H. Suginome

发表

Novel and convenient method for the stereo- and regiospecific synthesis of conjugated alkadienes and alkenynes via the palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with bromoalkenes and bromoalkynes

Norio Miyaura, N. Miyaura, Akira Suzuki, 1985 .

Stereospecific Synthesis of (2Z,4E,6E)-3,7,11-Trimethyl-2,4,6,10-dodecatetraene [trans(C10)-Allofarnesene]

N. Miyaura, A. Suzuki, H. Suginome, 1982 .

E/Z-Isomerization and Accompanying Photoreactions of Oximes, Oxime Ethers, Nitrones, Hydrazones, Imines, Azo- and Azoxy Compounds, and Various Applications

H. Suginome, 2004 .

Photoinduced molecular transformations. Part 106. Intramolecular addition vsβ-scission of oxyl radicals generated from A-homo-5α-cholest-1-en-4α- and -4β-ol hypoiodites and 4-methyl-A-homo-5α-cholest-1-en-4α- and -4β-ol hypoiodites

H. Suginome, K. Orito, Yoshimasa Yamamoto, 1990 .

A novel alumina-induced intramolecular cyclization accompanied by hydride transfer. Formation of oxepane ring from 3,4-seco-4-iodo-cholest-5-en-3-al

H. Suginome, Kimitoshi Kato, 1973 .

A stereospecific synthesis of conjugated (E, Z)- and (Z, Z)-alikadienes by a palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with 1-alkenyl bromides

N. Miyaura, A. Suzuki, H. Suginome, 1981 .

Replacement of a carbonyl group of camphor by an oxygen atom. Synthesis of 1,7,7-trimethyl-2-oxabicyclo(2.2.1)heptane.

S. Yamada, H. Suginome, 1985 .

New general synthesis of medium ring-lactones via a regioselective β-scission of alkoxyl radicals generated from catacondensed lactols

S. Yamada, H. Suginome, 1987 .

Iodination of Alkyl Aryl Ethers by Mercury(II) Oxide-Iodine Reagent in Dichloromethane

H. Suginome, K. Orito, Takahiro Hatakeyama, 1995 .

Synthesis of 5-Iodobenzofurans and 6-Iodobenzopyrans via Direct Iodination with Mercury(II) Oxide-Iodine Reagent

H. Suginome, K. Orito, M. Tokuda, 1997 .

IODINATION OF BENZOCYCLIC AMINES WITH MERCURY(II)OXIDE-IODINE REAGENT

H. Suginome, K. Orito, M. Tokuda, 1997 .

Synthesis of Phthalideisoquinoline and Protoberberine Alkaloids and Indolo[2,1-a]isoquinolines in a Divergent Route Involving Palladium(0)-Catalyzed Carbonylation(1).

H. Suginome, K. Orito, M. Tokuda, 1999, The Journal of organic chemistry.

Dimerization of Anilines and Benzylamines with Mercury(II) Oxide-Iodine Reagent.

H. Suginome, K. Orito, M. Tokuda, 1998 .

Dimerization of anilines and benzylamines with mercury(II) oxide-iodine reagent

H. Suginome, K. Orito, M. Tokuda, 1998 .

Stereoselective cyclization of δ-alkenylamines catalyzed with butyllithium. Synthesis of cis-N-methyl-2,5-disubstituted pyrrolidines

M. Nitta, H. Suginome, M. Tokuda, 1992 .

Photoinduced molecular transformations. Part 119. Photochemical nitrogen insertion into bicyclo[2.2.1]heptanones; the photochemistry of oximes of (+)-fenchone and (+)-camphor

K. Furukawa, H. Suginome, K. Orito, 1991 .

Photoinduced molecular transformations. Part 159. Formation of some furonaphthyridinones by selective β-scission of cyclobutanoxyl radicals generated from [2+2] photoadducts of 4-hydroxy-1-phenyl [1,8] naphthyridin-2(1H)-one with alkenes☆

H. Suginome, H. Senboku, Kazuhiro Kobayashi, 1996 .

Photochemical formation of cyclic nitrone from nitrite of a fused 5-membered ring alcohol

N. Sato, H. Suginome, T. Masamune, 1971 .

Cross-coupling reactions of 1-alkenylboranes with 3,4-epoxy-1-butene catalyzed by palladium or nickel complexes

N. Miyaura, A. Suzuki, H. Suginome, 1982 .

Photoinduced molecular transformations. Part 133. New photoinduced deconjugation of steroidal α,β-unsaturated cyclic ketone oxime into the β,γ-unsaturated isomer involving stereospecific proton transfer

T. Ohki, H. Suginome, H. Senboku, 1992 .

An efficient electrochemical coupling of allylic halides by using a copper anode.

H. Suginome, M. Tokuda, K. Endate, 1988 .

Formation of cyclic nitrone from nitrite of fused five-membered ring alcohol by photochemical rearrangement (1)

N. Sato, H. Suginome, T. Masamune, 1969 .

Photoinduced Molecular Transformations. Part 142. One‐step syntheses of 1H‐benz[f]indole‐4,9‐diones and 1H‐indole‐4,7‐diones by a new regioselective photoaddition of 2‐amino‐1,4‐naphthoquinones and 2‐amino‐1,4‐benzoquinones with alkenes

H. Suginome, Y. Kanno, Kazuhiro Kobayashi, 1993 .

Photo-induced molecular transformations. Part 123. One-step synthesis of 1H-benz[f]indole-4,9-diones by a new regioselective photoaddition of 2-amino-1,4-naphthoquinone with various alkenes and its application to one-step synthesis of kinamycin skeleton†‡

H. Suginome, Kazuhiro Kobayashi, S. Seko, 1991 .

New facile synthesis of substituted 2-benzylidene-pyrrolidines by the anionic cyclization of δ-alkynylamines

H. Suginome, M. Tokuda, Hirotake Fujita, 1990 .

Hypoiodite reaction of n-acetyljervine: an unprecedented radical addition to a carbonyl generated by β-cleavage of alkoxyl radical (1)

H. Suginome, T. Masamune, Kimitoshi Kato, 1974 .

One-step synthesis of 2,3-dihydronaphtho[2,3-b]thiophene-4,9-diones by a new regioselective [3 + 2] photoaddition of photogenerated 2-mercapto-1,4-naphthoquinone with alkenes

H. Suginome, Kazuhiro Kobayashi, H. Minakawa, 1993 .

Photoinduced molecular transformations. Part 137. New general synthesis of 3-substituted 3,4-dihydro-1H-benzo[2]pyran-1-ones (3,4-dihydroisocoumarins)via radical and photochemical fragmentations as the key step

H. Suginome, Y. Kanno, Kazuhiro Kobayashi, 1993 .

New short step general synthesis of isobenzofuran-1(3H)-ones (phthalides) based on a single or double β-scission of alkoxyl radicals generated from 1-ethyl-benzocyclobuten-1-ols and from 1,3-dihydroisobenzofuran-1-ols; synthesis of some natural phthalides

H. Suginome, Kazuhiro Kobayashi, A. Sasaki, 1991 .

New total synthesis of (+)-N-methylanisomycin by anodic cyclization of δ-alkenylamine

Toshizumi Miyamoto, H. Suginome, M. Tokuda, 1993 .

Stereoselective synthesis of 4- or 5-substituted 2-benzyl- and 2-benzoylpyrrolidines by means of anodic oxidation of δ-alkenylamines

Toshizumi Miyamoto, H. Suginome, M. Tokuda, 1991 .

Photoinduced molecular transformations. Part 156. New photoadditions of 2-hydroxy-1,4-naphthoquinones with naphthols and their derivatiyes☆

H. Suginome, H. Senboku, Kazuhiro Kobayashi, 1995 .

Photoinduced molecular transformations. 140. New one-step general synthesis of naphtho[2,3-b]furan-4,9-diones and their 2,3-dihydro derivatives by the regioselective [3 + 2] photoaddition of 2-hydroxy-1,4-naphthoquinones with various alkynes and alkenes: application of the photoaddition to a two-ste

H. Suginome, Hideki Shimizu, Kazuhiro Kobayashi, 1993 .

Photoinduced molecular transformations. Part 120. New one-step general synthesis of 2,3-dihydronaphtho[2,3-b]-furan-4,9-diones by regioselective photoaddition of 2-hydroxy-1,4-naphthoquinones with various alkenes and its application to a two-step synthesis of maturinone

H. Suginome, Hideki Shimizu, Kazuhiro Kobayashi, 1991 .

Fragmentation in hypoiodite and the related alkoxyl radical-involving reactions of alcohols with nitrogen attached to the β-carbon.

H. Umeda, H. Suginome, T. Masamune, 1970 .

New preparation of reactive zinc metal by electrolysis and its use for a facile isoprenylation of aldehydes and ketones

N. Mimura, H. Suginome, M. Tokuda, 1993 .

A new route to γ-substituted γ-lactones and δ-substituted δ-lactones based on the regioselective β-scission of alkoxyl radicals generated from transannular hemiacetals

H. Suginome, Y. Kanno, Kazuhiro Kobayashi, 1991 .

Photoinduced Molecular Transformations. Part 160. Furan Anneration of 2-Hydroxynaphthoquinone Involving Photochemical Addition and Radical Fragmentation: Exclusion of the Intermediacy of [2+2] Cycloadduct in a One-Pot Formation of Furanoquinones by the Regioselective 3+2 Photoaddition of Hydroxyquin

H. Suginome, H. Senboku, K. Kobayashi, 1997 .

Photoinduced molecular transformations. Part 151. One-pot synthesis of 1H-benz[g]indole-4,5-diones by a regioselective (3+2) photoaddition of 4

H. Suginome, Kazuhiro Kobayashi, A. Sasaki, 1994 .

Studies on carboxylation of alkoxy-substituted benzyl alcohols via direct lithiation and bromine-lithium exchange: Synthesis of phthalides and phthalideisoquinoline alkaloids

Hiroshi Suginome, Kazuhiko Orito, Mamoru Miyazawa, 1995 .

Photoinduced molecular transformations. Part 135. New synthesis of taiwanin C and justicidin E based on a radical cascade process involving β-scission of alkoxyl radicals generated from 3- and 8-aryl-1-ethyl-1,2-dihydrocyclobuta[b]naphthalen-1-ols prepared by thermolysis of (Z)-tert-butyl 3-amino-3-

H. Suginome, Y. Kanno, Kazuhiro Kobayashi, 1992 .

A new synthesis of phthalides through β-scission of benzocyclobutenol hypoiodites

H. Suginome, Kazuhiro Kobayashi, M. Itoh, 1987 .

Electrochemical Conjugate Additions of the Allyl Groups in Substituted Allyl Halides to α,β-Unsaturated Esters

H. Suginome, S. Satoh, M. Tokuda, 1981 .

Palladium-catalyzed cross-coupling of (2-ethoxyvinyl)boranes with aryl and benzyl halides. A new method for conversion of organic halides into aldehydes with two more carbon atoms

N. Miyaura, K. Maeda, H. Suginome, 1982 .

Photoinduced molecular transformations. Part 141. New one-step general synthesis of benzofuran-4,7-diones by the regioselective (3 + 2) photoaddition of 2-hydroxy-1,4-benzoquinones with various alkenes

H. Suginome, Y. Kanno, Kazuhiro Kobayashi, 1993 .

Photoinduced molecular transformations. 110. Formation of furoquinolinones via .beta.-scission of cyclobutanoxyl radicals generated from [2 + 2] photoadducts of 4-hydroxy-2-quinolone and acyclic and cyclic alkenes. X-ray crystal structure of (6a.alpha.,6b.beta.,10a.beta.,10b.alpha.)-(.+-.)-10b-aceto

A. Furusaki, H. Suginome, Kazuhiro Kobayashi, 1990 .

A simple new general synthesis of macrocyclic ketones: A new entry to the synthesis of exaltone and (±)-muscone

S. Yamada, H. Suginome, 1987 .

Benzolactams. 4. Reaction of 3',4'- or 4',5'-dialkoxy-substituted 1-(2'-Bromobenzyl)-2-ethoxycarbonyl-1,2,3,4-tetrahydroisoquinolines with alkyllithium. 1,2 and 1,4 additions of alkyllithium to benzolactams.

H. Suginome, K. Orito, M. Tokuda, 2000, The Journal of organic chemistry.

Regioselectivity in electrochemical allylation of carbonyl compounds. A synthesis of egomaketone by regioselective allylation

H. Suginome, S. Satoh, M. Tokuda, 1989 .

Oxidation with Mercury(II) Oxide-Iodine Reagent: Selective Oxidation of Sulfides to Sulfoxides

H. Suginome, K. Orito, Takahiro Hatakeyama, 1995 .

Oxidation with Mercury(II) Oxide-Iodine Reagent: Selective Oxidation of Sulfides to Sulfoxides

H. Suginome, K. Orito, Takahiro Hatakeyama, 1995 .

Chiroptical studies-part 99: The circular dichroism of seven-membered lactams and lactones

W. Klyne, H. Suginome, J. Tilley, 1980 .

The Absolute and Relative Stereochemical Correlation of Isoflavanone, Sophorol and Naturally-occurring Isoflavan Derivatives

H. Suginome, 1966 .

New stereo- and regiospecific synthesis of humulene by means of the palladium-catalyzed cyclization of haloalkenylboranes

N. Miyaura, A. Suzuki, H. Suginome, 1984 .

Photoinduced molecular transformations. Part 134. Photoinduced stereospecific addition of methanol to 5β-cholest-1-en-3-one oxime and photoinduced deconjugation of its 1-methyl derivative involving stereospecific proton transfer

H. Suginome, H. Senboku, Atsushi Nagaoka, 1992 .

The stereochemistry of dihydrojervine and related compounds

A. Murai, H. Suginome, T. Masamune, 1969 .

Photolysis of nitrites of 30,N-diacetyl-22,27-imino-17, 23-oxidojervan-5-ene-3β, 11α-and -3β,11β-diols

N. Sato, H. Suginome, Tadashi Musamune, 1967 .

The Photo-Beckmann Rearrangement of 3α,5-Cyclo-5α-cholestan-6-one Oxime

H. Suginome, T. Masamune, Hajime Takahashi, 1972 .

Photoinduced molecular transformations. Part 130. Novel stereospecific photorearrangement and stereospecific addition of methanol in steroidal α,β-unsaturated cyclic ketone oximes

S. Yamada, T. Ohtsuka, A. Furusaki, 1992 .

Cyclization of aminyl radicals generated by anodic oxidation of lithium alkenylamides. Stereo- and regioselective synthesis of cis-l-alkyl-2, 5-disubstituted pyrrolidines

A. Furusaki, H. Suginome, M. Tokuda, 1987 .

Photoinduced molecular transformations. Part 138. A new route to dibenzo[a,d]cycloalkanes and their naphtho analogues via the ring expansion of benzocyclobutenols involving a selective β-scission of cyclobutenoxyl radicals generated by photolysis of their hypoiodites

H. Suginome, Kazuhiro Kobayashi, A. Konishi, 1993 .

New general synthesis of medium-sized lactones: A new entry tothe synthesis of (+−)-phoracantholide I [(+−)-decan-9-olide]☆

S. Yamada, H. Suginome, 1985 .

Photoinduced molecular transformations. Part 149. Stereospecific photoadditions and photorearrangements of the oximes of some steroidal α,β-unsaturated cyclic ketones and their deuterio derivatives

T. Ohki, K. Ohshima, H. Suginome, 1994 .

Photoinduced Molecular Transformations. Part 133. New Photoinduced Deconjugation of Steroidal α,β-Unsaturated Cyclic Ketone Oxime into the β,γ-Unsaturated Isomer Involving Stereospecific Proton Transfer.

T. Ohki, H. Suginome, H. Senboku, 1992 .

Photoinduced molecular transformations. Part 132. A two-step intramolecular transposition of the 17β-acetyl group of pregnan-20-one to C-18 through the formation of cyclobutanols by the reaction of the excited carbonyl, followed by a selective β-scission of alkoxyl radicals generated from them

Y. Nakayama, H. Suginome, 1992 .

A new photoinduced rearrangement of steroidal α,β-unsaturated cyclic ketone oximes into the β,γ-unsaturated isomer involving an intramolecular stereospecific hydrogen transfer

T. Ohki, H. Suginome, 1988 .

Photo-induced transformations. Part 76. Ring expansion through a [2 + 2] photocycloaddition-?-scission sequence; the photorearrangement of endo-4-cyanotricyclo[6.4.0.0]dodeca-1(12),6,8,10-tetraen-5-yl hypoiodite to 4-cyanotricyclo[6.4.0.0]dodeca-1 (12),6,8,10-tetraen-5-one. X-Ray crystal structure o

A. Furusaki, C. F. Liu, H. Suginome, 1985 .

Photoinduced molecular transformations. 158. A total synthesis of (.+-.)-methyl piperitol: An unsymmetrically substituted 2,6-diaryl-3,7-dioxabicyclo[3.3.0]octane lignan

H. Suginome, K. Orito, Takahiro Sasaki, 1995 .

The Photo-Beckmann Rearrangement of Steroidal β,γ-Unsaturated Ketone Oximes

H. Suginome, N. Maeda, Yukoh Takahashi, 1981 .

Photo-induced transformations. Part 50. The photo-Beckmann rearrangement of 3α,5-cyclo-5α-cholestan-7-one oxime, a βγ-cyclopropyl ketone oxime

H. Suginome, C. Shea, 1981 .

Photoreaction of D-Nor-5α-androstan-16-one Oxime, a Steroidal Cyclobutanone Oxime

T. Uchida, H. Suginome, 1980 .

Photoinduced transformations. Part 41. Photo-Beckmann rearrangement of some cholestan-3-one oximes with methyl groups attached to the α-carbon

H. Suginome, Yukoh Takahashi, 1980 .

Photoinduced transformations. Part 36. Stereochemical integrity of the terminus of the migrating carbon in the photo-Beckmann rearrangements of some cholestanone oximes

H. Suginome, Fujio Yagihashi, 1978 .

Photo-Beckmann rearrangements of androsterone oxime and 13α-androsterone oxime (1)

T. Uchida, H. Suginome, 1973 .

Tandem cyclization of N-allylaminyl radicals: Stereoselective synthesis of 1,2,5-trisubstituted pyrrolizidines

Hikaru Hasegawa, H. Suginome, H. Senboku, 1999 .

Remote Functionalization by Alkoxyl Radicals Generated by the Photolysis of Nitrite Esters: The Barton Reaction and Related Reactions of Nitrite Esters

H. Suginome, 2004 .

The intermolecular nature of nitric oxide migration in photochemical formation of cyclic nitrones from nitrites of fused five-membered ring alcohols (1)

H. Suginome, T. Masamune, Terutoshi Mizuguchi, 1971 .

Photoinduced molecular transformations. Part 136. Reactions of alkoxyl radicals generated from hypoiodites of 3β-hydroxy-7-oxo-Δ5-steroids. Synthesis of some functionalized oxasteroids

H. Suginome, T. Kondoh, 1992 .

Electrochemical reductive coupling of allyl and benzyl halides in the presence of Cu(acac)2.

H. Suginome, M. Tokuda, Kuniaki Satoh, 1984 .

Synthesis of (E,E)- and (Z,Z)-1,5-Cycloalkadienes by Means of the Electrochemical Cyclization of Allylic 1,ω-Dibromides

H. Suginome, M. Tokuda, Kuniaki Satoh, 1987 .

New synthesis of phthalideisoquinoline alkaloids via a stereoselective hydride reduction of 1-(2'-bromobenzoyl)-3,4-dihydroisoquinoline methiodide, followed by palladium-catalyzed carbonylation aided by chlorotrimethylsilane

H. Suginome, K. Orito, M. Miyazawa, 1994 .

A Simple Synthesis of (±)-cis-(6-Methyltetrahydro-2-pyranyl)acetic Acid, a Constituent of Civet

H. Suginome, Kazuhiro Kobayashi, K. Kobayashi, 1989 .

New and Convenient Synthesis of 3-Methylenepent-4-enoic Acid by Electrochemical Carboxylation

A. Yoshikawa, H. Suginome, H. Senboku, 1997 .

Photoinduced transformations. Part 32. Scrambling of unlabelled and [15N]nitrogen monoxide in the photo-induced rearrangement of (22S,25S)-5α-veratr-13(17)-enin-11β-yl nitrites to nitrones

H. Suginome, T. Masamune, Terutoshi Mizuguchi, 1976 .

The Synthesis and Exhaustive Methylation of 5,6,7,8,9,10,6a,10a-Octahydrophenanthridines and Related Compounds1

H. Suginome, T. Masamune, M. Takasugi, 1964 .

Stereochemical integrity of the terminus of the migrating carbon in photo-Beckmann rearrangements

H. Suginome, Hajime Takahashi, 1970 .

Photoinduced molecular transformations. 104. Pathways of the photorearrangements of five-membered cyclic steroidal .alpha.-nitro ketones to N-hydroxy cyclic imides, cyclic hydroxamic acid, and cyclic imide

H. Suginome, Y. Kurokawa, 1989 .

The Photoinduced Removal of Nitro Groups from Steroidal 6-Membered α,α′-Dinitro Cyclic Ketones

H. Suginome, Y. Kurokawa, 1989 .

The Photochemistry of Steroidal 6-Membered Cyclic α-Nitro Ketones

H. Suginome, K. Orito, Y. Kurokawa, 1988 .

Control of the Stereoselectivity in the Synthesis of 1-Methyl-2,5-disubstituted Pyrrolidines by Mercury(II)-initiated Cyclization of Substituted Alk-4-enylamines

H. Suginome, M. Tokuda, Yasufumi Yamada, 1988 .

Efficient formation of a spirotetrahydrofuran ring by the ionic cyclization of bishomoallyl tertiary alcohols via their hypoiodites

H. Suginome, H. Senboku, Atsuhiko Tsunetoshi, 1992 .

Some Observations on Photolysis of Fused Cyclopentyl Nitrites

N. Sato, H. Suginome, T. Masamune, 1969 .

Aminyl radical cyclization by means of anodic oxidation. Stereoselective synthesis of -1-methyl-2,5-disubstituted pyrrolidines

A. Furusaki, H. Suginome, M. Tokuda, 1985 .

New stereospecific syntheses of pheromone bombykol and its three geometrical isomers

N. Miyaura, A. Suzuki, H. Suginome, 1983 .

Photoinduced molecular transformations. Part 144. One-carbon intercalation of γ- and δ-lactones involving the β-scission of alkoxyl radicals as the key step: synthesis of δ- and Îµ-lactones with α-substituents

H. Suginome, Kazuhiro Kobayashi, H. Minakawa, 1993 .

Industrial Electroorganic Synthesis in Europe

F. Beck, H. Suginome, 1991 .

Electrochemical Additions of the Allyl and the Benzyl Groups of Allyl and Benzyl Halides to Acetone

H. Suginome, S. Satoh, M. Tokuda, 1983 .

Regioselectivity in electrochemical additions of the allyl groups in substituted allyl halides to α,β-unsaturated esters or acetone

H. Suginome, S. Satoh, M. Tokuda, 1981 .

New Efficient Electrochemical Allylation of Aldehydes and Ketones with a Cadmium-modified Electrode

H. Suginome, M. Tokuda, M. Uchida, 1990 .

New stereoselective synthesis of trans-2,5-disubstituted pyrrolidines by cyclization of aminyl radicals generated from 2- and/or 5-substituted N-chloro-N-alkylalk-4-enylamines with Bu3SnH-azoisobutyronitrile

H. Suginome, M. Tokuda, Hirotake Fujita, 1994 .

Photoinduced molecular transformations. Part 154. On the mechanism of the formation of the 5-iodopentyl formate in the photolysis of cyclopentanol hypoiodite in solution in the presence of mercury(II) oxide-iodine.

H. Suginome, H. Senboku, 1994 .

Synthesis and Photoreaction of D-Nor-5α-androstan-16-one Acetylhydrazone in the Presence of Oxygen

T. Uchida, H. Suginome, T. Masamune, 1980 .

Photoinduced molecular transformations. Part 107. A versatile substitution of a carbonyl group of steroidal ketones by a heteroatom. The synthesis of aza-, oxa-, thia-, selena-, and tellurasteroids

Jian Bo Wang, S. Yamada, H. Suginome, 1990 .

The replacement of the carbonyl group of adamantanone by an oxygen or sulfur atom and the one-step transformation of 2-methyladamantan-2-ol into 2-oxa-adamantane. An efficient new synthesis of 2-oxa- and 2-thiaadamantane

S. Yamada, H. Suginome, 1986 .

Replacement of a carbonyl group of cyclic ketones by an oxygen atom: A four-step transformation of cyclic ketones into cyclic ethers

S. Yamada, H. Suginome, 1984 .

An Efficient Synthesis of 5,7-Dihydroxy-4-methylisobenzofuran-1(3N)-one, a Metabolite of aspergillus flavus and a Key Intermediate in the Synthesis of Mycophenolic Acid

H. Suginome, Hideki Shimizu, Kazuhiro Kobayashi, 1990 .

Photoinduced molecular transformations. Part 106. The formation of cyclic anhydrides via regioselective β-scission of alkoxyl radicals generated from 5-and 6-membered α-hydroxy cyclic ketones

Jian Bo Wang, S. Yamada, H. Suginome, 1990 .

Photoinduced Molecular Transformations. 157. A New Stereo- and Regioselective Synthesis of 2,6-Diaryl-3,7-dioxabicyclo[3.3.0]octane Lignans Involving a .beta.-Scission of Alkoxyl Radicals as the Key Step. New Total Syntheses of (.+-.)-Sesamin, (.+-.)-Eudesmin, and (.+-.)-Yangambin

H. Suginome, K. Orito, Takahiro Sasaki, 1995 .

A new stereo- and regioselective synthesis of (±)-sesamin involving a β-scission of alkoxyl radicals as the key step1

H. Suginome, K. Orito, K. Yorita, 1991 .

Photoinduoed molecular transformations. Part 146. Photoacylation and photoalkylation of 2-arylamino- and 2-alkylamino-1,4-naphthoquinones

H. Suginome, Masayoshi Suzuki, H. Takeuchi, 1994 .

Reaction and Synthetic Application of Oxygen- Centered Radicals Photochemically Generated from Alkyl Hypohalites

H. Suginome, 2003 .

Intramolecular β,γ-addition of allylic alkoxyl radicals. A new general synthesis of α-iodoepoxides by photolysis of allylic alcohol hypoiodites in the presence of mercury(II) oxide, iodine and pyridine in benzene

Jian Bo Wang, H. Suginome, 1990 .

Photoinduced molecular transformations. Part 153. Long-range intramolecular hydroxylation of C(25) of the cholestane side chain

H. Suginome, K. Orito, Shinji Sato, 1995 .

Photoinduced molecular transformations. CXXXXVII: [2+2] Photoaddition of protected 4-hydroxy-1(2H)-isoquinolinone with an electron-deficient alkene and the formation of a 3,6-epoxy-3,4,5,6-tetrahydro-2-benzazocin-1(2H)-one via a β-scission of cyclobutanoxyl radicals generated from the resulting phot

H. Suginome, H. Senboku, Masayoshi Suzuki, 1994 .

A new synthesis of a functionalized bicyclo[5.4.0]undecane skeleton based on a sequence involving [2 + 2] photoaddition and regioselective β-scission of alkoxyl radicals generated from the resulting cyclobutanols

Y. Nakayama, H. Suginome, K. Orito, 1994 .

Photoinduced molecular transformations. Part 150. A new total synthesis of (±)-α-Himachalene based on a Sequence involving [2+2] photoaddition and regioselective β-scission of alkoxyl radicals generated from the resulting cyclobutanols

H. Suginome, Y. Nakayama, 1994 .

Photoinduced molecular transformations. Part 113. One-step transformations of cyclic ethers into ω-iodoalkyl formates and of aldehyde cyclic acetals into monoesters of α,ω-alkanediols by iodoxyl radical

Jian Bo Wang, H. Suginome, 1990 .

A long-range intramolecular functionalization by alkoxyl radicals: a long-range intramolecular oxygenation of C(15) of the androstane skeleton

H. Suginome, K. Orito, M. Ohto, 1990 .

Photoinduced molecular transformations. Part 112. Transformation of steroids into ring-A-aromatized steroids and 19-norsteroids involving a regioselective β-scission of alkoxyl radicals; synthesis of two marine natural products, 19-nor-5α-cholestan-3β-ol and 19-norcholest-4-en-3-one, and new synthes

S. Yamada, H. Suginome, H. Senboku, 1990 .

Replacement of an 11-Carbonyl Group of 11-Oxo Steroid by an Oxygen Atom. A New Partial Synthesis of 11-Oxaprogesterone

Jian Bo Wang, H. Suginome, 1989 .

Regioselective β-scission of α-oxoalkoxyl radicals: a novel formation of α-hydroxy Îµ-lactones by photolysis of steroidal α-oxo alcohol hypoiodites in the presence of mercury(II) oxide and iodine

Jian Bo Wang, H. Suginome, G. Satoh, 1989 .

A Simple New Synthesis of Macrolides by a Four Atom Ring Expansion of Cyclic Ketones through a Consecutive Intramolecular Homolytic Addition—β-Scission of Alkoxyl Radicals. A New Entry to the Synthesis of 15-Pentadecanolide (Exaltolide)

S. Yamada, H. Suginome, 1988 .

The Transformation of Cyclic Alcohols into Cyclic Acetals through a New Oxygen Atom Insertion by Photolysis in the Presence of Lead Tetraacetate and Iodine

S. Yamada, H. Suginome, H. Washiyama, 1987 .

Photoinduced transformations. 76. A four-step substitution of a carbonyl group of steroidal ketones by an oxygen atom. A new method for the synthesis of cyclic ethers

S. Yamada, H. Suginome, 1985 .

Photoinduced transformations. Part 73. Transformations of five- (and six-) membered cyclic alcohols into five- (and six-) membered cyclic ethers - a new method of a two-step transformation of hydroxy steroids into oxasteroids

S. Yamada, H. Suginome, 1984 .

Photo-induced transformations. Part 69. The formation of bridged oxabicyclic compounds by intramolecular radical addition of oxyl radicals generated from B-homocholest-5-en-7a-ol hypoiodites

A. Furusaki, H. Suginome, S. Isayama, 1984 .

The Transformation of Jervine into 18-Functional C-Nor-D-homosteroids

H. Suginome, T. Masamune, Norihisa Yonekura, 1980 .

PHOTO-INDUCED REARRANGEMENT OF WIDDROL HYPOIODITE

Masaaki Ito, H. Suginome, T. Masamune, 1979 .

Stereochemical Aspects of the Photo-Beckmann Rearrangement. Stereochemical Integrity of the Terminus of the Migrating Carbon in the Photo-Beckmann Rearrangements of 5α- and 5β-Cholestan-6-one Oximes

H. Suginome, Hajime Takahashi, 1975 .

Transformation of epiandrosterone into 3-oxa-, 3-thia-, 3-selena-, and 3-aza-17-oxaandrostanes of the 5α series based on β-scission of alkoxyl radicals

Jian Bo Wang, H. Suginome, 1990, Steroids.

Long-range intramolecular functionalization by alkoxyl radicals; long-range intramolecular double functionalization of ring c of cholestane and androstane skeletons1

H. Suginome, K. Orito, Naoto Sugawara, 1990 .

Photoinduced molecular transformations. Part 131. Synthesis of 18-norsteroids, deoxofukujusonorone and the related steroids, based on a selective β-scission of alkoxyl radicals as the key step

Y. Nakayama, H. Suginome, H. Senboku, 1992 .

Intramolecular β,γ‐Addition of Allylic Alkoxyl Radicals. A New General Synthesis of α‐Iodo Epoxides by Photolysis of Allylic Alcohol Hypoiodites in the Presence of Mercury(II) Oxide, Iodine, and Pyridine in Benzene.

Jian Bo Wang, H. Suginome, 1991 .

Synthesis of Some Five- and Six-Membered Oxasteroids of Cholestane Series by Ring Contraction and the Mass Spectrometric Fragmentations of Oxasteroids

S. Yamada, H. Suginome, 1987 .

Photoinduced molecular transformations. Part 143. (2 + 2) Photoaddition of 3-hydroxy-1-benzopyran-2-one, 3-benzyloxycarbonyloxy-1-benzopyran-2-one, and their 8-methoxy derivatives, with alkenes and formation of 1,2-disubstituted 1,2-dihydrofuro[2,3-c][1]benzopyran-4-ones by way of β-scission of cycl

H. Suginome, Masayoshi Suzuki, K. Kobayashi, 1993 .

Studies on Friedel-Crafts acylation of N-acetylhomoveratrylamine and preparation of 1-substituted 3,4-dihydro-6,7-dimethoxyisoquinolines

R. Rodrigo, H. Suginome, K. Orito, 1988 .

The Synthesis of d, l-Homopterocarpin

T. Iwadare, H. Suginome, 1966 .

The Synthesis of the Pterocarpin Ring System

T. Iwadare, H. Suginome, 1960 .

Iodination of Alkyl Aryl Ethers by Mercury(II) Oxide-Iodine Reagent in Dichloromethane.

H. Suginome, K. Orito, Takahiro Hatakeyama, 1996 .

INSERTION OF OXYGEN ATOM INTO FUSED CYCLOBUTANE RINGS VIA AN ALKOXYL RADICAL REARRANGEMENT

A. Furusaki, H. Suginome, C. Liu, 1984 .

The Photo-induced Radical Rearrangement of 7-Oxocholesteryl Hypoiodite in the Presence of Mercury(II) Oxide and Iodine

H. Suginome, Fumihiro Yonebayashi, 1982 .

Photo-induced Radical Rearrangements of Hypoiodite of N-Acetyljervine and the Related C-nor-D-Homosteroid in the Presence of Mercury(II) Oxide and Iodine

H. Suginome, T. Masamune, Kimitoshi Kato, 1981 .

Relationship between NMR deshielding effects and nitrite photolysis in 3α,5α-cyclocholestane-6β-ol☆

H. Suginome, T. Masamune, Tatsuro Tsuneno, 1967 .

Synthesis of 5‐Iodobenzofurans and 6‐Iodobenzopyrans via Direct Iodination with Mercury(II) Oxide‐Iodine Reagent.

H. Suginome, K. Orito, M. Tokuda, 1997 .

New general synthesis of tert-butyl 3-amino-2-naphthalenecarboxylates by an electrocyclic reaction of o-quinonedimethides generated from tert-butyl (Z)-3-amino-3-(bicyclo[4.2.0]octa-1,3,5-trien-7-yl)prop-2-enoates

H. Suginome, Y. Kanno, S. Seko, 1992 .

Regioselective synthesis of β,γ-unsaturated acids by the electrochemical carboxylation of allylic bromides using a reactive-metal anode

Masao Tokuda, Takashi Kabuki, Yoshitaka Katoh, 1995 .

Electrochemical Carboxylation of Propargylic Halides by the Use of Reactive-metal Anode

H. Suginome, M. Tokuda, Takashi Kabuki, 1994 .

A One Step Transformation of a 7-Oxo Steroid into a 7-Oxa Steroid. A New Photo-oxidation of Cyclic Ketone

H. Suginome, C. Shea, 1980 .

Oxygen Heterocycles. A New Isoflavanone from Sophora japonica, L.

H. Suginome, 1959 .

Oxygen heterocycles. Maackiain, a new naturally occurring chromanocoumaran

H. Suginome, 1962, Experientia.

Oxygen heterocycles the structure of the isoflavanone sophorol

H. Suginome, 1960 .

Monochromatic Light-induced Reactions of Benzophenone Hydrazones and the N-Acetyl Derivatives in Carbon Tetrachloride in the Presence of Oxygen

T. Uchida, H. Suginome, 1980 .

A facile ring contraction of widdrol involving photolysis of the nitrite ester.

Masaaki Ito, H. Suginome, Hajime Takahashi, 1977 .

Synthesis of S-Methyl 2-Hydroxyalkanethioates, 2-Hydroxyalkanoic Acids and Related Compounds via the Addition Reaction of Tris(methylthio)methanide Ion to Alkanals

T. Iwadare, H. Suginome, K. Orito, 1989 .

Photoinduced molecular transformations. Part 145. Regioselective [3 + 2] photoadditions of 2-hydroxyphenanthrene-1,4-dione with electron-rich alkenes and phenylacetylene: new one-step synthesis of 9,10-dihydrophenanthro[2,3-b]furan-7,11-diones and 2-phenylphenanthro[2,3-b]furan-7,11-dione

H. Suginome, H. Senboku, Hisato Kamekawa, 1994 .

On the Mechanism of the Formation of Steroidal Cyclic Hydroxamic Acids in the Photolysis of Steroidal 17β-ol Nitrite

H. Suginome, T. Masamune, Terutoshi Mizuguchi, 1977 .

Synthesis of 2-Pyrrolidinylideneacetates by Means of a Reaction of Magnesium Ester Enolate with γ-Cyanoalkyl Tosylates

H. Suginome, K. Kobayashi, 1986 .

The transformation of 11-deoxojervine into 18-functional C-nor-D-homosteroids.

N. Sato, H. Suginome, T. Masamune, 1979 .

Synthesis of c-18-functionalized c-nor-d-homosteroid by hypoiodite reaction

N. Sato, H. Suginome, T. Masamune, 1969 .

Photoinduced molecular transformations. Part 127. A new [2 + 2] photoaddition of 2-amino-1,4-naphthoquinone with vinylarenes and the synthesis of 2,3-dihydronaphtho[1,2-b]furan-4,5-diones and 2,3-dihydronaphtho[2,3-b]furan-4,9-diones by β-scission of alkoxyl radicals generated from the resulting pho

H. Suginome, A. Sasaki, H. Takeuchi, 1992 .

New short step synthesis of A,B-aromatic oxasteroids by intra- and intermolecular Diels–Alder reactions of 1,2-naphthoquinone dimethides generated from substituted 1,2-cyclobutanaphthalenes

H. Suginome, M. Itoh, K. Kobayashi, 1991 .

Photolysis of Nitrite Esters bearing Nitrogen on the β-Carbon

H. Suginome, T. Masamune, Masakazu Murakami, 1968 .

Ring expansion through [2+2] photocycloaddition-β-scission sequence. Two carbon ring expansions of β-indanone and β-tetralone

H. Suginome, M. Itoh, K. Kobayashi, 1987 .

Ring Expansion Through (2 + 2) Photocycloaddition - β-Scission Sequence. Two Carbon Ring Expansions of β-Indanone and β-Tetralone.

H. Suginome, M. Itoh, K. Kobayashi, 1988 .

New route to phthalideisoquinoline alkaloids: synthesis of (±)-cordrastine I and II

R. Rodrigo, H. Suginome, S. O. D. Silva, 1987 .

Synthesis of Dimethyl 1,2-Cycloalkanedicarboxylates by Electrochemical Cyclization of Dimethyl α,α′-Dibromoalkanedioates Using a Copper Anode

H. Suginome, M. Tokuda, Atsushi. Hayashi, 1991 .

Photo-induced molecular transformations. Part 87. Regiospecific photo-Beckmann rearrangement of steroidal α,β-unsaturated ketone oximes: synthesis of some steroidal enamino lactams

S. Yamada, H. Suginome, M. Kaji, 1988 .

SYNTHESIS OF (±)-NOROORALYDINE AND (±)-TETRAHYDROPALMATINE

H. Suginome, K. Orito, T. Matsuzaki, 1989 .

NEW ANIONIC CYCLIZATION OF 4- AND 5-ALKYNYLAMINES : SYNTHESIS OF 2-BENZYLIDENE PYRROLIDINES AND PIPERIDINES

M. Nitta, H. Suginome, Hirotake Fujita, 1996 .

New Anionic Cyclization of 4‐ and 5‐Alkynylamines: Synthesis of 2‐ Benzylidene Pyrrolidines and Piperidines.

M. Nitta, H. Suginome, Hirotake Fujita, 1996 .

Revision of the C12 configuration of dihydrojervine

H. Suginome, T. Masamune, H. Ono, 1969 .