M. Galakhov

发表

Effect of substituents on the13C chemical shift of polyfluorinated olefins and allyl cations substituted in position 1

V. Bakhmutov, M. Galakhov, B. A. Kvasov, 1989 .

Polyfluorinated anions and cations — Intermediates in reactions of fluorine-containing vinyl ethers

V. Bakhmutov, V. Petrov, M. Galakhov, 1986 .

Synthesis of 5- and 3-(hydroxyhexafluoroprop-2-yl)-1-(β-D-glucopyranosyl)indoles

A. Fokin, M. Galakhov, N. D. Chkanikov, 1986 .

Synthesis of Hydride Tantalabenzocyclopentene and µ‐Alkylidene Complexes by Direct Alkylation Reactions of [TaCp*Cp′Cl2] − NMR Spectroscopic Study and X‐ray Crystal Structure of [TaCp*Cp′(H)(η2‐CH2‐CMe2‐o‐C6H4)], (Cp* = η5‐C5Me5; Cp′ = η5‐C5H4SiMe3)

P. Gómez-Sal, Avelino Martín, Manuel Gómez, 2002 .

Monocyclopentadienyl Bis(phenoxo-imino) Zirconium Complexes as Precatalyst Species for Olefin Polymerization. Stereospecific Methylation of an Imino Group with Formation of a Zirconium-amido Bond

M. Bochmann, S. Lancaster, A. Grassi, 2004 .

(Alkyl)‐ and (Alkyl)(alkylidene)(pentamethylcyclopentadienyl)tantalum Complexes

P. Gómez-Sal, Manuel Gómez, M. Galakhov, 2006 .

Redox-rotational phenomena in organometallic chemistry. Unique features of the crystal structure and stereodynamic behaviour of acetylacetonato- and cyclopentadienylrhodium complexes with potentially dipolar two-ring semiquinoid ligands in solution

V. I. Rozenberg, V. Bakhmutov, E. Stepanova, 1988 .

Insertion of Isocyanide into Metal−Carbon Bonds of Alkylchloro(pentamethylcyclopentadienyl)niobium- and -tantalum Complexes − X-ray Structure of [TaCp*Cl2(CH2CMe2Ph){η2-C(CH2CMe2Ph)=N(2,6-Me2C6H3)}] and Unexpected Decomposition of Alkyldichloro(η2-iminoacyl) Complexes of Tantalum

P. Gómez-Sal, Avelino Martín, Manuel Gómez, 2000 .

Half-sandwich dichloro, alkyl chloro, dialkyl, alkyl methyl and amido methyl imido cyclopentadienyl niobium and tantalum(V) complexes. Dynamic behaviour of amido imido tantalum derivatives

Manuel Gómez, M. Galakhov, A. Castro, 1999 .

Construction of Heterometallic Cubanes [{Ti3Cp*3(μ3‐CR)}(μ3‐O)3{Mo(CO)3}] (R=H, Me; Cp*=η5‐C5Me5) and [{Ti3Cp*3(μ3‐N)}(μ3‐NH)3{M(CO)3}] (M=Cr, Mo, W); Crystal Structure of [{Ti3Cp*3(μ3‐CMe)}(μ3‐O)3{Mo(CO)3}]

P. Gómez-Sal, Avelino Martín, J. Poblet, 2000 .

2 Routes of substitutional fluorination of [2.2]paracyclophane under the action of XeF2 - conservation of the initial macrocycle or its contraction

V. I. Rozenberg, V. Kharitonov, M. Galakhov, 1990 .

S-anions from 2,2,4,4-tetrakis(Trifluoromethyl)-1,3-dithietane and their reactions

M. Galakhov, Y. Zeifman, S. A. Postovoi, 1989 .

Reaction of 1,1-dicyano-2,2-bis(trifluoromethyl)ethylene with arylamines

A. Fokin, M. Galakhov, N. D. Chkanikov, 1990 .

The first three aromatic tribromides of the [2.2]paracyclophane series

V. I. Rozenberg, V. Kharitonov, M. Galakhov, 1992 .

Amalgam (Na.Hg) reduction of some 4‐Substituted‐2‐amino‐3,5‐dicyano‐6‐methoxypyridines. New evidence regarding the oxidation step in their synthesis

M. Galakhov, C. Marquez, M. Lorenzo, 1999 .

Reactions of polyfluorocarbonyl compounds with 1,3,3-trimethyl-3,4-dihydroisoquinoline and its derivatives

V. Shklyaev, M. Galakhov, V. D. Sviridov, 1990 .

Pentamethylcyclopentadienyl halo- and alkyl-alkoxo tantalum(V) complexes. Crystal structure of TaCp*(CH2SiMe3) 2{η2-O(2-CH2-6-MeC6H3)}

P. Gómez-Sal, Avelino Martín, Manuel Gómez, 1996 .

Dinuclear cationic zirconium complexes with the fulvalene ligand. Synthesis and reactivity

M. Bochmann, M. Galakhov, P. Royo, 1997 .

Steric effects of ortho substituents in reactions of phenols and phenolates with polyfluoroketones

A. Fokin, V. Dyachenko, M. Galakhov, 1989 .

Alkyl–η2-alkene niobocene and tantalocene complexes with the allyldimethylsilyl–η5-cyclopentadienyl ligand: synthesis, NMR studies and DFT calculations

H. Jacobsen, O. Blacque, H. Berke, 2004 .

Neutral and cationic di(tert-butyl) cyclopentadienyl titanium, zirconium and hafnium complexes dynamic NMR study of the ligand-free cations [M(1,3-tBu2-η5-C5H3)(η5-C5H5)(CH3)]+ (M = Zr, Hf)

P. Gómez-Sal, M. Galakhov, P. Royo, 1997 .

Thermal Decomposition of (Pentamethylcyclopentadienyl)titanium(IV) Complexes Containing Dialkylamido Ligands – X‐ray Structure of [{η5:η2‐C5Me4CH2CH2N(Me)CN(C6H3Me2)}TiCl2]

P. Gómez-Sal, Avelino Martín, M. Galakhov, 1998 .

Reactivity of vinyl and alkynyl zirconium complexes with the di-ansa-[1,1′,2,2′-bis(dimethylsilanediyl) dicyclopentadienyl] ligand

M. Galakhov, P. Royo, F. J. Fernández, 2000 .

Hydride derivatives of Group 4 metals with the ansa-( SiMe2)2(η5-C5H3)2 ligand

M. Galakhov, P. Royo, T. Cuenca, 1996 .

A Versatile Synthetic Route for Cyclopentadienyl−Amido Titanium(IV) Compounds. NMR Spectroscopy Study and X-ray Molecular Structure of [Ti{η5-C5H4SiMe2NMe(CH2)2-η-NMe}Cl2]

P. Gómez-Sal, E. Rodríguez, M. Galakhov, 2001 .

Reactivity of the dinuclear fulvalene cyclopentadienyl zirconium cationic species [{Zr(η5-C5H5)}2(μ-CH2)(μ-Cl)(μ-η5-C5H4-η5-C5H4)]+ with isocyanides and carbon monoxide: insertion reactions, spectroscopic characterization and synthetic aspects

M. Galakhov, P. Royo, T. Cuenca, 2001 .

Esters of trifluorovinylphosphonic acid

M. Galakhov, A. Kadyrov, E. M. Rokhlin, 1988 .

Reactivity ofμ3-Alkylidyne Groups on an Organotitanium Oxide: Insertion of Isocyanides and Carbon Monoxide into the Complexes [{TiCp*(μ-O)}3(μ3-CR)] (R=H, Me)

Avelino Martín, C. Santamaría, M. Galakhov, 1998 .

Chemical behaviour of alkyl imido cyclopentadienyl niobium and tantalum(V) complexes in insertion processes. X-ray crystal structures of [MCpCl(NAr){η2-C(Me)NAr}] (Ar=2,6-Me2C6H3; M=Nb, Cpη5-C5H4SiMe3; M=Ta, Cp=η5-C5Me5) and [Ta(η5-C5Me5)Me(NAr){η2-C(CH2CMe2Ph)O}] (Ar=2,6-Me2C6H3)

P. Gómez-Sal, Avelino Martín, Manuel Gómez, 2000 .

Synthesis of Novel Mono(pentamethylcyclopentadienyl)tantalacycloalkyl and -tantalacycloalkylidene Complexes. Crystal Structure of [TaCp*Cl2{η3-C6H4(2-CH2NMeCH2)}]

Manuel Gómez, M. Galakhov, P. Royo, 1996 .

Insertion of Isocyanides into Tantalum-Carbon Bonds of Azatantalacyclopropane Complexes. Crystal Structures of TaCp*Cl3(.eta.2-NRCMe2CNHR), TaCp*Me(NR)(NRCMe:CMe2), and TaCp*Me(NR)(.eta.2-NR:CCMe2CMe:NR) (R = 2,6-Me2C6H3)

Manuel Gómez, M. Pellinghelli, M. Galakhov, 1995 .

Synthesis and Dynamic Behavior of (Pentamethylcyclopentadienyl)azatantalacyclopropane Complexes. Crystal Structures of TaCp*Cl4[C(Me)(NHR)] and TaCp*Me2(.eta.2-Me2CNR)

Manuel Gómez, M. Pellinghelli, M. Galakhov, 1995 .

Synthesis, electrosynthesis and structural studies of bis(silylcyclopentadienyl) niobium complexes with acetylene ligands

A. Otero, A. Antiñolo, M. Fajardo, 1994 .

Insertion of CNAr into Ta-Me bonds of TaCp*ClnMe4-n (n=0-3) : intramolecular rearrangements, dynamic behavior, and X-ray crystal structure of TaCp*Cl2(NAr) (Ar=2,6-Me2C6H3)

Manuel Gómez, M. Pellinghelli, M. Galakhov, 1994 .

Reactions of hexafluoroacetone benzenesulfonyl- and trifluoroacetylimines with arylamines

A. Fokin, M. Galakhov, N. D. Chkanikov, 1989 .

Silver and copper salts of α,β-unsaturated perfluorocarboxylic acids in decarboxylation reactions

E. I. Mysov, M. Galakhov, S. Sterlin, 1989 .

Intramolecular coordination of an alkene to a mixed dicyclopentadienyl benzyl zirconium cation studied by NMR spectroscopy

M. Galakhov, 1998 .

Fulvalene titanium and zirconium complexes: synthesis and NMR study of phosphanido-, alkyl-, and alkynyl-derivatives. X-ray crystal structures of [{Ti(η5−C5H5)(μ−PPH2)}2{μ−(η5−C5H4−η5−C5H4)}] and [{Zr(η5−C5H5)(μ−C≡CSiMe3)}2{μ−(η5−C5H4−η5−C5H4)}]

M. Convery, M. Galakhov, C. Cardin, 1995 .

Transfer Hydrogenation Processes to μ3‐Alkylidyne Groups on the Organotitanium Oxide [Ti3Cp$\rm{^{{\ast}}_{3}}$O3]

Avelino Martín, C. Santamaría, M. Galakhov, 2002 .

Construction of Heterometallic Cubanes [{Ti3Cp(μ3‐CMe)}(μ3‐O)3{Mo(CO)3}]

P. Gómez-Sal, Avelino Martín, J. Poblet, 2000 .

Insertion of Terminal and Internal Acetylenes into the Zr−μ-Methylene Bond of the Dinuclear Cationic Zirconium Complex [{Zr(η5-C5H5)}2(μ-CH2)(μ-Cl)(μ-η5-C5H4-η5-C5H4)][BMe(C6F5)3]. Synthetic Aspects, NMR Spectroscopic Study, and Dynamic Behavior in Solution

M. Galakhov, T. Cuenca, Eva Royo, 2000 .

μ-Benzyl and μ-Chloro Dinuclear Cationic Titanium Compounds

M. Galakhov, T. Cuenca, Gerardo Jiménez, 2001 .

Synthetic and NMR Studies of Neutral and Cationic Dinuclear Fulvalene Zirconium Complexes Containing the “Zr2(μ-CNtBu)” Unit

M. Galakhov, T. Cuenca, Eva Royo, 2000 .

Synthesis of bis (tert-butyl)cyclopentadienyl derivatives of titanium and zirconium. NMR spectra and dynamic behaviour of the base-free [Zr(1,3-tBu2-η5-C5H3)(CH2Ph)2]+ cation

M. Galakhov, P. Royo, T. Cuenca, 1995 .

Electrochemical Oxidation of α-Bromoketones into Esters

M. Galakhov, Sergey K. Feducovich, F. Barba, 1995 .

1H and 13C NMR study of low-energy intramolecular transformations of coordinated propargyl cations [(μ-η2-η3-HCCCR1R2)Cp2Mo2(CO)4]+BF4−

V. Bakhmutov, M. Galakhov, O. Reutov, 1991 .

Synthesis via amine elimination and characterization of new heterobimetallic complexes containing the (pentamethylcyclopentadienyl) titanium(IV) moiety

Avelino Martín, M. Galakhov, M. Mena, 1995 .

[2.2]Paracyclophane as a model for the construction of “perpendicular” styrene

V. I. Rozenberg, V. Kharitonov, M. Galakhov, 1990 .

Alkyl chloro, dialkyl and mixed alkyl derivatives of imido(pentamethylcyclopentadienyl) tantalum(V).

P. Gómez-Sal, Avelino Martín, Manuel Gómez, 1998 .

13C CP‐MAS NMR spectra and fluxional behaviour of [M2(ηHCCCMe2)(CO)4(ηC5H5)2]+ [BF4]− (M = Mo, W) complexes in the solid state

V. Bakhmutov, M. Galakhov, I. Barinov, 1991 .

α,β-unsaturated fluorine-containing thiocyanates

E. I. Mysov, M. Galakhov, V. K. Osmanov, 1990 .

Reaction of polyhalodisulfides with hexaethylphosphorus triamide

M. Galakhov, I. L. Knunyants, V. Popkova, 1989 .

NMR structural and dynamic study of a carbenium ion with a steroidal substituent [Mo2Cp2(CO)4(.mu.-HC:CC19H24O]+BF4-

V. Sokolov, C. Cordier, G. Jaouen, 1991 .

Cyclopentadienyl dithiocarbamate and dithiophosphate molybdenum and tungsten complexes

P. Gómez-Sal, M. Pellinghelli, M. Galakhov, 1999 .

Reaction of acetic anhydride with monoterpene amine oxides possessing the 2,7-dimethyloctane skeleton

M. Galakhov, E. A. Petrushkina, L. Zakharkin, 1993 .

Dependence of the through-space19F-19F spin-spin coupling constant on the internuclear distance for polyfluorinated allyl cations

Yu. A. Borisov, V. Bakhmutov, N. Raevskii, 1987 .

Through‐space 19F,19F spin—spin coupling constants in some fluoroallyl cations

V. Bakhmutov, M. Galakhov, E. I. Fedin, 1985 .

NMR Spectroscopy of Polyfluorinated Allyl Cations

V. Bakhmutov, M. Galakhov, 1988 .

Electrophilic isomerization of fluoroaliphatic oxygen-containing compounds

E. I. Mysov, M. Galakhov, A. F. Aérov, 1991 .

Fluorinated ketones in the Baylis-Hillman reaction

A. Fokin, M. Galakhov, A. F. Kolomiets, 1992, Bulletin of the Russian Academy of Sciences Division of Chemical Science.

Bis-α-hydrohexafluoroisobutyrates and bis-pentafluoromethacrylates

E. I. Mysov, M. Galakhov, E. M. Rokhlin, 1989 .

Electrophilic isomerization of substituted perfluorocyclopropanes under the effect of SbF5

V. Petrov, E. I. Mysov, M. Galakhov, 1990 .

The fluoroacylation of diamines

A. Fokin, L. T. Zhuravlev, M. Galakhov, 1981 .

19F NMR spectra and structure for pentafluorophenyl-substituted analogs of the perfluoroallyl cation

V. Bakhmutov, V. Petrov, M. Galakhov, 1989 .

Structure and13C AND19F NMR spectra of 1-substituted analogs of perfluoromethallyl cation

V. Bakhmutov, V. Petrov, M. Galakhov, 1986 .

Relative stability of 1-substituted perfluoromethallyl cations according to19F NMR data

V. Bakhmutov, V. Petrov, M. Galakhov, 1986 .

Influence of a substituent at the 2 position on the stability of fluorine-containing allyl cations according to19F NMR spectroscopy data

V. Bakhmutov, V. Petrov, M. Galakhov, 1986 .

19F AND13C NMR spectra of perfluoroallyl cation and its analogs

V. Bakhmutov, V. Petrov, M. Galakhov, 1985 .

NMR spectra of the perfluoro-2-methallyl cation

V. Bakhmutov, V. Petrov, M. Galakhov, 1984 .

19F NMR spectrum of perfluoropentadienyl cation, and calculation of its geometry by the LCAO MO method in the indo approximation

Yu. A. Borisov, V. Bakhmutov, V. Petrov, 1986 .

Theoretical investigation of polyfluorinated allyl cations

Yu. A. Borisov, V. Bakhmutov, M. Galakhov, 1986 .

Reactions of hexafluoroisopropylimines with indole

A. Fokin, M. Galakhov, N. D. Chkanikov, 1985 .

The condensation of methyl trifluoropyruvate with carbonyl compounds

A. Fokin, M. Galakhov, A. F. Kolomiets, 1989 .

An unusual reaction of 1,1-dicyano-2,2-bis(trifluoromethyl)ethylene

A. Fokin, M. Galakhov, N. D. Chkanikov, 1988 .

Non-chair conformation of cis isomers of 1,4-disubstituted perfluorocyclohexanes

M. Galakhov, K. Makarov, L. Gervits, 1987 .

Reaction of ketones with the organotitanium oxide [{TiCp*(µ-O)}3(µ3-CMe)] via the hydride–vinylidene [{TiCp*(µ-O)}3(µ-CCH2)(H)] intermediate‡

C. Santamaría, M. Galakhov, M. Mena, 1998 .