J. Vila

发表

Cyclometallated [C,N,O] Complexes as Metalloligands: Synthesis and Structural Characterisation of New Di-, Tri-, Tetra- and Pentanuclear Heterometallic Complexes

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2009 .

Synthesis and Characterization of Pyrrolthiosemicarbazone Complexes of Palladium(II). Crystal Structures of [{Pd[C4H4NC(H)=NNC(S)NHMe](Cl)}2{μ‐Ph2P(CH2)3PPh2}] and[Pd{C4H4NC(H)=NNC(S)NHMe}{Ph2P(CH2)2PPh2‐P, P}](Cl)

Javier Martínez, Alberto Fernández, J. Vila, 2005 .

Novel Cyclometallated Complexes Derived From a Halogenated Thiosemicarbazone. Crystal and Molecular Structures of 2‐FC6H4C(Me)=NN(H)C(=S)NHPh and[(Pd{2‐FC6H3C(Me)=NN=C(S)NHPh})2(μ‐PPh2(CH2)2PPh2)]

Javier Martínez, Jesús J Fernández, J. Vila, 2005 .

Cyclometallated complexes of Pd(II) with heterobidentate P, As and P, N coordinating ligands

Jesús J Fernández, Alberto Fernández, M. López-Torres, 2003 .

Nucleophilic addition of 1,3-dicarbonyl compounds as a route to functionalized cyclopalladated complexes with chelated 1,1-bis(diphenylphosphino)ethene

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2002 .

The First Crystal and Molecular Structure of asyn-Acetato-Bridged Dinuclear Cyclometallated Complex [Pd{2,3,4-(MeO)3C6HC(H)=NCH2CH2OH}(μ-OAc)]2

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2002 .

Cyclometallated compounds of palladium(II) with diphosphines. The X-ray crystal structure of [{Pd[2,3,4-(MeO)3C6HC(H)NCy]}2- (μ-Ph2PC(CH2)PPh2)Cl2]

H. Adams, Jesús J Fernández, J. Vila, 1994 .

Imine Palladacycles: Synthesis, Structural Analysis and Application in Suzuki–Miyaura Cross Coupling in Semi-Aqueous Media

J. Vila, J. Ortigueira, L. A. Adrio, 2022, Molecules.

Palladacycle catalysis: an innovation to the Suzuki-Miyaura cross-coupling reaction.

H. Adams, Jesús J Fernández, J. Vila, 2016, Dalton transactions.

Activation of C–H and C–Br bonds in cyclopalladation reactions of Schiff base ligands: Influence of the benzylidene ring substituents

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2008 .

Tetranuclear Complexes of PdII with Tridentate [C,N,O] and [O,N,O] Ligands: Synthesis, Reactivity and Structural Isomerism

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2007 .

A new series of lanthanide complexes with the trans-disubstituted Py2[18]aneN6 macrocyclic ligand: synthesis, structures and properties

C. Nuñez, J. Vila, R. Bastida, 2019, Polyhedron.

Synthesis and crystal structure analysis of ferrocenylthiosemicarbazone complexes of palladium(II): Unusual σPd–C bond cleavage

Jesús J Fernández, J. Vila, J. Antelo, 2006 .

Novel palladacycle N-heterocyclic carbene complexes with bidentate [C,N] and terdentate [C,N,N] and [C,N,O] Schiff bases. Synthesis, characterization and crystal structure analysis

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2014 .

Crystal packing in a solvent-free or chloroform-solvated dinuclear platinum(III) organometallic complex

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2011 .

Reactivity of C(sp2)-Pd and C(sp3)-Pd bonded palladacycles with diphosphines. Crystal and molecular structure of the novel A-frame complex [{Pd[2,5-Me2C6H2C(H)N(2,4,6-Me3C6H2)-C6]}2(μ-Ph2PCH2PPh2)2(μ-Cl)][PF6]

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2011 .

Cyclometallated complexes derived from pyrimidin- and pyridazinehydrazones: Structural evidence of intermolecular “chelate metal ring” π–π interactions

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2009 .

Synthesis, characterization and solid state structures of thiosemicarbazone palladacycles: Influence of hydrogen bonding in the molecular arrangement

Javier Martínez, M. López-Torres, J. Vila, 2006 .

Cyclometallated thiosemicarbazone palladium(II) compounds: The first crystal and molecular structures of mononuclear complexes with a η1-diphosphine ligand

Javier Martínez, Jesús J Fernández, Alberto Fernández, 2006 .

Reactivity of cyclometallated palladium(II) compounds derived from N-(benzylidene)xylylendiamines

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2002 .

Sterically controlled reactivity of palladium(ii) tetranuclear cyclometallated complexes. Crystal and molecular structure of the novel tetranuclear compound [Pd2{1,3-[C(H)NCH2C4H7O]2C6H2}(µ-Cl)(Cl)(PPh3)]2Electronic supplementary information (ESI) available: 1H and 31P NMR data for compounds 1–15 an

Jesús J Fernández, Alberto Fernández, M. López-Torres, 2002 .

Cyclopalladated compounds derived from (C,N,O) terdentate ligands: synthesis, characterization and reactivity

Jesús J Fernández, Alberto Fernández, M. López-Torres, 2002 .

Cyclopalladated compounds derived from a [C,N,S] terdentate ligand: synthesis, characterization and reactivity. Crystal and molecular structures of [Pd{2-ClC6H3C(H)NCH2CH2SMe}(Cl)] and [{Pd[2-ClC6H3C(H)NCH2CH2SMe]}2{μ-Ph2P(CH2)4PPh2}][CF3SO3]2

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2002 .

Synthesis and reactivity of novel cyclometallated complexes derived from [C,N,O] terdentate ligands. Crystal structure of [Pd{2,3,4-(MeO)3C6HC(H)N[2-(O)C6H4]}(PPh3)]

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2002 .

Reactivity of cyclometallated semicarbazone complexes of Pd(II): crystal and molecular structures of

H. Adams, Jesús J Fernández, Alberto Fernández, 2000 .

Cyclometallated complexes of palladium(II) with a C, N, N′ terdentate Schiff base donor ligand. Oxidative addition of an arylchlorine bond to palladium(O)

Jesús J Fernández, Alberto Fernández, J. Vila, 1997 .

Palladacycles as Functionalized Metal-Ligand Precursors, Contain Tridentate [Csp2, N, S] Ligands

J. Vila, J. Ortigueira, Basma Al Janabi, 2021, ECSOC-25.

Cyclometallated Platinum(II) Complexes with Small Crown Ether Rings: Appropriate Choice of the Bridging Diphosphane to Coordinate Potassium Cations

H. Adams, J. Vila, M. T. Pereira, 2022, ACS omega.

Synthesis, characterization and crystal structures of cyclometallated palladium (II) compounds containing difunctional ligands with [P,P], [As,As], [N,N], [P,As], [P,N] and [P,O] donor atoms

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2008 .

Synthesis of cyclometallated complexes of PdII. The X-ray crystal structure of di-μ-bromo-bis[N-(3,4-dimethoxybenzylidene)cyclohexylaminato-C6,N]dipalladium(II)

M. Thornton-Pett, Jesús J Fernández, J. Vila, 1991 .

A practical and general synthesis of unsymmetrical terphenyls.

K. K. Hii, A. Sousa-Pedrares, J. Vila, 2007, The Journal of organic chemistry.

Palladium iminophosphorane complexes: the pre-cursors to the missing link in triphenylphosphane chalcogenide metallacycles.

H. Adams, J. Vila, M. T. Pereira, 2018, Dalton transactions.

Synthesis and characterization of new heterocyclic Schiff base palladacycles: Ring activation through N-oxide formation

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2009 .

[Pd{2-CH2-5-MeC6H3C(H)NNC(S)NHEt}]3: An unprecedented trinuclear cyclometallated palladium(II) cluster through induced flexibility in the metallated ring

K. K. Hii, Jesús J Fernández, J. Vila, 2009 .

Formation, characterization, and structural studies of novel thiosemicarbazone palladium(II) complexes. Crystal structures of [{Pd[C6H4C(Et)NNC(S)NH2]}4], [Pd{C6H4C(Et)NN C(S)NH2}(PMePh2)] and [{Pd[C6H4C(Et)NNC(S)NH2]}2(µ-Ph2PCH2PPh2)]

H. Adams, M. Graña, Jesús J Fernández, 1999 .

Cyclometallated Palladium(II) Complexes: An Approach to the First Dinuclear Bis(iminophosphorane)phosphane-[C,N,S] Metallacycle

J. Vila, M. T. Pereira, J. Ortigueira, 2022, Molecules.

Palladacycles as Efficient Precatalysts for Suzuki-Miyaura Cross-Coupling Reactions

J. Vila, M. T. Pereira, Fátima Lucio-Martínez, 2019, Palladacycles.

From Chemical Serendipity to Translational Chemistry: New Findings in the Reactivity of Palladacycles

J. Vila, M. T. Pereira, J. Ortigueira, 2018, ChemistryOpen.

Cyclopalladated Compounds with Bulky Phosphine (dppm): Synthesis, Characterization, and X-ray Diffraction

J. Vila, J. Ortigueira, Basma Al Janabi, 2022, The 26th International Electronic Conference on Synthetic Organic Chemistry.

The chelate-to-bridging shift of phosphane dipalladacycles: convenient synthesis of double A-frame tetranuclear complexes.

D. Vázquez-García, J. Vila, M. T. Pereira, 2018, Chemical communications.

Synthesis, coordination properties and DFT studies of novel trans-disubstituted hexaaza-macrocycles containing pyridine and/or ethyldioxolane arms

C. Nuñez, J. Vila, M. T. Pereira, 2018, Journal of Coordination Chemistry.

Synthesis and X-ray Diffraction of Cyclopalladated Compounds Derived from Imine Ligands

J. Vila, J. Ortigueira, B. Al Janabi, 2022, The 26th International Electronic Conference on Synthetic Organic Chemistry.

Functionalized cyclopalladated compounds with bidentate Group 15 donor atom ligands: the crystal and molecular structures of [{Pd[5-(COH)C6H3C(H)NCy-C2,N](Cl)}2(μ-Ph2PRPPh2)] (R=CH2CH2, Fe(C5H4)2], [Pd{5-(COH)C6H3C(H)NCy-C2,N}(Ph2PCH2PPh2-P,P)][PF6] and [Pd{5-(COH)C6H3C(H)N(Cy)-C2,N}(Ph2PCH2CH2AsPh2

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2003 .

Cyclopalladated compounds with bridging and chelating diphosphine ligands. Effect of ring size. Crystal and molecular structure of [{Pd[4-(COH)C6H3C(H)N(Cy)-C2,N](Cl)}2(μ-Ph2PCH2PPh2)]

Jesús J Fernández, Alberto Fernández, M. López-Torres, 2002 .

Synthesis and characterization of cyclometallated complexes of palladium(II) and manganese(I) with bidentate Schiff bases

Jesús J Fernández, Alberto Fernández, J. Vila, 1996 .

Influence of phenyl ring substituents in the cyclometallation of Schiff base ligands: crystal and molecular structures of [Pd-{3,4-(OCH2O)C6H2C(H)N(Cy)-C2,N}(μ-O2CMe)]2 and [Pd-{3,4-(OCH2CH2O)C6H2C(H)N(Cy)-C6,N}(μ-O2CMe)]2

Jesús J Fernández, Alberto Fernández, M. López-Torres, 2000 .

Seeking new metalloligands: Synthesis and reactivity of palladacycles with pyridine and pyrimidine rings

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2009 .

Versatile nuclephilic Michael addition to chelated (Ph2P)2CCH2 (vdpp) in Schiff base cyclometallated palladium(II) compounds: C–C, C–O and C–N bond formation, dinuclear palladacycles and geometrical isomerism

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2012 .

Synthesis and reactivity of new functionalized Pd(II) cyclometallated complexes with boronic esters

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2009 .

Cyclometallation of phenylhydrazones: Synthesis, reactivity, crystal structure analysis and novel trinuclear palladium(II) cyclometallated compounds with [C, N, N′] terdentate ligands

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2005 .

New thiosemicarbazone palladacycles with chelating bis(diphenylphosphino)methane

Javier Martínez, Jesús J Fernández, J. Vila, 2006 .

Cyclometallated Palladium Diphosphane Compounds Derived from the Chiral Ligand (S)-PhCH(Me)NMe2. Michael Addition Reactions to the Vinylidene Double Bond

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2011 .

The key role of sulfur in thiosemicarbazone compounds. Crystal and molecular structure of [Pd{4-MeOC6H4C(Me)NNC(S)NHPh}2]

Javier Martínez, M. Graña, M. López-Torres, 2001 .

Synthesis and reactivity of thiosemicarbazone palladacycles. Crystal structure analysis and theoretical calculations

Javier Martínez, E. Cabaleiro-Lago, J. Vila, 2016 .

Synthesis and structural characterization of tridentate [C,N,S] thiosemicarbazone palladacycles. Crystal and molecular structures of [Pd{3-FC6H3C(Me)NNC(S)NHMe}]4, [Pd{4-FC6H3C(Me)NNC(S)NHEt}]4 and [(Pd{2-BrC6H3C(Me)NNC(S)NHPh})2(μ-Ph2P(CH2)2PPh2)]

Javier Martínez, Alberto Fernández, J. Vila, 2012 .

Reversal of aryl bromide reactivity in Pd-catalysed aryl amination reactions promoted by a hemilabile aminophosphine ligand

K. K. Hii, J. Vila, L. A. Adrio, 2005 .

Preparation of Imidazol‐2‐ylidene Carbene Palladacycles with Bi‐ and Tridentate Schiff Bases – Analyses of the Spectroscopic, Molecular Structure, and DFT Calculation Data

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2016 .

A One-Pot Self-Assembly Reaction To Prepare a Supramolecular Palladium(II) Cyclometalated Complex: An Undergraduate Organometallic Laboratory Experiment

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2012 .

Mononuclear and tetranuclear palladacycles with terdentate [C,N,N] and [C,N,O] Schiff base ligands. C–H versus C–Br activation reactions

Nina Gómez-Blanco, Jesús J Fernández, Alberto Fernández, 2011 .

Functionalized palladium(II) cyclometallated complexes. Crystal and molecular structures of [Pd{3-(CHO)C6H3C(H)NCy}(μ-O2CMe)]2 and [Pd{3-(CHO)C6H3C(H)NCy}(Cl)(PR3)] (PR3=PEtPh2, and PEt2Ph)

Alberto Fernández, M. López-Torres, J. Vila, 2003 .

Polynuclear cyclometallated palladium(II) complexes. Crystal and molecular structures of [(PPh3)(Cl)PdN(Cy)C(H)C6H2C(H)N(Cy) Pd(Cl)(PPh3)] and [{PdN(Cy)C(H)C6H2C(H)N(Cy)Pd}{Ph2PC(H)C(H)PPh2-P,P}2][ClO4]2

Jesús J Fernández, Alberto Fernández, M. López-Torres, 2002 .

Preparation and characterization of terdentate [C,N,N] acetophenone and acetylpyridine hydrazone platinacycles: a DFT insight into the reaction mechanism.

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2017, Dalton transactions.

Synthesis, Characterization, and Crystal Structure Analysis of the First Terdentate [C,N,S] Thiosemicarbazone Complex with a Six-Membered Palladacycle: Influence of Steric Effects on Ring Size†

Javier Martínez, Alberto Fernández, J. Vila, 2006 .

Novel Bidentate [N,S] Palladacycle Metalloligands. 1H–15N HMBC as a Decisive NMR Technique for the Structural Characterization of Palladium–Rhodium and Palladium–Palladium Bimetallic Complexes

Javier Martínez, M. López-Torres, J. Vila, 2014 .

Spectroscopic and solid state characterization of bimetallic terdentate [C,N,S] thiosemicarbazone Palladium(II) metallacycles with bridging and chelating [P,P] diphosphine ligands

Javier Martínez, M. López-Torres, J. Vila, 2013 .

Synthesis and Structural Characterization of New Bimetallic [C,N,S] Palladacycles with Mixed Bridging [P,P] and Chelating [P,P] or [P,N] Phosphane Ligands

Alberto Fernández, J. Vila, M. T. Pereira, 2011 .

Cycloplatination of Thiosemicarbazones Derived from Furane. Crystal and Molecular Structure of [{Pt[(OC4H2)C(Me)=NN=C(S)NHEt]}2{μ‐Ph2P(CH2)2PPh2}]

M. López-Torres, J. Vila, D. Lata, 2007 .

A Comparative Study of Cyclometallated Palladium(II) Compounds with Terdentate [C,N,S] Pincer Ligands − Crystal and Molecular Structure of [Pd{4-MeC6H3C(Me)=NNC(=S)NHMe}(PPh3)] and [Pd{4-MeOC6H3C(H)=N[2-(SMe)C6H4]}(Cl)]

Javier Martínez, M. Graña, Jesús J Fernández, 2002 .

New cyclometallated platinum(II) compounds with thiosemicarbazones: crystal and molecular structure of [Pt{4-MeC6H3C(Me)NNC(S)NH2}(PPh3)]

H. Adams, Jesús J Fernández, Alberto Fernández, 2000 .

Cyclopalladated complexes with functionalized diphosphines via activation of chelated 1,1-bis(diphenylphosphino)ethene

Jesús J Fernández, Alberto Fernández, M. López-Torres, 2002 .

Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations

J. Vila, M. T. Pereira, J. Ortigueira, 2020, ChemistryOpen.

CBr versus CH bond activation in palladium(II) cyclopalladated compounds.

M. Graña, Alberto Fernández, M. López-Torres, 2002 .

Dinuclear cyclometallated platinum(III) complexes. Relationship between molecular structure and crystal packing

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2014 .

Palladium Cyclometallated Compounds: Evaluation of Their Catalytic Activity in Cross-Coupling Reactions

J. Vila, Paula Munín-Cruz, Marcos Rúa-Sueiro, 2022, ECCS 2021.

X-Ray diffraction study of fluorine-functionalized thiosemicarbazones and cyclometallated compounds.

J. Vila, J. Ortigueira, Paula Munín-Cruz, 2022 .

The chemistry of N-benzylidene-1,4-phenylenediamine palladacycles: The crystal and molecular structure of the first tetranuclear palladacycle with bridging Ph2PCH2PPh2 ligands

Jesús J Fernández, Alberto Fernández, J. Vila, 2009 .

Versatile reactivity of dioxaneferrocenylimine palladacycles by controlled acid hydrolysis. Crystal and molecular structure of [Pd{CpFe[η5-C5H2{CH(OMe)2}C(H)N-2,4,6-Me3C6H2]}(Cl)(PPh2Et)]

Javier Martínez, M. López-Torres, J. Vila, 2013 .

Thiosemicarbazone platinacycles with tertiary phosphines. Preparation of novel heterodinuclear platinum–tungsten complexes

Javier Martínez, Jesús J Fernández, J. Vila, 2012 .

Mononuclear cycloplatinated complexes derived from 2-tolylpyridine with N-donor ligands: Reactivity and structural characterization

Jesús J Fernández, Alberto Fernández, D. Vázquez-García, 2012 .

Synthesis of complexes of platinum (II) with C,N,N′-terdentate Schiff base donor ligands. Crystal and molecular structure of [Pt{3-Me-4-MeOC6H2C(H)NCH2CH2NMe2}(Me)]

H. Adams, Jesús J Fernández, Alberto Fernández, 1998 .

Cyclometalated Palladium(II) Fragments as Building Blocks in the Construction of New Heteronuclear Metalomacrocycles

Jesús J Fernández, Alberto Fernández, M. López-Torres, 2001 .

Cyclometallated compounds of manganese(I) with 1-methylphenylimidazoles

J. Vila, A. Suárez, M. Gayoso, 1987 .

Determination of the relative signs of 2J(31P–31P) in complexes of tungsten(0) and molybdenum(0) using two-dimensional [31P–31P]-COSY-45 nuclear magnetic resonance chemical shift correlation

J. Kennedy, B. Shaw, J. Vila, 1987 .

Cyclometalated Complexes with Triphosphine Ligands: A Novel Route for Promoting Pentacoordination in Palladium(II)

H. Adams, Jesús J Fernández, M. López-Torres, 1999 .

Rotation of a double C=N bond driven by palladium

J. Vila, Paula Polo‐Ces, M. Pereira, 2017 .

Cylometallated semicarbazone complexes of palladium(II). Crystal and molecular structure of [{Pd[C6H4C(Et)NN(H)C(O)NH2]}2(μ-Ph2P(CH2)3PPh2)][ClO4]2

Jesús J Fernández, Alberto Fernández, J. Vila, 1998 .

Palladium(II) Cyclometalated Thiosemicarbazone Compounds: A New Class of Bidentate P,S Metallo Ligands

Javier Martínez, Jesús J Fernández, M. López-Torres, 2003 .

Synthesis and catalytic study in the Suzuki-Miyaura reaction of a family of palladium compounds

J. Vila, Francisco Reigosa, M. Pereira, 2017 .

The Ni-mediated cyclocarbonylation of allyl halides and alkynes made catalytic. Evidence supporting the involvement of pseudoradical Ni(i) species in the mechanism.

S. Ricart, J. Vila, J. Moretó, 2005, Journal of the American Chemical Society.