J. López

发表

Synthesis of Furanosyl C‐1 Glycals through Palladium‐Catalyzed Reactions of a Furanosyl 2,3‐Anhydro‐exo‐glycal

A. Barrio, A. M. Gómez, A. Pedregosa, 2009 .

Synthesis of C-1 Alkyl and Aryl Glycals from Pyranosyl or Furanosyl Chlorides by Treatment with Organolithium Reagents

C. Uriel, A. M. Gómez, A. Pedregosa, 2009 .

BODIPYs as chemically stable fluorescent tags on synthetic glycosylation strategies towards fluorescently-labeled saccharides.

C. Uriel, I. García‐Moreno, A. M. Gómez, 2020, Chemistry.

Metathesis reactions of carbohydrates: Recent highlights in cross-metathesis

J. Plumet, J. López, Ana Aljarilla, 2010 .

A Survey of Recent Synthetic Applications of 2,3-Dideoxy-Hex-2-enopyranosides

V. Ferro, A. M. Gómez, J. López, 2015, Molecules.

A Concise Route to Water-Soluble 2,6-Disubstituted BODIPY-Carbohydrate Fluorophores by Direct Ferrier-Type C-Glycosylation

C. Uriel, I. García‐Moreno, A. M. Gómez, 2021, The Journal of organic chemistry.

Towards Efficient and Photostable Red-Emitting Photonic Materials Based on Symmetric all-BODIPY-Triads, -Pentads, and -Hexads.

C. Uriel, I. García‐Moreno, A. M. Gómez, 2019, Chemistry.

A Malonyl-Based Scaffold for Conjugatable Multivalent Carbohydrate-BODIPY Presentations

C. Uriel, A. M. Gómez, J. López, 2019, Molecules.

One-Pot Synthesis of Rotationally Restricted, Conjugatable, BODIPY Derivatives from Phthalides.

I. García‐Moreno, A. M. Gómez, J. López, 2017, The Journal of organic chemistry.

Ready access to a branched Man5 oligosaccharide based on regioselective glycosylations of a mannose-tetraol with n-pentenyl orthoesters.

C. Uriel, A. M. Gómez, J. López, 2012, Organic & biomolecular chemistry.

Glycosyl fluorides from n-pentenyl-related glycosyl donors-application to glycosylation strategies

C. Uriel, A. M. Gómez, J. López, 2013 .

Ready Transformation of Partially Unprotected Thioglycosides into Glycosyl Fluorides Mediated by NIS/HF–Pyridine or Et3N·3HF

C. Uriel, A. M. Gómez, J. López, 2008 .

Convenient Access to Carbohydrate–BODIPY Hybrids by Two Complementary Methods Involving One‐Pot Assembly of “Clickable” BODIPY Dyes

Á. Costela, I. L. Arbeloa, E. Peña‐Cabrera, 2014 .

Arsenic content of Spanish cows' milk determined by dry ashing hydride generation atomic absorption spectrometry

M. L. Cervera, R. Montoro, J. López, 1994, Journal of Dairy Research.

Sonogashira Couplings of Halo‐ and Epoxy‐Halo‐exo‐Glycals: Concise Entry to Carbohydrate‐Derived Enynes

C. Uriel, A. Barrio, A. M. Gómez, 2010 .

Recent Developments in the Ferrier Rearrangement

C. Uriel, A. M. Gómez, J. López, 2013 .

Metathesis reactions of carbohydrates: Recent highlights in cross-metathesis

J. Plumet, J. López, Ana Aljarilla, 2010 .

An expeditious entry to carbohydrate derived enynes and ene-diynes via Sonogashira coupling of halo-exo-glycals

A. Barrio, A. M. Gómez, A. Pedregosa, 2004 .

Stereoselective synthesis of substituted exo-glycals from 1-exo-methylene pyranoses

A. M. Gómez, A. Pedregosa, S. Valverde, 2003 .

A general method for convergent synthesis of functionalized exo-glycals based on halogenation and Suzuki cross-coupling of 1-exo-methylene sugars.

A. M. Gómez, A. Pedregosa, S. Valverde, 2002, Chemical communications.

Reactions at Oxygen Atoms

A. M. Gómez, J. López, 2001 .

Magnetic nanostructured based on cobalt–Zinc Ferrites designed for photocatalytic dye degradation

T. Hogan, F. Muñoz-Muñoz, H. Tiznado, 2021 .

Armed-disarmed effects in carbohydrate chemistry: history, synthetic and mechanistic studies.

J. López, B. Fraser-Reid, J. C. López, 2011, Topics in current chemistry.

A combined intramolecular–intermolecular one-potglycosylation approach for the synthesis of a branched trisaccharide

A. M. Gómez, S. Valverde, J. López, 2000 .

Template directed cyclo-glycosylation: Effect of the anchoring sites of the spacer and temperature in the regio- and stereo-selectivity of the glycosylation

B. Herradón, A. M. Gómez, S. Valverde, 1996 .

A novel strategy for regio- and stereo-control in glycosylation reactions: template-directed cyclo-glycosylation of monosaccharides

B. Herradón, A. M. Gómez, S. Valverde, 1995 .

O-Glycosyl Donors

J. López, J. C. López, 2008 .

Improved synthesis of 2,3:4,6-di-O-isopropylidene-d-glucopyranose and -d-galactopyranose

A. M. Gómez, S. Valverde, J. López, 1999 .

Methyl 1,2‐Orthoesters in Acid‐Washed Molecular Sieves Mediated Glycosylations

C. Uriel, P. Rijo, A. M. Gómez, 2016 .

Access to n-pentenyl tetra- and pentasaccharide analogues of the antitumor drug PI-88 based on 1,2-methyl orthoester glycosyl donors.

C. Uriel, A. M. Gómez, J. López, 2022, Carbohydrate research.

Synthetic Strategies Directed Towards 5a‐Carbahexopyranoses and Derivatives Based on 6‐endo‐trig Radical Cyclizations

C. Uriel, A. M. Gómez, J. López, 2011 .

6-endo Versus 5-exo radical cyclization: streamlined syntheses of carbahexopyranoses and derivatives by 6-endo-trig radical cyclization

C. Uriel, A. M. Gómez, S. Valverde, 2007 .

Six- versus five-membered ring formation in radical cyclization of 1-vinyl-5-methyl-5-hexenyl radicals

C. Uriel, A. M. Gómez, S. Valverde, 2002 .

Novel strategies for the preparation of aminocarbasugar analogues : syntheses of N-substituted aminocyclitols from D-mannose

C. Uriel, E. Moreno, A. M. Gómez, 2005 .

Parlaying C–O chirality into C–C chirality: improving the cost/benefit ratio of carbohydrate templates

J. López, B. Fraser-Reid, J. C. López, 1997 .

Silicon-tethered radical cyclization and intramolecular Diels–Alder strategies are combined to provide a ready route to highly functionalized decalins

A. M. Gómez, J. López, Bert Fraser-Heid, 1993 .

Actinobolin and Bactobolin: Chemical Aspects and Syntheses

J. López, B. Fraser-Reid, J. C. López, 1990 .

Ferrier Rearrangement under Nonacidic Conditions Based on Iodonium-Induced Rearrangements of Allylic n-Pentenyl Esters, n-Pentenyl Glycosides, and Phenyl Thioglycosides

A. M. Gómez, S. Valverde, J. López, 1995 .

n-Pentenyl esters facilitate an oxidative alternative to the Ferrier rearrangement. An expeditious route to sucrose

J. López, B. Fraser-Reid, 1992 .

Synthesis and conformational and biological aspects of carbasugars.

O. Arjona, J. Plumet, A. M. Gómez, 2007, Chemical reviews.

Serial Radical Cyclization of Pyranose-Derived Dienes in the Stereocontrolled Synthesis of Woodward's Reserpine Precursor

A. M. Gómez, J. López, B. Fraser-Reid, 1995 .

Serial Radical Reactions of Glycals: Ready Routes to Highly Functionalized C-Glycosyl Derivatives

A. M. Gómez, J. López, B. Fraser-Reid, 1989 .

Parlaying C—O Chirality into C—C Chirality: Improving the Cost/Benefit Ratio of Carbohydrate Templates

J. López, B. Fraser-Reid, 1998 .

Serial Radical Cyclization of Pyranose-Derived Dienes in the Stereocontrolled Synthesis of Densely Functionalized Cyclohexanes. A Route to Woodward's Reserpine Precursor

A. M. Gómez, J. López, B. Fraser-Reid, 1994 .

Alkoxyl radicals in 1,5-hydrogen shifts for site-specific, stereocontrolled alkylation of carbohydrates

J. López, R. Alonso, B. Fraser-Reid, 1989 .

Synthesis of Pyranoid and Furanoid Glycals from Glycosyl Sulfoxides by Treatment with Organolithium Reagents

A. Barrio, A. M. Gómez, J. López, 2008 .

Stereocontrolled entry to β-C-glycosides and bis-C,C-glycosides from C-glycals: preparation of a highly functionalized triene from d-mannose

A. M. Gómez, S. Valverde, J. López, 2001 .

Efficient routes to pyranosidic homologated conjugated enals and dienes from monosaccharides

G. Lukács, C. Burnouf, J. López, 1993 .

Ferrier rearrangement: an update on recent developments

A. M. Gómez, J. López, Silvia Miranda, 2016 .

A Reverse Strategy for synthesis of nucleosides based on n-pentenyl orthoester donors.

A. M. Gómez, J. López, B. Fraser-Reid, 2013, Chemical communications.

IPy2BF4/HF-pyridine: a new combination of reagents for the transformation of partially unprotected thioglycosides and n-pentenyl glycosides to glycosyl fluorides.

C. Uriel, S. Valverde, J. López, 2007, The Journal of organic chemistry.

IPy2BF4-mediated transformation of n-pentenyl glycosides to glycosyl fluorides: a new pair of semiorthogonal glycosyl donors.

C. Uriel, S. Valverde, J. López, 2007, Organic letters.

Diversity-Oriented Synthetic Endeavors of Newly Designed Ferrier and Ferrier-Nicholas Systems Derived from 1-C-Alkynyl-2-deoxy-2-C-Methylene Pyranosides

A. M. Gómez, J. López, Silvia Miranda, 2018, European Journal of Organic Chemistry.

Ferrier–Nicholas pyranosidic cations: application to diversity-oriented synthesis

C. Uriel, A. M. Gómez, J. López, 2014 .

A substrate-based approach to skeletal diversity from dicobalt hexacarbonyl (C1)-alkynyl glycals by exploiting its combined Ferrier-Nicholas reactivity.

A. M. Gómez, J. López, F. Lobo, 2014, Chemistry.

Carbohydrates to Carbocycles: Regio- and Stereoselectivity in the Intramolecular [2+2] Photocycloaddition of Dienic 2-Enono-δ-lactones

P. Herczegh, A. M. Gómez, S. Valverde, 1998 .

Thioglycoside and trichloroacetimidate donors in regioselective glycosidations. Comparison with n-pentenyl glycosides

C. Uriel, A. M. Gómez, J. López, 2003 .

Ferrier–Nicholas Cations from C-3-Alkynylglycals: Access to C-3-Branched Allylic Glycosides and Ring-Opening Derivatives

A. M. Gómez, J. López, F. Lobo, 2017 .

1‐exo‐Alkylidene‐2,3‐anhydrofuranoses: Valuable Synthons in the Preparation of Furanose‐Based Templates

C. Uriel, A. M. Gómez, A. Pedregosa, 2010 .

Regio- and Stereocontrolled 6-Endo-Trig Radical Cyclization of Vinyl Radicals: A Novel Entry to Carbasugars from Carbohydrates

A. M. Gómez, J. López, G. Danelon, 1998 .

Unexpected remarkable stability of primary ozonides derived from alkenyl stannanes. One-pot synthesis of 1,2-diols from alkynes.

A. M. Gómez, S. Valverde, J. López, 2002, Organic letters.

n-Pentenyl esters versus n-pentenyl glycosides. Synthesis and reactivity in glycosidation reactions

J. López, B. Fraser-Reid, 1991 .

Some studies on proximal addition–elimination procedures in intermolecular carbon–carbon bond-forming free radical reactions. Convenient synthesis of ethyl (E)-(ethyl 2,3,6,7,8-pentadeoxy-α-D-erythro-nona-2,7-dienopyranosid)uronate

J. López, B. Fraser-Reid, A. M. Gómez, 1994 .

Fine tuning of chemo- and stereo-selectivity in cyclization reactions of tethered radicals derived from 4-O-substituted-α-D-erythro-oct-2,6-dienopyranosides. Stereoselective access to carbocycles and branched-chain sugars

A. M. Gómez, J. López, B. Fraser-Reid, 1994 .

A novel entry to cyclohexanes and cyclopentanes from carbohydrates via inversion of radical reactivity in hex-2-enono-δ-lactones

A. M. Gómez, S. Valverde, J. López, 1992 .

Formation and reactivity of new Nicholas-Ferrier pyranosidic cations: novel access to oxepanes via a 1,6-hydride shift/cyclization sequence.

A. M. Gómez, S. Valverde, J. López, 2010, Chemical communications.

Access to 2,6-Dipropargylated BODIPYs as “Clickable” Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility

C. Uriel, I. García‐Moreno, A. M. Gómez, 2021, Organic letters.

Alkyne dicobalt complexes in carbohydrates: Synthetic applications

A. M. Gómez, J. López, 2020 .

Stereodivergent synthesis of 5a-carba-hexopyranoses from carbohydrates via 6-exo-dig radical cyclization: preparation of 5a-carba-β-d-manno-, α-d-allo-, β-l-talo- and α-l-gulopyranose pentaacetates from d-mannose

E. Moreno, A. M. Gómez, S. Valverde, 2003 .

A general stereodivergent strategy for the preparation of carbasugars. Syntheses of 5a-carba-α-d-glucose, α-d-galactose, and β-l-gulose pentaacetates from d-mannose

E. Moreno, A. M. Gómez, S. Valverde, 2002 .

Practical synthesis of an enantiomerically pure intermediate for the lactone moiety of mevinic acids

A. M. Gómez, S. Valverde, J. López, 1992 .

Stereocontrolled entry to 2,5-disubstituted tetrahydrofurans from hex-2-enono-δ-lactones under mild conditions

A. M. Gómez, S. Valverde, J. López, 1992 .

A combined, 6-exo-dig radical cyclization-palladium catalyzed allylic amination, approach to aminocarbasugar analogs: synthesis of novel N-substituted aminocyclitols from D-mannose

E. Moreno, A. M. Gómez, S. Valverde, 2002 .

Reciprocal Donor–Acceptor Selectivity: the Influence of the Donor O‐2 Substituent in the Regioselective Mannosylation of myo‐Inositol Orthopentanoate

C. Uriel, A. M. Gómez, J. López, 2009 .

Relevance of the glycosyl donor to the regioselectivity of glycosidation of primary-secondary diol acceptors and application of these ideas to in situ three-component double differential glycosidation.

C. Uriel, A. Agócs, J. López, 2005, Organic letters.

n-Pentenyl glycosides as mediators in the asymmetric synthesis of monosubstituted chiral nonracemic tetrahydrofurans and .gamma.-lactones

J. M. Llera, J. López, B. Fraser-Reid, 1990 .

Synthesis and Conformational and Biological Aspects of Carbasugars

O. Arjona, J. Plumet, A. M. Gómez, 2007 .

Convergent stereocontrolled synthesis of substituted exo-glycals by Stille cross-coupling of halo-exo-glycals and stannanes

A. Barrio, A. M. Gómez, S. Valverde, 2006 .

Formation and reactivity of novel pyranosidic nicholas oxocarbenium ions: access to C-ketosides and branched-chain C-ketosides.

C. Uriel, A. M. Gómez, S. Valverde, 2006, Organic letters.

Stereoselective synthesis of C-ketosides by Lewis acid-catalyzed C-glycosylation of alkynyl-ketoses

C. Uriel, A. M. Gómez, S. Valverde, 2002 .

A Simple Entry to Pyranoid Glycals: Reaction of Anomeric Glycosyl Sulfoxides with Organolithiums

A. M. Gómez, S. Valverde, J. López, 1996 .

One-pot synthesis of 1-exo-alkylidene-2,3-anhydro furanoses: convenient precursors for exo-glycals and functionalized C-glycals.

A. M. Gómez, A. Pedregosa, S. Valverde, 2002, Chemical communications.

Stereospecific access to equatorially functionalized geminal alkyl derivatives of hexopyranosides by cyclopalladation–oxidation

G. Lukács, J. López, A. Olesker, 1988 .

Expeditious entry to C-alkyl and C-aryl pyranoid glycals: reaction of anomeric glycosyl chlorides with organolithiums

A. M. Gómez, S. Valverde, J. López, 1996 .

Intramolecular Diels-Alder reactions on pyranose trienes. Stereoselective access to bis-annulated pyranosides.

G. Lukács, J. López, A. Ghini, 1990 .

π-Facial selectivity in Diels–Alder reactions of C-2-vinyl glycals. Stereocontrolled route to annulated C-glycopyranosides

G. Lukács, C. Burnouf, F. G. Calvo-Flores, 1990 .

Serial Radical Cyclization of Pyranose‐Derived Dienes in the Stereocontrolled Synthesis of Woodward′s Reserpine Precursor.

A. M. Gómez, J. López, B. Fraser-Reid, 1995 .

A novel entry to C-glycals via diethylzinc-mediated umpolung of π-allyl palladium derived from 1-exo-methylene 2,3-anhydrofuranoses

A. Barrio, A. M. Gómez, A. Pedregosa, 2003 .

Serial Radical Reactions of Glycals: Ready Routes to Highly Functionalized C-Glycosyl Derivatives.

A. M. Gómez, J. López, B. Fraser-Reid, 1995 .

A Stereodivergent Approach to 5a‐Carba‐α‐D‐gluco‐, ‐α‐D‐galacto and ‐β‐L‐gulopyranose Pentaacetates from D‐Mannose, Based on 6‐exo‐dig Radical Cyclization and Barton−McCombie Radical Deoxygenation

E. Moreno, A. M. Gómez, S. Valverde, 2004 .

A novel entry to 5a-carba-hexopyranoses from carbohydrates based on a 6-exo-dig radical cyclization: synthesis of 5a-carba-β-D-mannopyranose pentaacetate

E. Moreno, A. M. Gómez, S. Valverde, 1999 .

Unsaturated Sugars: A Rich Platform for Methodological and Synthetic Studies

J. López, B. Fraser-Reid, 2009 .

Serial Radical Cyclization of Pyranose‐Derived Dienes in the Stereocontrolled Synthesis of Densely Functionalized Cyclohexanes. A Route to Woodward′s Reserpine Precursor.

A. M. Gómez, J. López, B. Fraser-Reid, 1995 .

Alkoxyl Radicals in 1,5-Hydrogen Shifts for Site-Specific, Stereocontrolled Alkylation of Carbohydrates.

J. López, R. Alonso, B. Fraser-Reid, 1989 .

Stereocontrolled Entry to β-C-Glycosides and Bis-C,C-glycosides from C-Glycals: Preparation of a Highly Functionalized Triene from D-Mannose.

A. M. Gómez, S. Valverde, J. López, 2002 .

Synthesis of Pyranoid and Furanoid Glycals from Glycosyl Sulfoxides by Treatment with Organolithium Reagents.

A. Barrio, A. M. Gómez, J. López, 2008 .

Synthesis of Geminal Alkyl and Equatorially Functionalized Geminal Alkyl Derivatives of Hexopyranosides by Carbopalladation

G. Lukács, J. López, A. Olesker, 1989 .

Stereospecificity in Diels–Alder reactions of dienes and dienophiles derived from methyl 4,6-O-benzylidene-α-D-glucopyranoside

G. Lukács, J. López, E. Lameignère, 1988 .

Efficient Routes to Pyranosidic Homologated Conjugated Enals and Dienes from Monosaccharides.

C. Burnouf, J. López, A. Ghini, 1993 .

Chemoselective Conjugate Reduction of α,β-Unsaturated Esters and Lactones Under Mild Conditions

A. M. Gómez, S. Valverde, J. López, 1991 .

Determination of Arsenic in Orange Juice by Dry Ashing Hydride Generation Atomic Absorption Spectrometry

M. L. Cervera, R. Montoro, J. López, 1994 .

Unexpected stereocontrolled access to 1α,1'β-disaccharides from methyl 1,2-ortho esters.

C. Uriel, A. M. Gómez, J. López, 2012, The Journal of organic chemistry.

Two terpenoids from salvia bicolor

S. Valverde, J. López, R. Rabanal, 1985 .

Synthesis of a 28-mer oligosaccharide core of Mycobacterial lipoarabinomannan (LAM) requires only two n-pentenyl orthoester progenitors

K. Jayaprakash, Jun Lu, J. López, 2006 .

Methyl 1,2-Orthoesters as Useful Glycosyl Donors in Glycosylation Reactions: A Comparison with n-Pent-4-enyl 1,2-Orthoesters

C. Uriel, A. M. Gómez, J. López, 2012 .

A novel entry to naturally occurring 5-alkenyl α,β-unsaturated δ-lactones from d-glucose: syntheses of (+)-acetylphomalactone and (+)-asperlin

A. M. Gómez, S. Valverde, J. López, 1997 .

Pyranose glycals in the generation of skeletal diversity

A. M. Gómez, J. López, F. Lobo, 2015 .

Bringing Color to Sugars: The Chemical Assembly of Carbohydrates to BODIPY Dyes

A. M. Gómez, J. López, 2021, Chemical record.

Synthesis of a 28-mer oligosaccharide core of Mycobacterial lipoarabinomannan (LAM) requires only two n-pentenyl orthoester progenitors

K. Jayaprakash, Jun Lu, J. López, 2006 .

Iterative, orthogonal strategy for oligosaccharide synthesis based on the regioselective glycosylation of polyol acceptors with partially unprotected n-pentenyl-orthoesters: further evidence for reciprocal donor acceptor selectivity (RDAS).

C. Uriel, A. Agócs, A. M. Gómez, 2005, Chemical communications.

One pot/two donors/one diol give one differentiated trisaccharide: powerful evidence for reciprocal donor-acceptor selectivity (RDAS).

C. Uriel, K. Radhakrishnan, M. Nandakumar, 2002, Chemical communications.

Unexpected role of O-2 "protecting" groups of glycosyl donors in mediating regioselective glycosidation.

C. Uriel, K. Radhakrishnan, A. M. Gómez, 2002, Journal of the American Chemical Society.

Protecting Groups in Carbohydrate Chemistry Profoundly Influence All Selectivities in Glycosyl Couplings

C. Uriel, K. Jayaprakash, A. M. Gómez, 2008 .

Reciprocal donor acceptor selectivity (RDAS): A new concept for "matching" donors with acceptors

C. Uriel, K. Radhakrishnan, J. López, 2002 .

Reciprocal Donor Acceptor Selectivity (RDAS) and Paulsen’s Concept of “Match” in Saccharide Coupling

C. Uriel, A. M. Gómez, J. López, 2004 .

Synthesis of 2,3:4,6-di-O-isopropylidene-D-allopyranose from D-glucose.

C. Uriel, A. Agócs, A. M. Gómez, 2005, Carbohydrate research.

One Pot/Two Donors/One Diol Give One Differentiated Trisaccharide: Powerful Evidence for Reciprocal Donor—Acceptor Selectivity (RDAS).

C. Uriel, K. Radhakrishnan, M. Nandakumar, 2003 .

A route to functionalized branched-chain amino sugars via nitrous acid promoted spiroaziridine formation

G. Lukács, P. Herczegh, S. Castillón, 1988 .

A Convenient, Short Synthesis of (E)-1,3-Butadienyl(tributyl)stannane

A. M. Gómez, J. López, B. Fraser-Reid, 1993 .

The C4-exo methylene isomer of avermectin B1a: Synthesis via an allylic radical and bioactivity

J. López, R. Faghih, B. Fraser-Reid, 1992 .

Reaction of 1,2-orthoesters with HF-pyridine: a method for the preparation of partly unprotected glycosyl fluorides and their use in saccharide synthesis.

C. Uriel, J. López, Juan Ventura, 2009, Organic Letters.

Reaction of 1,2-orthoesters with HF-pyridine: a method for the preparation of partly unprotected glycosyl fluorides and their use in saccharide synthesis.

C. Uriel, A. M. Gómez, J. López, 2009, Organic letters.

Tuning the Photonic Behavior of Symmetrical bis-BODIPY Architectures: The Key Role of the Spacer Moiety

C. Uriel, I. García‐Moreno, A. M. Gómez, 2019, Front. Chem..