide and heterocycles

Etienne Rochette, Marc-André Courtemanche, Frédéric-Georges Fontaine, 2017 .

Heterodiatomic Multiple Bonding in Group 13: A Complex with a Boron-Aluminum π Bond Reduces CO2.

A. Hofmann, H. Braunschweig, Marc-André Légaré, 2019, Angewandte Chemie.

Silylosmium Anions for the Synthesis of Borylosmium(II) Complexes by Salt Elimination

H. Braunschweig, Marc-André Légaré, Alexander Matler, 2016 .

2,2'-Bipyridyl as a Redox-Active Borylene Abstraction Agent.

H. Braunschweig, Marc-André Légaré, Theresa Dellermann, 2020, Inorganic chemistry.

Reducing CO₂ to methanol using frustrated Lewis pairs: on the mechanism of phosphine-borane-mediated hydroboration of CO₂.

Marc-André Courtemanche, Frédéric-Georges Fontaine, L. Maron, 2014, Journal of the American Chemical Society.

A highly active phosphine-borane organocatalyst for the reduction of CO2 to methanol using hydroboranes.

Laurent Maron, Marc-André Courtemanche, Frédéric-Georges Fontaine, 2013, Journal of the American Chemical Society.

Transition-metal-carbene-like intermolecular insertion of a borylene into C-H bonds.

A. Hofmann, H. Braunschweig, Marc-André Légaré, 2020, Chemical communications.

Synthesis and Reactivity of Novel Mesityl Boratabenzene Ligands and Their Coordination to Transition Metals

Frédéric-Georges Fontaine, Marc-André Légaré, Wenhua Bi, 2014 .

Reactivity of a Cl-boratabenzene Pt(II) complex with Lewis bases: generation of the kinetically favoured Cl-boratabenzene anion.

Frédéric-Georges Fontaine, L. Maron, Marc-André Légaré, 2011, Dalton transactions.

The First Boron-Tellurium Double Bond: Direct Insertion of Heavy Chalcogens into a Mn=B Double Bond.

A. Hofmann, H. Braunschweig, Marc-André Légaré, 2017, Angewandte Chemie.

Phosphazenes: efficient organocatalysts for the catalytic hydrosilylation of carbon dioxide.

Etienne Rochette, Marc-André Courtemanche, Frédéric-Georges Fontaine, 2015, Chemical communications.

Bench-stable frustrated Lewis pair chemistry: fluoroborate salts as precatalysts for the C-H borylation of heteroarenes.

Etienne Rochette, Frédéric-Georges Fontaine, Marc-André Légaré, 2016, Chemical communications.

Lewis base activation of borane-dimethylsulfide into strongly reducing ion pairs for the transformation of carbon dioxide to methoxyboranes.

Marc-André Courtemanche, Frédéric-Georges Fontaine, Marc-André Légaré, 2014, Chemical communications.

Transition-metal-free catalytic reduction of carbon dioxide.

Marc-André Courtemanche, Frédéric-Georges Fontaine, Marc-André Légaré, 2014, Chemistry.

A Boradiselenirane and a Boraditellurirane: Isolable Heavy Analogs of Dioxiranes and Dithiiranes.

A. Hofmann, H. Braunschweig, Marc-André Légaré, 2018, Journal of the American Chemical Society.

Nitrogen fixation and reduction at boron

Rian D. Dewhurst, B. Engels, H. Braunschweig, 2018, Science.

Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron.

H. Braunschweig, K. Radacki, I. Krummenacher, 2017, Journal of the American Chemical Society.

Metal‐Free Catalytic C—H Bond Activation and Borylation of Heteroarenes.

Etienne Rochette, Marc-André Courtemanche, Frédéric-Georges Fontaine, 2015 .

Insights into the formation of borabenzene adducts via ligand exchange reactions and TMSCl elimination from boracyclohexadiene precursors

G. Robillard, Frédéric-Georges Fontaine, L. Maron, 2014 .

The Future of Scientific Leadership is Interdisciplinary: The 2019 CAS Future Leaders Share Their Vision

Connor W. Coley, Aisha N. Bismillah, Cassandra E. Callmann, 2020, iScience.

One-pot, room-temperature conversion of dinitrogen to ammonium chloride at a main-group element

Rian D. Dewhurst, H. Braunschweig, I. Krummenacher, 2020, Nature Chemistry.

Towards the catalytic activation of inert small molecules by main-group ambiphiles

Rian D. Dewhurst, H. Braunschweig, Marc-André Légaré, 2020, Communications Chemistry.

Achieving Control over the Reduction/Coupling Dichotomy of N2 by Boron Metallomimetics.

H. Braunschweig, Marc-André Légaré, Merle Arrowsmith, 2023, Journal of the American Chemical Society.

Metal-free catalytic C-H bond activation and borylation of heteroarenes

Etienne Rochette, Marc-André Courtemanche, Marc-André Légaré, 2015, Science.

Reversible hydrogen activation by a bulky haloborane based FLP system.

Etienne Rochette, Marc-André Courtemanche, Marc-André Légaré, 2016, Dalton transactions.

Lewis base activation of borane-dimethylsulfide into strongly reducing ion pairs for the transformation of carbon dioxide to methoxyboranes.

Marc-André Courtemanche, Marc-André Légaré, Frédéric‐Georges Fontaine, 2014, Chemical communications.