M. Karni

发表

Ab‐Initio Calculations and Ideal Gas Thermodynamic Functions of Cyclopentadiene and Cyclopentadiene Derivatives

A. Burcat, M. Karni, I. Oref, 1991 .

Theoretical Aspects of Compounds Containing Si, Ge, Sn and Pb

P. Schleyer, Y. Apeloig, M. Karni, 2003 .

Synthesis of an Isolable Bis(silylene)-Stabilized Silylone and Its Reactivity Toward Small Gaseous Molecules.

M. Driess, Y. Apeloig, Shenglai Yao, 2019, Journal of the American Chemical Society.

Preparative separation of isomeric and stereoisomeric dicarboxylic acids by pH-zone-refining counter-current chromatography.

M. Karni, A. Weisz, A. Mandelbaum, 2007, Journal of chromatography. A.

Thermochemistry and unimolecular reactions of ionized 1,2-dimesityl-2-phenylethanone and 2,2-dimesityl-1-phenylethanone and their enols and enol acetates in the gas phase

Z. Rappoport, C. Lifshitz, M. Karni, 1981 .

Structure and conformation of heterocycles. 16. Probing the anomeric effect. Trimethylsilyloxy and tert-butoxy substituents in 1,4-dioxane derivatives: theory vs. experiment

Israel Goldberg, Yitzhak Apeloig, Benzion Fuchs, 1987 .

Structure and Conformation of Heterocycles. Part 16. Probing the Anomeric Effect. Trimethylsilyloxy and tert-Butoxy Substituents in 1,4-Dioxane Derivatives: Theory vs. Experiment

I. Goldberg, P. Aped, Y. Apeloig, 1987 .

The Lise Meitner‐Minerva Center for Computational Quantum Chemistry: 18 Years of Israeli‐German Collaboration

S. Shaik, Y. Apeloig, D. Danovich, 2015 .

Substituent effects on the geometries and energies of the silicon-silicon double bond

Y. Apeloig, M. Karni, 1990 .

The effect of substituents on the first transition in the visible spectra of silanediyls (silylenes)

Y. Apeloig, M. Karni, 1985 .

The role of hydride migration in the mechanism of alcohol elimination from protonated ethers upon chemical ionization

Y. Apeloig, M. Karni, A. Mandelbaum, 2003 .

Why Is Methylene a Ground State Triplet while Silylene Is a Ground State Singlet

R. West, Y. Apeloig, M. Karni, 2003 .

Solid-state (29)Si NMR study of RSiSiR: a tool for analyzing the nature of the Si-Si bond.

R. West, A. Sekiguchi, Y. Apeloig, 2006, Journal of the American Chemical Society.

Preparation of a silanone through oxygen atom transfer to a stable cyclic silylene.

P. Schreiner, T. Müller, Y. Apeloig, 2015, Angewandte Chemie.

Silynes (RC≡SiR') and Disilynes (RSi≡SiR'): Why Are Less Bonds Worth Energetically More?

D. L. Cooper, S. Shaik, Y. Apeloig, 2001, Angewandte Chemie.

Silicon-Centered Radicals

Y. Apeloig, M. Karni, B. Tumanskii, 2017 .

HCSiF and HCSiCl: The First Detection of Molecules with Formal C≡Si Triple Bonds.

R. Rabezzana, H. Schwarz, Y. Apeloig, 1999, Angewandte Chemie.

Persistent and Stable Silyl Radicals

Y. Apeloig, M. Karni, B. Tumanskii, 2012 .

Activation of pentafluorophenylsilanes by weak Lewis bases in reaction with iminium cations.

V. V. Levin, Y. Apeloig, M. Karni, 2006, The Journal of organic chemistry.

Si=X multiple bonding with four-coordinate silicon? Insights into the nature of the Si=O and Si=S double bonds in stable silanoic esters and related thioesters: a combined NMR spectroscopic and computational study.

J. Epping, M. Driess, Y. Apeloig, 2010, Journal of the American Chemical Society.

Formation of three new bonds and two stereocenters in acyclic systems by zinc-mediated enantioselective alkynylation of acylsilanes, Brook rearrangement, and ene-allene carbocyclization reactions.

C. Bolm, Y. Apeloig, I. Marek, 2014, The Journal of organic chemistry.

The ‘even‐electron rule’

M. Karni, A. Mandelbaum, 1980 .

One-pot zinc-promoted asymmetric alkynylation/brook-type rearrangement/ene-allene cyclization: highly selective formation of three new bonds and two stereocenters in acyclic systems.

C. Bolm, Y. Apeloig, I. Marek, 2013, Angewandte Chemie.

Were reactions of triplet silylenes observed?

Y. Apeloig, M. Karni, M. Kosa, 2013, Journal of the American Chemical Society.

A theoretical survey of unsaturated or multiply bonded and divalent silicon compounds. Comparison with carbon analogs

J. Chandrasekhar, B. Luke, J. Pople, 1986 .

Substituent Effects on the Carbon-Silicon Double Bond. Monosubstituted Silenes

Y. Apeloig, M. Karni, 1984 .

Rearrangement vs. dissociation of gaseous silicon-containing cations: a combined experimental–theoretical approach

H. Schwarz, Y. Apeloig, G. Czekay, 1987 .

Theoretical Aspects and Quantum Mechanical Calculations of Silaaromatic Compounds

Y. Apeloig, M. Karni, 1999 .

Trisilaallene and the Relative Stability of Si3H4 Isomers.

Y. Apeloig, M. Karni, M. Kosa, 2006, Journal of chemical theory and computation.

Stereoselectivity of alkylidenecarbene addition to olefins. 2. Effect of orbital polarization in the alkenes

P. Stang, M. Karni, A. Yitzhak, 1986 .

Synthesis, molecular structure, and reactivity of the isolable silylenoid with a tricoordinate silicon.

Y. Apeloig, G. Molev, M. Karni, 2006, Journal of the American Chemical Society.

An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity.

M. Driess, Y. Apeloig, Shenglai Yao, 2018, Journal of the American Chemical Society.

Heavier congeners of CO and CO2 as ligands: from zero-valent germanium (‘germylone’) to isolable monomeric GeX and GeX2 complexes (X = S, Se, Te)

M. Driess, Y. Apeloig, Shenglai Yao, 2016, Chemical science.

A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity.

M. Driess, Y. Apeloig, Shenglai Yao, 2016, Angewandte Chemie.

Stereoselectivity of Alkylidenecarbene Addition to Olefins. Part 2. Effect of Orbital Polarization in the Alkenes

P. Stang, Y. Apeloig, M. Karni, 1986 .

The selectivity of isopropylidenecarbene

P. Stang, Y. Apeloig, M. Karni, 1986 .

Isomerization of cyclopropene to allene and propyne at elevated temperatures: experimental, ab initio, and model calculations

A. Lifshitz, M. Karni, I. Oref, 1988 .

(tBu2MeSi)2Sn=Sn(SiMetBu2)2: a distannene with a >Sn=Sn< double bond that is stable both in the solid state and in solution.

M. Nakamoto, A. Sekiguchi, Y. Apeloig, 2006, Journal of the American Chemical Society.

Continuous symmetry analysis of NMR chemical shielding anisotropy.

David Avnir, D. Avnir, Miriam Karni, 2006, Chemistry.

Mechanism of keto Å enol tautomerism of ionized vinyl alcohol versus acetaldehyde and their dissociation to C2H3O+ and H·. An ab initio molecular orbital study

G. Frenking, B. Ciommer, H. Schwarz, 1984 .

A single crystal molecular structure determination and theoretical calculations on alkynyl carboxylate esters

P. Stang, Y. Apeloig, T. Kitamura, 1990 .

MECHANISM OF CARBON DIOXIDE ELIMINATION FROM IONIZED METHYL HALOACETATES IN THE GAS PHASE. FORMATION OF CH3XCH2+.CNTDOT. AND CH3XCHX+.CNTDOT. (X = CL, BR) HALONIUM RADICAL IONS

G. Frenking, B. Ciommer, H. Schwarz, 1983 .

The stabilities of α-oxy and α-thio carbenium ions: the importance of the ground-state energies of the neutral precursors

Y. Apeloig, M. Karni, 1988 .

Novel stable ion/dipole complexes of HF and HCl with halocarbenes

G. Frenking, B. Ciommer, H. Schwarz, 1984 .

NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS. PART 29. ROLE OF HYPERCONJUGATION IN DETERMINING THE STEREOCHEMISTRY OF NUCLEOPHILIC EPOXIDATION AND CYCLOPROPANATION OF ELECTROPHILIC OLEFINS

Y. Apeloig, Z. Rappoport, M. Karni, 1983 .

Observation of a thermally accessible triplet state resulting from rotation around a main-group π bond.

A. Sekiguchi, Y. Apeloig, M. Ichinohe, 2015, Angewandte Chemie.

Conjugation, Resonance, and Stability in N-Heterocyclic Silylenes and in Phosphorus Ylide Substituted Silylenes

Y. Apeloig, M. Karni, 2012 .

Proton transfer in liquid ammonia solutions containing water and hydroxide ion—II

M. Karni, S. Marks, 1976 .

How to design linear allenic-type trisilaallenes and trigermaallenes.

Y. Apeloig, M. Karni, M. Kosa, 2004, Journal of the American Chemical Society.